KR20090061909A - Composition and preparation method of environmentalfriendly fishing weight - Google Patents

Composition and preparation method of environmentalfriendly fishing weight Download PDF

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KR20090061909A
KR20090061909A KR1020070128915A KR20070128915A KR20090061909A KR 20090061909 A KR20090061909 A KR 20090061909A KR 1020070128915 A KR1020070128915 A KR 1020070128915A KR 20070128915 A KR20070128915 A KR 20070128915A KR 20090061909 A KR20090061909 A KR 20090061909A
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South Korea
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protective film
ceramic
manufacturing
alcohol
shape
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KR1020070128915A
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Korean (ko)
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KR100926038B1 (en
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허성관
신재은
김해성
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허성관
신재은
김해성
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K75/00—Accessories for fishing nets; Details of fishing nets, e.g. structure
    • A01K75/06—Sinkers
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C04B41/87—Ceramics
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21—LIGHTING
    • F21V—FUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
    • F21V33/00—Structural combinations of lighting devices with other articles, not otherwise provided for
    • F21V33/008—Leisure, hobby or sport articles, e.g. toys, games or first-aid kits; Hand tools; Toolboxes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Environmental Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Wood Science & Technology (AREA)
  • Animal Husbandry (AREA)
  • Marine Sciences & Fisheries (AREA)
  • Structural Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Paints Or Removers (AREA)

Abstract

A method for manufacturing an environmentally friendly sinker of a fishing net, and a device for manufacturing an environmentally friendly sinker for a fishing net are provided to improve durability by forming the anticorrosive protection layer. A method for manufacturing an environmentally friendly sinker for a fishing net comprises the steps of washing an iron pipe with a diameter of 0.5~10cm and a length of 1.0~10cm with an alcohol to remove the contaminant; molding the iron pipe into a sinker shape in a compression molder; sanding the molded one with the sand of 80~120 mesh to the roughness of 5~10 micrometers so as to form the micro-unevenness on the surface; washing the sanded surface with a mixture of water and an alcohol, drying it, hanging it to a hanger equipped with an elastic unit, and dipping it in a ceramic paint solution to form a protection layer having a thickness of 25~50 micrometers; naturally drying the obtained product and baking it in a kiln at 150~250°C for 15~30 min; and wrapping it with a vinyl material to stabilize the ceramic protection layer for 3~5 days.

Description

친환경 어망추의 제조방법 및 그 제조장치{Composition and Preparation Method of EnvironmentalFriendly Fishing Weight}Composition and Preparation Method of Environmentally Friendly Fishing Nets {@Composition and Preparation Method of EnvironmentalFriendly Fishing Weight}

본 발명은 친환경 어망추를 공급하기 위한 제조방법 및 그 제조장치에 관한 것이다.The present invention relates to a manufacturing method for supplying eco-friendly fishing nets and a manufacturing apparatus thereof.

종래의 어망추는 납으로 제조되어 있으므로 내구성이 약해 마모가 용이하고 납 성분이 화합물로부터 분해되어 환경에 노출되었을 때 그 독성이 없어지지 않으며 인체에 오염되면 오랜 시간이 지난후 그 독성이 나타나므로 발병했을 때는 치명적이 되는 문제가 있다.Conventional fishing nets are made of lead, so they have low durability and are easy to wear. When lead is decomposed from compounds and exposed to the environment, its toxicity is not lost. If it is contaminated with human body, its toxicity appears after a long time. There is a problem of becoming fatal.

특히, 사람이 납중독에 걸리면 뇌와 신경계통에 지장을 초래하여 정신이상, 신체마비, 빈혈, 구토가 일어나는 증상을 보이며 심한 경우 사망할 수도 있다.In particular, when lead poisoning causes a disorder in the brain and nervous system, it can cause mental disorders, physical paralysis, anemia, vomiting, and death in severe cases.

특히 어린이가 납중독에 걸리면 비록 소량일지라도 그 폐해가 크다.In particular, if a child has lead poisoning, even in small quantities, the harm is great.

특히, 우리나라는 납중독에 대한 경각심이 낮은 편으로 체계적인 연구도 부족하여 이미 수질과 토양에 납성분이 오염되어 심한 상태에 와 있으므로 이를 더 이상 방치할 수 없는 시점에 있다.In particular, Korea is low in awareness of lead poisoning, and there is a lack of systematic research. Therefore, the contamination of lead components in water quality and soil is already in severe condition.

본 발명은 상기와 같은 문제점을 해결하기 위해 유해물이 발생되지 않는 친환경 어망추를 개발한 것이다.The present invention has been developed an eco-friendly fishing net that does not generate harmful to solve the above problems.

본 발명은 어망추의 소재를 철제로 하고 그 외면전체에 세라믹 또는 PVA와 같은 친환경 보호피막을 형성하여 보호함으로써 인체에 유해한 납성분이 발생하지 않는 내구적인 어망추가 되게 한 것이다.The present invention is made of a fishing net made of iron and by forming an environmentally friendly protective film such as ceramic or PVA on the entire outer surface of the fishing net is made of durable fishing nets that do not generate harmful lead components.

이와 같이 된 본 발명은 세라믹도료가 솔-겔푸로세스에 의하여 제조된 고순도 세라믹체를 목적으로 하는 산화물용 금속알콕사이드 금속, 아세탈 아세드네트화합물을 탈 이온수로 가수분해 중합반응을 한 조성체로 금속기재에 세라믹 막이 치밀하게 이루어지는 포리머인바 Si-0 결합을 가진 화합물(Si CoC2H5)4를 기본유니트로 하여 초순수물에 가용한 용액이므로 대기중의 저온소성(150℃범위)에서 산소와 반응하여 치밀한 고순도 Cilica(아몰파스 Si02)막을 형성하여 불활성분위기중에서 고온소성(450℃)에 의한 탈수소반응을 하여 열경화후 아몰파스 규소세라믹으로 자화하고 자연경화성 저온소성형의 환경친화적인 기능성 세라믹도료에 의한 보호피막을 형성하므로 15~10미크론 두께로 금속표면의 산화방지, 부식방지 기능을 가지는 보호피막을 형성할 수 있고 25~50미크론 도장작업을 함으로써 염수에서도 추본체를 완벽하게 보호하므로 내구적인 제품을 얻게 되며 인체에 해가 없는 추를 만들 수 있다.Thus, the present invention is a ceramic material is a metal-based composition for the hydrolysis polymerization of a metal alkoxide metal oxide, acetal acetnet compound for the purpose of the high-purity ceramic body manufactured by sol-gel furoseses with deionized water on because the ceramic film is densely formed by the Polymer-environment Si-0 compound having a binding (Si CoC 2 H 5) 4 to the main unit, usable in ultra pure water solution reacts with oxygen in the low-temperature co-fired (range 150 ℃) in the air Formed high purity Cilica (Amorphas Si0 2 ) film, dehydrogenation by high temperature baking (450 ℃) in inert atmosphere, magnetized into amorphous silicon ceramic after thermosetting, As a protective film is formed, it is possible to form a protective film having a function of preventing oxidation and corrosion of a metal surface with a thickness of 15 to 10 microns. And 25 to 50 microns by the painting because it fully protects the body weight in saline and get a durable product can make the weight without harm to the human body.

또한, 본 발명은 도막의 평활성 방수성이 우수하고 비교적 낮은 온도에서 작업이 되므로 에너지를 절약할 수 있고 형광,야광과 같은 발광물질이 포함되어 그물추를 수거하기 좋은 이점이 있으며 In addition, the present invention has excellent smoothness and waterproofness of the coating film and can be saved at a relatively low temperature to save energy and includes a light-emitting material such as fluorescence, luminous, there is a good advantage to collect the net weight

또한, 본 발명은 표면코팅제로 PVA를 병용할 수 있으므로 납성분에 의한 피해가 없는 친환경 그물추를 보다 저렴하게 만들 수 있도록 되는 효과가 있다.In addition, the present invention can be used in combination with the surface coating agent PVA, there is an effect that can be made more eco-friendly net weight without damage caused by the lead component.

특히, 본 발명은 철재관을 추길이에 대응하는 길이로 절단하여 압착성형기에 넣고 추형상을 제조하고 샌딩처리하여 세라믹도료를 침지 도장하기 때문에 도장두께를 25~50미크론까지 도포할 수 있고, 행거를 추모양 구멍에 끼워서 매달아 도장하고 인출하여 진동시키기 때문에 균등한 도장이 이루어지며 열처리후에 도장면이 평활면을 유지하므로 치밀한 도장이 가능케 되어 내구적인 제품이 되고 도장장치에 이어 소성처리까지 용이하므로 능률적인 제작이 이루어지고 친환경적인 그물추를 량산할 수 있는 효과를 얻는 것이다.In particular, the present invention is to cut the steel pipe to the length corresponding to the weight length, put into the compression molding machine to manufacture the weight shape and sanding process to apply the coating paint immersed in ceramic paint, the coating thickness can be applied to 25-50 microns, hangers Is applied by hanging it in the shape of a hole and painting it, drawing it out and vibrating it so that even coating is made. After the heat treatment, the coating surface maintains a smooth surface, so it is possible to make a dense coating and become a durable product. Phosphorus production is made and it is possible to produce eco-friendly net weight.

본 발명은 일정 직경(d)과 길이를 가지는 철재관을 추모양(1)으로 성형하고 그 표면전체에 세라믹도료나 PVC와 같은 친환경 소재의 보호막(2)을 형성하여서 되는 것을 특징으로 한다.The present invention is characterized by forming a steel tube having a certain diameter (d) and length in the shape of a weight (1) and forming a protective film (2) of an environmentally friendly material such as ceramic paint or PVC on its entire surface.

이를 위해 본 발명은 직경(d) 0.5~10cm 길이(ℓ)1.0~10cm되는 철재관을 알콜로 세척하여 오염물을 제거하는 준비단계와 To this end, the present invention is the preparatory step of removing contaminants by washing the steel pipe (d) 0.5 ~ 10cm length (ℓ) 1.0 ~ 10cm with alcohol with alcohol

오염물이 제거된 철재관을 압착성형기(4)에 넣어 추모양(1)으로 성형하는 성형단계와 Molding step of putting the contaminant-removed steel pipe into the compression molding machine (4) to form a weight (1) and

추모양(1)으로 성형된 소재를 80~120메쉬의 모래로 5~10마이크로 조도론 샌딩하여 표면에 미세요철을 만드는 표면처리단계와 The surface treatment step of sanding the material formed into the shape of the vertebrae (1) with sand of 80 to 120 mesh with 5 to 10 micro roughness of sand to make fine roughness on the surface;

샌딩된 표면을 물과 알코올의 혼합물로 세척하여 건조시키는 전처리공정을 실시하고 전처리 공정이 완료된 성형물을 신축수단이 구비된 행거(3)에 매달아서 30~40℃되는 세라믹도료(상품명 LIQUID CERAMIC YP-100W) 용액조에 침지하여 외면전체에 25~50미크론의 세라믹도료 보호막을 형성하고 인출하여 진동시키는 도장단계와 Perform the pretreatment process of washing the sanded surface with a mixture of water and alcohol, and drying the finished product, and suspending the molded product on the hanger (3) equipped with the expansion means (30 ~ 40 ℃). Ceramic paint (trade name LIQUID CERAMIC YP-) 100W) The coating step of immersing in the solution tank to form a protective film of 25 ~ 50 micron ceramic coating on the entire outer surface, and to take out and vibrate

세라믹보호막이 형성된 제품을 자연건조시킨 후 소성로에서 150~250℃에서 15~30분간 소부하는 소성단계를 거쳐 세라믹 보호막을 경화시키고 비닐지로 감싸서 3~5일간 안정화시키는 숙성단계를 거쳐 어망추를 완성하게 된다.After drying the product on which the ceramic protective film is formed, it is baked in a firing furnace at 150-250 ℃ for 15-30 minutes, and then, the ceramic protective film is cured and wrapped in plastic paper to be aged for 3-5 days to complete the fishing net. .

한편, 본 발명은 상기 제조공정에서 제조된 제품을 PVA(폴리비닐알콜)용액에 침지한후 인출하여 건조시키므로서 성형물 표면에 PVA피막을 더 형성하여 제조하는 것이 포함되고 On the other hand, the present invention includes the production by further forming a PVA film on the surface of the molding by immersing the product produced in the manufacturing process in PVA (polyvinyl alcohol) solution and then withdrawn and dried.

또한, 본 발명은 세라믹도료 또는 PVA용액에 발광물질을 혼합하여서 제품이 발광기능을 갖도록 제조되는 것을 포함한다.In addition, the present invention includes the manufacture of a product having a light emitting function by mixing a light emitting material in a ceramic paint or PVA solution.

한편, 본 발명은 0.5~10cm의 직경(d)과 1.0~10cm의 길이(ℓ)를 가지는 철재관을 준비하는 준비부와 On the other hand, the present invention and the preparation unit for preparing a steel pipe having a diameter (d) of 0.5 ~ 10cm and the length (l) of 1.0 ~ 10cm and

압착성형기(4)에 투입하여 추형상으로 성형하는 압착성형부와 추형상의 성형물을 80~120메쉬의 모래로 5~10마이크론 조도로 샌딩하여 표면에 미세요철을 형성하는 샌딩부와 The compression molding part which is put into the compression molding machine 4 and formed into a weight shape, and the sanding part which forms a fine roughness on the surface by sanding the shaped body with sand of 80 to 120 mesh with 5 to 10 micron roughness;

샌딩된 성형물을 신축장치가 구비된 행거(3)에 걸어서 세라믹도료용액(5)에 침지하여 25~50미크론의 보호막을 형성하고 인출하여 진동시키는 보호막 도장부와 The sanded molding is hung on the hanger (3) equipped with the stretching device to immerse in the ceramic paint solution (5) to form a protective film of 25-50 microns, and withdraws and vibrates the protective film coating portion;

보호막도장부를 30℃에서 5~7일간 건조시키는 자연건조부와 Natural drying part that dries the protective coating at 30 ℃ for 5-7 days

세라믹도료가 건조된 제품을 150~250℃에서 15~30분간 소부처리하는 소성부와 Firing part for baking the dried ceramic paint at 150 ~ 250 ℃ for 15 ~ 30 minutes

세라믹보호막이 소부처리된 제품을 비닐지로 감싸서 3~5일간 세라믹 보호막을 안정시키는 숙성처리부를 갖춘 제조장치에 의하여 제조되는 것을 특징으로 한다.It is characterized in that the ceramic protective film is manufactured by a manufacturing apparatus equipped with a aging treatment unit for stabilizing the ceramic protective film for 3 to 5 days by wrapping the product processed by baking.

도 1은 본 발명의 어망추 제조용 철재관 사시도1 is a perspective view of the steel pipe manufacturing fishing net of the present invention

도 2는 본 발명의 어망추 성형기 예시도Figure 2 is an illustration of a fishing net molding machine of the present invention

도 3은 본 발명의 어망추 성형물을 샌드브라스트한 예시도Figure 3 is an illustration of sandblasting fishing net moldings of the present invention

도 4는 본 발명의 세라믹도료 도장부 예시도Figure 4 is an illustration of a ceramic paint coating portion of the present invention

도 5는 본 발명의 제품 단면도5 is a cross-sectional view of the product of the present invention

도 6은 본 발명의 제조장치 공정도이다.6 is a manufacturing process diagram of the present invention.

* 도면의 주요부분에 대한 부호설명* Explanation of symbols on the main parts of the drawings

1 : 추모양 2 : 친환경보호막1: Shape 2: Eco-friendly protective film

3 : 행거 4 : 압착성형기3: hanger 4: press molding machine

5 : 세라믹도료용액 d : 직경5: ceramic paint solution d: diameter

ℓ: 길이ℓ: length

Claims (4)

직경(d) 0.5~10cm 길이(ℓ)1.0~10cm 되는 철재관을 준비하여 알콜로 세척하고 오염물을 제거하는 준비단계와 (D) preparing a steel pipe with a diameter of 0.5 to 10 cm (ℓ) 1.0 to 10 cm, washing it with alcohol and removing contaminants; 오염물이 제거된 철재관을 압착성형기(4)에 넣어 추모양(1)으로 성형하는 성형단계와 Molding step of putting the contaminant-removed steel pipe into the compression molding machine (4) to form a weight (1) and 추모양(1)으로 성형된 소재를 80~120메쉬의 모래로 5~10마이크로 조도론 샌딩하여 표면에 미세요철을 만드는 표면처리단계와 The surface treatment step of sanding the material formed into the shape of the vertebrae (1) with sand of 80 to 120 mesh with 5 to 10 micro roughness of sand to make fine roughness on the surface; 샌딩된 표면을 물과 알코올의 혼합물로 세척하여 건조시키는 전처리공정을 실시하고 전처리 공정이 완료된 성형물을 신축수단이 구비된 행거(3)에 매달아서 30~40℃ 되는 세라믹도료(상품명 LIQUID CERAMIC YP-100W) 용액(5)에 침지하여 25~50미크론의 두께 보호막을 형성하는 도장단계와 Perform the pretreatment process of washing the sanded surface with a mixture of water and alcohol and drying it, and suspend the molded product on a hanger (3) equipped with expansion means to hang the ceramic paint at 30 ~ 40 ℃ (trade name LIQUID CERAMIC YP-). 100W) a coating step of immersing in the solution (5) to form a protective film of 25 ~ 50 microns thick and 세라믹 보호막이 형성된 제품을 자연건조시켜서 소성로에서 150~250℃에서 15~30분간 소부하는 소성단계와 Firing step of baking the product on which ceramic protective film is formed by natural drying and baking it at 150 ~ 250 ℃ for 15 ~ 30 minutes in the kiln. 소성단계를 거친 제품을 비닐지로 감싸서 3~5일간 세라믹 보호막을 안정화시키는 숙성단계를 거쳐 제조되는 친환경 어망추의 제조방법Manufacturing method of eco-friendly fishing nets manufactured by aging step of stabilizing ceramic protective film by wrapping the product after firing with plastic paper 청구항 제1항에서,In claim 1, 표면보호막은 세라믹보호막의 외면에 PVA(폴리비닐알콜)피막이 더 형성되게 하여 제조하는 것을 포함하는 친환경 어망추의 제조방법 Surface protective film is a method of manufacturing an environmentally friendly fishing net including manufacturing the PVA (polyvinyl alcohol) film is further formed on the outer surface of the ceramic protective film 청구항 제1항에서,In claim 1, 보호막은 세라믹도료 또는 PVA용액에 발광물질을 더 혼합하여서 제조되는 것을 포함하는 친환경 어망추의 제조방법The protective film is a manufacturing method of environmentally friendly fishing nets, which is prepared by further mixing the light emitting material with ceramic paint or PVA solution 0.5~10cm의 직경(d)과 1.0~10cm의 길이(ℓ)를 가지는 철재관을 알콜로 세척하여 오염물을 제거하는 준비부와 The preparation unit for removing contaminants by washing the steel pipe having a diameter (d) of 0.5 ~ 10cm and the length (l) of 1.0 ~ 10cm with alcohol and 철재관을 압착성형기(4)에 넣어 추형상으로 성형하는 성형부와 추형상의 성형물을 80~120메쉬의 모래로 5~10마이크론 조도로 샌딩하여 표면에 미세요철을 형성하는 샌딩부와 The molding part which puts a steel pipe into the compression molding machine 4, and shape | molds it in the shape of a cone, and the sanding part which forms a fine roughness on the surface by sanding the shape of the shape of the cone with sand of 80-120 mesh with 5-10 micron roughness; 샌딩된 성형물을 신축장치가 구비된 행거에 걸어서 30~40℃의 세라믹도료로 용액내에 침지하여 25~50미크론의 보호막을 형성하고 인출하여 진동시키는 보호막 도장부와 The sanded moldings are hung on a hanger equipped with a stretching device and immersed in a solution with a ceramic paint of 30-40 ° C. to form a protective film of 25-50 microns, and withdrawn by vibrating a protective film. 보호막이 형성된 제품을 도장부에서 인출하여 30℃에서 5~7일간 자연건조시키는 자연건조부와 세라믹도료가 건조된 제품을 150~250℃에서 15~30분간 소부처리하는 소성로와 The natural drying part which draws the product with the protective film from the coating part and naturally dry it at 30 ℃ for 5 ~ 7 days, and the firing furnace which bakes the product dried ceramic paint at 150 ~ 250 ℃ for 15 ~ 30 minutes. 소부처리된 제품을 비닐지로 감싸서 3~5일간 세라믹보호막을 안정시키는 숙 성부를 갖추어서 되는 친환경 어망추의 제조장치A device for manufacturing eco-friendly fishing nets, which is equipped with a maturing part to stabilize the ceramic protective film for 3 to 5 days by wrapping the baked part with plastic paper.
KR1020070128915A 2007-12-12 2007-12-12 Composition and Preparation Method of EnvironmentalFriendly Fishing Weight KR100926038B1 (en)

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