CN100423648C - Production process of natural mineral lick additive - Google Patents

Production process of natural mineral lick additive Download PDF

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Publication number
CN100423648C
CN100423648C CNB2006100378646A CN200610037864A CN100423648C CN 100423648 C CN100423648 C CN 100423648C CN B2006100378646 A CNB2006100378646 A CN B2006100378646A CN 200610037864 A CN200610037864 A CN 200610037864A CN 100423648 C CN100423648 C CN 100423648C
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mineral
additive
natural mineral
sulfuric acid
acidification
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CN1810146A (en
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许庆华
王傲乾
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Beijing Shenli Technology Co Ltd
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Abstract

The present invention discloses a production method for a natural mineral licking brick additive. The present invention has the technical scheme that the natural mineral licking brick additive contains various abundant macroelements and trace elements of phosphorus, calcium, magnesium, potassium, sodium, sulfur, etc.; the production method for the natural mineral licking brick additive comprises proportioning, pulverization, acidification, activation treatment, grinding, packaging and product obtainment; the proportioned material comprises a mineral mixture composed of attapulgite clay, bentonite, zeolite, diatomite, medical stones and shells, and the mineral mixture can complement respective advantages and defects, improve the utilization rate of effective components, and promote the growth and the development of bred animals after acidification, activation and modification; the natural mineral licking brick additive has double characteristics of preferable cohesive property and dispersion property, and can be used for producing various licking bricks with different hardness and nutrient components, so that animals, such as cattle, sheep, etc., can conveniently absorb nutrient components in licking bricks when the animals lick the licking bricks.

Description

The production method of natural mineral lick additive
Technical field:
The present invention relates to feed, be specifically related to a kind of production method of natural mineral lick additive.
Background technology:
The feeding and management of China cattle and sheep is extensive, to herd, particularly to severe winter, early spring withered grass season, coarse fodder is generally based on hay, agricultural crop straw, even replenish a spot of fine fodder, but nutriment such as protein and mineral matter element intake is obviously not enough, has a strong impact on growing of cattle and sheep, has reduced economic benefit.
Lick brick and be the actual needs according to animal feedings such as cattle and sheep, the nutriment that it is required is processed into bulk through scientific formula, a kind of feed of licking for animals such as cattle and sheep.
The purpose that brick is licked in production be herd with feeding process in, replenish nutrients such as mineral matter element, nonprotein nitrogen, soluble sugar to cattle and sheep, improve feed intake and efficiency of feed utilization, control mineral nutrition deficiency disease, guarantee the normal growth growth of cattle and sheep, improve the economic benefit of raising.Particularly in winter, spring withered grass season, use and lick the brick feed and seem and be even more important.
The kind of licking brick is a lot, lick brick and lick brick based on the complex mineral that cries of mineral matter element, be the urea nutrition lap brick based on urea, be the molasses nutrition lap brick based on molasses, based on molasses and urea be molasses urea nutrition lap brick, based on urea and molasses be the urea and molasses nutrition lap brick, in the existing nutrition lap brick of China, contain compositions such as urea, molasses, mineral matter element mostly, generally be composite nutrient licking brick.
At present, the mineral feed of selling on the market is the synthetic chemical products of industry mostly at home, sodium sulphate, calcium chloride, magnesium sulfate, ferrous sulfate, copper sulphate, zinc sulfate and zinc oxide etc. are for example arranged, chemical reaction can take place in these chemical products in the process of feed, and also has in various degree peculiar smell, cause the palatability of mineral feed bad easily, the purchase cost of feed is than higher.
Licking brick selects for use bentonite, quick lime and portland cement to lick the curing agent or the adhesive of brick as preparation mostly.
Bentonite is in recovery process, be to be deposited in open-air place, be easy to by the environmental pollution around the place, in raw material, contain a large amount of moulds and virus, manufacturer does not carry out high temperature sterilization in process of production, just, be packaged as finished product through production technologies such as mining, airing, pulverizing or abrasive dusts.The mineral matter element that is contained in the bentonite material before not carrying out the modification processing, does not have activity, and animal can not well absorb these mineral matter elements in digestion process.
Quick lime and portland cement are when brick is licked in production, can play effect bonding and that solidify, but in reality is raised, use the brick of licking of quick lime and portland cement production, since solidify or suppress undue tight, dispersive property is bad, animals such as cattle and sheep are difficult to lick the nutritional labeling in the brick, nor digest easily, directly have influence on the normal growth of animals such as cattle and sheep.
Chinese patent publication number CN 1398537, open day is on February 26th, 2003, name is called " a kind of salt brick as animal feed ", disclose: " a kind of salt brick as animal feed; this block salt has not only added the necessary carbon of growth of animal, hydrogen, oxygen, nitrogen, calcium, phosphorus, chlorine, potassium, sodium, magnesium, 11 kinds of macroelements of sulphur and iron, copper, manganese, zinc, cobalt, molybdenum, boron, iodine, vanadium, silicon, selenium and other trace elements, but also added have immunologic function, disease-resistant former function, function for expelling pests, the Chinese herbal medicine of function, beneficial spleen stomach strengthening function, prophylactic function of helping digestion of regulating the flow of vital energy.The long-term feeding growth that can promote animal increases animal appetite, improves the animal rate of body weight gain.Because the present invention does not contain any antibiotic, hormone, therefore, can not make people and animals produce antibody in addition, can not work the mischief, have no side effect people and animals, free from environmental pollution, be a kind of comparatively desirable salt brick as animal feed ".
Chinese patent publication number CN 1709130, open day is on December 21st, 2005, name is called " a kind of mineral substance composite licking brick for cattle and sheep and preparation technology thereof ", disclose: " a kind of mineral substance composite licking brick for cattle and sheep and preparation technology thereof; every kg licks the ferrous 0.15-0.3g of brick sulfur acid; zinc sulfate 0.15-0.3g, copper sulphate 0.1-0.2g, manganese sulfate 0.2-0.3g; sodium selenite 0.01-0.02g; KI 0.05-0.3g, cobalt chloride 0.03-0.08g, magnesia 0.1-0.3g; nano zine oxide and cupric sulphate mixture 0.02-0.03g, nicotinic acid chromium 6-10g, sodium sulphate 30-150g, calcium monohydrogen phosphate 40-100g, salt 200-400g, curing agent 200-400g, carrier 50-200g, molasses 30-70g; Mineral matter and carrier stirring and evenly mixing are added salt and red glue soil stirring, add molasses again and stir back compression moulding promptly.The present invention combines chemocoagulation technology and mechanical pressing technology preferably, is aided with more comprehensive trace element simultaneously, and product density is big, feed intake is reasonable, comprehensive nutrition, is fit to different feed supplement modes ".
All contain industrial chemicals such as a large amount of copper sulphate, magnesium sulfate, zinc sulfate, ferrous sulfate in the foregoing invention, its weak point is, chemical reaction can take place in these chemical products in the process of feed, and also has in various degree peculiar smell, though also added sweetener, be difficult to correct its peculiar smell, cause the palatability of block salt bad easily, the purchase cost of feed is than higher, and curing agent is to adopt the bentonite of not handling through modification.
Summary of the invention:
The objective of the invention is to overcome weak point in the prior art, a kind of production method that contains the natural mineral lick additive of various active mineral matter element is provided.
Natural mineral lick additive by: Concave-convex clay rod, bentonite, zeolite, medical stone and shell are formed.
The production method of natural mineral lick additive is: batching, pulverizing, sulfuric acid acidation processing, high-temperature activation processing, abrasive dust, be packaged as finished product.
The natural minerals raw material, it is an indispensable class nutriment in animal life activity and the production process, contain macroelement such as calcium, phosphorus, sodium and chlorine and iron, copper, manganese, zinc, selenium and other trace elements, the natural minerals raw material has the function of good adsorption, caking property, dispersant, dissolubility and sterilization virus killing.
Concave-convex clay rod contains the required mineral matter element of growth of animal, Concave-convex clay rod after acidifying and the activation processing has unique absorption property, in the alimentary canal of animal, it is long-pending to have increased the nutriment reacted surface, acidifying digestive ferment, and the surface area that contacts with gastrointestinal mucosal of increase delay feed link and spend the gastral time, make that nutriment is easier to be absorbed, can also promote the synthetic of enzyme.Wherein the metallic element compound is soluble in diluted acid, when it passes through animal alimentary canal, can discharge contained element, and short its absorption can improve the animal alimentary canal function simultaneously, builds up one's resistance to disease, and improves growth performance.Concave-convex clay rod can and excrete the harmful substance in the intrusion animal digestive system, germ, virus absorption, thereby improves efficiency of feed utilization.Concave-convex clay rod has tangible anti-diarrhea effect, and transmissible gastroenteritis etc. is had good preventive and therapeutic effect.
Concave-convex clay rod has the higher characteristics of viscosity, and its viscosity can reach more than the 3000mPas, is a kind of tile adhesive of well licking, and Concave-convex clay rod also has mildew-resistant, dampproof effect.
Bentonite has higher molecule porosity, good water imbibition is arranged, dilatancy, dispersed, mobile, ion exchangeable and lubricity, bentonite can adsorb 8~15 times of water yields to its volume, in aqueous medium, can disperse to be soliquid, this suspension has certain viscosity, thixotropy and lubricity, stronger cation exchange capacity (CEC) is arranged, bentonite good palatability after the acidifying, can increase the feed intake of animal, also can reduce the content of free ammonia in the animal alimentary canal simultaneously, and delay feed link and spend the alimentary canal time, so the effect of certain control disease of digestive tract is arranged, thereby can more effectively utilize the nutrient in the feed, improve efficiency of feed utilization, can also reduce the moisture of ight soil, therefore reduced the air pollution that causes because of manure fermentation.
Zeolite is a kind of aluminium silicate mineral, contain calcium, phosphorus, potassium, sodium, magnesium, zinc, copper, more than 20 kind of constant such as manganese and trace element, ion exchangeable is one of critical nature of zeolite rock, zeolite can be selected some heavy metal of exchange, order to Na is followed successively by Ba>Pb>Cd>Zn>Cu, thereby can be used for removing heavy metal ion, zeolite has very big specific area, can produce bigger extension, so can be used as outstanding adsorbent, zeolite not only has the performance of adsorbed water, but also have the performance of absorption radioactive substance, as feed addictive, can promote the metabolism of animal, improve the resistance against diseases of body, promote to grow and increase economic efficiency.
Medical stone has strong absorption property, heavy metal and radioactive element etc. there is suction-operated, can reduce the content of beary metal in animal product such as meat, the egg, to the cyanide in the water, phthalic acid ester and the assorted bacterium of causing a disease, strong adsorptivity is arranged especially, medical stone has dissolubility, can leach multiple micro-beneficial element, medical stone can also be regulated the pH value of water, helps the interior refuse discharge of animal body and strengthens its immunity, and is very favourable to growing up healthy and sound of animal.
Shell is the shell of seawater and fresh water mollusk, shell main component be calcium carbonate, other composition has inorganic matters such as magnesium, iron, calcium phosphate, calcium sulfate and silicate, and is rich in essential trace element of animal and several amino acids, is easily absorbed by animal.
The mineral raw material modification adopts acidification and high-temperature activation to handle two kinds of methods, the purpose that modification is handled is specific area and the absorption property in order to strengthen mineral raw material, increase the activity of mineral raw material, in acidization, the sulfate such as magnesium sulfate, zinc sulfate, ferrous sulfate and calcium sulfate of all right generating portion, help the absorption of animal, improve the conversion ratio of feed, can also play the effect of deinsectization, sterilization and virus killing element in the mineral raw material.
The present invention is achieved by following technical proposals:
1, natural mineral lick additive batching, comprise following component by weight percentage: Concave-convex clay rod 20~60%, bentonite 10~40%, zeolite 5~30%, medical stone 2~15% and shell 2~10% mix mineral composition matter mixture.
2, pulverize: the mineral mixture after will preparing burden is pulverized, grain fineness≤2 millimeter.
3, sulfuric acid acidation is handled:
1. the preparation of dilute sulfuric acid comprises following component by weight percentage: the sulfuric acid 3~5% of concentration 98%, water 95~97%; 2. the batching of acidification comprises following component by weight percentage: mineral mixture 45~65%, dilute sulfuric acid 35~55%; 3. the mineral mixture after will pulverizing is transported in the acidification pool, slowly adds dilute sulfuric acid, and normal temperature carried out acidification 24~48 hours.
4, high-temperature activation is handled: the mineral mixture after acidification, and be transported to and carry out the high-temperature activation processing in the roaster, soak time was controlled at 1.5~3 hours, and temperature is controlled at 250~350 ℃.
5, abrasive dust: the mineral mixture after high-temperature activation is handled, be transported to and carry out abrasive dust in the grinding machine, fineness is controlled at 0.15~0.074 millimeter, is packaged as finished product.
Natural mineral lick additive is a kind of nontoxic lick additive, contains multiple constant and trace elements such as abundant phosphorus, calcium, magnesium, potassium, sodium, sulphur, also contains amino acid, protein, crude fat, vitamins and other nutritious components.The natural mineral lick additive that processes by these mineral raw materials, after the modification processing, can complementary pluses and minuses separately, improve the utilization rate of its active ingredient, can promote growing of letting animals feed, kipeming high yield, have again prevent and cure diseases, the function of deinsectization, sterilization and virus killing; Natural mineral lick additive has the saving feed grain, reduces production costs, the characteristics of improving food conversion ratio.
Contain a large amount of ammonia and hydrogen sulfide in the animal wastes, the harm animal health, contaminated environment, and use natural mineral lick additive, and its stink is reduced greatly, improved feeding environment, reduced pollution to environment.
Through chemical examination, the content of heavy metals such as the fluorine in the natural mineral lick additive, mercury, lead, arsenic, cadmium is all in the scope of relative national standards regulation.
Because natural mineral lick additive has bonding and all reasonable dual characteristics of dispersive property, can produce the brick of licking of various different hardness and Different Nutrition composition, animals such as cattle and sheep can absorb the nutritional labeling of licking in the brick very easily when licking brick.
Natural mineral lick additive can also add other trace element, vitamin and medicine according to the actual needs of raising.
The specific embodiment:
Below in conjunction with embodiment, the invention will be further described:
1, natural mineral lick additive batching, comprise following component by weight percentage: Concave-convex clay rod 40%, bentonite 20%, zeolite 20%, medical stone 12% and shell 8% mix mineral composition matter mixture.
2, pulverize: the mineral mixture after will preparing burden is pulverized, grain fineness≤2 millimeter.
3, sulfuric acid acidation is handled:
1. the preparation of dilute sulfuric acid comprises following component by weight percentage: the sulfuric acid 4% of concentration 98%, water 96%; 2. the batching of acidification comprises following component by weight percentage: mineral mixture 55%, dilute sulfuric acid 45%; 3. the mineral mixture after will pulverizing is transported in the acidification pool, slowly adds dilute sulfuric acid, and normal temperature carried out acidification 24 hours.
4, high-temperature activation is handled: the mineral mixture after acidification, and be transported to and carry out the high-temperature activation processing in the roaster, soak time 2 hours, temperature is controlled at 300~350 ℃.
5, abrasive dust: the mineral mixture after high-temperature activation is handled, be transported to and carry out abrasive dust in the grinding machine, fineness is 0.074 millimeter, is packaged as finished product.

Claims (1)

1. the production method of a natural mineral lick additive is characterized in that, the production method of natural mineral lick additive is: batching, pulverizing, sulfuric acid acidation processing, high-temperature activation processing, abrasive dust, be packaged as finished product;
The batching of described natural mineral lick additive comprises following component by weight percentage: Concave-convex clay rod 20~60%, bentonite 10~40%, zeolite 5~30%, medical stone 2~15% and shell 2~10% mix mineral composition matter mixture;
Described pulverizing is the mineral mixture after the batching to be pulverized grain fineness≤2 millimeter;
Described sulfuric acid acidation is treated to: 1. the preparation of dilute sulfuric acid comprises following component by weight percentage: the sulfuric acid 3~5% of concentration 98%, water 95~97%; 2. the batching of acidification comprises following component by weight percentage: mineral mixture 45~65%, dilute sulfuric acid 35~55%; 3. the mineral mixture after will pulverizing is transported in the acidification pool, slowly adds dilute sulfuric acid, and normal temperature carried out acidification 24~48 hours;
Described high-temperature activation is treated to: the mineral mixture after acidification, and be transported to and carry out the high-temperature activation processing in the roaster, soak time was controlled at 1.5~3 hours, and temperature is controlled at 250~350 ℃;
Described abrasive dust is: the mineral mixture after high-temperature activation is handled, and be transported to and carry out abrasive dust in the grinding machine, fineness is controlled at 0.074~0.15 millimeter, is packaged as finished product.
CNB2006100378646A 2006-01-19 2006-01-19 Production process of natural mineral lick additive Expired - Fee Related CN100423648C (en)

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* Cited by examiner, † Cited by third party
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CN102239959B (en) * 2010-05-11 2013-05-15 姜明一 Preparation method of ion activation liquid
CN102113637B (en) * 2010-12-17 2013-07-17 沈阳农业大学 Production method of weather-resistance nutritional lick block for promoting reproduction of cows
CN102687808B (en) * 2011-11-30 2013-06-12 河南科技大学 Chinese herbal medicine-type feed brick for sheep in winter and preparation method thereof
CN102845616B (en) * 2012-09-20 2013-10-30 常州大学 Phosphorus supplementing agent and preparation method thereof
CN106316561A (en) * 2015-07-06 2017-01-11 陈温乐 Method for rapidly manufacturing organic fertilizer and feed mineral element additive
WO2017103885A1 (en) * 2015-12-18 2017-06-22 Basagonda Bhagavanta Hanamapure Dietary compositions to control infections & metabolic disorders in livestock and method thereof
CN107348178A (en) * 2017-07-25 2017-11-17 贵州册亨海铭巍生态畜牧业开发有限公司 A kind of lamb feed and preparation method thereof
CN107981057A (en) * 2017-12-07 2018-05-04 西北师范大学 A kind of composite nutrient licking brick and preparation method thereof
CN110200146A (en) * 2019-07-05 2019-09-06 江苏神力特生物科技股份有限公司 One kind licking brick quality improver and preparation method thereof
CN110934228A (en) * 2019-12-12 2020-03-31 贵州镇宁韦起灵种养殖有限责任公司 Lick brick and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1081327A (en) * 1992-07-24 1994-02-02 王俊士 Natural salt block for animals

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1081327A (en) * 1992-07-24 1994-02-02 王俊士 Natural salt block for animals

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