GB1509586A - Process for the separation of 1,3-butadiene by selective adsorption on a zeolite adsorbent - Google Patents
Process for the separation of 1,3-butadiene by selective adsorption on a zeolite adsorbentInfo
- Publication number
- GB1509586A GB1509586A GB3333375A GB3333375A GB1509586A GB 1509586 A GB1509586 A GB 1509586A GB 3333375 A GB3333375 A GB 3333375A GB 3333375 A GB3333375 A GB 3333375A GB 1509586 A GB1509586 A GB 1509586A
- Authority
- GB
- United Kingdom
- Prior art keywords
- butadiene
- selective adsorption
- separation
- zeolite
- zeolite adsorbent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
- C07C7/13—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1509586 Selective adsorption of 1,3-butadiene UOP Inc 11 Aug 1975 [12 Aug 1974] 33333/75 Heading C5E 1,3-Butadiene is separated from a feed stream containing at least one C 4 unsaturate by selective adsorption on a type X or Y zeolite containing at least one cation selected from Li, Na, K, Rb, Cs and/or Ba. Subsequently the butadiene-containing adsorbent is treated with a desorbent such as benzene, toluene or linear monoolefin of substantially different boiling point from butadiene. Preferred adsorption and desorption conditions are 21-232‹C. and a pressure of 1-35 atmospheres to maintain the liquid phase. The zeolite is preferably exchanged to eliminate all the acid sites.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US49679374A | 1974-08-12 | 1974-08-12 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1509586A true GB1509586A (en) | 1978-05-04 |
Family
ID=23974160
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3333375A Expired GB1509586A (en) | 1974-08-12 | 1975-08-11 | Process for the separation of 1,3-butadiene by selective adsorption on a zeolite adsorbent |
Country Status (6)
Country | Link |
---|---|
JP (1) | JPS5143702A (en) |
CA (1) | CA1064829A (en) |
DE (1) | DE2535818C3 (en) |
FR (1) | FR2281910A1 (en) |
GB (1) | GB1509586A (en) |
IT (1) | IT1041175B (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6215037B1 (en) * | 1998-10-27 | 2001-04-10 | The Regents Of The University Of Michigan | Method for selective adsorption of dienes |
US6911569B1 (en) | 2000-08-07 | 2005-06-28 | The Regents Of The University Of Michigan | Sulfur resistant adsorbents |
CN104395268A (en) * | 2012-09-18 | 2015-03-04 | 昭和电工株式会社 | 1, 3-butadiene-separating material, and separation method using said separating material |
TWI554473B (en) * | 2012-06-08 | 2016-10-21 | Kyowa Chem Ind Co Ltd | Method for reducing cesium ions |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5398541A (en) * | 1977-02-10 | 1978-08-29 | Gastar Corp | Hot water utilization m ethod |
US4570029A (en) * | 1985-03-04 | 1986-02-11 | Uop Inc. | Process for separating isoprene |
US5220102A (en) * | 1991-12-23 | 1993-06-15 | Uop | Process for separating normal olefins from non-normal olefins |
JP5955135B2 (en) * | 2012-07-04 | 2016-07-20 | 昭和電工株式会社 | Gas separation material containing metal complex of oxocarbonic acid and method for separating hydrocarbon gas |
JP5980091B2 (en) * | 2012-10-30 | 2016-08-31 | 昭和電工株式会社 | Method for separating 1,3-butadiene and separation membrane |
WO2014103778A1 (en) * | 2012-12-26 | 2014-07-03 | 昭和電工株式会社 | Gas separation material using metal complex and gas separation method |
JP6305405B2 (en) | 2013-07-26 | 2018-04-04 | 昭和電工株式会社 | 1,3-butadiene separator and separation method using the separator |
WO2015012067A1 (en) | 2013-07-26 | 2015-01-29 | 昭和電工株式会社 | Metal complex, adsorbent, separating material, and 1, 3-butadiene separation method |
-
1975
- 1975-08-05 CA CA232,853A patent/CA1064829A/en not_active Expired
- 1975-08-07 IT IT5086975A patent/IT1041175B/en active
- 1975-08-11 GB GB3333375A patent/GB1509586A/en not_active Expired
- 1975-08-11 FR FR7524950A patent/FR2281910A1/en active Granted
- 1975-08-12 DE DE19752535818 patent/DE2535818C3/en not_active Expired
- 1975-08-12 JP JP9801775A patent/JPS5143702A/en active Granted
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6215037B1 (en) * | 1998-10-27 | 2001-04-10 | The Regents Of The University Of Michigan | Method for selective adsorption of dienes |
US6911569B1 (en) | 2000-08-07 | 2005-06-28 | The Regents Of The University Of Michigan | Sulfur resistant adsorbents |
TWI554473B (en) * | 2012-06-08 | 2016-10-21 | Kyowa Chem Ind Co Ltd | Method for reducing cesium ions |
CN104395268A (en) * | 2012-09-18 | 2015-03-04 | 昭和电工株式会社 | 1, 3-butadiene-separating material, and separation method using said separating material |
CN104395268B (en) * | 2012-09-18 | 2016-03-23 | 昭和电工株式会社 | 1,3-butadiene is separated material and uses the separation method of this separation material |
Also Published As
Publication number | Publication date |
---|---|
IT1041175B (en) | 1980-01-10 |
DE2535818A1 (en) | 1976-04-01 |
JPS5143702A (en) | 1976-04-14 |
JPS5250762B2 (en) | 1977-12-27 |
DE2535818C3 (en) | 1979-02-15 |
FR2281910A1 (en) | 1976-03-12 |
FR2281910B1 (en) | 1978-10-27 |
DE2535818B2 (en) | 1978-06-08 |
CA1064829A (en) | 1979-10-23 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |