JPH02154068A - Production of polyester yarn for reinforcing rubber - Google Patents

Production of polyester yarn for reinforcing rubber

Info

Publication number
JPH02154068A
JPH02154068A JP30263788A JP30263788A JPH02154068A JP H02154068 A JPH02154068 A JP H02154068A JP 30263788 A JP30263788 A JP 30263788A JP 30263788 A JP30263788 A JP 30263788A JP H02154068 A JPH02154068 A JP H02154068A
Authority
JP
Japan
Prior art keywords
roller
yarn
temperature
relaxing
polyester fibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP30263788A
Other languages
Japanese (ja)
Inventor
Takahiro Okubo
隆弘 大久保
Nobuhiko Tsuzuki
都築 信彦
Nobuo Kumakura
熊倉 信夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Priority to JP30263788A priority Critical patent/JPH02154068A/en
Publication of JPH02154068A publication Critical patent/JPH02154068A/en
Pending legal-status Critical Current

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  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Chemical Treatment Of Fibers During Manufacturing Processes (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Artificial Filaments (AREA)

Abstract

PURPOSE:To reduce stain on drawing roller and end breakage and to obtain polyester yarn for reinforcing rubber by setting temperature of final drawing roller and temperature of relaxing roller in specific temperature ranges and providing the yarn with an epoxy-containing treating agent between the drawing roller and the relaxing roller. CONSTITUTION:In drawing polyester yarn prepared by melt spinning by using a drawing roller group, subjecting the yarn to relaxing heat treatment using a relaxing roller and winding the yarn, temperature of the final roller among in the drawing roller group is controlled in a range of 150-235 deg.C, temperature of relaxing roller temperature <=140 deg.C and the polyester yarn between the final drawing roller and the relaxing roller is provided with a treating agent containing an epoxy compound.

Description

【発明の詳細な説明】 [産業上の利用分野1 本発明は、ゴム補強用ポリエステル繊維の製造方法に関
するものである。詳しくは、タイヤベルト、ホースなど
の補強コードに用いるポリエステル繊維にエポキシ系化
合物を含む処理剤を付jjするゴム補強用ポリエステル
繊維の製造方法に関するしのである。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application 1] The present invention relates to a method for producing polyester fibers for rubber reinforcement. Specifically, the present invention relates to a method for producing polyester fibers for reinforcing rubber, which involves applying a treatment agent containing an epoxy compound to polyester fibers used for reinforcing cords for tire belts, hoses, etc.

[従来の技術] ポリエステル繊維とゴムとの接着性を改良する方法とし
て、該ポリエステル繊維にエポキシ系化合物を含む処理
剤を付与する技術、例えば、特開昭57−128271
号公報、特開昭58−18473号公報、特開昭61−
12970号公報などに記載されたものが知られている
特開昭57−128271号公報は、ポリエステル繊維
の製糸時に製糸油剤と同時にエポキシ化合物、エチレン
尿素化合物および、エチレン尿素化合物の重合触媒を付
与させ、後の延伸工程時の熱処理を利用して処理剤を熱
処理する技術が記載されている。
[Prior Art] As a method of improving the adhesion between polyester fibers and rubber, a technique of applying a treatment agent containing an epoxy compound to the polyester fibers is disclosed, for example, in JP-A-57-128271.
No. 58-18473, JP-A-61-
JP-A No. 57-128271, which is known as described in No. 12970, discloses that an epoxy compound, an ethylene urea compound, and a polymerization catalyst of an ethylene urea compound are applied simultaneously with a spinning oil during spinning of polyester fibers. , a technique is described in which a treatment agent is heat-treated using heat treatment during a subsequent stretching process.

特開昭58−18473り公報は、ポリエステル繊維の
紡糸工程、延伸工程で、エポキシ化合物およびエポキシ
硬化剤を紡糸油剤と混合、あるいは独立して付与した後
、熱処理をする技術が記載されている。
JP-A-58-18473 describes a technique in which an epoxy compound and an epoxy curing agent are mixed with a spinning oil or applied independently in the spinning and drawing steps of polyester fibers, and then heat-treated.

特開昭61−12970号公報には、;1でリエステル
繊維の紡糸工程及び/又は延伸工程でエポキシ化合物を
付与し、熱セットした涜、平滑剤と活性剤および、これ
らの平滑剤と活性剤との分離を防ぐ水を含有した油剤を
付与する技術が記載されている。
JP-A No. 61-12970 describes; 1) a polyester fiber to which an epoxy compound is applied during the spinning process and/or drawing process and heat set; a smoothing agent and an activator; A technique is described in which a water-containing oil agent is applied to prevent separation from the oil.

[発明が解決しようとする課1fil 前記の従来技術は、ポリエステル繊維に対して、親ポリ
エステル接着剤であるエポキシ化合物を含む処理剤を紡
糸工程又は/及び延伸工程で付与した擾、熱処理を行な
うものである。:J。
[Problem to be Solved by the Invention 1fil] The above-mentioned prior art involves applying a treatment agent containing an epoxy compound, which is a parent polyester adhesive, to polyester fibers in the spinning process and/or drawing process, and subjecting the fibers to spinning and heat treatment. It is. :J.

た、エポキシ化合物の開環、硬化触蝶であるアミン類を
エポキシ化合物と同時、あるいは別々に付与され、延伸
と同時又は引続いて行なわれる熱処理工程でエポキシ化
合物の開環重合−硬化反応を促進する方法も知られてい
る。
In addition, amines, which act as ring-opening and curing agents for the epoxy compound, are applied simultaneously or separately with the epoxy compound to promote the ring-opening polymerization-curing reaction of the epoxy compound in a heat treatment process that is performed simultaneously with or subsequent to stretching. There are also known methods.

これらのエポキシ化合物の付与、エポキシ硬化促進剤の
付与は、ポリエステル繊維が未延伸糸の状態あるいは、
延伸糸の状態にかかわらず熱処理工程より6前に行なわ
れるものである。
These epoxy compounds and epoxy curing accelerators are added to the polyester fibers when they are in an undrawn state or
This is carried out 6 times before the heat treatment step, regardless of the condition of the drawn yarn.

前記のように、ポリエステル*1tにエポキシ化合物を
付与し、引続いて熱処理する技術においては、熱処理に
用いる加熱ローラの表面にエポキシ化合物が付着し、該
加熱ローラの表面でエポキシ共重合体の樹脂膜が形成さ
れる。この樹脂膜が形成された加熱ローラにポリエステ
ル繊維を巻回して、熱延伸あるいは熱処理を行なう場合
、加熱ローラとポリエステル繊維との牽擦抵抗が増加す
るとと6に、ボッエステル繊維への熱伝導率が低下し、
得られるポリエステル繊維の物性、特に強度、伸度およ
びゴムとの接着性が変化し、均質とならなく、また加熱
ローラ上での単糸切れが多くなり、糸条全体の切断頻度
が増加するという欠点を有していた。さらに加熱ローラ
の表面に凶脂膜が形成され、熱伝導率の低下が明らかに
なった場合は、加熱ローラを洗浄するという作業を有し
、この間操業を中断せざるを得なく、操業性の低下およ
び161脂膜除去作業を要するという欠点を有していた
As mentioned above, in the technique of applying an epoxy compound to polyester*1t and subsequently heat-treating it, the epoxy compound adheres to the surface of the heating roller used for heat treatment, and the epoxy copolymer resin is deposited on the surface of the heating roller. A film is formed. When polyester fibers are wound around a heating roller on which this resin film is formed and subjected to hot stretching or heat treatment, the thermal conductivity of the Bossester fibers increases as the frictional resistance between the heating roller and the polyester fibers increases. decreases,
The physical properties of the resulting polyester fibers, particularly their strength, elongation, and adhesion to rubber, change, making them less homogeneous, and single yarn breakage increases on the heating roller, increasing the frequency of cutting the entire yarn. It had drawbacks. Furthermore, if a fat film is formed on the surface of the heating roller and it becomes clear that the thermal conductivity has decreased, the heating roller must be cleaned. However, it has the drawbacks of lowering the temperature and requiring removal of the 161 oil film.

本発明の目的は、前記従来の技術が有していた欠点を解
消するものである。
The object of the present invention is to overcome the drawbacks of the prior art.

本発明の第1の目的は、ポリエステル繊維の製造1捏で
、ゴムとの接着性を向上させるために付与するエポキシ
系化合物の加熱ローラへの脱落、樹脂膜形成により生じ
る該ポリエステル繊維の経時変化による品質の不均一を
なくし、単糸切れを減少して高品質のゴム補強用ポリエ
ステル繊維を得ることにある。
The first object of the present invention is to solve the problem of changes in the polyester fibers over time that occur during one kneading process of polyester fibers, such as drop-off of the epoxy compound added to the heating roller to improve adhesion to rubber and formation of a resin film. The objective is to eliminate unevenness in quality caused by polyester fibers, reduce single yarn breakage, and obtain high quality polyester fibers for rubber reinforcement.

また、本発明の第2の目的は、0記ゴム補強用ポリエス
テル繊維の製造工程における該ポリエステル繊維の単糸
切れを減少し、製糸性を向上させることにある。
A second object of the present invention is to reduce single filament breakage of polyester fibers in the manufacturing process of polyester fibers for reinforcing No. 0 rubber, and to improve spinning properties.

さらに、本発明の第3の目的は、加熱ローラの表面にエ
ポキシ系化合物による樹脂膜が形成された場合の加熱ロ
ーラの洗浄作業を減少し、操業性を向上させることにあ
る。
Furthermore, a third object of the present invention is to reduce the cleaning work of the heating roller when a resin film made of an epoxy compound is formed on the surface of the heating roller, thereby improving operability.

[81題を解決するための手段および作用]本発明の梢
成は、 (1)ゴム補強用ポリエステル繊維の製造法において、
溶融紡糸されたポリエステル繊維を延伸ローラ群を用い
て延伸し、引続き弛緩ローラを用いて弛緩処理した後巻
取装置を用いて巻取るに際し、前記最終延伸ローラと弛
緩ローラの間のポリエステル繊維に、エポキシ化合物を
含む処理剤を付与することを特徴とするゴム補強用ポリ
エステル繊維の製造方法であり、 (2)特許請求の範囲第(1)項において、延伸ローラ
群の最終延伸ローラ温度を150〜235℃の範囲でか
つ、弛緩ローラの1品度を140℃以下に制御すること
を特徴とするゴム補強用ポリエステル繊維の製造法にあ
る。
[Means and effects for solving the 81 problems] The present invention has the following features: (1) In the method for producing polyester fiber for rubber reinforcement,
When the melt-spun polyester fibers are stretched using a group of stretching rollers, followed by relaxation treatment using a relaxation roller, and then wound up using a winding device, the polyester fibers between the final stretching roller and the relaxation roller are A method for producing polyester fibers for rubber reinforcement, characterized in that a processing agent containing an epoxy compound is applied, The present invention provides a method for producing polyester fibers for rubber reinforcement, characterized in that the temperature is within the range of 235°C and the quality of the relaxing roller is controlled to 140°C or less.

本発明について図面を用いて詳述する0図面は本発明の
方法に隔る一例を示ずらので、ポリエステル繊維の延伸
巻取装置の部分概略正面図である、ポリエステル繊維か
らなる糸条Y1は例えば紡糸工程(図示せず)から矢印
aの方向に延伸工程に至り、ネルソンを形成する延伸ロ
ーラ1.1゛および最終延伸1コーラ2.2′を経て延
伸されて延伸糸Y2となる0次いで弛緩ローラ3.3−
に巻回されて弛緩処理されて弛緩処理系Y3となり、 
@1!a’!4によってボビン5に巻取られる。
The present invention will be described in detail with reference to the drawings. The drawings do not show an example of the method of the present invention, so the yarn Y1 made of polyester fibers, which is a partially schematic front view of a drawing and winding device for polyester fibers, is for example The spinning process (not shown) leads to the drawing process in the direction of arrow a, where it is drawn through a drawing roller 1.1' forming a nelson and a final drawing cola 2.2' to become a drawn yarn Y2. Roller 3.3-
is wound and subjected to relaxation treatment to become relaxation treatment system Y3,
@1! a'! 4 onto a bobbin 5.

助記最終延伸ローラ2.2−と弛緩ローラ3.3゛との
間の糸道に処理剤付与装置6が設けられている。前記最
終延伸ローラ2.2“で延伸熱処理された延伸糸Y2は
、直ちに処理剤付与装置によって、エポキシ化合物を含
む処理剤を付与され延伸処理剤付jj糸2゛となる。エ
ポキシ化合物を含む処Jl!削が付与される際、前記延
伸糸Y2は、最終延伸ローラ2.2゛で加熱された熱を
保有しており、エポキシ化合物を含む処理剤は延伸糸Y
2の有する熱によって、直ちに熱処理された状態となる
。弛緩ローラ3.3−以降、巻11!fi4を用いて糸
巻ボビン5に糸条を巻取る。
A processing agent applying device 6 is provided in the yarn path between the final stretching roller 2.2- and the relaxing roller 3.3''. The drawn yarn Y2 that has been drawn and heat-treated by the final drawing roller 2.2'' is immediately applied with a treatment agent containing an epoxy compound by a treatment agent applying device to become a drawn yarn 2'' with a treatment agent. When the Jl! scraping is applied, the drawn yarn Y2 retains the heat heated by the final drawing roller 2.2゛, and the treatment agent containing the epoxy compound is applied to the drawn yarn Y2.
The heat of No. 2 immediately puts it in a heat-treated state. Relaxation roller 3.3-after, volume 11! The yarn is wound onto the bobbin 5 using fi4.

前記エポキシ化合物を含む処理剤が付与された廷仲処理
剤付与糸Y2−は、巻取機に巻かれるまでの距離を走行
する間、例えば弛緩ローラ3.3−上から巻取機までに
大部分が安定化されている。前記最終延伸ローラ2.2
−の温度が150’C未満の時は、延伸処理剤付与糸Y
2゛上でのエポキシ化合物を含む処理剤の固化速度が遅
く、得られた糸条とゴムとの接着力が低くかつ、強力が
低下することがある。
While the processing agent-applied yarn Y2- to which the processing agent containing the epoxy compound has been applied travels the distance until it is wound around the winder, for example, the yarn Y2- to which the treatment agent containing the epoxy compound has been applied runs a long distance from above the relaxation roller 3.3- to the winder. parts are stabilized. Said final stretching roller 2.2
- When the temperature is less than 150'C, the drawing agent applied yarn Y
The solidification rate of the processing agent containing the epoxy compound on the 2nd floor is slow, and the adhesive force between the obtained yarn and the rubber is low, and the strength may be reduced.

一方弛緩ローラ3.3゛の温度が150°Cよりも高い
場合、該弛緩ローラ3.3゛上で脱落したエポキシが樹
脂化し、強力低下などが見られ、得られた糸条の品質の
経時変化が生じるとともに単糸切れが生じ易くなる。
On the other hand, if the temperature of the relaxing roller 3.3'' is higher than 150°C, the epoxy that has fallen off on the relaxing roller 3.3'' will turn into resin, resulting in a decrease in strength, and the quality of the obtained yarn will deteriorate over time. As changes occur, single thread breakage becomes more likely.

したがって、エポキシ化合物を含む処理剤を付与する直
前の最終延伸ローラ2.2゛の温度を150〜235℃
の範囲、好ましくは200〜235℃とし、弛緩ローラ
3.3゛の温度を140℃以下、または無加熱に1:る
のが好まし[実施例] 実施例1〜7および比較例1〜6 高分子ポリエチレンテレフタレートを溶融紡糸し、得ら
れたポリエステル繊維を冷却および紡糸油剤の付与を行
なったのち、引取りローラを経て延伸ローラおよび弛緩
ローラを用いて、延伸および弛緩処理を施した。弛緩処
理系は1000デニール(単糸デニール5.2dlにな
るように条件を設定した。j!!仲は多段延伸で最終延
伸ローラの回転速度を2373 m/iinとし、該延
伸ローラの温度を種々変更した。
Therefore, the temperature of the final stretching roller 2.2'' immediately before applying the treatment agent containing the epoxy compound is set at 150 to 235℃.
The temperature of the relaxing roller 3.3 is preferably 140°C or lower or without heating [Example] Examples 1 to 7 and Comparative Examples 1 to 6 High-molecular polyethylene terephthalate was melt-spun, and the obtained polyester fibers were cooled and applied with a spinning oil, and then passed through a take-up roller and subjected to stretching and relaxing treatment using a stretching roller and a relaxing roller. Conditions were set so that the relaxation treatment system had a denier of 1000 (single yarn denier 5.2 dl). In the case of multi-stage stretching, the rotation speed of the final stretching roller was set to 2373 m/iin, and the temperature of the stretching roller was varied. changed.

一方、弛緩処理ローラの回転速度を2302!/1nと
し、弛緩ローラの温度を種々変更した。
On the other hand, the rotational speed of the relaxation processing roller is 2302! /1n, and the temperature of the relaxing roller was variously changed.

各条件は表1および表2に示すとおりである。Each condition is as shown in Tables 1 and 2.

また、前記の轟終延伸処理ローラと弛緩ローラとの間の
延伸糸にエポキシ化合物を含む処理剤としてポリグリセ
リンのジグリシジルエーテルの60%水溶液を用い、E
fIilO〜20e9/106付与した。
In addition, a 60% aqueous solution of diglycidyl ether of polyglycerin was used as a treatment agent containing an epoxy compound for the drawn yarn between the above-described final stretching roller and the relaxation roller, and E
fIilO~20e9/106 was given.

得られたポリエステル繊維の特性は表1および表2に示
すとおりであった。
The properties of the obtained polyester fibers were as shown in Tables 1 and 2.

(以下余白) 表1および表2に示すとおり、本発明の方法によると、
特に製糸中の糸切れが少なく安定してゴム補強用繊維を
製造することができ、得られたゴム補強用繊維の経時糸
質変化が少なく、ゴムとの接着性も良好である。特に従
来の方法である比較例1および比較例2の場合、延伸ロ
ーラの表面汚れによって単糸切れが生じ、糸切れの原因
となり品質が安定しない。
(The following is a blank space) As shown in Tables 1 and 2, according to the method of the present invention,
In particular, rubber reinforcing fibers can be stably produced with less thread breakage during spinning, and the obtained rubber reinforcing fibers show little change in quality over time and have good adhesion to rubber. In particular, in the case of Comparative Example 1 and Comparative Example 2, which are conventional methods, single yarn breakage occurs due to surface contamination of the drawing roller, causing yarn breakage and resulting in unstable quality.

したがって、比較例1および比較例2に限って0.2t
On製糸するごとにローラ洗浄を行なったにもかかわら
ず糸切れが多く発生した。他の実施例1〜7比較例3〜
6においては、紡糸油剤によるローラの表面汚れ除去の
ため2 ton製糸するごとにローラの表面汚れを洗浄
するというように、洗浄インターバルを10倍としても
糸切れは極めて少数であり製糸性が良好であった。
Therefore, only 0.2t in Comparative Example 1 and Comparative Example 2
Even though the rollers were cleaned every time yarn was spun, many yarn breakages occurred. Other Examples 1-7 Comparative Examples 3-
In No. 6, the roller surface dirt was cleaned every 2 tons of yarn to remove the surface stains on the roller caused by the spinning oil, and even if the cleaning interval was increased by 10 times, the yarn breakage was extremely small and the spinning performance was good. there were.

しかし、最終延伸ローラ温度が2715”Cの場合は糸
強力が低下し、140℃では熱処理不足のため、接着力
、糸強力が低下した。
However, when the final stretching roller temperature was 2715"C, the yarn strength decreased, and at 140.degree. C., the adhesive strength and yarn strength decreased due to insufficient heat treatment.

し発明の効果] 本発明のゴム補強用ポリエステル繊維の製造法によると
、エポキシ化合物を含む処理剤を最終延伸ローラから導
出された糸条に付与することによって、最終延伸ローラ
の汚れを減少し、製糸中の糸切れ数を減少することがで
きる。
[Effects of the Invention] According to the method for producing polyester fibers for rubber reinforcement of the present invention, staining of the final stretching roller is reduced by applying a treatment agent containing an epoxy compound to the yarn drawn out from the final stretching roller, The number of yarn breaks during yarn spinning can be reduced.

また、得られたゴム補強用ポリエステル繊維は経時糸質
変化を生じなく、ゴムとの接着力も良好であるなどの効
果を有する。
In addition, the obtained polyester fibers for reinforcing rubber do not change in quality over time and have good adhesion to rubber.

さらに、最終延伸ローラの汚れが減少したことによって
、延伸ローラの洗浄インターバルを延長することができ
、洗浄時に要する製糸の中断時間および洗浄作業を減少
し、生産性および作業上の向上にも効果を有する。
Furthermore, by reducing the contamination of the final drawing roller, the cleaning interval for the drawing roller can be extended, which reduces the interruption time of yarn spinning and the cleaning work required for cleaning, which also has the effect of improving productivity and operational efficiency. have

【図面の簡単な説明】[Brief explanation of the drawing]

図面は本発明のゴム補強用ポリエステル繊維の製造方法
に係る延伸巻取装置の部分概略図である。 1.1−・・・・・・延伸ローラ、 22−・・・・・・最終延伸ローラ、 3.3−・・・・・・弛緩ローラ、4・・・・・・巻取
装置、5・・・・・・ボビン、6・・・・・処理剤付与
装置、7・・・・・・ガイドローラ、Yl・・・・・・
糸条、¥2 ・・・・・・延伸糸 Yl−・・・・・・延伸処理剤付与糸 Y3 ・・・・・・弛#1処理系
The drawing is a partial schematic diagram of a stretching and winding device according to the method for producing polyester fibers for rubber reinforcement of the present invention. 1.1-... Stretching roller, 22-... Final stretching roller, 3.3-... Relaxing roller, 4... Winding device, 5 ...Bobbin, 6...Processing agent applying device, 7...Guide roller, Yl...
Yarn, ¥2 ..... Stretched yarn Yl - .... Stretching treatment agent added yarn Y3 ..... Relaxation #1 treatment system

Claims (2)

【特許請求の範囲】[Claims] (1)ゴム補強用ポリエステル繊維の製造法において、
溶融紡糸されたポリエステル繊維を延伸ローラ群を用い
て延伸し、引続き弛緩ローラを用いて弛緩処理した後巻
取装置を用いて巻取るに際し、前記最終延伸ローラと弛
緩ローラとの間のポリエステル繊維にエポキシ化合物を
含む処理剤を付与することを特徴とするゴム補強用ポリ
エステル繊維の製造法。
(1) In the manufacturing method of polyester fiber for rubber reinforcement,
When the melt-spun polyester fibers are stretched using a group of stretching rollers, followed by relaxation treatment using a relaxation roller, and then wound up using a winding device, the polyester fibers between the final stretching roller and the relaxation roller are A method for producing polyester fiber for rubber reinforcement, which comprises applying a treatment agent containing an epoxy compound.
(2)特許請求の範囲第(1)項において、延伸ローラ
群の最終延伸ローラ温度を150〜235℃の範囲でか
つ、弛緩ローラの温度を140℃以下に制御することを
特徴とするゴム補強用ポリエステル繊維の製造法。
(2) The rubber reinforcement according to claim (1), characterized in that the final stretching roller temperature of the stretching roller group is controlled in the range of 150 to 235°C, and the temperature of the relaxation roller is controlled to 140°C or less. Method for manufacturing polyester fiber for use.
JP30263788A 1988-11-30 1988-11-30 Production of polyester yarn for reinforcing rubber Pending JPH02154068A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP30263788A JPH02154068A (en) 1988-11-30 1988-11-30 Production of polyester yarn for reinforcing rubber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP30263788A JPH02154068A (en) 1988-11-30 1988-11-30 Production of polyester yarn for reinforcing rubber

Publications (1)

Publication Number Publication Date
JPH02154068A true JPH02154068A (en) 1990-06-13

Family

ID=17911382

Family Applications (1)

Application Number Title Priority Date Filing Date
JP30263788A Pending JPH02154068A (en) 1988-11-30 1988-11-30 Production of polyester yarn for reinforcing rubber

Country Status (1)

Country Link
JP (1) JPH02154068A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008056645A1 (en) * 2006-11-07 2008-05-15 Teijin Fibers Limited Polyester multifilament for resin reinforcement and process for producing the same

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5218921A (en) * 1975-08-01 1977-02-12 Teijin Ltd Preparation of polyester fiber material for reinforcing rubber
JPS59211626A (en) * 1983-05-18 1984-11-30 Toray Ind Inc Method for improving adhesive property of polyester fiber for reinforcing rubber

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5218921A (en) * 1975-08-01 1977-02-12 Teijin Ltd Preparation of polyester fiber material for reinforcing rubber
JPS59211626A (en) * 1983-05-18 1984-11-30 Toray Ind Inc Method for improving adhesive property of polyester fiber for reinforcing rubber

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008056645A1 (en) * 2006-11-07 2008-05-15 Teijin Fibers Limited Polyester multifilament for resin reinforcement and process for producing the same

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