JP2002322001A - Feeding type insect pest-controlling composition - Google Patents
Feeding type insect pest-controlling compositionInfo
- Publication number
- JP2002322001A JP2002322001A JP2002047926A JP2002047926A JP2002322001A JP 2002322001 A JP2002322001 A JP 2002322001A JP 2002047926 A JP2002047926 A JP 2002047926A JP 2002047926 A JP2002047926 A JP 2002047926A JP 2002322001 A JP2002322001 A JP 2002322001A
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- JP
- Japan
- Prior art keywords
- fatty acid
- component
- hydroxy group
- arthropods
- terrestrial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は有害な陸棲・水棲軟
体動物、等脚目節足動物を対象とする摂食性害虫駆除剤
組成物、およびその摂食性害虫駆除組成物を使用する駆
除方法に関する。[0001] The present invention relates to a composition for controlling pesticidal insect pests against harmful terrestrial and aquatic molluscs and arthropod arthropods, and a method of controlling the composition using the composition. .
【０００２】[0002]
【従来の技術】害虫駆除を目的として、駆除有効成分に
各種の穀物粉末などを加えて誘引性を向上させた各種の
摂食性害虫駆除組成物（以後、ベイト剤と略称する）が
知られている。屋外に散布した際に短期間で薬効がなく
なることを防ぐために、メタアルデヒドをカラギーナン
などのゲル化剤、水およびこれらをｐＨ７〜１０に調整
するｐＨ調整剤を必須成分とするゲル状、さらにはマイ
クロカプセル化した殺虫性化合物をも含有するゲル状の
ナメクジ駆除剤（特開平５−２８６８１０号公報）が開
示されている。しかしこの方法は逆にメタアルデヒドが
発散しにくくなるので、速効性が不足する。ゲル状にし
なくても済むように、ナメクジ類の捕獲器を併用する方
法（特開平８−１７５９０６号公報）も開示されている
が、専用の捕獲器が別に必要となってしまう。2. Description of the Related Art For the purpose of controlling pests, various ingestible pest control compositions (hereinafter abbreviated as bait) have been known, in which various cereal powders are added to an active control ingredient to improve attraction. I have. In order to prevent the medicinal effect from disappearing in a short period of time when sprayed outdoors, a gel form in which metaldehyde is a gelling agent such as carrageenan, water and a pH adjusting agent for adjusting these to pH 7 to 10 as an essential component, A gel slug repellent containing a microencapsulated insecticidal compound (JP-A-5-286810) is disclosed. However, in this method, on the other hand, the meta-aldehyde is less likely to emanate, so that the rapid effect is insufficient. Although a method using a trapper for slugs is also disclosed so as to eliminate the need for gelling (Japanese Patent Laid-Open No. 8-175906), a dedicated trapper is additionally required.
【０００３】誘引性、摂食性を向上させる工夫もなさ
れ、油カス、米ぬか、小麦粉を誘引性の餌として使用す
るベイト剤（特開平３−２１０４号公報）、さらに誘引
性の餌が賦形剤をも兼ねている酒粕を用いたことを特徴
とするベイト剤（特開平１０−２５２０７号公報）が開
示されている。しかし、有害な陸棲・水棲軟体動物、等
脚目節足動物は、摂食性害虫駆除剤有効成分に対して、
自身の体内に強力な解毒機構を持つ事が知られている。
具体的には、少量でも摂食性害虫駆除有効成分が体内に
取り込まれると、粘液分泌機構が刺激され、それら毒物
を体外へと排出してしまう。結果的に簡単なマヒ行動を
示すのみであり、完全駆除には至らないという問題点が
ある。[0003] Baits using oil scum, rice bran, or flour as an attractive bait (JP-A-3-2104), and an attractive bait are used as excipients. A bait (Japanese Patent Application Laid-Open No. 10-25207) characterized by using sake lees that also serves as a bait is disclosed. However, harmful terrestrial and aquatic molluscs, arthropod arthropods,
It is known that it has a powerful detoxification mechanism in its own body.
Specifically, when a small amount of the active ingredient for controlling pests is taken into the body, the mucus secretion mechanism is stimulated, and the toxic substances are discharged outside the body. As a result, there is a problem that it only shows simple paralysis and does not lead to complete eradication.
【０００４】[0004]
【発明が解決しようとする課題】酒粕のような成分を多
量に含むベイト剤を散布等した状態で、長期間にわたっ
て放置することは環境上好ましくなく、また、速効性を
求めて害虫駆除有効成分量を増加させると、製造コスト
が上昇し、環境上も好ましくない。It is environmentally unfavorable to leave a bait containing a large amount of a component such as sake lees in a sprayed state for a long period of time. Increasing the amount increases production costs and is environmentally unfavorable.
【０００５】本発明は、専用の捕獲器等を必要とせず、
より少ない害虫駆除有効成分含有量で高い駆除効果を発
現する、製造コストを低く抑えた、環境上も悪影響の少
ない、有害な陸棲・水棲軟体動物、等脚目節足動物用の
摂食性害虫駆除組成物を提供することを目的としてい
る。また本発明は、専用の捕獲器等を必要とせず、より
少ない害虫駆除有効成分含有量で高い駆除効果を発現す
る、製造コストを低く抑えた、環境上も悪影響の少な
い、有害な陸棲・水棲軟体動物、等脚目節足動物駆除方
法を提供することを目的としている。[0005] The present invention does not require a dedicated trap or the like,
Exterminate pests for harmful terrestrial and aquatic molluscs and arthropod arthropods, exhibiting high pesticidal effects with less active ingredient content, low production cost, low environmental impact It is intended to provide a composition. In addition, the present invention does not require a special trap, etc., and exhibits a high pesticidal effect with a smaller pest control active ingredient content, has a low production cost, has a low environmental impact, and is harmful to terrestrial and aquatic organisms. It is an object of the present invention to provide a method for controlling mollusks and arthropods.
【０００６】[0006]
【課題を解決するための手段】本発明者らは、駆除有効
成分と脂肪酸類やその塩類とを組み合わせて用いると、
予想外の相乗効果を示して有害な陸棲・水棲軟体動物、
等脚目節足動物を確実に駆除できることを見いだし、本
発明を完成するに至った。Means for Solving the Problems When the present inventors use a combination of an exterminating active ingredient and a fatty acid or a salt thereof,
Harmful terrestrial and aquatic mollusks that exhibit unexpected synergies
The present inventors have found that arthropods of the same order can be eliminated reliably and have completed the present invention.
【０００７】すなわち本発明は、有害な陸棲・水棲軟体
動物、等脚目節足動物を対象とする駆除有効成分の少な
くとも１種（Ａ成分）と、脂肪酸、脂肪酸塩、ヒドロキ
シ基を有する脂肪酸、ヒドロキシ基を有する脂肪酸の塩
およびヒドロキシ基を有する脂肪酸のエステルの中から
選択される少なくとも１種（Ｂ成分）を含有することを
特徴とする、有害な陸棲・水棲軟体動物、等脚目節足動
物用の摂食性害虫駆除組成物である。That is, the present invention provides at least one kind (A component) of a pesticidal active ingredient intended for harmful terrestrial and aquatic molluscs and arthropod arthropods, a fatty acid, a fatty acid salt, a fatty acid having a hydroxy group, Harmful terrestrial / aquatic molluscs, arthropod arthropods, characterized by containing at least one member (component B) selected from salts of fatty acids having a hydroxy group and esters of fatty acids having a hydroxy group. It is an ingestible pest control composition for animals.
【０００８】また本発明は、有害な陸棲・水棲軟体動
物、等脚目節足動物を対象とする駆除有効成分の少なく
とも１種（Ａ成分）と、脂肪酸、脂肪酸塩、ヒドロキシ
基を有する脂肪酸、ヒドロキシ基を有する脂肪酸の塩お
よびヒドロキシ基を有する脂肪酸のエステルの中から選
択される少なくとも１種（Ｂ成分）を含有し、Ｂ成分の
含有量が摂食性害虫駆除組成物１００重量部に対して
０．５〜１０重量部である摂食性害虫駆除組成物を使用
することを特徴とする、有害な陸棲・水棲軟体動物、等
脚目節足動物駆除方法である。[0008] The present invention also relates to at least one kind of active ingredients (A component) for controlling harmful terrestrial and aquatic molluscs and arthropod arthropods, and fatty acids, fatty acid salts, fatty acids having a hydroxy group, It contains at least one member (component B) selected from a salt of a fatty acid having a hydroxy group and an ester of a fatty acid having a hydroxy group, and the content of the component B is based on 100 parts by weight of the composition for controlling insect pests. A method for controlling harmful terrestrial and aquatic molluscs and isopod arthropods, which comprises using an insect pest-controlling composition in an amount of 0.5 to 10 parts by weight.
【０００９】本発明の摂食性害虫駆除組成物は、駆除有
効成分（Ａ成分）、脂肪酸・脂肪酸塩類（Ｂ成分）、可
食成分、賦形成分、その他の添加剤を含有している。本
発明のベイト剤は、Ａ成分とＢ成分とが優れた相乗効果
を示すので、より少ない害虫駆除有効成分含有量であっ
ても、有害な陸棲・水棲軟体動物、等脚目節足動物に対
して高い駆除効果を発揮できるのである。The composition for controlling insect pests of the present invention contains an effective control component (A component), fatty acids and fatty acid salts (B component), edible components, excipients, and other additives. Since the bait of the present invention exhibits an excellent synergistic effect between the A component and the B component, even if the content of the active ingredient for controlling pests is smaller, it can be used for harmful terrestrial and aquatic molluscs and arthropod arthropods. It can exhibit a high control effect.
【００１０】本発明のベイト剤に用いられるＡ成分は特
に限定されないが、次のような化合物が挙げられる。
３，５−キシリル−Ｎ−メチルカーバメート（マクバー
ル）、２，４，６，８−テトラメチル−１，３，５，７
−テトロキソカン（メタアルデヒド）、Ｏ，Ｏ−ジメチ
ル−Ｏ−ｐ−シアノフェニル＝チオホスフェート（サイ
アノックス）、Ｏ，Ｏ−ジメチル−Ｏ−［３−メチル−
４−（メチルチオ）フェニル］チオホスフェート（フェ
ニトロチオン）、Ｏ，Ｏ−ジメチル−Ｏ−３，５，６−
トリクロロ−２−ピリジルホスホロチオエート（クロル
ピリホスメチル）、１−ナフチル−Ｎ−メチルカーバメ
ート（カルバリル）、２−（エチルチオメチル）フェニ
ル＝メチルカーバメート、５−ベンジル−３−フリルメ
チルｄｌ−シス，トランス−クリサンテマート（レスメ
トリン）、（ＲＳ）−α−シアノ−３−フェノキシベン
ジル＝（１ＲＳ，３ＲＳ）−（１ＲＳ，３ＳＲ）−３−
（２，２−ジクロロビニル）−２，２ジメチルシクロプ
ロパンカルボキシラート。The component A used in the bait of the present invention is not particularly limited, but includes the following compounds.
3,5-xylyl-N-methylcarbamate (Macbar), 2,4,6,8-tetramethyl-1,3,5,7
-Tetroxocan (methaldehyde), O, O-dimethyl-Op-cyanophenyl thiophosphate (Cyanox), O, O-dimethyl-O- [3-methyl-
4- (methylthio) phenyl] thiophosphate (fenitrothion), O, O-dimethyl-O-3,5,6-
Trichloro-2-pyridyl phosphorothioate (chloropyrifosmethyl), 1-naphthyl-N-methylcarbamate (carbaryl), 2- (ethylthiomethyl) phenyl = methylcarbamate, 5-benzyl-3-furylmethyl dl-cis, trans-cli Santemate (resmethrin), (RS) -α-cyano-3-phenoxybenzyl = (1RS, 3RS)-(1RS, 3SR) -3-
(2,2-Dichlorovinyl) -2,2 dimethylcyclopropanecarboxylate.
【００１１】これらの中で好ましいものは、３，５−キ
シリル−Ｎ−メチルカーバメートである。Of these, preferred is 3,5-xylyl-N-methylcarbamate.
【００１２】本発明のベイト剤に用いられるＢ成分とし
ては特に限定されないが、次のような化合物が挙げられ
る。飽和脂肪酸としては、酢酸、プロピオン酸、酪酸、
吉草酸、カプロン酸、カプリル酸、カプリン酸、ラウリ
ン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ア
ラキン酸、ベヘン酸等がある。不飽和脂肪酸としては、
オレイン酸、エライジン酸、ソルビン酸、リノール酸、
リノレン酸等がある。ヒドロキシ基を有する脂肪酸とし
ては、１２−ヒドロキシステアリン酸、リシノール酸等
がある。低級の飽和脂肪酸は誘引剤として含有されてい
る先行技術も存在するが、本発明のベイト剤において
は、低級の飽和脂肪酸もＢ成分として使用されるもので
ある。The component B used in the bait of the present invention is not particularly limited, but includes the following compounds. As saturated fatty acids, acetic acid, propionic acid, butyric acid,
Valeric acid, caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, arachiic acid, behenic acid and the like. As unsaturated fatty acids,
Oleic acid, elaidic acid, sorbic acid, linoleic acid,
Linolenic acid and the like. Examples of the fatty acid having a hydroxy group include 12-hydroxystearic acid and ricinoleic acid. Although there is a prior art in which lower saturated fatty acids are contained as an attractant, in the bait of the present invention, lower saturated fatty acids are also used as the B component.
【００１３】また、以上掲げた脂肪酸類の塩としては、
ナトリウム塩、カリウム塩等のアルカリ金属塩、カルシ
ウム塩、マグネシウム塩等のアルカリ土類金属塩、アル
ミニウム塩、亜鉛塩、鉄塩、スズ塩、鉛塩等が挙げられ
る。また、以上の金属塩の他にアンモニウム塩等の有機
塩も挙げられる。ヒドロキシ基を有する脂肪酸の場合
は、そのエステルも挙げられる。エステルとしてはグリ
セリンエステルが代表的である。The salts of the fatty acids listed above include:
Examples thereof include alkali metal salts such as sodium salt and potassium salt, alkaline earth metal salts such as calcium salt and magnesium salt, aluminum salt, zinc salt, iron salt, tin salt and lead salt. Further, in addition to the above-mentioned metal salts, organic salts such as ammonium salts may also be used. In the case of a fatty acid having a hydroxy group, esters thereof are also included. As the ester, a glycerin ester is typical.
【００１４】以上のＢ成分の中では、ヒドロキシ基を有
する脂肪酸、ヒドロキシ基を有する脂肪酸の塩およびヒ
ドロキシ基を有する脂肪酸のエステルが好ましい。より
好ましいのは、リシノール酸、リシノール酸塩およびリ
シノール酸エステルである。Among the above components B, a fatty acid having a hydroxy group, a salt of a fatty acid having a hydroxy group, and an ester of a fatty acid having a hydroxy group are preferred. More preferred are ricinoleic acid, ricinoleate and ricinoleate.
【００１５】さらに、以上掲げたＢ成分の脂肪酸類の塩
の中では、アルカリ金属塩が好ましい。リシノール酸塩
の中でも、やはりアルカリ金属塩が好ましい。Further, among the above-mentioned salts of the component B fatty acids, alkali metal salts are preferable. Of the ricinoleates, alkali metal salts are also preferred.
【００１６】以上掲げたＡ成分およびＢ成分は、必要に
応じてそれぞれ１種づつ、あるいは２種以上混合して用
いることができる。これらの量比は対象とする害虫種、
Ａ成分の活性、Ａ成分の添加量、求める駆除効果との関
係から求められる。The components A and B listed above can be used alone or in combination of two or more, if necessary. These quantitative ratios are based on the target pest species,
It is determined from the relationship between the activity of the component A, the amount of the component A added, and the desired extermination effect.
【００１７】[0017]
【発明の実施の形態】本発明のベイト剤中のＡ成分添加
量は、使用時の簡便性、経済性、環境への影響の面か
ら、ベイト剤１００重量部に対して、０．０１〜１０重
量部が好ましい。BEST MODE FOR CARRYING OUT THE INVENTION The amount of the A component added to the bait of the present invention is 0.01 to 100 parts by weight of the bait from the viewpoint of simplicity in use, economy, and impact on the environment. 10 parts by weight are preferred.
【００１８】本発明のベイト剤中のＢ成分添加量は、ベ
イト剤１００重量部に対して０．１〜２０重量部であ
り、好ましくは０．５〜１０重量部である。The addition amount of the component B in the bait of the present invention is 0.1 to 20 parts by weight, preferably 0.5 to 10 parts by weight, per 100 parts by weight of the bait.
【００１９】本発明のベイト剤の可食成分として使用さ
れるものは、植物油、動物油、糖類、穀物粉末、動物質
粉末、ビスケット粉等である。The edible components of the bait of the present invention include vegetable oils, animal oils, sugars, cereal powders, animal substance powders, biscuit powders and the like.
【００２０】植物油としては、大豆油、菜種油、ごま
油、小麦胚芽油などが挙げられる。これらは一般的に食
用油としても使用されているものが多い。その使用量は
ベイト剤１００重量部に対して０〜２０部である。Examples of vegetable oils include soybean oil, rapeseed oil, sesame oil, wheat germ oil and the like. Many of these are generally used as edible oils. The amount used is 0 to 20 parts with respect to 100 parts by weight of the bait.
【００２１】動物油としては、獣脂、ラード、ステアリ
ン酸、魚油、魚肝油等が挙げられる。これらは一般的に
食用油としても使用されているものが多い。その使用量
はベイト剤１００重量部に対して０〜２０部である。Animal oils include tallow, lard, stearic acid, fish oil, fish liver oil and the like. Many of these are generally used as edible oils. The amount used is 0 to 20 parts with respect to 100 parts by weight of the bait.
【００２２】糖類としては、ショ糖、ブドウ糖、果糖、
乳糖、黒砂糖、赤砂糖、三温糖、廃糖蜜等が挙げられ
る。その使用量はベイト剤１００重量部に対して０〜２
０部である。The sugars include sucrose, glucose, fructose,
Lactose, brown sugar, brown sugar, brown sugar, molasses, and the like. The amount used is 0 to 2 with respect to 100 parts by weight of the bait.
0 parts.
【００２３】穀物粉末としては、ジャガイモ、サツマイ
モ、トウモロコシなどのデンプン粉、小麦粉、米粉、コ
ーンスターチ、グルテン等が挙げられる。その使用量は
ベイト剤１００重量部に対して０〜６０部である。Examples of the cereal powder include starch flour such as potato, sweet potato, and corn, flour, rice flour, corn starch, gluten and the like. The amount used is 0 to 60 parts with respect to 100 parts by weight of the bait.
【００２４】動物質粉末としては、魚粉、エビ粉、オキ
アミ粉、サナギ粉等が挙げられる。その使用量はベイト
剤１００重量部に対して０〜２０部である。Examples of the animal substance powder include fish meal, shrimp powder, krill powder, pupa powder and the like. The amount used is 0 to 20 parts with respect to 100 parts by weight of the bait.
【００２５】本発明のベイト剤には、必要に応じて分散
補助剤、防腐防ばい剤、賦形剤、可塑剤、安定化剤、そ
の他害虫に対する誘引性を増強するための香料、誘引剤
等を添加することができる。The bait of the present invention may contain, if necessary, a dispersing aid, a preservative and soaking agent, an excipient, a plasticizer, a stabilizer, and other fragrances and attractants for enhancing the attraction to pests. Can be added.
【００２６】防腐防ばい剤としては、ｐ−クロロ−ｍ−
キシレノール、ｐ−クロロ−ｍ−クレゾール、ｐ−オキ
シ安息香酸ブチル、ソルビタン酸、ソルビン酸カリウ
ム、トリフミン等があり、これらを単独または２種以上
を併用して用いることもできる。As the antiseptic / soiling agent, p-chloro-m-
There are xylenol, p-chloro-m-cresol, butyl p-oxybenzoate, sorbitanic acid, potassium sorbate, and trihumin, and these can be used alone or in combination of two or more.
【００２７】賦形剤としては、ベントナイト、クレー、
ゼオライト、サンド等がある。As excipients, bentonite, clay,
There are zeolites and sands.
【００２８】駆除有効成分の安定化剤として、酸化防止
剤、紫外線防止剤等を併用してもよい。An antioxidant, an ultraviolet ray inhibitor and the like may be used in combination as a stabilizer for the extermination active ingredient.
【００２９】害虫に対する誘引性を増強するための香
料、誘引剤としては、酒粕、ナタネ油カス等がある。こ
れらは前記した可食成分としても使用されるものであ
る。Flavors and attractants for enhancing the attraction to pests include sake lees and oilseed rape. These are also used as the edible components described above.
【００３０】本発明のベイト剤は、一般的農・医薬の製
剤機器を用いて容易に製剤可能であり、その製剤過程に
おいて添加成分を撹拌、造粒、混合することができる。The bait of the present invention can be easily formulated using general agricultural and pharmaceutical preparation equipment, and the ingredients can be stirred, granulated, and mixed in the course of the preparation.
【００３１】本発明のベイト剤は、次のようにして製剤
することができる。まず、ベイト食餌基材（以後、「基
材」と略称する）を次の［基材例］の組成で調製する。
次にこの基剤に対して、Ａ成分とＢ成分を必要量添加
し、賦形剤であるクレーを添加して１００重量部とし、
基本的な配合物とする。製剤はこの配合物に対して必要
に応じて水を加え、ニーダーで混練し、造粒機にかけて
造粒後乾燥して、直径２ｍｍ、長さ３ｍｍ程度の粒状ベ
イト剤を得ることができる。 ［基材例］ バイタルグルテン（三和澱粉工業株式会社製） １６部 コーンスターチ（日本食品工業株式会社製） ５０部 廃糖蜜（大日本精糖株式会社製） ５部 清酒酒粕（大関酒造株式会社製） １部 ナタネ油かす（日清製油株式会社製） １部 腐敗防止剤 トリフミン ０．０２部 合計 ７２．０２部The bait of the present invention can be prepared as follows. First, a bait bait base material (hereinafter, abbreviated as “base material”) is prepared with the following composition of “base material”.
Next, the necessary amount of the component A and the component B is added to the base, and a clay as an excipient is added to 100 parts by weight.
Make a basic composition. The preparation is mixed with water as needed, kneaded in a kneader, granulated in a granulator, and dried to obtain a granular bait having a diameter of about 2 mm and a length of about 3 mm. [Example of base material] Vital gluten (manufactured by Sanwa Starch Industry Co., Ltd.) 16 parts Corn starch (manufactured by Nippon Food Industry Co., Ltd.) 50 parts Molasses waste (manufactured by Dainippon Sugar Co., Ltd.) 5 parts Sake sake cake (manufactured by Ozeki Shuzo Co., Ltd.) 1 part Rapeseed oil cake (manufactured by Nisshin Oil Co., Ltd.) 1 part Antiseptic agent Trifmin 0.02 parts Total 72.02 parts
【００３２】[0032]
【実施例】次に実施例を挙げて本発明を詳細に説明する
が、本発明はこれらの例に限定されるものではない。な
お、以下の製剤例、比較例および実施例中の「部」は、
すべて重量部を表す。Next, the present invention will be described in detail with reference to examples, but the present invention is not limited to these examples. In the following formulation examples, comparative examples and examples, "parts"
All parts are by weight.
【００３３】［製剤例１］〜［製剤例１９］、［比較例
１］〜［比較例６］ 本発明のベイト剤の製剤例を次に示す。製剤にはベイト
食餌基材として「基剤」を使用し、賦形剤にはクレーを
使用した。製剤に使用したＡ成分およびＢ成分を次に示
す。また、Ａ成分について本発明で使用した化合物Ｎo.
およびＢ成分について本発明で使用した脂肪酸（塩）Ｎ
o.も併せて示した。Formulation Examples 1 to 19, Comparative Examples 1 to 6 Formulation examples of the bait of the present invention are shown below. The formulation used "base" as bait dietary base and clay was used as excipient. The components A and B used in the preparation are shown below. Further, for the component A, the compound No. used in the present invention.
Fatty acid (salt) N used in the present invention with respect to component B and B
o. is also shown.
【００３４】（Ａ成分） 化合物１：３，５−キシリル−Ｎ−メチルカーバメート 化合物２：１−ナフチル−Ｎ−メチルカーバメート 化合物３：４−メチルチオ−３，５−キシリル−Ｎ−メ
チルカーバメート 化合物４：３，７，９，１３−テトラメチル−５，１１
−ジオキサ−２，８，１４トリチア−４，７，９，１２
−テトラアザペンタデカ−３，１２−ジエン−６，１０
−ジオン 化合物５：Ｏ，Ｏ−ジメチル−Ｏ−［３−メチル−４−
（メチルチオ）フェニル］チオフォスフェート 化合物６：(ＲＳ）−α−シアノ−３−フェノキシベン
ジル＝（１ＲＳ，３ＲＳ）−（２，２−ジクロロビニ
ル）−２，２ジメチルシクロプロパンカルボキシラート(Component A) Compound 1: 3,5-xylyl-N-methyl carbamate Compound 2: 1-naphthyl-N-methyl carbamate Compound 3: 4-methylthio-3,5-xylyl-N-methyl carbamate Compound 4 : 3,7,9,13-tetramethyl-5,11
-Dioxa-2,8,14trithia-4,7,9,12
-Tetraazapentadeca-3,12-diene-6,10
-Dione compound 5: O, O-dimethyl-O- [3-methyl-4-
(Methylthio) phenyl] thiophosphate Compound 6: (RS) -α-cyano-3-phenoxybenzyl = (1RS, 3RS)-(2,2-dichlorovinyl) -2,2dimethylcyclopropanecarboxylate
【００３５】（Ｂ成分） 脂肪酸塩１：オレイン酸Ｎａ 脂肪酸塩２：ステアリン酸Ｎａ 脂肪酸塩３：ステアリン酸Ｋ 脂肪酸塩４：ステアリン酸Ｍｇ 脂肪酸塩５：ステアリン酸Ｃａ 脂肪酸 ６：ステアリン酸 脂肪酸塩７：リシノール酸Ｋ 脂肪酸塩８：ミリスチン酸Ｎａ 脂肪酸塩９：１２−ヒドロキシステアリン酸Ｍｇ 脂肪酸塩１０：リシノール酸Ｎａ(Component B) Fatty acid salt 1: Na oleate fatty acid salt 2: Na stearate fatty acid salt 3: Stearic acid K fatty acid salt 4: Mg stearate fatty acid salt 5: Ca stearate fatty acid salt 6: Stearic acid fatty acid salt 7 : Ricinoleic acid K fatty acid salt 8: Na myristic acid fatty acid salt 9: 12-hydroxystearic acid Mg fatty acid salt 10: Ricinoleic acid Na
【００３６】［製剤例１］〜［製剤例１９］、［比較例
１］〜［比較例６］について、［表１］に一覧表で示し
た。[Table 1] lists [Formulation Example 1] to [Formulation Example 19] and [Comparative Example 1] to [Comparative Example 6].
【００３７】[0037]
【表１】 [Table 1]
【００３８】次に本発明の有用性を実証するために実施
例を示す。 ［実施例１］１００ｃｍ２（１／１０，０００ａ相当）
ポットを１９個用意し、各ポットに水田土３００ｍｌを
入れ、芽だしのイネ種籾１０粒を植え付ける。その後水
３００ｍｌを入れ、本発明の製剤例および比較例の粒剤
を５０ｍｇ（５００ｇ／ａ相当）量で散粒し、淡水棲の
水稲加害軟体動物であるスクミリンゴガイの幼貝（殻口
長径が５〜１０ｍｍの貝）１０頭を放飼して２５〜２８
℃定温室内にて４８時間飼育し、貝の生死およびイネ芽
だし種籾への食害防止効果を試験した。その結果を［表
２］に示す。本発明のベイト剤が比較例のベイト剤に比
して、スクミリンゴガイの幼貝の死亡率、イネ幼芽食害
率ともに優れていることがわかる。Next, examples will be shown to demonstrate the usefulness of the present invention. [Example 1] 100 cm 2 (equivalent to 1 / 10,000a)
Prepare 19 pots, put 300 ml of paddy soil in each pot, and plant 10 seedlings of rice seeds. Thereafter, 300 ml of water was added thereto, and the granules of the preparation example and the comparative example of the present invention were sprinkled in an amount of 50 mg (equivalent to 500 g / a), and the young shellfish (shell ostium having a long diameter of 5 mm) of a freshwater aquatic rice-affected mollusk, the molluscs. 10 to 10 mm shellfish) 25 to 28
They were bred in a constant temperature room at 48 ° C. for 48 hours, and tested for their effects on the life and death of shellfish and on the prevention of damage to rice seeds. The results are shown in [Table 2]. It can be seen that the bait preparation of the present invention is superior to the bait preparation of the comparative example in both the mortality of the larvae of the apple snail and the rate of rice germ damage.
【００３９】[0039]
【表２】 [Table 2]
【００４０】［実施例２］シイタケホダ木栽培施設にて
採集したナメクジ（Ｉｎｃｉｌａｒｉａ ｂｉｌｉｎｅ
ａｔａ ＢＥＮＳＯＮ）成体（体長２０ｍｍ以上）を供
試軟体動物とし、直径１１ｃｍ、高さ６．５ｃｍのトー
ルビーカーを用い、ビーカー底部に粉砕したホダ木を１
ｃｍ厚に敷いて、容器の中に０．０５ｇの試験粒剤を置
き、ナメクジ１５頭づつを放飼して４８時間後の生死判
定で駆除効果を検定した。結果を［表３］に示す。本発
明のベイト剤が比較例のベイト剤に比して、ナメクジの
死亡数が多いことがわかる。Example 2 Slugs collected from a shiitake-hoda tree growing facility (Inciaria biline)
ata BENSON) An adult (20 mm or more in length) was used as a test mollusc, and a tall beaker with a diameter of 11 cm and a height of 6.5 cm was used.
The test granules were placed in a container, and 0.05 g of test granules were placed in a container. 15 slugs were released at a time, and the extermination effect was evaluated by judging viability 48 hours later. The results are shown in [Table 3]. It can be seen that the bait of the present invention has a greater number of slug deaths than the bait of the comparative example.
【００４１】[0041]
【表３】 [Table 3]
【００４２】［実施例３］刈り芝堆積場に多発していた
オビババヤスデ（Ｊａｐｏｎａｒｉａ ｌａｍｉｎｏｔ
ａ ＡＴＴＥＭＳ）を採集し、刈り芝堆積物２００ｃｃ
を入れた１２ｃｍ×１８ｃｍ（２１６ｃｍ２）、高さ６
ｃｍの蓋付きプラスチック容器に各３０頭づつ入れ、
０．１ｇの施用量（約５００ｇ／ａ）にてベイト剤を容
器中に散粒施用して、４８時間後のオビババヤスデの生
死を観察した。結果を［表４］に示す。本発明のベイト
剤が比較例のベイト剤に比して、ナメクジの死亡数がは
るかに多いことがわかる。[Example 3] A Japanese hornbill (Japonaria laminot) frequently occurring in a mowed turf pile
a ATTEMS) and cut grass turf sediment 200cc
A 12cm × 18cm were placed (216cm 2), height 6
30 each in a plastic container with a lid of 30 cm,
The bait was sprayed in the container at an application rate of 0.1 g (about 500 g / a), and the life and death of the obesia millipede was observed 48 hours later. The results are shown in [Table 4]. It can be seen that the bait of the present invention has a much larger number of slug deaths than the bait of the comparative example.
【００４３】[0043]
【表４】 [Table 4]
【００４４】［実施例４］１０ｃｍ×１５ｃｍ、高さ８
ｃｍの蓋付きプラスチック容器にベイト剤７５ｍｇ（５
００ｇ／ａ相当）を入れ、累代飼育中のコクヌストモド
キ成虫♂♀各１０頭を入れて金網で蓋をし、２５〜２７
℃定温器中で４８時間飼育して死亡数を測定した。結果
を［表５］に示す。本発明のベイト剤が比較例のベイト
剤に比して、コクヌストモドキ成虫♂♀双方の死亡数が
はるかに多いことがわかる。Example 4 10 cm × 15 cm, height 8
75mg (5mg) in a plastic container with lid
(Equivalent to 00 g / a), and put the adult adults of A. japonicus in continuous breeding.
The animals were bred for 48 hours in a constant temperature incubator and the number of deaths was measured. The results are shown in [Table 5]. It can be seen that the bait of the present invention has a far greater number of mortalities of both the adult and the adult bait than the bait of the comparative example.
【００４５】[0045]
【表５】 [Table 5]
【００４６】洋ラン栽培園の栽培棚下に多発しているオ
カダンゴムシ（Ａｒｍａｄｉｌｉｄｉｕｍ ｕｎｌａｒ
ｅ ＬＡＴＲＥＩＬＬＥ）及びヤケヤスデ（Ｏｘｉｄｕ
ｓｇｒａｃｉｌｉｓ Ｃ．Ｌ．ＫＯＣＨ）を供試動物と
し、１．８ｍ×０．９ｍ（１．６２ｍ２）を１区画とし
て現地試験を実施した。区間には隣接区への影響を避け
るため、約１ｍの間隔を置いた。試験区あたり１０ｇ
（６００ｇ／ａ相当）を散粒した。調査は７日後の区画
内の死亡オカダンゴムシ、死亡ヤケヤスデ数の計数によ
って行った。結果を［表６］に示した。本発明のベイト
剤を使用した場合は、比較例のベイト剤の場合に比し
て、オカダンゴ虫、ヤケヤスデともに死亡数がはるかに
多いことがわかる。Armadilidium unlar, which occurs frequently under the cultivation shelf of a western orchid cultivation orchard (Armadilidium unlar)
e LATERILLE) and Yasuyasude (Oxidu)
sgracilis C.I. L. KOCH) was used as a test animal, and a field test was performed using 1.8 mx 0.9 m (1.62 m 2 ) as one section. Sections were spaced about 1 m apart to avoid affecting adjacent areas. 10g per test plot
(Equivalent to 600 g / a). The survey was carried out 7 days later by counting the number of dead locust beetles and dead yasukade in the plot. The results are shown in [Table 6]. It can be seen that when the bait of the present invention was used, the number of deaths of both the Okadango insect and the yakusadeus was much higher than the bait of the comparative example.
【００４７】[0047]
【表６】 [Table 6]
【００４８】[0048]
【発明の効果】本発明の摂食性害虫駆除組成物は、専用
の捕獲器等を必要とせず、より少ない害虫駆除有効成分
含有量で高い駆除効果を発現することができる。そのた
め、有害な陸棲・水棲軟体動物、等脚目節足動物に対し
て高い駆除効果を発揮することができる。また本発明の
摂食性害虫駆除組成物は、製造コストを低く抑えること
が可能で、環境上の悪影響も少なくすることができる。EFFECTS OF THE INVENTION The insect pest-controlling composition of the present invention can exhibit a high controlling effect with a smaller content of the pest-controlling active ingredient without requiring a special trap or the like. Therefore, a high control effect can be exerted on harmful terrestrial / aquatic molluscs and arthropod arthropods. In addition, the composition for controlling pests of the present invention can keep production costs low and can reduce adverse effects on the environment.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 安斎 達雄 神奈川県川崎市幸区堀川町66番地２ 保土 谷化学工業株式会社内 Ｆターム(参考） 4H011 AF01 BA02 BB13 BC06 DA02 DD07 DF04 DG13 ────────────────────────────────────────────────── ─── Continuing on the front page (72) Inventor Tatsuo Ansai 66-2 Horikawa-cho, Saiwai-ku, Kawasaki-shi, Kanagawa F-term (reference) 4H011 AF01 BA02 BB13 BC06 DA02 DD07 DF04 DG13
Claims (10)
動物を対象とする駆除有効成分の少なくとも１種（Ａ成
分）と、脂肪酸、脂肪酸塩、ヒドロキシ基を有する脂肪
酸、ヒドロキシ基を有する脂肪酸の塩およびヒドロキシ
基を有する脂肪酸のエステルの中から選択される少なく
とも１種（Ｂ成分）を含有することを特徴とする、有害
な陸棲・水棲軟体動物、等脚目節足動物用の摂食性害虫
駆除組成物。[Claim 1] At least one kind (A component) of an exterminating active ingredient intended for harmful terrestrial / aquatic molluscs and arthropod arthropods, a fatty acid, a fatty acid salt, a fatty acid having a hydroxy group, and a hydroxy group. For harmful terrestrial / aquatic molluscs and arthropod arthropods, characterized by containing at least one member (component B) selected from salts of fatty acids having the same and esters of fatty acids having a hydroxy group. Feeding pest control composition.
る脂肪酸、ヒドロキシ基を有する脂肪酸の塩およびヒド
ロキシ基を有する脂肪酸のエステルの中から選択される
少なくとも１種である、請求項１記載の有害な陸棲・水
棲軟体動物、等脚目節足動物用の摂食性害虫駆除組成
物。2. The harmful substance according to claim 1, wherein the component B is at least one selected from a fatty acid having a hydroxy group, a salt of a fatty acid having a hydroxy group, and an ester of a fatty acid having a hydroxy group. A pest control composition for terrestrial and aquatic molluscs and arthropod arthropods.
ノール酸塩およびリシノール酸エステルの中から選択さ
れる少なくとも１種である、請求項１または請求項２記
載の有害な陸棲・水棲軟体動物、等脚目節足動物用の摂
食性害虫駆除組成物。3. The harmful terrestrial / aquatic mollusc according to claim 1, wherein the B component is at least one selected from ricinoleic acid, ricinoleate and ricinoleate. An insecticidal pest control composition for arthropod arthropods.
塩、ヒドロキシ基を有する脂肪酸アルカリ金属塩の中か
ら選択される少なくとも１種である、請求項１〜請求項
２記載の有害な陸棲・水棲軟体動物、等脚目節足動物用
の摂食性害虫駆除組成物。4. The harmful terrestrial / aquatic soft body according to claim 1, wherein the component B is at least one selected from a fatty acid alkali metal salt and a fatty acid alkali metal salt having a hydroxy group. A pest control composition for animals and arthropod arthropods.
リ金属塩の中から選択される少なくとも１種である、請
求項３または請求項４記載の有害な陸棲・水棲軟体動
物、等脚目節足動物用の摂食性害虫駆除組成物。5. The harmful terrestrial / aquatic mollusc, isopod arthropod according to claim 3, wherein the B component is at least one selected from alkali metal ricinoleate. An insect pest control composition for animals.
Ｎ−メチルカーバメートである、請求項１〜請求項５記
載の有害な陸棲・水棲軟体動物、等脚目節足動物用の摂
食性害虫駆除組成物。6. The composition according to claim 1, wherein the component A is 3,5-xylyl-
The harmful terrestrial / aquatic mollusc, an isopod arthropod pest control composition according to claim 1, which is N-methyl carbamate.
して、前記したＢ成分が０．５〜１０重量部含有される
ことを特徴とする請求項１〜請求項６記載の有害な陸棲
・水棲軟体動物、等脚目節足動物用の摂食性害虫駆除組
成物。7. The harmful terrestrial harmony according to claim 1, wherein the B component is contained in an amount of 0.5 to 10 parts by weight based on 100 parts by weight of the composition for controlling pests. -A pest control composition for aquatic molluscs and arthropod arthropods.
動物を対象とする駆除有効成分の少なくとも１種（Ａ成
分）と、脂肪酸、脂肪酸塩、ヒドロキシ基を有する脂肪
酸、ヒドロキシ基を有する脂肪酸の塩およびヒドロキシ
基を有する脂肪酸のエステルの中から選択される少なく
とも１種（Ｂ成分）を含有し、Ｂ成分の含有量が摂食性
害虫駆除組成物１００重量部に対して０．５〜１０重量
部である摂食性害虫駆除組成物を使用することを特徴と
する、有害な陸棲・水棲軟体動物、等脚目節足動物駆除
方法。8. A method for removing at least one active ingredient (A component) for harmful terrestrial and aquatic molluscs and arthropod arthropods, a fatty acid, a fatty acid salt, a fatty acid having a hydroxy group, and a hydroxy group. At least one selected from the group consisting of a salt of a fatty acid and a ester of a fatty acid having a hydroxy group (component B), and the content of the component B is 0.5 to 100 parts by weight of the ingestible pest control composition. A method for controlling harmful terrestrial and aquatic molluscs and arthropod arthropods, which comprises using a composition for controlling pests which is 10 to 10 parts by weight.
る脂肪酸、ヒドロキシ基を有する脂肪酸の塩およびヒド
ロキシ基を有する脂肪酸のエステルの中から選択される
少なくとも１種である、請求項８記載の有害な陸棲・水
棲軟体動物、等脚目節足動物駆除方法。9. The harmful substance according to claim 8, wherein the component B is at least one selected from a fatty acid having a hydroxy group, a salt of a fatty acid having a hydroxy group, and an ester of a fatty acid having a hydroxy group. How to control terrestrial and aquatic molluscs and arthropod arthropods.
シノール酸塩およびリシノール酸エステルの中から選択
される少なくとも１種である、請求項８または請求項９
記載の有害な陸棲・水棲軟体動物、等脚目節足動物駆除
方法。10. The method according to claim 8, wherein the component B is at least one selected from ricinoleic acid, ricinoleate and ricinoleate.
The method for controlling harmful terrestrial and aquatic molluscs and isopods of arthropods as described.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002047926A JP4256105B2 (en) | 2001-02-23 | 2002-02-25 | Feeding pest control composition |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001048134 | 2001-02-23 | ||
| JP2001-48134 | 2001-02-23 | ||
| JP2002047926A JP4256105B2 (en) | 2001-02-23 | 2002-02-25 | Feeding pest control composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002322001A true JP2002322001A (en) | 2002-11-08 |
| JP4256105B2 JP4256105B2 (en) | 2009-04-22 |
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| Application Number | Title | Priority Date | Filing Date |
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| JP2002047926A Expired - Fee Related JP4256105B2 (en) | 2001-02-23 | 2002-02-25 | Feeding pest control composition |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004292411A (en) * | 2003-03-28 | 2004-10-21 | Hodogaya Chem Co Ltd | Ingestion-type pesticide composition having water resistance |
| JP2007223984A (en) * | 2006-02-27 | 2007-09-06 | Hodogaya Chem Co Ltd | Repellent for annelid worm |
| FR2899061A1 (en) * | 2006-03-31 | 2007-10-05 | Cid Lines Nv | Hygienic, cosmetic and/or disinfectant composition, useful for treating and/or washing of teats and/or udder of mammals e.g. cow, comprises a fatty acid as repellent and/or insecticide composition against arthropods e.g. flies |
| JP2009161560A (en) * | 2009-04-20 | 2009-07-23 | Kao Corp | Attractant and attracting-insecticide for gastropoda |
| JP2019089728A (en) * | 2017-11-14 | 2019-06-13 | フマキラー株式会社 | Gastropod expellent |
| JP2020158428A (en) * | 2019-03-26 | 2020-10-01 | 昭和産業株式会社 | Mite attractant, and method for producing the same |
-
2002
- 2002-02-25 JP JP2002047926A patent/JP4256105B2/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004292411A (en) * | 2003-03-28 | 2004-10-21 | Hodogaya Chem Co Ltd | Ingestion-type pesticide composition having water resistance |
| JP4617063B2 (en) * | 2003-03-28 | 2011-01-19 | 保土谷化学工業株式会社 | Feeding pest control composition with water resistance |
| JP2007223984A (en) * | 2006-02-27 | 2007-09-06 | Hodogaya Chem Co Ltd | Repellent for annelid worm |
| FR2899061A1 (en) * | 2006-03-31 | 2007-10-05 | Cid Lines Nv | Hygienic, cosmetic and/or disinfectant composition, useful for treating and/or washing of teats and/or udder of mammals e.g. cow, comprises a fatty acid as repellent and/or insecticide composition against arthropods e.g. flies |
| EP1842425A1 (en) | 2006-03-31 | 2007-10-10 | Cid Lines N.V. | Hygienic and/or cosmetic and/or disinfectant composition containing at least one anti-parasite and/or insect repellent agent |
| JP2009161560A (en) * | 2009-04-20 | 2009-07-23 | Kao Corp | Attractant and attracting-insecticide for gastropoda |
| JP2019089728A (en) * | 2017-11-14 | 2019-06-13 | フマキラー株式会社 | Gastropod expellent |
| JP2020158428A (en) * | 2019-03-26 | 2020-10-01 | 昭和産業株式会社 | Mite attractant, and method for producing the same |
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| Publication number | Publication date |
|---|---|
| JP4256105B2 (en) | 2009-04-22 |
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