CN100360053C - Preparation method of brick for animal licking containing natural mineral, urea and molasses - Google Patents
Preparation method of brick for animal licking containing natural mineral, urea and molasses Download PDFInfo
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- CN100360053C CN100360053C CNB2006100378665A CN200610037866A CN100360053C CN 100360053 C CN100360053 C CN 100360053C CN B2006100378665 A CNB2006100378665 A CN B2006100378665A CN 200610037866 A CN200610037866 A CN 200610037866A CN 100360053 C CN100360053 C CN 100360053C
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- urea
- molasses
- brick
- natural mineral
- mineral
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- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 79
- 239000011707 mineral Substances 0.000 title claims abstract description 79
- 241001465754 Metazoa Species 0.000 title claims abstract description 48
- 239000011449 brick Substances 0.000 title claims abstract description 44
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 239000004202 carbamide Substances 0.000 title claims abstract description 39
- 235000013379 molasses Nutrition 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000000654 additive Substances 0.000 claims abstract description 17
- 230000000996 additive effect Effects 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 150000003839 salts Chemical class 0.000 claims abstract description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 27
- 238000004519 manufacturing process Methods 0.000 claims description 16
- 230000020477 pH reduction Effects 0.000 claims description 12
- 230000004913 activation Effects 0.000 claims description 11
- 239000000440 bentonite Substances 0.000 claims description 11
- 229910000278 bentonite Inorganic materials 0.000 claims description 11
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 11
- 239000004927 clay Substances 0.000 claims description 10
- 229910021536 Zeolite Inorganic materials 0.000 claims description 9
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 9
- 239000010457 zeolite Substances 0.000 claims description 9
- 239000004575 stone Substances 0.000 claims description 7
- 239000000428 dust Substances 0.000 claims description 6
- 238000010298 pulverizing process Methods 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 3
- 238000004260 weight control Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims 1
- 238000009472 formulation Methods 0.000 claims 1
- 235000010755 mineral Nutrition 0.000 abstract description 71
- 235000013877 carbamide Nutrition 0.000 abstract description 26
- 241000283690 Bos taurus Species 0.000 abstract description 14
- 241001494479 Pecora Species 0.000 abstract description 14
- 241000282849 Ruminantia Species 0.000 abstract description 11
- 238000003756 stirring Methods 0.000 abstract description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 7
- 102000004169 proteins and genes Human genes 0.000 abstract description 7
- 108090000623 proteins and genes Proteins 0.000 abstract description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 6
- 239000011573 trace mineral Substances 0.000 abstract description 6
- 235000013619 trace mineral Nutrition 0.000 abstract description 6
- 239000010949 copper Substances 0.000 abstract description 5
- 239000011734 sodium Substances 0.000 abstract description 5
- 239000011701 zinc Substances 0.000 abstract description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052791 calcium Inorganic materials 0.000 abstract description 4
- 239000011575 calcium Substances 0.000 abstract description 4
- 229910052802 copper Inorganic materials 0.000 abstract description 4
- 239000011574 phosphorus Substances 0.000 abstract description 4
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 4
- 229910052708 sodium Inorganic materials 0.000 abstract description 4
- 229910052725 zinc Inorganic materials 0.000 abstract description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 3
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000460 chlorine Substances 0.000 abstract description 3
- 229910052801 chlorine Inorganic materials 0.000 abstract description 3
- -1 etc. Substances 0.000 abstract description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract description 3
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 3
- 229910017464 nitrogen compound Inorganic materials 0.000 abstract description 3
- 150000002830 nitrogen compounds Chemical class 0.000 abstract description 3
- 229910052711 selenium Inorganic materials 0.000 abstract description 3
- 239000011669 selenium Substances 0.000 abstract description 3
- 150000001720 carbohydrates Chemical class 0.000 abstract description 2
- 235000019621 digestibility Nutrition 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 230000000284 resting effect Effects 0.000 abstract 1
- 230000004584 weight gain Effects 0.000 abstract 1
- 235000019786 weight gain Nutrition 0.000 abstract 1
- 239000000047 product Substances 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 235000002639 sodium chloride Nutrition 0.000 description 7
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 241000700605 Viruses Species 0.000 description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 201000010099 disease Diseases 0.000 description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 4
- 229910001385 heavy metal Inorganic materials 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 4
- 229960001763 zinc sulfate Drugs 0.000 description 4
- 229910000368 zinc sulfate Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000000748 compression moulding Methods 0.000 description 3
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 3
- 235000021050 feed intake Nutrition 0.000 description 3
- 239000011790 ferrous sulphate Substances 0.000 description 3
- 235000003891 ferrous sulphate Nutrition 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 3
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 3
- 235000019341 magnesium sulphate Nutrition 0.000 description 3
- 235000016709 nutrition Nutrition 0.000 description 3
- 235000019629 palatability Nutrition 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000035764 nutrition Effects 0.000 description 2
- 230000000050 nutritive effect Effects 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 229940091258 selenium supplement Drugs 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 208000005577 Gastroenteritis Diseases 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 241000237852 Mollusca Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- 208000001649 Pica Diseases 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- PNNCWTXUWKENPE-UHFFFAOYSA-N [N].NC(N)=O Chemical compound [N].NC(N)=O PNNCWTXUWKENPE-UHFFFAOYSA-N 0.000 description 1
- DZHMRSPXDUUJER-UHFFFAOYSA-N [amino(hydroxy)methylidene]azanium;dihydrogen phosphate Chemical compound NC(N)=O.OP(O)(O)=O DZHMRSPXDUUJER-UHFFFAOYSA-N 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 208000007502 anemia Diseases 0.000 description 1
- 239000010828 animal waste Substances 0.000 description 1
- 230000001142 anti-diarrhea Effects 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 235000011148 calcium chloride Nutrition 0.000 description 1
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- HPCCGRCEBFBZQP-UHFFFAOYSA-N chromium;pyridine-3-carboxylic acid Chemical compound [Cr].OC(=O)C1=CC=CN=C1 HPCCGRCEBFBZQP-UHFFFAOYSA-N 0.000 description 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000019700 dicalcium phosphate Nutrition 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 230000001079 digestive effect Effects 0.000 description 1
- 210000002249 digestive system Anatomy 0.000 description 1
- BVTBRVFYZUCAKH-UHFFFAOYSA-L disodium selenite Chemical compound [Na+].[Na+].[O-][Se]([O-])=O BVTBRVFYZUCAKH-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000006052 feed supplement Substances 0.000 description 1
- 230000003031 feeding effect Effects 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 235000004426 flaxseed Nutrition 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 230000002496 gastric effect Effects 0.000 description 1
- 210000001035 gastrointestinal tract Anatomy 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 244000144980 herd Species 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229940099596 manganese sulfate Drugs 0.000 description 1
- 239000011702 manganese sulphate Substances 0.000 description 1
- 235000007079 manganese sulphate Nutrition 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 235000006180 nutrition needs Nutrition 0.000 description 1
- 208000015380 nutritional deficiency disease Diseases 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 239000000941 radioactive substance Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 208000007442 rickets Diseases 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000011781 sodium selenite Substances 0.000 description 1
- 229960001471 sodium selenite Drugs 0.000 description 1
- 235000015921 sodium selenite Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 208000024877 white muscle disease Diseases 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/80—Food processing, e.g. use of renewable energies or variable speed drives in handling, conveying or stacking
- Y02P60/87—Re-use of by-products of food processing for fodder production
Landscapes
- Fodder In General (AREA)
Abstract
The present invention discloses a preparation method of a natural mineral, urea and molasses licking brick. The present invention has the technical scheme that the preparation method of a natural mineral, urea and molasses licking brick comprises proportioning, stirring, press forming, natural airing, packaging and product obtainment; the proportioned material is composed of urea, molasses, salt, a natural mineral licking brick additive and water, and the natural mineral, urea and molasses licking brick contains a nonprotein nitrogen compound, macroelements of calcium, phosphorus, sodium, chlorine, etc., trace elements of ferrum, copper, manganese, zinc, selenium, etc., and a carbohydrate used for supplying energy; the natural mineral, urea and molasses licking brick can effectively replace a part of protein in feed for cattle, sheep and other ruminant domestic animals, can improve the digestibility of coarse fibres in low protein feed, weight gain and nitrogen reserving quantity, and can be hung or placed above mangers and water tanks or in resting places of cattle, sheep and other ruminant domestic animals for licking.
Description
Technical field:
The present invention relates to feed, be specifically related to a kind of production method of brick for animal licking containing natural mineral, urea and molasses.
Background technology:
The feeding and management of China cattle and sheep is extensive, to herd, particularly to severe winter, early spring withered grass season, coarse fodder is generally based on hay, agricultural crop straw, even replenish a spot of fine fodder, but nutriment such as protein and mineral matter element intake is obviously not enough, has a strong impact on growing of cattle and sheep, has reduced economic benefit.
It is that non-protein nitrogen compounds such as urea, molasses, salt and mineral matter etc. are fully mixed that mineral, urea and molasses is licked brick, is pressed into the brick shape and licks brick.Production practices show, urea and molasses is licked brick to be to avoid the effective ways of the excessive additional nonprotein nitrogen of eating urea of ruminant and to be labour-saving method.The main component that mineral, urea and molasses is licked brick is based on urea, molasses, salt are auxilliary, then according to the mineral matter nutritional needs of ruminant domestic animals such as cattle and sheep, factors such as daily ration mineral content situation and regional mineral matter element distribution situation are added various mineral raw materials, to improve its feeding effect.
At present, the mineral feed of selling on the market is the synthetic chemical products of industry mostly at home, sodium sulphate, calcium chloride, magnesium sulfate, ferrous sulfate, copper sulphate, zinc sulfate and zinc oxide etc. are for example arranged, chemical reaction can take place in these chemical products in the process of feed, and also has in various degree peculiar smell, cause the palatability of mineral feed bad easily, the purchase cost of feed is than higher.
Mineral, urea and molasses is licked the brick multiselect is licked brick as preparation with bentonite curing agent or adhesive.
Bentonite is to be deposited in open-air place in recovery process, is easy to be contained a large amount of moulds and virus by the environmental pollution around the place in raw material, and the manufacturer of feed does not carry out high temperature sterilization in process of production; The mineral matter element that is contained in the bentonite material before not carrying out the modification processing, does not have activity, and animal can not well absorb these mineral matter elements in digestion process.
Chinese patent publication number CN 1709131, open day is on December 21st, 2005, name is called " a kind of high-protein composite licking brick for cattle and sheep and preparation technology thereof ", and disclose: " a kind of high-protein composite licking brick for cattle and sheep and preparation technology thereof, every kg lick the ferrous 0.21-0.35g of brick sulfur acid; zinc sulfate 0.21-0.35g; copper sulphate 0.14-0.21g, manganese sulfate 0.24-0.35g, sodium selenite 0.01-0.02g; KI 0.07-0.35g; cobalt chloride 0.03-0.07g, magnesia 0.14-0.35g, nano zine oxide and cupric sulphate mixture 0.24-0.38g; nicotinic acid chromium 6-8g, sodium sulphate 30-150g, calcium monohydrogen phosphate 50-100g, carrier 50-200g, salt 200-300g, curing agent 200-300g, molasses 30-60g, urea 100-150g, urea phosphate 30-60g, physiological regulating control agent 3-7g.Combine chemocoagulation technology and mechanical pressing technology preferably, be aided with more comprehensive trace element simultaneously, product density is big, feed intake is reasonable, comprehensive nutrition, is fit to different feed supplement modes ".
Contain industrial chemicals such as a large amount of copper sulphate, magnesium sulfate, zinc sulfate, ferrous sulfate in the foregoing invention, its weak point is, chemical reaction can take place in these chemical products in the process of feed, and also has in various degree peculiar smell, though added the molasses sweetener, be difficult to correct its peculiar smell, cause the palatability of licking brick bad easily, the purchase cost of feed is than higher, and curing agent is to adopt the bentonite of not handling through modification.
Summary of the invention:
The objective of the invention is to overcome weak point in the prior art, a kind of production method that contains the brick for animal licking containing natural mineral, urea and molasses of urea, molasses, salt and various active mineral matter element is provided.
The production method of brick for animal licking containing natural mineral, urea and molasses is made up of two parts:
1, at first will produce natural mineral lick additive, the production method of natural mineral lick additive is: batching, pulverizing, sulfuric acid acidation are handled, high-temperature activation is handled, abrasive dust.The batching of natural mineral lick additive is made up of Concave-convex clay rod, bentonite, zeolite, medical stone and shell.
2, brick for animal licking containing natural mineral, urea and molasses, the production method of brick for animal licking containing natural mineral, urea and molasses are produced in regeneration: batching, stirring, compression moulding, dry, be packaged as finished product naturally.
The batching of brick for animal licking containing natural mineral, urea and molasses is made up of urea, molasses, salt, natural mineral lick additive and water.
The natural minerals raw material, it is an indispensable class nutriment in animal life activity and the production process, contain macroelement such as calcium, phosphorus, sodium and chlorine and iron, copper, manganese, zinc, selenium and other trace elements, the natural minerals raw material has the function of good adsorption, caking property, dispersant, dissolubility and sterilization virus killing.
Concave-convex clay rod contains the required mineral matter element of growth of animal, Concave-convex clay rod after acidifying and the activation processing has unique absorption property, in the alimentary canal of animal, it is long-pending to have increased the nutriment reacted surface, acidifying digestive ferment, and the surface area that contacts with gastrointestinal mucosal of increase delay feed link and spend the gastral time, make that nutriment is easier to be absorbed, can also promote the synthetic of enzyme.Wherein the metallic element compound is soluble in diluted acid, when it passes through animal alimentary canal, can discharge contained element, and short its absorption can improve the animal alimentary canal function simultaneously, builds up one's resistance to disease, and improves growth performance.Concave-convex clay rod can and excrete the harmful substance in the intrusion animal digestive system, germ, virus absorption, thereby improves efficiency of feed utilization.Concave-convex clay rod has tangible anti-diarrhea effect, and transmissible gastroenteritis etc. is had good preventive and therapeutic effect.
Concave-convex clay rod has the higher characteristics of viscosity, and its viscosity can reach more than the 3000mPas, is a kind of tile adhesive of well licking, and Concave-convex clay rod also has mildew-resistant, dampproof effect.
Bentonite has higher molecule porosity, good water imbibition is arranged, dilatancy, dispersed, mobile, ion exchangeable and lubricity, bentonite can adsorb 8～15 times of water yields to its volume, in aqueous medium, can disperse to be soliquid, this suspension has certain viscosity, thixotropy and lubricity, stronger cation exchange capacity (CEC) is arranged, bentonite good palatability after the acidifying, can increase the feed intake of animal, also can reduce the content of free ammonia in the animal alimentary canal simultaneously, and delay feed link and spend the alimentary canal time, so the effect of certain control disease of digestive tract is arranged, thereby can more effectively utilize the nutrient in the feed, improve efficiency of feed utilization, can also reduce the moisture in the ight soil, therefore reduced the air pollution that causes because of manure fermentation.
Zeolite is a kind of aluminium silicate mineral, contain calcium, phosphorus, potassium, sodium, magnesium, zinc, copper, more than 20 kind of constant such as manganese and trace element, ion exchangeable is one of critical nature of zeolite rock, zeolite can be selected some heavy metal of exchange, order to Na is followed successively by Ba＞Pb＞Cd＞Zn＞Cu, thereby can be used for removing heavy metal ion, zeolite has very big specific area, can produce bigger extension, so can be used as outstanding adsorbent, zeolite not only has the performance of adsorbed water, but also have the performance of absorption radioactive substance, as feed addictive, can promote the metabolism of animal, improve the resistance against diseases of body, promote to grow and increase economic efficiency.
Medical stone has strong absorption property, heavy metal and radioactive element etc. there is suction-operated, can reduce the content of beary metal in animal product such as meat, the egg, to the cyanide in the water, phthalic acid ester and the assorted bacterium of causing a disease, strong adsorptivity is arranged especially, medical stone has dissolubility, can leach multiple micro-beneficial element, medical stone can also be regulated the pH value of water, helps the interior refuse discharge of animal body and strengthens its immunity, and is very favourable to growing up healthy and sound of animal.
Shell is the shell of seawater and fresh water mollusk, shell main component be calcium carbonate.Other composition has inorganic matters such as magnesium, iron, calcium phosphate, calcium sulfate and silicate, and is rich in essential trace element of animal and several amino acids, is easily absorbed by animal.
The mineral raw material modification adopts acidification and high-temperature activation to handle two kinds of methods, the purpose that modification is handled is specific area and the absorption property in order to strengthen mineral raw material, increase the activity of mineral raw material, in acidization, the sulfate such as magnesium sulfate, zinc sulfate, ferrous sulfate and calcium sulfate of all right generating portion, help the absorption of animal, improve the conversion ratio of feed, can also play the effect of deinsectization, sterilization and virus killing element in the mineral raw material.
Contain a large amount of ammonia and hydrogen sulfide in the animal wastes, the harm animal health, contaminated environment, and use natural mineral lick additive, and its stink is reduced greatly, improved feeding environment, reduced pollution to environment.
Because natural mineral lick additive has bonding and all reasonable dual characteristics of dispersive property, can produce the brick of licking of various different hardness and Different Nutrition composition, ruminant domestic animals such as cattle and sheep can absorb the nutritional labeling of licking in the brick very easily when licking brick.
The present invention is achieved by following technical proposals:
One, the production method of natural mineral lick additive:
1, natural mineral lick additive batching, comprise following component by weight percentage: Concave-convex clay rod 20～60%, bentonite 10～40%, zeolite 5～30%, medical stone 2～15% and shell 2～10%, after mixing, mineral composition matter mixture.
2, pulverize: the mineral mixture after will preparing burden is pulverized, grain fineness≤2 millimeter.
3, sulfuric acid acidation is handled:
1. the preparation of dilute sulfuric acid comprises following component by weight percentage: the sulfuric acid 3～5% of concentration 98%, water 95～97%; 2. the batching of acidification comprises following component by weight percentage: mineral mixture 45～65%, dilute sulfuric acid 35～55%; 3. the mineral mixture after will pulverizing is transported in the acidification pool, slowly adds dilute sulfuric acid, and normal temperature carried out acidification 24～48 hours.
4, high-temperature activation is handled: the mineral mixture after acidification, and be transported to and carry out the high-temperature activation processing in the roaster, soak time was controlled at 1.5～3 hours, and temperature is controlled at 250～350 ℃.
5, abrasive dust: the mineral mixture after high-temperature activation is handled, be transported to and carry out abrasive dust in the grinding machine, fineness is controlled at 0.15～0.074 millimeter.
Two, the production method of brick for animal licking containing natural mineral, urea and molasses
1, the batching of brick for animal licking containing natural mineral, urea and molasses comprises following component by weight percentage: urea 45～65%, natural mineral lick additive 10～30%, water 5～30%, molasses 5～15% and salt 2～5%.
2, stir: the mixture after will preparing burden stirs.
3, compression moulding: the mixture after stirring, use brick machine to be pressed, brick for animal licking containing natural mineral, urea and molasses has rectangle, square, annular and cylindrical, and every Weight control is at 0.5～50 kilogram.
4, dry naturally after, be packaged as finished product.
Brick for animal licking containing natural mineral, urea and molasses contains macroelement such as non-protein nitrogen compound, calcium, phosphorus, sodium and chlorine and iron, copper, manganese, zinc, selenium and other trace elements and as the carbohydrate of energize, brick for animal licking containing natural mineral, urea and molasses can replace a part of protein in the ruminant domestic animal feeds such as cattle and sheep effectively, improve coarse-fibred digestibility in the low-protein feed, improve the reservation amount of weightening finish and increase nitrogen.Because urea nitrogen can change into amino acid and true albumen in cud, at last at enteron aisle by ruminant domestic animal utilizations such as cattle and sheep, formative tissue albumen and milk proem.According to surveying and determination, the nutritive value of every kg urea is equivalent to the nutritive value of 5 kilograms of soybean cakes or 7 kilograms of linseed cake protein, thereby the cowboying cost is reduced, and economic benefit improves.
Brick for animal licking containing natural mineral, urea and molasses can also be kept the electrolyte balance of ruminant domestic animal bodies such as cattle and sheep, control domestic animal mineral matter nutritional deficiency disease, as allotriophagy, white muscle disease, high yield ox postpartum paralysis, cub rickets, alimentary anemia etc., improve feed intake and efficiency of feed utilization, guarantee that the normal growth of ruminant domestic animals such as cattle and sheep is grown.
The place that ruminant domestic animals such as crib, the tank top of ruminant domestic animals such as cattle and sheep or cattle and sheep are had a rest can be hung or be placed on to brick for animal licking containing natural mineral, urea and molasses, freely licks for it.
Through chemical examination, the content of heavy metals such as the fluorine in the brick for animal licking containing natural mineral, urea and molasses, mercury, lead, arsenic, cadmium is all in the scope of relative national standards regulation.
The production method of natural mineral lick additive, in separate case application on the same day patent of invention.
The specific embodiment:
Below in conjunction with embodiment, the invention will be further described:
One, produce the production method of natural mineral lick additive:
1, natural mineral lick additive batching comprises following component by weight percentage: Concave-convex clay rod 55%, bentonite 20%, zeolite 10%, medical stone 10% and shell 5%, and after mixing, mineral composition matter mixture.
2, pulverize: the mineral mixture after will preparing burden is pulverized, grain fineness≤2 millimeter.
3, sulfuric acid acidation is handled: 1. the preparation of dilute sulfuric acid comprises following component by weight percentage: the sulfuric acid 4% of concentration 98%, water 96%; 2. the batching of acidification comprises following component by weight percentage: mineral mixture 55%, dilute sulfuric acid 45%; 3. the mineral mixture after will pulverizing is transported in the acidification pool, slowly adds dilute sulfuric acid, and normal temperature carried out acidification 48 hours.
4, high-temperature activation is handled: the mineral mixture after acidification, and be transported to and carry out the high-temperature activation processing in the roaster, soak time was controlled at 2.5 hours, and temperature is controlled at 250～350 ℃.
5, abrasive dust: the mineral mixture after high-temperature activation is handled, be transported to and carry out abrasive dust in the grinding machine, fineness is 0.074 millimeter.
Two, the production method of brick for animal licking containing natural mineral, urea and molasses
1, the batching of brick for animal licking containing natural mineral, urea and molasses comprises following component by weight percentage: urea 50%, natural mineral lick additive 20%, water 15%, molasses 12% and salt 3%.
2, stir: the mixture after will preparing burden stirs.
3, compression moulding: the mixture after stirring, use brick machine to be pressed, brick for animal licking containing natural mineral, urea and molasses be shaped as annular, every weight is 1.5 kilograms.
4, dry naturally after, be packaged as finished product.
Claims (1)
1, a kind of production method of brick for animal licking containing natural mineral, urea and molasses, it is characterized in that: the batching of licking brick is made up of following component by weight percentage: urea 45～65%, natural mineral lick additive 10～30%, water 5～30%, molasses 5～15% and salt 2～5%; Mixture after the batching is stirred, use brick machine to be pressed, licking brick has rectangle, square, annular and cylindrical, and every Weight control after drying naturally, is packaged as finished product at 0.5～50 kilogram; The production method of described natural mineral lick additive is as follows: additive formulations is made up of following component by weight percentage: Concave-convex clay rod 20～60%, bentonite 10～40%, zeolite 5～30%, medical stone 2～15% and shell 2～10%; Mineral mixture after the batching is pulverized grain fineness≤2 millimeter; Get the sulfuric acid of 3～5% concentration 98% by weight percentage, 95～97% water preparation dilute sulfuric acid, the mineral mixture of getting by weight percentage after 45～65% the above-mentioned pulverizing is transported in the acidification pool, slowly adds the dilute sulfuric acid of preparing above, normal temperature acidification 24～48 hours; Mineral mixture after acidification is transported to and carries out the high-temperature activation processing in the roaster, and soak time was controlled at 1.5～3 hours, and temperature is controlled at 250～350 ℃; Mineral mixture after high-temperature activation is handled is transported to and carries out abrasive dust in the grinding machine, and fineness is controlled at 0.15～0.074 millimeter.
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| CN103315146B (en) * | 2013-06-06 | 2015-01-28 | 甘肃农业大学 | Nutritional licking brick comprising alfalfa protein, and preparation method thereof |
| CN105104784A (en) * | 2015-07-24 | 2015-12-02 | 张作勤 | Palygorskite clay preparation capable of increasing hen laying rate, and preparation method thereof |
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| CN105104785A (en) * | 2015-07-24 | 2015-12-02 | 张作勤 | Palygorskite clay enhancing chick physique and preparation method therefor |
| CN105918636A (en) * | 2016-04-27 | 2016-09-07 | 新疆畜牧科学院饲料研究所 | Camel special-purpose compound nutritive block for lapping and production method thereof |
| CN107981044A (en) * | 2017-12-13 | 2018-05-04 | 临沧宏胜生物科技开发有限公司 | Feed/food additives made of one kind molasses and/or blackstrap |
| CA3086151A1 (en) * | 2017-12-14 | 2019-06-20 | Agro Innovation International | Urea supplement for animal nutrition |
| CN110200146A (en) * | 2019-07-05 | 2019-09-06 | 江苏神力特生物科技股份有限公司 | One kind licking brick quality improver and preparation method thereof |
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