JP4718141B2 - 薄膜形成方法及び薄膜形成装置 - Google Patents
薄膜形成方法及び薄膜形成装置 Download PDFInfo
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- 239000010409 thin film Substances 0.000 title claims description 52
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
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- 229910000856 hastalloy Inorganic materials 0.000 description 1
- -1 hydrogen ions Chemical class 0.000 description 1
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- 238000004518 low pressure chemical vapour deposition Methods 0.000 description 1
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- C23C16/45525—Atomic layer deposition [ALD]
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- C23C16/45536—Use of plasma, radiation or electromagnetic fields
- C23C16/45542—Plasma being used non-continuously during the ALD reactions
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- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
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- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
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- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/314—Inorganic layers
- H01L21/3141—Deposition using atomic layer deposition techniques [ALD]
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
- H01L21/0226—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process
- H01L21/02263—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase
- H01L21/02271—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition
- H01L21/0228—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition deposition by cyclic CVD, e.g. ALD, ALE, pulsed CVD
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Description
12 ガス供給ライン
14 ガス供給部
16 プラズマ発生部
18 排気ライン(排気路)
20 真空ポンプ
22 コンダクタンスバルブ
24 圧力制御部
26 バルブコントローラ
28 圧力検出器
30 バルブ駆動部
32 バルブ開度検出部
34 バルブ開度同定部
36 主制御部
40 サセプタ
46 シャワーヘッド部
Claims (27)
- 減圧可能な処理容器と真空ポンプとを結ぶ排気路にコンダクタンスバルブを設け、前記処理容器内に被処理基板を配置して、成膜処理時間中に第1の反応ガスを供給する第1のステップと第2の反応ガスを供給する第2のステップとを含むサイクルを1回または複数回繰り返して、前記基板上に前記第1の反応ガスと前記第2の反応ガスとの化学反応を利用して膜を形成する薄膜形成方法であって、
前記成膜処理時間の開始に先立つ準備時間中に、前記処理容器内を排気しながら所望のガスを設定流量で前記処理容器内に供給し、前記処理容器内の圧力が設定値にほぼ一致するときの前記コンダクタンスバルブのバルブ開度を同定して基準値とする第1の工程と、
前記成膜処理時間中の各々の前記サイクルにおいて少なくとも前記第1および第2のステップ中は前記コンダクタンスバルブのバルブ開度を前記基準値に保持する第2の工程と
を有する薄膜形成方法。 - 1サイクル内で前記第1の反応ガスと前記第2の反応ガスとの化学反応により前記基板上で1原子または1分子の層を成長させ、サイクルの繰り返し回数に応じた膜厚の薄膜を前記基板上に形成する、請求項1に記載の薄膜形成方法。
- 前記準備時間が、前記処理容器に前記基板が入っていない時間帯に設定される、請求項1または請求項2に記載の薄膜形成方法。
- 前記準備時間が、前記処理容器に前記基板が搬入された後の時間帯に設定される、請求項1または請求項2に記載の薄膜形成方法。
- 前記準備時間中に、前記第1および第2の反応ガスの少なくとも一方を含む圧力調整用のガスを前記成膜処理時と同等のガス流量で前記処理容器内に供給する、請求項1〜4のいずれか一項に記載の薄膜形成方法。
- 前記第1の反応ガスが前記薄膜の原料を化合物として含む原料ガスであり、前記第2のガスが前記化合物を還元する還元ガスである、請求項5に記載の薄膜形成方法。
- 前記第2の反応ガスを前記処理容器内でプラズマ励起してラジカルおよび/またはイオンを生成する、請求項6に記載の薄膜形成方法。
- 各々の前記サイクルが、前記第1のステップの直後に余分な前記第1の反応ガスを前記処理容器から排出する第3のステップを含む、請求項1〜7のいずれか一項に記載の薄膜形成方法。
- 前記第3のステップで不活性ガスを含むパージガスを前記処理容器内に供給する、請求項8に記載の薄膜形成方法。
- 前記第3のステップ中も前記コンダクタンスバルブのバルブ開度を前記基準値に保持する、請求項8または請求項9に記載の薄膜形成方法。
- 前記第3のステップ中は前記コンダクタンスバルブのバルブ開度を最大値付近に切り換える、請求項8または請求項9に記載の薄膜形成方法。
- 各々の前記サイクルが、前記第2のステップの直後に余分な前記第2の反応ガスを前記処理容器から排出する第4のステップを含む、請求項1〜11のいずれか一項に記載の薄膜形成方法。
- 前記第4のステップで不活性ガスを含むパージガスを前記処理容器内に供給する、請求項12に記載の薄膜形成方法。
- 前記第4のステップ中も前記コンダクタンスバルブのバルブ開度を前記基準値に保持する、請求項12または請求項13に記載の薄膜形成方法。
- 前記第4のステップ中は前記コンダクタンスバルブのバルブ開度を最大値付近に切り換える、請求項12または請求項13に記載の薄膜形成方法。
- 前記第1の工程が、
前記処理容器内の圧力の検出値が前記設定圧力に一致するように圧力フィードバック方式で前記コンダクタンスバルブのバルブ開度を可変制御する第3の工程と、
前記第3の工程中に前記コンダクタンスバルブのバルブ開度を測定する第4の工程と
を有する、請求項1〜15のいずれか一項に記載の薄膜形成方法。 - 前記第4の工程が前記準備期間の終了間際に行われる、請求項16に記載の薄膜形成方法。
- 前記第4の工程が、前記コンダクタンスバルブのバルブ開度の瞬時値を一定の時間間隔でサンプリングし、n個(nは自然数)のサンプル値の平均をとる第5の工程を含む、請求項16または請求項17に記載の薄膜形成方法。
- 前記第5の工程が、
前記一定の時間間隔毎に新たなサンプル値をそれまでの連続するn個(nは自然数)のサンプル値に加えると同時にそれらn+1個の中で最も古いサンプル値を除外する第6の工程と、
前記第6の工程における入れ替え後の連続するn個のサンプル値について相加平均を求める第7の工程と
を有する、請求項18に記載の薄膜形成方法。 - 前記第2の工程が、
前記コンダクタンスバルブのバルブ開度を検出する第8の工程と、
前記バルブ開度の検出値を前記基準値と比較して比較誤差を求める第9の工程と、
前記比較誤差に応じて前記コンダクタンスバルブのバルブ開度を可変制御する第10の工程と
を有する、請求項1〜19のいずれか一項に記載の薄膜形成方法。 - 前記準備期間中に前記基板を設定温度まで加熱し、前記成膜処理時間中も前記基板の温度を前記設定温度に保つ、請求項4〜20のいずれか一項に記載の薄膜形成方法。
- 前記第1の工程で、前記処理容器に少なくとも前記第1の反応ガスを含む第1の圧力調整用ガスを供給して前記処理容器内の圧力が第1の設定値にほぼ一致するときの前記コンダクタンスバルブのバルブ開度を同定して第1の基準値とするとともに、前記処理容器に少なくとも前記第2の反応ガスを含む第2の圧力調整用ガスを供給して前記処理容器内の圧力が第2の設定値にほぼ一致するときの前記コンダクタンスバルブのバルブ開度を同定して第2の基準値とし、
前記第2の工程で、前記第1のステップ中は前記コンダクタンスバルブのバルブ開度を前記第1の基準値に保持し、前記第2のステップ中は前記コンダクタンスバルブのバルブ開度を前記第2の基準値に保持する、
請求項1に記載の薄膜形成方法。 - 減圧可能な処理容器と真空ポンプとを結ぶ排気路にコンダクタンスバルブを設け、前記処理容器内に被処理基板を配置して、成膜処理時間中に第1の反応ガスを供給するステップと第2の反応ガスを供給するステップとを含むサイクルを1回または複数回繰り返して、前記基板上に前記第1の反応ガスと前記第2の反応ガスとの化学反応を利用して膜を形成する薄膜形成装置であって、
前記処理容器内の圧力を設定値に一致させるように圧力フィードバック方式で前記コンダクタンスバルブのバルブ開度を可変制御するための自動圧力制御部と、
前記処理容器内の圧力が設定値にほぼ一致するときの前記コンダクタンスバルブのバルブ開度を同定して基準値とするバルブ開度同定部と、
前記コンダクタンスバルブのバルブ開度を前記基準値に保持するためのバルブ開度ホールド部と
を有する薄膜形成装置。 - 前記バルブ開度同定部が、
前記自動圧力制御部により前記コンダクタンスバルブのバルブ開度が可変制御されている最中に前記コンダクタンスバルブのバルブ開度を検出して一定の時間間隔でサンプリングするサンプリング部と、
前記サンプリング部より前記一定の時間間隔毎に与えられるサンプル値を先入れ先出し方式で一時にn個(nは自然数)蓄積するFIFOバッファメモリと、
前記FIFOバッファメモリに蓄積されているn個のサンプル値について前記一定の時間間隔毎に相加平均を求める演算部と、
前記演算部で前記一定の時間間隔毎に得られる相加平均値を所望のタイミングで取り込んで前記基準値とする基準値決定部と
を有する、請求項23に記載の薄膜形成装置。 - 前記バルブ開度ホールド部が、
前記コンダクタンスバルブのバルブ開度を可変するバルブ駆動部と、
前記コンダクタンスバルブのバルブ開度の瞬時値を検出するバルブ開度検出部と、
前記バルブ開度の瞬時値を前記基準値と比較して比較誤差を生成する比較部と、
前記比較誤差に応じて前記バルブ駆動部を制御するバルブ制御部と
を有する、請求項23または請求項24に記載の薄膜形成装置。 - 前記処理容器内で前記第1および第2の反応ガスの少なくとも一方をプラズマ状態にするためのプラズマ発生部を有する、請求項23〜25のいずれか一項に記載の薄膜形成装置。
- 1サイクル内で前記第1の反応ガスと前記第2の反応ガスとの化学反応により前記基板上で1原子または1分子の層を成長させ、サイクルの繰り返し回数に応じた膜厚の薄膜を前記基板上に形成する、請求項23〜26のいずれか一項に記載の薄膜形成装置。
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US20080050538A1 (en) | 2008-02-28 |
WO2006013720A1 (ja) | 2006-02-09 |
CN1993496A (zh) | 2007-07-04 |
CN100523291C (zh) | 2009-08-05 |
US7972649B2 (en) | 2011-07-05 |
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