GB1002345A - Photographic layers for the silver dyestuff bleaching method - Google Patents
Photographic layers for the silver dyestuff bleaching methodInfo
- Publication number
- GB1002345A GB1002345A GB39870/63A GB3987063A GB1002345A GB 1002345 A GB1002345 A GB 1002345A GB 39870/63 A GB39870/63 A GB 39870/63A GB 3987063 A GB3987063 A GB 3987063A GB 1002345 A GB1002345 A GB 1002345A
- Authority
- GB
- United Kingdom
- Prior art keywords
- azo
- formula
- methoxy
- groups
- och3
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000975 dye Substances 0.000 title abstract 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title 1
- 238000004061 bleaching Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 229910052709 silver Inorganic materials 0.000 title 1
- 239000004332 silver Substances 0.000 title 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 5
- -1 amino-azo Chemical group 0.000 abstract 3
- 239000000987 azo dye Substances 0.000 abstract 2
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical group C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 1
- 239000005749 Copper compound Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 125000005337 azoxy group Chemical group [N+]([O-])(=N*)* 0.000 abstract 1
- 150000001880 copper compounds Chemical class 0.000 abstract 1
- 230000008878 coupling Effects 0.000 abstract 1
- 238000010168 coupling process Methods 0.000 abstract 1
- 238000005859 coupling reaction Methods 0.000 abstract 1
- 230000001335 demethylating effect Effects 0.000 abstract 1
- 239000012954 diazonium Substances 0.000 abstract 1
- 150000001989 diazonium salts Chemical class 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical group OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B45/00—Complex metal compounds of azo dyes
- C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
- C09B45/24—Disazo or polyazo compounds
- C09B45/28—Disazo or polyazo compounds containing copper
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B27/00—Preparations in which the azo group is formed in any way other than by diazotising and coupling, e.g. oxidation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B43/00—Preparation of azo dyes from other azo compounds
- C09B43/08—Preparation of azo dyes from other azo compounds by reduction
- C09B43/085—Preparation of azo dyes from other azo compounds by reduction by reacting nitro azo dyes with amine or amino azo dye with nitro compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B43/00—Preparation of azo dyes from other azo compounds
- C09B43/08—Preparation of azo dyes from other azo compounds by reduction
- C09B43/10—Preparation of azo dyes from other azo compounds by reduction with formation of a new azo or an azoxy bridge
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/28—Silver dye bleach processes; Materials therefor; Preparing or processing such materials
- G03C7/29—Azo dyes therefor
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Paper (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
Dyes having the general formula <FORM:1002345/C4-C5/1> wherein R1 and R2 are benzine residues having the azo and -O-Cu-O- links in ortho position, the azo and azoxy groups being linked to R2 in para position, are prepared by condensing 1 mol. of 4,41-dinitro-stilbene-2,21-disulphonic acid with two mols. of an amino-azo dye of the formula HO3S-R1(OH)-N = N-R2(OCH3)-NH2 and then demethylating the methoxy groups and metallizing with a copper compound. The amino-azo dye is itself prepared by coupling the diazonium salt of an o-hydroxyamine of the formula HO3S-R1(OH)-NH2 with an amine of the formula H-R2(OCH3)-NH2. The benzene residue R2 may have additional substituents in para position to the methoxy group (i.e. to the -O-Cu-O-linkage in the final dye) such as methyl, methoxy or ethoxy substituents. The benzene residue R1 also may have additional substituents such as chloro, methyl, ethyl, nitro or further sulphonic acid groups.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH270060A CH386247A (en) | 1960-03-09 | 1960-03-09 | Photographic layer for the silver dye bleaching process |
| CH1442062A CH415295A (en) | 1960-03-09 | 1962-12-07 | Photographic layer for the silver dye bleaching process |
| CH1442162A CH415296A (en) | 1960-03-09 | 1962-12-07 | Photographic layer for the silver dye bleaching process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1002345A true GB1002345A (en) | 1965-08-25 |
Family
ID=27173858
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB8681/61A Expired GB923265A (en) | 1960-03-09 | 1961-03-09 | Photographic layers for the silver dyestuff bleaching method |
| GB39870/63A Expired GB1002345A (en) | 1960-03-09 | 1963-10-09 | Photographic layers for the silver dyestuff bleaching method |
| GB39871/63A Expired GB999996A (en) | 1960-03-09 | 1963-10-09 | Photographic layers for the silver dyestuff bleaching method |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB8681/61A Expired GB923265A (en) | 1960-03-09 | 1961-03-09 | Photographic layers for the silver dyestuff bleaching method |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB39871/63A Expired GB999996A (en) | 1960-03-09 | 1963-10-09 | Photographic layers for the silver dyestuff bleaching method |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3211556A (en) |
| BE (3) | BE640911A (en) |
| CH (3) | CH415296A (en) |
| DE (3) | DE1121469B (en) |
| FR (3) | FR1290363A (en) |
| GB (3) | GB923265A (en) |
| NL (1) | NL262127A (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE630637A (en) * | 1962-04-10 | |||
| GB1077484A (en) * | 1964-06-02 | 1967-07-26 | Ciba Ltd | Photographic materials for the silver dyestuff bleaching process |
| US4235957A (en) * | 1979-01-25 | 1980-11-25 | Eastman Kodak Company | Thermal silver-dye bleach element and process |
| DE2948022A1 (en) * | 1979-11-29 | 1981-06-04 | Bayer Ag, 5090 Leverkusen | POLYAZO DYES, METHOD FOR THEIR PRODUCTION AND THEIR USE FOR COLORING VEGETABILIC FIBER MATERIALS AND LEATHER |
| EP0043792B1 (en) * | 1980-06-03 | 1986-03-05 | Ciba-Geigy Ag | Dyeing paper |
| CH654588A5 (en) * | 1981-12-31 | 1986-02-28 | Sandoz Ag | METALIZED STYLENE AZO COMPOUNDS, METHOD FOR PRODUCING AND USE. |
| US20090246529A1 (en) | 2008-03-28 | 2009-10-01 | Conopco, Inc., D/B/A Unilever | Particle with Bipolar Topospecific Characteristics and Process for Preparation Thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2987513A (en) * | 1958-01-31 | 1961-06-06 | Bayer Ag | Azo dyestuffs and process for their manufacture |
| US3148062A (en) * | 1959-04-06 | 1964-09-08 | Eastman Kodak Co | Photographic elements and processes using splittable couplers |
-
0
- NL NL262127D patent/NL262127A/xx unknown
- BE BE601095D patent/BE601095A/xx unknown
-
1961
- 1961-03-07 FR FR854756A patent/FR1290363A/en not_active Expired
- 1961-03-08 DE DEC23591A patent/DE1121469B/en active Pending
- 1961-03-09 GB GB8681/61A patent/GB923265A/en not_active Expired
-
1962
- 1962-12-07 CH CH1442162A patent/CH415296A/en unknown
- 1962-12-07 CH CH1442062A patent/CH415295A/en unknown
-
1963
- 1963-10-09 GB GB39870/63A patent/GB1002345A/en not_active Expired
- 1963-10-09 GB GB39871/63A patent/GB999996A/en not_active Expired
- 1963-11-25 FR FR954919A patent/FR84794E/en not_active Expired
- 1963-11-25 FR FR954918A patent/FR84793E/en not_active Expired
- 1963-12-06 BE BE640911A patent/BE640911A/xx unknown
- 1963-12-06 BE BE640912A patent/BE640912A/xx unknown
- 1963-12-06 DE DEC31610A patent/DE1174613B/en active Pending
- 1963-12-06 DE DEC31611A patent/DE1173337B/en active Pending
-
1964
- 1964-02-27 CH CH240464A patent/CH431272A/en unknown
- 1964-03-13 US US351839A patent/US3211556A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE1173337B (en) | 1964-07-02 |
| BE601095A (en) | |
| DE1121469B (en) | 1962-01-04 |
| GB999996A (en) | 1965-07-28 |
| NL262127A (en) | |
| BE640911A (en) | 1964-06-08 |
| DE1174613B (en) | 1964-07-23 |
| CH415296A (en) | 1966-06-15 |
| CH431272A (en) | 1967-02-28 |
| US3211556A (en) | 1965-10-12 |
| BE640912A (en) | 1964-06-08 |
| FR84793E (en) | 1965-04-16 |
| FR1290363A (en) | 1962-04-13 |
| GB923265A (en) | 1963-04-10 |
| FR84794E (en) | 1965-04-16 |
| CH415295A (en) | 1966-06-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB1002345A (en) | Photographic layers for the silver dyestuff bleaching method | |
| GB1101750A (en) | New copper complexes of disazo dyestuffs containing a triazine nucleus | |
| GB1104915A (en) | New azo dyestuffs of the halogenotriazine series | |
| GB705171A (en) | Colour photography | |
| GB858183A (en) | Water-soluble azo dyestuffs containing acryloylamino groups | |
| GB1015025A (en) | Photographic material for the silver dyestuff bleaching method | |
| GB1023799A (en) | Novel azo-stilbene dyestuffs | |
| ES381937A1 (en) | Disazo dyestuffs | |
| US2342451A (en) | Chrome disazo dye | |
| US3565884A (en) | Disperse monoazo dyes derived from 3-aminodiphenylene oxides | |
| GB1004957A (en) | Photographic layers for the silver dyestuff bleaching process | |
| GB803810A (en) | Copper-containing trisazo dyestuffs | |
| GB980399A (en) | Photographic materials for the silver dyestuff bleaching process | |
| GB957419A (en) | Benzene monoazo dyestuffs | |
| GB914505A (en) | Monoazo and disazo dyes free from carboxylic and sulphonic acid groups | |
| GB930479A (en) | Photographic layers suitable for the silver dyestuff bleaching method | |
| GB955892A (en) | Photographic layers suitable for the silver dyestuff bleaching process | |
| ES387358A1 (en) | A method of manufacturing an acid coloring for natural and synthetic polyamide fibers and for secondary cellulose acetate fibers. (Machine-translation by Google Translate, not legally binding) | |
| GB922568A (en) | Photographic layers suitable for the silver dyestuff bleaching method | |
| ES415501A1 (en) | Yellow orange and scarlet disazo dyes | |
| GB889658A (en) | Improvements relating to metallisable trisazo dyestuffs and their use | |
| GB928675A (en) | New monoazo dyes containing 3-chlorotetrahydrofuryl-(2)-oxy groups and their manufacture and use | |
| GB875672A (en) | Copper containing trisazo dyestuffs | |
| GB482342A (en) | Manufacture of disazo-dyestuffs soluble in water | |
| GB825431A (en) | Improvements relating to copper containing disazo dyestuffs of the stilbene series |