WO2009013964A1 - メタセシス触媒の再活性化方法およびその再活性化工程を含むオレフィン類の製造方法 - Google Patents

メタセシス触媒の再活性化方法およびその再活性化工程を含むオレフィン類の製造方法 Download PDF

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Publication number
WO2009013964A1
WO2009013964A1 PCT/JP2008/061399 JP2008061399W WO2009013964A1 WO 2009013964 A1 WO2009013964 A1 WO 2009013964A1 JP 2008061399 W JP2008061399 W JP 2008061399W WO 2009013964 A1 WO2009013964 A1 WO 2009013964A1
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WIPO (PCT)
Prior art keywords
reactivation
catalyst
metathesis
olefins
production
Prior art date
Application number
PCT/JP2008/061399
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English (en)
French (fr)
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WO2009013964A8 (ja
Inventor
Hirokazu Ikenaga
Original Assignee
Mitsui Chemicals, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Chemicals, Inc. filed Critical Mitsui Chemicals, Inc.
Priority to US12/452,651 priority Critical patent/US20100191030A1/en
Priority to EP08777512.8A priority patent/EP2184106A4/en
Priority to JP2009524427A priority patent/JP5345058B2/ja
Priority to KR1020097024439A priority patent/KR101095194B1/ko
Priority to CN2008800236303A priority patent/CN101687182B/zh
Publication of WO2009013964A1 publication Critical patent/WO2009013964A1/ja
Publication of WO2009013964A8 publication Critical patent/WO2009013964A8/ja

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/92—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/20—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/36—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/06—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/10—Magnesium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/36—Rhenium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

　反応と高温で被毒物質やコークを燃焼除去する再生処理を長期間繰り返すことにより劣化したタングステン、モリブデン、レニウムから選ばれた少なくとも１種以上の金属元素を含む化合物からなる触媒１および、酸化マグネシウム、ハイドロタルサイト焼成体から選ばれた少なくとも１種以上の触媒２からなるメタセシス触媒を、簡便かつ効果的に新品同等または要求水準まで再活性化する方法および該工程を含むメタセシス反応によるオレフィン類の製造方法を提供する。 　劣化したメタセシス触媒を５０°C以下の水もしくは１７０°C以下の水蒸気と接触させることにより、簡便かつ効果的に触媒を再活性化する。
PCT/JP2008/061399 2007-07-26 2008-06-23 メタセシス触媒の再活性化方法およびその再活性化工程を含むオレフィン類の製造方法 WO2009013964A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US12/452,651 US20100191030A1 (en) 2007-07-26 2008-06-23 Method for reactivating metathesis catalysts, and olefin production process including reactivating step
EP08777512.8A EP2184106A4 (en) 2007-07-26 2008-06-23 PROCESS FOR REACTIVATING METATHESIS CATALYSTS AND PROCESS FOR PRODUCING OLEFINS COMPRISING REACTIVATION
JP2009524427A JP5345058B2 (ja) 2007-07-26 2008-06-23 メタセシス触媒の再活性化方法およびその再活性化工程を含むオレフィン類の製造方法
KR1020097024439A KR101095194B1 (ko) 2007-07-26 2008-06-23 메타세시스 촉매의 재활성화 방법 및 그 재활성화 공정을 포함하는 올레핀류의 제조방법
CN2008800236303A CN101687182B (zh) 2007-07-26 2008-06-23 复分解催化剂的再活化方法及含有该再活化工序的烯烃类的制造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007194918 2007-07-26
JP2007-194918 2007-07-26

Publications (2)

Publication Number Publication Date
WO2009013964A1 true WO2009013964A1 (ja) 2009-01-29
WO2009013964A8 WO2009013964A8 (ja) 2010-03-18

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PCT/JP2008/061399 WO2009013964A1 (ja) 2007-07-26 2008-06-23 メタセシス触媒の再活性化方法およびその再活性化工程を含むオレフィン類の製造方法

Country Status (8)

Country Link
US (1) US20100191030A1 (ja)
EP (1) EP2184106A4 (ja)
JP (1) JP5345058B2 (ja)
KR (1) KR101095194B1 (ja)
CN (1) CN101687182B (ja)
MY (1) MY148550A (ja)
TW (1) TW200909052A (ja)
WO (1) WO2009013964A1 (ja)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010024319A1 (ja) * 2008-08-28 2010-03-04 三井化学株式会社 オレフィンの製造方法
WO2010077265A1 (en) * 2008-12-30 2010-07-08 Lyondell Chemical Technology, L.P. Catalyst regeneration
US9815753B2 (en) 2014-09-15 2017-11-14 Northwestern University Supported metal oxides for olefin metathesis and related methods

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103539602B (zh) * 2012-07-12 2015-06-10 中国石油化工股份有限公司 用于异丁烯歧化制四甲基乙烯的方法
WO2014123972A1 (en) * 2013-02-08 2014-08-14 Lyondell Chemical Technology, L.P. Propylene production process
EP2873459A1 (en) * 2013-11-14 2015-05-20 Borealis AG Catalyst bed configuration for olefin conversion and process for obtaining olefins
EP3050621A1 (en) 2015-01-30 2016-08-03 Terramark Markencreation GmbH Metathesis catalyst and process for producing olefin
CN109865530B (zh) * 2017-12-05 2021-12-21 中国科学院大连化学物理研究所 部分再生甲醇制烯烃催化剂的方法和甲醇制烯烃方法
WO2020137157A1 (ja) * 2018-12-27 2020-07-02 東亞合成株式会社 非エンベロープ型抗ウイルス剤及びそれを含む組成物並びに抗ウイルス製品及びその製造方法

Citations (6)

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JPS596698B2 (ja) 1974-11-25 1984-02-14 ゼネラル エレクトリツク カンパニイ サンカマグネシウムシヨクバイ ノ サイカツセイカホウ
US4575575A (en) 1984-04-05 1986-03-11 Phillips Petroleum Company Catalysts and process for olefin conversion
JPS62197147A (ja) * 1986-02-24 1987-08-31 フイリツプス　ピトロ−リアム　カンパニ− オレフイン化合物の二重結合異性化及び不均化反応触媒、及びそれらの方法
JPH11217340A (ja) * 1997-10-17 1999-08-10 Basf Ag プロペンの製造方法
WO2005023420A1 (ja) * 2003-09-03 2005-03-17 The Circle For The Promotion Of Science And Engineering メタセシス触媒およびそれを用いるオレフィンの製造方法
WO2006093058A1 (ja) 2005-03-03 2006-09-08 Mitsui Chemicals, Inc. オレフィン類の製造方法

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US5120894A (en) * 1988-09-19 1992-06-09 Lyondell Petrochemical Company Olefin conversion process
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JPS596698B2 (ja) 1974-11-25 1984-02-14 ゼネラル エレクトリツク カンパニイ サンカマグネシウムシヨクバイ ノ サイカツセイカホウ
US4575575A (en) 1984-04-05 1986-03-11 Phillips Petroleum Company Catalysts and process for olefin conversion
JPS62197147A (ja) * 1986-02-24 1987-08-31 フイリツプス　ピトロ−リアム　カンパニ− オレフイン化合物の二重結合異性化及び不均化反応触媒、及びそれらの方法
JPH11217340A (ja) * 1997-10-17 1999-08-10 Basf Ag プロペンの製造方法
WO2005023420A1 (ja) * 2003-09-03 2005-03-17 The Circle For The Promotion Of Science And Engineering メタセシス触媒およびそれを用いるオレフィンの製造方法
WO2006093058A1 (ja) 2005-03-03 2006-09-08 Mitsui Chemicals, Inc. オレフィン類の製造方法

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Title
See also references of EP2184106A4

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010024319A1 (ja) * 2008-08-28 2010-03-04 三井化学株式会社 オレフィンの製造方法
CN102131752A (zh) * 2008-08-28 2011-07-20 三井化学株式会社 烯烃制造方法
US8299313B2 (en) 2008-08-28 2012-10-30 Mitsui Chemicals, Inc. Olefin production process
JP5432905B2 (ja) * 2008-08-28 2014-03-05 三井化学株式会社 オレフィンの製造方法
WO2010077265A1 (en) * 2008-12-30 2010-07-08 Lyondell Chemical Technology, L.P. Catalyst regeneration
JP2012513895A (ja) * 2008-12-30 2012-06-21 ライオンデル ケミカル テクノロジー、 エル．ピー． 触媒の再生
US8722557B2 (en) 2008-12-30 2014-05-13 Lyondell Chemical Technology, L.P. Catalyst regeneration
JP2015145004A (ja) * 2008-12-30 2015-08-13 ライオンデル ケミカル テクノロジー、エル．ピー． 触媒の再生
US9815753B2 (en) 2014-09-15 2017-11-14 Northwestern University Supported metal oxides for olefin metathesis and related methods

Also Published As

Publication number Publication date
EP2184106A4 (en) 2013-12-11
US20100191030A1 (en) 2010-07-29
TW200909052A (en) 2009-03-01
KR20090130324A (ko) 2009-12-22
KR101095194B1 (ko) 2011-12-16
WO2009013964A8 (ja) 2010-03-18
CN101687182B (zh) 2012-06-27
EP2184106A1 (en) 2010-05-12
MY148550A (en) 2013-04-30
CN101687182A (zh) 2010-03-31
JP5345058B2 (ja) 2013-11-20
JPWO2009013964A1 (ja) 2010-09-30

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