US2662058A - Petroleum lubricating jelly - Google Patents
Petroleum lubricating jelly Download PDFInfo
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- US2662058A US2662058A US102448A US10244849A US2662058A US 2662058 A US2662058 A US 2662058A US 102448 A US102448 A US 102448A US 10244849 A US10244849 A US 10244849A US 2662058 A US2662058 A US 2662058A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M5/00—Solid or semi-solid compositions containing as the essential lubricating ingredient mineral lubricating oils or fatty oils and their use
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/14—Inorganic compounds or elements as ingredients in lubricant compositions inorganic compounds surface treated with organic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/14—Synthetic waxes, e.g. polythene waxes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/17—Fisher Tropsch reaction products
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
- C10M2215/065—Phenyl-Naphthyl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/26—Amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/02—Bearings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Semi-solids; greasy
Definitions
- This invention relates to improved petroleum lubricating jellies and, in particular, to thixotropic petroleum lubricating jellies having high dropping points, low running torques, and low oil separation characteristics.
- thixotropic petroleum jellies having thixotropic properties, that is, of jellylike consistency when quiescent and liquid when agitated, have been recommended.
- thixotropic petroleum jellies are mixtures of lubricating oils with Waxes having melting points above about 120 F. and generally have a soap incorporated therein.
- These compositions have proved to be satisfactory lubricants under most condi- 7 tions: however, they are subject to the disadvantage that they have relatively low dropping points and are rather unstable with respect to oil separation characteristics.
- compositions result which while retaining their thixotropic properties have considerably higher dropping points and lower oil separation characteristics than similar soap-containing compositions. This combination of properties makes these compositions particularly valuable in certain types of lubrication such, for example, as in the lubrication of aircraft instruments and control bearings.
- these compositions are better retained in the bearings at elevated temperatures; and because of their relative softness at low temperatures, as indicated by their high penetration and low running torque at low temperatures, they function satisfactorily as lubricants over the broad temperature range to which such bearings are subjected.
- wax of high melting point advantageously wax substantially free from oil and having an ASTM wax melting point above about 120 F.
- Ceresin wax such as is obtained from ozokerit'e having an ASTM wax melting point of about 160 F, has proved particularly satisfactory although other waxes may be used, such as beeswax, paraifin wax, petroleum ceresin, or refined rod wax, montan wax, shellac wax, or mixtures of these waxes with oil-free petroleum waxes having melting points above about 120 F.
- the amount of wax used may be varied widely, depending on the particular wax used and the properties desired in the lubricant. In general, the amount of wax used should be suiiicient to provide an oil-waxmixture having a cloud point above about F. In order to obtain this cloud point, at least about 4.0 per cent by weight of wax having a melting point above about F. is usually required. Generally, it is not necessary to employ more than about 28 per cent by Weight of Wax.
- the oil used in forming these thixotropic jellies may vary widely in properties. I substantially any oil properly designated as a lubricating oil may be used, depending upon its intended application. Thus, oils having viscosities as low as 50 SUS and as high as 4000 SUS at 100 F. may be used under appropriate circumstances. The viscosity index of the oil may vary from 50 to or more In general, however,
- oils having viscosity indexes above about ⁇ )0 are most advantageous.
- the percentage of 011 in the jelly may be varied to regulate the temperature-consistency characteristics of the In general,
- lubricant but generally should comprise about '70 to about 90 per cent by weight of the total composition.
- the bentonite compounds employed in accordance with the invention are compounds composed of a montmorillonite mineral in which at least a part of the cation content of the mineral has been replaced by an organic base.
- Clays that swell at least to some extent on being contacted with water and contain as a primary constituent a mineral of the group known as montmorillonites are generally referred to as bentonites.
- Such clays, which contain exchangeable alkali metal atoms either naturally or after treatment, constitute the raw materials employed in making the bentonite-organic base compounds us'euin the compositions of this invention.
- the bentonite-organic base compounds are preferably prepared as described in U. S. Patent No. 2,033,856, issued March 10, 1936, by bringing together the bentonite and the 'organic'b'as'e in the presence of aqueous mineral acid toeffect base exchange.
- the organic bases should pref- Among these reactive bases are many alkaloids, and cyclic, aliphatic, and heterocyclic amines.
- the bentonite-organic base compounds used in preparing the lubricating compositions of this invention are preferably those prepared by bringing together a bentonite clay and such organic bases as aliphatic amines, their salts; and quaternary ammonium salts.
- Examples of such amines and salts are: decylamine, dodecylamine, tetradecylamine, hexadecylamine, octadecylamin'e, hexadecyl ammonium acetate, octadecyl ammonium acetate, dimethyldioctyl ammonium acetate, dimethyldidodecyl ammonium acetate, dimethyldodecyhexadecyl ammonium acetate, dimethyldicetyl ammonium acetate, dimethylhexadecyloctadecyl ammonium acetate, dimethyldi'octadecyl ammonium acetate, and the corresponding chlorides and quaternary ammonium chlorides.
- the organic bases employed should be such as to impart substantial organ'ophilic properties to the resulting. compounds.
- the preferred bentonite compounds are prepared from quaternary ammonium com'poun'ds'in which the N-substituents are aliphatic groups containing at least one alkyl group with a total of at least to 12 carbon'at'om's. When aliphatic amines are used they preferably contain at least one alkyl group containing at least 10 to12. carbon atoms.
- the amount of bentonite compound used may vary over wide limits depending upon theparticu' lar oil "with which the bentonite compound is to be blended andupon the properties desired in the final lubricating compositions. Whileas niuch'as 15 per cent by weight of the total composition may comprise the bentonite compound, I prefer to use smaller amounts, that is, the order' of about? to 10 per cent by'weight. Itshould'be understood, however, that depending upon the consistency of' the composition desired, less than 2 per cent or more than 10 per cent of the bentonite compound may be employed. In accordance with my invention, the bentonite compound isalways used in amounts su'chthat the weight acid; acetone, methyl alcohol,
- Suitable solvating agents are polar organic compounds such as organic acids, esters, alcohols, ethers, ketones,
- solvating agents are: ethyl acetate, acetic ethyl alcohol, benzoyl chloride, butyl stearate, cocoanut oil, cyclohexanone, ethylene dichloride, ethyl ether,
- diaryl amine oxidation inhibitor of the diaryl amines which may beused in the compositions of my invention may be'ment'ioned diphenylamine, plienyl alpha naphthylamine, phenyl beta naphthylamine, alpha alpha, alpha beta andbeta beta dinaphthylamines, and the like.
- Other diarylamines as well as their derivatives wherein one or more hydrogen atoms on one or both ofthe aromatic nuclei are replaced by a substituent group may be'u'sed.
- the substituting group may, for example, be one selected from the class of aryl, alk'y'l, amino, ar yloxy and alkyloxy radicals, so long asaie presence of the substituent does not render the diaryl amine insoluble in oil, or soluble in water or otherwise adversely affect the effectiveness of the diaryl amine.
- the amount of the diaryl amine employed Will depend to a large extent upon the severity of theconditiens towhich the composition'is subjected, as Well as-the particular diaryl amine used. For instance whenthe com-position issubiected to prolonged use under oxidizing conditions',-such as under extreme temperature and pressure, the diaryl amin'eTequirement will be much greater than when relatively mild" operating conditions are-encountered.
- the amount'of the diaryl amine employed is between about 0.1 and 1.5 percent by weight based upon the weight of the total-composition; In'a'n y case, ail-amount suiiicient' -t'o"substantially inhibit bneauonm uetencranen is employed.
- the Wax and oil to which a diaryl amine has previously beenadded are customarily first mated together.
- the bentonite compound is then stirred into the mixture and. the mixture is milled until a uniform composition entrained.
- composition B a-thixotropic oil-Wax mixture
- Composition A a thixotropic soap-type jelly
- composition Parts by Weight:
- a thixotropic petroleum lubricating jelly consisting essentially of a mixture of a major amount of a petroleum lubricating oil with a wax having a wax melting point above about 120 F., the amount of said wax being sufficient to provide an oil-wax mixture having a cloudspoint above about 110 F., and having incorporated therein an amount of a compound of a bentonite and an organic nitrogen base such that the ratio of bentonite compound to wax by weight is not greater than 1: 1.
- a thixotropic petroleum lubricating jelly consisting essentially of a mixture of a major amount of a petroleum lubricating oil with a wax having a wax melting point above about 120 F., the amount of said wax being sufficient to provide an oil-wax mixture having a cloud point above about 110 F., and having incorporated therein an amount of a compound of a bentonite and an aliphatic organic nitrogen base such that the ratio of bentonitecompound to wax by weight is between about 1:1 and 1 15.
- a thixotropic petroleum lubricating jelly consisting of about to about per cent by weight of a petroleum lubricating oil, at least about 4.0 per cent by weight of a Wax having a melting point above about F., and between about 1 and about 15 per cent by weight of a compound of a bentonite and an aliphatic organic nitrogen base such that the ratio of the bentonite compound to wax by weight is not greater than 1:1.
- a thixotropic petroleum lubricating jelly consisting of about '70 to about 90 per cent by weight of a petroleum lubricating oil, about 4.0 to about 28 per cent by weight of a wax having a melting point above about 120 F., and between about 2.0 and 10.0 per cent by weight of a compound of a bentonite and an aliphatic organic nitrogen base such that the ratio of the bentonite compound to wax by weight is between about 1:1 and 1:15.
- a thixotropic petroleum lubricating jelly consisting of about 70 to about 90 per cent by weight of a petroleum lubricating oil, about 4 to about 28.0 per cent by weight of ceresin wax, about 2 to about 10 per cent by weight of dimethyldicetyl ammonium bentonite such that the ratio of the bentonite compound to wax by weight is between about 1:1 and 1:15, and between about 0.1 and about 1.5 per cent by weight of a diaryl amine.
- a thixotropic petroleum lubricating jelly consisting of about '78 per cent by weight of a petroleum lubricating oil, about 18 per cent by weight of ceresin wax, about 4 per cent by weight of dimethyldicetyl ammonium bentonite and about 0.2 per cent by weight of diphenyl amine.
- a thixotropic petroleum lubricating jelly consisting of about 70 to about 90 per cent by weight of a petroleum lubricating oil, about 4.0 to about 28 per cent by weight of a wax having a melting point above about 120 F., and between about 2.0 and 10.0 per cent by weight of dimethyldicetyl ammonium bentonite such that the ratio of the bentonite compound to wax by weight is between about 1: 1 and 1:15.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Description
Patented Dec. 8, 1953 UNITED STATES PATENT OFFICE 2,662,058 I PETROLEUM LUBRICATING JELLY Paul R. McCarthy, Allison Park, Pa., assignor to Gulf Research & Development Company, Pittsburgh, Pa., a corporation of Delaware No Drawing. Application June 30, 1949, Serial No. 102,448
7 Claims.
This invention relates to improved petroleum lubricating jellies and, in particular, to thixotropic petroleum lubricating jellies having high dropping points, low running torques, and low oil separation characteristics.
In certain types of lubrication there are encountered conditions under which neither greases nor liquid oils are entirely satisfactory lubricants. For example, in the lubrication of ball bearings and other open bearing surfaces, particularly in .greases are too viscous.
For this type of lubrication, petroleum jellies having thixotropic properties, that is, of jellylike consistency when quiescent and liquid when agitated, have been recommended. These thixotropic petroleum jellies are mixtures of lubricating oils with Waxes having melting points above about 120 F. and generally have a soap incorporated therein. These compositions have proved to be satisfactory lubricants under most condi- 7 tions: however, they are subject to the disadvantage that they have relatively low dropping points and are rather unstable with respect to oil separation characteristics.
It is therefore an object achieved by this invention to provide thixotropic petroleum jellies having high dropping points and low oil separation characteristics.
This and other objects achieved by' this invention will become apparent in the following detailed description thereof. 7 f
I have discovered that when a compound of a bentonite with an organic base is incorporated in thixotropic mixtures of wax and oil in such amount that the ratio of bentonite compound to wax is substantially less than 1:1, compositions result which while retaining their thixotropic properties have considerably higher dropping points and lower oil separation characteristics than similar soap-containing compositions. This combination of properties makes these compositions particularly valuable in certain types of lubrication such, for example, as in the lubrication of aircraft instruments and control bearings. Because of their thixotropic properties combined with high dropping point and low oil separation, these compositions are better retained in the bearings at elevated temperatures; and because of their relative softness at low temperatures, as indicated by their high penetration and low running torque at low temperatures, they function satisfactorily as lubricants over the broad temperature range to which such bearings are subjected.
In preparing the improved thixotropic jellies of my invention, wax of high melting point, advantageously wax substantially free from oil and having an ASTM wax melting point above about 120 F., is used. Ceresin wax such as is obtained from ozokerit'e having an ASTM wax melting point of about 160 F, has proved particularly satisfactory although other waxes may be used, such as beeswax, paraifin wax, petroleum ceresin, or refined rod wax, montan wax, shellac wax, or mixtures of these waxes with oil-free petroleum waxes having melting points above about 120 F.
The amount of wax used may be varied widely, depending on the particular wax used and the properties desired in the lubricant. In general, the amount of wax used should be suiiicient to provide an oil-waxmixture having a cloud point above about F. In order to obtain this cloud point, at least about 4.0 per cent by weight of wax having a melting point above about F. is usually required. Generally, it is not necessary to employ more than about 28 per cent by Weight of Wax.
The oil used in forming these thixotropic jellies may vary widely in properties. I substantially any oil properly designated as a lubricating oil may be used, depending upon its intended application. Thus, oils having viscosities as low as 50 SUS and as high as 4000 SUS at 100 F. may be used under appropriate circumstances. The viscosity index of the oil may vary from 50 to or more In general, however,
I have found oils having viscosity indexes above about {)0 are most advantageous. The percentage of 011 in the jelly may be varied to regulate the temperature-consistency characteristics of the In general,
v erably be titratable'with mineral acids.
lubricant, but generally should comprise about '70 to about 90 per cent by weight of the total composition.
The bentonite compounds employed in accordance with the invention are compounds composed of a montmorillonite mineral in which at least a part of the cation content of the mineral has been replaced by an organic base. Clays that swell at least to some extent on being contacted with water and contain as a primary constituent a mineral of the group known as montmorillonites are generally referred to as bentonites. Such clays, which contain exchangeable alkali metal atoms either naturally or after treatment, constitute the raw materials employed in making the bentonite-organic base compounds us'euin the compositions of this invention. So far as known, all naturally occurring 'montmorillonites contain some magnesium and'certainofthe'm, as exemplified by Hector clay, contain such ahigh percentage of magnesium that they-largely have magnesium in place of the aluminum content characteristic of the more typical montmorillonites.
The bentonite-organic base compounds are preferably prepared as described in U. S. Patent No. 2,033,856, issued March 10, 1936, by bringing together the bentonite and the 'organic'b'as'e in the presence of aqueous mineral acid toeffect base exchange. The organic bases should pref- Among these reactive bases are many alkaloids, and cyclic, aliphatic, and heterocyclic amines. The bentonite-organic base compounds used in preparing the lubricating compositions of this invention are preferably those prepared by bringing together a bentonite clay and such organic bases as aliphatic amines, their salts; and quaternary ammonium salts. Examples of such amines and salts are: decylamine, dodecylamine, tetradecylamine, hexadecylamine, octadecylamin'e, hexadecyl ammonium acetate, octadecyl ammonium acetate, dimethyldioctyl ammonium acetate, dimethyldidodecyl ammonium acetate, dimethyldodecyhexadecyl ammonium acetate, dimethyldicetyl ammonium acetate, dimethylhexadecyloctadecyl ammonium acetate, dimethyldi'octadecyl ammonium acetate, and the corresponding chlorides and quaternary ammonium chlorides. The organic bases employed should be such as to impart substantial organ'ophilic properties to the resulting. compounds. The preferred bentonite compounds are prepared from quaternary ammonium com'poun'ds'in which the N-substituents are aliphatic groups containing at least one alkyl group with a total of at least to 12 carbon'at'om's. When aliphatic amines are used they preferably contain at least one alkyl group containing at least 10 to12. carbon atoms.
The amount of bentonite compound used may vary over wide limits depending upon theparticu' lar oil "with which the bentonite compound is to be blended andupon the properties desired in the final lubricating compositions. Whileas niuch'as 15 per cent by weight of the total composition may comprise the bentonite compound, I prefer to use smaller amounts, that is, the order' of about? to 10 per cent by'weight. Itshould'be understood, however, that depending upon the consistency of' the composition desired, less than 2 per cent or more than 10 per cent of the bentonite compound may be employed. In accordance with my invention, the bentonite compound isalways used in amounts su'chthat the weight acid; acetone, methyl alcohol,
of one or more solvating agents. "Suitable solvating agents are polar organic compounds such as organic acids, esters, alcohols, ethers, ketones,
and aldehydes, especially low molecular weight compounds of these classes. Examples of suitable solvating agents are: ethyl acetate, acetic ethyl alcohol, benzoyl chloride, butyl stearate, cocoanut oil, cyclohexanone, ethylene dichloride, ethyl ether,
fur-fural, isoamy-l acetate, methyl ethyl ketone,
and nitrobenzene. In cases Where the use of a solvating agent is desirable for effecting more rapid and more complete dispersion of the organic bentonite compound in the oil, ordinarily only a relatively small amount of such agent may be necessary. However, as much as aboiit50 'per cent by weight based on the amount of the beetonite compound can be" used.
In instances where the petroleum lubricating jelly is subjected to 'p'rolong'edu'se under oxidizing. conditions, I advantageously incorporate in the lubricating jelly a small amount-of a diaryl amine oxidation inhibitor; of the diaryl amines which may beused in the compositions of my invention may be'ment'ioned diphenylamine, plienyl alpha naphthylamine, phenyl beta naphthylamine, alpha alpha, alpha beta andbeta beta dinaphthylamines, and the like. Other diarylamines as well as their derivatives wherein one or more hydrogen atoms on one or both ofthe aromatic nuclei are replaced by a substituent group may be'u'sed. The substituting group may, for example, be one selected from the class of aryl, alk'y'l, amino, ar yloxy and alkyloxy radicals, so long asaie presence of the substituent does not render the diaryl amine insoluble in oil, or soluble in water or otherwise adversely affect the effectiveness of the diaryl amine. The amount of the diaryl amine employed Will depend to a large extent upon the severity of theconditiens towhich the composition'is subjected, as Well as-the particular diaryl amine used. For instance whenthe com-position issubiected to prolonged use under oxidizing conditions',-such as under extreme temperature and pressure, the diaryl amin'eTequirement will be much greater than when relatively mild" operating conditions are-encountered. Generally, however, the amount'of the diaryl amine employed is between about 0.1 and 1.5 percent by weight based upon the weight of the total-composition; In'a'n y case, ail-amount suiiicient' -t'o"substantially inhibit bneauonm uetencranen is employed.
In compounding these thixotlopic lubricants, the Wax and oil to which a diaryl amine has previously beenadded are customarily first mated together. The bentonite compound is then stirred into the mixture and. the mixture is milled until a uniform composition entrained.
The advantageous properties obtained by incorporating. dimethyl'dicetyl ammonium bentonite in a-thixotropic oil-Wax mixture (Composition B), as compared with a thixotropic soap-type jelly As examples of some- (Composition A), are illustrated in the followin table.
Composition (Parts by Weight):
Oil (58 SUV at 100 F.) 78.0 78.0 Aluminum soap 4.0 White Oeresin Wax 18. 0 18. 0 Dimethyldicetyl amnioni n1 bento 4. 0 Diphenylamine (added) 0. 2 0.2 Consistency (A. S. T. M. D217-44l):
Unworked 235 330 Worked 379 385 Percent Increase over Unworked. 61. 2 l6 7 Dropping Point (A. S. T. M. D566-42), "F 199 450 ABEC Machine:
Final Running Torque- At 80 F 180 175 At 150 F 120 90 Percent Grease Leakage-At 80 F 31 24 Low Temperature Torque:
202? Ball Bearing, Gm-Cm for 1st Revolu- At 0 F 712 961 At 40 F 815 1, 090 Oil Separation, percent: Grams in Nickel Filter Gone, 24 hrs. at 160 F (i9 6 It is apparent from these results that a compound of a bentonite with an organic base has a very beneficial effect in increasing the dropping point and. decreasing the oil separation of a thixotropic lubricant. It will be seen from a comparison of the results obtained that there is less change in consistency between the unworked and worked composition containing dimethyldicetyl ammonium bentonite than there is in the composition containing soap. It will further be seen that whereas the low temperature torque of the composition containing the bentonite compound is slightly greater than that of the soap-containing compound, the running torque of the bentonite compound is lower.
While this invention has been described with reference to specific details and examples of the production and properties of the compositions of my invention, it is to be understood that the invention is not intended to be limited to such details and examples except as recited hereinafter in the appended claims.
I claim:
1. A thixotropic petroleum lubricating jelly consisting essentially of a mixture of a major amount of a petroleum lubricating oil with a wax having a wax melting point above about 120 F., the amount of said wax being sufficient to provide an oil-wax mixture having a cloudspoint above about 110 F., and having incorporated therein an amount of a compound of a bentonite and an organic nitrogen base such that the ratio of bentonite compound to wax by weight is not greater than 1: 1.
2. A thixotropic petroleum lubricating jelly consisting essentially of a mixture of a major amount of a petroleum lubricating oil with a wax having a wax melting point above about 120 F., the amount of said wax being sufficient to provide an oil-wax mixture having a cloud point above about 110 F., and having incorporated therein an amount of a compound of a bentonite and an aliphatic organic nitrogen base such that the ratio of bentonitecompound to wax by weight is between about 1:1 and 1 15. V
3. A thixotropic petroleum lubricating jelly consisting of about to about per cent by weight of a petroleum lubricating oil, at least about 4.0 per cent by weight of a Wax having a melting point above about F., and between about 1 and about 15 per cent by weight of a compound of a bentonite and an aliphatic organic nitrogen base such that the ratio of the bentonite compound to wax by weight is not greater than 1:1.
4. A thixotropic petroleum lubricating jelly consisting of about '70 to about 90 per cent by weight of a petroleum lubricating oil, about 4.0 to about 28 per cent by weight of a wax having a melting point above about 120 F., and between about 2.0 and 10.0 per cent by weight of a compound of a bentonite and an aliphatic organic nitrogen base such that the ratio of the bentonite compound to wax by weight is between about 1:1 and 1:15.
5. A thixotropic petroleum lubricating jelly consisting of about 70 to about 90 per cent by weight of a petroleum lubricating oil, about 4 to about 28.0 per cent by weight of ceresin wax, about 2 to about 10 per cent by weight of dimethyldicetyl ammonium bentonite such that the ratio of the bentonite compound to wax by weight is between about 1:1 and 1:15, and between about 0.1 and about 1.5 per cent by weight of a diaryl amine.
6. A thixotropic petroleum lubricating jelly consisting of about '78 per cent by weight of a petroleum lubricating oil, about 18 per cent by weight of ceresin wax, about 4 per cent by weight of dimethyldicetyl ammonium bentonite and about 0.2 per cent by weight of diphenyl amine.
7. A thixotropic petroleum lubricating jelly consisting of about 70 to about 90 per cent by weight of a petroleum lubricating oil, about 4.0 to about 28 per cent by weight of a wax having a melting point above about 120 F., and between about 2.0 and 10.0 per cent by weight of dimethyldicetyl ammonium bentonite such that the ratio of the bentonite compound to wax by weight is between about 1: 1 and 1:15.
' PAUL R. MCCARTHY.
References Cited in the file of this patent UNITED STATES PATENTS Number Name Date 2,248,636 Marsden July 8, 1941 2,320,002 Lutz May 25, 1943 2,435,655 Rhodes et al. Feb. 10, 1948 2,450,221 Ashburn Sept. 28, 1948 2,531,440 Jordan Nov. 28, 1950
Claims (1)
1. A THIOXTROPIC PETROLEUM LUBRICATING JELLY CONSISTING ESSENTIALLY OF A MIXTUE OF A MAJOR AMOUNT OF A PETROLEUM LUBRICATING OIL WITH A WAX HAVING A WAX MELTING POINT ABOVE ABOUT 120* F., THE AMOUNT OF SAID WAX BEING SUFFICIENT TO PROVIDE AN OIL-WAX MIXTURE HAVING A CLOUD POINT ABOVE ABOUT 110* F., AND HAVING INCORPORATED THEREIN AN AMOUNT OF A COMPOUND OF A BENTONITE AND AN ORGANIC NITROGEN BASE SUCH THAT THE RATION OF BENTONITE COMPOUND TO WAX BY WEIGHT IS NOT GREATER THAN 1:1.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US102448A US2662058A (en) | 1949-06-30 | 1949-06-30 | Petroleum lubricating jelly |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US102448A US2662058A (en) | 1949-06-30 | 1949-06-30 | Petroleum lubricating jelly |
Publications (1)
Publication Number | Publication Date |
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US2662058A true US2662058A (en) | 1953-12-08 |
Family
ID=22289896
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US102448A Expired - Lifetime US2662058A (en) | 1949-06-30 | 1949-06-30 | Petroleum lubricating jelly |
Country Status (1)
Country | Link |
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US (1) | US2662058A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2833720A (en) * | 1954-09-02 | 1958-05-06 | Phillips Petroleum Co | Organophilic bentonite bodied lubricant containing a nitroparaffin |
US20100248879A1 (en) * | 2007-12-12 | 2010-09-30 | Tsubakimoto Chain Co. | Lubricant composition for chains, and chain |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2248636A (en) * | 1939-03-25 | 1941-07-08 | Gen Electric | Bentonite product |
US2320002A (en) * | 1941-08-22 | 1943-05-25 | Gulf Research Development Co | Petroleum lubricating jelly |
US2435655A (en) * | 1944-06-29 | 1948-02-10 | Standard Oil Co | Lubricant |
US2450221A (en) * | 1945-08-21 | 1948-09-28 | Texas Co | Shear-resistant grease |
US2531440A (en) * | 1947-03-29 | 1950-11-28 | Nat Lead Co | Lubricants |
-
1949
- 1949-06-30 US US102448A patent/US2662058A/en not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2248636A (en) * | 1939-03-25 | 1941-07-08 | Gen Electric | Bentonite product |
US2320002A (en) * | 1941-08-22 | 1943-05-25 | Gulf Research Development Co | Petroleum lubricating jelly |
US2435655A (en) * | 1944-06-29 | 1948-02-10 | Standard Oil Co | Lubricant |
US2450221A (en) * | 1945-08-21 | 1948-09-28 | Texas Co | Shear-resistant grease |
US2531440A (en) * | 1947-03-29 | 1950-11-28 | Nat Lead Co | Lubricants |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2833720A (en) * | 1954-09-02 | 1958-05-06 | Phillips Petroleum Co | Organophilic bentonite bodied lubricant containing a nitroparaffin |
US20100248879A1 (en) * | 2007-12-12 | 2010-09-30 | Tsubakimoto Chain Co. | Lubricant composition for chains, and chain |
EP2236592A1 (en) * | 2007-12-12 | 2010-10-06 | Tsubakimoto Chain Co. | Lubricant composition for chain and chain |
EP2236592A4 (en) * | 2007-12-12 | 2011-05-18 | Tsubakimoto Chain Co | Lubricant composition for chain and chain |
US8771119B2 (en) | 2007-12-12 | 2014-07-08 | Tsubakimoto Chain Co. | Lubricant composition for chains, and chain |
TWI473875B (en) * | 2007-12-12 | 2015-02-21 | Tsubakimoto Chain Co | Lubricant composition for chain and chain |
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