TWI790912B - Optoelectronic device - Google Patents

Optoelectronic device Download PDF

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TWI790912B
TWI790912B TW111104461A TW111104461A TWI790912B TW I790912 B TWI790912 B TW I790912B TW 111104461 A TW111104461 A TW 111104461A TW 111104461 A TW111104461 A TW 111104461A TW I790912 B TWI790912 B TW I790912B
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electrode
semiconductor layer
boundaries
layer
electrical type
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TW111104461A
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TW202224215A (en
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陳昭興
王佳琨
廖健智
曾咨耀
柯淙凱
沈建賦
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晶元光電股份有限公司
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Abstract

An optoelectronic device including a epitaxial stack including a first semiconductor layer, an active layer formed on the first semiconductor layer, and a second semiconductor layer formed on the active layer, wherein the first semiconductor layer includes multiple first boundaries and a peripheral exposing region adjacent to the multiple first boundaries and not covered by the active layer and the second semiconductor layer; a second electrode formed on the second semiconductor layer and including multiple second boundaries; an insulating layer covering the second semiconductor layer and the second electrode and including multiple first openings, wherein a portion of the multiple first openings is on a portion of the peripheral exposing region, and the portion of the peripheral exposing region is adjacent to one of the multiple first boundaries; a third electrode formed on the insulating layer and including multiple edges; and a fourth electrode formed on the insulating layer and electrically connected to the second semiconductor layer, wherein the one of the multiple first boundaries is adjacent to one of the multiple second boundaries, one of the multiple edges is adjacent to the one of the multiple first boundaries and away from the fourth electrode, the one of the multiple edges includes one or multiple first concaves on the second electrode and inside the one of the multiple second boundaries, and the one of the multiple edges includes one or multiple first protrusions protruded from the one or multiple first concaves and beyond the one of the multiple second boundaries to electrically connected to the first semiconductor layer through the portion of the multiple first openings.

Description

光電元件 Photoelectric components

本發明係關於一種光電元件,尤其是關於一種光電元件之電極設計。 The invention relates to a photoelectric element, in particular to an electrode design of a photoelectric element.

發光二極體(light-emitting diode,LED)的發光原理是利用電子在n型半導體與p型半導體間移動的能量差,以光的形式將能量釋放,這樣的發光原理係有別於白熾燈發熱的發光原理,因此發光二極體被稱為冷光源。此外,發光二極體具有高耐久性、壽命長、輕巧、耗電量低等優點,因此現今的照明市場對於發光二極體寄予厚望,將其視為新一代的照明工具,已逐漸取代傳統光源,並且應用於各種領域,如交通號誌、背光模組、路燈照明、醫療設備等。 The light-emitting diode (light-emitting diode, LED) uses the energy difference between n-type semiconductors and p-type semiconductors to release energy in the form of light. This light-emitting principle is different from incandescent lamps. The principle of heating light, so light-emitting diodes are called cold light sources. In addition, light-emitting diodes have the advantages of high durability, long life, light weight, and low power consumption. Therefore, today's lighting market has high expectations for light-emitting diodes, which are regarded as a new generation of lighting tools, which have gradually replaced traditional lighting. Light source, and used in various fields, such as traffic signs, backlight modules, street lighting, medical equipment, etc.

第1圖係習知之發光元件結構示意圖,如第1圖所示,習知之發光元件100,包含有一透明基板10、一位於透明基板10上之半導體疊層12,以及至少一電極14位於上述半導體疊層12上,其中上述之半導體疊層12由上而下至少包含一第一導電型半導體層120、一活性層122,以及一第二導電型半導體層124。 Figure 1 is a schematic structural view of a known light-emitting element. As shown in Figure 1, a known light-emitting element 100 includes a transparent substrate 10, a semiconductor stack 12 on the transparent substrate 10, and at least one electrode 14 located on the above-mentioned semiconductor. On the laminated layer 12 , the semiconductor laminated layer 12 includes at least a first conductive type semiconductor layer 120 , an active layer 122 , and a second conductive type semiconductor layer 124 from top to bottom.

此外,上述之發光元件100更可以進一步地與其他元件組合連接以形成一發光裝置(light-emitting apparatus)。第2圖為習知之發光裝置結構示意圖,如第2圖所示,一發光裝置200包含一具有至少一電路202之次載體 (sub-mount)20;至少一焊料(solder)22位於上述次載體20上,藉由此焊料22將上述發光元件100黏結固定於次載體20上並使發光元件100之基板10與次載體20上之電路202形成電連接;以及,一電性連接結構24,以電性連接發光元件100之電極14與次載體20上之電路202;其中,上述之次載體20可以是導線架(lead frame)或大尺寸鑲嵌基底(mounting substrate),以方便發光裝置200之電路規劃並提高其散熱效果。 In addition, the above-mentioned light-emitting device 100 can be further combined and connected with other devices to form a light-emitting apparatus. FIG. 2 is a schematic structural diagram of a conventional light-emitting device. As shown in FIG. 2, a light-emitting device 200 includes a sub-carrier with at least one circuit 202 (sub-mount) 20; at least one solder (solder) 22 is located on the above-mentioned sub-carrier 20, through this solder 22, the above-mentioned light-emitting element 100 is bonded and fixed on the sub-carrier 20 and the substrate 10 of the light-emitting element 100 and the sub-carrier 20 The circuit 202 on it forms an electrical connection; and an electrical connection structure 24 is used to electrically connect the electrode 14 of the light-emitting element 100 and the circuit 202 on the sub-carrier 20; wherein, the above-mentioned sub-carrier 20 can be a lead frame (lead frame ) or a large-size mounting substrate to facilitate the circuit planning of the light emitting device 200 and improve its heat dissipation effect.

一種光電元件,包含:一磊晶疊層,包含一第一半導體層,一活性層形成於第一半導體層上,以及一第二半導體層形成於活性層上,其中第一半導體層包含複數個第一邊界及一周圍裸露區域鄰近複數個第一邊界且不被活性層及第二半導體層覆蓋;一第二電極形成於第二半導體層上且包含複數個第二邊界;一絕緣層覆蓋第二半導體層及第二電極,且包含複數個第一開口,其中複數個第一開口之一部分位於周圍裸露區域之一部分上,周圍裸露區域之部分鄰近複數個第一邊界之一;一第三電極形成於絕緣層上且包含複數個邊緣;以及一第四電極形成於絕緣層上電性連接第二半導體層,其中複數個第一邊界之一鄰近複數個第二邊界之一,複數個邊緣之一鄰近複數個第一邊界之一且遠離第四電極,複數個邊緣之一包含一或多個第一凹部位於第二電極上且位於複數個第二邊界之一內,複數邊緣之一包含一或多個第一凸部凸出於一或多個第一凹部且超出複數個第二邊界之一以經由複數個第一開口之一部分電性連接第一半導體層。 A photoelectric element, comprising: an epitaxial stack comprising a first semiconductor layer, an active layer formed on the first semiconductor layer, and a second semiconductor layer formed on the active layer, wherein the first semiconductor layer comprises a plurality of The first boundary and a surrounding exposed area are adjacent to a plurality of first boundaries and are not covered by the active layer and the second semiconductor layer; a second electrode is formed on the second semiconductor layer and includes a plurality of second boundaries; an insulating layer covers the first boundary. Two semiconductor layers and a second electrode, including a plurality of first openings, wherein a part of the plurality of first openings is located on a part of the surrounding exposed area, and a part of the surrounding exposed area is adjacent to one of the plurality of first boundaries; a third electrode It is formed on the insulating layer and includes a plurality of edges; and a fourth electrode is formed on the insulating layer and electrically connected to the second semiconductor layer, wherein one of the plurality of first boundaries is adjacent to one of the plurality of second boundaries, and one of the plurality of edges One adjacent to one of the plurality of first boundaries and away from the fourth electrode, one of the plurality of edges includes one or more first recesses located on the second electrode and within one of the plurality of second boundaries, one of the plurality of edges includes a The one or more first protrusions protrude from the one or more first recesses and exceed one of the plurality of second boundaries to electrically connect the first semiconductor layer through a part of the plurality of first openings.

100、200、300、400、500、600、700、700’:發光元件 100, 200, 300, 400, 500, 600, 700, 700': light emitting element

10:透明基板 10: Transparent substrate

12:半導體疊層 12: Semiconductor stack

14、E1、E2:電極 14. E1, E2: electrodes

30:基板 30: Substrate

31:磊晶疊層 31: Epitaxy stack

311:第一半導體層 311: the first semiconductor layer

312:活性層 312: active layer

313:第二半導體層 313: the second semiconductor layer

S:溝渠 S: ditch

341:第一絕緣層 341: first insulating layer

342:第二絕緣層 342: second insulating layer

3421:第一開口 3421: first opening

3422:第二開口 3422: second opening

3423:第三開口 3423: the third opening

3424:第四開口 3424: The fourth opening

3425:第五開口 3425: fifth opening

321:第一第一電性電極 321: the first first electrical electrode

322:第二第一電性電極 322: the second first electrical electrode

323:第三第一電性電極 323: the third first electrical electrode

324:第四第一電性電極 324: the fourth first electrical electrode

33:第二電性電極 33: Second electrical electrode

35:第三電極 35: The third electrode

B1:第一長邊 B1: the first long side

B3:第二長邊 B3: second long side

B2:第一短邊 B2: First short side

B4:第二短邊 B4: second short side

351:長形延伸部 351: Long extension

R:凹口 R: notch

36:第四電極 36: The fourth electrode

800:發光模組 800: Lighting module

501:下載體 501: download body

502:載體 502: carrier

503:上載體 503: upload carrier

504、506、508、510:透鏡 504, 506, 508, 510: lens

512、514:電源供應終端 512, 514: power supply terminals

515:通孔 515: through hole

519:反射層 519: reflective layer

521:膠材 521: Glue

540:外殼 540: shell

900:光源產生裝置 900: light source generating device

1000:燈泡 1000: bulb

721:外殼 721: shell

722:透鏡 722: lens

724:照明模組 724:Lighting module

725:支架 725: Bracket

726:散熱器 726: Radiator

727:串接部 727: Serial connection

728:電串接器 728: Electric serial connector

ABC:方向 ABC: Direction

D1:距離 D1: distance

H1、H2:高度 H1, H2: Height

第1圖為一結構圖,顯示一習知陣列光電元件側視結構圖;第2圖為一示意圖,顯示一習知發光裝置結構示意圖;第3A圖為一結構圖,顯示依據本發明一實施例的光電元件單元上視結構圖;第3B圖為一結構圖,顯示依據本發明一實施例的光電元件單元側視結構圖;第3C圖為一結構圖,顯示依據本發明另一實施例的光電元件單元上視結構圖;第4A-4D圖為一結構圖,顯示依據本發明另一實施例的光電元件單元上視結構圖;第5A-5C圖係繪示出一發光模組示意圖;第6A-6B圖係繪示出一光源產生裝置示意圖;及第7圖係繪示一燈泡示意圖。 Fig. 1 is a structural diagram showing a side-view structural diagram of a conventional array photoelectric element; Fig. 2 is a schematic diagram showing a schematic structural diagram of a conventional light-emitting device; Fig. 3A is a structural diagram showing an implementation according to the present invention Figure 3B is a structural diagram showing a side view structural diagram of a photoelectric element unit according to an embodiment of the present invention; Figure 3C is a structural diagram showing another embodiment of the present invention Figure 4A-4D is a structural diagram showing a top structural view of a photoelectric element unit according to another embodiment of the present invention; Figure 5A-5C is a schematic diagram of a light-emitting module ; Figures 6A-6B show a schematic diagram of a light source generating device; and Figure 7 shows a schematic diagram of a light bulb.

本發明揭示一種發光元件及其製造方法,為了使本發明之敘述更加詳盡與完備,請參照下列描述並配合第3A圖至第7圖之圖示。 The present invention discloses a light-emitting element and a manufacturing method thereof. In order to make the description of the present invention more detailed and complete, please refer to the following description and cooperate with the illustrations in FIG. 3A to FIG. 7 .

第3A圖與第3B圖所示為本發明第一實施例之光電元件300的上視圖與側視圖。第3B圖係顯示第3A圖中A-B-C方向之側視結構圖。光電元件300具有一個基板30。基板30並不限定為單一材料,亦可以是由複數不同材料組合 而成的複合式基板。例如:基板30可以包含兩個相互接合的第一基板(圖未示)與第二基板(圖未示)。 FIG. 3A and FIG. 3B show a top view and a side view of a photoelectric device 300 according to a first embodiment of the present invention. Fig. 3B is a side view structure diagram showing the direction A-B-C in Fig. 3A. The photovoltaic element 300 has a substrate 30 . The substrate 30 is not limited to a single material, and can also be composed of a plurality of different materials composite substrate. For example, the substrate 30 may include two first substrates (not shown) and second substrates (not shown) bonded to each other.

在基板30上以傳統的磊晶成長製程,形成一磊晶疊層31,包含第一半導體層311具有一第一表面3111及一與第一表面相對之第二表面3112,一活性層312形成於第一半導體層311之第一表面3111之上,以及一第二半導體層313形成於活性層312之上。接著,藉由黃光微影製程技術選擇性移除部分磊晶疊層以在光電元件300之邊界裸露出部分第一半導體層311,並形成一溝渠S於光電元件300之中。在一實施例中,此溝渠S裸露出部分第一半導體層311且被第二半導體層313所圍繞。在一實施例中,溝渠S於上視圖中為一長條形。 On the substrate 30, a conventional epitaxial growth process is used to form an epitaxial stack 31, including a first semiconductor layer 311 having a first surface 3111 and a second surface 3112 opposite to the first surface, and an active layer 312 is formed. On the first surface 3111 of the first semiconductor layer 311 , and a second semiconductor layer 313 are formed on the active layer 312 . Then, a part of the epitaxial stack is selectively removed by yellow light lithography process technology to expose part of the first semiconductor layer 311 at the boundary of the photoelectric device 300 , and a trench S is formed in the photoelectric device 300 . In one embodiment, the trench S exposes part of the first semiconductor layer 311 and is surrounded by the second semiconductor layer 313 . In one embodiment, the ditch S is a long strip in a top view.

接著,在光電元件300磊晶疊層31的表面及上述溝渠S側壁上以化學氣相沉積方式(CVD)或物理氣相沉積方式(PVD)等技術沉積形成第一絕緣層341。 Next, the first insulating layer 341 is deposited and formed on the surface of the epitaxial stack 31 of the photoelectric element 300 and the sidewalls of the trench S by chemical vapor deposition (CVD) or physical vapor deposition (PVD).

接著,形成至少一第一第一電性電極321於上述光電元件300之邊界旁所裸露出之第一半導體層311之上。在一實施例中,第一第一電性電極321未被第二半導體層313圍繞,以及一第二第一電性電極322形成於上述溝渠S之中。在此實施例中,分離的第一第一電性電極321及第二第一電性電極322形成一種第一電性電極的電極設計型態。 Next, at least one first first electrical type electrode 321 is formed on the exposed first semiconductor layer 311 beside the boundary of the optoelectronic element 300 . In one embodiment, the first first electrical type electrode 321 is not surrounded by the second semiconductor layer 313 , and a second first electrical type electrode 322 is formed in the trench S above. In this embodiment, the separated first first electrical type electrode 321 and second first electrical type electrode 322 form an electrode design type of a first electrical type electrode.

在本發明之實施例中,電極設計型態可包括電極數量、電極形狀及電極位置的選擇,以增進光電元件靠近邊界區域之電流散佈。例如,第一電性電極之電極設計型態可以包含一或多個第一第一電性電極321以及一或多個第二第一電性電極322,且第二第一電性電極322自上視觀之係被第二半導體層313圍繞,且係為一延伸狀。 In an embodiment of the present invention, the design of the electrodes may include the selection of the number of electrodes, the shape of the electrodes, and the location of the electrodes, so as to enhance the current spreading of the photoelectric element near the boundary area. For example, the electrode design pattern of the first electrical type electrode may include one or more first first electrical type electrodes 321 and one or more second first electrical type electrodes 322, and the second first electrical type electrodes 322 are Viewed from above, it is surrounded by the second semiconductor layer 313 and is in an extended shape.

在一實施例中,光電元件300之第一半導體層311具有至少四個邊界,相鄰兩邊界可構成一角落,且無跨越邊界之導電結構。在本實施例中,第一第一電性電極321形成於光電元件300之同一邊界上的兩個角落,彼此分離且未跨越光電元件300之邊界。 In one embodiment, the first semiconductor layer 311 of the photoelectric element 300 has at least four boundaries, two adjacent boundaries can form a corner, and there is no conductive structure crossing the boundaries. In this embodiment, the first first electrical type electrodes 321 are formed at two corners on the same boundary of the photoelectric element 300 , are separated from each other and do not cross the boundary of the photoelectric element 300 .

在一實施例中,第一第一電性電極321於第一半導體層上311之投影可具有一圖形,此圖形可為一多邊形、一圓形、一橢圓形、一半圓形或具有一圓弧面。第二第一電性電極322可為線形、弧形、線形與弧形混合形、或可具有至少一分支。在一實施例中,第二第一電性電極322可具有一頭端與尾端,且上述頭端具有一寬度大於尾端之一寬度。 In one embodiment, the projection of the first first electrical type electrode 321 on the first semiconductor layer 311 may have a pattern, which may be a polygon, a circle, an ellipse, a semicircle or a circle. curved surface. The second first electrical type electrode 322 can be linear, curved, a mixture of linear and curved, or have at least one branch. In one embodiment, the second first electrical type electrode 322 may have a head end and a tail end, and the head end has a width greater than that of the tail end.

接著,形成一第二電性電極33於第二半導體層313之上。在一實施例中,第二電性電極33於第一半導體層311之投影面積與第二半導體層313之上表面積的比值係介於90~100%。 Next, a second electrical type electrode 33 is formed on the second semiconductor layer 313 . In one embodiment, the ratio of the projected area of the second electrical type electrode 33 on the first semiconductor layer 311 to the upper surface area of the second semiconductor layer 313 is between 90% and 100%.

之後,可形成一第二絕緣層342於上述第一第一電性電極321、第二第一電性電極322、第二電性電極33及部分第一絕緣層341之上。其中第二絕緣層342可具有第一開口3421以作為第二電性電極33與後續形成之第四電極36電性連接之用,第二絕緣層342也可具有一第二開口3422以作為第一第一電性電極321與後續形成之第三電極35電性連接之用。在一實施例中,第一絕緣層341或第二絕緣層342可完全覆蓋上述裸露出之第一半導體層311。 After that, a second insulating layer 342 can be formed on the first first electrical type electrode 321 , the second first electrical type electrode 322 , the second electrical type electrode 33 and part of the first insulating layer 341 . Wherein the second insulating layer 342 may have a first opening 3421 for electrically connecting the second electrical electrode 33 with the subsequently formed fourth electrode 36, and the second insulating layer 342 may also have a second opening 3422 as a first A first electrical electrode 321 is used for electrical connection with the subsequently formed third electrode 35 . In one embodiment, the first insulating layer 341 or the second insulating layer 342 can completely cover the exposed first semiconductor layer 311 .

在一實施例中,上述第一絕緣層341或第二絕緣層342可為一透明絕緣層。上述第一絕緣層341或第二絕緣層342的材質可以是氧化物、氮化物、或聚合物(polymer),氧化物可包含氧化鋁(Al2O3)、氧化矽(SiO2)、二氧化鈦(TiO2)、五氧化二鉭(Tantalum Pentoxide,Ta2O5)或氧化鋁(AlOx);氮化物可包含 氮化鋁(AlN)、氮化矽(SiNx);聚合物可包含聚醯亞胺(polyimide)或苯并環丁烷(benzocyclobutane,BCB)等材料或為上述之複合組合。在一實施例中,第一絕緣層341或第二絕緣層342可為一布拉格反射鏡(Distributed Bragg Reflector)結構。 In one embodiment, the first insulating layer 341 or the second insulating layer 342 may be a transparent insulating layer. The material of the first insulating layer 341 or the second insulating layer 342 can be oxide, nitride, or polymer, and the oxide can include aluminum oxide (Al2O3), silicon oxide (SiO2), titanium dioxide (TiO2), Tantalum Pentoxide (Ta2O5) or Aluminum Oxide (AlOx); nitrides may contain Aluminum nitride (AlN), silicon nitride (SiNx); polymers may include polyimide (polyimide) or benzocyclobutane (benzocyclobutane, BCB) and other materials or a composite combination of the above. In one embodiment, the first insulating layer 341 or the second insulating layer 342 may be a Distributed Bragg Reflector structure.

最後,形成一第三電極35於上述第二絕緣層342、第一第一電性電極321、第二第一電性電極322之上並與第一第一電性電極321、第二第一電性電極322電性連接;及形成一第四電極36於上述第二絕緣層342、第二電性電極33之上並與第二電性電極33電性連接。在一實施例中,自上視觀之,第三電極35與第四電極36於第一半導體層311上之投影面積的比值介於80~100%。 Finally, a third electrode 35 is formed on the second insulating layer 342, the first first electrical type electrode 321, and the second first electrical type electrode 322 and is connected with the first first electrical type electrode 321, the second first electrical type electrode 322 The electrical electrode 322 is electrically connected; and a fourth electrode 36 is formed on the second insulating layer 342 and the second electrical electrode 33 and is electrically connected to the second electrical electrode 33 . In one embodiment, viewed from above, the ratio of the projected areas of the third electrode 35 and the fourth electrode 36 on the first semiconductor layer 311 is between 80% and 100%.

在一實施例中,第三電極35可以只覆蓋部分第一第一電性電極321;在另一實施例中,第三電極35可以完全不覆蓋第一第一電性電極321。 In one embodiment, the third electrode 35 may only cover part of the first first electrical type electrode 321 ; in another embodiment, the third electrode 35 may not cover the first first electrical type electrode 321 at all.

在一實施例中,第三電極35之上緣至基板30上緣有一高度H1,第四電極36之上緣至基板30上緣有一高度H2,且H1大致相等於H2。在一實施例中,H1與H2之差異小於5~10%。藉由調整H1與H2之差異,可減少光電元件300後續與載板或電路元件形成覆晶式結構之斷線機率,進而增加產品良率。在一實施例中,第三電極35之邊界與第四電極36之邊界具有一最小距離D1,且D1大於50μm,在一實施例中D1可為50-200μm、100-200μm。 In one embodiment, there is a height H1 from the upper edge of the third electrode 35 to the upper edge of the substrate 30 , and a height H2 from the upper edge of the fourth electrode 36 to the upper edge of the substrate 30 , and H1 is substantially equal to H2 . In one embodiment, the difference between H1 and H2 is less than 5-10%. By adjusting the difference between H1 and H2, the disconnection probability of the photoelectric element 300 and the carrier board or circuit element forming a flip-chip structure can be reduced, thereby increasing the product yield. In one embodiment, the boundary of the third electrode 35 and the boundary of the fourth electrode 36 have a minimum distance D1, and D1 is greater than 50 μm , in one embodiment D1 can be 50-200 μm , 100-200 μm m.

在一實施例中,第一第一電性電極321、第二第一電性電極322、第二電性電極33、第三電極35及第四電極36可為一多層結構,及/或包含一反射層(圖未示),且可對活性層312發出之光線具有80%以上之反射率。在一實施例中,第一第一電性電極321、第二第一電性電極322及第三電極35也可於同一製程中形成。在一實施例中,光電元件300發出之光線可經第一第一電性電極321、 第二第一電性電極322、第二電性電極33、第三電極35或第四電極36反射而從基板30方向離開光電元件300。 In one embodiment, the first first electrical type electrode 321 , the second first electrical type electrode 322 , the second electrical type electrode 33 , the third electrode 35 and the fourth electrode 36 may be a multilayer structure, and/or It includes a reflective layer (not shown in the figure), and can have a reflectivity of more than 80% for the light emitted by the active layer 312 . In one embodiment, the first first electrical type electrode 321 , the second first electrical type electrode 322 and the third electrode 35 may also be formed in the same process. In one embodiment, the light emitted by the photoelectric element 300 can pass through the first first electrical type electrode 321, The second first electrical type electrode 322 , the second electrical type electrode 33 , the third electrode 35 or the fourth electrode 36 reflect and leave the photoelectric element 300 from the direction of the substrate 30 .

為了達到一定的導電度,第一第一電性電極321、第二第一電性電極322、第二電性電極33、第三電極35及第四電極36之材質較佳例如可以是金屬,例如金(Au)、銀(Ag)、銅(Cu)、鉻(Cr)、鋁(Al)、鉑(Pt)、鎳(Ni)、鈦(Ti)、錫(Sn)等,其合金或其疊層組合。 In order to achieve a certain degree of electrical conductivity, the material of the first first electrical type electrode 321, the second first electrical type electrode 322, the second electrical type electrode 33, the third electrode 35 and the fourth electrode 36 is preferably metal, for example, Such as gold (Au), silver (Ag), copper (Cu), chromium (Cr), aluminum (Al), platinum (Pt), nickel (Ni), titanium (Ti), tin (Sn), etc., their alloys or its layered combination.

在一實施例中,可提供一載板或一電路元件(圖未示),藉由打線或焊錫等方式於載板或電路元件上形成一第一載板電極(圖未示)、及一第二載板電極(圖未示)。此第一載板電極、及第二載板電極可與光電元件300之第三電極35、第四電極36形成一覆晶式結構。 In one embodiment, a carrier board or a circuit element (not shown) may be provided, and a first carrier electrode (not shown) and a The second carrier electrode (not shown). The first carrier electrode and the second carrier electrode can form a flip-chip structure with the third electrode 35 and the fourth electrode 36 of the photoelectric element 300 .

在一實施例中,可形成一第一調整層(圖未示)於第一第一電性電極321、及/或第二第一電性電極322與第三電極35之間,且電性連接於第一第一電性電極321、及/或第二第一電性電極322與第三電極35。在一實施例中,可形成一第二調整層(圖未示)於第二電性電極33與第四電極36之間,且電性連接於第二電性電極33與第四電極36。在本實施例中,第一調整層及第二調整層可分別具有一高度,且因為第一調整層及第二調整層之形成位置,使得第一調整層及第二調整層之高度會影響上述H1與H2之高度。因此藉由分別設計第一調整層及/或第二調整層之形成高度,可以減少上述H1與H2之高度差異,而可減少光電元件300後續與載板或電路元件形成覆晶式結構之斷線機率,進而增加產品良率。在一實施例中,第一調整層於第一半導體層311上之投影面積大於第三電極35於第一半導體層311上之投影面積,或第二調整層於第一半導體層311上之投影面積大於第四電極36於第一半導體層311上之投影面積。在一實施例中,第一調整 層或第二調整層之材質較佳例如可以是金屬,例如金(Au)、銀(Ag)、銅(Cu)、鉻(Cr)、鋁(Al)、鉑(Pt)、鎳(Ni)、鈦(Ti)、錫(Sn)等,其合金或其疊層組合。在一實施例中,第一調整層或第二調整層可為一多層結構,及/或包含一反射層(圖未示),且可對活性層312發出之光線具有80%以上之反射率。 In one embodiment, a first adjustment layer (not shown) can be formed between the first first electrical electrode 321 and/or between the second first electrical electrode 322 and the third electrode 35, and the electrical It is connected to the first first electrical type electrode 321 and/or the second first electrical type electrode 322 and the third electrode 35 . In one embodiment, a second adjustment layer (not shown) may be formed between the second electrical type electrode 33 and the fourth electrode 36 and electrically connected to the second electrical type electrode 33 and the fourth electrode 36 . In this embodiment, the first adjustment layer and the second adjustment layer can have a height respectively, and because of the formation positions of the first adjustment layer and the second adjustment layer, the height of the first adjustment layer and the second adjustment layer will affect The height of H1 and H2 mentioned above. Therefore, by designing the formation heights of the first adjustment layer and/or the second adjustment layer respectively, the above-mentioned height difference between H1 and H2 can be reduced, thereby reducing the subsequent disconnection between the photoelectric element 300 and the substrate or circuit element to form a flip-chip structure. Line probability, thereby increasing product yield. In one embodiment, the projected area of the first adjustment layer on the first semiconductor layer 311 is larger than the projected area of the third electrode 35 on the first semiconductor layer 311, or the projected area of the second adjustment layer on the first semiconductor layer 311 The area is larger than the projected area of the fourth electrode 36 on the first semiconductor layer 311 . In one embodiment, the first adjustment The material of the layer or the second adjustment layer is preferably metal, such as gold (Au), silver (Ag), copper (Cu), chromium (Cr), aluminum (Al), platinum (Pt), nickel (Ni) , titanium (Ti), tin (Sn), etc., their alloys or their laminated combinations. In one embodiment, the first adjustment layer or the second adjustment layer can be a multi-layer structure, and/or include a reflective layer (not shown), and can reflect more than 80% of the light emitted by the active layer 312 Rate.

第3C圖係顯示本發明第二實施例之光電元件400上視圖。本實施例其製作方法、使用材料及標號等與上述第一實施例相同,在此不再贅述。在本發明之實施例中,電極設計型態可包括電極數量、電極形狀及電極位置的選擇,以增進光電元件400靠近邊界區域之電流散佈。 FIG. 3C is a top view of the photoelectric element 400 according to the second embodiment of the present invention. The manufacturing method, materials and labels of this embodiment are the same as those of the first embodiment above, and will not be repeated here. In the embodiment of the present invention, the design of the electrodes may include the selection of the number of electrodes, the shape of the electrodes, and the positions of the electrodes, so as to improve the current spreading near the border region of the photovoltaic device 400 .

在一實施例中,光電元件400之第一半導體層311具有至少四個邊界,相鄰兩邊界可構成一角落,且無跨越邊界之導電結構。在本實施例中,第一第一電性電極321形成於第一半導體層311的任一角落之上,且第二絕緣層342可具有一第二開口3422以作為第一第一電性電極321與後續形成之第三電極35電性連接之用。第二第一電性電極322形成於第一半導體層311之上,且被第二半導體層313圍繞,且第二絕緣層342也可具有一第三開口3423以作為第二第一電性電極322與後續形成之第三電極35電性連接之用。 In one embodiment, the first semiconductor layer 311 of the photoelectric element 400 has at least four boundaries, two adjacent boundaries can form a corner, and there is no conductive structure crossing the boundaries. In this embodiment, the first first electrical type electrode 321 is formed on any corner of the first semiconductor layer 311, and the second insulating layer 342 may have a second opening 3422 as the first first electrical type electrode 321 is used for electrical connection with the third electrode 35 formed later. The second first electrical type electrode 322 is formed on the first semiconductor layer 311 and surrounded by the second semiconductor layer 313, and the second insulating layer 342 may also have a third opening 3423 as the second first electrical type electrode 322 is used for electrical connection with the third electrode 35 formed later.

在本實施例中,第一第一電性電極321於第一半導體層上311之投影可具有一圖形,其中此圖形可為一多邊形、一圓形、一橢圓形、一半圓形或具有一圓弧面。第二第一電性電極322係為延伸狀,且形狀可為線形、弧形、線形與弧形混合形、或可具有至少一分支。在一實施例中,第二第一電性電極322可具有一頭端及一尾端,且上述頭端可具有一寬度大於尾端之一寬度。 In this embodiment, the projection of the first first electrical type electrode 321 on the first semiconductor layer 311 can have a pattern, wherein the pattern can be a polygon, a circle, an ellipse, a semicircle or have a Arc surface. The second first electrical type electrode 322 is an extension shape, and the shape can be linear, arc, a mixture of linear and arc, or can have at least one branch. In one embodiment, the second first electrical type electrode 322 may have a head end and a tail end, and the head end may have a width greater than that of the tail end.

在本實施例中,第三第一電性電極323係形成於光電元件400之邊界旁所裸露出之第一半導體層311之上。在一實施例中,第三第一電性電極323 未被第二半導體層313圍繞,且第二絕緣層342具有一第四開口3424以作為第三第一電性電極323與後續形成之第三電極35電性連接之用。第四第一電性電極324係形成於光電元件400之邊界旁所裸露出之第一半導體層311之上。在一實施例中,第四第一電性電極324未被第二半導體層313圍繞,且第二絕緣層342具有一第五開口3425以作為第四第一電性電極324與後續形成之第三電極35電性連接之用。 In this embodiment, the third first electrical type electrode 323 is formed on the exposed first semiconductor layer 311 near the boundary of the photoelectric element 400 . In one embodiment, the third first electrical type electrode 323 It is not surrounded by the second semiconductor layer 313 , and the second insulating layer 342 has a fourth opening 3424 for electrically connecting the third first electrical electrode 323 to the third electrode 35 formed later. The fourth first electrical type electrode 324 is formed on the exposed first semiconductor layer 311 near the boundary of the photoelectric element 400 . In one embodiment, the fourth first electrical type electrode 324 is not surrounded by the second semiconductor layer 313 , and the second insulating layer 342 has a fifth opening 3425 to serve as the fourth first electrical type electrode 324 and the subsequent formed second semiconductor layer 313 . The three electrodes 35 are used for electrical connection.

在本實施例中,第三第一電性電極323於第一半導體層上311之投影可具有一圖形,其中此圖形可為一多邊形、一圓形、一橢圓形、一半圓形或具有一圓弧面。第四第一電性電極324之形狀可為線形、弧形、線形與弧形混合形、或可具有至少一分支。在一實施例中,第四第一電性電極324可具有一頭端及一尾端,且上述頭端可具有一寬度大於尾端之一寬度。在一實施例中,第三第一電性電極323與第四第一電性電極324之形狀不同。 In this embodiment, the projection of the third first electrical type electrode 323 on the first semiconductor layer 311 can have a pattern, wherein the pattern can be a polygon, a circle, an ellipse, a semicircle or have a Arc surface. The shape of the fourth first electrical type electrode 324 may be linear, arc, a mixture of linear and arc, or may have at least one branch. In one embodiment, the fourth first electrical type electrode 324 may have a head end and a tail end, and the head end may have a width greater than that of the tail end. In one embodiment, the shapes of the third first electrical type electrode 323 and the fourth first electrical type electrode 324 are different.

在一實施例中,依據產品設計之要求,第一第一電性電極321與第三第一電性電極323可形成在光電元件400之同一邊界旁,且彼此分離。在一實施例中,第一第一電性電極321及第四第一電性電極324、或第三第一電性電極323及第四第一電性電極324不形成在光電元件400之同一邊界旁。 In one embodiment, according to product design requirements, the first first electrical type electrode 321 and the third first electrical type electrode 323 may be formed beside the same boundary of the photoelectric element 400 and separated from each other. In one embodiment, the first first electrical type electrode 321 and the fourth first electrical type electrode 324, or the third first electrical type electrode 323 and the fourth first electrical type electrode 324 are not formed on the same side of the photoelectric element 400. next to the border.

在一實施例中,第四第一電性電極324的頭端可被第三電極35所覆蓋,且第四第一電性電極324的尾端不被第四電極36所覆蓋。在本實施例中,第三電極35於第一半導體層311上之投影面積大於第四電極36於第一半導體層311上之投影面積,且第三電極35及第四電極36於第一半導體層311上之投影面積之比值介於110~120%。在一實施例中,上述第二第一電性電極322及第四第一電性電極324之尾端延伸方向為大致相互平行。 In one embodiment, the head end of the fourth first electrical type electrode 324 may be covered by the third electrode 35 , and the tail end of the fourth first electrical type electrode 324 is not covered by the fourth electrode 36 . In this embodiment, the projected area of the third electrode 35 on the first semiconductor layer 311 is greater than the projected area of the fourth electrode 36 on the first semiconductor layer 311, and the third electrode 35 and the fourth electrode 36 are on the first semiconductor layer 311. The ratio of the projected area on the layer 311 is between 110-120%. In one embodiment, the extension directions of the tail ends of the second first electrical type electrode 322 and the fourth first electrical type electrode 324 are substantially parallel to each other.

第4A圖係顯示本發明第三實施例之光電元件500上視圖。本實施例其製作方法、使用材料及標號等與上述第一實施例相同,在此不再贅述。在本發明之實施例中,電極設計型態可包括電極數量、電極形狀及電極位置的選擇,以增進光電元件500靠近邊界區域之電流散佈。 FIG. 4A is a top view of a photoelectric device 500 according to a third embodiment of the present invention. The manufacturing method, materials and labels of this embodiment are the same as those of the first embodiment above, and will not be repeated here. In the embodiment of the present invention, the design of the electrodes may include the selection of the number of electrodes, the shape of the electrodes, and the positions of the electrodes, so as to improve the current spreading near the boundary region of the photovoltaic device 500 .

在本實施例中,光電元件500之四個邊界形成一長方形,相鄰兩邊界可構成一角落,且無跨越邊界之導電結構,上述邊界具有一第一長邊B1、一第二長邊B3、一第一短邊B2及一第二短邊B4。在一實施例中,上述第一長邊B1或第二長邊B3之長度大於第一短邊B2或第二短邊B4。在本實施例中,第三電極35及第四電極36於第一半導體層311上之投影係沿著第一長邊B1或第二長邊B3排列。 In this embodiment, the four boundaries of the photoelectric element 500 form a rectangle, two adjacent boundaries can form a corner, and there is no conductive structure crossing the boundary, the above boundary has a first long side B1 and a second long side B3 , a first short side B2 and a second short side B4. In one embodiment, the first long side B1 or the second long side B3 is longer than the first short side B2 or the second short side B4. In this embodiment, the projections of the third electrode 35 and the fourth electrode 36 on the first semiconductor layer 311 are arranged along the first long side B1 or the second long side B3.

在本實施例中,兩個彼此分離之第一第一電性電極321係形成於第一短邊B2之兩個角落之上,且第二絕緣層342也可具有一第二開口3422以作為第一第一電性電極321與後續形成之第三電極35電性連接之用。兩個第四第一電性電極324分別位於第一長邊B1及一第二長邊B3之邊界旁所裸露出之第一半導體層311之上。在本實施例中,第三第一電性電極323係形成於第一短邊B2之上,且第二絕緣層342也可具有一第四開口3424以作為第三第一電性電極323與後續形成之第三電極35電性連接之用。第四第一電性電極324未被第二半導體層313圍繞,且第二絕緣層342也可具有一第三開口3423以作為第四第一電性電極324與後續形成之第三電極35電性連接之用。 In this embodiment, two first first electrical electrodes 321 separated from each other are formed on two corners of the first short side B2, and the second insulating layer 342 may also have a second opening 3422 as a The first first electrical type electrode 321 is used for electrical connection with the subsequently formed third electrode 35 . The two fourth electrodes 324 of the first electrical type are respectively located on the exposed first semiconductor layer 311 beside the boundary of the first long side B1 and a second long side B3 . In this embodiment, the third first electrical type electrode 323 is formed on the first short side B2, and the second insulating layer 342 may also have a fourth opening 3424 as the third first electrical type electrode 323 and The third electrode 35 formed later is used for electrical connection. The fourth first electrical type electrode 324 is not surrounded by the second semiconductor layer 313, and the second insulating layer 342 may also have a third opening 3423 as an electrical connection between the fourth first electrical type electrode 324 and the subsequently formed third electrode 35. for sexual connection.

在一實施例中,第三第一電性電極323與上述兩第一第一電性電極321之距離大致相等。此外,第一第一電性電極321、第四第一電性電極324、及第三電極35可於同一製程中形成。 In one embodiment, the distance between the third first electrical type electrode 323 and the above two first first electrical type electrodes 321 is approximately equal. In addition, the first first electrical type electrode 321 , the fourth first electrical type electrode 324 , and the third electrode 35 can be formed in the same process.

在本實施例中,第一第一電性電極321於第一半導體層上311之投影可具有一圖形,其中圖形為一多邊形、一圓形、一橢圓形、一半圓形或具有一圓弧面。第三第一電性電極323於第一半導體層上311之投影可具有一圖形,其中圖形為一多邊形、一圓形、一橢圓形、一半圓形或具有一圓弧面。第四第一電性電極324為延伸狀,可為線形、弧形、線形與弧形混合形、或可具有至少一分支。在一實施例中,第四第一電性電極324具有一頭端及一尾端,且上述頭端可具有一寬度大於尾端之一寬度。在一實施例中,第三第一電性電極323與第四第一電性電極324之形狀不同。 In this embodiment, the projection of the first first electrical type electrode 321 on the first semiconductor layer 311 may have a pattern, wherein the pattern is a polygon, a circle, an ellipse, a semicircle or an arc noodle. The projection of the third first electrical type electrode 323 on the first semiconductor layer 311 may have a pattern, wherein the pattern is a polygon, a circle, an ellipse, a semicircle or an arc surface. The fourth first electrical type electrode 324 is extended, and may be linear, arc-shaped, a mixture of linear and arc-shaped, or may have at least one branch. In one embodiment, the fourth first electrical type electrode 324 has a head end and a tail end, and the head end may have a width greater than that of the tail end. In one embodiment, the shapes of the third first electrical type electrode 323 and the fourth first electrical type electrode 324 are different.

在一實施例中,上述第四第一電性電極324之頭端指向第一短邊B2且尾端指向第二短邊B4。在一實施例中,此第四第一電性電極324的頭端可被第三電極35所覆蓋,且第四第一電性電極324的尾端不被第四電極36所覆蓋。在一實施例中,上述兩第四第一電性電極324之尾端延伸方向大致相互平行。在本實施例中,第三電極35於第一半導體層311上之投影面積大於第四電極36於第一半導體層311上之投影面積;且第三電極35及第四電極36於第一半導體層311上之投影面積之比值介於110~120%。 In one embodiment, the head end of the fourth first electrical type electrode 324 points to the first short side B2 and the tail end points to the second short side B4. In one embodiment, the head end of the fourth first electrical type electrode 324 can be covered by the third electrode 35 , and the tail end of the fourth first electrical type electrode 324 is not covered by the fourth electrode 36 . In one embodiment, the extension directions of the tail ends of the two fourth electrodes 324 of the first electrical type are substantially parallel to each other. In this embodiment, the projected area of the third electrode 35 on the first semiconductor layer 311 is larger than the projected area of the fourth electrode 36 on the first semiconductor layer 311; The ratio of the projected area on the layer 311 is between 110-120%.

第4B圖係顯示本發明第四實施例之光電元件600之上視圖。本實施例其製作方法、使用材料及標號等與上述第一實施例相同,在此不再贅述。在本發明之實施例中,電極設計型態可包括電極數量、電極形狀及電極位置的選擇,以增進光電元件600靠近邊界區域之電流散佈。 FIG. 4B is a top view of a photoelectric element 600 according to a fourth embodiment of the present invention. The manufacturing method, materials and labels of this embodiment are the same as those of the first embodiment above, and will not be repeated here. In the embodiment of the present invention, the design of the electrodes may include the selection of the number of electrodes, the shape of the electrodes, and the positions of the electrodes, so as to improve the current spreading of the photoelectric device 600 near the boundary region.

在本實施例中,光電元件600之四個邊界形成一長方形,相鄰兩邊界可構成一角落,且無跨越邊界之導電結構。光電元件600具有一第一長邊B1、一第二長邊B3、一第一短邊B2及一第二短邊B4。在一實施例中,上述第一長邊B1或第二長邊B3之長度大於第一短邊B2或第二短邊B4。在本實施例中,第 三電極35及第四電極36於第一半導體層311上之投影係沿著第一長邊B1或第二長邊B3排列。 In this embodiment, the four boundaries of the photoelectric element 600 form a rectangle, two adjacent boundaries can form a corner, and there is no conductive structure crossing the boundaries. The photoelectric element 600 has a first long side B1 , a second long side B3 , a first short side B2 and a second short side B4 . In one embodiment, the first long side B1 or the second long side B3 is longer than the first short side B2 or the second short side B4. In this example, the first Projections of the three electrodes 35 and the fourth electrode 36 on the first semiconductor layer 311 are arranged along the first long side B1 or the second long side B3.

在本實施例中,包含至少一個第一第一電性電極321。在一實施例中,可形成四個第一第一電性電極321於第一半導體層311的四個角落之上,且第二絕緣層342也可具有一第二開口3422以作為第一第一電性電極321與後續形成之第三電極35電性連接之用。兩個第二第一電性電極322形成於第一半導體層311之上,且被第二半導體層313圍繞,且第二絕緣層342也可具有一第三開口3423以作為第二第一電性電極322與後續形成之第三電極35電性連接之用。 In this embodiment, at least one first first electrical type electrode 321 is included. In one embodiment, four first electrodes 321 of the first electrical type can be formed on the four corners of the first semiconductor layer 311, and the second insulating layer 342 can also have a second opening 3422 as the first first electrode. An electrical electrode 321 is used for electrical connection with the subsequently formed third electrode 35 . Two second first electrical electrodes 322 are formed on the first semiconductor layer 311 and surrounded by the second semiconductor layer 313, and the second insulating layer 342 may also have a third opening 3423 as the second first electrical electrode. The sex electrode 322 is electrically connected to the third electrode 35 formed later.

在本實施例中,第一第一電性電極321於第一半導體層上311之投影可具有一圖形,其中圖形為一多邊形、一圓形、一橢圓形、一半圓形或具有一圓弧面。第二第一電性電極322於第一半導體層上311之投影可具有一圖形,其中圖形為一多邊形、一圓形、一橢圓形、一半圓形或具有一圓弧面。在一實施例中,上述兩個第二第一電性電極322於第一半導體層311上之投影形狀可為相同或不同。 In this embodiment, the projection of the first first electrical type electrode 321 on the first semiconductor layer 311 may have a pattern, wherein the pattern is a polygon, a circle, an ellipse, a semicircle or an arc noodle. The projection of the second first electrical type electrode 322 on the first semiconductor layer 311 may have a pattern, wherein the pattern is a polygon, a circle, an ellipse, a semicircle or an arc surface. In one embodiment, the projected shapes of the two second first electrical type electrodes 322 on the first semiconductor layer 311 may be the same or different.

在本實施例中,第三電極35係包含兩個延伸部351,且上述兩延伸部351可大致形成一凹口R,且第四電極36位於凹口R內。此外,第一第一電性電極321、第二第一電性電極322及第三電極35可於同一製程中形成。 In this embodiment, the third electrode 35 includes two extensions 351 , and the two extensions 351 can roughly form a notch R, and the fourth electrode 36 is located in the notch R. Referring to FIG. In addition, the first first electrical type electrode 321 , the second first electrical type electrode 322 and the third electrode 35 can be formed in the same process.

第4C圖係顯示本發明第五實施例之光電元件700之上視圖。本實施例其製作方法、使用材料及標號等與上述第一實施例相同,在此不再贅述。在本發明之實施例中,電極設計型態可包括電極數量、電極形狀及電極位置的選擇,以增進光電元件700靠近邊界區域之電流散佈。 FIG. 4C is a top view of a photoelectric element 700 according to a fifth embodiment of the present invention. The manufacturing method, materials and labels of this embodiment are the same as those of the first embodiment above, and will not be repeated here. In the embodiment of the present invention, the design of the electrodes may include the selection of the number of electrodes, the shape of the electrodes, and the positions of the electrodes, so as to improve the current distribution of the photoelectric device 700 near the boundary region.

在一實施例中,光電元件700之第一半導體層311具有至少四個邊界,相鄰兩邊界可構成一角落,且無跨越邊界之導電結構。在本實施例中,包含四個第一第一電性電極321,係分別形成於第一半導體層311的四個角落之 上,且第二絕緣層342也可具有一第二開口3422以作為第一第一電性電極321與後續形成之第三電極35電性連接之用。複數個第二第一電性電極322形成於第一半導體層311之上,係被第二半導體層313圍繞,且第二絕緣層342也可具有一第四開口3424以作為第二第一電性電極322與後續形成之第三電極35電性連接之用。複數個第三第一電性電極323,係形成於光電元件700之邊界旁所裸露出之第一半導體層311之上。換言之,第三第一電性電極323未被第二半導體層313圍繞,且第一半導體層311的任一邊界旁可包含一個或多個第三第一電性電極323。第二絕緣層342可具有一第三開口3423以作為第二第一電性電極322與後續形成之第三電極35電性連接之用。 In one embodiment, the first semiconductor layer 311 of the photoelectric element 700 has at least four boundaries, two adjacent boundaries can form a corner, and there is no conductive structure crossing the boundaries. In this embodiment, there are four first electrodes 321 of the first electrical type, which are respectively formed at the four corners of the first semiconductor layer 311 and the second insulating layer 342 may also have a second opening 3422 for electrical connection between the first first electrical type electrode 321 and the subsequently formed third electrode 35 . A plurality of second first electrical electrodes 322 are formed on the first semiconductor layer 311 and surrounded by the second semiconductor layer 313, and the second insulating layer 342 may also have a fourth opening 3424 as the second first electrical electrode. The sex electrode 322 is electrically connected to the third electrode 35 formed later. A plurality of third electrodes 323 of the first electrical type are formed on the exposed first semiconductor layer 311 beside the boundary of the photoelectric element 700 . In other words, the third first electrical type electrode 323 is not surrounded by the second semiconductor layer 313 , and one or more third first electrical type electrodes 323 may be included beside any boundary of the first semiconductor layer 311 . The second insulating layer 342 may have a third opening 3423 for electrically connecting the second first electrical electrode 322 with the third electrode 35 formed later.

在本實施例中,第一第一電性電極321於第一半導體層上311之投影可具有一圖形,其中圖形為一多邊形、一圓形、一橢圓形、一半圓形或具有一圓弧面。第二第一電性電極322於第一半導體層上311之投影可具有一圖形,其中圖形為一多邊形、一圓形、一橢圓形、一半圓形或具有一圓弧面。在一實施例中,第二第一電性電極322之形狀可為延伸狀,且其延伸方向可平行於延伸部351之延伸方向。第二第一電性電極322可為線形、弧形、線形與弧形混合形、或可具有至少一分支。在一實施例中,上述複數個第二第一電性電極322於第一半導體層311上之投影面積可為相同或不同。第三第一電性電極323於第一半導體層上311之投影可具有一圖形,其中圖形為一多邊形、一圓形、一橢圓形、一半圓形或具有一圓弧面。 In this embodiment, the projection of the first first electrical type electrode 321 on the first semiconductor layer 311 may have a pattern, wherein the pattern is a polygon, a circle, an ellipse, a semicircle or an arc noodle. The projection of the second first electrical type electrode 322 on the first semiconductor layer 311 may have a pattern, wherein the pattern is a polygon, a circle, an ellipse, a semicircle or an arc surface. In one embodiment, the shape of the second first electrical type electrode 322 may be extended, and its extending direction may be parallel to the extending direction of the extending portion 351 . The second first electrical type electrode 322 can be linear, curved, a mixture of linear and curved, or have at least one branch. In one embodiment, the projected areas of the plurality of second first electrical type electrodes 322 on the first semiconductor layer 311 may be the same or different. The projection of the third first electrical type electrode 323 on the first semiconductor layer 311 may have a pattern, wherein the pattern is a polygon, a circle, an ellipse, a semicircle or an arc surface.

在本實施例中,第三電極35係包含三個延伸部351,且上述三個延伸部351可大致形成兩凹口R,且兩個第四電極36可形成於上述兩個凹口R內。在本實施例中,至少一第二第一電性電極322可形成於上述延伸部351之中。 In this embodiment, the third electrode 35 includes three extensions 351, and the three extensions 351 can roughly form two notches R, and two fourth electrodes 36 can be formed in the two notches R . In this embodiment, at least one second first electrical type electrode 322 can be formed in the extension portion 351 .

在一實施例中,上述第一第一電性電極321、第二第一電性電極322、第三第一電性電極323於第一半導體層311上之投影形狀也可為相同或不 同。此外,第一第一電性電極321、第二第一電性電極322、第三第一電性電極323及第三電極35也可於同一製程中形成。 In one embodiment, the projected shapes of the first first electrical type electrode 321, the second first electrical type electrode 322, and the third first electrical type electrode 323 on the first semiconductor layer 311 may also be the same or different. same. In addition, the first first electrical type electrode 321 , the second first electrical type electrode 322 , the third first electrical type electrode 323 and the third electrode 35 can also be formed in the same process.

第4D圖係顯示本發明第六實施例之光電元件700’之上視圖。本實施例係為第五實施例之可能變化例,其製作方法、使用材料、電極設計及標號等與上述第五實施例相同,在此不再贅述。 Fig. 4D is a top view showing the photoelectric element 700' of the sixth embodiment of the present invention. This embodiment is a possible modification of the fifth embodiment. Its manufacturing method, materials used, electrode design and labels are the same as those of the fifth embodiment above, and will not be repeated here.

在本實施例中,光電元件700’之第二絕緣層342具有複數個第一開口3421’以作為第二電性電極33與後續形成之第四電極36電性連接之用。在本實施例中,第二絕緣層342具有複數個第一開口3421可以減少第三電極35及第四電極36高度的差異,減少後續與載板或電路元件形成覆晶式結構之斷線機率,進而增加產品良率。 In this embodiment, the second insulating layer 342 of the photoelectric element 700' has a plurality of first openings 3421' for electrically connecting the second electrical electrode 33 to the fourth electrode 36 formed later. In this embodiment, the second insulating layer 342 has a plurality of first openings 3421, which can reduce the height difference between the third electrode 35 and the fourth electrode 36, and reduce the probability of disconnection in subsequent flip-chip structure formation with the carrier board or circuit components. , thereby increasing product yield.

第5A圖至第5C圖係繪示出一發光模組示意圖,第5A圖係顯示一發光模組外部透視圖,一發光模組800可包含一載體502,一光電元件(未顯示),複數個透鏡504、506、508及510,及兩電源供應終端512及514。此發光模組800可連接於之後描述之發光單元540。 Figures 5A to 5C are schematic diagrams of a light-emitting module. Figure 5A shows an external perspective view of a light-emitting module. A light-emitting module 800 may include a carrier 502, a photoelectric element (not shown), and a plurality of There are three lenses 504, 506, 508 and 510, and two power supply terminals 512 and 514. The light emitting module 800 can be connected to the light emitting unit 540 described later.

第5B-5C圖係顯示一發光模組800之剖面圖,其中第8C圖係第8B圖之E區的放大圖。載體502可包含一上載體503及下載體501,其中下載體501之一表面可與上載體503接觸。透鏡504及508形成在上載體503之上。上載體503可形成至少一通孔515,而依本發明實施例形成之光電元件300或其他實施例之光電元件(圖未示)可形成在上述通孔515中並與下載體501接觸,且被膠材521圍繞。膠材521之上具有一透鏡508,其中膠材521之材料可為矽膠樹脂、環氧樹脂或其他材料。在一實施例中,通孔515之兩側壁之上可形成一反射層519以增加出光效率;下載體501之下表面可形成一金屬層517以增進散熱效率。 5B-5C are cross-sectional views showing a light emitting module 800, wherein FIG. 8C is an enlarged view of area E in FIG. 8B. The carrier 502 can include an upper carrier 503 and a lower carrier 501 , wherein a surface of the lower carrier 501 can be in contact with the upper carrier 503 . Lenses 504 and 508 are formed on the upper carrier 503 . The upper carrier 503 can form at least one through hole 515, and the photoelectric element 300 formed according to the embodiment of the present invention or the photoelectric element (not shown) of other embodiments can be formed in the above-mentioned through hole 515 and contact with the lower carrier 501, and be Adhesive material 521 surrounds. There is a lens 508 on the adhesive material 521 , wherein the material of the adhesive material 521 can be silicone resin, epoxy resin or other materials. In one embodiment, a reflective layer 519 may be formed on both sidewalls of the through hole 515 to increase light extraction efficiency; a metal layer 517 may be formed on the lower surface of the lower carrier 501 to enhance heat dissipation efficiency.

第6A-6B圖係繪示出一光源產生裝置示意圖900,一光源產生裝置900可包含一發光模組800、一發光單元540、一電源供應系統(未顯示)以供應 發光模組800一電流、以及一控制元件(未顯示),用以控制電源供應系統(未顯示)。光源產生裝置900可以是一照明裝置,例如路燈、車燈或室內照明光源,也可以是交通號誌或一平面顯示器中背光模組的一背光光源。 Figures 6A-6B show a schematic diagram of a light source generating device 900. A light source generating device 900 may include a light emitting module 800, a light emitting unit 540, and a power supply system (not shown) to supply The light emitting module 800 has a current and a control element (not shown) for controlling the power supply system (not shown). The light source generating device 900 can be a lighting device, such as a street lamp, a car lamp or an indoor lighting source, and can also be a traffic sign or a backlight source of a backlight module in a flat panel display.

第7圖係繪示一燈泡示意圖。燈泡1000包括一個外殼921,一透鏡922,一照明模組924,一支架925,一散熱器926,一串接部927及一電串接器928。其中照明模組924係包括一載體923,並在載體923上包含至少一個上述實施例中的光電元件300或其他實施例之光電元件(圖未示)。 Fig. 7 is a schematic diagram of a light bulb. The bulb 1000 includes a housing 921 , a lens 922 , a lighting module 924 , a bracket 925 , a radiator 926 , a serial connection 927 and an electrical serial connector 928 . The lighting module 924 includes a carrier 923, and the carrier 923 includes at least one optoelectronic element 300 in the above embodiment or the optoelectronic element in other embodiments (not shown).

具體而言,基板30係為一成長及/或承載基礎。候選材料可包含導電基板或不導電基板、透光基板或不透光基板。其中導電基板材料其一可為鍺(Ge)、砷化鎵(GaAs)、銦化磷(InP)、碳化矽(SiC)、矽(Si)、鋁酸鋰(LiAlO2)、氧化鋅(ZnO)、氮化鎵(GaN)、氮化鋁(AlN)、金屬。透光基板材料其一可為藍寶石(Sapphire)、鋁酸鋰(LiAlO2)、氧化鋅(ZnO)、氮化鎵(GaN)、玻璃、鑽石、CVD鑽石、與類鑽碳(Diamond-Like Carbon;DLC)、尖晶石(spinel,MgAl2O4)、氧化鋁(Al2O3)、氧化矽(SiOX)及鎵酸鋰(LiGaO2)。 Specifically, the substrate 30 is a growth and/or carrying base. Candidate materials may include conductive substrates or non-conductive substrates, light-transmissive substrates or light-impermeable substrates. One of the conductive substrate materials can be germanium (Ge), gallium arsenide (GaAs), indium phosphorus (InP), silicon carbide (SiC), silicon (Si), lithium aluminate (LiAlO2), zinc oxide (ZnO) , Gallium Nitride (GaN), Aluminum Nitride (AlN), Metal. One of the transparent substrate materials can be sapphire (Sapphire), lithium aluminate (LiAlO2), zinc oxide (ZnO), gallium nitride (GaN), glass, diamond, CVD diamond, and diamond-like carbon (Diamond-Like Carbon; DLC), spinel (spinel, MgAl2O4), aluminum oxide (Al2O3), silicon oxide (SiOX) and lithium gallate (LiGaO2).

磊晶疊層31包含第一半導體層311,一活性層312,以及一第二半導體層313。第一半導體層311及第二半導體層313例如為包覆層(cladding layer)或限制層(confinement layer),可為一單層或多層結構。上述第一半導體層311與第二半導體層313係電性、極性或摻雜物相異,其電性選擇可以為p型、n型、及i型中至少任意二者之組合,可分別提供電子、電洞,使電子、電洞於活性層312中結合以發光。第一半導體層311、活性層312,以及第二半導體層313之材料可包含Ⅲ-V族半導體材料,例如AlxInyGa(1-x-y)N或AlxInyGa(1-x-y)P,其中0≦x,y≦1;(x+y)≦1。依據活性層312之材料,磊晶疊層可發出波長介於610nm 及650nm之間的紅光,波長介於530nm及570nm之間的綠光,波長介於450nm及490nm之間的藍光,或是波長小於400nm之紫外光。 The epitaxial stack 31 includes a first semiconductor layer 311 , an active layer 312 , and a second semiconductor layer 313 . The first semiconductor layer 311 and the second semiconductor layer 313 are, for example, cladding layers or confinement layers, which can be a single-layer or multi-layer structure. The above-mentioned first semiconductor layer 311 and the second semiconductor layer 313 are different in electrical property, polarity or dopant, and the electrical property selection can be a combination of at least any two of p-type, n-type, and i-type, and can provide Electrons and holes are combined in the active layer 312 to emit light. The materials of the first semiconductor layer 311, the active layer 312, and the second semiconductor layer 313 may include III-V group semiconductor materials, such as AlxInyGa(1-x-y)N or AlxInyGa(1-x-y)P, where 0≦x,y ≦1; (x+y)≦1. Depending on the material of the active layer 312, the epitaxial stack can emit wavelengths between 610nm Red light with a wavelength between 530nm and 570nm, blue light with a wavelength between 450nm and 490nm, or ultraviolet light with a wavelength less than 400nm.

在本發明的另一實施例中,光電元件300、400、500、600、700、700’可為一磊晶元件或一發光二極體,其發光頻譜可以藉由改變磊晶疊層單層或多層之物理或化學要素進行調整。此單層或多層之磊晶疊層材料可選自鋁(Al)、鎵(Ga)、銦(In)、磷(P)、氮(N)、鋅(Zn)以及氧(O)所構成群組。活性層312之結構係如:單異質結構(single heterostructure;SH)、雙異質結構(double heterostructure;DH)、雙側雙異質結構(double-side double heterostructure;DDH)、或多層量子井(multi-quantum well;MQW)結構。再者,調整活性層312量子井之對數亦可以改變發光波長。 In another embodiment of the present invention, the photoelectric element 300, 400, 500, 600, 700, 700' can be an epitaxial element or a light-emitting diode, and its light emission spectrum can be changed by changing the single layer of the epitaxial stack or multi-layer physical or chemical elements to be adjusted. The single-layer or multi-layer epitaxial stack material can be selected from aluminum (Al), gallium (Ga), indium (In), phosphorus (P), nitrogen (N), zinc (Zn) and oxygen (O) group. The structure of the active layer 312 is such as: single heterostructure (single heterostructure; SH), double heterostructure (double heterostructure; DH), double-side double heterostructure (double-side double heterostructure; DDH), or multi-layer quantum wells (multi- quantum well; MQW) structure. Furthermore, adjusting the logarithm of the quantum wells in the active layer 312 can also change the emission wavelength.

於本發明之一實施例中,第一半導體層311與基板30間尚可選擇性地包含一緩衝層(buffer layer,未顯示)。此緩衝層係介於二種材料系統之間,使基板30之材料系統”過渡”至第一半導體層311之材料系統。對發光二極體之結構而言,一方面,緩衝層係用以降低二種材料間晶格不匹配之材料層。另一方面,緩衝層亦可以是用以結合二種材料或二個分離結構之單層、多層或結構,其可選用之材料係如:有機材料、無機材料、金屬、及半導體等;其可選用之結構係如:反射層、導熱層、導電層、歐姆接觸(ohmic contact)層、抗形變層、應力釋放(stress release)層、應力調整(stress adjustment)層、接合(bonding)層、波長轉換層、及機械固定構造等。在一實施例中,此緩衝層之材料可選自氮化鋁或氮化鎵,且此緩衝層可由濺鍍或原子層沉積(Atomic Layer Deposition,ALD)之方式形成。 In an embodiment of the present invention, a buffer layer (not shown) may optionally be included between the first semiconductor layer 311 and the substrate 30 . The buffer layer is between the two material systems, so that the material system of the substrate 30 “transitions” to the material system of the first semiconductor layer 311 . For the structure of light-emitting diodes, on the one hand, the buffer layer is a material layer used to reduce the lattice mismatch between the two materials. On the other hand, the buffer layer can also be a single layer, multi-layer or structure used to combine two materials or two separate structures, and the optional materials are such as: organic materials, inorganic materials, metals, and semiconductors; The selected structure is such as: reflective layer, thermal conductive layer, conductive layer, ohmic contact layer, anti-deformation layer, stress release layer, stress adjustment layer, bonding layer, wavelength Conversion layer, and mechanical fixing structure, etc. In one embodiment, the material of the buffer layer can be selected from aluminum nitride or gallium nitride, and the buffer layer can be formed by sputtering or atomic layer deposition (Atomic Layer Deposition, ALD).

第二半導體層313與第二電性電極33之間更可選擇性地形成一接觸層(未顯示)。具體而言,接觸層可以為光學層、電學層、或其二者之組合。光學層係可以改變來自於或進入活性層的電磁輻射或光線。在此所稱之「改變」 係指改變電磁輻射或光之至少一種光學特性,前述特性係包含但不限於頻率、波長、強度、通量、效率、色溫、演色性(rendering index)、光場(light field)、及可視角(angle of view)。電學層係可以使得接觸層之任一組相對側間之電壓、電阻、電流、電容中至少其一之數值、密度、分布發生變化或有發生變化之趨勢。接觸層之構成材料係包含氧化物、導電氧化物、透明氧化物、具有50%或以上穿透率之氧化物、金屬、相對透光金屬、具有50%或以上穿透率之金屬、有機質、無機質、螢光物、磷光物、陶瓷、半導體、摻雜之半導體、及無摻雜之半導體中至少其一。於某些應用中,接觸層之材料係為氧化銦錫、氧化鎘錫、氧化銻錫、氧化銦鋅、氧化鋅鋁、與氧化鋅錫中至少其一。若為相對透光金屬,其厚度較佳地約為0.005μm~0.6μm。 A contact layer (not shown) can be optionally formed between the second semiconductor layer 313 and the second electrical type electrode 33 . Specifically, the contact layer may be an optical layer, an electrical layer, or a combination thereof. The optical layer system can modify electromagnetic radiation or light from or into the active layer. here called "change" Refers to the modification of at least one optical property of electromagnetic radiation or light, including but not limited to frequency, wavelength, intensity, flux, efficiency, color temperature, rendering index, light field, and viewing angle (angle of view). The electrical layer system can cause the value, density, and distribution of at least one of voltage, resistance, current, and capacitance between any set of opposite sides of the contact layer to change or have a tendency to change. The constituent materials of the contact layer include oxides, conductive oxides, transparent oxides, oxides with a transmittance of 50% or more, metals, relatively transparent metals, metals with a transmittance of 50% or more, organic matter, At least one of inorganic substances, fluorescent substances, phosphorescent substances, ceramics, semiconductors, doped semiconductors, and undoped semiconductors. In some applications, the material of the contact layer is at least one of indium tin oxide, cadmium tin oxide, antimony tin oxide, indium zinc oxide, zinc aluminum oxide, and zinc tin oxide. If it is a relatively light-transmitting metal, its thickness is preferably about 0.005 μm˜0.6 μm.

以上各圖式與說明雖僅分別對應特定實施例,然而,各個實施例中所說明或揭露之元件、實施方式、設計準則、及技術原理除在彼此顯相衝突、矛盾、或難以共同實施之外,吾人當可依其所需任意參照、交換、搭配、協調、或合併。雖然本發明已說明如上,然其並非用以限制本發明之範圍、實施順序、或使用之材料與製程方法。對於本發明所作之各種修飾與變更,皆不脫本發明之精神與範圍。 Although the above drawings and descriptions only correspond to specific embodiments, however, the components, implementation methods, design principles, and technical principles described or disclosed in each embodiment are unless they conflict with each other, contradict, or are difficult to implement together. In addition, we can refer to, exchange, match, coordinate, or merge arbitrarily according to our needs. Although the present invention has been described above, it is not intended to limit the scope of the present invention, the implementation sequence, or the materials and process methods used. Various modifications and changes made to the present invention do not depart from the spirit and scope of the present invention.

700:光電元件 700: photoelectric components

311:第一半導體層 311: the first semiconductor layer

321:第一第一電性電極 321: the first first electrical electrode

322:第二第一電性電極 322: the second first electrical electrode

323:第三第一電性電極 323: the third first electrical electrode

342:第二絕緣層 342: second insulating layer

3422:第二開口 3422: second opening

3423:第三開口 3423: the third opening

3424:第四開口 3424: The fourth opening

35:第三電極 35: The third electrode

351:延伸部 351: Extension

36:第四電極 36: The fourth electrode

Claims (10)

一種光電元件,包含:一磊晶疊層,包含一第一半導體層,一活性層形成於該第一半導體層上,以及一第二半導體層形成於該活性層上,其中該第一半導體層包含複數個第一邊界及一周圍裸露區域鄰近該複數個第一邊界且不被該活性層及該第二半導體層覆蓋;一第一電極,形成於該第二半導體層上,且包含複數個第二邊界;一絕緣層,覆蓋該第二半導體層及該第一電極,且包含複數個第一開口,其中該複數個第一開口之一部分位於該周圍裸露區域之一部分上,該周圍裸露區域之該部分鄰近該複數個第一邊界之一;一第二電極,形成於該絕緣層上且包含複數個邊緣;以及一第三電極形成於該絕緣層上,電性連接該第二半導體層,其中該複數個第一邊界之該一鄰近該複數個第二邊界之一,該複數個邊緣之一鄰近該複數個第一邊界之該一且遠離該第三電極,該複數個邊緣之該一包含一或多個第一凹部位於該第一電極上且位於該複數個第二邊界之該一內,該複數邊緣之該一包含一或多個第一凸部凸出於該一或多個第一凹部且超出該複數個第二邊界之該一以經由該複數個第一開口之該部分電性連接該第一半導體層。 A photoelectric element, comprising: an epitaxial stack including a first semiconductor layer, an active layer formed on the first semiconductor layer, and a second semiconductor layer formed on the active layer, wherein the first semiconductor layer Including a plurality of first boundaries and a surrounding bare area adjacent to the plurality of first boundaries and not covered by the active layer and the second semiconductor layer; a first electrode formed on the second semiconductor layer and comprising a plurality of The second boundary: an insulating layer covering the second semiconductor layer and the first electrode, and including a plurality of first openings, wherein a part of the plurality of first openings is located on a part of the surrounding exposed area, and the surrounding exposed area The portion is adjacent to one of the plurality of first boundaries; a second electrode is formed on the insulating layer and includes a plurality of edges; and a third electrode is formed on the insulating layer and is electrically connected to the second semiconductor layer , wherein the one of the plurality of first boundaries is adjacent to one of the plurality of second boundaries, one of the plurality of edges is adjacent to the one of the plurality of first boundaries and away from the third electrode, and the one of the plurality of edges One comprising one or more first recesses located on the first electrode and within one of the plurality of second boundaries, one of the plurality of edges comprising one or more first protrusions protruding from the one or more a first recess and beyond the one of the plurality of second boundaries to electrically connect the first semiconductor layer through the portion of the plurality of first openings. 如申請專利範圍第1項所述的光電元件,其中該第三電極包含兩個電極部,該第二電極之一部分位於該兩個電極部之間。 The photoelectric element as described in claim 1, wherein the third electrode includes two electrode parts, and a part of the second electrode is located between the two electrode parts. 如申請專利範圍第1項所述的光電元件,其中該第二電極包含複數個延伸部,該複數個延伸部形成一凹口。 The photoelectric element described in claim 1, wherein the second electrode includes a plurality of extensions, and the plurality of extensions form a notch. 如申請專利範圍第1項所述的光電元件,其中該第一半導體層包含複數個內部裸露區域不被該活性層及該第二半導體層覆蓋,且被該第二半導體層所圍繞。 The optoelectronic device as described in claim 1, wherein the first semiconductor layer includes a plurality of inner exposed regions not covered by the active layer and the second semiconductor layer, and surrounded by the second semiconductor layer. 如申請專利範圍第4項所述的光電元件,其中該第二電極位於該複數個內部裸露區域上,且藉由該複數個內部裸露區域電性連接該第一半導體層。 The photoelectric element as described in item 4 of the scope of the present invention, wherein the second electrode is located on the plurality of inner exposed regions, and is electrically connected to the first semiconductor layer through the plurality of inner exposed regions. 如申請專利範圍第4項所述的光電元件,其中該磊晶疊層包含一表面,圍繞該複數個內部裸露區域的該第二半導體層包含複數個內側壁連接該表面,該絕緣層形成於該表面及該複數個內側壁上。 The photoelectric element as described in claim 4 of the scope of the patent application, wherein the epitaxial stack includes a surface, the second semiconductor layer surrounding the plurality of inner exposed regions includes a plurality of inner sidewalls connecting the surface, and the insulating layer is formed on on the surface and the plurality of inner sidewalls. 如申請專利範圍第1項所述的光電元件,其中該複數個第一開口之另一部分位於該周圍裸露區域之另一部分上,其中該周圍裸露區域之該另一部分鄰近該複數個第一邊界之另一,該複數個第一邊界之該另一鄰近該複數個第二邊界之另一,該複數個邊緣之另一鄰近該複數個第二邊界之該另一,該複數個邊緣之該另一包含一或多個第二凹部位於該第一電極上且位於該複數個第二邊界之該另一內,該複數個邊緣之該另一包含一或多個第二凸部凸出於該一或多個第二凹部且超出該複數個第二邊界之該另一以經由該複數個第一開口之該另一部分電性連接該第一半導體層。 The photoelectric element described in claim 1, wherein another part of the plurality of first openings is located on another part of the surrounding exposed area, wherein the other part of the surrounding exposed area is adjacent to the plurality of first boundaries In addition, the other of the plurality of first boundaries is adjacent to the other of the plurality of second boundaries, the other of the plurality of edges is adjacent to the other of the plurality of second boundaries, and the other of the plurality of edges one comprising one or more second recesses located on the first electrode and within the other of the plurality of second boundaries, the other of the plurality of edges comprising one or more second protrusions protruding from the One or more second recesses and beyond the other of the plurality of second boundaries are electrically connected to the first semiconductor layer through the other part of the plurality of first openings. 如申請專利範圍第1項所述的光電元件,其中該複數個第一開口之該部分的開口數目大於該複數個第一開口之該另一部分的開口數目。 The optoelectronic element as described in claim 1 of the patent claims, wherein the number of openings in the part of the plurality of first openings is greater than the number of openings in the other part of the plurality of first openings. 如申請專利範圍第1項所述的光電元件,其中自上視觀之,該第三電極之一上視面積小於該第二電極之一上視面積。 The optoelectronic element as described in claim 1, wherein viewed from above, a top view area of the third electrode is smaller than a top view area of the second electrode. 如申請專利範圍第1項所述的光電元件,其中該第二電極之一邊界與該第三電極之一邊界之間具有一最小距離大於50μm。 The photoelectric element as described in claim 1, wherein a minimum distance between a boundary of the second electrode and a boundary of the third electrode is greater than 50 μm .
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