JPH02154067A - Production of polyester yarn for reinforcing rubber - Google Patents
Production of polyester yarn for reinforcing rubberInfo
- Publication number
- JPH02154067A JPH02154067A JP30263688A JP30263688A JPH02154067A JP H02154067 A JPH02154067 A JP H02154067A JP 30263688 A JP30263688 A JP 30263688A JP 30263688 A JP30263688 A JP 30263688A JP H02154067 A JPH02154067 A JP H02154067A
- Authority
- JP
- Japan
- Prior art keywords
- roller
- yarn
- heat treatment
- epoxy compound
- relaxation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000728 polyester Polymers 0.000 title claims abstract description 38
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 230000003014 reinforcing effect Effects 0.000 title abstract description 5
- 150000001875 compounds Chemical class 0.000 claims abstract description 30
- 238000010438 heat treatment Methods 0.000 claims abstract description 29
- 239000004593 Epoxy Substances 0.000 claims abstract description 28
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 230000002040 relaxant effect Effects 0.000 claims abstract description 10
- 239000000835 fiber Substances 0.000 claims description 32
- 238000004804 winding Methods 0.000 claims description 11
- 230000002787 reinforcement Effects 0.000 claims description 9
- 238000000926 separation method Methods 0.000 abstract description 3
- 238000002074 melt spinning Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 description 15
- 238000009987 spinning Methods 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- -1 ethylene urea compound Chemical class 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000007142 ring opening reaction Methods 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000035922 thirst Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Artificial Filaments (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Chemical Treatment Of Fibers During Manufacturing Processes (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分前］
本発明は、ゴム補強用ポリエステル繊維の製造方法に関
するものである。詳しくは、タイヤベルト、ホースなど
の補強コードに用いるポリエステル繊維に１ポキシ系化
合物を含む処理剤を付与するゴム補強用ポリエステルｗ
４Ｎの製造方法に関づるものである。DETAILED DESCRIPTION OF THE INVENTION [Prior to Industrial Use] The present invention relates to a method for producing polyester fibers for rubber reinforcement. For details, please refer to our rubber reinforcing polyester w, which applies a treatment agent containing a 1-poxy compound to polyester fibers used in reinforcing cords for tire belts, hoses, etc.
This relates to a method of manufacturing 4N.
「従来の技術１
ポリ」−ステル繊刺１とゴムとの接着性を改良Ｊる方法
としで、該ポリエステル繊維にエポキシ系化合物を含む
処理剤を付与する技術としては例えば、特開昭５７−１
２８２７１号公報、特開昭５８−１８４７３号公報、特
開昭６１−１２９７０号公ｔｌ１などに詔載されたちの
が知られている。"Prior Art 1 Poly" - As a method of improving the adhesion between the stellate fibers 1 and rubber, techniques for applying a treatment agent containing an epoxy compound to the polyester fibers include, for example, JP-A-57- 1
It is known that this is published in JP-A No. 28271, JP-A-58-18473, JP-A-61-12970 tl1, etc.
特開昭５７−１２８２７１号公報は、ポリエステル繊維
の製糸時に製糸油剤と同時にエポキシ化合物、１チレン
尿素化合物Ｊ３Ｊ：び、エチレン尿素化合物の重合触媒
を付与させ、後の延伸工程時の熱処理を利用して熱処理
をする技術が記載されている。JP-A-57-128271 discloses that a polymerization catalyst of an epoxy compound, a 1-thylene urea compound J3J: and an ethylene urea compound is applied simultaneously with a spinning oil agent during spinning of polyester fiber, and then heat treatment is used during the subsequent stretching process. A technique for heat treatment is described.
特開昭５８−１８４７３号公報は、ポリエステル繊維の
紡糸■稈、延伸工程″Ｃ、エポキシ化合物およびエポキ
シ硬化剤を紡糸油剤と混合、あるいは独立してイ・］与
した後熱処理をづる技術が記載されている。JP-A No. 58-18473 describes a technique of spinning polyester fibers, drawing process ``C'', mixing an epoxy compound and an epoxy curing agent with a spinning oil, or independently applying heat treatment after applying ``C''. has been done.
特開昭６１−１２９７０号公報には、ポリニスデル繊維
の紡糸工程及び／又は延伸工程で］−ボキシ化合物を付
与し、熱セットした後、平滑剤と活性剤および、これら
の平滑剤と活性剤との分離を防ぐ水を金石したｉ＋ｌ＋
剤をイ４ち４る技術が記載されている。JP-A No. 61-12970 discloses that in the spinning process and/or drawing process of polynisder fibers, a -boxy compound is added, and after heat setting, a smoothing agent and an activator, and i+l+ containing water to prevent separation of
Techniques for preparing agents are described.
し発明が解決しようとＪる課題１
前記の従来技術は、ポリエステル繊維に対して、親ポリ
ニスデル接着剤であるエポキシ化合物を含む処理剤を紡
糸工程又は／及び延伸工程で付与し後熱処理を行なうも
のである。また、エポキシ化合物の開環、硬化触媒ひあ
るアミン類をエポキシ化合物と同時、あるいは別々に付
与され、延伸と同時又は引続いて行なわれる熱処理工程
でエポキシ化合物の開環重合−硬化反応を促進づる方法
も知られている。Problem 1 to be Solved by the Invention The above-mentioned prior art applies a treatment agent containing an epoxy compound, which is a parent polynisder adhesive, to polyester fibers during the spinning process and/or drawing process, and then performs a post-heat treatment. It is. In addition, a ring-opening and curing catalyst for the epoxy compound, such as amines, can be applied simultaneously or separately with the epoxy compound to promote the ring-opening polymerization-curing reaction of the epoxy compound in a heat treatment process that is carried out simultaneously with or subsequent to the stretching. Methods are also known.
これらのエポキシ化合物の付与、エポキシ硬化促進剤の
イ」勺は、ポリエステル繊維が未延伸糸の状態あるいは
、延伸糸の状態にかかわらず熱処理工程よりも前に行な
われるものである。The application of these epoxy compounds and the application of the epoxy curing accelerator are carried out before the heat treatment step, regardless of whether the polyester fiber is in an undrawn yarn state or a drawn yarn state.
前記のように、ポリエステル繊維にエポキシ化合物を付
与し引続いて熱処理する技術においては、熱処理に用い
る加熱ローラの表面にエポキシ化合物が付着し、該加熱
ローラの表面でエボ４シ共重合体の樹脂膜が形成される
。この樹脂膜が形成された加熱Ｌ−１−ラにポリエステ
ル繊維を巻回して、熱延伸あるいは熱処理を行なう場合
、加熱［１−ラとポリエステル繊維との摩擦抵抗が変化
するとともに、ポリエステル繊和への熱伝導率が変化し
、１！１られるポリエステル繊維の物性、特に強度、伸
度およびゴムとの接着性が変化し、均質とならなく、ま
た加熱ローラ上での単糸切れが多くなり、糸条全体の切
断頻瓜が増加するという欠点を有していた。さらに加熱
ローラの表面に樹脂膜が形成された熱伝導率の低下が明
らかになった場合は、加熱ローラを交換するという作業
をイｊし、この間操業を中断せざるを得なく、操業性の
低下および樹脂膜除去作業を要するという欠点を有して
いた。As mentioned above, in the technique of applying an epoxy compound to polyester fibers and subsequently heat-treating them, the epoxy compound adheres to the surface of the heating roller used for the heat treatment, and the resin of the EVO 4 copolymer is deposited on the surface of the heating roller. A film is formed. When polyester fibers are wound around the heated L-1-la on which this resin film has been formed and subjected to hot stretching or heat treatment, the heating [1-la] changes the frictional resistance between the polyester fiber and the polyester fibers. The thermal conductivity of the polyester fiber changes, and the physical properties of the polyester fiber, especially its strength, elongation, and adhesion to rubber, change by 1! This method has the disadvantage that the frequency of cutting of the entire thread increases. Furthermore, if it becomes clear that a resin film has formed on the surface of the heating roller, resulting in a decrease in thermal conductivity, the work of replacing the heating roller will have to be canceled, and operations will have to be interrupted during this period, resulting in poor operability. However, it has the drawbacks of lowering the temperature and requiring work to remove the resin film.
本発明の目的は、前記従来の技術が有していた欠点を解
消するものであり、本発明の第１の目的は、ゴムとの接
着性を向トさせるために付与するエポキシ系化合物が付
与されたゴム補強用ポリエステル繊維の製造工程におけ
る該ポリニス７ ）Ｌｔ繊維経時変化による品質の不均
一をなくし、単糸切れを減少して高品質のゴム補強用ポ
リエステル繊維を得ることにある。The purpose of the present invention is to eliminate the drawbacks of the conventional techniques, and the first purpose of the present invention is to improve the adhesion with rubber by applying an epoxy compound. The polyvarnish in the manufacturing process of rubber-reinforcing polyester fibers 7) To eliminate unevenness in quality due to aging of Lt fibers and to reduce single yarn breakage to obtain high-quality rubber-reinforcing polyester fibers.
また、本発明の第２の目的は、前記ゴム補強用ポリエス
テルＩＩＩＩの製造工程における該ポリエステル繊維単
糸切れを誠少し、製糸性を向上させることにある。A second object of the present invention is to reduce the breakage of single filaments of the polyester fibers in the manufacturing process of the rubber-reinforcing polyester III, thereby improving yarn spinning properties.
ざらに、本発明の第３の目的１ま、加熱Ｌｌ−ラの表面
にエポキシ系化合物による樹脂膜が形成された場合の加
熱ローラの洗浄作業を減少し、操業性を向りさＵること
にある。In summary, the third object of the present invention is to reduce the cleaning work of the heating roller when a resin film made of an epoxy compound is formed on the surface of the heating roller, and to improve operability. be.
［課題を解決するための手段および作用１本発明の構成
は、
（１）ゴム補強用ポリエステル繊維雑の製造方法におい
て、溶融紡糸されたポリエステルｔｌｉ雑を延伸ローラ
群を用いて延伸し、引続き弛緩［１−ラを用いて弛緩熱
処理した後巻取装置を用いて巻取るに際し、前記弛緩Ｌ
］−ラを餠服した直後のポリ１ステルｍ紺にエポキシ化
合物を含む処理剤を付与することを特徴とする徴どする
ゴム補強用ポリエステル４＆ｌｉ雑の製造方法にあり、
（２）特許請求の範囲第（１）項において、延伸Ｌ】−
ラ群の最終の延伸ローラおよび弛緩ローラのｆ；Ａ度を
１５０〜２３５℃の間開となるように制Ｍｌることを特
徴とするゴム補強用ポリエステルＩｌｉ雑の製造方法に
ある。[Means and Effects for Solving the Problems 1] The constitution of the present invention is as follows: (1) In a method for producing polyester fiber miscellaneous material for rubber reinforcement, melt-spun polyester tli miscellaneous material is stretched using a group of stretching rollers, and then relaxed. [1-When winding up using a winding device after the relaxation heat treatment using L, the relaxation L
] - A method for producing polyester 4 & li miscellaneous for rubber reinforcement characterized by applying a treatment agent containing an epoxy compound to polyester 1 stel m navy blue immediately after coating with rubber, (2) patent claim In range item (1), stretching L]-
A method for producing polyester materials for rubber reinforcement, characterized in that the final stretching roller and relaxation roller of the A group are controlled to have a degree of A of 150 DEG to 235 DEG C.
本発明について図面を用いて詳ｊホする。図面は本発明
の方にに係る一例を示すもので、ポリエステル繊維の延
伸巻取装；Ｎの部分概略正面図である。ポリ１ステル繊
維からなる糸条Ｙ１は例えば紡糸工程（図示せず）から
矢印ａの方向に延伸Ｉ Ｐｆ！至り、ネルソンを形成す
る延伸ローラ１．１′および延伸ローラ２．２′を紅で
延伸されて延伸糸Ｙ２となり、次いで弛緩ローラ３．３
′巻回されて弛緩熱処理されて弛緩熱処理系Ｙ３となり
、巻取ｌ５１４によってボビン５に巻取られる。The present invention will be described in detail with reference to the drawings. The drawing shows an example of the present invention, and is a partially schematic front view of a drawing and winding device for polyester fiber; The yarn Y1 made of poly 1 stellate fiber is stretched in the direction of arrow a from a spinning process (not shown), for example. Finally, the drawing roller 1.1' and the drawing roller 2.2' forming the nelson are drawn in red to form the drawn yarn Y2, and then the relaxing roller 3.3 is drawn.
' It is wound and subjected to a relaxation heat treatment to become a relaxation heat treatment system Y3, which is then wound onto the bobbin 5 by a winder 1514.
前記弛緩ローラ３．３−と巻取機４との間の糸道に処理
剤付与装置６が設りられている。前記弛緩し］−ラ３．
３−で弛緩熱処理された弛緩熱処理糸Ｙ３は、直ちに処
理剤付与装置によって、エポキシ化合物を含む処理剤を
付与されるエポキシ化合物を含む処理剤が付与される際
、前記弛緩熱処理系Ｙ３は、弛緩ローラ３．３′で加熱
された熱を保有しており、エポキシ化合物を含む処理剤
は弛緩熱１１！ｌ糸Ｙ３のイｊする熱によって、直ちに
熱処理された状態となる。巻取機４を用いて糸巻ボビン
５に糸条を巻取る際には、巻取機４に設けられているト
ラバースガイドなどによって、糸条がトシバースされる
がこの場合１−ラバース幅によって一定笥囲のフリーレ
ングスを要する。A treatment agent applying device 6 is provided in the yarn path between the relaxation roller 3.3- and the winder 4. said relaxation] - La 3.
The relaxed heat-treated yarn Y3 subjected to the relaxation heat treatment in step 3- is immediately applied with a processing agent containing an epoxy compound by a processing agent application device.When the processing agent containing an epoxy compound is applied, the relaxation heat treatment system Y3 It has heat heated by roller 3.3', and the treatment agent containing an epoxy compound has a heat of relaxation of 11! The heat generated by the yarn Y3 immediately brings it into a heat-treated state. When the yarn is wound onto the bobbin 5 using the winder 4, the yarn is traversed by a traverse guide provided in the winder 4. Requires free length.
前記エポキシ化合物を含む処理剤が付与された弛緩熱処
理系Ｙ３は、フリーレングスに要するに距離を走行する
間、例えばガイド［＋−ラフに至るまでに大部分が安定
化されている。ガイドローラフを設けることなく直接巻
取機に到達させて巻取る場合には、該巻取機に到達する
までの間安定化される。若し、前記の弛緩熱処理系Ｙ３
にエポキシ化合物を含む処理された侵のフリーレングス
が短く、ガイドローラ７あるいは、巻取Ｉａ４にエポキ
シ化合物を含む処理剤が付着して）りれる場合には、前
記延伸ローラ２．２′および弛緩ロー′７３．３′の湿
度を１５０〜２３５℃の範囲と／２るように制御するこ
とによつＣ１弛緩熱処理系Ｙ３の渇痕を間接制御し前記
ガイドローラ７および巻取機へのエポキシ化合物を含む
処理剤の付着を皆無あるいは、微少けに留めることがで
きる。The relaxation heat treatment system Y3 to which the treatment agent containing the epoxy compound has been applied is largely stabilized while it travels the free length distance, for example, until it reaches the guide [+-rough]. When winding the material directly by reaching the winding machine without providing a guide roller rough, it is stabilized until it reaches the winding machine. If the above relaxation heat treatment system Y3
If the free length of the treatment agent containing an epoxy compound is short and the treatment agent containing the epoxy compound adheres to the guide roller 7 or the winding Ia4), the stretching roller 2.2' and the relaxation By controlling the humidity of the row '73.3' to be within the range of 150 to 235°C, the thirst marks of the C1 relaxation heat treatment system Y3 are indirectly controlled, and the epoxy is applied to the guide roller 7 and the winding machine. Adhesion of processing agents containing compounds can be eliminated or minimized.
前記延伸Ｌ】−ラ２．２′および弛緩［］−ラ３３′の
温度が１５０℃未満の時は、弛緩熱処理系Ｙ３１でのＪ
９ポ４シ化合物を含む処理剤の固化速度が遅く、ガイド
ローラ７および巻取装置を汚すことがあるのみではなく
、得られた糸条とゴムとの接着力の低下および強力が低
下することがある。When the temperature of the stretching L]-Ra 2.2' and relaxation []-Ra 33' is less than 150°C, J in the relaxation heat treatment system Y31
The solidification rate of the processing agent containing the 9-4-polymer compound is slow, which may not only stain the guide roller 7 and the winding device, but also reduce the adhesive strength and strength between the obtained yarn and the rubber. There is.
一方、延伸ローラ２．２′および弛緩【］−５３，３−
の温度が２３５℃よりも高い場合、該弛緩ローラ３．３
′上で弛緩熱処理系Ｙ３の強力の低ドなどが見られ、得
られた糸条の品質の経時変化が生じるとともに中糸切れ
が生じ易くなる。したがって、エポキシ化合物を含む処
理剤を付与する直前の弛緩ローラ３．３−および最終の
延伸ローラ２．２−の温度を１５０〜２３５℃の範囲と
するのがより好ましい。On the other hand, the stretching roller 2.2' and the relaxation []-53,3-
If the temperature of the relaxation roller 3.3 is higher than 235°C.
'A decrease in the strength of the relaxation heat treatment system Y3 was observed, and the quality of the obtained yarn changed over time, and intermediate thread breakage was likely to occur. Therefore, it is more preferable that the temperature of the relaxing roller 3.3- and the final stretching roller 2.2- immediately before applying the treatment agent containing the epoxy compound is in the range of 150 to 235°C.
［実施例１
実施例１〜１１Ｊ３よび比較例１〜２
八分子ポリエヂレンテレフタレートを溶融紡糸し、得ら
れたポリエステル繊維を冷却および紡糸油剤の付与を（
１なったのら、引取り目−ラを経て延伸ローラおよび弛
緩ローラを用いて、延伸および弛緩処理を施した。該延
伸および弛緩処理糸条は１０００デニール（単糸デニー
ル５．２ｄ）になるように条件を設定した。延伸（よ多
段延伸とし最終の延伸ローラの回転速度を２３７３ ｍ
／ｍｉｎとし、該延伸ローラの温度を種々変更した。[Example 1 Examples 1 to 11J3 and Comparative Examples 1 to 2 Octamolecular polyethylene terephthalate was melt-spun, and the obtained polyester fiber was cooled and a spinning oil was applied (
1, the film was subjected to stretching and relaxing treatment using a stretching roller and a relaxing roller after passing through a drawing line. Conditions were set so that the stretched and relaxed yarn had a denier of 1000 (single yarn denier 5.2 d). Stretching (Multi-stage stretching with final stretching roller rotation speed of 2373 m)
/min, and the temperature of the stretching roller was variously changed.
一方、弛Ｍ処１！ｌ １１−ラの回転速度を２３０２１
１／ｌｌ１ｉｎとした。各条件は表１および表２に示Ｊ
とおりである。On the other hand, slack M place 1! l The rotation speed of 11-ra is 23021
It was set to 1/11in. Each condition is shown in Tables 1 and 2.
That's right.
また、前記の弛緩処理ローラと巻取装置との間の弛緩ロ
ーラから導出された直後の弛緩処理糸条にエポキシ化合
物を含む処理剤としてポリグリセリンのジグリシジルエ
ーテルの６０％水溶液をＥｌｌ ０〜２０ｅＱ／１０６
付与した。In addition, a 60% aqueous solution of diglycidyl ether of polyglycerin is added as a treatment agent containing an epoxy compound to the loosened yarn immediately after being drawn out from the relaxation roller between the relaxation roller and the winding device. /106
Granted.
１ワられたポリエステル繊維の特性は表１および表２に
示すとおりであった。The properties of the polyester fibers subjected to 1-waking were as shown in Tables 1 and 2.
（以下余白）
表１および表２に示すとおり、本発明の方法によると特
に製糸中の糸切れが少なく安定してゴム補強用繊維を製
造することができ、得られたゴム補強用Ｉ！雛の経時糸
質変化が少なく、ゴムとの接着性も良好である。特に従
来の方法である比較例１および比較例２の場合、延伸ロ
ーラの表面汚れによって単糸切れが牛じ糸切れのＫ（囚
となり品質が安定しない。(The following is a blank space) As shown in Tables 1 and 2, according to the method of the present invention, it is possible to stably produce rubber reinforcing fibers with less thread breakage during spinning, and the resulting rubber reinforcing I! There is little change in the texture of the chicks over time, and the adhesion to rubber is also good. In particular, in the case of Comparative Example 1 and Comparative Example 2, which are conventional methods, single yarn breakage is caused by cow thread breakage due to dirt on the surface of the drawing roller, resulting in unstable quality.
したがって、比較例１および比較例２に限って１【０口
製糸するごとにローラ洗浄を行なったにもかかわらず糸
切れが多く発生した。他の実施例１乃至実施例１１にお
いては紡糸油剤によるローラの表面汚れ除去のため４
ｔｏｎ製糸することにＯ−ラの表面汚れを洗浄するとい
うように洗浄インターバルを４倍としても糸切れは極め
て少数であり製糸性が良好であった。Therefore, only in Comparative Example 1 and Comparative Example 2, many thread breakages occurred even though the roller was cleaned every time 1 thread was spun. In other Examples 1 to 11, 4
Even if the washing interval was four times that of washing the surface dirt of the O-ra after ton of thread spinning, there were very few thread breakages and the thread spinning performance was good.
［発明の効果］
本発明のゴム補強用ポリエステルｔＪＡＨの製造方法に
よると、エポキシ化合物を含む処理剤を弛緩ローラから
導出された糸条に付与することによって、延伸ローラの
汚れを減少し、製糸中の糸切れ数を減少することができ
る。 また、得られたゴム補強用ポリエステルｍ維は経
時糸質変化を生じなく、ゴムとの接着力も良好であるな
どの効果を有する。[Effects of the Invention] According to the method for producing polyester tJAH for rubber reinforcement of the present invention, by applying a treatment agent containing an epoxy compound to the yarn drawn out from the relaxation roller, staining of the drawing roller is reduced, and staining of the drawing roller is reduced. The number of thread breaks can be reduced. In addition, the obtained polyester m-fiber for rubber reinforcement has effects such as no change in fiber quality over time and good adhesion to rubber.
さらに、延伸ローラの汚れが減少したことによって、延
伸ローラの洗浄インターバルを延長することができ、洗
浄時に要する製糸の中断時間および洗浄作業を減少し、
生産性および作業上の工場にも効果を右する。Furthermore, due to the reduced contamination of the drawing rollers, the cleaning interval for the drawing rollers can be extended, reducing the interruption time of yarn spinning and the cleaning work required during cleaning.
It also has an effect on productivity and factory work.
図面は本発明のゴム補強用ポリエステル繊維のＩｌｌｌ
ｌ法に係る延伸巻取装釘の部分概略図である。The drawings show illustrations of the rubber-reinforcing polyester fibers of the present invention.
FIG. 1 is a partial schematic diagram of a stretch rewinding nail according to the I method.
Claims (2)
、溶融紡糸されたポリエステル繊維を延伸ローラ群を用
いて延伸し、引続き弛緩ローラを用いて弛緩熱処理した
後巻取装置を用いて巻取るに際し、前記弛緩ローラを離
脱した直後のポリエステル繊維にエポキシ化合物を含む
処理剤を付与することを特徴とする徴とするゴム補強用
ポリエステル繊維の製造方法。(1) In the method for producing polyester fibers for rubber reinforcement, melt-spun polyester fibers are stretched using a group of stretching rollers, followed by relaxation heat treatment using relaxation rollers, and then wound up using a winding device. 1. A method for producing polyester fibers for rubber reinforcement, which comprises applying a treatment agent containing an epoxy compound to polyester fibers immediately after leaving a relaxing roller.
群の最終の延伸ローラおよび弛緩ローラの温度を１５０
〜２３５℃の範囲となるように制御することを特徴とす
るゴム補強用ポリエステル繊維の製造方法。(2) In claim (1), the temperature of the final stretching roller and relaxation roller of the stretching roller group is set to 150.
A method for producing polyester fibers for rubber reinforcement, characterized in that the temperature is controlled to be in the range of -235°C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30263688A JPH02154067A (en) | 1988-11-30 | 1988-11-30 | Production of polyester yarn for reinforcing rubber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30263688A JPH02154067A (en) | 1988-11-30 | 1988-11-30 | Production of polyester yarn for reinforcing rubber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02154067A true JPH02154067A (en) | 1990-06-13 |
Family
ID=17911371
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP30263688A Pending JPH02154067A (en) | 1988-11-30 | 1988-11-30 | Production of polyester yarn for reinforcing rubber |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02154067A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR19980053184A (en) * | 1996-12-26 | 1998-09-25 | 구광시 | Manufacturing method of polyester fiber for rubber reinforcement |
| KR100415183B1 (en) * | 2001-12-28 | 2004-01-16 | 주식회사 효성 | A process for producing polyester fibers useful for reinforcing rubbers or polyvinyl chloride |
| WO2008056645A1 (en) * | 2006-11-07 | 2008-05-15 | Teijin Fibers Limited | Polyester multifilament for resin reinforcement and process for producing the same |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS514322A (en) * | 1974-07-02 | 1976-01-14 | Teijin Ltd | Horiesuterusenino seizoho |
| JPS57101074A (en) * | 1980-12-09 | 1982-06-23 | Allied Chem | Oil composition for polyester fiber |
| JPS5846178A (en) * | 1981-09-11 | 1983-03-17 | 帝人株式会社 | Production of polyester fiber for reinforcing rubber structure |
-
1988
- 1988-11-30 JP JP30263688A patent/JPH02154067A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS514322A (en) * | 1974-07-02 | 1976-01-14 | Teijin Ltd | Horiesuterusenino seizoho |
| JPS57101074A (en) * | 1980-12-09 | 1982-06-23 | Allied Chem | Oil composition for polyester fiber |
| JPS5846178A (en) * | 1981-09-11 | 1983-03-17 | 帝人株式会社 | Production of polyester fiber for reinforcing rubber structure |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR19980053184A (en) * | 1996-12-26 | 1998-09-25 | 구광시 | Manufacturing method of polyester fiber for rubber reinforcement |
| KR100415183B1 (en) * | 2001-12-28 | 2004-01-16 | 주식회사 효성 | A process for producing polyester fibers useful for reinforcing rubbers or polyvinyl chloride |
| WO2008056645A1 (en) * | 2006-11-07 | 2008-05-15 | Teijin Fibers Limited | Polyester multifilament for resin reinforcement and process for producing the same |
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