WO2001066078A1 - Composition cosmetique a caracteristiques ameliorees d'absorption et d'adherence - Google Patents

Composition cosmetique a caracteristiques ameliorees d'absorption et d'adherence Download PDF

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Publication number
WO2001066078A1
WO2001066078A1 PCT/GB2000/003948 GB0003948W WO0166078A1 WO 2001066078 A1 WO2001066078 A1 WO 2001066078A1 GB 0003948 W GB0003948 W GB 0003948W WO 0166078 A1 WO0166078 A1 WO 0166078A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
waxy
starch
superabsorbent polymer
powder
Prior art date
Application number
PCT/GB2000/003948
Other languages
English (en)
Inventor
Adonis R. Buelo
Joseph D. Synodis
William N. Bilodeau
Original Assignee
Block Drug Company, Inc.
Whalley, Kevin
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Block Drug Company, Inc., Whalley, Kevin filed Critical Block Drug Company, Inc.
Priority to AU2000278058A priority Critical patent/AU2000278058A1/en
Publication of WO2001066078A1 publication Critical patent/WO2001066078A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/91—Graft copolymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/12—Face or body powders for grooming, adorning or absorbing

Definitions

  • the present invention relates generally to personal care and cosmetic compositions in powder form providing excellent moisture absorbency and adhesive properties. More particularly, the present invention relates to personal care and cosmetic compositions in powder form comprising superabsorbent polymers.
  • talc which is a natural hydrous magnesium silicate
  • various other ingredients have also been proposed and utilized for body powders including starches, cellulose derivatives, polymeric substances and the like.
  • talc and non-talc compositions are available through commercial channels, numerous attempts to develop improved body powder compositions have been on-going. See for example, U.S. Patent No. 4,185,086 to Zeitx which teaches and claims a body powder composition comprising talc, fragrance and from about 0.1 to 1 wt. % polyethylene glycol. Since one of the primary purposes of a body powder is to absorb moisture, the effectiveness of the body powder is diminished when the powder has reached its capacity for absorbency.
  • U.S. Patent No. 5,417,963 to Murphy et al. discloses body and body powder compositions with enhanced deodorant and moist absorbency characteristics consisting of from about 70 wt. % talc and the remainder comprising micro-crystallite particles of a bicarbonate salt coated with a hydrophobic polymer such as xanthan gum, carrageenan, alginate salt, guar gum, gum arabic, casein, dextran, agar, methyl cellulose, carboxymethyl cellulose, and the like.
  • a hydrophobic polymer such as xanthan gum, carrageenan, alginate salt, guar gum, gum arabic, casein, dextran, agar, methyl cellulose, carboxymethyl cellulose, and the like.
  • Superabsorbent polymers are known and are mainly used in the production of diapers and incontinence articles as well as wound dressings.
  • U.S. Patent No. 5,064,653 to Sessions et al. discloses the use of superabsorbent polymers in a foam composition for applications in sanitary napkins, diapers, and the like.
  • Superabsorbent polymers are also added in some cosmetic compacted powders to add in the absorbency.
  • U.S. Patent No. 5,211 ,892 discloses the addition of superabsorbent polymers to pharmaceutical or cosmetic compacted powder comprising
  • thermoplastic product such as polyethylene wax to provide an absorbent or partially friable compacted product.
  • U.S. Patent No. 4,661,476 discloses the addition of superabsorbent polymers to skin lotion comprising about 75 to 99 wt. % water, to cool the surface of skin that has been overheated by excessive exposure to sun and/or wind.
  • U.S. Patent No. 6,013,271 discloses the addition of superabsorbent materials to an oil-in-water dispersion which comprises from about 30 to 98.89 wt. % of water.
  • a method to improve the resistance to wash-off characteristic of a skin care, cosmetic or pharmaceutical composition comprising from 25 wt. % to 99 wt. % (preferably from 25 wt. % to 95 wt. %) a powder carrier, by including in said composition from 0.01 wt. % to 20 wt. % of a superabsorbent polymer.
  • a skin care, cosmetic or pharmaceutical composition having superior resistance to wash-off characteristics, the composition comprising from 25 wt. % to 99 wt. % (preferably from 25 wt.% to 95 wt. % ) a powder carrier and from 0.01 wt. % to 20 wt. % of a superabsorbent polymer, wherein the adherence to skin of said composition is improved as compared to an analogous composition not containing said superabsorbent polymer.
  • the skin care, cosmetic or pharmaceutical composition is preferably in loose powder form.
  • the composition is preferably in loose powder form when it is a cosmetic composition.
  • compositions of the present invention comprise one of a number of superabsorbent polymers combined with several other ingredients well-known in the cosmetic, skin care, or pharmaceutical art. It has surprisingly been found that superabsorbent polymers, when added to the composition of the present invention, surprisingly and unexpectedly provide and promote resistance to wash-off of the compositions from the skin.
  • Binder superabsorbent polymers are water-insoluble, crosslinked, high molecular weight polymers capable of absorbing and retaining large quantities of aqueous fluids. These polymers are well known in the art by a few other names such as hydrogels, hydrocoUoids, water absorbent hydrophilic polymers, etc.
  • these super-absorbent polymers are wide-mesh crosslinked, water-insoluble polymers based on alkali metal salts of polyacrylic acid or copolymers of alkali metal salts of acrylic acid and acrylamide which are obtained by radical-initiated copolymerization of acrylic acid and polyfunctional monomers, such as divinylbenzene, ethylene glycol dimethacrylate, ethylene glycol diallylether, butanediol acrylate, hexanediol methacrylate, polyglycol diacrylate, trimethylol propane diacrylate, allyl acrylate, diallyl acrylamide, triallylamine, diallylether, methylene bis-acrylamide and N- methylol acrylamide.
  • polymers of this type are capable of absorbing large quantities of liquids, swelling and forming hydrogels in the process, and of retaining them, even under pressure.
  • Superabsorbent polymers include but are not limited to cross-linked polyacrylamide copolymer, sodium polyacrylate, starch-graft copolymer, hydrolyzed starch acrylonitrile copolymer, cross-linked polyacrylamide copolymer, and other water- swellable, and/or water absorbing agents.
  • Superabsorbent polymers which have been found suitable for the compositions of the present invention are hydrolyzed starch-polyacrylonitrile graft copolymer salts, commercially available from Grain Processing Corporation under the trademark Waterlock®. These polymers have the chemical name starch-g-poly(2-propenamide-co- 2-propenoic acid, mixed sodium and aluminum salt). Another suitable example is poly- 2-propenoic acid, sodium salt, commercially available from Sanyo Corp.
  • the superabsorbent polymer may be used alone, or in combination to achieve the desired absorptivity and adhesion characteristics in the compositions.
  • the superabsorbent polymers are added to the composition in an amount of from 0.01 wt. % to 20 wt. %. Preferably these are added in an amount of from 5 to 15 wt. % and more preferably in an amount of about 10 wt. %.
  • Powder Carrier The superabsorbent polymer is then combined with a typical powder carrier which comprises the bulk of the composition of the present invention.
  • Powder carriers include but are not limited to starch or flour.
  • Typical sources for the starches and flours are cereals, tubers, roots, legumes and fruits.
  • the native source can be corn, white corn, pea, potato, sweet potato, banana, barley, wheat, rice, sago, amaranth, tapioca, sorghum, waxy maize, waxy tapioca, waxy pea, waxy wheat, waxy rice, waxy barley, waxy potato, waxy sorghum, high amylose starches containing greater than 40% amylose, and the like.
  • Preferred starches are potato, corn, rice, oat, and waxy starches such as waxy maize, waxy tapioca, waxy rice, and waxy barley, legume starches, soy starch, turnip starch, microcrystalline cellulose, aluminum starch octenyl succinate, kaolin, and mixtures thereof.
  • a most preferred powder carrier is cornstarch, which consists of a carbohydrate polymer derived chiefly from waxy maize corn. In a form of a white powder, it rapidly swells in water.
  • Powder carriers typically comprise from 25%o to 99%o, preferably from 30% to 80%, more preferably from 35% to 75%, and most preferably from 40% to 70%, by weight of the composition.
  • Optional Anti-caking and Anti-clustering agents are selected from the group comprising calcium phosphates (e.g., calcium triphosphate), aluminum calcium sulfate, silicas (or silicon dioxide), silicates, carbonates and mixtures thereof.
  • the anti-clustering / anti-caking agent also acts as a buffer and is incorporated in the body powder in amounts of from about 0.1 to 2 wt. % and preferably in an amount of from about 1 to 1.5 wt. %.
  • hydrophobic silicon dioxide can be also added in an amount of preferably 0.1 to 2% by weight to further impart free-flowing properties to the composition.
  • compositions of the present invention may also contain compounds which function as anti -bacterial agents to combat bacteria which cause diaper rash, perspiration odor and/or athlete's foot in personal care applications.
  • the anti-bacterial compounds may be present in an anti-bacterially effective amount of from 0.025 to 2%o by weight, preferably 0.05 to 1% by weight. Examples of suitable anti-bacterial compounds are 8-hydroxyquinoline, methylbenzethonium chloride, benzethonium chloride, benzalkonium chloride, and the like.
  • the compositions of the present invention also optionally include skin aids.
  • skin aids refers to skin protectants, emollients, moisturizers, astringents, and antioxidants.
  • Preferred skin protectants are corn starch, kaolin, mineral oil, sodium bicarbonate, dimethicone, zinc oxide, colloidal oatmeal, and mixtures thereof.
  • the skin protectants comprise from about 0.1% to about 80%), preferably from about 0.1%o to about 30%, most preferably from about 0.1% to about 10%), by weight of the composition.
  • Typical emollients and moisturizers useful in the present invention are tocopherol, tocopheryl acetate, aloe, mineral oil, jojoba oil, and mixtures thereof.
  • the emollients/moisturizers comprise from about 0.1% to about 50%, preferably from about 0.1% to about 25%o, most preferably from about 0.1%) to about 10%), by weight of the composition.
  • Antioxidants useful in the present invention include retinol, retinyl acetate, and retinyl palmitate, and more preferred, encapsulated antioxidants.
  • Optional antioxidants comprise up to about 25%, preferably from about 0.1%o to about 10%, by weight of the composition.
  • compositions may further contain zinc oxide in baby powder applications for the relief of skin rash and chafing in addition to acting as a whitening agent and also imparting astringent properties.
  • the zinc oxide may be present in an amount of 1 to 30%) by weight, preferably 5 to 20% by weight of the composition.
  • the perfumes which are useful in the present invention are any commercial perfumes which result in the fragrance desired by the formula.
  • Commercial perfumes are mixtures of many components and these components all contribute to the particular fragrance which is characteristic of the mixture.
  • Examples of typical perfume which can be formulated to make up a particular pleasant aroma include lemon oil, musk ketone, ionone, diphenyl oxide, cedarwood-terpeneless; geranyl acetate; ylang ylang oil; cedryl acetate, isoeugenol; cinnamic alcohol, aurantheol, methyl anthranilate; vanillin, oil bergamot, eugenol; oil of cananga; citral; tetrahydro linalool; oil patchouly, methyl isoeugenol; hexylcinnamic aldehyde; resil oilbanum, resin balsam fir; musk aurbrette, resin balsam Peru;
  • the perfume is typically utilized in an amount of from 0.005 to 1 wt. % of the total composition, preferably from about 0.1 to 0.3 wt. %.
  • composition of the present invention may optionally include odor control agents such as uncomplexed cyclodextrin, zeolites, carbon odor-controlling agents, sodium bicarbonates, and/or antimicrobial agents for added body odor control.
  • odor control agents such as uncomplexed cyclodextrin, zeolites, carbon odor-controlling agents, sodium bicarbonates, and/or antimicrobial agents for added body odor control.
  • the composition of the present invention may be specially formulated to provide good skin feel characteristics, by further comprising skin feel components in an amount of up to 50%) by weight of the composition.
  • skin feel components commonly refer to three groups of ingredients which are 1) stearates and/or fatty acid derivatives, 2) spherical particles, and 3) platelet-shaped particles.
  • Stearates and/or fatty acid derivatives useful herein include metallic stearates such as magnesium stearate or zinc stearate, and similar fatty acid derivatives such as fatty acid esters which possess unctuous, oily characteristics.
  • Spherical particles useful herein include nylon, polyethylene, and polytetrafluoroethylene. Platelet-shaped particles which are useful herein include mica, talc, lauroyl lysine, boron nitride, and barium sulfate.
  • compositions comprising superabsorbent polymers of the present invention may also, optionally, be utilized as topical active carrier systems.
  • suitable topical active ingredients include anti-microbials; anti-fungals; topical analgesics and anesthetics; anti-inflammatories; protectants; astringents; anti-septics such as benzenthonium chloride; skin moisturizer compounds such as lauryl lysine, waxes, petroleum jelly and oils; skin treatment compounds such as alpha hydroxy acids; antioxidants; medicinals such as camphor, zinc oxide and sulfur; among others, including vitamins such as vitamin A, D and E, in amounts ranging from about 0.1% to about 50%) by weight of the final compositions.
  • inert and active agents can be added if desired, such as dyes, colorants, and/or preservatives, for visual appeal and performance impression.
  • compositions of the present invention can be conveniently prepared in the form of dusting powders, liquid body powders, stick forms or cream forms.
  • a most preferred application form is a dusting powder for the application to the skin.
  • compositions of the present invention can be prepared by well-known mixing or blending procedures using a commercial blender.
  • the superabsorbent polymer and optional additives can be pre-mixed and then blended directly into the powder carriers and other ingredients or through a liquid addition bar.
  • Example 1 Powder compositions were prepared as follows:
  • Example 2 Compositions were prepared as follows:
  • the formulated powder was liberally applied to buttocks and thighs of an infant suffering from diaper rash.
  • the composition of Example 2 visibly adhered to the skin better and for a much longer period of time as compared to a comparative example without any superabsorbent polymers added.
  • the rash completely cleared up. There was not evidence in any instance of the caking of the powder on the skin, nor there was any sign of irritation of the portions of the infant's skin treated with the composition of the present invention.
  • Example 3 A formulation for a liquid powder of the present invention with excellent adhesion properties can be prepared by mixing melted petroleum jelly with decamethylcyclopentasiloxane, and then adding the resulting colloidal mixture to corn starch to form a liquid body powder mixture according to the formula:
  • Example 4 A face powder with superior adhesion properties compared to a comparative product which does not contain any superabsorbent polymers can be prepared using the following formulation:

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Medicinal Preparation (AREA)

Abstract

L'invention porte sur une composition dermatologique, cosmétique ou pharmaceutique présentant une résistance supérieure au délavage, et comprenant de 25 % en poids à 99 % en poids d'une poudre support, et de 0,01 % en poids à 20 % en poids d'un polymère superabsorbant, et dont l'adhérence à la peau est améliorée par rapport aux compositions analogues ne contenant pas ledit polymère.
PCT/GB2000/003948 2000-03-08 2000-10-13 Composition cosmetique a caracteristiques ameliorees d'absorption et d'adherence WO2001066078A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2000278058A AU2000278058A1 (en) 2000-03-08 2000-10-13 Cosmetic composition having improved absorption and adhesion characteristics

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US52116500A 2000-03-08 2000-03-08
US09/521,165 2000-03-08

Publications (1)

Publication Number Publication Date
WO2001066078A1 true WO2001066078A1 (fr) 2001-09-13

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WO (1) WO2001066078A1 (fr)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003030853A1 (fr) * 2001-10-05 2003-04-17 Colgate-Palmolive Company Produits pour aisselles a constituant capteur d'humidite
WO2003030854A1 (fr) * 2001-10-05 2003-04-17 Colgate-Palmolive Company Produits de gel pour les aisselles avec composante polymere superabsorbante
WO2004000255A1 (fr) * 2002-06-24 2003-12-31 Colgate-Palmolive Company Batonnet antitranspirant a effet rafraichissant et sechant
WO2004000254A1 (fr) * 2002-06-24 2003-12-31 Colgate-Palmolive Company Antiperspirant solide et mou a effet rafraichissant et sec
WO2005087181A2 (fr) * 2004-02-27 2005-09-22 Colgate-Palmolive Company Desodorant sec contenant un alcool de sesquiterpene et un oxyde de zinc
WO2005107695A1 (fr) * 2004-05-10 2005-11-17 Unilever Plc Compositions cosmetiques comprenant de la fecule de manioc
FR2874174A1 (fr) * 2004-08-11 2006-02-17 Bourjois Soc Par Actions Simpl Composition cosmetique comprenant un polymere superabsorbant
FR2902004A1 (fr) * 2006-04-14 2007-12-14 Lvmh Rech Composition cosmetique de type masque pour le soin de la peau
WO2012059343A1 (fr) * 2010-11-05 2012-05-10 L'oreal Composition sous forme de poudre comprenant au moins une huile essentielle et une fécule de manioc modifiée
US9549891B2 (en) 2012-03-19 2017-01-24 The Procter & Gamble Company Superabsorbent polymers and sunscreen actives for use in skin care compositions
US10285926B2 (en) 2015-06-29 2019-05-14 The Procter & Gamble Company Superabsorbent polymers and starch powders for use in skin care compositions
EP3708146A1 (fr) * 2019-03-12 2020-09-16 The Procter & Gamble Company Compositions cosmétiques anhydres et leurs utilisations
EP3708147A1 (fr) * 2019-03-12 2020-09-16 The Procter & Gamble Company Compositions cosmétiques anhydres et leurs utilisations
US11376199B2 (en) 2019-03-12 2022-07-05 The Procter & Gamble Company Anhydrous cosmetic compositions and uses

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2384493A1 (fr) * 1977-03-23 1978-10-20 Stiefel Laboratories Composition de poudre absorbante pour la toilette du corps
US4272514A (en) * 1979-11-06 1981-06-09 Spenco Medical Corporation High absorption body powder
JPS6081120A (ja) * 1983-10-13 1985-05-09 Shiseido Co Ltd メーキャップ化粧料
JPH04356415A (ja) * 1990-08-02 1992-12-10 Kao Corp 汗のべとつき抑制剤

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2384493A1 (fr) * 1977-03-23 1978-10-20 Stiefel Laboratories Composition de poudre absorbante pour la toilette du corps
US4272514A (en) * 1979-11-06 1981-06-09 Spenco Medical Corporation High absorption body powder
JPS6081120A (ja) * 1983-10-13 1985-05-09 Shiseido Co Ltd メーキャップ化粧料
JPH04356415A (ja) * 1990-08-02 1992-12-10 Kao Corp 汗のべとつき抑制剤

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 198525, Derwent World Patents Index; AN 1985-149123, XP002157853 *
DATABASE WPI Week 199304, Derwent World Patents Index; AN 1993-030479, XP002157854 *

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003030853A1 (fr) * 2001-10-05 2003-04-17 Colgate-Palmolive Company Produits pour aisselles a constituant capteur d'humidite
WO2003030854A1 (fr) * 2001-10-05 2003-04-17 Colgate-Palmolive Company Produits de gel pour les aisselles avec composante polymere superabsorbante
WO2004000255A1 (fr) * 2002-06-24 2003-12-31 Colgate-Palmolive Company Batonnet antitranspirant a effet rafraichissant et sechant
WO2004000254A1 (fr) * 2002-06-24 2003-12-31 Colgate-Palmolive Company Antiperspirant solide et mou a effet rafraichissant et sec
US6793915B1 (en) 2002-06-24 2004-09-21 Colgate-Palmolive Company Cool and dry soft solid antiperspirant
US6805855B2 (en) 2002-06-24 2004-10-19 Colgate-Palmolive Company Cool and dry antiperspirant stick
WO2005087181A2 (fr) * 2004-02-27 2005-09-22 Colgate-Palmolive Company Desodorant sec contenant un alcool de sesquiterpene et un oxyde de zinc
WO2005087181A3 (fr) * 2004-02-27 2006-01-05 Colgate Palmolive Co Desodorant sec contenant un alcool de sesquiterpene et un oxyde de zinc
WO2005107695A1 (fr) * 2004-05-10 2005-11-17 Unilever Plc Compositions cosmetiques comprenant de la fecule de manioc
AU2005239805B2 (en) * 2004-05-10 2008-01-24 Unilever Plc Cosmetic compositons with tapioca starch
FR2874174A1 (fr) * 2004-08-11 2006-02-17 Bourjois Soc Par Actions Simpl Composition cosmetique comprenant un polymere superabsorbant
WO2006024768A2 (fr) * 2004-08-11 2006-03-09 Bourjois Composition cosmetique comprenant un polymere superabsorbant
WO2006024768A3 (fr) * 2004-08-11 2006-12-28 Bourjois Composition cosmetique comprenant un polymere superabsorbant
FR2902004A1 (fr) * 2006-04-14 2007-12-14 Lvmh Rech Composition cosmetique de type masque pour le soin de la peau
WO2012059343A1 (fr) * 2010-11-05 2012-05-10 L'oreal Composition sous forme de poudre comprenant au moins une huile essentielle et une fécule de manioc modifiée
FR2967060A1 (fr) * 2010-11-05 2012-05-11 Oreal Composition sous forme de poudre comprenant au moins une huile essentielle, un amidon de tapioca modifie
US9549891B2 (en) 2012-03-19 2017-01-24 The Procter & Gamble Company Superabsorbent polymers and sunscreen actives for use in skin care compositions
US9839598B2 (en) 2012-03-19 2017-12-12 The Procter & Gamble Company Superabsorbent polymers and sunscreen actives for use in skin care compositions
US10285926B2 (en) 2015-06-29 2019-05-14 The Procter & Gamble Company Superabsorbent polymers and starch powders for use in skin care compositions
EP3708146A1 (fr) * 2019-03-12 2020-09-16 The Procter & Gamble Company Compositions cosmétiques anhydres et leurs utilisations
EP3708147A1 (fr) * 2019-03-12 2020-09-16 The Procter & Gamble Company Compositions cosmétiques anhydres et leurs utilisations
WO2020185457A1 (fr) * 2019-03-12 2020-09-17 The Procter & Gamble Company Compositions cosmétiques anhydres et leurs utilisations
WO2020185458A1 (fr) * 2019-03-12 2020-09-17 The Procter & Gamble Company Compositions cosmétiques anhydres et leurs utilisations
US11376199B2 (en) 2019-03-12 2022-07-05 The Procter & Gamble Company Anhydrous cosmetic compositions and uses

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