CN1810146A - Production process of natural mineral lick additive - Google Patents
Production process of natural mineral lick additive Download PDFInfo
- Publication number
- CN1810146A CN1810146A CNA2006100378646A CN200610037864A CN1810146A CN 1810146 A CN1810146 A CN 1810146A CN A2006100378646 A CNA2006100378646 A CN A2006100378646A CN 200610037864 A CN200610037864 A CN 200610037864A CN 1810146 A CN1810146 A CN 1810146A
- Authority
- CN
- China
- Prior art keywords
- additive
- lick
- natural mineral
- mineral
- production method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 66
- 239000011707 mineral Substances 0.000 title claims abstract description 66
- 239000000654 additive Substances 0.000 title claims abstract description 26
- 230000000996 additive effect Effects 0.000 title claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 20
- 239000000440 bentonite Substances 0.000 claims abstract description 12
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 12
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004927 clay Substances 0.000 claims abstract description 11
- 239000004575 stone Substances 0.000 claims abstract description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 28
- 230000004913 activation Effects 0.000 claims description 13
- 230000020477 pH reduction Effects 0.000 claims description 13
- 229910021536 Zeolite Inorganic materials 0.000 claims description 9
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 9
- 239000010457 zeolite Substances 0.000 claims description 9
- 239000000428 dust Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000010298 pulverizing process Methods 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 3
- 235000010755 mineral Nutrition 0.000 abstract description 51
- 241001465754 Metazoa Species 0.000 abstract description 33
- 241001494479 Pecora Species 0.000 abstract description 12
- 239000011573 trace mineral Substances 0.000 abstract description 8
- 235000013619 trace mineral Nutrition 0.000 abstract description 8
- 229910052791 calcium Inorganic materials 0.000 abstract description 5
- 229910052749 magnesium Inorganic materials 0.000 abstract description 5
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 5
- 229910052708 sodium Inorganic materials 0.000 abstract description 5
- 229910052700 potassium Inorganic materials 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 2
- 229910052717 sulfur Inorganic materials 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 230000003213 activating effect Effects 0.000 abstract 1
- 229960000892 attapulgite Drugs 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 238000003801 milling Methods 0.000 abstract 1
- 238000012856 packing Methods 0.000 abstract 1
- 229910052625 palygorskite Inorganic materials 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
- 239000011449 brick Substances 0.000 description 26
- 241000283690 Bos taurus Species 0.000 description 11
- 235000016709 nutrition Nutrition 0.000 description 10
- 235000013379 molasses Nutrition 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 230000035764 nutrition Effects 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 7
- 239000004202 carbamide Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 6
- 201000010099 disease Diseases 0.000 description 6
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 241000700605 Viruses Species 0.000 description 5
- 230000035611 feeding Effects 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 229910001385 heavy metal Inorganic materials 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 230000001954 sterilising effect Effects 0.000 description 4
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 4
- 229960001763 zinc sulfate Drugs 0.000 description 4
- 229910000368 zinc sulfate Inorganic materials 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 239000011398 Portland cement Substances 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 239000000292 calcium oxide Substances 0.000 description 3
- 235000012255 calcium oxide Nutrition 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 3
- 235000021050 feed intake Nutrition 0.000 description 3
- 239000011790 ferrous sulphate Substances 0.000 description 3
- 235000003891 ferrous sulphate Nutrition 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 3
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 3
- 235000019341 magnesium sulphate Nutrition 0.000 description 3
- 235000015097 nutrients Nutrition 0.000 description 3
- 235000019629 palatability Nutrition 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 230000029087 digestion Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 244000144980 herd Species 0.000 description 2
- 238000002372 labelling Methods 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 229910052711 selenium Inorganic materials 0.000 description 2
- 239000011669 selenium Substances 0.000 description 2
- 229940091258 selenium supplement Drugs 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- 239000011782 vitamin Substances 0.000 description 2
- 229940088594 vitamin Drugs 0.000 description 2
- 229930003231 vitamin Natural products 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- 208000027219 Deficiency disease Diseases 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 208000005577 Gastroenteritis Diseases 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 241000237852 Mollusca Species 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 239000010828 animal waste Substances 0.000 description 1
- 230000001142 anti-diarrhea Effects 0.000 description 1
- 230000036528 appetite Effects 0.000 description 1
- 235000019789 appetite Nutrition 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000037396 body weight Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 235000011148 calcium chloride Nutrition 0.000 description 1
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- HPCCGRCEBFBZQP-UHFFFAOYSA-N chromium;pyridine-3-carboxylic acid Chemical compound [Cr].OC(=O)C1=CC=CN=C1 HPCCGRCEBFBZQP-UHFFFAOYSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 235000019784 crude fat Nutrition 0.000 description 1
- 235000019700 dicalcium phosphate Nutrition 0.000 description 1
- 230000001079 digestive effect Effects 0.000 description 1
- 210000002249 digestive system Anatomy 0.000 description 1
- BVTBRVFYZUCAKH-UHFFFAOYSA-L disodium selenite Chemical compound [Na+].[Na+].[O-][Se]([O-])=O BVTBRVFYZUCAKH-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000006052 feed supplement Substances 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 230000002496 gastric effect Effects 0.000 description 1
- 210000001035 gastrointestinal tract Anatomy 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 241000411851 herbal medicine Species 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 230000036737 immune function Effects 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229940099596 manganese sulfate Drugs 0.000 description 1
- 239000011702 manganese sulphate Substances 0.000 description 1
- 235000007079 manganese sulphate Nutrition 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 235000008935 nutritious Nutrition 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- -1 phthalic acid ester Chemical class 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000000069 prophylactic effect Effects 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 239000000941 radioactive substance Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011781 sodium selenite Substances 0.000 description 1
- 229960001471 sodium selenite Drugs 0.000 description 1
- 235000015921 sodium selenite Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 210000000952 spleen Anatomy 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 235000019786 weight gain Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Fodder In General (AREA)
Abstract
The natural mineral lick additive contains rich P, Ca, Mg, K, Na, S and other macro elements and trace elements. Its production process includes compounding materials, including attapulgite clay, bentonite, elite, diatomite, Chinese medicinal stone and shell; crushing; acidifying; activating; milling and packing. The natural mineral lick additive has high utilization rate of the effective components, capacity of promoting the growth of animal, excellent adhering and dispersing performances. It is suitable for producing various kinds of lick for ox, sheep, etc.
Description
Technical field:
The present invention relates to feed, be specifically related to a kind of production method of natural mineral lick additive.
Background technology:
The feeding and management of China cattle and sheep is extensive, to herd, particularly to severe winter, early spring withered grass season, coarse fodder is generally based on hay, agricultural crop straw, even replenish a spot of fine fodder, but nutriment such as protein and mineral matter element intake is obviously not enough, has a strong impact on growing of cattle and sheep, has reduced economic benefit.
Lick brick and be the actual needs according to animal feedings such as cattle and sheep, the nutriment that it is required is processed into bulk through scientific formula, a kind of feed of licking for animals such as cattle and sheep.
The purpose that brick is licked in production be herd with feeding process in, replenish nutrients such as mineral matter element, nonprotein nitrogen, soluble sugar to cattle and sheep, improve feed intake and efficiency of feed utilization, control mineral nutrition deficiency disease, guarantee the normal growth growth of cattle and sheep, improve the economic benefit of raising.Particularly in winter, spring withered grass season, use and lick the brick feed and seem and be even more important.
The kind of licking brick is a lot, lick brick and lick brick based on the complex mineral that cries of mineral matter element, be the urea nutrition lap brick based on urea, be the molasses nutrition lap brick based on molasses, based on molasses and urea be molasses urea nutrition lap brick, based on urea and molasses be the urea and molasses nutrition lap brick, in the existing nutrition lap brick of China, contain compositions such as urea, molasses, mineral matter element mostly, generally be composite nutrient licking brick.
At present, the mineral feed of selling on the market is the synthetic chemical products of industry mostly at home, sodium sulphate, calcium chloride, magnesium sulfate, ferrous sulfate, copper sulphate, zinc sulfate and zinc oxide etc. are for example arranged, chemical reaction can take place in these chemical products in the process of feed, and also has in various degree peculiar smell, cause the palatability of mineral feed bad easily, the purchase cost of feed is than higher.
Licking brick selects for use bentonite, quick lime and portland cement to lick the curing agent or the adhesive of brick as preparation mostly.
Bentonite is in recovery process, be to be deposited in open-air place, be easy to by the environmental pollution around the place, in raw material, contain a large amount of moulds and virus, manufacturer does not carry out high temperature sterilization in process of production, just, be packaged as finished product through production technologies such as mining, airing, pulverizing or abrasive dusts.The mineral matter element that is contained in the bentonite material before not carrying out the modification processing, does not have activity, and animal can not well absorb these mineral matter elements in digestion process.
Quick lime and portland cement are when brick is licked in production, can play effect bonding and that solidify, but in reality is raised, use the brick of licking of quick lime and portland cement production, since solidify or suppress undue tight, dispersive property is bad, animals such as cattle and sheep are difficult to lick the nutritional labeling in the brick, nor digest easily, directly have influence on the normal growth of animals such as cattle and sheep.
Chinese patent publication number CN 1398537, open day is on February 26th, 2003, name is called " a kind of salt brick as animal feed ", disclose: " a kind of salt brick as animal feed; this block salt has not only added the necessary carbon of growth of animal, hydrogen, oxygen, nitrogen, calcium, phosphorus, chlorine, potassium, sodium, magnesium, 11 kinds of macroelements of sulphur and iron, copper, manganese, zinc, cobalt, molybdenum, boron, iodine, vanadium, silicon, selenium and other trace elements, but also added have immunologic function, disease-resistant former function, function for expelling pests, the Chinese herbal medicine of function, beneficial spleen stomach strengthening function, prophylactic function of helping digestion of regulating the flow of vital energy.The long-term feeding growth that can promote animal increases animal appetite, improves the animal rate of body weight gain.Because the present invention does not contain any antibiotic, hormone, therefore, can not make people and animals produce antibody in addition, can not work the mischief, have no side effect people and animals, free from environmental pollution, be a kind of comparatively desirable salt brick as animal feed ".
Chinese patent publication number CN 1709130, open day is on December 21st, 2005, name is called " a kind of mineral substance composite licking brick for cattle and sheep and preparation technology thereof ", disclose: " a kind of mineral substance composite licking brick for cattle and sheep and preparation technology thereof; every kg licks the ferrous 0.15-0.3g of brick sulfur acid; zinc sulfate 0.15-0.3g, copper sulphate 0.1-0.2g, manganese sulfate 0.2-0.3g; sodium selenite 0.01-0.02g; KI 0.05-0.3g, cobalt chloride 0.03-0.08g, magnesia 0.1-0.3g; nano zine oxide and cupric sulphate mixture 0.02-0.03g, nicotinic acid chromium 6-10g, sodium sulphate 30-150g, calcium monohydrogen phosphate 40-100g, salt 200-400g, curing agent 200-400g, carrier 50-200g, molasses 30-70g; Mineral matter and carrier stirring and evenly mixing are added salt and red glue soil stirring, add molasses again and stir back compression moulding promptly.The present invention combines chemocoagulation technology and mechanical pressing technology preferably, is aided with more comprehensive trace element simultaneously, and product density is big, feed intake is reasonable, comprehensive nutrition, is fit to different feed supplement modes ".
All contain industrial chemicals such as a large amount of copper sulphate, magnesium sulfate, zinc sulfate, ferrous sulfate in the foregoing invention, its weak point is, chemical reaction can take place in these chemical products in the process of feed, and also has in various degree peculiar smell, though also added sweetener, be difficult to correct its peculiar smell, cause the palatability of block salt bad easily, the purchase cost of feed is than higher, and curing agent is to adopt the bentonite of not handling through modification.
Summary of the invention:
The objective of the invention is to overcome weak point in the prior art, a kind of production method that contains the natural mineral lick additive of various active mineral matter element is provided.
Natural mineral lick additive by: Concave-convex clay rod, bentonite, zeolite, medical stone and shell are formed.
The production method of natural mineral lick additive is: batching, pulverizing, sulfuric acid acidation processing, high-temperature activation processing, abrasive dust, be packaged as finished product.
The natural minerals raw material, it is an indispensable class nutriment in animal life activity and the production process, contain macroelement such as calcium, phosphorus, sodium and chlorine and iron, copper, manganese, zinc, selenium and other trace elements, the natural minerals raw material has the function of good adsorption, caking property, dispersant, dissolubility and sterilization virus killing.
Concave-convex clay rod contains the required mineral matter element of growth of animal, Concave-convex clay rod after acidifying and the activation processing has unique absorption property, in the alimentary canal of animal, it is long-pending to have increased the nutriment reacted surface, acidifying digestive ferment, and the surface area that contacts with gastrointestinal mucosal of increase delay feed link and spend the gastral time, make that nutriment is easier to be absorbed, can also promote the synthetic of enzyme.Wherein the metallic element compound is soluble in diluted acid, when it passes through animal alimentary canal, can discharge contained element, and short its absorption can improve the animal alimentary canal function simultaneously, builds up one's resistance to disease, and improves growth performance.Concave-convex clay rod can and excrete the harmful substance in the intrusion animal digestive system, germ, virus absorption, thereby improves efficiency of feed utilization.Concave-convex clay rod has tangible anti-diarrhea effect, and transmissible gastroenteritis etc. is had good preventive and therapeutic effect.
Concave-convex clay rod has the higher characteristics of viscosity, and its viscosity can reach more than the 3000mPas, is a kind of tile adhesive of well licking, and Concave-convex clay rod also has mildew-resistant, dampproof effect.
Bentonite has higher molecule porosity, good water imbibition is arranged, dilatancy, dispersed, mobile, ion exchangeable and lubricity, bentonite can adsorb 8～15 times of water yields to its volume, in aqueous medium, can disperse to be soliquid, this suspension has certain viscosity, thixotropy and lubricity, stronger cation exchange capacity (CEC) is arranged, bentonite good palatability after the acidifying, can increase the feed intake of animal, also can reduce the content of free ammonia in the animal alimentary canal simultaneously, and delay feed link and spend the alimentary canal time, so the effect of certain control disease of digestive tract is arranged, thereby can more effectively utilize the nutrient in the feed, improve efficiency of feed utilization, can also reduce the moisture of ight soil, therefore reduced the air pollution that causes because of manure fermentation.
Zeolite is a kind of aluminium silicate mineral, contain calcium, phosphorus, potassium, sodium, magnesium, zinc, copper, more than 20 kind of constant such as manganese and trace element, ion exchangeable is one of critical nature of zeolite rock, zeolite can be selected some heavy metal of exchange, order to Na is followed successively by Ba＞Pb＞Cd＞Zn＞Cu, thereby can be used for removing heavy metal ion, zeolite has very big specific area, can produce bigger extension, so can be used as outstanding adsorbent, zeolite not only has the performance of adsorbed water, but also have the performance of absorption radioactive substance, as feed addictive, can promote the metabolism of animal, improve the resistance against diseases of body, promote to grow and increase economic efficiency.
Medical stone has strong absorption property, heavy metal and radioactive element etc. there is suction-operated, can reduce the content of beary metal in animal product such as meat, the egg, to the cyanide in the water, phthalic acid ester and the assorted bacterium of causing a disease, strong adsorptivity is arranged especially, medical stone has dissolubility, can leach multiple micro-beneficial element, medical stone can also be regulated the pH value of water, helps the interior refuse discharge of animal body and strengthens its immunity, and is very favourable to growing up healthy and sound of animal.
Shell is the shell of seawater and fresh water mollusk, shell main component be calcium carbonate, other composition has inorganic matters such as magnesium, iron, calcium phosphate, calcium sulfate and silicate, and is rich in essential trace element of animal and several amino acids, is easily absorbed by animal.
The mineral raw material modification adopts acidification and high-temperature activation to handle two kinds of methods, the purpose that modification is handled is specific area and the absorption property in order to strengthen mineral raw material, increase the activity of mineral raw material, in acidization, the sulfate such as magnesium sulfate, zinc sulfate, ferrous sulfate and calcium sulfate of all right generating portion, help the absorption of animal, improve the conversion ratio of feed, can also play the effect of deinsectization, sterilization and virus killing element in the mineral raw material.
The present invention is achieved by following technical proposals:
1, natural mineral lick additive batching, comprise following component by weight percentage: Concave-convex clay rod 20～60%, bentonite 10～40%, zeolite 5～30%, medical stone 2～15% and shell 2～10% mix mineral composition matter mixture.
2, pulverize: the mineral mixture after will preparing burden is pulverized, grain fineness≤2 millimeter.
3, sulfuric acid acidation is handled:
1. the preparation of dilute sulfuric acid comprises following component by weight percentage: the sulfuric acid 3～5% of concentration 98%, water 95～97%; 2. the batching of acidification comprises following component by weight percentage: mineral mixture 45～65%, dilute sulfuric acid 35～55%; 3. the mineral mixture after will pulverizing is transported in the acidification pool, slowly adds dilute sulfuric acid, and normal temperature carried out acidification 24～48 hours.
4, high-temperature activation is handled: the mineral mixture after acidification, and be transported to and carry out the high-temperature activation processing in the roaster, soak time was controlled at 1.5～3 hours, and temperature is controlled at 250～350 ℃.
5, abrasive dust: the mineral mixture after high-temperature activation is handled, be transported to and carry out abrasive dust in the grinding machine, fineness is controlled at 0.15～0.074 millimeter, is packaged as finished product.
Natural mineral lick additive is a kind of nontoxic lick additive, contains multiple constant and trace elements such as abundant phosphorus, calcium, magnesium, potassium, sodium, sulphur, also contains amino acid, protein, crude fat, vitamins and other nutritious components.The natural mineral lick additive that processes by these mineral raw materials, after the modification processing, can complementary pluses and minuses separately, improve the utilization rate of its active ingredient, can promote growing of letting animals feed, kipeming high yield, have again prevent and cure diseases, the function of deinsectization, sterilization and virus killing; Natural mineral lick additive has the saving feed grain, reduces production costs, the characteristics of improving food conversion ratio.
Contain a large amount of ammonia and hydrogen sulfide in the animal wastes, the harm animal health, contaminated environment, and use natural mineral lick additive, and its stink is reduced greatly, improved feeding environment, reduced pollution to environment.
Through chemical examination, the content of heavy metals such as the fluorine in the natural mineral lick additive, mercury, lead, arsenic, cadmium is all in the scope of relative national standards regulation.
Because natural mineral lick additive has bonding and all reasonable dual characteristics of dispersive property, can produce the brick of licking of various different hardness and Different Nutrition composition, animals such as cattle and sheep can absorb the nutritional labeling of licking in the brick very easily when licking brick.
Natural mineral lick additive can also add other trace element, vitamin and medicine according to the actual needs of raising.
The specific embodiment:
Below in conjunction with embodiment, the invention will be further described:
1, natural mineral lick additive batching, comprise following component by weight percentage: Concave-convex clay rod 40%, bentonite 20%, zeolite 20%, medical stone 12% and shell 8% mix mineral composition matter mixture.
2, pulverize: the mineral mixture after will preparing burden is pulverized, grain fineness≤2 millimeter.
3, sulfuric acid acidation is handled:
1. the preparation of dilute sulfuric acid comprises following component by weight percentage: the sulfuric acid 4% of concentration 98%, water 96%; 2. the batching of acidification comprises following component by weight percentage: mineral mixture 55%, dilute sulfuric acid 45%; 3. the mineral mixture after will pulverizing is transported in the acidification pool, slowly adds dilute sulfuric acid, and normal temperature carried out acidification 24 hours.
4, high-temperature activation is handled: the mineral mixture after acidification, and be transported to and carry out the high-temperature activation processing in the roaster, soak time 2 hours, temperature is controlled at 300～350 ℃.
5, abrasive dust: the mineral mixture after high-temperature activation is handled, be transported to and carry out abrasive dust in the grinding machine, fineness is 0.074 millimeter, is packaged as finished product.
Claims (6)
1, a kind of production method of natural mineral lick additive is characterized in that, the production method of natural mineral lick additive is: batching, pulverizing, sulfuric acid acidation processing, high-temperature activation processing, abrasive dust, be packaged as finished product.
2, a kind of production method of natural mineral lick additive, it is characterized in that, the batching of natural mineral lick additive, comprise following component by weight percentage: Concave-convex clay rod 20～60%, bentonite 10～40%, zeolite 5～30%, medical stone 2～15% and shell 2～10% mix mineral composition matter mixture.
3, a kind of production method of natural mineral lick additive is characterized in that, pulverizes: be the mineral mixture after the batching is pulverized, and grain fineness≤2 millimeter.
4, a kind of production method of natural mineral lick additive is characterized in that, sulfuric acid acidation is handled:
1. the preparation of dilute sulfuric acid comprises following component by weight percentage: the sulfuric acid 3～5% of concentration 98%, water 95～97%; 2. the batching of acidification comprises following component by weight percentage: mineral mixture 45～65%, dilute sulfuric acid 35～55%; 3. the mineral mixture after will pulverizing is transported in the acidification pool, slowly adds dilute sulfuric acid, and normal temperature carried out acidification 24～48 hours.
5, a kind of production method of natural mineral lick additive, it is characterized in that high-temperature activation is handled: the mineral mixture after acidification is transported to and carries out the high-temperature activation processing in the roaster, soak time was controlled at 1.5～3 hours, and temperature is controlled at 250～350 ℃.
6, a kind of production method of natural mineral lick additive is characterized in that, abrasive dust: the mineral mixture after high-temperature activation is handled, and be transported to and carry out abrasive dust in the grinding machine, fineness is controlled at 0.15～0.074 millimeter, is packaged as finished product.
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| CN102113637A (en) * | 2010-12-17 | 2011-07-06 | 沈阳农业大学 | Weather-resistance nutritional lick block for promoting reproduction of cows |
| CN102239959A (en) * | 2010-05-11 | 2011-11-16 | 姜明一 | Preparation method of ion activation liquid |
| CN102687808A (en) * | 2011-11-30 | 2012-09-26 | 河南科技大学 | Chinese herbal medicine-type feed brick for sheep in winter and preparation method thereof |
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| CN1081327A (en) * | 1992-07-24 | 1994-02-02 | 王俊士 | Natural salt block for animals |
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| CN102113637B (en) * | 2010-12-17 | 2013-07-17 | 沈阳农业大学 | Production method of weather-resistance nutritional lick block for promoting reproduction of cows |
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| CN102845616A (en) * | 2012-09-20 | 2013-01-02 | 常州大学 | Phosphorus supplementing agent and preparation method thereof |
| CN106316561A (en) * | 2015-07-06 | 2017-01-11 | 陈温乐 | Method for rapidly manufacturing organic fertilizer and feed mineral element additive |
| WO2017103885A1 (en) * | 2015-12-18 | 2017-06-22 | Basagonda Bhagavanta Hanamapure | Dietary compositions to control infections & metabolic disorders in livestock and method thereof |
| CN107348178A (en) * | 2017-07-25 | 2017-11-17 | 贵州册亨海铭巍生态畜牧业开发有限公司 | A kind of lamb feed and preparation method thereof |
| CN107981057A (en) * | 2017-12-07 | 2018-05-04 | 西北师范大学 | A kind of composite nutrient licking brick and preparation method thereof |
| CN110200146A (en) * | 2019-07-05 | 2019-09-06 | 江苏神力特生物科技股份有限公司 | One kind licking brick quality improver and preparation method thereof |
| CN110934228A (en) * | 2019-12-12 | 2020-03-31 | 贵州镇宁韦起灵种养殖有限责任公司 | Lick brick and preparation method thereof |
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