RU2004109136A - Способ и катализатор высокоактивной изомеризации - Google Patents
Способ и катализатор высокоактивной изомеризации Download PDFInfo
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- RU2004109136A RU2004109136A RU2004109136/04A RU2004109136A RU2004109136A RU 2004109136 A RU2004109136 A RU 2004109136A RU 2004109136/04 A RU2004109136/04 A RU 2004109136/04A RU 2004109136 A RU2004109136 A RU 2004109136A RU 2004109136 A RU2004109136 A RU 2004109136A
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- Prior art keywords
- component
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- group
- mixtures
- thulium
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- 239000003054 catalyst Substances 0.000 title claims 16
- 238000000034 method Methods 0.000 title claims 7
- 238000006317 isomerization reaction Methods 0.000 title claims 5
- 239000000203 mixture Substances 0.000 claims 9
- 229910052765 Lutetium Inorganic materials 0.000 claims 5
- 229910052775 Thulium Inorganic materials 0.000 claims 5
- 229910052769 Ytterbium Inorganic materials 0.000 claims 5
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 claims 5
- 229910052751 metal Inorganic materials 0.000 claims 5
- 239000002184 metal Substances 0.000 claims 5
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims 5
- 229910052691 Erbium Inorganic materials 0.000 claims 4
- 229910052689 Holmium Inorganic materials 0.000 claims 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 4
- 229910052771 Terbium Inorganic materials 0.000 claims 4
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims 4
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 claims 4
- 230000000737 periodic effect Effects 0.000 claims 4
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims 4
- 229910052727 yttrium Inorganic materials 0.000 claims 4
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 3
- -1 platinum group metals Chemical class 0.000 claims 3
- 239000000047 product Substances 0.000 claims 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- 229930195733 hydrocarbon Natural products 0.000 claims 2
- 150000002430 hydrocarbons Chemical class 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 2
- 229910052747 lanthanoid Inorganic materials 0.000 claims 2
- 150000002602 lanthanoids Chemical class 0.000 claims 2
- 239000012188 paraffin wax Substances 0.000 claims 2
- 239000011973 solid acid Substances 0.000 claims 2
- 101100208976 Schistosoma mansoni UPPA gene Proteins 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- 239000011230 binding agent Substances 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 239000012084 conversion product Substances 0.000 claims 1
- 239000012530 fluid Substances 0.000 claims 1
- 150000004679 hydroxides Chemical class 0.000 claims 1
- 229910052809 inorganic oxide Inorganic materials 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 230000008929 regeneration Effects 0.000 claims 1
- 238000011069 regeneration method Methods 0.000 claims 1
- 229910052702 rhenium Inorganic materials 0.000 claims 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 230000001180 sulfating effect Effects 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/053—Sulfates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/894—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Claims (13)
1. Катализатор, содержащий носитель, включающий нанесенный на него сульфатированный оксид или гидроксид по меньшей мере одного элемента IVB группы (IUPAC 4) периодической таблицы; первый компонент, выбранный из группы, состоящей из лютеция, иттербия, тулия, эрбия, гольмия, тербия, их смесей и иттрия, и второй компонент, содержащий по меньшей мере один металл группы платины.
2. Катализатор по п.1, в котором, первый компонент составляет 0,01-10 мас.% от количества катализатора, а второй компонент составляет 0,01-2 мас.% от количества катализатора в расчете на его элементный состав.
3. Катализатор по п.1, в котором элемент IVB группы (IUPAC 4) представляет собой цирконий.
4. Катализатор по п.1, 2 или 3, отличающийся тем, что он содержит 0,5-5% масс серы в расчете на элементный состав.
5. Катализатор по п.1, 2 или 3, в котором первый компонент представляет собой иттрий или один лантанидный элемент, выбранный из группы, состоящей из лютеция, иттербия, тулия, эрбия, гольмия, и тербия, а второй компонент представляет собой один металл, выбранный из металлов группы платины.
6. Катализатор по п.1, 2 или 3 дополнительно включающий третий компонент, выбранный из группы, состоящей из железа, кобальта, никеля, рения и их смесей.
7. Катализатор по пункту 6, в котором третий компонент представляет собой железо в количестве 0,1-5 мас.%, а второй компонент представляет собой платину.
8. Катализатор по п.2 или 3, в котором лантанидный компонент представляет собой иттербий, лютеций, тулий и их смеси.
9. Способ получения катализатора, предназначенного для конверсии углеводородов, содержащего сульфатированный носитель, включающий по меньшей мере одно вещество, выбранное из оксидов и гидроксидов элементов IVB группы (IUPAC 4) периодической таблицы, первый компонент, выбранный из группы, состоящей из лютеция, иттербия, тулия, эрбия, гольмия, тербия, их смесей и иттрия, и второй компонент, выбранный из металлов группы платины и их смесей, причем такой способ заключается в сульфатировании оксида или гидроксида по меньшей мере одного элемента IVB группы (IUPAC 4) периодической таблицы с образованием сульфатированного носителя; нанесении на сульфатированный носитель первого компонента; и последующего нанесения второго компонента с образованием указанного катализатора.
10. Способ конверсии углеводородов путем контактирования сырья с твердым кислотным катализатором, включающим носитель, содержащий сульфатированный оксид или гидроксид по меньшей мере одного элемента IVB группы (IUPAC 4) периодической таблицы, первый компонент, выбранный из группы, состоящей из лютеция, иттербия, тулия, эрбия, гольмия, тербия, их смесей и иттрия, и второй компонент, выбранный из металлов группы платины и их смесей, с образованием продуктов конверсии.
11. Способ по п.10, в котором парафиновое сырье подвергают изомеризации с целью получения продукта с повышенным содержанием изопарафинов, в результате контакта парафинового сырья с твердым кислотным катализатором в зоне изомеризации, в которой поддерживаются изомеризационные условия, включающие температуру в интервале 40-250°С, давление в интервале от 100 кПа до 10 МПа и среднечасовую скорость подачи жидкости 0,2-25 ч-1, с последующей регенерацией продукта обогащенного изопарафинами.
12. Способ по п.10 или 11, в котором катализатор изомеризации дополнительно включает тугоплавкий неорганический оксидный связующий компонент.
13. Способ по п.12, в котором дополнительно используют по меньшей мере часть обогащенного изопарафинами продукта для смешивания с бензином.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/942,237 | 2001-08-29 | ||
| US09/942,237 US6706659B2 (en) | 2001-08-29 | 2001-08-29 | High-activity isomerization catalyst and process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2004109136A true RU2004109136A (ru) | 2005-10-10 |
| RU2294797C2 RU2294797C2 (ru) | 2007-03-10 |
Family
ID=25477776
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2004109136/04A RU2294797C2 (ru) | 2001-08-29 | 2002-08-28 | Катализатор для конверсии углеводородов и способ получения катализатора, способ конверсии углеводородов |
Country Status (15)
| Country | Link |
|---|---|
| US (4) | US6706659B2 (ru) |
| EP (1) | EP1425095B1 (ru) |
| JP (1) | JP4217617B2 (ru) |
| KR (1) | KR100786600B1 (ru) |
| CN (1) | CN1254308C (ru) |
| AT (1) | ATE311249T1 (ru) |
| AU (1) | AU2002326792B2 (ru) |
| BR (1) | BR0212264B1 (ru) |
| CA (1) | CA2458885C (ru) |
| DE (1) | DE60207738T2 (ru) |
| ES (1) | ES2254718T3 (ru) |
| HU (1) | HU226762B1 (ru) |
| MX (1) | MXPA04001915A (ru) |
| RU (1) | RU2294797C2 (ru) |
| WO (1) | WO2003020420A1 (ru) |
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- 2001-08-29 US US09/942,237 patent/US6706659B2/en not_active Expired - Lifetime
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- 2002-08-28 JP JP2003524722A patent/JP4217617B2/ja not_active Expired - Lifetime
- 2002-08-28 KR KR1020047002893A patent/KR100786600B1/ko active IP Right Grant
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- 2002-08-28 AT AT02761534T patent/ATE311249T1/de active
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| US6881873B2 (en) | 2005-04-19 |
| JP2005501697A (ja) | 2005-01-20 |
| WO2003020420A1 (en) | 2003-03-13 |
| US6927188B2 (en) | 2005-08-09 |
| BR0212264A (pt) | 2004-10-19 |
| CN1555291A (zh) | 2004-12-15 |
| KR20040029074A (ko) | 2004-04-03 |
| US20050161368A1 (en) | 2005-07-28 |
| CN1254308C (zh) | 2006-05-03 |
| CA2458885A1 (en) | 2003-03-13 |
| US20040259726A1 (en) | 2004-12-23 |
| HUP0401513A3 (en) | 2008-05-28 |
| KR100786600B1 (ko) | 2007-12-21 |
| EP1425095A1 (en) | 2004-06-09 |
| US7326819B2 (en) | 2008-02-05 |
| ATE311249T1 (de) | 2005-12-15 |
| HUP0401513A2 (hu) | 2004-10-28 |
| MXPA04001915A (es) | 2004-06-15 |
| US6706659B2 (en) | 2004-03-16 |
| BR0212264B1 (pt) | 2013-02-19 |
| DE60207738T2 (de) | 2006-08-10 |
| CA2458885C (en) | 2007-12-04 |
| DE60207738D1 (de) | 2006-01-05 |
| US20030050523A1 (en) | 2003-03-13 |
| ES2254718T3 (es) | 2006-06-16 |
| RU2294797C2 (ru) | 2007-03-10 |
| HU226762B1 (en) | 2009-09-28 |
| US20040077915A1 (en) | 2004-04-22 |
| EP1425095B1 (en) | 2005-11-30 |
| AU2002326792B2 (en) | 2007-06-07 |
| JP4217617B2 (ja) | 2009-02-04 |
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