US20160089317A1

US20160089317A1 - Antiperspirant and deodorant compositions comprising malodor reduction compositions

Info

Publication number: US20160089317A1
Application number: US14/865,048
Authority: US
Inventors: Jonathan Robert Cetti; Gayle Marie Frankenbach; Steven Anthony Horenziak; Judith Ann Hollingshead
Original assignee: Procter and Gamble Co
Current assignee: Procter and Gamble Co
Priority date: 2014-09-26
Filing date: 2015-09-25
Publication date: 2016-03-31
Also published as: JP2017535628A; CA2959695A1; CA2959691A1; US20170249408A1; US10113140B2; JP6923439B2; US20170255725A1; US20170137752A1; US11334694B2; WO2016049389A1; WO2016049395A1; US20160296656A1; US20160089465A1; JP2017536859A; JP2019162428A; US20160092661A1; CN107073154A; US11334695B2; US20190155975A9; KR101971378B1

Abstract

The present invention relates to antiperspirant and deodorant compositions comprising malodor reduction compositions and methods of making and using such antiperspirant and deodorant compositions. Such antiperspirant and deodorant compositions comprising the malodor control technologies disclosed herein provide malodor control without leaving an undesirable scent and when perfume is used to scent such compositions, such scent is not unduely altered by the malodor control technology.

Description

FIELD OF THE INVENTION

The present invention relates to antiperspirant and deodorant compositions comprising malodor reduction compositions and methods of making and using such antiperspirant and deodorant compositions.

BACKGROUND OF THE INVENTION

Unscented or scented products are desired by consumers as they may be considered more natural and discreet than scented products. Manufacturers of unscented or scented products for controlling malodors rely on malodor reduction ingredients or other technologies (e.g. filters) to reduce malodors. However, effectively controlling malodors, for example, amine-based malodors (e.g. fish and urine), thiol and sulfide-based malodors (e.g. garlic and onion), C₂-C₁₂carboxylic acid based malodors (e.g. body and pet odor), indole based malodors (e.g. fecal and bad breath), short chain fatty aldehyde based malodors (e.g. grease) and geosmin based malodors (e.g. mold/mildew) may be difficult, and the time required for a product to noticeably reduce malodors may create consumer doubt as to the product's efficacy on malodors. Often times, manufacturers incorporate scented perfumes to help mask these difficult malodors.
Unfortunately, malodor control technologies typically cover up the malodor with a stronger scent and thus interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology. Thus, limited nature of the current malodor control technologies is extremely constraining. Thus what is needed is a broader palette of malodor control technologies so the perfume community can deliver the desired level of character in a greater number of situations/applications. Surprisingly, Applicants recognized that in addition to blocking a malodor's access to a sensory cell, in order to achieve the desired goal, a malodor control technology must leave such sensor cell open to other molecules, for example scent molecules. Thus, antiperspirant and deodorant compositions comprising the malodor control technologies disclosed herein provide malodor control without leaving an undesirable scent and when perfume is used to scent such compositions, such scent is not unduely altered by the malodor control technology.

SUMMARY OF THE INVENTION

DETAILED DESCRIPTION OF THE INVENTION

Definitions
“Ambient” refers to surrounding conditions at about one atmosphere of pressure, 50% relative humidity and about 25° C.
“Anhydrous” refers to compositions and/or components which are substantially free of added or free water.
“Antiperspirant composition” refers to antiperspirant compositions, deodorant compositions, and the like. For example, antiperspirant creams, gels, soft solid sticks, body sprays, and aerosols.
“Soft solid” refers to a composition with a static yield stress of about 200 Pa to about 1,300 Pa. The term “solid” includes granular, powder, bar and tablet product forms.
The term “fluid” includes liquid, gel, paste and gas product forms.
The term “situs” includes paper products, fabrics, garments, hard surfaces, hair and skin.
The term “substantially free of refers to about 2% or less, about 1% or less, or about 0.1% or less of a stated ingredient. “Free of refers to no detectable amount of the stated ingredient or thing.
As used herein “MORV” is the calculated malodor reduction value for a subject material. A material's MORV indicates such material's ability to decrease or even eliminate the perception of one or more malodors. For purposes of the present application, a material's MORV is calculated in accordance with method found in the test methods section of the present application.
As used herein, “malodor” refers to compounds generally offensive or unpleasant to most people, such as the complex odors associated with bowel movements.
As used herein, “neutralize” or “neutralization” refers to the ability of a compound or product to reduce or eliminate malodorous compounds. Odor neutralization may be partial, affecting only some of the malodorous compounds in a given context, or affecting only part of a malodorous compound. A malodorous compound may be neutralized by chemical reaction resulting in a new chemical entity, by sequestration, by chelation, by association, or by any other interaction rendering the malodorous compound less malodorous or non-malodorous. Neutralization is distinguishable from odor masking or odor blocking by a change in the malodorous compound, as opposed to a change in the ability to perceive the malodor without any corresponding change in the condition of the malodorous compound. Malodor neutralization provides a sensory and analytically measurable (e.g. gas chromatograph) malodor reduction. Thus, if a malodor reduction composition delivers genuine malodor neutralization, the composition will reduce malodors in the vapor and/or liquid phase.
As used herein, “odor blocking” refers to the ability of a compound to dull the human sense of smell.
As used herein, “odor masking” refers to the ability of a compound with a non-offensive or pleasant smell that is dosed such that it limits the ability to sense a malodorous compound. Odor-masking may involve the selection of compounds which coordinate with an anticipated malodor to change the perception of the overall scent provided by the combination of odorous compounds.
As used herein, the term “perfume” does not include malodor reduction materials. Thus, the perfume portion of a composition does not include, when determining the perfume's composition, any malodor reduction materials found in the composition as such malodor reduction materials are described herein. In short, if a material has a malodor reduction value “MORV” that is within the range of the MORV recited in the subject claim, such material is a malodor reduction material for purposes of such claim.
As used herein, the terms “a” and “an” mean “at least one”.
As used herein, the terms “include”, “includes” and “including” are meant to be non-limiting.
Unless otherwise noted, all component or composition levels are in reference to the active portion of that component or composition, and are exclusive of impurities, for example, residual solvents or by-products, which may be present in commercially available sources of such components or compositions.
All percentages and ratios are calculated by weight unless otherwise indicated. All percentages and ratios are calculated based on the total composition unless otherwise indicated.
It should be understood that every maximum numerical limitation given throughout this specification includes every lower numerical limitation, as if such lower numerical limitations were expressly written herein. Every minimum numerical limitation given throughout this specification will include every higher numerical limitation, as if such higher numerical limitations were expressly written herein. Every numerical range given throughout this specification will include every narrower numerical range that falls within such broader numerical range, as if such narrower numerical ranges were all expressly written herein.

Malodor Reduction Materials

A non-limiting set of suitable malodor reduction materials are provided in the tables below. For ease of use, each material in Tables 1-3 is assigned a numerical indentifier which is found in the column for each table that is designated Number. Table 4 is a subset of Table 1, Table 5 is a subset of Table 2 and Table 6 is a subset of Table 3 and there for Tables 4, 5 and 6 each use the same numerical identifier as found, respectively, in Tables 1-3.

Codes

A=Vapor Pressure>0.1 torr
B=Vapor Pressure is between 0.01 torr and 0.1 torr

C=LogP<3

D=LogP>3

E=Probability of Ingredient Color Instability=0%

F=Probability of Ingredient Color Instability<71%

G=Odor Detection Threshold less than p.ol=8
H=Odor Detection Threshold greater than p.ol=8
I=Melamine formaldehyde PMC Headspace Response Ratio greater than or equal to 10
J=Melamine formaldehyde PMC leakage less than or equal to 5%
K=Log of liquid dish neat product liquid-air partition coefficient greater than or equal to -7
L=Log of liquid dish neat product liquid-air partition coefficient greater than or equal to -5

TABLE 1

List of materials with at least one MORV from 1 to 5

Num-		CAS	Comment
ber	Material Name	Number	Code

1	2-ethylhexyl (Z)-3-(4-	5466-77-3	DEFHJ
	methoxyphenyl)acrylate
2	2,4-dimethyl-2-(5,5,8,8-tetramethyl-	131812-67-4	DFHJ
	5,6,7,8-tetrahydronaphthalen-2-yl)-
	1,3-dioxolane
3	1,1-dimethoxynon-2-yne	13257-44-8	ACEFHJK
4	para-Cymen-8-ol	1197-01-9	BCGIJK
7	3-methoxy-7,7-dimethyl-10-	216970-21-7	BDEFHJK
	methylenebicyclo[4.3.1]decane
9	Methoxycyclododecane	2986-54-1	DEFHJK
10	1,1-dimethoxycyclododecane	950-33-4	DEFHJK
11	(Z)-tridec-2-enenitrile	22629-49-8	DEFHJK
13	Oxybenzone	131-57-7	DEFGJ
14	Oxyoctaline formate	65405-72-3	DFHJK
16	4-methyl-1-oxaspiro[5.5]undecan-4-	57094-40-3	CFGIJK
	ol
17	7-methyl-2H-benzo[b][1,4]dioxepin-	28940-11-6	CGIK
	3(4H)-one
18	1,8-dioxacycloheptadecan-9-one	1725-01-5	DGJ
21	4-(tert-pentyl)cyclohexan-1-one	16587-71-6	ADFGIJKL
22	o-Phenyl anisol	86-26-0	DEFHJK
23	3a,5,6,7,8,8b-hexahydro-	823178-41-2	DEFHJK
	2,2,6,6,7,8,8-heptamethyl-4H-
	indeno(4,5-d)-1,3-dioxole
25	7-isopropyl-8,8-dimethyl-6,10-	62406-73-9	BDEFHIJK
	dioxaspiro[4.5]decane
28	Octyl 2-furoate	39251-88-2	DEFHJK
29	Octyl acetate	112-14-1	BDEFHJKL
30	octanal propylene glycol acetal	74094-61-4	BDEFHJKL
31	Octanal	124-13-0	ACHIKL
32	Octanal dimethyl acetal	10022-28-3	ACEFGJKL
33	Myrcene	123-35-3	ADEFGIKL
34	Myrcenol	543-39-5	BCEFGIJK
35	Myrcenyl acetate	1118-39-4	ADEFGJK
36	Myristaldehyde	124-25-4	DFHJK
37	Myristicine	607-91-0	CGJK
38	Myristyl nitrile	629-63-0	DEFHJK
39	2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a-	103614-86-4	DEFHIJK
	octahydronaphthalen-1-ol
42	Ocimenol	5986-38-9	BCHIJK
43	Ocimenol	28977-58-4	BCHIJK
47	Nopyl acetate	128-51-8	DEFHJK
48	Nootkatone	4674-50-4	DHJK
49	Nonyl alcohol	143-08-8	BDEFGIJKL
50	Nonaldehyde	124-19-6	ADHIKL
52	12-methyl-14-tetradec-9-enolide	223104-61-8	DFHJK
57	N-ethyl-p-menthane-3-carboxamide	39711-79-0	DEFGIJK
61	1-(3-methylbenzofuran-2-yl)ethan-1-	23911-56-0	CEFHIK
	one
62	2-methoxynaphthalene	93-04-9	BDEFHK
63	Nerolidol	7212-44-4	DEFHJK
64	Nerol	106-25-2	BCHIK
65	1-ethyl-3-	31996-78-8	ACEFHIJKL
	methoxytricyclo[2.2.1.02,6]heptane
67	Methyl (E)-non-2-enoate	111-79-5	ADEFHJKL
68	10-isopropyl-2,7-dimethyl-1-	89079-92-5	BDEFHIJK
	oxaspiro[4.5]deca-3,6-diene
69	2-(2-(4-methylcyclohex-3-en-1-	95962-14-4	DHJK
	yl)propyl)cyclopentan-1-one
70	Myrtenal	564-94-3	ACFHIJKL
71	(E)-4-(2,2,3,6-	54992-90-4	BDEFHIJK
	tetramethylcyclohexyl)but-3-en-2-
	one
74	Myraldyl acetate	53889-39-7	DHJK
75	Musk tibetine	145-39-1	DHIJ
76	1,7-dioxacycloheptadecan-8-one	3391-83-1	DGJ
77	Musk ketone	81-14-1	DHJ
78	Musk ambrette	83-66-9	DHIJ
79	3-methylcyclopentadecan-1-one	541-91-3	DEFHJK
80	(E)-3-methylcyclopentadec-4-en-1-	82356-51-2	DHJK
	one
82	3-methyl-4-phenylbutan-2-ol	56836-93-2	BCEFHIK
83	1-(4-isopropylcyclohexyl)ethan-1-ol	63767-86-2	BDEFHIJK
85	Milk Lactone	72881-27-7	DEFHJK
91	Methyl octine carbonate	111-80-8	BDEFHKL
92	Methyl octyl acetaldehyde	19009-56-4	ADFHJKL
93	6,6-dimethoxy-2,5,5-trimethylhex-2-	67674-46-8	ACHIJKL
	ene
98	Methyl phenylethyl carbinol	2344-70-9	BCEFHIK
100	Methyl stearate	112-61-8	DEFHJ
101	Methyl nonyl acetaldehyde dimethyl	68141-17-3	BDEFHJK
	acetal
102	Methyl nonyl ketone	112-12-9	BDFHJKL
103	Methyl nonyl acetaldehyde	110-41-8	BDFHJK
104	Methyl myristate	124-10-7	DEFHJK
105	Methyl linoleate	112-63-0	DEFHJ
106	Methyl lavender ketone	67633-95-8	CFHJK
108	Methyl isoeugenol	93-16-3	ACEFHK
109	Methyl hexadecanoate	112-39-0	DEFHJK
110	Methyl eugenol	93-15-2	ACEFHK
112	Methyl epijasmonate	1211-29-6	CHJK
113	Methyl dihydrojasmonate	24851-98-7	DFHJK
114	Methyl diphenyl ether	3586-14-9	DEFHJK
117	Methyl cinnamate	103-26-4	BCEFHK
119	Methyl chavicol	140-67-0	ADEFHK
120	Methyl beta-naphthyl ketone	93-08-3	CEFHK
122	Methyl 2-octynoate	111-12-6	ACEFHKL
123	Methyl alpha-cyclogeranate	28043-10-9	ACHIJKL
126	Methoxycitronellal	3613-30-7	ACFGIJK
128	Menthone 1,2-glycerol ketal	67785-70-0	CEFHJ
	(racemic)
130	Octahydro-1H-4,7-methanoindene-1-	30772-79-3	BCFHIJKL
	carbaldehyde
134	3-(3-(tert-butyl)phenyl)-2-	62518-65-4	BDHJK
	methylpropanal
135	(E)-4-(4,8-dimethylnona-3,7-dien-1-	38462-23-6	DEFHJK
	yl)pyridine
137	(E)-trideca-3,12-dienenitrile	134769-33-8	DEFHJK
140	2,2-dimethyl-3-(m-tolyl)propan-1-ol	103694-68-4	CEFHIJK
141	2,4-dimethyl-4,4a,5,9b-	27606-09-3	CEFHJK
	tetrahydroindeno[1,2-d][1,3]dioxine
142	Maceal	67845-30-1	BDFHJK
143	4-(4-hydroxy-4-	31906-04-4	CHJ
	methylpentyl)cyclohex-3-ene-1-
	carbaldehyde
145	l-Limonene	5989-54-8	ADEFGIJKL
146	(Z)-3-hexen-1-yl-2-cyclopenten-1-	53253-09-1	BDHK
	one
148	Linalyl octanoate	10024-64-3	DEFHJ
149	Linalyl isobutyrate	78-35-3	BDHJK
152	Linalyl benzoate	126-64-7	DFHJ
153	Linalyl anthranilate	7149-26-0	DFHJ
155	Linalool oxide (furanoid)	60047-17-8	BCHIJK
156	linalool oxide	1365-19-1	CGIJK
158	(2Z,6E)-3,7-dimethylnona-2,6-	61792-11-8	BDEFHJK
	dienenitrile
159	3-(4-methylcyclohex-3-en-1-	6784-13-0	ACFHIJK
	yl)butanal
161	(2,5-dimethyl-1,3-dihydroinden-2-	285977-85-7	CEFHJK
	yl)methanol
162	3-(4-(tert-butyl)phenyl)-2-	80-54-6	BDHJK
	methylpropanal
167	(E)-1-(1-methoxypropoxy)hex-3-ene	97358-54-8	ACEFGJKL
168	Leaf acetal	88683-94-7	ACEFGJKL
170	l-Carveol	2102-58-1	BCHIJK
174	Lauryl alcohol	112-53-8	DEFGJK
175	Lauryl acetate	112-66-3	DEFHJK
176	Lauric acid	143-07-7	DEFHJ
177	Lactojasmone	7011-83-8	BDEFHIJKL
178	Lauraldehyde	112-54-9	BDFHJK
179	3,6-dimethylhexahydrobenzofuran-	92015-65-1	BCEFHIJKL
	2(3H)-one
182	4-(1-ethoxyvinyl)-3,3,5,5-	36306-87-3	BDFHIJK
	tetramethylcyclohexan-1-one
183	Khusimol	16223-63-5	CEFHJK
184	5-(sec-butyl)-2-(2,4-	117933-89-8	DEFHJ
	dimethylcyclohex-3-en-1-yl)-5-
	methyl-1,3-dioxane
185	(1-methyl-2-((1,2,2-	198404-98-7	DEFHJK
	trimethylbicyclo[3.1.0]hexan-3-
	yl)methyl)cyclopropyl)methanol
186	2-propylheptanenitrile	208041-98-9	ADEFHIJKL
187	(E)-6-(pent-3-en-1-yl)tetrahydro-2H-	32764-98-0	BCFHIKL
	pyran-2-one
189	2-hexylcyclopentan-1-one	13074-65-2	BDFHJKL
190	2-methyl-4-phenyl-1,3-dioxolane	33941-99-0	BCEFGIK
192	2,6,9,10-tetramethyl-1-	71078-31-4	BDEFHIJK
	oxaspiro(4.5)deca-3,6-diene
193	Isopulegol	89-79-2	BCEFHIJKL
195	Isopropyl palmitate	142-91-6	DEFHJ
196	Isopropyl myristate	110-27-0	DEFHJK
197	Isopropyl dodecanoate	10233-13-3	DEFHJK
199	Isopimpinellin	482-27-9	CFGJ
206	Iso3-methylcyclopentadecan-1-one	3100-36-5	DEFGJK
208	Isomenthone	491-07-6	ADEFGIJKL
209	Isojasmone	95-41-0	BDFHJKL
210	Isomenthone	36977-92-1	ADEFGIJKL
211	Isohexenyl cyclohexenyl	37677-14-8	DFHJK
	carboxaldehyde
212	Isoeugenyl benzyl ether	120-11-6	DFHJ
215	1-((2S,3S)-2,3,8,8-tetramethyl-	54464-57-2	DHJK
	1,2,3,4,5,6,7,8-octahydronaphthalen-
	2-yl)ethan-1-one
218	Isocyclocitral	1335-66-6	ACFHIJKL
221	Isobutyl quinoline	65442-31-1	DEFHJK
227	Isobornylcyclohexanol	68877-29-2	DEFHJK
228	Isobornyl propionate	2756-56-1	BDEFHIJK
229	Isobornyl isobutyrate	85586-67-0	BDEFHIJK
230	Isobornyl cyclohexanol	66072-32-0	DEFHJK
231	Isobornyl acetate	125-12-2	ADEFHIJKL
233	Isobergamate	68683-20-5	DEFHJK
234	Isoamyl undecylenate	12262-03-2	DEFHJK
238	Isoamyl laurate	6309-51-9	DEFHJK
242	Isoambrettolide	28645-51-4	DGJ
243	Irisnitrile	29127-83-1	ADEFHKL
244	Indolene	68527-79-7	DEFHJ
246	Indol/Hydroxycitronellal Schiff base	67801-36-9	DEFHJ
247	4,4a,5,9b-tetrahydroindeno[1,2-	18096-62-3	BCEFGJK
	d][1,3]dioxine
249	Hydroxy-citronellol	107-74-4	CEFGIJK
252	2-cyclododecylpropan-1-ol	118562-73-5	DEFHJK
253	Hydrocitronitrile	54089-83-7	CEFHJK
254	Hydrocinnamyl alcohol	122-97-4	BCEFHIK
256	Hydratropaldehyde dimethyl acetal	90-87-9	ACEFHJK
259	5-ethyl-4-hydroxy-2-methylfuran-	27538-09-6	CFGIK
	3(2H)-one
260	2,3-dihydro-3,3-dimethyl-1H-indene-	173445-44-8	DHJK
	5-propanal
261	3-(3,3-dimethyl-2,3-dihydro-1H-	173445-65-3	DHJK
	inden-5-yl)propanal
263	Hexyl octanoate	1117-55-1	DEFHJK
267	Hexyl hexanoate	6378-65-0	DEFHJKL
269	Hexyl cinnamic aldehyde	101-86-0	DHJ
271	Hexyl benzoate	6789-88-4	DEFHJK
274	Hexenyl tiglate	84060-80-0	BDEFHJK
276	(E)-3,7-dimethylocta-2,6-dien-1-yl	3681-73-0	DEFHJ
	palmitate
277	Hexadecanolide	109-29-5	DEFGJK
278	2-butyl-4,4,6-trimethyl-1,3-dioxane	54546-26-8	ADEFHIJKL
280	Ethyl (1R,2R,3R,4R)-3-	116126-82-0	BDEFHIJK
	isopropylbicyclo[2.2.1]hept-5-ene-2-
	carboxylate
281	3a,4,5,6,7,7a-hexahydro-1H-4,7-	5413-60-5	CEFGJK
	methanoinden-6-yl acetate
285	2-(1-(3,3-	141773-73-1	DEFHJ
	dimethylcyclohexyl)ethoxy)-2-
	methylpropyl propionate
286	Heliotropine diethyl acetal	40527-42-2	CEFGJ
288	Helional	1205-17-0	CHJK
289	(E)-oxacyclohexadec-13-en-2-one	111879-80-2	DGJK
290	Gyrane	24237-00-1	ADEFHIJKL
292	Guaiol	489-86-1	DEFHJK
293	1-(2,6,6-trimethylcyclohex-2-en-1-	68611-23-4	DHJK
	yl)pentan-3-one
294	Ethyl 2-ethyl-6,6-dimethylcyclohex-	57934-97-1	BDEFHIJK
	2-ene-1-carboxylate
295	Germacrene B	15423-57-1	DEFHJK
296	Germacrene D	23986-74-5	DEFHJK
300	Geranyl phenylacetate	102-22-7	DFHJ
301	Geranyl phenyl acetate	71648-43-6	DFHJ
303	Geranyl linalool	1113-21-9	DFHJ
307	Geranyl cyclopentanone	68133-79-9	DHJK
316	gamma-Undecalactone (racemic)	104-67-6	DEFHJKL
317	gamma-Terpinyl acetate	10235-63-9	BDHJK
318	gamma-Terpineol	586-81-2	BCGIJK
321	gamma-Nonalactone	104-61-0	BCEFHIKL
322	gamma-Muurolene	30021-74-0	DEFHJKL
323	gamma-(E)-6-(pent-3-en-1-	63095-33-0	BCEFHKL
	yl)tetrahydro-2H-pyran-2-one
324	gamma-Ionone	79-76-5	BDEFHIJK
325	gamma-Himachalene	53111-25-4	BDEFHJKL
328	gamma-Gurjunene	22567-17-5	DEFHJKL
329	gamma-Eudesmol	1209-71-8	DFHJK
330	gamma-Dodecalactone	2305-05-7	DEFHJK
331	gamma-Damascone	35087-49-1	BDEFHIJK
332	gamma-Decalactone	706-14-9	BDEFHIJKL
333	gamma-Cadinene	39029-41-9	DEFHJKL
334	1-(3,3-dimethylcyclohexyl)pent-4-	56973-87-6	BDEFHJK
	en-1-one
335	4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-	1222-05-5	DEFHJK
	hexahydrocyclopenta[g]isochromene
336	Furfuryl octanoate	39252-03-4	DEFHJK
338	Furfuryl hexanoate	39252-02-3	CEFHJK
339	Furfuryl heptanoate	39481-28-2	CEFHJK
342	2-methyldecanenitrile	69300-15-8	BDEFHJKL
343	8,8-dimethyl-3a,4,5,6,7,7a-	76842-49-4	DEFHJK
	hexahydro-1H-4,7-methanoinden-6-
	yl propionate
344	Ethyl (3aR,4S,7R,7aR)-octahydro-	80657-64-3	DEFHIJK
	3aH-4,7-methanoindene-3a-
	carboxylate
347	Diethyl cyclohexane-1,4-	72903-27-6	CEFHJK
	dicarboxylate
349	(6-isopropyl-9-methyl-1,4-	63187-91-7	CEFHJ
	dioxaspiro[4.5]decan-2-yl)methanol
350	2-isobutyl-4-methyltetrahydro-2H-	63500-71-0	BCEFHIJK
	pyran-4-ol
352	Undec-10-enenitrile	53179-04-7	BDEFHJK
353	(Z)-6-ethylideneoctahydro-2H-5,8-	69486-14-2	CEFGJK
	methanochromen-2-one
356	3-(2-ethylphenyl)-2,2-	67634-15-5	BDHJK
	dimethylpropanal
358	(E)-4,8-dimethyldeca-4,9-dienal	71077-31-1	BDFHJK
359	(E)-4-((3aR,4R,7R,7aR)-	501929-47-1	DEFHJK
	1,3a,4,6,7,7a-hexahydro-5H-4,7-
	methanoinden-5-ylidene)-3-
	methylbutan-2-ol
360	8,8-dimethyl-3a,4,5,6,7,7a-	171102-41-3	DEFHJK
	hexahydro-1H-4,7-methanoinden-6-
	yl acetate
361	3-(4-ethylphenyl)-2,2-	134123-93-6	DEFHJK
	dimethylpropanenitrile
362	2-heptylcyclopentan-1-one	137-03-1	DFHJKL
363	1-ethoxyethoxy Cyclododecane	389083-83-4	DEFHJK
364	3-cyclohexene-1-carboxylic acid,	815580-59-7	ACHIJKL
	2,6,6-trimethyl-, methyl ester
368	Farnesyl acetate	29548-30-9	DEFHJK
369	Farnesol	4602-84-0	DEFHJK
370	Oxacyclohexadecan-2-one	106-02-5	DEFGJK
371	1-cyclopentadec-4-en-1-one	14595-54-1	DEFGJK
372	1-cyclopentadec-4-en-1-one	35720-57-1	DEFGJK
373	2-methoxy-4-(4-	128489-04-3	CGJ
	methylenetetrahydro-2H-pyran-2-
	yl)phenol
374	Eugenyl acetate	93-28-7	CFHJK
375	Eugenol	97-53-0	CHIK
377	Ethylmethylphenylglycidate	77-83-8	CFHJK
378	Ethylene brassylate	105-95-3	DFGJ
381	Ethyl undecylenate	692-86-4	DEFHJK
385	Ethyl palmitate	628-97-7	DEFHJ
386	Ethyl nonanoate	123-29-5	BDEFHJKL
388	Ethyl myristate	124-06-1	DEFHJK
390	Ethyl linalool	10339-55-6	BCEFHJK
391	Ethyl laurate	106-33-2	DEFHJK
394	Ethyl hexyl ketone	925-78-0	ADFHIKL
397	Ethyl decanoate	110-38-3	BDEFHJK
398	Ethyl gamma-Safranate	35044-57-6	ADHIJK
407	Ethyl 3-phenylglycidate	121-39-1	CGJK
413	6-ethyl-2,10,10-trimethyl-1-	79893-63-3	BDEFHIJK
	oxaspiro[4.5]deca-3,6-diene
414	Elemol	639-99-6	DEFHJK
415	(2-(1-ethoxyethoxy)ethyl)benzene	2556-10-7	BCEFHJK
416	(E)-3-methyl-5-(2,2,3-	67801-20-1	DHJK
	trimethylcyclopent-3-en-1-yl)pent-4-
	en-2-ol
417	d-xylose	58-86-6	CGIJ
418	(E)-4-((3aS,7aS)-octahydro-5H-4,7-	30168-23-1	DFHJK
	methanoinden-5-ylidene)butanal
421	Dodecanal dimethyl acetal	14620-52-1	DEFHJK
424	d-Limonene	5989-27-5	ADEFGIJKL
425	Dipropylene Glycol	25265-71-8	CEFGIK
426	Dispirone	83863-64-3	BDEFHJK
428	Diphenyloxide	101-84-8	BDEFHK
429	Diphenylmethane	101-81-5	DEFGK
432	Dimethyl benzyl carbinyl butyrate	10094-34-5	DEFHJK
436	2,6-dimethyloct-7-en-4-one	1879-00-1	ADEFHIJKL
441	Octahydro-1H-4,7-methanoinden-5-	64001-15-6	DEFHJKL
	yl acetate
444	Dihydrocarveol acetate	20777-49-5	BDEFHIJK
445	Dihydrocarveol	619-01-2	BCEFHIJKL
449	Dihydro Linalool	18479-51-1	BCEFGIJKL
450	Dihydro Isojasmonate	37172-53-5	DHJK
453	Dibutyl sulfide	544-40-1	ADEFHIKL
457	Dibenzyl	103-29-7	DEFGJK
459	delta-Undecalactone	710-04-3	DEFHJKL
461	delta-Elemene	20307-84-0	BDEFHJK
462	delta-Guaiene	3691-11-0	DEFHJKL
463	delta-Dodecalactone	713-95-1	DEFHJK
464	delta-Decalactone	705-86-2	BDEFHIJKL
465	delta-Cadinene	483-76-1	DEFHJKL
466	delta-damascone	57378-68-4	ADHIJK
467	delta-Amorphene	189165-79-5	DEFHJKL
468	delta-3-Carene	13466-78-9	ADEFGIJKL
470	Decylenic alcohol	13019-22-2	BDEFHJK
471	Decyl propionate	5454-19-3	DEFHJK
473	Decanal diethyl acetal	34764-02-8	DEFHJK
474	Decahydro-beta-naphthol	825-51-4	BCEFGIK
475	1-cyclohexylethyl (E)-but-2-enoate	68039-69-0	BDFHJK
478	3-(4-isopropylphenyl)-2-	103-95-7	BDFHJK
	methylpropanal
479	Cyclotetradecane	295-17-0	DEFGJKL
480	Cyclopentadecanone	502-72-7	DEFGJK
482	Cyclohexyl salicylate	25485-88-5	DFGJ
484	3a,4,5,6,7,7a-hexahydro-1H-4,7-	113889-23-9	DEFHJK
	methanoinden-6-yl butyrate
485	Cyclic ethylene dodecanedioate	54982-83-1	DFGJ
486	8,8-dimethyl-1,2,3,4,5,6,7,8-	68991-97-9	DHJK
	octahydronaphthalene-2-
	carbaldehyde
487	3a,4,5,6,7,7a-hexahydro-1H-4,7-	67634-20-2	DEFHJK
	methanoinden-5-yl isobutyrate
488	Curzerene	17910-09-7	DHJK
491	Cumic alcohol	536-60-7	CHIJK
493	Coumarone	1646-26-0	BCEFHIK
497	2-(3-phenylpropyl)pyridine	2110-18-1	CEFHJK
498	Dodecanenitrile	2437-25-4	DEFHJK
501	(E)-cycloheptadec-9-en-1-one	542-46-1	DEFGJ
502	Citryl acetate	6819-19-8	DFHJK
503	Citrus Propanol	15760-18-6	CEFHIJK
505	Citronitrile	93893-89-1	CEFHJK
519	Citral propylene glycol acetal	10444-50-5	CEFHJK
520	Citral dimethyl acetal	7549-37-3	BCEFHJK
521	Citral diethyl acetal	7492-66-2	BDEFHJK
524	cis-Ocimene	3338-55-4	ADGIKL
527	cis-Limonene oxide	13837-75-7	ADEFGIJKL
529	Cis-iso-ambrettolide	36508-31-3	DGJ
530	cis-6-nonenol	35854-86-5	BCEFHIKL
531	cis-carveol	1197-06-4	BCHIJK
532	cis-4-Decen-1-al	21662-09-9	ADHKL
534	cis-3-hexenyl-cis-3-hexenoate	61444-38-0	BDEFHJK
537	cis-3-Hexenyl salicylate	65405-77-8	DEFGJ
541	Cis-3-hexenyl Benzoate	25152-85-6	DEFHJK
544	cis-3-Hexenyl 2-methylbutyrate	53398-85-9	ADEFHJKL
546	cis-3, cis-6-nonadienol	53046-97-2	ACEFHK
548	Cinnamyl propionate	103-56-0	DEFHJK
550	Cinnamyl isobutyrate	103-59-3	DEFHJK
551	Cinnamyl formate	104-65-4	BCEFHK
552	Cinnamyl cinnamate	122-69-0	DHJ
553	Cinnamyl acetate	103-54-8	BCEFHK
555	Cinnamic alcohol	104-54-1	BCEFHIK
558	Cetyl alcohol	36653-82-4	DEFHJ
559	(E)-1-(2,6,6-trimethylcyclohex-2-en-	79-78-7	DHJK
	1-yl)hepta-1,6-dien-3-one
560	2-methyl-4-(2,6,6-trimethylcyclohex-	65405-84-7	DFHJK
	1-en-1-yl)butanal
561	(3aR,5aR,9aR,9bR)-3a,6,6,9a-	3738-00-9	DEFHJK
	tetramethyldodecahydronaphtho[2,1-
	b]furan
562	1,6-dioxacycloheptadecan-7-one	6707-60-4	DGJ
563	1-(6-(tert-butyl)-1,1-dimethyl-2,3-	13171-00-1	DEFHJK
	dihydro-1H-inden-4-yl)ethan-1-one
565	Cedryl methyl ether	19870-74-7	ADEFHJK
566	Cedryl formate	39900-38-4	BDEFHJK
567	Cedryl acetate	77-54-3	DEFHJK
568	(4Z,8Z)-1,5,9-trimethyl-13-	71735-79-0	DFHJK
	oxabicyclo[10.1.0]trideca-4,8-diene
569	Cedrol	77-53-2	DEFHJK
570	5-methyl-1-(2,2,3-	139539-66-5	DEFHJK
	trimethylcyclopent-3-en-1-yl)-6-
	oxabicyclo[3.2.1]octane
571	5-methyl-1-(2,2,3-	426218-78-2	DFHJ
	trimethylcyclopent-3-en-1-yl)-6-
	oxabicyclo[3.2.1]octane
572	1,1,2,3,3-pentamethyl-1,2,3,5,6,7-	33704-61-9	BDEFHIJK
	hexahydro-4H-inden-4-one
573	Caryophyllene alcohol acetate	32214-91-8	DEFHJK
574	Caryolan-1-ol	472-97-9	DEFHJK
577	Carvyl acetate	97-42-7	BDHIJK
578	Caprylnitrile	124-12-9	ACEFGIKL
580	Caprylic alcohol	111-87-5	ACEFGIKL
581	Caprylic acid	124-07-2	BCEFHIK
582	Capric acid	334-48-5	DEFHJK
584	Capraldehyde	112-31-2	ADHKL
586	3-(4-methoxyphenyl)-2-	5462-06-6	BCHJK
	methylpropanal
587	Camphorquinone	10373-78-1	ACEFGIJK
589	Camphene	79-92-5	ADEFGIJKL
591	Ethyl 2-methyl-4-oxo-6-	59151-19-8	DHJ
	pentylcyclohex-2-ene-1-carboxylate
592	Butylated hydroxytoluene	128-37-0	DEFGIJK
594	Butyl stearate	123-95-5	DEFHJ
595	Butyl butyryl lactate	7492-70-8	CEFGJK
599	Butyl 10-undecenoate	109-42-2	DEFHJK
600	2-methyl-4-(2,2,3-	72089-08-8	DEFHJK
	trimethylcyclopent-3-en-1-yl)butan-
	1-ol
601	3-(4-(tert-butyl)phenyl)propanal	18127-01-0	BDHJK
603	Bornyl isobutyrate	24717-86-0	BDEFHIJK
604	Bornyl acetate	76-49-3	ADEFHIJKL
606	2-ethoxy-2,6,6-trimethyl-9-	68845-00-1	BDEFHJK
	methylenebicyclo[3.3.1]nonane
607	(ethoxymethoxy)cyclododecane	58567-11-6	DEFHJK
608	Bisabolene	495-62-5	DEFHJK
609	Bigarade oxide	72429-08-4	ADEFHJKL
610	beta-Vetivone	18444-79-6	DHJK
611	beta-Terpinyl acetate	10198-23-9	BDHJK
612	beta-Terpineol	138-87-4	BCGIJK
613	beta-Sinensal	60066-88-8	DHJK
614	beta-Sesquiphellandrene	20307-83-9	DEFHJK
615	beta-Selinene	17066-67-0	BDEFGJK
616	beta-Santalol	77-42-9	DEFHJK
618	beta-Pinene	127-91-3	ADEFGIJKL
620	beta-Naphthyl ethyl ether	93-18-5	BDEFHJK
621	beta-Patchoulline	514-51-2	BDEFGJKL
624	beta-Himachalene Oxide	57819-73-5	BDFHJK
625	beta-Himachalene	1461-03-6	DEFHJKL
626	beta-Guaiene	88-84-6	DEFHJKL
627	(2,2-dimethoxyethyl)benzene	101-48-4	DHJK
628	beta-Farnesene	18794-84-8	DEFHJK
631	beta-Copaene	18252-44-3	BDEFHJKL
632	beta-Cedrene	546-28-1	BDEFGJKL
633	beta-Caryophyllene	87-44-5	DEFHJKL
635	beta-Bisabolol	15352-77-9	DFHJK
636	Beta ionone epoxide	23267-57-4	BDEFHIJK
638	Bergaptene	484-20-8	CGJ
639	Benzyl-tert-butanol	103-05-9	CEFGJK
644	Benzyl laurate	140-25-0	DEFHJ
649	Benzyl dimethyl carbinol	100-86-7	BCEFGIK
650	Benzyl cinnamate	103-41-3	DHJ
653	Benzyl benzoate	120-51-4	DHJ
655	Benzophenone	119-61-9	DEFHK
658	7-isopentyl-2H-	362467-67-2	DHJ
	benzo[b][1,4]dioxepin-3(4H)-one
659	2′-isopropyl-1,7,7-	188199-50-0	DEFHJK
	trimethylspiro[bicyclo[2.2.1]heptane-
	2,4′-[1,3]dioxane]
660	4-(4-methylpent-3-en-1-yl)cyclohex-	21690-43-7	DEFHJK
	3-ene-1-carbonitrile
661	Aurantiol	89-43-0	DEFHJ
663	Anisyl phenylacetate	102-17-0	DFHJ
668	Methyl (E)-octa-4,7-dienoate	189440-77-5	ACEFHKL
671	Amyl Cinnamate	3487-99-8	DEFHJK
673	(3aR,5aS,9aS,9bR)-3a,6,6,9a-	6790-58-5	DEFHJK
	tetramethyldodecahydronaphtho[2,1-
	b]furan
674	(4aR,5R,7aS,9R)-2,2,5,8,8,9a-	211299-54-6	DEFHJK
	hexamethyloctahydro-4H-4a,9-
	methanoazuleno[5,6-d][1,3]dioxole
675	2,5,5-trimethyl-1,2,3,4,5,6,7,8-	71832-76-3	DEFHJK
	octahydronaphthalen-2-ol
676	2,5,5-trimethyl-1,2,3,4,5,6,7,8-	41199-19-3	DEFHJK
	octahydronaphthalen-2-ol
677	1-((2-(tert-	139504-68-0	DEFHJK
	butyl)cyclohexyl)oxy)butan-2-ol
678	(3S,5aR,7aS,11aS,11bR)-3,8,8,11a-	57345-19-4	DEFHJ
	tetramethyldodecahydro-5H-3,5a-
	epoxynaphtho[2,1-c]oxepine
679	2,2,6,6,7,8,8-heptamethyldecahydro-	476332-65-7	ADEFHJK
	2H-indeno[4,5-b]furan
680	2,2,6,6,7,8,8-heptamethyldecahydro-	647828-16-8	ADEFHJK
	2H-indeno[4,5-b]furan
681	Amber acetate	37172-02-4	BDEFHJK
682	Alpinofix	811436-82-5	DEFHJ
683	alpha-Thujone	546-80-5	ADEFGIJKL
684	alpha-Vetivone	15764-04-2	DHJK
686	alpha-Terpinyl propionate	80-27-3	BDEFHJK
691	alpha-Sinensal	17909-77-2	DHJK
692	alpha-Selinene	473-13-2	BDEFHJK
693	alpha-Santalene	512-61-8	ADEFHJKL
694	alpha-Santalol	115-71-9	DEFHJK
696	alpha-Patchoulene	560-32-7	ADEFHJKL
697	alpha-neobutenone	56973-85-4	BDHJK
698	alpha-Muurolene	10208-80-7	DEFHJKL
700	alpha-methyl ionone	127-42-4	BDHJK
702	alpha-Limonene	138-86-3	ADEFGIJKL
704	alpha-Irone	79-69-6	BDHJK
706	alpha-Humulene	6753-98-6	DEFHJK
707	alpha-Himachalene	186538-22-7	BDEFHJK
708	alpha-Gurjunene	489-40-7	BDEFHJKL
709	alpha-Guaiene	3691-12-1	DEFHJKL
710	alpha-Farnesene	502-61-4	DEFHJK
711	alpha-Fenchene	471-84-1	ADEFGIJKL
712	alpha-Eudesmol	473-16-5	DEFHJK
713	alpha-Curcumene	4176-17-4	DEFHJK
714	alpha-Cubebene	17699-14-8	ADEFHJKL
715	alpha-Cedrene epoxide	13567-39-0	ADEFHJK
716	alpha-Cadinol	481-34-5	DEFHJK
717	alpha-Cadinene	24406-05-1	DEFHJKL
718	alpha-Bisabolol	515-69-5	DFHJK
719	alpha-bisabolene	17627-44-0	DEFHJK
720	alpha-Bergamotene	17699-05-7	BDEFHJKL
721	alpha-Amylcinnamyl alcohol	101-85-9	DEFHJ
722	alpha-Amylcinnamyl acetate	7493-78-9	DEFHJ
723	alpha-Amylcinnamaldehyde diethyl	60763-41-9	DEFHJ
	acetal
724	alpha-Amylcinnamaldehyde	122-40-7	DHJK
725	alpha-Amorphene	23515-88-0	DEFHJKL
726	alpha-Agarofuran	5956-12-7	BDEFHJK
727	1-methyl-4-(4-methyl-3-penten-1-	52475-86-2	DFHJK
	yl)-3-Cyclohexene-1-carboxaldehyde
730	1-Phenyl-2-pentanol	705-73-7	CEFHK
731	1-Phenyl-3-methyl-3-pentanol	10415-87-9	CEFHJK
733	2,3,4-trimethoxy-benzaldehyde	2103-57-3	BCGI
735	2,4,5-trimethoxy-benzaldehyde	4460-86-0	BCG
736	2,4,6-trimethoxybenzaldehyde	830-79-5	BCGI
738	2,4-Nonadienal	6750-03-4	ACHKL
741	2,6,10-Trimethylundecanal	105-88-4	BDFGJK
742	alpha,4-Dimethyl benzenepropanal	41496-43-9	ACHJK
746	Allyl cyclohexyl propionate	2705-87-5	BDEFHJK
748	Allyl amyl glycolate	67634-00-8	BCEFGJK
750	Allo-aromadendrene	25246-27-9	BDEFHJKL
752	Aldehyde C-11	143-14-6	ADHJK
754	Methyl (E)-2-(((3,5-	94022-83-0	DEFHJ
	dimethylcyclohex-3-en-1-
	yl)methylene)amino)benzoate
757	2,6,10-trimethylundec-9-enal	141-13-9	BDFHJK
758	Acetoxymethyl-isolongifolene	59056-62-1	BDEFHJK
	(isomers)
763	Acetate C9	143-13-5	BDEFHJKL
764	Acetarolle	744266-61-3	DFHJK
766	Acetaldehyde phenylethyl propyl	7493-57-4	CEFHJK
	acetal
767	Acetaldehyde dipropyl acetal	105-82-8	ACEFGIKL
768	Acetaldehyde benzyl 2-methoxyethyl	7492-39-9	BCEFHJK
	acetal
769	(Z)-2-(4-methylbenzylidene)heptanal	84697-09-6	DHJ
770	9-decenal	39770-05-3	ADHKL
771	8-Hexadecenolide	123-69-3	DGJ
772	7-Methoxycoumarin	531-59-9	CHK
774	7-epi-alpha-Selinene	123123-37-5	BDEFHJK
775	7-eip-alpha-Eudesmol	123123-38-6	DEFHJK
776	7-Acetyl-1,1,3,4,4,6-	1506-02-1	DEFHJ
	hexamethyltetralin
778	6-Isopropylquinoline	135-79-5	CEFHJK
781	6,6-dimethyl-2-norpinene-2-	33885-51-7	BCFHJK
	propionaldehyde
782	6,10,14-trimethyl-2-Pentadecanone	502-69-2	DEFHJK
786	5-Isopropenyl-2-methyl-2-	13679-86-2	ACGIJKL
	vinyltetrahydrofuran
788	5-Cyclohexadecenone	37609-25-9	DEFGJK
791	4-Terpinenol	562-74-3	BCHIJK
792	4-Pentenophenone	3240-29-7	BCEFHIK
800	4-Carvomenthenol	28219-82-1	BCHIJK
802	4,5,6,7-Tetrahydro-3,6-	494-90-6	BCEFHIJKL
	dimethylbenzofuran
803	4-(p-Methoxyphenyl)-2-butanone	104-20-1	BCEFHJK
804	3-Thujopsanone	25966-79-4	BDEFHJK
805	3-Propylidenephthalide	17369-59-4	CEFHK
806	3-Nonylacrolein	20407-84-5	BDFHJK
807	3-Methyl-5-phenyl-1-pentanal	55066-49-4	BDFHJK
814	3-Hexenyl isovalerate	10032-11-8	ADEFHJKL
821	3,6-Dimethyl-3-octanyl acetate	60763-42-0	ADEFHIJKL
824	3,4,5-trimethoxybenzaldehyde	86-81-7	BCGIK
826	3-(p-	7775-00-0	BDFHJK
	Isopropylphenyl)propionaldehyde
827	2-Undecenenitrile	22629-48-7	BDEFHJK
828	2-Undecenal	2463-77-6	ADHJK
829	2-trans-6-trans-Nonadienal	17587-33-6	ACHKL
831	2-Phenylethyl butyrate	103-52-6	DEFHJK
833	2-Phenyl-3-(2-furyl)prop-2-enal	57568-60-2	CHJ
834	2-Phenoxyethanol	122-99-6	BCEFGIK
837	2-Nonen-1-al	2463-53-8	ADHKL
839	2-Nonanol	628-99-9	BDEFGIKL
840	2-Nonanone	821-55-6	ADFHIKL
849	2-Isobutyl quinoline	93-19-6	CEFHJK
850	2-Hexylidene cyclopentanone	17373-89-6	DFHJKL
852	2-Heptyl tetrahydrofuran	2435-16-7	BDEFHJKL
856	2-Decenal	3913-71-1	ADHKL
864	2,6-Nonadienal	26370-28-5	ACHKL
865	2,6-Nonadien-1-ol	7786-44-9	ACEFHK
866	2,6-dimethyl-octanal	7779-07-9	ADFGIJKL
868	1-Decanol	112-30-1	BDEFGJK
869	1-Hepten-1-ol, 1-acetate	35468-97-4	ACEFHKL
870	10-Undecen-1-ol	112-43-6	DEFHJK
871	10-Undecenal	112-45-8	ADHJK
872	10-epi-gamma-Eudesmol	15051-81-7	DFHJK
873	1,8-Thiocineol	68391-28-6	ADEFHIJKL
876	1,3,5-undecatriene	16356-11-9	ADEFHJKL
877	1,2-Dihydrolinalool	2270-57-7	BCEFGIJKL
878	1,3,3-trimethyl-2-norbornanyl	13851-11-1	ADEFHIJKL
	acetate
879	1,1,2,3,3-Pentamethylindan	1203-17-4	ADHIJKL
881	(Z)-6,10-dimethylundeca-5,9-dien-2-	3239-37-0	DEFHJK
	yl acetate
884	(Z)-3-Dodecenal	68141-15-1	BCFHJK
885	(S)-gamma-Undecalactone	74568-05-1	DEFHJKL
886	(R)-gamma-Undecalactone	74568-06-2	DEFHJKL
890	(E)-6,10-dimethylundeca-5,9-dien-2-	3239-35-8	DEFHJK
	yl acetate
892	(2Z)-3-methyl-5-phenyl-2-	53243-59-7	DEFHJK
	Pentenenitrile
893	(2S,5S,6S)-2,6,10,10-tetramethyl-1-	65620-50-0	DFHIJK
	oxaspiro[4_5]decan-6-ol
894	(2E)-3-methyl-5-phenyl-2-	53243-60-0	CEFHJK
	pentenenitrile
897	(+)-Dihydrocarveol	22567-21-1	BCEFHIJKL
905	Menthone	89-80-5	ADEFGIJKL
908	(R,E)-2-methyl-4-(2,2,3-	185068-69-3	CHJK
	trimethylcyclopent-3-en-1-yl)but-2-
	en-1-ol
912	2-(8-isopropyl-6-	68901-32-6	DEFHJK
	methylbicyclo[2.2.2]oct-5-en-2-yl)-
	1,3-dioxolane
913	gamma-methyl ionone	7388-22-9	BDHIJK
914	3-(3-isopropylphenyl)butanal	125109-85-5	BDHJK
916	3-(1-ethoxyethoxy)-3,7-	40910-49-4	BDEFHJK
	dimethylocta-1,6-diene
919	3a,4,5,6,7,7a-hexahydro-1H-4,7-	17511-60-3	CEFHJK
	methanoinden-6-yl propionate
920	Bulnesol	22451-73-6	DEFHJK
922	Benzyl phenylacetate	102-16-9	DHJ
923	Benzoin	119-53-9	CEFHJ
924	(E)-1,2,4-trimethoxy-5-(prop-1-en-1-	2883-98-9	BCFGJK
	yl)benzene
925	alpha,alpha,6,6-tetramethyl	33885-52-8	BDFHJK
	bicyclo[3.1.1]hept-2-ene-propanal
926	7-epi-sesquithujene	159407-35-9	DEFHJKL
927	5-Acetyl-1,1,2,3,3,6-	15323-35-0	DEFHJK
	hexamethylindan
928	3-Methylphenethyl alcohol	1875-89-4	BCEFHIK
929	3,6-Nonadien-1-ol	76649-25-7	ACEFHK
930	2-Tridecenal	7774-82-5	BDFHJK
933	Patchouli alcohol	5986-55-0	DEFHIJK
937	p-Cresyl isobutyrate	103-93-5	BDHJK
939	p-Cresyl n-hexanoate	68141-11-7	DEFHJK
941	5-hexyl-4-methyldihydrofuran-	67663-01-8	BDEFHIJKL
	2(3H)-one
942	Ethyl (2Z,4E)-deca-2,4-dienoate	3025-30-7	BDEFHJK
943	Pelargene	68039-40-7	DEFHJK
945	2-cyclohexylidene-2-	10461-98-0	DFHJK
	phenylacetonitrile
946	Perillaldehyde	2111-75-3	ACHIJK
947	Perillyl acetate	15111-96-3	DFHJK
948	Perillyl alcohol	536-59-4	CHIJK
950	(2-isopropoxyethyl)benzene	68039-47-4	ACEFHJKL
951	Ethyl (2Z,4E)-deca-2,4-dienoate	313973-37-4	BDEFHJK
953	(2-(cyclohexyloxy)ethyl)benzene	80858-47-5	DEFHJK
954	Phenethyl 2-methylbutyrate	24817-51-4	DEFHJK
955	Phenethyl alcohol	60-12-8	BCEFGIK
959	Phenethyl phenylacetate	102-20-5	DHJ
962	Phenoxanol	55066-48-3	DEFHJK
965	Phenyl benzoate	93-99-2	DFHJK
967	Phenyl ethyl benzoate	94-47-3	DHJ
969	Phenylacetaldehyde ethyleneglycol	101-49-5	BCEFGIK
	acetal
973	2-(6,6-dimethylbicyclo[3.1.1]hept-2-	30897-75-7	ACFHIJKL
	en-2-yl)acetaldehyde
974	Pinocarveol	5947-36-4	BCEFGIJKL
976	Piperonyl acetone	55418-52-5	CEFGJ
978	3a,4,5,6,7,7a-hexahydro-1H-4,7-	68039-44-1	DEFHJK
	methanoinden-6-yl pivalate
980	(4aR,8aS)-7-methyloctahydro-1,4-	41724-19-0	CEFGJKL
	methanonaphthalen-6(2H)-one
982	p-Menth-3-en-1-ol	586-82-3	BCGIJK
985	(E)-3,3-dimethyl-5-(2,2,3-	107898-54-4	DHJK
	trimethylcyclopent-3-en-1-yl)pent-4-
	en-2-ol
988	1-methyl-4-(4-methylpent-3-en-1-	52474-60-9	DFHJK
	yl)cyclohex-3-ene-1-carbaldehyde
993	Propylene glycol	57-55-6	ACEFGIKL
998	p-Tolyl phenylacetate	101-94-0	DFHJ
1000	Ethyl 2,4,7-decatrienoate	78417-28-4	BDEFHJK
1003	2-benzyl-4,4,6-trimethyl-1,3-dioxane	67633-94-7	DEFHJK
1006	2,4-dimethyl-4-	82461-14-1	BDEFHJK
	phenyltetrahydrofuran
1007	(2R,4a′R,8a′R)-3,7′-dimethyl-	41816-03-9	DEFHJK
	3′,4′,4a′,5′,8′,8a′-hexahydro-1′H-
	spiro[oxirane-2,2′-
	[1,4]methanonaphthalene]
1008	(Z)-6-ethylideneoctahydro-2H-5,8-	93939-86-7	BCEFHJKL
	methanochromene
1009	2-((S)-1-((S)-3,3-	236391-76-7	DFHJ
	dimethylcyclohexyl)ethoxy)-2-
	oxoethyl propionate
1010	Methyl 2,2-dimethyl-6-	81752-87-6	ADHIJKL
	methylenecyclohexane-1-carboxylate
1012	2-methyl-5-phenylpentan-1-ol	25634-93-9	DEFHJK
1016	4-methyl-2-phenyl-3,6-dihydro-2H-	60335-71-9	BCEFGJK
	pyran
1020	Sabinol	471-16-9	BCEFHIJKL
1021	Safrole	94-59-7	BCEFHK
1022	2,2,7,9-tetramethylspiro(5.5)undec-	502847-01-0	DHIJK
	8-en-1-one
1023	3-methyl-5-(2,2,3-	65113-99-7	DEFHJK
	trimethylcyclopent-3-en-1-yl)pentan-
	2-ol
1024	(Z)-2-ethyl-4-(2,2,3-	28219-61-6	DEFHJK
	trimethylcyclopent-3-en-1-yl)but-2-
	en-1-ol
1025	(E)-2-methyl-4-(2,2,3-	28219-60-5	CHJK
	trimethylcyclopent-3-en-1-yl)but-2-
	en-1-ol
1026	5-methoxyoctahydro-1H-4,7-	86803-90-9	CHJK
	methanoindene-2-carbaldehyde
1027	5-methoxyoctahydro-1H-4,7-	193425-86-4	CHJK
	methanoindene-2-carbaldehyde
1028	Sclareol	515-03-7	DEFHJ
1029	Sclareol oxide	5153-92-4	DEFHJK
1031	Selina-3,7(11)-diene	6813-21-4	DEFHJKL
1032	2-(1-(3,3-	477218-42-1	DEFHJ
	dimethylcyclohexyl)ethoxy)-2-
	methylpropyl
	cyclopropanecarboxylate
1033	3-(4-isobutylphenyl)-2-	6658-48-6	DHJK
	methylpropanal
1035	Spathulenol	6750-60-3	DEFHJK
1036	Spirambrene	533925-08-5	BCEFHJK
1037	Spirodecane	6413-26-9	BCEFGIJKL
1038	1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-	224031-70-3	DGJK
	1-one
1042	2-(4-methylthiazol-5-yl)ethan-1-ol	137-00-8	CGIKL
1043	2-(heptan-3-yl)-1,3-dioxolane	4359-47-1	ACEFHIJKL
1045	(Z)-dodec-4-enal	21944-98-9	BDFHJK
1046	tau-Cadinol	5937-11-1	DEFHJK
1047	tau-Muurolol	19912-62-0	DEFHJK
1053	Tetrahydrojasmone	13074-63-0	BDFHIJKL
1057	2,6,10,10-tetramethyl-1-	36431-72-8	BDFHIJKL
	oxaspiro[4.5]dec-6-ene
1059	Thiomenthone	38462-22-5	BDEFHIJKL
1060	Thujopsene	470-40-6	BDEFGJKL
1062	Thymol methyl ether	1076-56-8	ADHIJKL
1063	1-(2,2,6-trimethylcyclohexyl)hexan-	70788-30-6	DEFHJK
	3-ol
1064	trans, trans-2,4-Nonadienal	5910-87-2	ACHKL
1065	trans, trans-Farnesol	106-28-5	DEFHJK
1066	trans-2, cis-6-Nonadienal	557-48-2	ACHKL
1067	trans-2-Decenal	3913-81-3	ADHKL
1070	trans-2-Nonen-1-al	18829-56-6	ADHKL
1072	trans-3, cis-6-nonadienol	56805-23-3	ACEFHK
1073	trans-4-Decen-1-al	65405-70-1	ADHKL
1075	trans-ambrettolide	51155-12-5	DGJ
1077	trans-beta-ocimene	13877-91-3	ADGIKL
1078	trans-beta-Ocimene	3779-61-1	ADGIKL
1082	trans-Geraniol	106-24-1	BCHIK
1083	trans-Hedione	2570-03-8	DFHJK
1085	7-(1,1-Dimethylethyl)-2H-1,5-	195251-91-3	CEFHJ
	benzodioxepin-3(4H)-one
1089	Tricyclone	68433-81-8	DEFHJK
1090	Tridecyl alcohol	112-70-9	DEFGJK
1091	Triethyl citrate	77-93-0	CEFGJ
1093	Methyl 2-((1-hydroxy-3-	144761-91-1	DFHJ
	phenylbutyl)amino)benzoate
1095	1-((2E,5Z,9Z)-2,6,10-	28371-99-5	DHJK
	trimethylcyclododeca-2,5,9-trien-1-
	yl)ethan-1-one
1097	Decahydro-2,6,6,7,8,8-hexamethyl-	338735-71-0	BDEFHJK
	2h-indeno(4,5-b)furan
1099	13-methyl oxacyclopentadec-10-en-	365411-50-3	DEFHJK
	2-one
1102	Undecanal	112-44-7	BDHJK
1104	(E)-4-methyldec-3-en-5-ol	81782-77-6	BDEFHIJK
1105	Valencene	4630-07-3	BDEFHJK
1107	Valerianol	20489-45-6	DEFHJK
1111	Vanillin isobutyrate	20665-85-4	CHJ
1113	Vaniwhite	5533-03-9	CGIK
1116	(Z)-2-methyl-4-(2,6,6-	68555-62-4	BDFHJK
	trimethylcyclohex-2-en-1-yl)but-2-
	enal
1117	Methyl 2,4-dihydroxy-3,6-	4707-47-5	CGIJ
	dimethylbenzoate
1120	1-methoxy-3a,4,5,6,7,7a-hexahydro-	27135-90-6	ACEFHJKL
	1H-4,7-methanoindene
1121	Methyl (Z)-2-((3-(4-(tert-	91-51-0	DFHJ
	butyl)phenyl)-2-
	methylpropylidene)amino)benzoate
1125	(Z)-hex-3-en-1-yl isobutyrate	41519-23-7	ADEFHJKL
1126	Vertacetal	5182-36-5	BCFHJK
1129	1-((3R,3aR,7R,8aS)-3,6,8,8-	32388-55-9	DHJK
	tetramethyl-2,3,4,7,8,8a-hexahydro-
	1H-3a,7-methanoazulen-5-yl)ethan-
	1-one
1131	Methyl (Z)-2-(((2,4-	68738-99-8	DEFHJ
	dimethylcyclohex-3-en-1-
	yl)methylene)amino)benzoate
1135	Vetiverol	89-88-3	CEFHIJK
1136	Vetivert Acetate	117-98-6	DEFHJK
1137	Decahydro-3H-spiro[furan-2,5′-	68480-11-5	DEFGJKL
	[4,7]methanoindene]
1138	(2Z,6E)-nona-2,6-dienenitrile	67019-89-0	ACEFHKL
1139	(Z)-cyclooct-4-en-1-yl methyl	87731-18-8	BCHJKL
	carbonate
1140	(1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7-	552-02-3	DEFHJK
	tetramethyldecahydro-1H-
	cyclopropa[e]azulen-4-ol
1142	3,5,5,6,7,8,8-heptamethyl-5,6,7,8-	127459-79-4	DHJ
	tetrahydronaphthalene-2-carbonitrile
1143	(1S,2S,3S,5R)-2,6,6-	133636-82-5	DEFHJK
	trimethylspiro[bicyclo[3.1.1]heptane-
	3,1′-cyclohexan]-2′-en-4′-one
1144	1′,1′,5′,5′-tetramethylhexahydro-	154171-76-3	DEFHJK
	2′H,5′H-spiro[[1,3]dioxolane-2,8′-
	[2,4a]methanonaphthalene]
1145	1′,1′,5′,5′-tetramethylhexahydro-	154171-77-4	DEFHJK
	2′H,5′H-spiro[[1,3]dioxolane-2,8′-
	[2,4a]methanonaphthalene] K
1146	4-(4-hydroxy-3-	122-48-5	CEFGJ
	methoxyphenyl)butan-2-one
1147	(1R,8aR)-4-isopropyl-1,6-dimethyl-	41929-05-9	DEFHJKL
	1,2,3,7,8,8a-hexahydronaphthalene
1148	4,5-epoxy-4,11,11-trimethyl-8-	1139-30-6	DEFHJK
	methylenebicyclo(7.2.0)undecane
1149	1,3,4,6,7,8alpha-hexahydro-1,1,5,5-	23787-90-8	DEFHIJK
	tetramethyl-2H-2,4alpha-
	methanophtalen-8(5H)-one

TABLE 2

List of materials with at least one MORV greater than 5 to 10

Num-		CAS	Comment
ber	Material Name	Number	Code

2	2,4-dimethyl-2-(5,5,8,8-tetramethyl-	131812-67-4	DFHJ
	5,6,7,8-tetrahydronaphthalen-2-yl)-
	1,3-dioxolane
23	3a,5,6,7,8,8b-hexahydro-	823178-41-2	DEFHJK
	2,2,6,6,7,8,8-heptamethyl-4H-
	indeno(4,5-d)-1,3-dioxole
141	2,4-dimethyl-4,4a,5,9b-	27606-09-3	CEFHJK
	tetrahydroindeno[1,2-d][1,3]dioxine
185	(1-methyl-2-((1,2,2-	198404-98-7	DEFHJK
	trimethylbicyclo[3.1.0]hexan-3-
	yl)methyl)cyclopropyl)methanol
227	Isobornylcyclohexanol	68877-29-2	DEFHJK
230	Isobornyl cyclohexanol	66072-32-0	DEFHJK
246	Indol/Hydroxycitronellal Schiff base	67801-36-9	DEFHJ
248	Hydroxymethyl isolongifolene	59056-64-3	DEFHJK
343	8,8-dimethyl-3a,4,5,6,7,7a-	76842-49-4	DEFHJK
	hexahydro-1H-4,7-methanoinden-6-
	yl propionate
359	(E)-4-((3aR,4R,7R,7aR)-	501929-47-1	DEFHJK
	1,3a,4,6,7,7a-hexahydro-5H-4,7-
	methanoinden-5-ylidene)-3-
	methylbutan-2-ol
565	Cedryl methyl ether	19870-74-7	BDEFHJK
631	beta-Copaene	18252-44-3	BDEFHJKL
659	2′-isopropyl-1,7,7-	869292-93-3	BDEFHJK
	trimethylspiro[bicyclo[2.2.1]heptane-
	2,4′-[1,3]dioxane]
674	(4aR,5R,7aS,9R)-2,2,5,8,8,9a-	211299-54-6	DEFHJK
	hexamethyloctahydro-4H-4a,9-
	methanoazuleno[5,6-d][1,3]dioxole
678	(3S,5aR,7aS,11aS,11bR)-3,8,8,11a-	57345-19-4	DEFHJ
	tetramethyldodecahydro-5H-3,5a-
	epoxynaphtho[2,1-c]oxepine
679	2,2,6,6,7,8,8-heptamethyldecahydro-	476332-65-7	DEFHJK
	2H-indeno[4,5-b]furan
715	alpha-Cedrene epoxide	13567-39-0	BDEFHJK
758	Acetoxymethyl-isolongifolene	59056-62-1	DEFHJK
	(isomers)
1028	Sclareol	515-03-7	DEFHJ
1097	Decahydro-2,6,6,7,8,8-hexamethyl-	338735-71-0	DEFHJK
	2h-indeno(4,5-b)furan

TABLE 3

List of materials with at least one MORV from 0.5 to less than 1

Number	Material Name	CAS Number	Comment Code

12	1-ethoxy-4-(tert-	181258-89-9	ADEFHJK
	pentyl)cyclohexane
19	(3Z)-1-(2-buten-1-yloxy)-3-	888744-18-1	ADEFHJKL
	hexene
20	4-(2-methoxypropan-2-yl)-1-	14576-08-0	ADHIJKL
	methylcyclohex-1-ene
24	O-Methyl linalool	60763-44-2	ADHIJKL
26	o-Methoxycinnamaldehyde	1504-74-1	ACHK
27	Octanal, 3,7-dimethyl-	25795-46-4	ADGIJKL
53	3,3-Dimethyl-5(2,2,3-	329925-33-9	CEFHJ
	Trimethyl-3-Cyclopenten-
	1yl)-4-Penten-2-ol
54	n-Hexyl salicylate	6259-76-3	DEFHJ
55	n-Hexyl 2-butenoate	19089-92-0	ADEFHJKL
59	Neryl Formate	2142-94-1	BCEFHJK
72	Methyl-beta-ionone	127-43-5	DHJK
73	Myroxide	28977-57-3	ADGIJKL
81	(E)-3,7-dimethylocta-4,6-	18479-54-4	BCEFGIJK
	dien-3-ol
84	(Z)-hex-3-en-1-yl	188570-78-7	BCEFHIKL
	cyclopropanecarboxylate
96	Methyl phenyl carbinyl	120-45-6	BCHJK
	propionate
97	Methyl phenylacetate	101-41-7	ACEFHIKL
107	2-methyl-6-	91069-37-3	BCEFGIKL
	oxaspiro[4.5]decan-7-one
111	Methyl geraniate	2349-14-6	BCHJKL
115	2-ethoxy-4-	5595-79-9	CFGK
	(methoxymethyl)phenol
116	Methyl	40203-73-4	ACEFHIKL
	cyclopentylideneacetate
125	Methoxymelonal	62439-41-2	ACGIJK
133	((1s,4s)-4-	13828-37-0	BDEFHIJK
	isopropylcyclohexyl)methanol
147	Linalyl propionate	144-39-8	BDFHJK
150	Linalyl formate	115-99-1	ACFHJK
151	Linalyl butyrate	78-36-4	BDEFHJK
154	Linalyl acetate	115-95-7	BDHJK
157	Linalool	78-70-6	BCEFGIJK
163	(Z)-hex-3-en-1-yl methyl	67633-96-9	ACEFGKL
	carbonate
166	Lepidine	491-35-0	BCEFHIKL
169	L-Carvone	6485-40-1	ACGIJKL
181	Khusinil	75490-39-0	DHJK
191	Isoraldeine	1335-46-2	BDHIJK
194	Isopropylvinylcarbinol	4798-45-2	ACGIKL
198	Isopropyl 2-methylbutyrate	66576-71-4	ACEFGIJKL
201	Isopentyrate	80118-06-5	ADEFGIJKL
204	Isononyl acetate	40379-24-6	BDEFHJKL
205	Isononanol	27458-94-2	BDEFGIKL
213	Isoeugenyl acetate	93-29-8	CFHJK
214	Isoeugenol	97-54-1	CEFHIK
232	Isoborneol	124-76-5	ACEFHIJKL
237	Isoamyl octanoate	2035-99-6	DEFHJK
239	Isoamyl isobutyrate	2050-01-3	ACEFGIJKL
255	Hydrocinnamic acid	501-52-0	CEFHIK
258	Hydratopic alcohol	1123-85-9	BCEFHIK
264	Hexyl propanoate	2445-76-3	ADEFHIKL
270	Hexyl butyrate	2639-63-6	BDEFHJKL
273	Hexyl 2-methylbutanoate	10032-15-2	BDEFHJKL
275	Hexyl 2-furoate	39251-86-0	DEFHJK
282	Heptyl alcohol	111-70-6	ACEFGIKL
283	Heptyl acetate	112-06-1	ADEFHKL
284	Heptaldehyde	111-71-7	ACHIKL
287	Heliotropin	120-57-0	BCGIK
302	Geranyl nitrile	5146-66-7	BCEFHKL
306	Geranyl formate	105-86-2	BCEFHJK
308	Geranyl caprylate	51532-26-4	DEFHJ
310	Geranyl benzoate	94-48-4	DFHJ
312	Geranial	141-27-5	ACHIKL
314	N,2-dimethyl-N-	84434-18-4	BCEFHJK
	phenylbutanamide
319	gamma-Terpinene	99-85-4	ADEFGIJKL
346	2-(sec-butyl)cyclohexan-1-	14765-30-1	ADFHIKL
	one
354	3-(2-ethylphenyl)-2,2-	67634-14-4	BDHJK
	dimethylpropanal
355	2-(tert-butyl)cyclohexyl ethyl	67801-64-3	BDFHJK
	carbonate
365	2-(tert-butyl)cyclohexyl ethyl	81925-81-7	ACFHIKL
	carbonate
366	Fenchyl alcohol	1632-73-1	ACGIJKL
376	Eucalyptol	470-82-6	ADEFGIJKL
379	Ethyl vanillin acetate	72207-94-4	CHJ
387	Ethyl octanoate	106-32-1	BDEFHJKL
400	Ethyl cinnamate	103-36-6	BCEFHK
412	Ethyl 2-	2511-00-4	BDFHIJKL
	(cyclohexyl)propionate
419	d-p-8(9)-Menthen-2-one	5524-05-0	ACGIJKL
420	4-methyl-2-phenyltetrahydro-	94201-73-7	BDEFHJK
	2H-pyran
437	Dihydromyrcenol	18479-58-8	ADEFGIJK
438	Dihydrojasmone	1128-08-1	BCFHIJKL
439	Dihydroisophorone	873-94-9	ACEFGIJKL
440	Dihydroeugenol	2785-87-7	CEFHIJK
442	Dihydrocoumarin	119-84-6	BCGIKL
443	Dihydrocarvone	7764-50-3	ACGIJKL
447	Dihydro-alpha-terpinyl	80-25-1	BDEFHIJKL
	acetate
448	Dihydro-alpha-ionone	31499-72-6	BDHIJK
454	Dibenzyl ether	103-50-4	DEFHJK
455	Dibutyl o-phthalate	84-74-2	DEFHJ
469	2-pentylcyclopentan-1-one	4819-67-4	BDFHIKL
472	Decyl anthranilate	18189-07-6	DEFHJ
477	Methyl (1s,4s)-1,4-	23059-38-3	ADEFHIJKL
	dimethylcyclohexane-1-
	carboxylate
481	Cyclohexylethyl acetate	21722-83-8	BDEFHJKL
492	Creosol	93-51-6	BCHIK
495	Cosmene	460-01-5	ADEFGIKL
496	4-cyclohexyl-2-methylbutan-	83926-73-2	BDEFGIJK
	2-ol
504	2-benzyl-2-methylbut-3-	97384-48-0	BDHJK
	enenitrile
509	Citronellyl nitrile	51566-62-2	BCEFGIKL
510	Citronellyl phenylacetate	139-70-8	DFHJ
512	Citronellyl formate	105-85-1	BCEFGJKL
515	Citronellyl benzoate	10482-77-6	DFHJ
517	Citronellol	106-22-9	BCHIJKL
518	Citronellal	106-23-0	ACHIJKL
522	Citral	5392-40-5	ACHIKL
525	cis-Pinane	6876-13-7	ADEFGIJKL
526	(Z)-3-methyl-2-(pent-2-en-1-	488-10-8	BCHIJKL
	yl)cyclopent-2-en-1-one
528	cis-iso-Eugenol	5912-86-7	CEFHIK
535	cis-3-Hexenyl valerate	35852-46-1	BDEFHJKL
536	cis-3-Hexenyl tiglate	67883-79-8	BDEFHJK
538	cis-3-Hexenyl propionate	33467-74-2	ACEFHIKL
540	cis-3-Hexenyl butyrate	16491-36-4	ADEFHJKL
542	cis-3-Hexen-1-ol	928-96-1	ACEFHIKL
547	cis-2-Hexenol	928-94-9	ACEFHIKL
549	Cinnamyl nitrile	4360-47-8	ACEFGIK
554	Cinnamic aldehyde	104-55-2	ACHIK
556	Cinnamyl nitrile	1885-38-7	ACEFGIK
557	Chloroxylenol	88-04-0	BCHIJK
575	Carvacrol	499-75-2	DHIJK
576	Carvone	99-49-0	ACGIJKL
579	Carbitol	111-90-0	BCEFGIK
583	Caproyl alcohol	111-27-3	ACEFGIKL
585	2-(2,2,3-trimethylcyclopent-3-	15373-31-6	ACGIJKL
	en-1-yl)acetonitrile
588	Camphor	76-22-2	ACEFGIJKL
602	(E)-2-methyl-4-(2,6,6-	3155-71-3	DHJK
	trimethylcyclohex-1-en-1-
	yl)but-2-enal
605	Borneol	507-70-0	ACEFHIJKL
617	beta-Pinene epoxide	6931-54-0	ACEFGIJKL
619	beta-Phellandrene	555-10-2	ADEFGIJKL
640	Benzylacetone	2550-26-7	ACEFGIK
641	Benzyl salicylate	118-58-1	DFGJ
645	Benzyl isovalerate	103-38-8	BDEFHJK
647	Benzyl isobutyrate	103-28-6	BCHJK
651	Benzyl butyrate	103-37-7	BCEFHJK
652	Benzyl alcohol	100-51-6	ACEFGIKL
662	1-(3,3-	25225-08-5	ADEFHIJKL
	dimethylcyclohexyl)ethyl
	formate
664	Anisyl acetate	104-21-2	BCEFGK
665	Anisyl formate	122-91-8	BCEFGK
667	Anethole	104-46-1	ACEFHK
672	Amyl benzoate	2049-96-9	DEFHJK
687	alpha-Terpinyl acetate	80-26-2	BDHJK
699	alpha-methyl-	10528-67-3	BDEFHIK
	cyclohexanepropanol
701	alpha-methyl cinnamaldehyde	101-39-3	ACHIK
703	alpha-Isomethylionone	127-51-5	BDHIJK
740	2,5-Dimethyl-4-methoxy-	4077-47-8	ACEFGIJKL
	3(2H)-furanone
743	Allyl phenoxyacetate	7493-74-5	BCGK
744	Allyl Phenethyl ether	14289-65-7	ACEFHK
745	Allyl heptanoate	142-19-8	ADEFHJKL
755	N-ethyl-N-(m-	179911-08-1	CEFHJK
	tolyl)propionamide
760	3-hydroxybutan-2-one	513-86-0	ACEFGIKL
761	Acetoanisole	100-06-1	BCEFHIK
777	6-Methylquinoline	91-62-3	BCEFHIKL
779	6,8-Diethyl-2-nonanol	70214-77-6	BDEFGIJKL
784	5-Methyl-3-heptanone	541-85-5	ACFGIKL
789	4-Vinylphenol	2628-17-3	BCHIK
796	4-hydroxy-3-methoxy-	458-36-6	CH
	cinnamaldehyde
797	4-Ethylguaiacol	2785-89-9	CEFHIK
799	4-Damascol	4927-36-0	BDFHJK
808	3-methyl-4-phenylpyrazole	13788-84-6	CEFHK
810	3-Methyl-1,2-	765-70-8	ACEFGIKL
	cyclopentanedione
811	3-Methoxy-5-methylphenol	3209-13-0	BCHIK
812	3-Methoxy-3-Methyl Butanol	56539-66-3	ACGIKL
817	3-Hexenol	544-12-7	ACEFHIKL
819	3,7-dimethyl-2-methylene-6-	22418-66-2	ADFHIJK
	octenal
820	3,7-dimethyl-1-octanol	106-21-8	BDEFGIJKL
832	2-Phenylethyl acetate	103-45-7	BCEFHK
835	2-Phenethyl propionate	122-70-3	BCEFHJK
836	2-Pentylcyclopentan-1-ol	84560-00-9	DEFHIKL
838	2-nonanone propylene glycol	165191-91-3	BDEFHJK
	acetal
845	2-Methoxy-3-(1-	24168-70-5	BCEFGIK
	methylpropyl)pyrazine
846	2-isopropyl-N,2,3-	51115-67-4	ACEFGIJK
	trimethylbutyramide
847	2-Isopropyl-5-methyl-2-	35158-25-9	ADFGIJKL
	hexenal
848	2-Isopropyl-4-methylthiazole	15679-13-7	ACHIJKL
851	2-Hexen-1-ol	2305-21-7	ACEFHIKL
858	2-Butoxyethanol	111-76-2	ACEFGIKL
875	1,4-Cineole	470-67-7	ADGIJKL
880	1-(2,6,6-Trimethyl-2-	43052-87-5	BDHIJK
	cyclohexen-1-yl)-2-buten-1-
	one
882	(Z)-3-hepten-1-yl acetate	1576-78-9	ACEFHKL
883	(S)—(1R,5R)-4,6,6-	1196-01-6	ACEFGIJKL
	trimethylbicyclo[3.1.1]hept-3-
	en-2-one
888	(R)-(−)-Linalool	126-91-0	BCEFGIJK
889	(l)-Citronellal	5949-05-3	ACHIJKL
891	(d)-Citronellal	2385-77-5	ACHIJKL
899	(+)-Citronellol	1117-61-9	BCHIJKL
900	(−)-Citronellol	7540-51-4	BCHIJKL
901	(+)-alpha-Pinene	7785-70-8	ADEFGIJKL
902	(+)-Carvone	2244-16-8	ACGIJKL
903	(−)-alpha-Pinene	7785-26-4	ADEFGIJKL
904	Methyl 2-methylbutyrate	868-57-5	ACEFGIKL
909	Hexyl tiglate	16930-96-4	BDEFHJKL
918	Allyl 2-	68901-15-5	CHJK
	(cyclohexyloxy)acetate
921	1,5-	75147-23-8	CFHIJK
	dimethylbicyclo[3.2.1]octan-
	8-one oxime
931	alpha-acetoxystyrene	2206-94-2	ACEFHIK
940	p-Cymene	99-87-6	ADGIJKL
956	Phenethyl formate	104-62-1	ACEFHK
958	Phenethyl isobutyrate	103-48-0	DHJK
960	Phenethyl tiglate	55719-85-2	DHJK
971	Phenylethyl methacrylate	3683-12-3	DHJK
977	p-	4395-92-0	BDFHK
	Isopropylphenylacetaldehyde
981	1,2-dimethyl-3-(prop-1-en-2-	72402-00-7	BCEFGIJKL
	yl)cyclopentan-1-ol
983	p-Methoxyphenylacetone	122-84-9	BCEFHK
986	(2Z,5Z)-5,6,7-trimethylocta-	358331-95-0	ADHIJKL
	2,5-dien-4-one
987	p-Propyl anisole	104-45-0	ADEFHKL
994	p-t-butyl phenyl acetaldehyde	109347-45-7	BDHJK
995	p-tert-Amyl cyclohexanol	5349-51-9	BDEFHIJK
1001	Racemic alpha-Pinene	80-56-8	ADEFGIJKL
1002	4-(4-hydroxyphenyl)butan-2-	5471-51-2	CEFGIK
	one
1004	Rhodinol	141-25-3	BCHIJKL
1005	Ethyl (2,3,6-	93981-50-1	BDEFHJKL
	trimethylcyclohexyl)carbonate
1011	1-(3,3-	25225-10-9	ADHIJKL
	dimethylcyclohexyl)ethyl
	acetate
1017	S)-(+)-Linalool	126-90-9	BCEFGIJK
1018	Sabinene	3387-41-5	ADEFGIJKL
1019	Sabinene hydrate	546-79-2	ADEFGIJKL
1030	Propyl (S)-2-(tert-	319002-92-1	BDEFHJK
	pentyloxy)propanoate
1039	Spirolide	699-61-6	BCGIKL
1040	(Z)-5-methylheptan-3-one	22457-23-4	BCEFGIJKL
	oxime
1041	1-phenylethyl acetate	93-92-5	ACEFHIK
1051	Tetrahydrogeranial	5988-91-0	ADGIJKL
1052	Tetrahydroionol	4361-23-3	BDEFHIJK
1054	Tetrahydrolinalool	78-69-3	BDEFGIJKL
1055	Tetrahydrolinalyl acetate	20780-48-7	ADEFHJKL
1058	Ethyl (1R,6S)-2,2,6-	22471-55-2	ADEFHIJKL
	trimethylcyclohexane-1-
	carboxylate
1061	Thymol	89-83-8	BDHIJK
1069	trans-2-Hexenol	928-95-0	ACEFHIKL
1071	trans-2-tert-	5448-22-6	ACGIJKL
	Butylcyclohexanol
1074	trans-alpha-Damascone	24720-09-0	BDHIJK
1076	trans-Anethole	4180-23-8	ACEFHK
1079	trans-Cinnamic acid	140-10-3	CEFHK
1081	trans-Dihydrocarvone	5948-04-9	ACGIJKL
1084	trans-Isoeugenol	5932-68-3	CEFHIK
1088	Trichloromethyl phenyl	90-17-5	BDEFGJ
	carbinyl acetate
1098	2-mercapto-2-methylpentan-	258823-39-1	ACEFHIJKL
	1-ol
1110	Vanillin acetate	881-68-5	CH
1112	Vanitrope	94-86-0	CEFHK
1115	2,2,5-trimethyl-5-	65443-14-3	BDFGIJKL
	pentylcyclopentan-1-one
1118	Veratraldehyde	120-14-9	BCGIK
1119	(1R,5R)-4,6,6-	18309-32-5	ACEFGIJKL
	trimethylbicyclo[3.1.1]hept-3-
	en-2-one
1122	Verdol	13491-79-7	ACGIJKL
1127	4-(tert-butyl)cyclohexyl	10411-92-4	BDEFHJK
	acetate
1128	4-(tert-butyl)cyclohexyl	32210-23-4	BDEFHJK
	acetate
1133	Vethymine	7193-87-5	CEFGK
1134	4-methyl-4-phenylpentan-2-yl	68083-58-9	BDFHJK
	acetate
1141	(Z)-1-((2-	292605-05-1	ADEFHKL
	methylallyl)oxy)hex-3-ene

TABLE 4

List of materials with ALL MORVs from 1 to 5

Num-		CAS	Comment
ber	Material Name	Number	Code

7	3-methoxy-7,7-dimethyl-10-	216970-21-7	BDEFHJK
	methylenebicyclo[4.3.1]decane
14	Oxyoctaline formate	65405-72-3	DFHJK
39	2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a-	103614-86-4	DEFHIJK
	octahydronaphthalen-1-ol
48	Nootkatone	4674-50-4	DHJK
183	Khusimol	16223-63-5	CEFHJK
199	Isopimpinellin	482-27-9	CFGJ
206	Iso3-methylcyclopentadecan-1-one	3100-36-5	DEFGJK
212	Isoeugenyl benzyl ether	120-11-6	DFHJ
215	1-((2S,3S)-2,3,8,8-tetramethyl-	54464-57-2	DHJK
	1,2,3,4,5,6,7,8-octahydronaphthalen-
	2-yl)ethan-1-one
229	Isobornyl isobutyrate	85586-67-0	BDEFHIJK
260	2,3-dihydro-3,3-dimethyl-1H-indene-	173445-44-8	DHJK
	5-propanal
261	3-(3,3-dimethyl-2,3-dihydro-1H-	173445-65-3	DHJK
	inden-5-yl)propanal
281	3a,4,5,6,7,7a-hexahydro-1H-4,7-	5413-60-5	CEFGJK
	methanoinden-6-yl acetate
329	gamma-Eudesmol	1209-71-8	DFHJK
335	4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-	1222-05-5	DEFHJK
	hexahydrocyclopenta[g]isochromene
353	(Z)-6-ethylideneoctahydro-2H-5,8-	69486-14-2	CEFGJK
	methanochromen-2-one
360	8,8-dimethyl-3a,4,5,6,7,7a-	171102-41-3	DEFHJK
	hexahydro-1H-4,7-methanoinden-6-
	yl acetate
441	Octahydro-1H-4,7-methanoinden-5-	64001-15-6	DEFHJKL
	yl acetate
484	3a,4,5,6,7,7a-hexahydro-1H-4,7-	113889-23-9	DEFHJK
	methanoinden-6-yl butyrate
487	3a,4,5,6,7,7a-hexahydro-1H-4,7-	67634-20-2	DEFHJK
	methanoinden-5-yl isobutyrate
488	Curzerene	17910-09-7	DHJK
501	(E)-cycloheptadec-9-en-1-one	542-46-1	DEFGJ
566	Cedryl formate	39900-38-4	BDEFHJK
567	Cedryl acetate	77-54-3	DEFHJK
569	Cedrol	77-53-2	DEFHJK
570	5-methyl-1-(2,2,3-	139539-66-5	DEFHJK
	trimethylcyclopent-3-en-1-yl)-6-
	oxabicyclo[3.2.1]octane
573	Caryophyllene alcohol acetate	32214-91-8	DEFHJK
574	Caryolan-1-ol	472-97-9	DEFHJK
603	Bornyl isobutyrate	24717-86-0	BDEFHIJK
616	beta-Santalol	77-42-9	DEFHJK
621	beta-Patchoulline	514-51-2	BDEFGJKL
624	beta-Himachalene Oxide	57819-73-5	BDFHJK
627	(2,2-dimethoxyethyl)benzene	101-48-4	DHJK
632	beta-Cedrene	546-28-1	BDEFGJKL
663	Anisyl phenylacetate	102-17-0	DFHJ
680	2,2,6,6,7,8,8-heptamethyldecahydro-	647828-16-8	ADEFHJK
	2H-indeno[4,5-b]furan
684	alpha-Vetivone	15764-04-2	DHJK
694	alpha-Santalol	115-71-9	DEFHJK
696	alpha-Patchoulene	560-32-7	ADEFHJKL
708	alpha-Gurjunene	489-40-7	BDEFHJKL
712	alpha-Eudesmol	473-16-5	DEFHJK
714	alpha-Cubebene	17699-14-8	ADEFHJKL
726	alpha-Agarofuran	5956-12-7	BDEFHJK
750	Allo-aromadendrene	25246-27-9	BDEFHJKL
764	Acetarolle	744266-61-3	DFHJK
775	7-eip-alpha-Eudesmol	123123-38-6	DEFHJK
776	7-Acetyl-1,1,3,4,4,6-	1506-02-1	DEFHJ
	hexamethyltetralin
788	5-Cyclohexadecenone	37609-25-9	DEFGJK
804	3-Thujopsanone	25966-79-4	BDEFHJK
872	10-epi-gamma-Eudesmol	15051-81-7	DFHJK
919	3a,4,5,6,7,7a-hexahydro-1H-4,7-	17511-60-3	CEFHJK
	methanoinden-6-yl propionate
927	5-Acetyl-1,1,2,3,3,6-	15323-35-0	DEFHJK
	hexamethylindan
933	Patchouli alcohol	5986-55-0	DEFHIJK
978	3a,4,5,6,7,7a-hexahydro-1H-4,7-	68039-44-1	DEFHJK
	methanoinden-6-yl pivalate
1007	(2R,4a′R,8a′R)-3,7′-dimethyl-	41816-03-9	DEFHJK
	3′,4′,4a′,5′,8′,8a′-hexahydro-1′H-
	spiro[oxirane-2,2′-
	[1,4]methanonaphthalene]
1022	2,2,7,9-tetramethylspiro(5.5)undec-	502847-01-0	DHIJK
	8-en-1-one
1024	(Z)-2-ethyl-4-(2,2,3-	28219-61-6	DEFHJK
	trimethylcyclopent-3-en-1-yl)but-2-
	en-1-ol
1027	5-methoxyoctahydro-1H-4,7-	193425-86-4	CHJK
	methanoindene-2-carbaldehyde
1029	Sclareol oxide	5153-92-4	DEFHJK
1035	Spathulenol	6750-60-3	DEFHJK
1038	1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-	224031-70-3	DGJK
	1-one
1060	Thujopsene	470-40-6	BDEFGJKL
1089	Tricyclone	68433-81-8	DEFHJK
1107	Valerianol	20489-45-6	DEFHJK
1129	1-((3R,3aR,7R,8aS)-3,6,8,8-	32388-55-9	DHJK
	tetramethyl-2,3,4,7,8,8a-hexahydro-
	1H-3a,7-methanoazulen-5-yl)ethan-
	1-one
1131	Methyl (Z)-2-(((2,4-	68738-99-8	DEFHJ
	dimethylcyclohex-3-en-1-
	yl)methylene)amino)benzoate
1136	Vetivert Acetate	117-98-6	DEFHJK
1137	Decahydro-3H-spiro[furan-2,5′-	68480-11-5	DEFGJKL
	[4,7]methanoindene]
1140	(1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7-	552-02-3	DEFHJK
	tetramethyldecahydro-1H-
	cyclopropa[e]azulen-4-ol
1142	3,5,5,6,7,8,8-heptamethyl-5,6,7,8-	127459-79-4	DHJ
	tetrahydronaphthalene-2-carbonitrile
1143	(1S,2S,3S,5R)-2,6,6-	133636-82-5	DEFHJK
	trimethylspiro[bicyclo[3.1.1]heptane-
	3,1′-cyclohexan]-2′-en-4′-one
1144	1′,1′,5′,5′-tetramethylhexahydro-	154171-76-3	DEFHJK
	2′H,5′H-spiro[[1,3]dioxolane-2,8′-
	[2,4a]methanonaphthalene]
1145	1′,1′,5′,5′-tetramethylhexahydro-	154171-77-4	DEFHJK
	2′H,5′H-spiro[[1,3]dioxolane-2,8′-
	[2,4a]methanonaphthalene] K
1148	4,5-epoxy-4,11,11-trimethyl-8-	1139-30-6	DEFHJK
	methylenebicyclo(7.2.0)undecane
1149	1,3,4,6,7,8alpha-hexahydro-1,1,5,5-	23787-90-8	DEFHIJK
	tetramethyl-2H-2,4alpha-
	methanophtalen-8(5H)-one

TABLE 5

List of materials with ALL MORVs greater than 5 to 10

Number	Material Name	CAS Number	Comment Code

248	Hydroxymethyl	59056-64-3	BDEFHJK
	isolongifolene

TABLE 6

List of materials with ALL MORVs from 0.5 to less than 1

Number Material Name CAS Number Comment Code

472 Decyl anthranilate 18189-07-6 DEFHJ

526 (Z)-3-methyl-2-(pent- 488-10-8 BCHIJKL

2-en-1-yl)cyclopent-

2-en-1-one

The materials in Tables 1-6 can be supplied by one or more of the following:

Firmenich Inc. of Plainsboro N.J. USA; International Flavor and Fragrance Inc. New York, N.Y. USA; Takasago Corp. Teterboro, N.J. USA; Symrise Inc. Teterboro, N.J. USA; Sigma-Aldrich/SAFC Inc. Carlsbad, Calif. USA; and Bedoukian Research Inc. Danbury, Conn. USA.
Actual MORV values for each material listed in Tables 1-6 above are as follows:


	MORV	MORV Value		MORV
Material	value for	for	MORV Value	value for
No.	Equation a.)	Equation b.)	for Equation c.)	Equation d.)

1	0.548223914	0.876283261	1.22018588	−0.41901144
2	1.520311929	3.493450446	2.70657265	5.11342862
3	2.267801995	−0.81712657	0.43218875	1.595983683
4	−0.591063369	−0.48283571	0.16199804	1.210497701
7	1.437444636	2.131822996	3.81633465	1.318339345
9	2.151445882	−0.46189495	0.56090469	1.206360803
10	2.5733592	−0.58780849	1.39751471	1.258361951
11	3.052627325	1.008519135	−0.30475953	0.076323462
12	0.683776599	−0.01157903	0.82853231	0.326169402
13	1.549643217	1.809183231	0.70864531	2.22799611
14	2.82111224	2.339505033	1.240818	2.502429355
16	−0.31551128	−0.06816599	−0.04371934	2.76742389
17	−1.334904153	−0.5773313	1.75644798	1.898455724
18	−1.34154226	−2.63596666	0.06885109	1.001431671
19	0.15532384	0.09866097	0.64214585	−0.33330779
20	0.640261783	0.693213268	0.54637273	−0.97556029
21	0.936895364	−0.01521118	1.1697513	−0.63510809
22	1.158981042	1.115900089	−0.25859776	1.318200884
23	3.702361074	1.399942641	5.23954766	7.089933671
24	0.773874141	0.146848137	−1.05705847	−0.36193173
25	−1.016103969	−1.18967936	0.78064625	2.944710012
25	−1.016103969	−1.18967936	0.78064625	2.944710012
26	0.615085491	−0.00096877	−0.35697252	−0.18121401
27	0.70261974	−0.22197386	0.19710806	−2.37196477
28	1.366472597	−0.42546942	−0.59394241	−0.01417395
29	1.096043453	−1.02972898	−1.42167356	−0.63817943
30	1.143415203	−0.85945441	−0.41416913	2.499807942
31	1.138642907	−0.19595476	−0.54547769	−0.98828898
32	1.914414495	−0.64487788	0.63212987	1.166699371
33	0.314847366	1.848003955	−1.3905032	−0.62848261
34	−0.113542761	0.981530917	0.32824239	1.126524277
35	0.472382903	1.494882467	−0.07201236	−0.64589543
36	3.158513795	1.084094934	−0.00328981	−0.17786385
37	−1.055631982	2.240172964	0.92596118	2.105391988
38	3.158513795	0.592820874	−0.49326241	0.212867212
39	1.083800659	2.069727985	2.48170879	3.205630609
42	−0.103134861	0.267726008	−0.65350189	1.125952363
43	0.323961628	1.469295081	−0.52991193	0.797908251
47	1.703678841	1.348737095	2.00634162	−0.16505407
48	2.370955056	2.783472865	2.68240273	1.221864405
49	1.670680003	−0.41866107	−0.9173849	1.181929544
50	1.670680003	0.076369374	−0.49915943	−0.85392575
52	0.464485039	0.057512869	1.31230219	−0.11170276
53	0.626671823	−0.46954947	−0.33383736	0.277079201
54	0.666149043	0.009549925	−0.36226343	0.197224432
55	0.723473579	−1.50916383	−0.3848989	−0.71458778
57	0.381273227	1.192994109	1.65593321	−1.65739236
59	0.561360663	−0.17793966	−1.63250554	−0.7564969
61	0.146473611	−0.01535544	−0.16339658	1.738656146
62	1.20162032	−0.3576095	−0.10695443	1.322155191
63	1.084291915	2.258720158	−1.01245416	1.688283974
64	0.744770665	0.155243763	−1.8029919	1.023503542
65	0.972835178	2.797151284	1.53453579	0.857051645
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1107	2.352582059	2.595496601	3.20492728	2.844590737
1110	0.302703712	0.599942142	−0.25637571	−0.03195517
1111	0.750930333	0.656784751	1.68326413	0.329846578
1112	−0.205527848	0.287622624	−0.00340777	0.59203719
1115	0.999825037	0.662221152	0.43571192	0.342558518
1116	0.873381263	1.544324176	0.13703728	−0.38172701
1117	−0.682983903	1.798204302	2.42110319	−0.39173951
1118	0.069769623	0.496895599	0.67857133	−0.14954441
1119	−0.671908804	−0.65984824	0.5238174	−0.85314111
1120	0.953790113	1.106552668	3.00006904	1.585038764
1121	−1.184630973	2.476138312	4.80971952	2.450646806
1122	−1.02687397	−0.36244273	0.13010074	0.535909448
1125	0.387315524	−0.36101406	1.14153708	−0.75303953
1126	1.021783831	−0.0070257	−0.14327539	3.954381426
1127	0.990592079	0.305612583	0.14155512	−0.29526854
1128	0.990592079	0.305612583	0.14155512	−0.29526854
1129	3.18966648	3.284362987	4.49398568	3.950809104
1131	1.650621055	1.545704806	2.37535081	1.259373143
1133	−1.519747805	−0.60804324	0.02746106	0.590708892
1134	0.815942067	−0.16126019	−0.54117238	0.613093526
1135	0.626973385	1.998305877	2.61706075	1.570404253
1136	2.812199484	1.353198146	2.05618426	1.869204406
1137	2.208307057	1.387136198	3.21521374	2.069795393
1138	1.670680003	1.316442078	0.14822999	−0.46985154
1139	1.408517438	0.890457374	1.24524408	0.685687797
1140	2.765860952	2.525539595	4.12464228	3.833744077
1141	−0.484394663	0.677713073	−0.22783646	−0.37267608
1142	2.54335679	4.298105601	3.36234238	2.684404542
1143	4.204367611	3.062126931	3.4234313	2.072899554
1144	2.479165229	3.226545885	4.65897152	4.952127235
1145	2.479158921	3.226545885	4.65897152	4.952127235
1146	0.774334025	1.075800774	1.06893156	1.011113116
1147	0.844648531	1.21935371	2.59138595	0.805938034
1148	2.906236436	1.550674121	3.56959167	2.832126896
1149	2.837627443	3.707154326	4.53384262	2.625871865

Antiperspirant and/or Deodorant Compositions and Methods of Use

An antiperspirant and/or deodorant composition comprising, based on total composition weight,

- a) a sum total of from about 0.0001% to about 2%, preferably from about 0.0001% to about 0.75%, more preferably from about 0.001% to about 0.5%, most preferably from about 0.007% to about 0.25% of 1 or more malodor reduction materials, preferably 1 to about 75 malodor reduction materials, more preferably 1 to about 50 malodor reduction materials, more preferably 1 to about 35 malodor reduction materials, most preferably 1 to about 20 malodor reduction materials, each of said malodor reduction materials having a MORV of at least 0.5, preferably from 0.5 to 10, more preferably from 1 to 10, most preferably from 1 to 5, and preferably each of said malodor reduction materials having a Universal MORV, or said sum total of malodor reduction materials having a Blocker Index of less than 3, more preferable less than about 2.5 even more preferably less than about 2 and still more preferably less than about 1 and most preferably 0 and/or a Blocker Index average of 3 to about 0.001; and
- b) from about 0% to about 12%, preferably from about 0% to about 8%, more preferably from about 0.1% to about 4%, of one or more perfume raw materials having a MORV of less than 0.5, preferably less than 0, more preferably less than −2, most preferably less than −5;
- c) from about 0.1% to about 99%, preferably from about 1% to about 80%, more preferably from about 5% to about 55%, most preferably from about 10% to about 50% of a solvent, preferably said solvent is selected from cyclopentasiloxane, ethanol, water, propylene glycol, dipropylene glycol, and mixtures thereof;
- d) from about 0% to about 30%, preferably from about 0% to about 20%, more preferably from about 0.1% to about 4%, most preferably from about 0.1% to about 4% of a material selected from the group consisting of a structurant, a residue masker, an antimicrobial, and mixtures thereof
  is disclosed. The aforementioned solvent levels help disperse perfume and MORV materials into the APDO base to give even coverage when used

In one aspect of said antiperspirant and/or deodorant composition, said sum total of malodor reduction materials has a Blocker Index of less than 3, more preferable less than about 2.5 even more preferably less than about 2 and still more preferably less than about 1 and most preferably 0 and/or a Blocker Index average of 3 to about 0.001.
In one aspect of said antiperspirant and/or deodorant composition, each of said malodor reduction materials has a MORV of at least 0.5, preferably from 0.5 to 10, more preferably from 1 to 10, most preferably from 1 to 5, and preferably each of said malodor reduction materials has a Universal MORV.
In one aspect of said antiperspirant and/or deodorant composition, said sum total of malodor reduction materials has a Fragrance Fidelity Index average of 3 to about 0.001 Fragrance Fidelity Index, preferably each malodor reduction material in said sum total of malodor reduction materials has a Fragrance Fidelity Index of less than 3, preferably less than 2, more preferably less than 1 and most preferably each malodor reduction material in said sum total of malodor reduction materials has a Fragrance Fidelity Index of 0.
In one aspect of said antiperspirant and/or deodorant composition, said sum total of malodor reduction materials has an average boiling point, based on the weight percent of each malodor reduction material in said sum total of malodor reduction materials, of from about 160° C. to about 400° C., preferably from about 180° C. to about 400° C.; preferably 25%, more preferably 50%, more preferably 75%, most preferably each of said malodor reduction materials in said sum total of malodor reduction materials has a of from about 160° C. to about 400° C., preferably from about 180° C. to about 400° C.
In one aspect of antiperspirant and/or deodorant composition, said composition comprises a malodor reduction material is selected from the group consisting of Table 1 materials and mixtures thereof; preferably said material is selected from the group consisting of Table 1 materials 1, 2, 3, 4, 7, 9, 10, 11, 13, 14, 16, 17, 18, 21, 22, 23, 25, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 42, 43, 47, 48, 49, 50, 52, 57, 61, 62, 63, 64, 65, 67, 68, 69, 70, 71, 74, 75, 76, 77, 78, 79, 80, 82, 83, 85, 91, 92, 93, 98, 100, 101, 102, 103, 104, 105, 106, 108, 109, 110, 112, 113, 114, 117, 119, 120, 122, 123, 126, 128, 130, 134, 135, 137, 140, 141, 142, 143, 145, 146, 148, 149, 152, 153, 155, 156, 158, 159, 161, 162, 167, 168, 170, 174, 175, 176, 177, 178, 179, 182, 183, 184, 185, 186, 187, 189, 190, 192, 193, 195, 196, 197, 199, 206, 208, 209, 210, 211, 212, 215, 218, 221, 227, 228, 229, 230, 231, 233, 234, 238, 242, 243, 244, 246, 247, 249, 252, 253, 254, 256, 259, 260, 261, 263, 267, 269, 271, 274, 276, 277, 278, 280, 281, 285, 286, 288, 289, 290, 292, 293, 294, 295, 296, 300, 301, 303, 307, 316, 317, 318, 321, 322, 323, 324, 325, 328, 329, 330, 331, 332, 333, 334, 335, 336, 338, 339, 342, 343, 344, 347, 349, 350, 352, 353, 356, 358, 359, 360, 361, 362, 363, 364, 368, 369, 370, 371, 372, 373, 374, 375, 377, 378, 381, 385, 386, 388, 390, 391, 394, 397, 398, 407, 413, 414, 415, 416, 417, 418, 421, 424, 425, 426, 428, 429, 432, 436, 441, 444, 445, 449, 450, 453, 457, 459, 461, 462, 463, 464, 465, 466, 467, 468, 470, 471, 473, 474, 475, 478, 479, 480, 482, 484, 485, 486, 487, 488, 491, 493, 497, 498, 501, 502, 503, 505, 519, 520, 521, 524, 527, 529, 530, 531, 532, 534, 537, 541, 544, 546, 548, 550, 551, 552, 553, 555, 558, 559, 560, 561, 562, 563, 565, 566, 567, 568, 569, 570, 571, 572, 573, 574, 577, 578, 580, 581, 582, 584, 586, 587, 589, 591, 592, 594, 595, 599, 600, 601, 603, 604, 606, 607, 608, 609, 610, 611, 612, 613, 614, 615, 616, 618, 620, 621, 624, 625, 626, 627, 628, 631, 632, 633, 635, 636, 638, 639, 644, 649, 650, 653, 655, 658, 659, 660, 661, 663, 668, 671, 673, 674, 675, 676, 677, 678, 679, 680, 681, 682, 683, 684, 686, 691, 692, 693, 694, 696, 697, 698, 700, 702, 704, 706, 707, 708, 709, 710, 711, 712, 713, 714, 715, 716, 717, 718, 719, 720, 721, 722, 723, 724, 725, 726, 727, 730, 731, 733, 735, 736, 738, 741, 742, 746, 748, 750, 752, 754, 757, 758, 763, 764, 766, 767, 768, 769, 770, 771, 772, 774, 775, 776, 778, 781, 782, 786, 788, 791, 792, 800, 802, 803, 804, 805, 806, 807, 814, 821, 824, 826, 827, 828, 829, 831, 833, 834, 837, 839, 840, 849, 850, 852, 856, 864, 865, 866, 868, 869, 870, 871, 872, 873, 876, 877, 878, 879, 881, 884, 885, 886, 890, 892, 893, 894, 897, 905, 908, 912, 913, 914, 916, 919, 920, 922, 923, 924, 925, 926, 927, 928, 929, 930, 933, 937, 939, 941, 942, 943, 945, 946, 947, 948, 950, 951, 953, 954, 955, 959, 962, 965, 967, 969, 973, 974, 976, 978, 980, 982, 985, 988, 993, 998, 1000, 1003, 1006, 1007, 1008, 1009, 1010, 1012, 1016, 1020, 1021, 1022, 1023, 1024, 1025, 1026, 1027, 1028, 1029, 1031, 1032, 1033, 1035, 1036, 1037, 1038, 1042, 1043, 1045, 1046, 1047, 1053, 1057, 1059, 1060, 1062, 1063, 1064, 1065, 1066, 1067, 1070, 1072, 1073, 1075, 1077, 1078, 1082, 1083, 1085, 1089, 1090, 1091, 1093, 1095, 1097, 1099, 1102, 1104, 1105, 1107, 1111, 1113, 1116, 1117, 1120, 1121, 1125, 1126, 1129, 1131, 1135, 1136, 1137, 1138, 1139, 1140, 1142, 1143, 1144, 1145, 1146, 1147, 1148, 1149, Table 2 materials 2, 23, 141, 185, 227, 230, 246, 248, 343, 359, 565, 631, 659, 674, 678, 679, 715, 758, 1028, 1097, Table 3 materials 12, 19, 20, 24, 26, 27, 53, 54, 55, 59, 72, 73, 81, 84, 96, 97, 107, 111, 115, 116, 125, 133, 147, 150, 151, 154, 157, 163, 166, 169, 181, 191, 194, 198, 201, 204, 205, 213, 214, 232, 237, 239, 255, 258, 264, 270, 273, 275, 282, 283, 284, 287, 302, 306, 308, 310, 312, 314, 319, 346, 354, 355, 365, 366, 376, 379, 387, 400, 412, 419, 420, 437, 438, 439, 440, 442, 443, 447, 448, 454, 455, 469, 472, 477, 481, 492, 495, 496, 504, 509, 510, 512, 515, 517, 518, 522, 525, 526, 528, 535, 536, 538, 540, 542, 547, 549, 554, 556, 557, 575, 576, 579, 583, 585, 588, 602, 605, 617, 619, 640, 641, 645, 647, 651, 652, 662, 664, 665, 667, 672, 687, 699, 701, 703, 740, 743, 744, 745, 755, 760, 761, 777, 779, 784, 789, 796, 797, 799, 808, 810, 811, 812, 817, 819, 820, 832, 835, 836, 838, 845, 846, 847, 848, 851, 858, 875, 880, 882, 883, 888, 889, 891, 899, 900, 901, 902, 903, 904, 909, 918, 921, 931, 940, 956, 958, 960, 971, 977, 981, 983, 986, 987, 994, 995, 1001, 1002, 1004, 1005, 1011, 1017, 1018, 1019, 1030, 1039, 1040, 1041, 1051, 1052, 1054, 1055, 1058, 1061, 1069, 1071, 1074, 1076, 1079, 1081, 1084, 1088, 1098, 1110, 1112, 1115, 1118, 1119, 1122, 1127, 1128, 1133, 1134, 1141 and mixtures thereof; more preferably said material is selected from the group consisting of Table 1 materials 1, 2, 3, 4, 7, 9, 10, 11, 13, 14, 16, 17, 18, 21, 22, 23, 25, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 42, 43, 47, 48, 49, 50, 52, 57, 61, 62, 63, 64, 65, 67, 68, 69, 70, 71, 74, 75, 76, 77, 78, 79, 80, 82, 83, 85, 91, 92, 93, 98, 100, 101, 102, 103, 104, 105, 106, 108, 109, 110, 112, 113, 114, 117, 119, 120, 122, 123, 126, 128, 130, 134, 135, 137, 140, 141, 142, 143, 145, 146, 148, 149, 152, 153, 155, 156, 158, 159, 161, 162, 167, 168, 170, 174, 175, 176, 177, 178, 179, 182, 183, 184, 185, 186, 187, 189, 190, 192, 193, 195, 196, 197, 199, 206, 208, 209, 210, 211, 212, 215, 218, 221, 227, 228, 229, 230, 231, 233, 234, 238, 242, 243, 244, 246, 247, 249, 252, 253, 254, 256, 259, 260, 261, 263, 267, 269, 271, 274, 276, 277, 278, 280, 281, 285, 286, 288, 289, 290, 292, 293, 294, 295, 296, 300, 301, 303, 307, 316, 317, 318, 321, 322, 323, 324, 325, 328, 329, 330, 331, 332, 333, 334, 335, 336, 338, 339, 342, 343, 344, 347, 349, 350, 352, 353, 356, 358, 359, 360, 361, 362, 363, 364, 368, 369, 370, 371, 372, 373, 374, 375, 377, 378, 381, 385, 386, 388, 390, 391, 394, 397, 398, 407, 413, 414, 415, 416, 417, 418, 421, 424, 425, 426, 428, 429, 432, 436, 441, 444, 445, 449, 450, 453, 457, 459, 461, 462, 463, 464, 465, 466, 467, 468, 470, 471, 473, 474, 475, 478, 479, 480, 482, 484, 485, 486, 487, 488, 491, 493, 497, 498, 501, 502, 503, 505, 519, 520, 521, 524, 527, 529, 530, 531, 532, 534, 537, 541, 544, 546, 548, 550, 551, 552, 553, 555, 558, 559, 560, 561, 562, 563, 565, 566, 567, 568, 569, 570, 571, 572, 573, 574, 577, 578, 580, 581, 582, 584, 586, 587, 589, 591, 592, 594, 595, 599, 600, 601, 603, 604, 606, 607, 608, 609, 610, 611, 612, 613, 614, 615, 616, 618, 620, 621, 624, 625, 626, 627, 628, 631, 632, 633, 635, 636, 638, 639, 644, 649, 650, 653, 655, 658, 659, 660, 661, 663, 668, 671, 673, 674, 675, 676, 677, 678, 679, 680, 681, 682, 683, 684, 686, 691, 692, 693, 694, 696, 697, 698, 700, 702, 704, 706, 707, 708, 709, 710, 711, 712, 713, 714, 715, 716, 717, 718, 719, 720, 721, 722, 723, 724, 725, 726, 727, 730, 731, 733, 735, 736, 738, 741, 742, 746, 748, 750, 752, 754, 757, 758, 763, 764, 766, 767, 768, 769, 770, 771, 772, 774, 775, 776, 778, 781, 782, 786, 788, 791, 792, 800, 802, 803, 804, 805, 806, 807, 814, 821, 824, 826, 827, 828, 829, 831, 833, 834, 837, 839, 840, 849, 850, 852, 856, 864, 865, 866, 868, 869, 870, 871, 872, 873, 876, 877, 878, 879, 881, 884, 885, 886, 890, 892, 893, 894, 897, 905, 908, 912, 913, 914, 916, 919, 920, 922, 923, 924, 925, 926, 927, 928, 929, 930, 933, 937, 939, 941, 942, 943, 945, 946, 947, 948, 950, 951, 953, 954, 955, 959, 962, 965, 967, 969, 973, 974, 976, 978, 980, 982, 985, 988, 993, 998, 1000, 1003, 1006, 1007, 1008, 1009, 1010, 1012, 1016, 1020, 1021, 1022, 1023, 1024, 1025, 1026, 1027, 1028, 1029, 1031, 1032, 1033, 1035, 1036, 1037, 1038, 1042, 1043, 1045, 1046, 1047, 1053, 1057, 1059, 1060, 1062, 1063, 1064, 1065, 1066, 1067, 1070, 1072, 1073, 1075, 1077, 1078, 1082, 1083, 1085, 1089, 1090, 1091, 1093, 1095, 1097, 1099, 1102, 1104, 1105, 1107, 1111, 1113, 1116, 1117, 1120, 1121, 1125, 1126, 1129, 1131, 1135, 1136, 1137, 1138, 1139, 1140, 1142, 1143, 1144, 1145, 1146, 1147, 1148, 1149, Table 2 materials 2, 23, 141, 185, 227, 230, 246, 248, 343, 359, 565, 631, 659, 674, 678, 679, 715, 758, 1028, 1097 and mixtures thereof, more preferably said material is selected from the group consisting of Table 4 materials 7, 14, 39, 48, 183, 199, 206, 212, 215, 229, 260, 261, 281, 329, 335, 353, 360, 441, 484, 487, 488, 501, 566, 567, 569, 570, 573, 574, 603, 616, 621, 624, 627, 632, 663, 680, 684, 694, 696, 708, 712, 714, 726, 750, 764, 775, 776, 788, 804, 872, 919, 927, 933, 978, 1007, 1022, 1024, 1027, 1029, 1035, 1038, 1060, 1089, 1107, 1129, 1131, 1136, 1137, 1140, 1142, 1143, 1144, 1145, 1148, 1149, Table 5 materials 248, more preferably said material is selected from the group consisting of Table 4 and 5 materials 261, 680, 788, 1129, 1148, 1149 and mixtures thereof.
In one aspect of said antiperspirant and/or deodorant composition, said sum total of malodor reduction materials has an average boiling point, based on the weight percent of each malodor reduction material in said sum total of malodor reduction materials, of from about 160° C. to about 400° C., preferably from about 180° C. to about 400° C.; preferably 25%, more preferably 50%, more preferably 75%, most preferably each of said malodor reduction materials in said sum total of malodor reduction materials has a of from about 160° C. to about 400° C., preferably from about 180° C. to about 400° C.
In one aspect of said antiperspirant and/or deodorant composition, said composition comprises one or more perfume raw materials.
In one aspect of said antiperspirant and/or deodorant composition, said combination of said sum total of malodor reduction materials and said one or more perfume raw materials combined has an average boiling point, based on the weight percent of each malodor reduction material in said sum total of malodor reduction materials, of from about 160° C. to about 400° C., preferably from about 180° C. to about 400° C.; preferably 25%, more preferably 50%, more preferably 75%, most preferably each of said malodor reduction materials in said sum total of malodor reduction materials and each of said one or more perfume raw materials has a boiling point of from about 160° C. to about 400° C., preferably from about 180° C. to about 400° C.
In one aspect of said antiperspirant and/or deodorant composition, the ratio of said one or more perfume raw materials to said sum total of malodor reduction material is from about 500:1 to about 1:1, preferably from about 50:1 to about 1:1, more preferably from about 20:1 to about 1:1, most preferably from about 2:1 to about 1:1.
In one aspect of said antiperspirant and/or deodorant composition, less than 10%, preferably less than 5%, more preferably less than 1% of said malodor reduction materials and said one or more perfume raw materials, based on total combined weight of malodor reduction materials and said one or more perfume raw materials comprise an ionone moiety.
In one aspect of said antiperspirant and/or deodorant composition, said malodor reduction materials are not selected from the group consisting of Table 1-3 materials 302; 288; 50; 157; 1017; 888; 64; 1054; 832; 375; 390; 745; 504; 505; 140; 1012; 498; 362; 103; 356; 1074; 908; 1127; 475; 918; 687; 611; 317; 9; 141; 550; 602; 913; 1005; 521; 10; 215; 370; 335; 378; 1121; 360; 565; 1136; 1129; 655; 369; 1065; 914; 757; 601; 478; 889; 891; 358; 973; 162; 554; 522; 312; 125; 26; 418; 92; 586; 1026; 218; 31; 828; 871; 829; 1066; 287; 269; 769; 701; 1118; 70; 946; 142; 109; 108 or mixtures thereof.
In one aspect of said antiperspirant and/or deodorant composition, said said antiperspirant and/or deodorant composition is a antiperspirant composition that comprises a total of, based on total antiperspirant composition weight, from about 0.1% to about 7% of one or more of said malodor reduction materials and, optionally, from about 1% to about 25% of an aluminum salt antiperspirant active.
In one aspect of said antiperspirant and/or deodorant composition, said composition is an anhydrous antiperspirant composition, said anhydrous antiperspirant composition comprising a total of, based on total anhydrous antiperspirant composition weight, from about 0.1% to about 7% of one or more of said malodor reduction materials and from about 1% to about 25% of an antiperspirant actives selected from the group consisting of astringent metallic salts, preferably inorganic and organic salts of aluminum, zirconium and zinc, as well as mixtures thereof, more preferably aluminum halides, aluminum chlorohydrate, aluminum hydroxyhalides, zirconyl oxyhalides, zirconyl hydroxyhalides, and mixtures thereof.
In one aspect of said antiperspirant and/or deodorant composition, said composition comprises an adjunct ingredient selected from the group consisting of clay mineral powders, pearl pigments, organic powders, emulsifiers, distributing agents, pharmaceutical active, topical active, preservatives, surfactants and mixtures thereof.
A method of controlling malodors comprising: contacting a situs comprising a malodor and/or a situs that may become malodorous with an antiperspirant or deodorant composition selected from the group consisting of the antiperspirant and/or deodorant composition disclosed herein, is disclosed.
In one aspect of said method, said situs is an underarm and said contacting step comprises contacting said underarm with a sufficient amount of Applicants' antiperspirant and/or deodorant composition containing said sum of malodor reduction materials to provide said underarm with a level of malodor reduction materials of at least 0.0001 mg of malodor reduction material per underarm, preferably from about 0.0001 mg of malodor reduction material per underarm to about 10 mg of malodor reduction material per underarm, more preferably from about 0.001 mg of malodor reduction material per underarm about 5 mg of malodor reduction material per underarm, most preferably from about 0.01 of malodor reduction material per underarm to about 0.2 mg of malodor reduction material per underarm.

Antiperspirant Compositions

Antiperspirant compositions can be formulated in many forms. For example an antiperspirant composition can be, without limitation, a roll on product, a body spray, a stick including soft solid sticks and invisible solids, or an aerosol. Each of the antiperspirant compositions described below can include perfume materials as described herein.
A. Roll-On and Clear Gel
A roll-on antiperspirant composition can comprise, for example, water, emollient, solubilizer, deodorant actives, antioxidants, preservatives, or combinations thereof. A clear gel antiperspirant composition can comprise, for example, water, emollient, solubilizer, deodorant actives, antioxidants, preservatives, ethanol, or combinations thereof.
Water
The roll-on composition can include water. Water can be present in an amount of about 1% to about 99.5%, about 25% to about 99.5%, about 50% to about 99.5%, about 75% to about 99.5% about 80% to about 99.5%, from about 15% to about 45%, or any combination of the end points and points encompassed within the ranges, by weight of the deodorant composition.
Emollients
Roll-on compositions can comprise an emollient system including at least one emollient, but it could also be a combination of emollients. Suitable emollients are often liquid under ambient conditions. Depending on the type of product form desired, concentrations of the emollient(s) in the deodorant compositions can range from about 1% to about 95%, from about 5% to about 95%, from about 15% to about 75%, from about 1% to about 10%, from about 15% to about 45%, or from about 1% to about 30%, by weight of the deodorant composition.
Emollients suitable for use in the roll-on compositions include, but are not limited to, propylene glycol, polypropylene glycol (like dipropylene glycol, tripropylene glycol, etc.), diethylene glycol, triethylene glycol, PEG-4, PEG-8, 1,2 pentanediol, 1,2 hexanediol, hexylene glycol, glycerin, C2 to C20 monohydric alcohols, C2 to C40 dihydric or polyhydric alcohols, alkyl ethers of polyhydric and monohydric alcohols, volatile silicone emollients such as cyclopentasiloxane, nonvolatile silicone emollients such as dimethicone, mineral oils, polydecenes, petrolatum, and combinations thereof. One example of a suitable emollient comprises PPG-15 stearyl ether. Other examples of suitable emollients include dipropylene glycol and propylene glycol.
Deodorant Actives
Suitable deodorant actives can include any topical material that is known or otherwise effective in preventing or eliminating malodor associated with perspiration. Suitable deodorant actives may be selected from the group consisting of antimicrobial agents (e.g., bacteriocides, fungicides), malodor-absorbing material, and combinations thereof. For example, antimicrobial agents may comprise cetyl-trimethylammonium bromide, cetyl pyridinium chloride, benzethonium chloride, diisobutyl phenoxy ethoxy ethyl dimethyl benzyl ammonium chloride, sodium N-lauryl sarcosine, sodium N-palmethyl sarcosine, lauroyl sarcosine, N-myristoyl glycine, potassium N-lauryl sarcosine, trimethyl ammonium chloride, sodium aluminum chlorohydroxy lactate, triethyl citrate, tricetylmethyl ammonium chloride, 2,4,4′-trichloro-2′-hydroxy diphenyl ether (triclosan), 3,4,4′-trichlorocarbanilide (triclocarban), diaminoalkyl amides such as L-lysine hexadecyl amide, heavy metal salts of citrate, salicylate, and piroctose, especially zinc salts, and acids thereof, heavy metal salts of pyrithione, especially zinc pyrithione, zinc phenolsulfate, farnesol, and combinations thereof. The concentration of the optional deodorant active may range from about 0.001%, from about 0.01%, of from about 0.1%, by weight of the composition to about 20%, to about 10%, to about 5%, or to about 1%, by weight of the composition.
Odor Entrappers
The composition can include an odor entrapper. Suitable odor entrappers for use herein include, for example, solubilized, water-soluble, uncomplexed cyclodextrin. As used herein, the term “cyclodextrin” includes any of the known cyclodextrins such as unsubstituted cyclodextrins containing from six to twelve glucose units, especially, alpha-cyclodextrin, beta-cyclodextrin, gamma-cyclodextrin and/or their derivatives and/or mixtures thereof. The alpha-cyclodextrin consists of six glucose units, the beta-cyclodextrin consists of seven glucose units, and the gamma-cyclodextrin consists of eight glucose units arranged in a donut-shaped ring. The specific coupling and conformation of the glucose units give the cyclodextrins a rigid, conical molecular structure with a hollow interior of a specific volume. The “lining” of the internal cavity is formed by hydrogen atoms and glycosidic bridging oxygen atoms, therefore this surface is fairly hydrophobic. The unique shape and physical-chemical property of the cavity enable the cyclodextrin molecules to absorb (form inclusion complexes with) organic molecules or parts of organic molecules which can fit into the cavity. Many perfume molecules can fit into the cavity. Cyclodextrin molecules are described in U.S. Pat. No. 5,714,137, and U.S. Pat. No. 5,942,217. Suitable levels of cyclodextrin are from about 0.1% to about 5%, alternatively from about 0.2% to about 4%, alternatively from about 0.3% to about 3%, alternatively from about 0.4% to about 2%, by weight of the composition.
Buffering Agent
The composition can include a buffering agent which may be alkaline, acidic or neutral. The buffer can be used in the composition for maintaining the desired pH. The composition may have a pH from about 3 to about 10, from about 4 to about 9, from about 5 to about 8, from about 6 to about 7, or it may have a pH of about 6.5. One unique feature of the polyvinyl amine malodor control polymers is its ability to maintain active nitrogen sites at high pH levels which can help enhance the antibacterial effect which comes, at least in part, from the nitrogen sites.
Suitable buffering agents include, for example, hydrochloric acid, sodium hydroxide, potassium hydroxide, and combinations thereof.
The compositions can contain at least about 0%, alternatively at least about 0.001%, alternatively at least about 0.01%, by weight of the composition, of a buffering agent. The composition may also contain no more than about 1%, alternatively no more than about 0.75%, alternatively no more than about 0.5%, by weight of the composition, of a buffering agent.
Solubilizer
The composition can contain a solubilizer. A suitable solubilizer can be, for example, a surfactant, such as a no-foaming or low-foaming surfactant. Suitable surfactants are nonionic surfactants, cationic surfactants, amphoteric surfactants, zwitterionic surfactants, and mixtures thereof.
Suitable solubilizers include, for example, hydrogenated castor oil, polyoxyethylene 2 stearyl ether, polyoxyethylene 20 stearyl ether, and combinations thereof. One suitable hydrogenated castor oil that may be used in the present composition is polyoxyethylene hydrogenated castor oil.
When the solubilizing agent is present, it is typically present at a level of from about 0.01% to about 5%, alternatively from about 0.01% to about 3%, alternatively from about 0.05% to about 1%, alternatively from about 0.01% to about 0.05%, by weight of the composition.
Preservatives
The composition can include a preservative. The preservative is included in an amount sufficient to prevent spoilage or prevent growth of inadvertently added microorganisms for a specific period of time, but not sufficient enough to contribute to the odor neutralizing performance of the composition. In other words, the preservative is not being used as the antimicrobial compound to kill microorganisms on the surface onto which the composition is deposited in order to eliminate odors produced by microorganisms. Instead, it is being used to prevent spoilage of the composition in order to increase shelf-life.
The preservative can be any organic preservative material which will not cause damage to fabric appearance, e.g., discoloration, coloration, bleaching. Suitable water-soluble preservatives include organic sulfur compounds, halogenated compounds, cyclic organic nitrogen compounds, low molecular weight aldehydes, parabens, propane diol materials, isothiazolinones, quaternary compounds, benzoates, low molecular weight alcohols, dehydroacetic acid, phenyl and phenoxy compounds, or mixtures thereof.
Non-limiting examples of commercially available water-soluble preservatives include a mixture of about 77% 5-chloro-2-methyl-4-isothiazolin-3-one and about 23% 2-methyl-4-isothiazolin-3-one, a broad spectrum preservative available as a 1.5% aqueous solution under the trade name Kathon® CG by Rohm and Haas Co.; 5-bromo-5-nitro-1,3-dioxane, available under the tradename Bronidox L® from Henkel; 2-bromo-2-nitropropane-1,3-diol, available under the trade name Bronopol® from Inolex; 1,1′-hexamethylene bis(5-(p-chlorophenyl)biguanide), commonly known as chlorhexidine, and its salts, e.g., with acetic and digluconic acids; a 95:5 mixture of 1,3-bis(hydroxymethyl)-5,5-dimethyl-2,4-imidazolidinedione and 3-butyl-2-iodopropynyl carbamate, available under the trade name Glydant Plus® from Lonza; N-[1,3-bis(hydroxymethyl)2,5-dioxo-4-imidazolidinyl]-N,N′-bis(hydroxy-methyl)urea, commonly known as diazolidinyl urea, available under the trade name Germall® II from Sutton Laboratories, Inc.; N,N″-methylenebis{N′-[1-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl]urea}, commonly known as imidazolidinyl urea, available, e.g., under the trade name Abiol® from 3V-Sigma, Unicide U-13® from Induchem, Germall 115® from Sutton Laboratories, Inc.; polymethoxy bicyclic oxazolidine, available under the trade name Nuosept® C from Hüls America; formaldehyde; glutaraldehyde; polyaminopropyl biguanide, available under the trade name Cosmocil CQ® from ICI Americas, Inc., or under the trade name Mikrokill® from Brooks, Inc; dehydroacetic acid; and benzsiothiazolinone available under the trade name Koralone™ B-119 from Rohm and Hass Corporation.
Suitable levels of preservative can range from about 0.0001% to about 0.5%, alternatively from about 0.0002% to about 0.2%, alternatively from about 0.0003% to about 0.1%, by weight of the composition.
B. Body Spray
A body spray can contain, for example, a carrier, perfume, a deodorant active, odor entrappers, propellant, or combinations thereof. The body spray compositions can be applied as a liquid.
Carrier
A carrier suitable for use in a body spray can include, water, alcohol, or combinations thereof. The carrier may be present in an amount of about 1% to about 99.5%, about 25% to about 99.5%, about 50% to about 99.5%, about 75% to about 99.5% about 80% to about 99.5%, from about 15% to about 45%, or any combination of the end points and points encompassed within the ranges, by weight of the composition. A suitable example of an alcohol can include ethanol.
Propellant
The compositions described herein can include a propellant. Some examples of propellants include compressed air, nitrogen, inert gases, carbon dioxide, and mixtures thereof. Propellants may also include gaseous hydrocarbons like propane, n-butane, isobutene, cyclopropane, and mixtures thereof. Halogenated hydrocarbons like 1,1-difluoroethane may also be used as propellants. Some non-limiting examples of propellants include 1,1,1,2,2-pentafluoroethane, 1,1,1,2-tetrafluoroethane, 1,1,1,2,3,3,3-heptafluoropropane, trans-1,3,3,3-tetrafluoroprop-1-ene, dimethyl ether, dichlorodifluoromethane (propellant 12), 1,1-dichloro-1,1,2,2-tetrafluoroethane (propellant 114), 1-chloro-1,1-difluoro-2,2-trifluoroethane (propellant 115), 1-chloro-1,1-difluoroethylene (propellant 142B), 1,1-difluoroethane (propellant 152A), monochlorodifluoromethane, and mixtures thereof. Some other propellants suitable for use include, but are not limited to, A-46 (a mixture of isobutane, butane and propane), A-31 (isobutane), A-17 (n-butane), A-108 (propane), AP70 (a mixture of propane, isobutane and n-butane), AP40 (a mixture of propane, isobutene and n-butane), AP30 (a mixture of propane, isobutane and n-butane), and 152A (1,1 diflouroethane). The propellant may have a concentration from about 15%, 25%, 30%, 32%, 34%, 35%, 36%, 38%, 40%, or 42% to about 70%, 65%, 60%, 54%, 52%, 50%, 48%, 46%, 44%, or 42%, or any combination thereof, by weight of the total fill of materials stored within the container.
C. Invisible Solid
Invisible solid antiperspirant compositions as described herein can contain a primary structurant, an antiperspirant active, a perfume, and additional chassis ingredient(s). The antiperspirant composition can further comprise other optional ingredient(s). The compositions can be in the form of a solid stick. The compositions can have a product hardness of about 600 gram force or more. The compositions may be free of dipropylene glycol, added water, castor wax, or any combination thereof. The antiperspirant composition may be anhydrous. The antiperspirant composition may be free of added water.
Hardness
The invisible solid can have a product hardness of least about 600 gram·force, more specifically from about 600 gram·force to about 5,000 gram·force, still more specifically from about 750 gram·force to about 2,000 gram·force, and yet more specifically from about 800 gram·force to about 1,400 gram·force.
The term “product hardness” or “hardness” as used herein is a reflection of how much force is required to move a penetration cone a specified distance and at a controlled rate into an antiperspirant composition under the test conditions described herein below. Higher values represent harder product, and lower values represent softer product. These values are measured at 27° C., 15% relative humidity, using a TA-XT2 Texture Analyzer, available from Texture Technology Corp., Scarsdale, N.Y., U.S.A. The product hardness value as used herein represents the peak force required to move a standard 45-degree angle penetration cone through the composition for a distance of 10 mm at a speed of 2 mm/second. The standard cone is available from Texture Technology Corp., as part number TA-15, and has a total cone length of about 24.7 mm, angled cone length of about 18.3 mm, and a maximum diameter of the angled surface of the cone of about 15.5 mm. The cone is a smooth, stainless steel construction and weighs about 17.8 grams.
Primary Structurants
The invisible solid can comprise a suitable concentration of a primary structurant to help provide the antiperspirant with the desired viscosity, rheology, texture and/or product hardness, or to otherwise help suspend any dispersed solids or liquids within the composition.
The term “solid structurant” as used herein means any material known or otherwise effective in providing suspending, gelling, viscosifying, solidifying, and/or thickening properties to the composition or which otherwise provide structure to the final product form. These solid structurants include gelling agents, and polymeric or non-polymeric or inorganic thickening or viscosifying agents. Such materials will typically be solids under ambient conditions and include organic solids, crystalline or other gellants, inorganic particulates such as clays or silicas, or combinations thereof.
The concentration and type of solid structurant selected for use in the antiperspirant compositions will vary depending upon the desired product hardness, rheology, and/or other related product characteristics. For most structurants suitable for use herein, the total structurant concentration ranges from about 5% to about 35%, more typically from about 10% to about 30%, or from about 7% to about 20%, by weight of the composition.
Non-limiting examples of suitable primary structurants include stearyl alcohol and other fatty alcohols; hydrogenated castor wax (e.g., Castorwax MP80, Castor Wax, etc.); hydrocarbon waxes include paraffin wax, beeswax, carnauba, candelilla, spermaceti wax, ozokerite, ceresin, baysberry, synthetic waxes such as Fischer-Tropsch waxes, and microcrystalline wax; polyethylenes with molecular weight of 200 to 1000 daltons; solid triglycerides; behenyl alcohol, or combinations thereof.
Other non-limiting examples of primary structurants suitable for use herein are described in U.S. Pat. No. 5,976,514 and U.S. Pat. No. 5,891,424,the descriptions of which are incorporated herein by reference.
Antiperspirant Active
The antiperspirant stick compositions can comprise a particulate antiperspirant active suitable for application to human skin. The concentration of antiperspirant active in the composition should be sufficient to provide the desired perspiration wetness and odor control from the antiperspirant stick formulation selected.
The antiperspirant stick compositions can comprise an antiperspirant active at concentrations of from about 0.5% to about 60%, and more specifically from about 5% to about 35%, by weight of the composition. These weight percentages are calculated on an anhydrous metal salt basis exclusive of water and any complexing agents such as, for example, glycine, and glycine salts. The antiperspirant active as formulated in the composition can be in the form of dispersed particulate solids having an average particle size or equivalent diameter of less than about 100 microns, more specifically less than about 20 microns, and even more specifically less than about 10 microns.
The antiperspirant active for use in the anhydrous antiperspirant compositions of the present invention can include any compound, composition or other material having antiperspirant activity. More specifically, the antiperspirant actives may include astringent metallic salts, especially inorganic and organic salts of aluminum, zirconium and zinc, as well as mixtures thereof. Even more specifically, the antiperspirant actives may include aluminum-containing and/or zirconium-containing salts or materials, such as, for example, aluminum halides, aluminum chlorohydrate, aluminum hydroxyhalides, zirconyl oxyhalides, zirconyl hydroxyhalides, and mixtures thereof.
Aluminum salts for use in the anhydrous antiperspirant stick compositions include those that conform to the formula:
Al₂(OH)_aCl_b.xH₂O,

wherein a is from about 2 to about 5;
the sum of a and b is about 6;
x is from about 1 to about 6; and
a, b, and x may have non-integer values.

More specifically, aluminum chlorohydroxides referred to as “5/6 basic chlorohydroxide” can be used, wherein a=5, and “2/3 basic chlorohydroxide”, wherein a=4.
Processes for preparing aluminum salts are disclosed in U.S. Pat. No. 3,887,692; U.S. Pat. No. 3,904,741; U.S. Pat. No. 4,359,456; and British Patent Specification 2,048,229, the disclosures of which are incorporated herein by reference for the purpose of describing processes for preparing aluminum salts.
Mixtures of aluminum salts are described in British Patent Specification 1,347,950, which description is also incorporated herein by reference.
Zirconium salts for use in the anhydrous antiperspirant stick compositions include those which conform to the formula:
ZrO(OH)_2-aCl_a.xH₂O,

wherein a is from about 1.5 to about 1.87;
x is from about 1 to about 7; and
a and x may both have non-integer values.

These zirconium salts are described in Belgian Patent 825,146, Schmitz, issued Aug. 4, 1975, which description is incorporated herein by reference. Zirconium salts that additionally contain aluminum and glycine, commonly known as “ZAG complexes,” are believed to be especially beneficial. These ZAG complexes contain aluminum chlorohydroxide and zirconyl hydroxy chloride conforming to the above-described formulas. Such ZAG complexes are described in U.S. Pat. No. 3,792,068; Great Britain Patent Application 2,144,992; and U.S. Pat. No. 4,120,948, disclosures of which are incorporated herein by reference for the limited purpose of describing ZAG complexes.
Also suitable for use herein are enhanced efficacy aluminum-zirconium chlorohydrex-amino acid which typically has the empirical formula Al_nZr(OH)_{[3n+4-m(n+1)]}(Cl)_[m(n+1)]-AA_qwhere n is 2.0 to 10.0, preferably 3.0 to 8.0; m is about 0.48 to about 1.11 (which corresponds to M:Cl approximately equal to 2.1-0.9), preferably about 0.56 to about 0.83 (which corresponds to M:Cl approximately equal to 1.8-1.2); q is about 0.8 to about 4.0, preferably about 1.0 to 2.0; and AA is an amino acid such as glycine, alanine, valine, serine, leucine, isoleucine, β-alanine, cysteine, β-amino-n-butyric acid, or y-amino-n-butyric acid, preferably glycine. These salts also generally have some water of hydration associated with them, typically on the order of 1 to 5 moles per mole of salt (typically, about 1% to about 16%, more typically about 4% to about 13% by weight). These salts are generally referred to as aluminum-zirconium trichlorohydrex or tetrachlorohydrex when the Al:Zr ratio is between 2 and 6 and as aluminum-zirconium pentachlorohydrex or octachlorohydrex when the Al:Zr ratio is between 6 and 10. The term “aluminum-zirconium chlorohydrex” is intended to embrace all of these forms. The preferred aluminum-zirconium salt is aluminum-zirconium chlorohydrex-glycine. Additional examples of suitable high efficacy antiperspirant actives can include Aluminum Zirconium Pentachlorohydrex Glycine, Aluminum Zirconium Octachlorohydrex Glycine, or a combination thereof. These high efficacy actives are more fully described in U.S. App. Pub. No. 2007/0003499 by Shen et al. filed Jun. 30, 2005.

Additional Chassis Ingredients

Additional Structurant

The antiperspirant composition can further comprise an additional structurant. The additional structurant may be present in an amount from 1% to about 10%, by weight of the composition. The additional structurant(s) will likely be present at an amount less than the primary structurant.
Non-limiting examples of suitable additional structurants include stearyl alcohol and other fatty alcohols; hydrogenated castor wax (e.g., Castorwax MP80, Castor Wax, etc.); hydrocarbon waxes include paraffin wax, beeswax, carnauba, candelilla, spermaceti wax, ozokerite, ceresin, baysberry, synthetic waxes such as Fisher-Tropsch waxes, and microcrystalline wax; polyethylenes with molecular weight of 200 to 1000 daltons; and solid triglycerides; behenyl alcohol, or combinations thereof.
Other non-limiting examples of additional structurants suitable for use herein are described in U.S. Pat. No. 5,976,514 and U.S. Pat. No. 5,891,424.
Solvent
The antiperspirant composition can comprise a solvent at concentrations ranging from about 20% to about 80%, and more specifically from about 30% to about 70%, by weight of the composition. The solvent can be a volatile silicone which may be cyclic or linear.
“Volatile silicone” as used herein refers to those silicone materials that have measurable vapor pressure under ambient conditions. Non-limiting examples of suitable volatile silicones are described in Todd et al., “Volatile Silicone Fluids for Cosmetics”, Cosmetics and Toiletries, 91:27-32 (1976), which descriptions are incorporated herein by reference.
The volatile silicone can be a cyclic silicone having from 3 to 7, and more specifically from 5 to 6, silicon atoms, and still more specifically 5, like cyclopentasiloxane. These cyclic silicone materials will generally have viscosities of less than about 10 centistokes at 25° C. Linear volatile silicone materials suitable for use in the antiperspirant compositions include those represented by the formula:
wherein n is from 1 to 7, and more specifically from 2 to 3. These linear silicone materials will generally have viscosities of less than about 5 centistokes at 25° C.
Specific examples of volatile silicone solvents suitable for use in the antiperspirant compositions include, but are not limited to, Cyclomethicone D-5; GE 7207 and GE 7158 (commercially available from General Electric Co.); Dow Corning 344; Dow Corning 345; Dow Corning 200; and DC1184 (commercially available from Dow Corning Corp.); and SWS-03314 (commercially available from SWS Silicones).
Non-Volatile Organic Fluids
Non-volatile organic fluids may be present, for example, in an amount of about 15% or less, by weight of the composition.
Non-limiting examples of nonvolatile organic fluids include mineral oil, PPG-14 butyl ether, isopropyl myristate, petrolatum, butyl stearate, cetyl octanoate, butyl myristate, myristyl myristate, C12-15 alkylbenzoate (e.g., Finsolv™), octyldodecanol, isostearyl isostearate, octododecyl benzoate, isostearyl lactate, isostearyl palmitate, and isobutyl stearate.

Adjunct Ingredients

The anhydrous antiperspirant compositions can further comprise any optional material that is known for use in antiperspirant and deodorant compositions or other personal care products, or which is otherwise suitable for topical application to human skin.
One example of optional materials are clay mineral powders such as talc, mica, sericite, silica, magnesium silicate, synthetic fluorphlogopite, calcium silicate, aluminum silicate, bentonite and montomorillonite; pearl pigments such as alumina, barium sulfate, calcium secondary phosphate, calcium carbonate, titanium oxide, finely divided titanium oxide, zirconium oxide, zinc oxide, hydroxy apatite, iron oxide, iron titrate, ultramarine blue, Prussian blue, chromium oxide, chromium hydroxide, cobalt oxide, cobalt titanate, titanium oxide coated mica; organic powders such as polyester, polyethylene, polystyrene, methyl methacrylate resin, cellulose, 12-nylon, 6-nylon, styrene-acrylic acid copolymers, poly propylene, vinyl chloride polymer, tetrafluoroethylene polymer, boron nitride, fish scale guanine, laked tar color dyes, laked natural color dyes; and combinations thereof.
Talc, if used at higher levels can produce a significant amount of white residue which has been found to be a consumer negative for product acceptance. Therefore it is best to limit the composition to less than 10%, less than about 8%, less than about 6%, or less than about 3%, by weight of the composition.
Nonlimiting examples of other optional materials include emulsifiers, distributing agents, antimicrobials, pharmaceutical or other topical active, preservatives, surfactants, and so forth. Examples of such optional materials are described in U.S. Pat. No. 4,049,792; U.S. Pat. No. 5,019,375; and U.S. Pat. No. 5,429,816; which descriptions are incorporated herein by reference.
D. Soft Solid
Soft solid composition can comprise volatile silicone, antiperspirant active, gellant, residue masking material, or combinations thereof. In addition, soft solids generally have a hardness value after dispensing of about 500 gram force or less.
Volatile Silicone Solvent
The soft solid can comprises a volatile silicone solvent at concentrations ranging from about 20% to about 80%, preferably from about 30% to about 70%, more preferably from about 45% to about 70%, by weight of the composition. The volatile silicone of the solvent may be cyclic or linear.
“Volatile silicone” as used herein refers to those silicone materials which have measurable vapor pressure under ambient conditions. Nonlimiting examples of suitable volatile silicones are described in Todd et al., “Volatile Silicone Fluids for Cosmetics”, Cosmetics and Toiletries, 91:27-32 (1976), which descriptions are incorporated herein by reference. Preferred volatile silicone materials are those having from about 3 to about 7, preferably from about 4 to about 5, silicon atoms.
Cyclic volatile silicones are preferred for use in the antiperspirant compositions herein, and include those represented by the formula:
wherein n is from about 3 to about 7, preferably from about 4 to about 5, most preferably 5. These cyclic silicone materials will generally have viscosities of less than about 10 centistokes at 25° C.
Linear volatile silicone materials suitable for use in the antiperspirant compositions include those represented by the formula:
wherein n is from about 1 to about 7, preferably from about 2 to about 3. These linear silicone materials will generally have viscosities of less than about 5 centistokes at 25° C.
Specific examples of volatile silicone solvents suitable for use in the antiperspirant compositions include, but are not limited to, Cyclomethicone D-5 (commercially available from G. E. Silicones), Dow Corning 344, Dow Corning 345 and Dow Corning 200 (commercially available from Dow Corning Corp.), GE 7207 and 7158 (commercially available from General Electric Co.) and SWS-03314 (commercially available from SWS Silicones Corp.).
Gellant Material
The soft solid can include a gellant material comprising fatty alcohols having from about 20 to about 60 carbon atoms, or combinations thereof, at concentrations ranging from about 0.1% to about 8% by weight of the composition. The gellant material, when combined with the volatile silicone solvent described hereinbefore, provides the composition with a physically stable structure within which the particulate antiperspirant materials are dispersed, and maintained as such over an extended period of time.
Specifically, the gellant material can comprise saturated or unsaturated, substituted or unsubstituted, fatty alcohols or mixtures of fatty alcohols having from about 20 to about 60 carbons atoms, preferably from about 20 to about 40 carbon atoms. Preferred are combinations of the fatty alcohols. The fatty alcohol gellants are preferably saturated, unsubstituted monohydric alcohols or combinations thereof, which have a melting point of at less than about 110° C., more preferably from about 60° to about 110° C., even more preferably between about 100° C. and 110° C.
It has been found that this fatty alcohol-based gellant material, when combined with volatile silicone solvents provides a stable structure for maintaining a dispersion of particulate antiperspirant material in a topical formulation without the necessity of using conventional particulate thickening agents. This gellant material is especially useful in maintaining the physical stability of particulate dispersions containing higher concentrations of volatile silicone solvents.
It was also found that penetration force values for the antiperspirant compositions can be controlled by adjusting total fatty alcohol concentrations. In controlling penetration force values in this manner, there is no longer a need to use organic solvents or thickening agents to control penetration force values, which solvents or thickening agents often add cost to the formulation, introduce additional compatibility issues, and often contribute undesirable cosmetics such as prolonged stickiness, difficulty in ease of spreading, increased dry-down times and reduced dry feel after application.
Specific concentrations of the gellant materials can be selected according to the desired penetration force value. For roll-on formulations having a penetration force value of from about 20 gram·force to about 100 gram·force, gellant material concentrations preferably range from about 0.1% to about 3% , preferably from about 1.5% to about 3%, by weight of the antiperspirant composition. For other cream formulations, including those formulations suitable for use in cream applicator devices, which have a penetration force value of from about 100 gram·force to about 500 gram·force, gellant material concentrations preferably range from about 3% to about 8%, preferably from about 3% to about 6%, by weight of the antiperspirant composition.
Specific examples of fatty alcohol gellants for use in the antiperspirant compositions that are commercially available include, but are not limited to, Unilin® 425, Unilin® 350, Unilin® 550 and Unilin® 700 (supplied by Petrolite)
Residue Masking Material
The soft solid compositions can further comprise a nonvolatile emollient as a residue masking material Such materials and their use in antiperspirant products are well known in the antiperspirant art, and any such material may be incorporated into the composition of the present invention, provided that such optional material is compatible with the essential elements of the composition, or does not unduly impair product performance or cosmetics.
Concentrations of the optional residue masking material can range from about 0.1% to about 40%, preferably from about 1% to about 10%, by weight of the antiperspirant composition. These optional materials can be liquid at ambient temperatures, and can be nonvolatile. The term “nonvolatile” as used in this context refers to materials which have a boiling point under atmospheric pressure of at least about 200° C. Nonlimiting examples of suitable residue masking materials for use in the antiperspirant products include butyl stearate, diisopropyl adipate, petrolatum, nonvolatile silicones, octyldodecanol, phenyl trimethicone, isopropyl myristate, C12-15 ethanol benzoates and PPG-14 Butyl Ether. Residue masking materials are described, for example, in U.S. Pat. No. 4,985,238, which description is incorporated herein by reference.
Other Materials
The soft solid compositions can further comprise one, or more, other materials which modify the physical characteristics of the compositions or serve as additional “active” components when deposited on the skin. Many such materials are known in the antiperspirant art and can be used in the antiperspirant compositions herein, provided that such optional materials are compatible with the essential materials described herein, or do not otherwise unduly impair product performance.
Non limiting examples of materials can include active components such as bacteriostats and fungiostats, and “non-active” components such as colorants, perfumes, cosmetic powders, emulsifiers, chelants, distributing agents, preservatives, and wash-off aids. Examples of such optional materials are described in U.S. Pat. No. 4,049,792; Canadian Patent 1,164,347; U.S. Pat. No. 5,019,375; and U.S. Pat. No. 5,429,816; which descriptions are incorporated herein by reference.
E. Aerosol
An aerosol composition can comprise a concentrate, a propellant, or a combination thereof. Alcohol is a predominant component of the concentrates provided herein. Useful alcohols include C₁-C₃alcohols, with the preferred alcohol being ethanol. In certain examples, the alcohol is employed at a concentration level of from at least about 40%, 50% or 55% to about 80%, by weight of the concentrate.
An antiperspirant active is dissolved in the alcohol, at a level of from about 1% to about 15%, by weight of the concentrate. Various antiperspirant actives can be employed, including, for example, aluminum chloride, aluminum chlorohydrate, aluminum chlorohydrex, aluminum chlorohydrex PG, aluminum chlorohydrex PEG, aluminum dichlorohydrate, aluminum dichlorohydrex PG, aluminum dichlorohydrex PEG, aluminum sesquichlorohydrate, aluminum sesquichlorohydrex PG, aluminum sesquichlorohydrex PEG, aluminum sulfate, aluminum zirconium octachlorohydrate, aluminum zirconium octachlorohydrex GLY, aluminum zirconium pentachlorohydrate, aluminum zirconium pentachlorohydrex GLY, aluminum zirconium tetrachlorohydrate, aluminum zirconium trichlorohydrate, aluminum zirconium tetrachlorohydrate GLY, and aluminum zirconium trichlorohydrate GLY. In one example, aluminum chlorohydrex PG is the chosen antiperspirant active.
The antiperspirant concentrates can also include an oil or a mixture of two or more oils. Useful oils include, for example, volatile silicone oils and non-volatile organic oils. “Volatile silicone”, as used herein, refers to those silicone materials that have measurable vapor pressure under ambient conditions. Non-limiting examples of suitable volatile silicones are described in Todd et al., “Volatile Silicone Fluids for Cosmetics”, Cosmetics and Toiletries, 91:27-32 (1976). The volatile silicone can be a cyclic silicone having from at least about 3 silicone atoms or from at least about 5 silicone atoms but no more than about 7 silicone atoms or no more than about 6 silicone atoms. For example, volatile silicones can be used which conform to the formula:
wherein n is from about 3 or from about 5 but no more than about 7 or no more than about 6. These volatile cyclic silicones generally have a viscosity of less than about 10 centistokes at 25° C. Suitable volatile silicones for use herein include, but are not limited to, Cyclomethicone D5 (commercially available from G. E. Silicones); Dow Corning 344, and Dow Corning 345 (commercially available from Dow Corning Corp.); and GE 7207, GE 7158 and Silicone Fluids SF-1202 and SF-1173 (available from General Electric Co.). SWS-03314, SWS-03400, F-222, F-223, F-250, F-251 (available from SWS Silicones Corp.); Volatile Silicones 7158, 7207, 7349 (available from Union Carbide); MASIL SF-V (available from Mazer) and combinations thereof. Suitable volatile silicone oils can also include linear silicone oils such as, for example, DC200 (1 cSt), DC200 (0.65 cSt), and DC2-1184, all of which are available from Dow Corning Corp. In certain examples, the volatile silicone oil can have a viscosity of less than 10 centistokes at 25° C.
Non-volatile organic, emollient oils can also be employed. A representative, non-limiting list of emollient oils includes CETIOL CC (dicaprylyl carbonate), CETIOL OE (dicaprylyl ether), CETIOL S (diethylhexylcyclohexane), and CETIOL B (dibutyl adipate), all of which are available from Cognis, and LEXFEEL 7 (neopentyl glycol diheptanoate) from Inolex. In certain examples, the organic emollient oils have a viscosity of less than 50 centistokes at 25° C. The term “organic emollient oil” as used herein means silicon-free emollient oils that are liquid at 25° C., and that are safe and light to skin and can be miscible with volatile silicone oils (as described above) and the antiperspirant active-alcohol solution in the concentration ranges described below.
The oil or mixture of oils is generally included in the concentrate formulas at a level of from about 5% to about 45%, by weight of the concentrate. This viscosity ranges noted above in connection with the different classes of oil can facilitate desired spray rates and patterns, and can help minimize nozzle clogging. To provide desired skin feel, minimal nozzle clogging, and good concentrate stability, the ratio of alcohol to volatile silicone oil is preferably greater than 1.0, 1.35, or 1.5. And in examples having both a volatile silicone oil and an organic emollient oil, the ratio of alcohol to total oil is preferably greater than or equal to about 0.90. The oils in certain examples are miscible with the alcohol and antiperspirant active solution. Although various levels of miscibility are acceptable, the oils are preferably miscible enough with the alcohol and antiperspirant active solution to yield a concentrate having a clear appearance.
The antiperspirant compositions can also include residue-masking agents and propellants as discussed above.

Test Methods

Malodor reduction materials may be separated from mixtures, including but not limited to finished products such as consumer products and identified, by analytical methods that include GC-MS and/or NMR.

Test Method for Determining Saturation Vapour Pressure (VP)

The saturation Vapour Pressure (VP) values are computed for each PRM in the perfume mixture being tested. The VP of an individual PRM is calculated using the VP Computational Model, version 14.02 (Linux) available from Advanced Chemistry Development Inc. (ACD/Labs) (Toronto, Canada) to provide the VP value at 25° C. expressed in units of torr. The ACD/Labs' Vapor Pressure model is part of the ACD/Labs model suite.

Test Method for Determining the Logarithm of the Octanol/Water Partition Coefficient (log P)

The value of the log of the Octanol/Water Partition Coefficient (log P) is computed for each PRM in the perfume mixture being tested. The log P of an individual PRM is calculated using the Consensus log P Computational Model, version 14.02 (Linux) available from Advanced Chemistry Development Inc. (ACD/Labs) (Toronto, Canada) to provide the unitless log P value. The ACD/Labs' Consensus log P Computational Model is part of the ACD/Labs model suite.

Test Method for the Generation of Molecular Descriptors

In order to conduct the calculations involved in the computed-value test methods described herein, the starting information required includes the identity, weight percent, and molar percent of each PRM in the perfume being tested, as a proportion of that perfume, wherein all PRMs in the perfume composition are included in the calculations. Additionally for each of those PRMs, the molecular structure, and the values of various computationally-derived molecular descriptors are also required, as determined in accordance with the Test Method for the Generation of Molecular Descriptors described herein.
For each PRM in a perfume mixture or composition, its molecular structure is used to compute various molecular descriptors. The molecular structure is determined by the graphic molecular structure representations provided by the Chemical Abstract Service (“CAS”), a division of the American Chemical Society, Columbus, Ohio, U.S.A. These molecular structures may be obtained from the CAS Chemical Registry System database by looking up the index name or CAS number of each PRM. For PRMs, which at the time of their testing are not yet listed in the CAS Chemical Registry System database, other databases or information sources may be used to determine their structures. For a PRM which has potentially more than one isomer present, the molecular descriptor computations are conducted using the molecular structure of only one of the isomers, which is selected to represent that PRM. The selection of isomer is determined by the relative amount of extension in the molecular structures of the isomers. Of all the isomers of a given PRM, it is the isomer whose molecular structure that is the most prevalent which is the one that is selected to represent that PRM. The structures for other potential isomers of that PRM are excluded from the computations. The molecular structure of the isomer that is the most prevalent is paired with the concentration of that PRM, where the concentration reflects the presence of all the isomers of that PRM that are present.
A molecule editor or molecular sketching software program, such as ChemDraw (CambridgeSoft/PerkinElmer Inc., Waltham, Mass., U.S.A.), is used to duplicate the 2-dimensional molecular structure representing each PRM. Molecular structures should be represented as neutral species (quaternary nitrogen atoms are allowed) with no disconnected fragments (e.g., single structures with no counter ions). The winMolconn program described below can convert any deprotonated functional groups to the neutral form by adding the appropriate number of hydrogen atoms and will discard the counter ion.
For each PRM, the molecular sketching software is used to generate a file which describes the molecular structure of the PRM. The file(s) describing the molecular structures of the PRMs is subsequently submitted to the computer software program winMolconn, version 1.0.1.3 (Hall Associates Consulting, Quincy, Mass., U.S.A., www.molconn.com), in order to derive various molecular descriptors for each PRM. As such, it is the winMolconn software program which dictates the structure notations and file formats that are acceptable options. These options include either a MACCS SDF formatted file (i.e., a Structure-Data File); or a Simplified Molecular Input Line Entry Specification (i.e., a SMILES string structure line notation) which is commonly used within a simple text file, often with a “.smi” or “.txt” file name extension. The SDF file represents each molecular structure in the format of a multi-line record, while the syntax for a SMILES structure is a single line of text with no white space. A structure name or identifier can be added to the SMILES string by including it on the same line following the SMILES string and separated by a space, e.g.: C1=CC═CC═C1 benzene.
The winMolconn software program is used to generate numerous molecular descriptors for each PRM, which are then output in a table format. Specific molecular descriptors derived by winMolconn are subsequently used as inputs (i.e., as variable terms in mathematical equations) for a variety of computer model test methods in order to calculate values such as: saturation Vapour Pressure (VP); Boiling Point (BP); logarithm of the Octanol/Water Partition Coefficient (log P); Odour Detection Threshold (ODT); Malodour Reduction Value (MORV); and/or Universal Malodour Reduction Value (Universal MORV) for each PRM. The molecular descriptor labels used in the models' test method computations are the same labels reported by the winMolconn program, and their descriptions and definitions can be found listed in the winMolconn documentation. The following is a generic description of how to execute the winMolconn software program and generate the required molecular structure descriptors for each PRM in a composition.
Computing Molecular Structure Descriptors using winMolconn:

- 1) Assemble the molecular structure for one or more perfume ingredients in the form of a MACCS Structure-Data File, also called an SDF file, or as a SMILES file.
- 2) Using version 1.0.1.3 of the winMolconn program, running on an appropriate computer, compute the full complement of molecular descriptors that are available from the program, using the SDF or SMILES file described above as input.
  - a. The output of winMolconn is in the form of an ASCII text file, typically space delimited, containing the structure identifiers in the first column and respective molecular descriptors in the remaining columns for each structure in the input file.
- 3) Parse the text file into columns using a spreadsheet software program or some other appropriate technique. The molecular descriptor labels are found on the first row of the resulting table.
- 4) Find and extract the descriptor columns, identified by the molecular descriptor label, corresponding to the inputs required for each model.
  - a. Note that the winMolconn molecular descriptor labels are case-sensitive.

MORV and Universal MORV Calculation

1.) Input Molecular Descriptor values as determined via the method above into the following four equations:

MORV=−8.5096+2.8597×(dxp9)+1.1253×(knotpv)−0.34484×(e1C2O2)−0.00046231×(idw)+3.3509×(idcbar)+0.11158×(n2pag22) a)
MORV=−5.2917+2.1741×(dxvp5)−2.6595×(dxvp8)+0.45297×(c1C2C2d)−0.6202×(c1C2O2)+1.3542×(CdCH2)+0.68105×(CaasC)+1.7129×(idcbar) b)
MORV=−0.0035+0.8028×(SHCsatu)+2.1673×(xvp7)−1.3507×(c1C1C3d)+0.61496×(c1C1O2)+0.00403×(idc)−0.23286×(nd2). c)
MORV=−0.9926−0.03882×(SdO)+0.1869×(Ssp3OH)+2.1847×(xp7)+0.34344×(e1C302)−0.45767×(c1C2C3)+0.7684×(CKetone) d)

Equation a) relates a material's effectiveness in reducing the malodor trans-3-methyl-2-hexenoic acid (carboxylic acid based malodors)
Equation b) relates a material's effectiveness in reducing the malodor trimethylamine (amine based malodors)
Equation c) relates a material's effectiveness in reducing the malodor 3-mercapto-3-methylhexan-1-ol (thiol based malodors)
Equation d) relates a material's effectiveness in reducing the malodor skatole (indole based malodors)
2.) For purpose of the present application, a material's MORV is the highest MORV value from equations 1.)a) through 1.)d).
3.) If all MORVvalues from equations 1.)a) through 1.)d) above are greater than 0.5, the subject material has a Universal MORV.

Method for Assigning Fragrance Fidelity Index (FFI) and the Blocker Index (BI) for a Malodor Reduction Compound

Blocker materials suitable for use in consumer products of the present invention are chosen for their ability to decrease malodor, while not interfering with perception of a fragrance. Material selection is done by assigning two indices to a test sample material from two reference scales in order to rank odor strengths. The two reference scales are the Fragrance Fidelity Index (FFI) scale and the Blocker Index (BI) scale. The FFI ranks the ability of the test sample material to impart a perceivable odor which could cause interference when combined with another fragrance and the BI ranks the ability of the test sample material to reduce malodor perception. The two methods for assigning the indices to a test sample on the FFI and the BI reference scales are given below.
Method for Assigning the FFI to Test samples
The first step in the method for assigning an FFI on the FFI reference scale is to create the FFI reference swatches. The swatches for the scale are created by treating clean fabrics swatches with a known amount of a known concentration of an ethyl vanillin solution. Fabric swatches for this test are white knit polycotton (4 inch×4 inch) swatches from EMC ordered as PC 50/50. The supplier is instructed to strip the swatches first, stripping involves washing twice with a fragrance-free detergent and rinsing three times.

Making the FFI Reference Swatches

Make three solutions of ethyl vanillin using a 50%/50% EtOH/water as the diluent at the following concentrations: 25 ppm, 120 ppm and 1000 ppm. Pipette 13 μL of each of the three solutions into the middle of a clean swatch resulting in about a 1 cm diameter of the solution in the middle of the swatch. This will create a sensory scale of three swatches with three different odor levels based on the concentration of the solution pipetted onto the swatch. After drying for 30 minutes in a vented hood, the swatches are wrapped in aluminum foil to prevent odor contamination to the treated swatch. A clean untreated swatch is also included as the lowest anchor point of reference for odor strength on the FFI scale. The FFI reference scale swatches should be used within 0.5 to 12 hours and discarded after 12 hours. The swatches are used as scale anchor points when graders evaluate a test sample(s) and are assigned a Fragrance Fidelity Index (FFI) as show in Table 7.
At least four perfumers/expert graders are used to rank the ethyl vanillin swatches in the FFI scale. The perfumer/expert grader needs to demonstrate adequate discrimination on the scale. The perfumer/expert panel is asked to rank order swatches according to a scale between 0 and 3. The panel must demonstrate statistical differences between the swatches as seen in Table 7.

TABLE 7

Results FFI of reference swatches
from six perfumers/expert graders.

Expert Grader

Std

FFI	Swatch	1	2	3	4	5	6	Ave	Dev.

0	Control: stripped	0	0	0.5	0	0	0	0.08	0.2
	swatch NIL
	ethyl vanillin
1	Stripped swatch with	0.5	0.5	0.5	1.5	0.5	1.0	0.75	0.4
	13 μL 25 ppm
	ethyl vanillin
2	Stripped swatch with	2.0	1.5	1.5	2.0	2.0	2.0	1.8	0.2
	13 μL 120 ppm
	ethyl vanillin
3	Stripped swatch with	3.0	2.0	3.0	3.0	3.0	3.0	2.8	0.4
	13 μL 1000 ppm
	ethyl vanillin

The expert graders must demonstrate a full range of 2.5 over the 4 swatches to be acceptably discriminating. Grader 2 in table 1 has a range of only 2 and is eliminated from the panel. The panel of expert graders must also demonstrated the ability to statistically discriminate between swatches in the scale.

TABLE 8

This table demonstrates acceptable expert graders
with an acceptable range and the panel meets the
requirement for discriminating statistics.

Expert Grader

Std

FFI	Swatch	1	3	4	5	6	Ave	Dev.

0	Control: stripped	0	0.5	0	0	0	0.08	0.2
	swatch NIL
	ethyl vanillin
1	Stripped swatch with	0.5	0.5	1.5	0.5	1.0	0.80	0.4
	13 μL 25 ppm
	ethyl vanillin
2	Stripped swatch with	2.0	1.5	2.0	2.0	2.0	1.9	0.2
	13 μL 120 ppm
	ethyl vanillin
3	Stripped swatch with	3.0	3.0	3.0	3.0	3.0	3.0	0.0
	13 μL 1000 ppm
	ethyl vanillin

The reference swatches represent the 0, 1, 2, and 3 FFIs on the FFI reference scale, Table 9. The expert grader should familiarize them self with the strength of the odor on the FFI reference swatches by sniffing each one starting at 0 (the lowest odor strength) and ending at 3 (the highest odor strength). This should be done prior to evaluating the test sample material treated swatch.

TABLE 9

Swatch treatments comprising the Fragrance Fidelity
Index (FFI) reference scale

Swatch treatment	Conc. of ethyl vanillin	FFI

Clean fabric swatch w/ 13 μL ethyl	1000 ppm ethyl vanillin	3
vanillin
Clean fabric swatch w/ 13 μL ethyl	120 ppm ethyl vanillin	2
vanillin
Clean fabric swatch w/ 13 μL ethyl	25 ppm ethyl vanillin	1
vanillin
Clean fabric swatch NIL ethyl vanillin	NIL ethyl vanillin	0

Making Swatches Treated with the Test Material

A clean swatch is treated with 13 μL of a known concentration of a test sample material resulting in an about 1 cm of the solution on the clean swatch. Just like the reference swatches, the test sample material swatch is dried in a vented hood for 30 minutes and then wrapped in aluminum foil to prevent contamination. The test material swatches and the FFI reference swatches should be made within 2 hrs. of each other. The test material swatch must be used within 0.5 to 12 hours and discarded after 12 hours.

Assigning the FFI to the Test Material

At least two perfumers/expert graders are used to assign an FFI grade to a test sample. The perfumer/expert grader smells the test sample swatch by holding that swatch 1 inch from their nose with their nose centered over the area where the test sample was pipetted on to the fabric and then assigns the test sample an FFI grade using the FFI reference scale anchor swatches as references. The test sample swatch is assigned an FFI grade at or between numbers on the FFI scale shown in Table 9. In cases where the test sample material is graded greater than 3, the test material is not a blocker material or the concentration of the material needs to be lowered and reevaluated to determine if a lower level has a malodor blocker functionality.

Method for Assigning the BI to Test Sample

The first step in the method for assigning a BI to a test sample material on the BI reference scale is to create the BI reference swatches. The swatches for the scale are created by treating clean fabrics swatches with a known amount of a known volume of isovaleric acid solution at a known concentration. Fabric swatches for this test are white knit polycotton (4 inch×4 inch) swatches from EMC ordered as PC 50/50. The supplier is instructed to strip the swatches first, stripping involves washing twice with a fragrance-free detergent and rinsing three times.

Making the BI Reference Swatches

Make one solution of 0.08% isovaleric acid using 50%/50% EtOH/water as the diluent. The BI scale contains one clean swatch with no malodor applied. Three other swatches each have a different volume of the 0.08% isovaleric acid applied. Pipette 2 μL of the 0.08% isovaleric acid solution to one clean swatch, 5 μL of the 0.08% isovaleric acid solution to the next swatch and 20 μL of isovaleric acid to the final clean swatch. These solutions are pipetted to the middle of the swatches. This will create a sensory scale of three swatches with three different odor levels based on the volume of the 0.08% isovaleric acid solution pipetted onto the swatch. After drying for 30 minutes in a vented hood, the swatches are wrapped in aluminum foil to prevent odor contamination to the treated swatch. A clean untreated swatch is also included as the lowest anchor point of reference for malodor strength on the BI scale. The BI reference scale swatches should be used within 0.5 to 12 hours and discarded after 12 hours. The swatches are used as scale anchor points when graders evaluate a test sample(s) and are assigned a Blocker Index (BI) as show in Table 12.
At least four perfumers/expert graders are used to rank the isovaleric acid swatches in the BI scale. The perfumer/expert grader needs to demonstrate adequate discrimination on the scale. The perfumer/expert grader is asked to rank order swatches according to a scale between 0 and 3. The panel of graders must demonstrate statistical differences between the swatches as seen in Table 10.

TABLE 10

Results from six perfumers/expert graders to create the BI scale.

Expert Grader

Std

BI	Swatch	1	2	3	4	5	Ave	Dev.

0	Control: stripped swatch	0	0	0	0	0	0	0
	NIL isovaleric acid
1	Stripped swatch with 2 μL	0.5	2.0	1.0	1.0	0.5	1.0	0.5
	0.08% isovaleric acid
2	Stripped swatch with 5 μL	2.0	2.5	2.0	2.0	2.0	2.1	0.2
	0.08% isovaleric acid
3	Stripped swatch with 20 μL	3.0	3.0	3.0	3.0	2.5	2.8	0.2
	0.08% isovaleric acid

The expert graders must demonstrate a full range of 2.5 over the 4 swatches to be acceptably discriminating. The panel of expert graders must also demonstrated the ability to statistically discriminate between swatches in the scale. Expert grader #2 did not demonstrate the ability to discriminate between the swatches and is eliminated from the panel, see Table 11.

TABLE 11

This table demonstrates acceptable expert graders
with an acceptable range and the panel meets the
requirement for discriminating statistics.

Expert Grader

Std

BI	Swatch	1	3	4	5	Ave	Dev.

0	Control: stripped swatch	0	0	0	0	0	0
	NIL isovaleric acid
1	Stripped swatch with 2 μL	0.5	1.0	1.0	0.5	0.8	0.3
	0.08% isovaleric acid
2	Stripped swatch with 5 μL	2.0	2.0	2.0	2.0	2.0	0
	0.08% isovaleric acid
3	Stripped swatch with 20 μL	3.0	3.0	3.0	2.5	2.9	0.2
	0.08% isovaleric acid

The reference swatches represent the 0, 1, 2, and 3 BIs on the BI reference scale, Table 12. The expert grader should familiarizes him/herself with the strength of the odor on the BI reference swatches by sniffing each one starting at 0 (the lowest odor strength) and ending at 3 (the highest odor strength). This should be done prior to evaluating the swatch treated with the test material.

TABLE 12

Swatch treatments comprising the Blocker Index (BI) reference scale.

Swatch/treatment	Wt. of isovaleric acid	BI

Clean fabric swatch w/ 20 μL 0.08%	16 mg isovaleric acid	3
isovaleric acid
Clean fabric swatch w/ 5 μL 0.08%	4 mg isovaleric acid	2
isovaleric acid
Clean fabric swatch w/ 2 μL 0.08%	1.6 mg isovaleric acid	1
isovaleric acid
Clean fabric swatch NIL isovaleric acid	NIL isovaleric acid	0

Making the Malodorous Swatch and Treating it with a Test Material

To evaluate the BI, the test material is applied to a malodorous swatch to determine how well the test material blocks the malodor. The malodorous swatch is made by treating a clean swatch with 20 μL of a 0.08% solution of isovaleric acid. Dry the malodorous swatch treated with isovaleric acid in a vented hood for 30 minutes. After drying the malodorous swatch a known concentration of test material solution, between 1 ppm and 100 ppm is pipetted onto the malodorous swatch. Apply the test material solution right on top of the spot where the isovaleric acid solution was applied making an about 1 cm diameter spot. Just like the BI reference swatches, the isovaleric acid+test material swatch is dried in a vented hood for 30 minutes and then wrapped in aluminum foil to prevent contamination. The isovaleric acid+test material swatches and the BI reference swatches should be made within 2 hrs. of each other. The isovaleric acid+test material swatch must be used between 1-12 hours just like the reference swatches. It is sometimes necessary to evaluate several levels of the test material between about 1 and about 100 ppm to determine the BI.

Assigning the BI to the Test Material

At least two perfumers/expert graders are used to assign the BI to the test sample. The expert grader smells the isovaleric acid+test material swatch by holding that swatch one inch from their nose with their nose centered over the area where the Test sample was pipetted on to the fabric and then assigns the isovaleric acid+test material swatch a BI based on ranking its odor strength against the odor strength of the swatches in the BI reference scale. The test sample swatch is assigned a BI at or between numbers on the BI in table. In cases where the isovaleric acid+test material swatch odor is greater than 3 on the BI reference scale, this indicates the material is not a blocker or the concentration of the test material needs to be lowered to achieve its blocker functionality.
Malodor Reduction Compounds with FFI and BI Grades Based on the Aforementioned


Table
Ref #	CAS#	log P	Name	Conc	FFI	BI

281	54830-99-8	3.11	3a,4,5,6,7,7a-hexahydro-4,7-	10 ppm	0	2.0
			methano-1H-indenyl acetate	50 ppm	0.5	2.0
677	139504-68-0	3.75	1-((2-(tert-	10 ppm	0	2.3
			butyl)cyclohexyl)oxy)butan-2-ol	50 ppm	1.8	2.0
962	55066-48-3	3.17	3-methyl-5-phenylpentan-1-ol	10 ppm	0	2.3
				50 ppm	0.5	1.7
261	173445-65-3	3.29	3-(3,3-dimethyl-2,3-dihydro-1H-	10 ppm	0	1.8
			inden-5-yl)propanal	50 ppm	1.3	1.3
1139	87731-18-8	2.11	(Z)-cyclooct-4-en-1-yl methyl	10 ppm	0	2.0
			carbonate	50 ppm	1.0	2.7
	4430-31-3	1.43	3,4,4a,5,6,7,8,8a-octahydrochromen-	10 ppm	0	2.0
			2-one	50 ppm	0	2.0
204	40379-24-6	3.89	7-methyloctyl acetate	10 ppm	0	2.0
				50 ppm	0	2.7
1005	93981-50-1	5.59	ethyl (2,3,6-trimethylcyclohexyl)	50 ppm	0.5	2.6
			carbonate
391	106-33-2	5.73	Ethyl laurate	50 ppm	0.3	2.2
1148	1139-30-6	4.06	Caryophyllene Oxide	50 ppm	0.5	2.3
524	13877-91-3	4.31	3,7-Dimethyl-1,3,6-Octatriene(cis-β	50 ppm	0	2.8
	3338-55-4		ocimene 70%)
1149	23787-90-8	4	1,3,4,6,7,8alpha-hexahydro-	10 ppm	0	1.5
			1,1,5,5-tetramethyl-2H-2,4alpha-	50 ppm	0.8	2.3
			methanophtalen-8(5H)-one
	112-42-5	4.62	Undecanol	50 ppm	0.8	2.3
174	112-53-8	5.17	1-dodecanol	50 ppm	0.5	2.3
	98-52-2	2.78	4-tert-butyl cyclohexane	10 ppm	0	2.0
				50 ppm	0.3	2.0
109	112-39-0	6.41	Methyl palmitate	10 ppm		2.0

Malodor Control Compounds with Improved Performance at Lower Levels.
Below are some non-limiting examples of preferred behavior by which the malodor control compound gives improved malodor control at lower concentration. These nonlimiting data provide additional compelling data that malodor is being blocked, not masked.


Table
Ref #	CAS#	Name	Conc	FFI	BI

N/A	68912-13-0	8,8-dimethyl-3a,4,5,6,7,7a-	10 ppm	0	1.5
		hexahydro-1H-4,7-	50 ppm	0	2.2
		methanoinden-6-yl propionate
N/A	TBD	4,8-dimethyl-1-(methylethyl)-	10 ppm		2.0
		7-oxybiciclo [4.3.0]nonane	50 ppm	0.3	2.2

about 0.001 Fragrance Fidelity

868686868686868686868686868686868686868686868686868686868686868686868686868686 868686868686868686868686868686868686868686868686868686868686868686868686868686 868686868686868686868686868686868686

Retesting Malodor Reduction Compounds at Lower Levels.

The example below demonstrates that while a malodor control compound could fail to demonstrate odor blocking (BI>2.5) at a higher concentration it should be retested at a lower concentration to determine if it passes.


Table
Ref #	CAS #	Name	Conc	FFI	BI

N/A	173445-65-3	1H-Indene-5-propanal, 2,3-	10 ppm	0	1.5
		dihydro-3,3-dimethyl-	50 ppm	0.5	2.7

EXAMPLE 1

Compositions Comprising Malodor Reduction Compounds

In the present invention blends enable more potent malodor reduction because blends are useful at a higher % of the product composition before becoming olfactively noticeable. Below are non-limiting examples of malodor reduction compounds.


	% wt. Active

Component	CAS#	A	B	C	D	E

2,2,8,8-tetramethyl-octahydro-1H-	29461-14-1	35-45	15-25	5-20	10-30	15-25
2,4a-methanonapthalene-10-one
1H-Indene-ar-propanal, 2,3-	300371-33-9	10-20	1-30	NIL	5-10	1-5
dihydro-1,1-dimethyl-
Hexadecanoic acid, (2E)-3,7-	3681-73-0	35-45	10-25	NIL	30-40	35-50
dimethyl-2,6-octadien-1-yl ester
1-Pentanol-3-methyl-5-phenyl	55066-48-3	10-20	10-25	2-10	5-17	10
4,7-Methano-1H-inden-5-ol,	171102-41-3	0-5	10-25	NIL	1-6	1-5
3a,4,5,6,7,7a-hexahydro-, 5-acetate
4,8-dimethyl-1-(methylethyl)-7-	N/A	0-5	NIL	NIL	NIL	1-5
oxybiciclo [4.3.0]nonane
(3Z)-3,7-dimethylocta-1,3,6-triene	3338-55-4	NIL	NIL	10-20	2-5	NIL
1H-Indene-5-propanal, 2,3-	173445-65-3	NIL	NIL	NIL	7.5-16	1-15
dihydro-3,3-dimethyl-
3,4,4a,5,6,7,8,8a-	4430-31-3	NIL	NIL	NIL	3-7	1-15
octahydrochromen-2-one
1-(2-tert-	139504-68-0	NIL	NIL	NIL	0.25-1.5	NIL
butylcyclohexyl)oxybutan-2-ol
ethyl (2,3,6-trimethylcyclohexyl)	93981-50-1	NIL	NIL	15-30	NIL	2
carbonate
benzyl 2-hydroxypropanoate	2051-96-9	NIL	NIL	2-5	NIL	NIL
(3,5-dimethylcyclohex-3-en-1-	67634-16-6	NIL	NIL	5-30	NIL	NIL
yl)methanol
2-Dodecanol	10203-28-8	NIL	0.25-1	NIL	0.5-3	NIL

EXAMPLE 2

Compositions Comprising Malodor Reduction Compounds


	% wt. Active

Ingredient	CAS #	A	B	C	B	D	E

(E)-1-(2,6,6-trimethyl-1-	127-42-4	4	8	2	8	3	2
cyclohex-2-enyl)pent-1-en-3-
one
ethyl dodecanoate	106-33-2	NIL	1	NIL	3	NIL	NIL
3a,4,5,6,7,7a-hexahydro-1H-	68912-13-0	8	30	1	4	1	3.5
4,7-methanoinden-1-yl
propanoate
[1R-(1R,4R,6R,10S)]-	1139-30-6	NIL	0.3	2	0.5	NIL	0.5
4,12,12-trimethyl-9-
methylene-5-
oxatricyclo[8.2.0.04,6]dodecane
(8E)-cyclohexadec-8-en-1-one	3100-36-5	NIL	5	NIL	7	NIL	NIL
3,5,5-trimethylhexyl acetate	58430-94-7	25	15	50	35	60	56
ethyl (2,3,6-	93981-50-1	NIL	1	NIL	5	NIL	NIL
trimethylcyclohexyl)
carbonate
2,4-dimethyl-4,4a,5,9b-	27606-09-3	25	10	15	15	16	15
tetrahydroindeno[1,2-
d][1,3]dioxine
2,2,7,7-	23787-90-8	8	9	5	7	5	5
tetramethyltricyclo[6.2.1.01,6]
undecan-5-one
(3,5-dimethylcyclohex-3-en-	67634-16-6	NIL	0.7	NIL	0.5	NIL	NIL
1-yl)methanol
3-(7,7-dimethyl-4-	33885-52-8	30	20	25	15	15	18
bicyclo[3.1.1]hept-3-enyl)-
2,2-dimethylpropanal
Total		100	100	100	100	100	100

EXAMPLE 3

Malodor Reduction Composition


	% wt. Active

Ingredient	CAS #	A	B	C

5-Cyclohexadecen-1-One	37609-25-9	15.0	2.00	2.00
decahydro-2,2,7,7,8,9,9-	476332-65-7	0.005	0.01	0.01
heptamethylindeno(4,3a-b)furan
2,3-Dihydro-5,6-dimethoxy-2-(4-	33704-61-9	0.3	0.5	0.5
piperidinylmethylene)-1H-inden-1-one
Cedryl Methyl Ether	19870-74-7	6.0	10.0	4.0
Trans-4-Decenal	65405-70-1	0.005	0.002	0.002
Decyl Aldehyde	112-31-2	3.74	2.0	2.0
3-methyl cyclopentadecenone	63314-79-4	0.4	1.0	1.0
Diphenyl Oxide	101-84-8	0.5	1.0	1.0
3a,4,5,6,7,7a-hexahydro-4,7-methano-	54830-99-8	5.0	8.0	8.0
1H-indenyl acetate
3a,4,5,6,7,7a-hexahydro-1H-4,7-	68912-13-0	6.0	8.0	8.0
methanoinden-1-yl propanoate
2-(5-methyl-2-propan-2-yl-8-	68901-32-6	10.0	15.0	15.0
bicyclo[2.2.2]oct-5-enyl)-1,3-dioxolane
(E)-3,7-dimethyl-2,6-	3681-73-0	10.0	10.0	16.0
octadienylhexadecanoate
Iso Nonyl Acetate	58430-94-7	6.65	8.0	3.0
2,2,7,7-	23787-90-8	10.0	8.0	8.0
tetramethyltricyclo[6.2.1.01,6]undecan-5-one
(1-Methyl-2-(1,2,2-	198404-98-7	0.1	0.3	0.3
trimethylbicyclo[3.1.0]-hex-3-
ylmethyl)cyclopropyl)methanol
Lauric Aldehyde	112-54-9	0.625	1.0	0.7
Methyl Iso Eugenol	93-16-3	18.000	10.0	13.0
Methyl hexadecanoate	112-39-00	3.000	10.0	12.0
2,3-dihydro-1,1-1H-dimethyl-indene-ar-	300371-33-9	0.400	0.0	0.3
propanal
4-tert-butylcyclohexanol	98-52-2	0.400	0.1	0.1
2-isobutyl-4-hydroxy-4-	63500-71-0	1.600	2.0	2.0
methyltetrahydropyran
Undecyl Aldehyde	112-44-7	1.725	2.888	1.888
Undecylenic Aldehyde	112-45-8	0.550	0.2	1.2
Total		100	100.0	100.0

EXAMPLE 4.1-4.5

Deodorant Example with Malodor Reducing Composition

An example of Deodorant compositions prepared with malodor reduction composition, according to the compositions shown in Example 1 to 3.


Ingredient	4.1	4.2	4.3	4.4	4.5

Product Form	Solid	Solid	Solid	Solid	Aerosol
	Deodorant	Deodor-	Deodor-	Deodor-	Deodorant
	Control	ant	ant	ant	or Body
					Spray
dipropylene glycol	48	48	20	30	20
propylene glycol	19.3	19.3	22	—	—
tripopylene glycol	—	—	25	—	—
Glycerine	—	—	—	10	—
PEG-8	—	—	—	20	—
Propylene Glycol 3	1.4	1.4	—	—	—
Myristyl Ether
ethanol	—	—	—	—	QS
Water	QS	QS	QS	QS	—
sodium stearate	5.4	5.4	5.5	5.5	—
tetra sodium EDTA	0.5	0.5	0.05	0.05	—
sodium hydroxide	—	—	0.04	0.04	—
triclosan	—	—	0.3	0.3	—
Neat Perfume	2.8	2.8	2	1.5	1.5
Malodor reducing	—	0.7	1.0	0.5	0.35
composition
Blue 1	0.0009	0.0009	—	—	—
Propellant (1,1	—	—	—	—	40
difluoroethane)

QS - Indicates that this material is used to bring the total to 100%.

EXAMPLES 5.1-5.6

Antiperspirant Examples with Malodor Reducing Composition

An example of Antiperspirant compositions prepared with malodor reduction composition, according to the compositions shown in Example 1-3.


5.1	5.2	5.3	5.4	5.5	5.6
Invisible	Invisible	Invisible	Soft	Soft	Soft
Solid	Solid	Solid	Solid	Solid	Solid

Aluminum	24	24	24	26.5	26.5	26.5
Zirconium
Trichlorohydrex
Glycine Powder
Cyclopentasiloxane	Q.S	Q.S.	Q.S.	Q.S.	Q.S.	Q.S.
Dimethicone	—	—	—	5	5	5
CO-1897 Stearyl	14	14	14	—	—	—
Alcohol NF
Hydrogenated	3.85	3.85	3.85	—	—	—
Castor Oil MP80
Deodorized
Behenyl Alcohol	0.2	0.2	0.2	—	—	—
Tribehenin	—	—	—	4.5	4.5	4.5
C 18-36 acid	—	—	—	1.125	1.125	1.125
triglyceride
C12-15 Alkyl	9.5	9.5	5	—	—	—
Benzoate
PPG-14 Butyl	6.5	6.5	—	0.5	0.5	0.5
Ether
Phenyl	3	—	3	—	—	—
Trimethicone
White Petrolatum	3	—	—	3	3	3
Mineral Oil	1.0	1.0	1.0	—	—	—
Free (Neat)	1.0	0.75	2.0	0.75	1.0	1.25
Perfume
Malodor reducing	0.25	—	0.35	0.175	0.25	0.1
composition
Beta-Cyclodextrin	—	3.0	—	—	—	3.0
complexed with
Malodor reducing
composition
Talc Imperial 250	3.0	3.0	3.0	—	—	—
USP
Polyacrylate	—	—	1.9	—	—	—
Microcapsule
loaded with
Malodor reducing
composition

QS - indicates that this material is used to bring the total to 100%.

EXAMPLE 6.1-6.5

Clear Gel Antiperspirant Examples with Malodor Reducing Composition


6.1	6.2	6.3	6.4	6.5
Clear Gel	Clear Gel	Clear Gel	Clear Gel	Clear Gel
Antiperspirant	Antiperspirant	Antiperspirant	Antiperspirant	Antiperspirant

Aluminum	20	18.5	20	18	10
Zirconium
Octachlorohydrex
Gly
Water	Q.S	Q.S.	Q.S.	Q.S.	Q.S.
Ethanol	5.5	8	6	6.5	5
Propylene Glycol	5.3	5	7	5.5	8
DC 5225c -	7.8	9	6.5	7	8
Cyclopentasiloxane
& PEG/PPG-
18/18
Dimethicone
Dimethicone	5.6	4.5	5.8	5	4.1
Cyclopentasiloxane	2.6	3	1	3	2.5
Free (Neat)	1.0	0.75	2.0	0.75	1.0
Perfume
Malodor reducing	0.25	—	0.35	0.175	0.25
composition

QS - indicates that this material is used to bring the total to 100%.

The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm.”
Every document cited herein, including any cross referenced or related patent or application, is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests, or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.
While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is, therefore, intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.

Claims

What is claimed:

1. An antiperspirant and/or deodorant composition comprising, based on total composition weight,

a) a sum total of from about 0.0001% to about 2%, preferably from about 0.0001% to about 0.75%, more preferably from about 0.001% to about 0.5%, most preferably from about 0.007% to about 0.25% of 1 or more malodor reduction materials, preferably 1 to about 75 malodor reduction materials, more preferably 1 to about 50 malodor reduction materials, more preferably 1 to about 35 malodor reduction materials, most preferably 1 to about 20 malodor reduction materials, each of said malodor reduction materials having a MORV of at least 0.5, preferably from 0.5 to 10, more preferably from 1 to 10, most preferably from 1 to 5, and preferably each of said malodor reduction materials having a Universal MORV, or said sum total of malodor reduction materials having a Blocker Index of less than 3, more preferable less than about 2.5 even more preferably less than about 2 and still more preferably less than about 1 and most preferably 0 and/or a Blocker Index average of 3 to about 0.001; and

b) from about 0% to about 12%, preferably from about 0% to about 8%, more preferably from about 0.1% to about 4%, of one or more perfume raw materials having a MORV of less than 0.5, preferably less than 0, more preferably less than −2, most preferably less than −5;

c) from about 0.1% to about 99%, preferably from about 1% to about 80%, more preferably from about 5% to about 55%, most preferably from about 10% to about 50% of a solvent, preferably said solvent is selected from cyclopentasiloxane, ethanol, water, propylene glycol, dipropylene glycol, and mixtures thereof;

d) from about 0% to about 30%, preferably from about 0% to about 20%, more preferably from about 0.1% to about 4%, most preferably from about 0.1% to about 4% of a material selected from the group consisting of a structurant, a residue masker, an antimicrobial, and mixtures thereof.

2. An antiperspirant and/or deodorant composition according to claim 1, wherein said sum total of malodor reduction materials has a Blocker Index of less than 3, more preferable less than about 2.5 even more preferably less than about 2 and still more preferably less than about 1 and most preferably 0 and/or a Blocker Index average of 3 to about 0.001.

3. An antiperspirant and/or deodorant composition according to any preceding claim, wherein each of said malodor reduction materials has a MORV of at least 0.5, preferably from 0.5 to 10, more preferably from 1 to 10, most preferably from 1 to 5, and preferably each of said malodor reduction materials having a Universal MORV.

4. An antiperspirant and/or deodorant composition according to any preceding claim wherein, said sum total of malodor reduction materials has a Fragrance Fidelity Index average of 3 to about 0.001 Fragrance Fidelity Index, preferably each malodor reduction material in said sum total of malodor reduction materials has a Fragrance Fidelity Index of less than 3, preferably less than 2, more preferably less than 1 and most preferably each malodor reduction material in said sum total of malodor reduction materials has a Fragrance Fidelity Index of 0.

5. An antiperspirant and/or deodorant composition according to any preceding claim, wherein said malodor reduction materials are selected from the group consisting of 2-ethylhexyl(Z)-(3-(4-methoxyphenyl)acrylate; 2,4-dimethyl-2-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-1,3-dioxolane; 1,1-dimethoxynon-2-yne; 2-(p-tolyl)propan-2-ol; 3-methoxy-7,7-dimethyl-10-methylenebicyclo[4.3.1]decane; methoxycyclododecane; 1,1-dimethoxycyclododecane; (Z)-tridec-2-enenitrile; (2-hydroxy-4-methoxyphenyl)(phenyl)methanone; 2,4a,5,8a-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-yl formate; 4-methyl-1-oxaspiro[5.5]undecan-4-ol; 7-methyl-2H-benzo[b][1,4]dioxepin-3(4H)-one; 1,8-dioxacycloheptadecan-9-one; 4-(tert-pentyl)cyclohexan-1-one; 2-methoxy-1,1′-biphenyl; 3a,5,6,7,8,8b-hexahydro-2,2,6,6,7,8,8-heptamethyl-4H-indeno(4,5-d)-1,3-dioxole; 7-isopropyl-8,8-dimethyl-6,10-dioxaspiro[4.5]decane; octyl furan-2-carboxylate; octyl acetate; 2-heptyl-4-methyl-1,3-dioxolane; octanal; 1,1-dimethoxyoctane; 7-methyl-3-methyleneocta-1,6-diene; 2-methyl-6-methyleneoct-7-en-2-ol; 2-methyl-6-methyleneoct-7-en-2-yl acetate; tetradecanal; 4-methoxy-6-prop-2-enyl-1,3-benzodioxole; tetradecanenitrile; 2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a-octahydronaphthalen-1-ol; (E)-2,6-dimethylocta-5,7-dien-2-ol; (E)-2,7-dimethylocta-1,5,7-trien-3-ol; 2-((1S,5R)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethyl acetate; (4R,4aS,6R)-4,4a-dimethyl-6-(prop-1-en-2-yl)-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one; nonan-1-ol; nonanal; 12-methyl-14-tetradec-9-enolide; N-ethyl-2-isopropyl-5-methylcyclohexane-1-carboxamide; 1-(3-methylbenzofuran-2-yl)ethan-1-one; 2-methoxynaphthalene; (E)-3,7,11-trimethyldodeca-1,6,10-trien-3-ol; (Z)-3,7-dimethylocta-2,6-dien-1-ol; 1-ethyl-3-methoxytricyclo[2.2.1.02,6]heptane; methyl(E)-non-2-enoate; 10-isopropyl-2,7-dimethyl-1-oxaspiro[4.5]deca-3,6-diene; 2-(2-(4-methylcyclohex-3-en-1-yl)propyl)cyclopentan-1-one; 6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde; (E)-4-(2,2,3,6-tetramethylcyclohexyl)but-3-en-2-one; (4-(4-methylpent-3-en-1-yl)cyclohex-3-en-1-yl)methyl acetate; 2-(tert-butyl)-4,5,6-trimethyl-1,3-phenylene dinitrite; 1,7-dioxacycloheptadecan-8-one; 1-(4-(tert-butyl)-2,6-dimethyl-3,5-dinitrophenyl)ethan-1-one; 1-(tert-butyl)-2-methoxy-4-methyl-3,5-dinitrobenzene; 3-methylcyclopentadecan-1-one; (E)-3-methylcyclopentadec-4-en-1-one; 3-methyl-4-phenylbutan-2-ol; 1-(4-isopropylcyclohexyl)ethan-1-ol; (E)-dec-5-enoic acid; methyl non-2-ynoate; 2-methyldecanal; 6,6-dimethoxy-2,5,5-trimethylhex-2-ene; 4-phenylbutan-2-ol; methyl stearate; 1,1-dimethoxy-2-methylundecane; undecan-2-one; 2-methylundecanal; methyl tetradecanoate; methyl(9Z,12Z)-octadeca-9,12-dienoate; 1-hydroxydecan-3-one; (Z)-1,2-dimethoxy-4-(prop-1-en-1-yl)benzene; methyl palmitate; 4-allyl-1,2-dimethoxybenzene; methyl 2-((1R,2R)-3-oxo-2-((Z)-pent-2-en-1-yl)cyclopentyl)acetate; methyl 2-(3-oxo-2-pentylcyclopentyl)acetate; 1-methyl-2-phenoxybenzene; methyl cinnamate; 1-allyl-4-methoxybenzene; 1-(naphthalen-2-yl)ethan-1-one; methyl oct-2-ynoate; methyl 2,6,6-trimethylcyclohex-2-ene-1-carboxylate; 7-methoxy-3,7-dimethyloctanal; 7-isopropyl-10-methyl-1,5-dioxaspiro[5.5]undecan-3-ol; octahydro-1H-4,7-methanoindene-1-carbaldehyde; 3-(3-(tert-butyl)phenyl)-2-methylpropanal; (E)-4-(4,8-dimethylnona-3,7-dien-1-yl)pyridine; (E)-trideca-3,12-dienenitrile; 2,2-dimethyl-3-(m-tolyl)propan-1-ol; 2,4-dimethyl-4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine; 8-isopropyl-6-methylbicyclo[2.2.2]oct-5-ene-2-carbaldehyde; 4-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1-carbaldehyde; (S)-1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene; (Z)-3-hexen-1-yl-2-cyclopenten-1-one; 3,7-dimethylocta-1,6-dien-3-yl octanoate; 3,7-dimethylocta-1,6-dien-3-yl isobutyrate; 3,7-dimethylocta-1,6-dien-3-yl benzoate; 3,7-dimethylocta-1,6-dien-3-yl 2-aminobenzoate; 2-(5-methyl-5-vinyltetrahydrofuran-2-yl)propan-2-ol; 6-methyl-2-(oxiran-2-yl)hept-5-en-2-ol; (2Z,6E)-3,7-dimethylnona-2,6-dienenitrile; 3-(4-methylcyclohex-3-en-1-yl)butanal; (2,5-dimethyl-1,3-dihydroinden-2-yl)methanol; 3-(4-(tert-butyl)phenyl)-2-methylpropanal; (E)-1-(1-methoxypropoxy)hex-3-ene; (E)-1-(1-ethoxyethoxy)hex-3-ene; (1S,5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-ol; dodecan-1-ol; dodecyl acetate; dodecanoic acid; 5-hexyl-5-methyldihydrofuran-2(3H)-one; dodecanal; 3,6-dimethylhexahydrobenzofuran-2(3H)-one; 4-(1-ethoxyvinyl)-3,3,5,5-tetramethylcyclohexan-1-one; ((3S,3aR,6R,8aS)-7,7-dimethyl-8-methyleneoctahydro-1H-3a,6-methanoazulen-3-yl)methanol; 5-(sec-butyl)-2-(2,4-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane; (1-methyl-2-((1,2,2-trimethylbicyclo[3.1.0]hexan-3-yl)methyl)cyclopropyl)methanol; 2-propylheptanenitrile; (E)-6-(pent-3-en-1-yl)tetrahydro-2H-pyran-2-one; 2-hexylcyclopentan-1-one; 2-methyl-4-phenyl-1,3-dioxolane; 2,6,9,10-tetramethyl-1-oxaspiro(4.5)deca-3,6-diene; (1R,2S,5R)-5-methyl-2-(prop-1-en-2-yl)cyclohexan-1-ol; isopropyl palmitate; isopropyl tetradecanoate; isopropyl dodecanoate; 4,9-dimethoxy-7H-furo[3,2-g]chromen-7-one; (E)-cyclohexadec-8-en-1-one; (2S,5S)-2-isopropyl-5-methylcyclohexan-1-one; 2-hexylcyclopent-2-en-1-one; (2S,5S)-2-isopropyl-5-methylcyclohexan-1-one; 4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde; (Z)-1-(benzyloxy)-2-methoxy-4-(prop-1-en-1-yl)benzene; 1-((2S,3S)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yl)ethan-1-one; 2,5,6-trimethylcyclohex-3-ene-1-carbaldehyde; 6-(sec-butyl)quinoline; 2-(cyclohexyloxy)-1,7,7-trimethylbicyclo[2.2.1]heptane; (1R,2R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl propionate; (1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate; 4-((2R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)cyclohexan-1-ol; (1R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl acetate; 2-(4-isopropylcyclohexa-1,4-dien-1-yl)ethyl formate; isopentyl(E)-undec-6-enoate; isopentyl dodecanoate; (E)-oxacycloheptadec-10-en-2-one; (E)-non-2-enenitrile; (E)-8-(1H-indol-1-yl)-2,6-dimethyloct-7-en-2-ol; 8,8-di(1H-indol-1-yl)-2,6-dimethyloctan-2-ol; 4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine; 3,7-dimethyloctane-1,7-diol; 2-cyclododecylpropan-1-ol; 3-methyl-5-phenylpentanenitrile; 3-phenylpropan-1-ol; (1,1-dimethoxypropan-2-yl)benzene; 5-ethyl-4-hydroxy-2-methylfuran-3(2H)-one; 2,3-dihydro-3,3-dimethyl-1H-indene-5-propanal; 3-(3,3-dimethyl-2,3-dihydro-1H-inden-5-yl)propanal; hexyl octanoate; hexyl hexanoate; (Z)-2-benzylideneoctanal; hexyl benzoate; (Z)-hex-1-en-1-yl(Z)-2-methylbut-2-enoate; (E)-3,7-dimethylocta-2,6-dien-1-yl palmitate; oxacycloheptadecan-2-one; 2-butyl-4,4,6-trimethyl-1,3-dioxane; ethyl(1R,2R,3R,4R)-3-isopropylbicyclo[2.2.1]hept-5-ene-2-carboxylate; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl acetate; 2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-methylpropyl propionate; 5-(diethoxymethyl)benzo[d][1,3]dioxole; 3-(benzo[d][1,3]dioxol-5-yl)-2-methylpropanal; (E)-oxacyclohexadec-13-en-2-one; 6-butyl-2,4-dimethyl-3,6-dihydro-2H-pyran; 2-((3S,5R,8S)-3,8-dimethyl-1,2,3,4,5,6,7,8-octahydroazulen-5-yl)propan-2-ol; 1-(2,6,6-trimethylcyclohex-2-en-1-yl)pentan-3-one; ethyl 2-ethyl-6,6-dimethylcyclohex-2-ene-1-carboxylate; (1Z,5Z)-1,5-dimethyl-8-(propan-2-ylidene)cyclodeca-1,5-diene; (1E,6E)-8-isopropyl-1-methyl-5-methylenecyclodeca-1,6-diene; (E)-3,7-dimethylocta-2,6-dien-1-yl 2-phenylacetate; (E)-3,7-dimethylocta-2,6-dien-1-yl 2-phenylacetate; (6E,10E)-3,7,11,15-tetramethylhexadeca-1,6,10,14-tetraen-3-ol; (E)-2-(3,7-dimethylocta-2,6-dien-1-yl)cyclopentan-1-one; 5-heptyldihydrofuran-2(3H)-one; 1-methyl-4-(propan-2-ylidene)cyclohexyl acetate; 1-methyl-4-(propan-2-ylidene)cyclohexan-1-ol; 5-pentyldihydrofuran-2(3H)-one; (1R,4aR,8aS)-1-isopropyl-7-methyl-4-methylene-1,2,3,4,4a,5,6,8a-octahydronaphthalene; 5-[(Z)-hex-3-enyl]oxolan-2-one; (Z)-4-(2,2-dimethyl-6-methylenecyclohexyl)but-3-en-2-one; (4aS,9aR)-3,5,5,9-tetramethyl-2,4a,5,6,7,9a-hexahydro-1H-benzo[7]annulene; (1R,3aR,4R,7R)-1,4-dimethyl-7-(prop-1-en-2-yl)-1,2,3,3a,4,5,6,7-octahydroazulene; 2-((2R,4aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-yl)propan-2-ol; 5-octyldihydrofuran-2(3H)-one; (Z)-1-(2,2-dimethyl-6-methylenecyclohexyl)but-2-en-1-one; 5-hexyldihydrofuran-2(3H)-one; (1R,4aS,8aS)-1-isopropyl-7-methyl-4-methylene-1,2,3,4,4a,5,6,8a-octahydronaphthalene; 1-(3,3-dimethylcyclohexyl)pent-4-en-1-one; 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopenta[g]isochromene; furan-2-ylmethyl octanoate; furan-2-ylmethyl hexanoate; furan-2-ylmethyl heptanoate; 2-methyldecanenitrile; 8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl propionate; ethyl(3aR,4S,7R,7aR)-octahydro-3aH-4,7-methanoindene-3a-carboxylate; diethyl cyclohexane-1,4-dicarboxylate; (6-isopropyl-9-methyl-1,4-dioxaspiro[4.5]decan-2-yl)methanol; 2-isobutyl-4-methyltetrahydro-2H-pyran-4-ol; undec-10-enenitrile; (Z)-6-ethylideneoctahydro-2H-5,8-methanochromen-2-one; 3-(2-ethylphenyl)-2,2-dimethylpropanal; (E)-4,8-dimethyldeca-4,9-dienal; (E)-4-((3aR,4R,7R,7aR)-1,3a,4,6,7,7a-hexahydro-5H-4,7-methanoinden-5-ylidene)-3-methylbutan-2-ol; 8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl acetate; 3-(4-ethylphenyl)-2,2-dimethylpropanenitrile; 2-heptylcyclopentan-1-one; 1-ethoxyethoxy Cyclododecane; 3-cyclohexene-1-carboxylic acid, 2,6,6-trimethyl-, methyl ester; (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-yl acetate; (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol; oxacyclohexadecan-2-one; (E)-cyclopentadec-4-en-1-one; 1-cyclopentadec-4-en-1-one; 2-methoxy-4-(4-methylenetetrahydro-2H-pyran-2-yl)phenol; 4-allyl-2-methoxyphenyl acetate; 4-allyl-2-methoxyphenol; ethyl 3-methyl-3-phenyloxirane-2-carboxylate; 1,4-dioxacycloheptadecane-5,17-dione; ethyl undec-10-enoate; ethyl palmitate; ethyl nonanoate; ethyl tetradecanoate; (E)-3,7-dimethylnona-1,6-dien-3-ol; ethyl dodecanoate; nonan-3-one; ethyl decanoate; ethyl 6,6-dimethyl-2-methylenecyclohex-3-ene-1-carboxylate; ethyl 3-phenyloxirane-2-carboxylate; 6-ethyl-2,10,10-trimethyl-1-oxaspiro[4.5]deca-3,6-diene; 2-((1R,3S,4S)-4-methyl-3-(prop-1-en-2-yl)-4-vinylcyclohexyl)propan-2-ol; (2-(1-ethoxyethoxy)ethyl)benzene; (E)-3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol; (2R,3S,4R)-2,3,4,5-tetrahydroxypentanal; (E)-4-((3aS,7aS)-octahydro-5H-4,7-methanoinden-5-ylidene)butanal; 1,1-dimethoxydodecane; (R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene; 2-(2-hydroxypropoxy)propan-1-ol; 7,9-dimethylspiro[5.5]undecan-3-one; oxydibenzene; diphenylmethane; 2-methyl-1-phenylpropan-2-yl butyrate; 2,6-dimethyloct-7-en-4-one; octahydro-1H-4,7-methanoinden-5-yl acetate; 2-methyl-5-(prop-1-en-2-yl)cyclohexyl acetate; 2-methyl-5-(prop-1-en-2-yl)cyclohexan-1-ol; 3,7-dimethyloct-6-en-3-ol; methyl 2-hexyl-3-oxocyclopentane-1-carboxylate; dibutylsulfane; 1,2-diphenylethane; 6-hexyltetrahydro-2H-pyran-2-one; (3R,4R)-1-isopropyl-4-methyl-3-(prop-1-en-2-yl)-4-vinylcyclohex-1-ene; (3S,3aS,5R)-3,8-dimethyl-5-(prop-1-en-2-yl)-1,2,3,3a,4,5,6,7-octahydroazulene; 6-heptyltetrahydro-2H-pyran-2-one; 6-pentyltetrahydro-2H-pyran-2-one; (1S,8aR)-4,7-dimethyl-1-(propan-2-yl)-1,2,3,5,6,8a-hexahydronaphthalene; (Z)-1-((1R,2S)-2,6,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one; (1S,8aS)-1-isopropyl-4,7-dimethyl-1,2,3,5,6,8a-hexahydronaphthalene; 3,7,7-trimethylbicyclo[4.1.0]hept-3-ene; dec-9-en-1-ol; decyl propionate; 1,1-diethoxydecane; decahydronaphthalen-2-ol; 1-cyclohexylethyl(E)-but-2-enoate; 3-(4-isopropylphenyl)-2-methylpropanal; cyclotetradecane; cyclopentadecanone; cyclohexyl 2-hydroxybenzoate; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl butyrate; 1,4-dioxacyclohexadecane-5,16-dione; 8,8-dimethyl-1,2,3,4,5,6,7,8-octahydronaphthalene-2-carbaldehyde; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-5-yl isobutyrate; (5R,6R)-3,6-dimethyl-5-(prop-1-en-2-yl)-6-vinyl-4,5,6,7-tetrahydrobenzofuran; (4-isopropylphenyl)methanol; 1-(benzofuran-2-yl)ethan-1-one; 2-(3-phenylpropyl)pyridine; dodecanenitrile; (E)-cycloheptadec-9-en-1-one; 3-(4-methylcyclohex-3-en-1-yl)but-3-en-1-yl acetate; 3-(4-methylcyclohex-3-en-1-yl)butan-1-ol; (E)-3-methyl-5-phenylpent-2-enenitrile; (E)-2-(2,6-dimethylhepta-1,5-dien-1-yl)-4-methyl-1,3-dioxolane; (E)-1,1-dimethoxy-3,7-dimethylocta-2,6-diene; (E)-1,1-diethoxy-3,7-dimethylocta-2,6-diene; (E)-3,7-dimethylocta-1,3,6-triene; (1R,4R,6S)-1-methyl-4-(prop-1-en-2-yl)-7-oxabicyclo[4.1.0]heptane; (E)-oxacycloheptadec-11-en-2-one; (Z)-non-6-en-1-ol; (1R,5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-ol; (Z)-dec-4-enal; (E)-hex-3-en-1-yl(E)-hex-3-enoate; (Z)-hex-3-en-1-yl 2-hydroxybenzoate; (Z)-hex-3-en-1-yl benzoate; (Z)-hex-3-en-1-yl 2-methylbutanoate; (3Z,6Z)-nona-3,6-dien-1-ol; cinnamyl propionate; cinnamyl isobutyrate; cinnamyl formate; cinnamyl cinnamate; cinnamyl acetate; (E)-3-phenylprop-2-en-1-ol; hexadecan-1-ol; (E)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)hepta-1,6-dien-3-one; 2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)butanal; (3aR,5aR,9aR,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan; 1,6-dioxacycloheptadecan-7-one; 1-(6-(tert-butyl)-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl)ethan-1-one; (3R,3aR,6S,7S,8aS)-6-methoxy-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulene; (3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-3-yl formate; (3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-yl acetate; (4Z,8Z)-1,5,9-trimethyl-13-oxabicyclo[10.1.0]trideca-4,8-diene; (3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-ol; 5-methyl-1-(2,2,3-trimethylcyclopent-3-en-1-yl)-6-oxabicyclo[3.2.1]octane; 5-methyl-1-(2,2,3-trimethylcyclopent-3-en-1-yl)-6-oxabicyclo[3.2.1]octane; 1,1,2,3,3-pentamethyl-1,2,3,5,6,7-hexahydro-4H-inden-4-one; (Z)-4,11,11-trimethyl-8-methylenebicyclo[7.2.0]undec-3-en-5-yl acetate; (1S,2S,5R,8S)-4,4,8-trimethyltricyclo[6.3.1.02,5]dodecan-1-ol; 2-methyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-yl acetate; octanenitrile; octan-1-ol; octanoic acid; decanoic acid; decanal; 3-(4-methoxyphenyl)-2-methylpropanal; 1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione; 2,2-dimethyl-3-methylenebicyclo[2.2.1]heptane; ethyl 2-methyl-4-oxo-6-pentylcyclohex-2-ene-1-carboxylate; 2,6-di-tert-butyl-4-methylphenol; butyl stearate; 1-butoxy-1-oxopropan-2-yl butyrate; butyl undec-10-enoate; 2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)butan-1-ol; 3-(4-(tert-butyl)phenyl)propanal; (1S,2S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate; 1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl acetate; 2-ethoxy-2,6,6-trimethyl-9-methylenebicyclo[3.3.1]nonane; (ethoxymethoxy)cyclododecane; (E)-1-methyl-4-(6-methylhept-5-en-2-ylidene)cyclohex-1-ene; 3,3,6,7-tetramethyloctahydro-2H-chromene; (5R,10R)-6,10-dimethyl-2-(propan-2-ylidene)spiro[4.5]dec-6-en-8-one; 1-methyl-4-(prop-1-en-2-yl)cyclohexyl acetate; 1-methyl-4-(prop-1-en-2-yl)cyclohexan-1-ol; (2Z,6E)-2,6-dimethyl-10-methylenedodeca-2,6,11-trienal; (R)-3-methylene-6-((S)-6-methylhept-5-en-2-yl)cyclohex-1-ene; (4aR,7R,8aS)-4a-methyl-1-methylene-7-(prop-1-en-2-yl)decahydronaphthalene; (Z)-2-methyl-5-((1S,2R,4R)-2-methyl-3-methylenebicyclo[2.2.1]heptan-2-yl)pent-2-en-1-ol; 6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane; 2-ethoxynaphthalene; (1S,4R,7R)-1,4,9,9-tetramethyl-1,2,3,4,5,6,7,8-octahydro-4,7-methanoazulene; (1aS,5aR,9aR)-1a,5,5,7-tetramethyl-1a,2,3,4,5,5a,8,9-octahydrobenzo[1,7]cyclohepta[1,2-b]oxirene; (R)-3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzo[7]annulene; (1S,4S)-1,4-dimethyl-7-(propan-2-ylidene)-1,2,3,4,5,6,7,8-octahydroazulene; (2,2-dimethoxyethyl)benzene; (E)-7,11-dimethyl-3-methylenedodeca-1,6,10-triene; (1R,2S,6S,7S,8S)-8-isopropyl-1-methyl-3-methylenetricyclo[4.4.0.02,7]decane; (3R,3aS,7S,8aS)-3,8,8-trimethyl-6-methyleneoctahydro-1H-3a,7-methanoazulene; (1R,9S,Z)-4,11,11-trimethyl-8-methylenebicyclo[7.2.0]undec-4-ene; (S)-4-methyl-1-((S)-6-methylhept-5-en-2-yl)cyclohex-3-en-1-ol; (Z)-4-(2,2,6-trimethyl-7-oxabicyclo[4.1.0]heptan-1-yl)but-3-en-2-one; 4-methoxy-7H-furo[3,2-g]chromen-7-one; 2-methyl-4-phenylbutan-2-ol; benzyl dodecanoate; 2-methyl-1-phenylpropan-2-ol; benzyl cinnamate; benzyl benzoate; benzophenone; 7-isopentyl-2H-benzo[b][1,4]dioxepin-3(4H)-one; 2′ -isopropyl-1,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,4′-[1,3]dioxane]/A; 4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbonitrile; methyl(E)-2-((7-hydroxy-3,7-dimethyloctylidene)amino)benzoate; 4-methoxybenzyl 2-phenylacetate; methyl(E)-octa-4,7-dienoate; pentyl(Z)-3-phenylacrylate; (3aR,5aS,9aS,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan; (4aR,5R,7aS,9R)-2,2,5,8,8,9a-hexamethyloctahydro-4H-4a,9-methanoazuleno[5,6-d][1,3]dioxole; 2,5,5-trimethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-ol; 2,5,5-trimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-ol; 1-((2-(tert-butyl)cyclohexyl)oxy)butan-2-ol; (3S,5aR,7aS,11aS,11bR)-3,8,8,11a-tetramethyldodecahydro-5H-3,5a-epoxynaphtho[2,1-c]oxepine; 2,2,6,6,7,8,8-heptamethyldecahydro-2H-indeno[4,5-b]furan; 2,2,7,7,8,9,9-heptamethyldecahydroindeno[4,3a-b]furan; 2-(sec-butyl)-1-vinylcyclohexyl acetate; (1S,4R,5R)-1-isopropyl-4-methylbicyclo[3.1.0]hexan-3-one; (4R,4aS)-4,4a-dimethyl-6-(propan-2-ylidene)-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one; 2-(4-methylcyclohex-3-en-1-yl)propan-2-yl propionate; (2Z,6E,9E)-2,6,10-trimethyldodeca-2,6,9,11-tetraenal; (2R,4aR,8aR)-4a,8-dimethyl-2-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,8a-octahydronaphthalene; 1,7-dimethyl-7-(4-methylpent-3-en-1-yl)tricyclo[2.2.1.02,6]heptane; (E)-5-(2,3-dimethyltricyclo[2.2.1.02,6]heptan-3-yl)-2-methylpent-2-en-1-ol; (1R,3aS,7S,8aR)-1,4,9,9-tetramethyl-2,3,6,7,8,8a-hexahydro-1H-3a,7-methanoazulene; 1-(5,5-dimethylcyclohex-1-en-1-yl)pent-4-en-1-one; (1S,4aS,8aR)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene; (R,Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)pent-1-en-3-one; 1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene; (Z)-4-(2,5,6,6-tetramethylcyclohex-2-en-1-yl)but-3-en-2-one; (1Z,4E,8Z)-2,6,6,9-tetramethylcycloundeca-1,4,8-triene; (4aR,8S,9aS)-3,5,5,8-tetramethyl-9-methylene-2,4a,5,6,7,8,9,9a-octahydro-1H-benzo[7]annulene; (1aR,4R,4aR,7bS)-1,1,4,7-tetramethyl-1a,2,3,4,4a,5,6,7b-octahydro-1H-cyclopropa[e]azulene; 1,4-dimethyl-7-(prop-1-en-2-yl)-1,2,3,4,5,6,7,8-octahydroazulene; (3E,6E)-3,7,11-trimethyldodeca-1,3,6,10-tetraene; 7,7-dimethyl-2-methylenebicyclo[2.2.1]heptane; 2-((2R,4aR,8aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)propan-2-ol; (R)-1-methyl-4-(6-methylhept-5-en-2-yl)benzene; (3aR,3bR,4S,7R,7aS)-4-isopropyl-7-methyl-3a,3b,4,5,6,7-hexahydro-1H-cyclopenta[1,3]cyclopropa[1,2]benzene; (1aS,2aR,3R,5aS,7R,7aR)-3,6,6,7a-tetramethyloctahydro-2H-2a,7-methanoazuleno[5,6-b]oxirene; (1R,4S,4aR,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol; (1S,4aR,8aR)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene; (R)-2-((R)-4-methylcyclohex-3-en-1-yl)hex-5-en-2-ol; (Z)-1-methyl-4-(6-methylhepta-2,5-dien-2-yl)cyclohex-1-ene; 2,6-dimethyl-6-(4-methylpent-3-en-1-yl)bicyclo[3.1.1]hept-2-ene; (E)-2-benzylideneheptan-1-ol; (E)-2-benzylideneheptyl acetate; (Z)-(2-(diethoxymethyl)hept-1-en-1-yl)benzene; (E)-2-benzylideneheptanal; (1S,4aR,8aS)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene; (3R,5aS,9aR)-2,2,5a,9-tetramethyl-3,4,5,5a,6,7-hexahydro-2H-3,9a-methanobenzo[b]oxepine; 1-methyl-4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde; 1-phenylpentan-2-ol; 3-methyl-1-phenylpentan-3-ol; 2,3,4-trimethoxybenzaldehyde; 2,4,5-trimethoxybenzaldehyde; 2,4,6-trimethoxybenzaldehyde; Trans,Trans-2,4-Nonadienal; 2,6,10-trimethylundecanal; alpha-4-Dimethyl benzenepropanal; allyl 3-cyclohexylpropanoate; allyl 2-(isopentyloxy)acetate; (1aR,4aS,7R,7aR,7bS)-1,1,7-trimethyl-4-methylenedecahydro-1H-cyclopropa[e]azulene; (E)-undec-9-enal; methyl(E)-2-(((3,5-dimethylcyclohex-3-en-1-yl)methylene)amino)benzoate; 2,6,10-trimethylundec-9-enal; (7,7,8,8-tetramethyloctahydro-2,3b-methanocyclopenta[1,3]cyclopropa[1,2]benzen-4-yl)methyl acetate; nonyl acetate; (2-(1-propoxyethoxy)ethyl)benzene; 1-(1-propoxyethoxy)propane; ((1-(2-methoxyethoxy)ethoxy)methyl)benzene; (Z)-2-(4-methylbenzylidene)heptanal; dec-9-enal; (Z)-oxacycloheptadec-8-en-2-one; 7-methoxy-2H-chromen-2-one; (2S,4aR,8aR)-4a,8-dimethyl-2-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,8a-octahydronaphthalene; 2-((2S,4aR,8aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)propan-2-ol; 1-(3,5,5,6,8,8-hexamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)ethan-1-one; 6-isopropylquinoline; 3-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal; 6,10,14-trimethylpentadecan-2-one; 2-methyl-5-(prop-1-en-2-yl)-2-vinyltetrahydrofuran; (E)-cyclohexadec-5-en-1-one; 1-isopropyl-4-methylcyclohex-3-en-1-ol; 1-phenylpent-4-en-1-one; 1-isopropyl-4-methylcyclohex-3-en-1-ol; 3,6-dimethyl-4,5,6,7-tetrahydrobenzofuran; 4-(4-methoxyphenyl)butan-2-one; (1aR,2S,4aS)-2,4a,8,8-tetramethyloctahydrocyclopropa[d]naphthalen-3(1H)-one; (E)-3-propylideneisobenzofuran-1(3H)-one; (Z)-dodec-2-enal; 3-methyl-5-phenylpentanal; (E)-hex-3-en-1-yl 3-methylbutanoate; 3,6-dimethyloctan-3-yl acetate; 3,4,5-trimethoxybenzaldehyde; 3-(4-isopropylphenyl)propanal; (Z)-undec-2-enenitrile; (E)-undec-2-enal; (2E,6E)-nona-2,6-dienal; phenethyl butyrate; (Z)-3-(furan-2-yl)-2-phenylacrylaldehyde; 2-phenoxyethan-1-ol; (Z)-non-2-enal; nonan-2-ol; nonan-2-one; 2-isobutylquinoline; (E)-2-hexylidenecyclopentan-1-one; 2-heptyltetrahydrofuran; (E)-dec-2-enal; (2E,6E)-nona-2,6-dienal; (2E,6E)-nona-2,6-dien-1-ol; 2,6-dimethyloctanal; decan-1-ol; (E)-hept-1-en-1-yl acetate; undec-10-en-1-ol; undec-10-enal; 2-((2R,4aS)-4a,8-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-yl)propan-2-ol; 1-isopropyl-4-methyl-7-thiabicyclo[2.2.1]heptane; (3E,5Z)-undeca-1,3,5-triene; 3,7-dimethyloct-6-en-3-ol; 1,3,3-trimethylbicyclo[2.2.1]heptan-2-yl acetate; 1,1,2,3,3-pentamethyl-2,3-dihydro-1H-indene; (Z)-6,10-dimethylundeca-5,9-dien-2-yl acetate; (Z)-dodec-3-enal; (S)-5-heptyldihydrofuran-2(3H)-one; (R)-5-heptyldihydrofuran-2(3H)-one; (E)-6,10-dimethylundeca-5,9-dien-2-yl acetate; (Z)-3-methyl-5-phenylpent-2-enenitrile; (2S,5S,6S)-2,6,10,10-tetramethyl-1-oxaspiro[4.5]decan-6-ol; (2E)-3-methyl-5-phenyl-2-pentenenitrile; (1S,2S,5S)-2-methyl-5-(prop-1-en-2-yl)cyclohexan-1-ol; (2S,5R)-2-isopropyl-5-methylcyclohexan-1-one; (R,E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol; 2-(8-isopropyl-6-methylbicyclo[2.2.2]oct-5-en-2-yl)-1,3-dioxolane; (E)-4-(2,2-dimethyl-6-methylenecyclohexyl)-3-methylbut-3-en-2-one; 3-(3-isopropylphenyl)butanal; 3-(1-ethoxyethoxy)-3,7-dimethylocta-1,6-diene; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl propionate; 2-((3S,3aS,5R)-3,8-dimethyl-1,2,3,3a,4,5,6,7-octahydroazulen-5-yl)propan-2-ol; benzyl 2-phenylacetate; 2-hydroxy-1,2-diphenylethan-1-one; (E)-1,2,4-trimethoxy-5-(prop-1-en-1-yl)benzene; 3-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2,2-dimethylpropanal; 2-methyl-5-(6-methylhept-5-en-2-yl)bicyclo[3.1.0]hex-2-ene; 1-(1,1,2,3,3,6-hexamethyl-2,3-dihydro-1H-inden-5-yl)ethan-1-one; 2-(m-tolyl)ethan-1-ol; (3E,6E)-nona-3,6-dien-1-ol; (E)-tridec-2-enal; (1R,4S,4aS,6R,8aS)-4,8a,9,9-tetramethyloctahydro-1,6-methanonaphthalen-1(2H)-ol; p-tolyl isobutyrate; p-tolyl hexanoate; 5-hexyl-4-methyldihydrofuran-2(3H)-one; ethyl(2Z,4E)-deca-2,4-dienoate; 2,4-dimethyl-6-phenyl-3,6-dihydro-2H-pyran; 2-cyclohexylidene-2-phenylacetonitrile; 4-(prop-1-en-2-yl)cyclohex-1-ene-1-carbaldehyde; (4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)methyl acetate; (4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)methanol; (2-isopropoxyethyl)benzene; 2-cyclohexylhepta-1,6-dien-3-one; (2-(cyclohexyloxy)ethyl)benzene; phenethyl 2-methylbutanoate; 2-phenylethan-1-ol; phenethyl 2-phenylacetate; 3-methyl-5-phenylpentan-1-ol; phenyl benzoate; phenethyl benzoate; 2-benzyl-1,3-dioxolane; 2-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acetaldehyde; 6,6-dimethyl-2-methylenebicyclo[3.1.1]heptan-3-ol; 4-(benzo[d][1,3]dioxol-5-yl)butan-2-one; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl pivalate; (4aR,8aS)-7-methyloctahydro-1,4-methanonaphthalen-6(2H)-one; 4-isopropyl-1-methylcyclohex-3-en-1-ol; (E)-3,3-dimethyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol; 1-methyl-4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde; propane-1,2-diol; p-tolyl 2-phenylacetate; Ethyl 2,4,7-decatrienoate; 2-benzyl-4,4,6-trimethyl-1,3-dioxane; 2,4-dimethyl-4-phenyltetrahydrofuran; (2R,4a′R,8a′R)-3,7′-dimethyl-3′,4′,4a′,5′,8′,8a′-hexahydro-1′H-spiro[oxirane-2,2′-[1,4]methanonaphthalene]; (Z)-6-ethylideneoctahydro-2H-5,8-methanochromene; 2-((S)-1-((S)-3,3-dimethylcyclohexyl)ethoxy)-2-oxoethyl propionate; methyl 2,2-dimethyl-6-methylenecyclohexane-1-carboxylate; 2-methyl-5-phenylpentan-1-ol; 4-methyl-2-phenyl-3,6-dihydro-2H-pyran; (1S,3R,5S)-1-isopropyl-4-methylenebicyclo[3.1.0]hexan-3-ol; 5-allylbenzo[d][1,3]dioxole; 2,2,7,9-tetramethylspiro(5.5)undec-8-en-1-one; 3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pentan-2-ol; (Z)-2-ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol; (E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol; 5-methoxyoctahydro-1H-4,7-methanoindene-2-carbaldehyde; 5-methoxyoctahydro-1H-4,7-methanoindene-2-carbaldehyde; 1-(3-hydroxy-3-methylpent-4-en-1-yl)-2,5,5,8a-tetramethyldecahydronaphthalen-2-ol; (4aR,6aS,10aS,10bR)-3,4a,7,7,10a-pentamethyl-4a,5,6,6a,7,8,9,10,10a,10b-decahydro-1H-benzo[f]chromene; (4aR,8aR)-4a,8-dimethyl-2-(propan-2-ylidene)-1,2,3,4,4a,5,6,8a-octahydronaphthalene; 2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-methylpropyl cyclopropanecarboxylate; 3-(4-isobutylphenyl)-2-methylpropanal; (1aR,4aR,7S,7aR,7bR)-1,1,7-trimethyl-4-methylenedecahydro-1H-cyclopropa[e]azulen-7-ol; (1R,3R,6R)-2′,2′,3,7,7-pentamethylspiro[bicyclo[4.1.0]heptane-2,5′-[1,3]dioxane]; 2-methyl-1,5-dioxaspiro[5.5]undecane; 1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-1-one; 2-(4-methylthiazol-5-yl)ethan-1-ol; 2-(heptan-3-yl)-1,3-dioxolane; (Z)-dodec-4-enal; (1S,4S,4aR,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol; (1S,4S,4aR,8aS)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol; 3-methyl-2-pentylcyclopentan-1-one; 2,6,10,10-tetramethyl-1-oxaspiro[4.5]dec-6-ene; 2-(2-mercaptopropan-2-yl)-5-methylcyclohexan-1-one; (1aR,4aS)-2,4a,8,8-tetramethyl-1,1a,4,4a,5,6,7,8-octahydrocyclopropa[d]naphthalene; 1-isopropyl-2-methoxy-4-methylbenzene; 1-(2,2,6-trimethylcyclohexyl)hexan-3-ol; (2Z,4E)-nona-2,4-dienal; (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol; (2E,6Z)-nona-2,6-dienal; (Z)-dec-2-enal; (E)-non-2-enal; (3E,6Z)-nona-3,6-dien-1-ol; (E)-dec-4-enal; (Z)-oxacycloheptadec-8-en-2-one; (Z)-3,7-dimethylocta-1,3,6-triene; (Z)-3,7-dimethylocta-1,3,6-triene; (E)-3,7-dimethylocta-2,6-dien-1-ol; methyl 2-((1S,2S)-3-oxo-2-pentylcyclopentyl)acetate; 7-(1,1-Dimethylethyl)-2H-1,5-benzodioxepin-3(4H)-one; (1R-(1alpha,3alpha,4aalpha))-2,3,4,4a,5,6-hexahydro-2,2-dimethyl-1,3-methanonaphthalen-7(1H)-one; tridecan-1-ol; triethyl 2-hydroxypropane-1,2,3-tricarboxylate; methyl 2-((1-hydroxy-3-phenylbutyl)amino)benzoate; 1-((2E,5Z,9Z)-2,6,10-trimethylcyclododeca-2,5,9-trien-1-yl)ethan-1-one; decahydro-2,6,6,7,8,8-hexamethyl-2h-indeno(4,5-b)furan; 13-methyl oxacyclopentadec-10-en-2-one; undecanal; (E)-4-methyldec-3-en-5-ol; (3R,4aS,5R)-4a,5-dimethyl-3-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,7-octahydronaphthalene; 2-((2R,8R,8aS)-8,8a-dimethyl-1,2,3,4,6,7,8,8a-octahydronaphthalen-2-yl)propan-2-ol; 4-formyl-2-methoxyphenyl isobutyrate; (Z)-2-methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-enal; methyl 2,4-dihydroxy-3,6-dimethylbenzoate; 1-methoxy-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoindene; methyl(Z)-2-((3-(4-(tert-butyl)phenyl)-2-methylpropylidene)amino)benzoate; (Z)-hex-3-en-1-yl isobutyrate; 2,4,6-trimethyl-4-phenyl-1,3-dioxane; 1-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-methanoazulen-5-yl)ethan-1-one; methyl(Z)-2-(((2,4-dimethylcyclohex-3-en-1-yl)methylene)amino)benzoate; 4,8-dimethyl-2-(propan-2-ylidene)-1,2,3,3a,4,5,6,8a-octahydroazulen-6-ol; 4,8-dimethyl-2-(propan-2-ylidene)-1,2,3,3a,4,5,6,8a-octahydroazulen-6-yl acetate; decahydro-3H-spiro[furan-2,5′-[4,7]methanoindene]; (2Z,6E)-nona-2,6-dienenitrile; (Z)-cyclooct-4-en-1-yl methyl carbonate; (1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7-tetramethyldecahydro-1H-cyclopropa[e]azulen-4-ol; 3,5,5,6,7,8,8-heptamethyl-5,6,7,8-tetrahydronaphthalene-2-carbonitrile; (1S,2S,3S,5R)-2,6,6-trimethylspiro[bicyclo[3.1.1]heptane-3,1′-cyclohexan]-2′-en-4′-one; 1′,1′,5′,5′-tetramethylhexahydro-2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene]; (2′S,4a′S,8a′S)-1′,1′,5′,5′-tetramethylhexahydro-2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene]; 4-(4-hydroxy-3-methoxyphenyl)butan-2-one; (1R,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,7,8,8a-hexahydronaphthalene; 2,4-dimethyl-2-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-1,3-dioxolane; 3a,5,6,7,8,8b-hexahydro-2,2,6,6,7,8,8-heptamethyl-4H-indeno(4,5-d)-1,3-dioxole; 2,4-dimethyl-4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine; (1-methyl-2-((1,2,2-trimethylbicyclo[3.1.0]hexan-3-yl)methyl)cyclopropyl)methanol; 2-(cyclohexyloxy)-1,7,7-trimethylbicyclo[2.2.1]heptane; 4-((2R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)cyclohexan-1-ol; 8,8-di(1H-indol-1-yl)-2,6-dimethyloctan-2-ol; (7,7,8,8-tetramethyloctahydro-2,3b-methanocyclopenta[1,3]cyclopropa[1,2]benzen-4-yl)methanol; 8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl propionate; (E)-4-((3aR,4R,7R,7aR)-1,3a,4,6,7,7a-hexahydro-5H-4,7-methanoinden-5-ylidene)-3-methylbutan-2-ol; (3R,3aR,6S,7S,8aS)-6-methoxy-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulene; (1R,2S,6S,7S,8S)-8-isopropyl-1-methyl-3-methylenetricyclo[4.4.0.02,7]decane; 2′-isopropyl-1,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,4′-[1,3]dioxane]; (4aR,5R,7aS,9R)-2,2,5,8,8,9a-hexamethyloctahydro-4H-4a,9-methanoazuleno[5,6-d][1,3]dioxole; (3S,5aR,7aS,11aS,11bR)-3,8,8,11a-tetramethyldodecahydro-5H-3,5a-epoxynaphtho[2,1-c]oxepine; 2,2,6,6,7,8,8-heptamethyldecahydro-2H-indeno[4,5-b]furan; (1aS,2aR,3R,5aS,7R,7aR)-3,6,6,7a-tetramethyloctahydro-2H-2a,7-methanoazuleno[5,6-b]oxirene; (7,7,8,8-tetramethyloctahydro-2,3b-methanocyclopenta[1,3]cyclopropa[1,2]benzen-4-yl)methyl acetate; 1-(3-hydroxy-3-methylpent-4-en-1-yl)-2,5,5,8a-tetramethyldecahydronaphthalen-2-ol; decahydro-2,6,6,7,8,8-hexamethyl-2h-indeno(4,5-b)furan; 2-ethylhexyl(Z)-3-(4-methoxyphenyl)acrylate; methoxycyclododecane; 1-ethoxy-4-(tert-pentyl)cyclohexane; (2-hydroxy-4-methoxyphenyl)(phenyl)methanone; (3Z)-1-(2-buten-1-yloxy)-3-hexene; 4-(2-methoxypropan-2-yl)-1-methylcyclohex-1-ene; 4-(tert-pentyl)cyclohexan-1-one; 3-methoxy-3,7-dimethylocta-1,6-diene; 7-isopropyl-8,8-dimethyl-6,10-dioxaspiro[4.5]decane; (E)-3-(2-methoxyphenyl)acrylaldehyde; 3,7-dimethyloctanal; 1,1-dimethoxyoctane; 2-methyl-6-methyleneoct-7-en-2-ol; 4-methoxy-6-prop-2-enyl-1,3-benzodioxole; tetradecanenitrile; (E)-2,7-dimethylocta-1,5,7-trien-3-ol; 3,3-Dimethyl-5(2,2,3-Trimethyl-3-Cyclopenten-1yl)-4-Penten-2-ol; hexyl 2-hydroxybenzoate; hexyl(Z)-but-2-enoate; (Z)-3,7-dimethylocta-2,6-dien-1-yl formate; (Z)-3,7-dimethylocta-2,6-dien-1-ol; 1-ethyl-3-methoxytricyclo[2.2.1.02,6]heptane; 10-isopropyl-2,7-dimethyl-1-oxaspiro[4.5]deca-3,6-diene; 6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde; (E)-4-(2,2,3,6-tetramethylcyclohexyl)but-3-en-2-one; (Z)-1-(2,6,6-trimethylcyclohex-1-en-1-yl)pent-1-en-3-one; (E)-2,2-dimethyl-3-(3-methylpenta-2,4-dien-1-yl)oxirane; 3-methylcyclopentadecan-1-one; (E)-3,7-dimethylocta-4,6-dien-3-ol; 3-methyl-4-phenylbutan-2-ol; 1-(4-isopropylcyclohexyl)ethan-1-ol; (Z)-hex-3-en-1-yl cyclopropanecarboxylate; (E)-dec-5-enoic acid; 1-phenylethyl propionate; methyl 2-phenylacetate; 4-phenylbutan-2-ol; methyl stearate; methyl(9Z,12Z)-octadeca-9,12-dienoate; 1-hydroxydecan-3-one; 2-methyl-6-oxaspiro[4.5]decan-7-one; (Z)-1,2-dimethoxy-4-(prop-1-en-1-yl)benzene; methyl palmitate; 4-allyl-1,2-dimethoxybenzene; methyl(Z)-3,7-dimethylocta-2,6-dienoate; 1-methyl-2-phenoxybenzene; 2-ethoxy-4-(methoxymethyl)phenol; methyl 2-cyclopentylideneacetate; 1-allyl-4-methoxybenzene; 6-methoxy-2,6-dimethylheptanal; 7-methoxy-3,7-dimethyloctanal; ((1s,4s)-4-isopropylcyclohexyl)methanol; 3-(3-(tert-butyl)phenyl)-2-methylpropanal; (E)-4-(4,8-dimethylnona-3,7-dien-1-yl)pyridine; (E)-trideca-3,12-dienenitrile; 2,2-dimethyl-3-(m-tolyl)propan-1-ol; 8-isopropyl-6-methylbicyclo[2.2.2]oct-5-ene-2-carbaldehyde; 4-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1-carbaldehyde; (Z)-3-hexen-1-yl-2-cyclopenten-1-one; 3,7-dimethylocta-1,6-dien-3-yl propionate; 3,7-dimethylocta-1,6-dien-3-yl octanoate; 3,7-dimethylocta-1,6-dien-3-yl formate; 3,7-dimethylocta-1,6-dien-3-yl butyrate; 3,7-dimethylocta-1,6-dien-3-yl benzoate; 3,7-dimethylocta-1,6-dien-3-yl 2-aminobenzoate; 3,7-dimethylocta-1,6-dien-3-yl acetate; 3,7-dimethylocta-1,6-dien-3-ol; 3-(4-methylcyclohex-3-en-1-yl)butanal; 3-(4-(tert-butyl)phenyl)-2-methylpropanal; (Z)-hex-3-en-1-yl methyl carbonate; 4-methylquinoline; (E)-1-(1-methoxypropoxy)hex-3-ene; 2-Methyl-5-(1-methylethenyl)-2-cyclohexenone; dodecanal; 2,2-dimethyl-5-phenylhexanenitrile; (E)-6-(pent-3-en-1-yl)tetrahydro-2H-pyran-2-one; 2-hexylcyclopentan-1-one; (Z)-4-(6,6-dimethylcyclohex-2-en-1-yl)-3-methylbut-3-en-2-one; 2,6,9,10-tetramethyl-1-oxaspiro(4.5)deca-3,6-diene; 4-methylpent-1-en-3-ol; isopropyl palmitate; isopropyl dodecanoate; isopropyl 2-methylbutanoate; 4-methylpent-4-en-2-yl isobutyrate; 7-methyloctyl acetate; 7-methyloctan-1-ol; 4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde; (Z)-2-methoxy-4-(prop-1-en-1-yl)phenyl acetate; (Z)-2-methoxy-4-(prop-1-en-1-yl)phenol; (1R,2R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl propionate; (1R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl acetate; 1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol; 2-(4-isopropylcyclohexa-1,4-dien-1-yl)ethyl formate; isopentyl(E)-undec-6-enoate; isopentyl octanoate; isopentyl dodecanoate; isopentyl isobutyrate; (E)-oxacycloheptadec-10-en-2-one; 8,8-di(1H-indol-1-yl)-2,6-dimethyloctan-2-ol; 2-cyclododecylpropan-1-ol; 3-phenylpropan-1-ol; 3-phenylpropanoic acid; (1,1-dimethoxypropan-2-yl)benzene; 2-phenylpropan-1-ol; hexyl propionate; hexyl butyrate; hexyl 2-methylbutanoate; hexyl furan-2-carboxylate; oxacycloheptadecan-2-one; heptan-1-ol; heptyl acetate; heptanal; 2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-methylpropyl propionate; 5-(diethoxymethyl)benzo[d][1,3]dioxole; benzo[d][1,3]dioxole-5-carbaldehyde; 3-(benzo[d][1,3]dioxol-5-yl)-2-methylpropanal; (E)-oxacyclohexadec-13-en-2-one; 6-butyl-2,4-dimethyl-3,6-dihydro-2H-pyran; 2-((3S,5R,8S)-3,8-dimethyl-1,2,3,4,5,6,7,8-octahydroazulen-5-yl)propan-2-ol; 1-(2,6,6-trimethylcyclohex-2-en-1-yl)pentan-3-one; (1Z,5Z)-1,5-dimethyl-8-(propan-2-ylidene)cyclodeca-1,5-diene; (E)-3,7-dimethylocta-2,6-dien-1-yl 2-phenylacetate; (E)-3,7-dimethylocta-2,6-dien-1-yl 2-phenylacetate; (Z)-3,7-dimethylocta-2,6-dienenitrile; (E)-3,7-dimethylocta-2,6-dien-1-yl formate; (E)-3,7-dimethylocta-2,6-dien-1-yl octanoate; (E)-3,7-dimethylocta-2,6-dien-1-yl benzoate; (E)-3,7-dimethylocta-2,6-dienal; N,2-dimethyl-N-phenylbutanamide; 1-isopropyl-4-methylcyclohexa-1,4-diene; (1R,4aR,8aS)-1-isopropyl-7-methyl-4-methylene-1,2,3,4,4a,5,6,8a-octahydronaphthalene; 5-[(Z)-hex-3-enyl]oxolan-2-one; (4aS,9aR)-3,5,5,9-tetramethyl-2,4a,5,6,7,9a-hexahydro-1H-benzo[7]annulene; (Z)-1-(2,2-dimethyl-6-methylenecyclohexyl)but-2-en-1-one; (1R,4aS,8aS)-1-isopropyl-7-methyl-4-methylene-1,2,3,4,4a,5,6,8a-octahydronaphthalene; 1-(3,3-dimethylcyclohexyl)pent-4-en-1-one; furan-2-ylmethyl octanoate; furan-2-ylmethyl hexanoate; furan-2-ylmethyl heptanoate; ethyl (3aR,4S,7R,7aR)-octahydro-3aH-4,7-methanoindene-3a-carboxylate; 2-(sec-butyl)cyclohexan-1-one; 3-(2-ethylphenyl)-2,2-dimethylpropanal; 2-(tert-butyl)cyclohexyl ethyl carbonate; 3-(2-ethylphenyl)-2,2-dimethylpropanal; (E)-4,8-dimethyldeca-4,9-dienal; 3-(4-ethylphenyl)-2,2-dimethylpropanenitrile; 2-heptylcyclopentan-1-one; 1-ethoxyethoxy Cyclododecane; (Z)-5-methylhept-2-en-4-one; 1,3,3-trimethylbicyclo[2.2.1]heptan-2-ol; oxacyclohexadecan-2-one; (E)-cyclopentadec-4-en-1-one; 1-cyclopentadec-4-en-1-one; 4-allyl-2-methoxyphenyl acetate; 4-allyl-2-methoxyphenol; 1,3,3-trimethyl-2-oxabicyclo[2.2.2]octane; ethyl 3-methyl-3-phenyloxirane-2-carboxylate; 1,4-dioxacycloheptadecane-5,17-dione; 2-ethoxy-4-formylphenyl acetate; ethyl undec-10-enoate; ethyl palmitate; ethyl octanoate; ethyl tetradecanoate; (E)-3,7-dimethylnona-1,6-dien-3-ol; ethyl cinnamate; ethyl 3-phenyloxirane-2-carboxylate; ethyl 2-cyclohexylpropanoate; 6-ethyl-2,10,10-trimethyl-1-oxaspiro[4.5]deca-3,6-diene; (2R,3S,4R)-2,3,4,5-tetrahydroxypentanal; (E)-4-((3aS,7aS)-octahydro-5H-4,7-methanoinden-5-ylidene)butanal; (2R,5R)-2-methyl-5-(prop-1-en-2-yl)cyclohexan-1-one; 4-methyl-2-phenyltetrahydro-2H-pyran; oxydibenzene; diphenylmethane; 2-methyl-1-phenylpropan-2-yl butyrate; 2,6-dimethyloct-7-en-2-ol; 3-methyl-2-pentylcyclopent-2-en-1-one; 3,3,5-trimethylcyclohexan-1-one; 2-methoxy-4-propylphenol; chroman-2-one; 2-methyl-5-(prop-1-en-2-yl)cyclohexan-1-one; 2-methyl-5-(prop-1-en-2-yl)cyclohexyl acetate; 2-(4-methylcyclohexyl)propan-2-yl acetate; 4-(2,6,6-trimethylcyclohex-2-en-1-yl)butan-2-one; (oxybis(methylene))dibenzene; dibutyl phthalate; 1,2-diphenylethane; (3R,4R)-1-isopropyl-4-methyl-3-(prop-1-en-2-yl)-4-vinylcyclohex-1-ene; (1S,8aR)-4,7-dimethyl-1-(propan-2-yl)-1,2,3,5,6,8a-hexahydronaphthalene; (1S,8aS)-1-isopropyl-4,7-dimethyl-1,2,3,5,6,8a-hexahydronaphthalene; 2-pentylcyclopentan-1-one; decyl 2-aminobenzoate; decahydronaphthalen-2-ol; methyl(1s,4s)-1,4-dimethylcyclohexane-1-carboxylate; 3-(4-isopropylphenyl)-2-methylpropanal; cyclotetradecane; cyclopentadecanone; 2-cyclohexylethyl acetate; cyclohexyl 2-hydroxybenzoate; 1,4-dioxacyclohexadecane-5,16-dione; (4-isopropylphenyl)methanol; 2-methoxy-4-methylphenol; (3Z,5Z)-2,6-dimethylocta-1,3,5,7-tetraene; 4-cyclohexyl-2-methylbutan-2-ol; 2-(3-phenylpropyl)pyridine; 3-(4-methylcyclohex-3-en-1-yl)but-3-en-1-yl acetate; 3-(4-methylcyclohex-3-en-1-yl)butan-1-ol; 2-benzyl-2-methylbut-3-enenitrile; 3,7-dimethyloct-6-enenitrile; 3,7-dimethyloct-6-en-1-yl 2-phenylacetate; 3,7-dimethyloct-6-en-1-yl formate; 3,7-dimethyloct-6-en-1-yl benzoate; 3,7-dimethyloct-6-en-1-ol; 3,7-dimethyloct-6-enal; (E)-3,7-dimethylocta-2,6-dienal; (1R,2S,5R)-2,6,6-trimethylbicyclo[3.1.1]heptane; (Z)-3-methyl-2-(pent-2-en-1-yl)cyclopent-2-en-1-one; (E)-2-methoxy-4-(prop-1-en-1-yl)phenol; (E)-oxacycloheptadec-11-en-2-one; (Z)-non-6-en-1-ol; (Z)-hex-3-en-1-yl pentanoate; (E)-hex-3-en-1-yl(E)-2-methylbut-2-enoate; (Z)-hex-3-en-1-yl 2-hydroxybenzoate; (Z)-hex-3-en-1-yl propionate; (Z)-hex-3-en-1-yl butyrate; (Z)-hex-3-en-1-yl benzoate; (Z)-hex-3-en-1-ol; (Z)-hex-3-en-1-yl 2-methylbutanoate; (Z)-hex-2-en-1-ol; cinnamonitrile; cinnamyl isobutyrate; cinnamaldehyde; (E)-3-phenylprop-2-en-1-ol; cinnamonitrile; 4-chloro-3,5-dimethylphenol; hexadecan-1-ol; (E)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)hepta-1,6-dien-3-one; 2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)butanal; (3aR,5aR,9aR,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan; (4Z,8Z)-1,5,9-trimethyl-13-oxabicyclo[10.1.0]trideca-4,8-diene; 5-methyl-1-(2,2,3-trimethylcyclopent-3-en-1-yl)-6-oxabicyclo[3.2.1]octane; 1,1,2,3,3-pentamethyl-1,2,3,5,6,7-hexahydro-4H-inden-4-one; 5-isopropyl-2-methylphenol; 2-methyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-one; 2-(2-ethoxyethoxy)ethan-1-ol; hexan-1-ol; 2-(2,2,3-trimethylcyclopent-3-en-1-yl)acetonitrile; 1,7,7-trimethylbicyclo[2.2.1]heptan-2-one; 2,2-dimethyl-3-methylenebicyclo[2.2.1]heptane; 2,6-di-tert-butyl-4-methylphenol; butyl stearate; butyl undec-10-enoate; 2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)butan-1-ol; (E)-2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-2-enal; 1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl acetate; (1S,2R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol; 3,3,6,7-tetramethyloctahydro-2H-chromene; 6,6-dimethylspiro[bicyclo[3.1.1]heptane-2,2′-oxirane]; 3-isopropyl-6-methylenecyclohex-1-ene; 2-ethoxynaphthalene; (R)-3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzo[7]annulene; (1S,4S)-1,4-dimethyl-7-(propan-2-ylidene)-1,2,3,4,5,6,7,8-octahydroazulene; (1R,9S,Z)-4,11,11-trimethyl-8-methylenebicyclo[7.2.0]undec-4-ene; (Z)-4-(2,2,6-trimethyl-7-oxabicyclo[4.1.0]heptan-1-yl)but-3-en-2-one; 4-methoxy-7H-furo[3,2-g]chromen-7-one; 4-phenylbutan-2-one; benzyl 2-hydroxybenzoate; benzyl dodecanoate; benzyl 3-methylbutanoate; benzyl isobutyrate; benzyl cinnamate; benzyl butyrate; phenylmethanol; benzyl benzoate; 1-(3,3-dimethylcyclohexyl)ethyl formate; 4-methoxybenzyl acetate; 4-methoxybenzyl formate; (Z)-1-methoxy-4-(prop-1-en-1-yl)benzene; pentyl benzoate; (3aR,5aS,9aS,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan; 2,5,5-trimethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-ol; 2,5,5-trimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-ol; 2-(sec-butyl)-1-vinylcyclohexyl acetate; (1S,4R,5R)-1-isopropyl-4-methylbicyclo[3.1.0]hexan-3-one; 2-(4-methylcyclohex-3-en-1-yl)propan-2-yl propionate; 2-(4-methylcyclohex-3-en-1-yl)propan-2-yl acetate; 1,7-dimethyl-7-(4-methylpent-3-en-1-yl)tricyclo[2.2.1.02,6]heptane; 1-(5,5-dimethylcyclohex-1-en-1-yl)pent-4-en-1-one; (1S,4aS,8aR)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene; 4-cyclohexylbutan-2-ol; (R,Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)pent-1-en-3-one; (E)-2-methyl-3-phenylacrylaldehyde; (Z)-3-methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-2-one; (Z)-4-(2,5,6,6-tetramethylcyclohex-2-en-1-yl)but-3-en-2-one; (1Z,4E,8Z)-2,6,6,9-tetramethylcycloundeca-1,4,8-triene; (4aR,8S,9aS)-3,5,5,8-tetramethyl-9-methylene-2,4a,5,6,7,8,9,9a-octahydro-1H-benzo[7]annulene; (1R,4S,4aR,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol; (1S,4aR,8aR)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene; (R)-2-((R)-4-methylcyclohex-3-en-1-yl)hex-5-en-2-ol; (E)-2-benzylideneheptyl acetate; (1S,4aR,8aS)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene; 1-phenylpentan-2-ol; 4-methoxy-2,5-dimethylfuran-3(2H)-one; alpha-4-Dimethyl benzenepropanal; allyl 2-phenoxyacetate; (2-(allyloxy)ethyl)benzene; allyl heptanoate; allyl 3-cyclohexylpropanoate; N-ethyl-N-(m-tolyl)propionamide; 2,6,10-trimethylundec-9-enal; 3-hydroxybutan-2-one; 1-(4-methoxyphenyl)ethan-1-one; (Z)-2-(4-methylbenzylidene)heptanal; (Z)-oxacycloheptadec-8-en-2-one; 7-methoxy-2H-chromen-2-one; 6-methylquinoline; 6,8-dimethylnonan-2-ol; 6,10,14-trimethylpentadecan-2-one; 5-methylheptan-3-one; 4-vinylphenol; 1-phenylpent-4-en-1-one; (E)-3-(4-hydroxy-3-methoxyphenyl)acrylaldehyde; 4-ethyl-2-methoxyphenol; 5-methyl-5-phenylhexan-3-one; 4-(4-methoxyphenyl)butan-2-one; (E)-3-propylideneisobenzofuran-1(3H)-one; (Z)-dodec-2-enal; 3-methyl-5-phenylpentanal; 3-methyl-4-phenyl-1H-pyrazole; 3-methylcyclopentane-1,2-dione; 3-methoxy-5-methylphenol; 3-methoxy-3-methylbutan-1-ol; (E)-hex-3-en-1-ol; 3,7-dimethyl-2-methyleneoct-6-enal; 3,7-dimethyloctan-1-ol; (Z)-undec-2-enenitrile; (E)-undec-2-enal; phenethyl acetate; (Z)-3-(furan-2-yl)-2-phenylacrylaldehyde; phenethyl propionate; 2-pentylcyclopentan-1-ol; (2S,4S)-2-heptyl-2,4-dimethyl-1,3-dioxolane; nonan-2-ol; 2-(sec-butyl)-3-methoxypyrazine; 2-isopropyl-N,2,3-trimethylbutanamide; (E)-2-isopropyl-5-methylhex-2-enal; 2-isopropyl-4-methylthiazole; (E)-2-hexylidenecyclopentan-1-one; (E)-hex-2-en-1-ol; 2-butoxyethan-1-ol; (2E,6E)-nona-2,6-dien-1-ol; 1-isopropyl-4-methyl-7-oxabicyclo[2.2.1]heptane; 1,3,3-trimethylbicyclo[2.2.1]heptan-2-yl acetate; 1,1,2,3,3-pentamethyl-2,3-dihydro-1H-indene; (Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en-1-one; (Z)-6,10-dimethylundeca-5,9-dien-2-yl acetate; (Z)-hept-3-en-1-yl acetate; (1S,5S)-4,6,6-trimethylbicyclo[3.1.1]hept-3-en-2-one; (R)-3,7-dimethylocta-1,6-dien-3-ol; 3,7-dimethyloct-6-enal; (E)-6,10-dimethylundeca-5,9-dien-2-yl acetate; (R)-3,7-dimethyloct-6-enal; (2S,5S,6S)-2,6,10,10-tetramethyl-1-oxaspiro[4.5]decan-6-ol; 3,7-dimethyloct-6-en-1-ol; 3,7-dimethyloct-6-en-1-ol; (1R,5R)-2,6,6-trimethylbicyclo[3.1.1]hept-2-ene; (S)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-one; (1S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-2-ene; methyl 2-methylbutanoate; hexyl(Z)-2-methylbut-2-enoate; 2-(8-isopropyl-6-methylbicyclo[2.2.2]oct-5-en-2-yl)-1,3-dioxolane; 3-(3-isopropylphenyl)butanal; allyl 2-(cyclohexyloxy)acetate; 2-((3S,3aS,5R)-3,8-dimethyl-1,2,3,3a,4,5,6,7-octahydroazulen-5-yl)propan-2-ol; 1,5-dimethylbicyclo[3.2.1]octan-8-one oxime; benzyl 2-phenylacetate; 2-hydroxy-1,2-diphenylethan-1-one; (E)-tridec-2-enal; 1-phenylvinyl acetate; p-tolyl isobutyrate; p-tolyl hexanoate; p-cymene; 5-hexyl-4-methyldihydrofuran-2(3H)-one; 2-cyclohexylidene-2-phenylacetonitrile; 4-(prop-1-en-2-yl)cyclohex-1-ene-1-carbaldehyde; (4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)methyl acetate; (4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)methanol; (2-(cyclohexyloxy)ethyl)benzene; phenethyl 2-methylbutanoate; phenethyl formate; phenethyl isobutyrate; phenethyl 2-phenylacetate; phenethyl(Z)-2-methylbut-2-enoate; phenyl benzoate; phenethyl benzoate; phenethyl methacrylate; 2-(4-isopropylphenyl)acetaldehyde; 1,2-dimethyl-3-(prop-1-en-2-yl)cyclopentan-1-ol; 1-(4-methoxyphenyl)propan-2-one; (2Z,5Z)-5,6,7-trimethylocta-2,5-dien-4-one; 1-methoxy-4-propylbenzene; 2-(4-(tert-butyl)phenyl)acetaldehyde; 4-(tert-pentyl)cyclohexan-1-ol; p-tolyl 2-phenylacetate; Ethyl 2,4,7-decatrienoate; 2,6,6-trimethylbicyclo[3.1.1]hept-2-ene; 4-(4-hydroxyphenyl)butan-2-one; 2-benzyl-4,4,6-trimethyl-1,3-dioxane; 3,7-dimethyloct-7-en-1-ol; ethyl(2,3,6-trimethylcyclohexyl)carbonate; (Z)-6-ethylideneoctahydro-2H-5,8-methanochromene; 2-((S)-1-((S)-3,3-dimethylcyclohexyl)ethoxy)-2-oxoethyl propionate; methyl 2,2-dimethyl-6-methylenecyclohexane-1-carboxylate; 1-(3,3-dimethylcyclohexyl)ethyl acetate; (S)-3,7-dimethylocta-1,6-dien-3-ol; 1-isopropyl-4-methylenebicyclo[3.1.0]hexane; 5-isopropyl-2-methylbicyclo[3.1.0]hexan-2-ol; (1S,3R,5S)-1-isopropyl-4-methylenebicyclo[3.1.0]hexan-3-ol; 3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pentan-2-ol; 5-methoxyoctahydro-1H-4,7-methanoindene-2-carbaldehyde; propyl (S)-2-(tert-pentyloxy)propanoate; (4aR,8aR)-4a,8-dimethyl-2-(propan-2-ylidene)-1,2,3,4,4a,5,6,8a-octahydronaphthalene; 2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-methylpropyl cyclopropanecarboxylate; (1R,3R,6R)-2′,2′,3,7,7-pentamethylspiro[bicyclo[4.1.0]heptane-2,5′-[1,3]dioxanel; 1-oxaspiro(4,5)decan-2-one; (Z)-5-methylheptan-3-one oxime; 1-phenylethyl acetate; (1S,4S,4aR,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol; (1S,4S,4aR,8aS)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol; 3,7-dimethyloctanal; 4-(2,2,6-trimethylcyclohexyl)butan-2-ol; 3-methyl-2-pentylcyclopentan-1-one; 3,7-dimethyloctan-3-ol; 3,7-dimethyloctan-3-yl acetate; 2,6,10,10-tetramethyl-1-oxaspiro[4.5]dec-6-ene; ethyl(1R,6S)-2,2,6-trimethylcyclohexane-1-carboxylate; 2-isopropyl-5-methylphenol; 1-isopropyl-2-methoxy-4-methylbenzene; 1-(2,2,6-trimethylcyclohexyl)hexan-3-ol; (E)-hex-2-en-1-ol; (1R,2S)-2-(tert-butyl)cyclohexan-1-ol; (Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en-1-one; (Z)-oxacycloheptadec-8-en-2-one; (Z)-1-methoxy-4-(prop-1-en-1-yl)benzene; cinnamic acid; (2R,5R)-2-methyl-5-(prop-1-en-2-yl)cyclohexan-1-one; (E)-3,7-dimethylocta-2,6-dien-1-ol; (Z)-2-methoxy-4-(prop-1-en-1-yl)phenol; 2,2,2-trichloro-1-phenylethyl acetate; triethyl 2-hydroxypropane-1,2,3-tricarboxylate; methyl 2-((1-hydroxy-3-phenylbutyl)amino)benzoate; 1-((2E,5Z,9Z)-2,6,10-trimethylcyclododeca-2,5,9-trien-1-yl)ethan-1-one; 2-mercapto-2-methylpentan-1-ol; 13-methyl oxacyclopentadec-10-en-2-one; undecanal; (E)-4-methyldec-3-en-5-ol; (3R,4aS,5R)-4a,5-dimethyl-3-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,7-octahydronaphthalene; 4-formyl-2-methoxyphenyl acetate; 4-formyl-2-methoxyphenyl isobutyrate; (Z)-2-ethoxy-5-(prop-1-en-1-yl)phenol; 2,2,5-trimethyl-5-pentylcyclopentan-1-one; (Z)-2-methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-enal; 3,4-dimethoxybenzaldehyde; (1R,5R)-4,6,6-trimethylbicyclo[3.1.1]hept-3-en-2-one; 1-methoxy-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoindene; 2-(tert-butyl)cyclohexan-1-ol; cis-(4-tert-butylcyclohexyl) acetate; 4-(tert-butyl)cyclohexyl acetate; 2,4-diethoxy-5-methylpyrimidine; 4-methyl-4-phenylpentan-2-yl acetate; 4,8-dimethyl-2-(propan-2-ylidene)-1,2,3,3a,4,5,6,8a-octahydroazulen-6-ol; (Z)-cyclooct-4-en-1-yl methyl carbonate; (Z)-1-((2-methylallyl)oxy)hex-3-ene; 4-(4-hydroxy-3-methoxyphenyl)butan-2-one; (1R,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,7,8,8a-hexahydronaphthalene; 4,5-epoxy-4,11,11-trimethyl-8-methylenebicyclo(7.2.0)undecane; 1,3,4,6,7,8alpha-hexahydro-1,1,5,5-tetramethyl-2H-2,4alpha-methanophtalen-8(5H)-one preferably said malodor reduction materials are selected from the group consisting of 2-ethylhexyl(Z)-3-(4-methoxyphenyl)acrylate; 2,4-dimethyl-2-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-1,3-dioxolane; 1,1-dimethoxynon-2-yne; 2-(p-tolyl)propan-2-ol; 3-methoxy-7,7-dimethyl-10-methylenebicyclo[4.3.1]decane; methoxycyclododecane; 1,1-dimethoxycyclododecane; (Z)-tridec-2-enenitrile; (2-hydroxy-4-methoxyphenyl)(phenyl)methanone; 2,4a,5,8a-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-yl formate; 4-methyl-1-oxaspiro[5.5]undecan-4-ol; 7-methyl-2H-benzo[b][1,4]dioxepin-3(4H)-one; 1,8-dioxacycloheptadecan-9-one; 4-(tert-pentyl)cyclohexan-1-one; 2-methoxy-1,1′-biphenyl; 3a,5,6,7,8,8b-hexahydro-2,2,6,6,7,8,8-heptamethyl-4H-indeno(4,5-d)-1,3-dioxole; 7-isopropyl-8,8-dimethyl-6,10-dioxaspiro[4.5]decane; octyl furan-2-carboxylate; octyl acetate; 2-heptyl-4-methyl-1,3-dioxolane; octanal; 1,1-dimethoxyoctane; 7-methyl-3-methyleneocta-1,6-diene; 2-methyl-6-methyleneoct-7-en-2-ol; 2-methyl-6-methyleneoct-7-en-2-yl acetate; tetradecanal; 4-methoxy-6-prop-2-enyl-1,3-benzodioxole; tetradecanenitrile; 2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a-octahydronaphthalen-1-ol; (E)-2,6-dimethylocta-5,7-dien-2-ol; (E)-2,7-dimethylocta-1,5,7-trien-3-ol; 2-((1S,5R)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethyl acetate; (4R,4aS,6R)-4,4a-dimethyl-6-(prop-1-en-2-yl)-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one; nonan-1-ol; nonanal; 12-methyl-14-tetradec-9-enolide; N-ethyl-2-isopropyl-5-methylcyclohexane-1-carboxamide; 1-(3-methylbenzofuran-2-yl)ethan-1-one; 2-methoxynaphthalene; (E)-3,7,11-trimethyldodeca-1,6,10-trien-3-ol; (Z)-3,7-dimethylocta-2,6-dien-1-ol; 1-ethyl-3-methoxytricyclo[2.2.1.02,6]heptane; methyl(E)-non-2-enoate; 10-isopropyl-2,7-dimethyl-1-oxaspiro[4.5]deca-3,6-diene; 2-(2-(4-methylcyclohex-3-en-1-yl)propyl)cyclopentan-1-one; 6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde; (E)-4-(2,2,3,6-tetramethylcyclohexyl)but-3-en-2-one; (4-(4-methylpent-3-en-1-yl)cyclohex-3-en-1-yl)methyl acetate; 2-(tert-butyl)-4,5,6-trimethyl-1,3-phenylene dinitrite; 1,7-dioxacycloheptadecan-8-one; 1-(4-(tert-butyl)-2,6-dimethyl-3,5-dinitrophenyl)ethan-1-one; 1-(tert-butyl)-2-methoxy-4-methyl-3,5-dinitrobenzene; 3-methylcyclopentadecan-1-one; (E)-3-methylcyclopentadec-4-en-1-one; 3-methyl-4-phenylbutan-2-ol; 1-(4-isopropylcyclohexyl)ethan-1-ol; (E)-dec-5-enoic acid; methyl non-2-ynoate; 2-methyldecanal; 6,6-dimethoxy-2,5,5-trimethylhex-2-ene; 4-phenylbutan-2-ol; methyl stearate; 1,1-dimethoxy-2-methylundecane; undecan-2-one; 2-methylundecanal; methyl tetradecanoate; methyl(9Z,12Z)-octadeca-9,12-dienoate; 1-hydroxydecan-3-one; (Z)-1,2-dimethoxy-4-(prop-1-en-1-yl)benzene; methyl palmitate; 4-allyl-1,2-dimethoxybenzene; methyl 2-((1R,2R)-3-oxo-2-((Z)-pent-2-en-1-yl)cyclopentyl)acetate; methyl 2-(3-oxo-2-pentylcyclopentyl)acetate; 1-methyl-2-phenoxybenzene; methyl cinnamate; 1-allyl-4-methoxybenzene; 1-(naphthalen-2-yl)ethan-1-one; methyl oct-2-ynoate; methyl 2,6,6-trimethylcyclohex-2-ene-1-carboxylate; 7-methoxy-3,7-dimethyloctanal; 7-isopropyl-10-methyl-1,5-dioxaspiro[5.5]undecan-3-ol; octahydro-1H-4,7-methanoindene-1-carbaldehyde; 3-(3-(tert-butyl)phenyl)-2-methylpropanal; (E)-4-(4,8-dimethylnona-3,7-dien-1-yl)pyridine; (E)-trideca-3,12-dienenitrile; 2,2-dimethyl-3-(m-tolyl)propan-1-ol; 2,4-dimethyl-4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine; 8-isopropyl-6-methylbicyclo[2.2.2]oct-5-ene-2-carbaldehyde; 4-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1-carbaldehyde; (S)-1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene; (Z)-3-hexen-1-yl-2-cyclopenten-1-one; 3,7-dimethylocta-1,6-dien-3-yl octanoate; 3,7-dimethylocta-1,6-dien-3-yl isobutyrate; 3,7-dimethylocta-1,6-dien-3-yl benzoate; 3,7-dimethylocta-1,6-dien-3-yl 2-aminobenzoate; 2-(5-methyl-5-vinyltetrahydrofuran-2-yl)propan-2-ol; 6-methyl-2-(oxiran-2-yl)hept-5-en-2-ol; (2Z,6E)-3,7-dimethylnona-2,6-dienenitrile; 3-(4-methylcyclohex-3-en-1-yl)butanal; (2,5-dimethyl-1,3-dihydroinden-2-yl)methanol; 3-(4-(tert-butyl)phenyl)-2-methylpropanal; (E)-1-(1-methoxypropoxy)hex-3-ene; (E)-1-(1-ethoxyethoxy)hex-3-ene; (1S,5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-ol; dodecan-1-ol; dodecyl acetate; dodecanoic acid; 5-hexyl-5-methyldihydrofuran-2(3H)-one; dodecanal; 3,6-dimethylhexahydrobenzofuran-2(3H)-one; 4-(1-ethoxyvinyl)-3,3,5,5-tetramethylcyclohexan-1-one; ((3S,3aR,6R,8aS)-7,7-dimethyl-8-methyleneoctahydro-1H-3a,6-methanoazulen-3-yl)methanol; 5-(sec-butyl)-2-(2,4-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane; (1-methyl-2-((1,2,2-trimethylbicyclo[3.1.0]hexan-3-yl)methyl)cyclopropyl)methanol; 2-propylheptanenitrile; (E)-6-(pent-3-en-1-yl)tetrahydro-2H-pyran-2-one; 2-hexylcyclopentan-1-one; 2-methyl-4-phenyl-1,3-dioxolane; 2,6,9,10-tetramethyl-1-oxaspiro(4.5)deca-3,6-diene; (1R,2S,5R)-5-methyl-2-(prop-1-en-2-yl)cyclohexan-1-ol; isopropyl palmitate; isopropyl tetradecanoate; isopropyl dodecanoate; 4,9-dimethoxy-7H-furo[3,2-g]chromen-7-one; (E)-cyclohexadec-8-en-1-one; (2S,5S)-2-isopropyl-5-methylcyclohexan-1-one; 2-hexylcyclopent-2-en-1-one; (2S,5S)-2-isopropyl-5-methylcyclohexan-1-one; 4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde; (Z)-1-(benzyloxy)-2-methoxy-4-(prop-1-en-1-yl)benzene; 1-((2S,3S)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yl)ethan-1-one; 2,5,6-trimethylcyclohex-3-ene-1-carbaldehyde; 6-(sec-butyl)quinoline; 2-(cyclohexyloxy)-1,7,7-trimethylbicyclo[2.2.1]heptane; (1R,2R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl propionate; (1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate; 4-((2R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)cyclohexan-1-ol; (1R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl acetate; 2-(4-isopropylcyclohexa-1,4-dien-1-yl)ethyl formate; isopentyl(E)-undec-6-enoate; isopentyl dodecanoate; (E)-oxacycloheptadec-10-en-2-one; (E)-non-2-enenitrile; (E)-8-(1H-indol-1-yl)-2,6-dimethyloct-7-en-2-ol; 8,8-di(1H-indol-1-yl)-2,6-dimethyloctan-2-ol; 4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine; 3,7-dimethyloctane-1,7-diol; 2-cyclododecylpropan-1-ol; 3-methyl-5-phenylpentanenitrile; 3-phenylpropan-1-ol; (1,1-dimethoxypropan-2-yl)benzene; 5-ethyl-4-hydroxy-2-methylfuran-3(2H)-one; 2,3-dihydro-3,3-dimethyl-1H-indene-5-propanal; 3-(3,3-dimethyl-2,3-dihydro-1H-inden-5-yl)propanal; hexyl octanoate; hexyl hexanoate; (Z)-2-benzylideneoctanal; hexyl benzoate; (Z)-hex-1-en-1-yl(Z)-2-methylbut-2-enoate; (E)-3,7-dimethylocta-2,6-dien-1-yl palmitate; oxacycloheptadecan-2-one; 2-butyl-4,4,6-trimethyl-1,3-dioxane; ethyl(1R,2R,3R,4R)-3-isopropylbicyclo[2.2.1]hept-5-ene-2-carboxylate; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl acetate; 2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-methylpropyl propionate; 5-(diethoxymethyl)benzo[d][1,3]dioxole; 3-(benzo[d][1,3]dioxol-5-yl)-2-methylpropanal; (E)-oxacyclohexadec-13-en-2-one; 6-butyl-2,4-dimethyl-3,6-dihydro-2H-pyran; 2-((3S,5R,8S)-3,8-dimethyl-1,2,3,4,5,6,7,8-octahydroazulen-5-yl)propan-2-ol; 1-(2,6,6-trimethylcyclohex-2-en-1-yl)pentan-3-one; ethyl 2-ethyl-6,6-dimethylcyclohex-2-ene-1-carboxylate; (1Z,5Z)-1,5-dimethyl-8-(propan-2-ylidene)cyclodeca-1,5-diene; (1E,6E)-8-isopropyl-1-methyl-5-methylenecyclodeca-1,6-diene; (E)-3,7-dimethylocta-2,6-dien-1-yl 2-phenylacetate; (E)-3,7-dimethylocta-2,6-dien-1-yl 2-phenylacetate; (6E,10E)-3,7,11,15-tetramethylhexadeca-1,6,10,14-tetraen-3-ol; (E)-2-(3,7-dimethylocta-2,6-dien-1-yl)cyclopentan-1-one; 5-heptyldihydrofuran-2(3H)-one; 1-methyl-4-(propan-2-ylidene)cyclohexyl acetate; 1-methyl-4-(propan-2-ylidene)cyclohexan-1-ol; 5-pentyldihydrofuran-2(3H)-one; (1R,4aR,8aS)-1-isopropyl-7-methyl-4-methylene-1,2,3,4,4a,5,6,8a-octahydronaphthalene; 5-[(Z)-hex-3-enyl]oxolan-2-one; (Z)-4-(2,2-dimethyl-6-methylenecyclohexyl)but-3-en-2-one; (4aS,9aR)-3,5,5,9-tetramethyl-2,4a,5,6,7,9a-hexahydro-1H-benzo[7]annulene; (1R,3aR,4R,7R)-1,4-dimethyl-7-(prop-1-en-2-yl)-1,2,3,3a,4,5,6,7-octahydroazulene; 2-((2R,4aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-yl)propan-2-ol; 5-octyldihydrofuran-2(3H)-one; (Z)-1-(2,2-dimethyl-6-methylenecyclohexyl)but-2-en-1-one; 5-hexyldihydrofuran-2(3H)-one; (1R,4aS,8aS)-1-isopropyl-7-methyl-4-methylene-1,2,3,4,4a,5,6,8a-octahydronaphthalene; 1-(3,3-dimethylcyclohexyl)pent-4-en-1-one; 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopenta[g]isochromene; furan-2-ylmethyl octanoate; furan-2-ylmethyl hexanoate; furan-2-ylmethyl heptanoate; 2-methyldecanenitrile; 8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl propionate; ethyl(3aR,4S,7R,7aR)-octahydro-3aH-4,7-methanoindene-3a-carboxylate; diethyl cyclohexane-1,4-dicarboxylate; (6-isopropyl-9-methyl-1,4-dioxaspiro[4.5]decan-2-yl)methanol; 2-isobutyl-4-methyltetrahydro-2H-pyran-4-ol; undec-10-enenitrile; (Z)-6-ethylideneoctahydro-2H-5,8-methanochromen-2-one; 3-(2-ethylphenyl)-2,2-dimethylpropanal; (E)-4,8-dimethyldeca-4,9-dienal; (E)-4-((3aR,4R,7R,7aR)-1,3a,4,6,7,7a-hexahydro-5H-4,7-methanoinden-5-ylidene)-3-methylbutan-2-ol; 8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl acetate; 3-(4-ethylphenyl)-2,2-dimethylpropanenitrile; 2-heptylcyclopentan-1-one; 1-ethoxyethoxy Cyclododecane; 3-cyclohexene-1-carboxylic acid, 2,6,6-trimethyl-, methyl ester; (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-yl acetate; (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol; oxacyclohexadecan-2-one; (E)-cyclopentadec-4-en-1-one; 1-cyclopentadec-4-en-1-one; 2-methoxy-4-(4-methylenetetrahydro-2H-pyran-2-yl)phenol; 4-allyl-2-methoxyphenyl acetate; 4-allyl-2-methoxyphenol; ethyl 3-methyl-3-phenyloxirane-2-carboxylate; 1,4-dioxacycloheptadecane-5,17-dione; ethyl undec-10-enoate; ethyl palmitate; ethyl nonanoate; ethyl tetradecanoate; (E)-3,7-dimethylnona-1,6-dien-3-ol; ethyl dodecanoate; nonan-3-one; ethyl decanoate; ethyl 6,6-dimethyl-2-methylenecyclohex-3-ene-1-carboxylate; ethyl 3-phenyloxirane-2-carboxylate; 6-ethyl-2,10,10-trimethyl-1-oxaspiro[4.5]deca-3,6-diene; 2-((1R,3S,4S)-4-methyl-3-(prop-1-en-2-yl)-4-vinylcyclohexyl)propan-2-ol; (2-(1-ethoxyethoxy)ethyl)benzene; (E)-3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol; (2R,3S,4R)-2,3,4,5-tetrahydroxypentanal; (E)-4-((3aS,7aS)-octahydro-5H-4,7-methanoinden-5-ylidene)butanal; 1,1-dimethoxydodecane; (R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene; 2-(2-hydroxypropoxy)propan-1-ol; 7,9-dimethylspiro[5.5]undecan-3-one; oxydibenzene; diphenylmethane; 2-methyl-1-phenylpropan-2-yl butyrate; 2,6-dimethyloct-7-en-4-one; octahydro-1H-4,7-methanoinden-5-yl acetate; 2-methyl-5-(prop-1-en-2-yl)cyclohexyl acetate; 2-methyl-5-(prop-1-en-2-yl)cyclohexan-1-ol; 3,7-dimethyloct-6-en-3-ol; methyl 2-hexyl-3-oxocyclopentane-1-carboxylate; dibutylsulfane; 1,2-diphenylethane; 6-hexyltetrahydro-2H-pyran-2-one; (3R,4R)-1-isopropyl-4-methyl-3-(prop-1-en-2-yl)-4-vinylcyclohex-1-ene; (3S,3aS,5R)-3,8-dimethyl-5-(prop-1-en-2-yl)-1,2,3,3a,4,5,6,7-octahydroazulene; 6-heptyltetrahydro-2H-pyran-2-one; 6-pentyltetrahydro-2H-pyran-2-one; (1S,8aR)-4,7-dimethyl-1-(propan-2-yl)-1,2,3,5,6,8a-hexahydronaphthalene; (Z)-1-((1R,2S)-2,6,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one; (1S,8aS)-1-isopropyl-4,7-dimethyl-1,2,3,5,6,8a-hexahydronaphthalene; 3,7,7-trimethylbicyclo[4.1.0]hept-3-ene; dec-9-en-1-ol; decyl propionate; 1,1-diethoxydecane; decahydronaphthalen-2-ol; 1-cyclohexylethyl(E)-but-2-enoate; 3-(4-isopropylphenyl)-2-methylpropanal; cyclotetradecane; cyclopentadecanone; cyclohexyl 2-hydroxybenzoate; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl butyrate; 1,4-dioxacyclohexadecane-5,16-dione; 8,8-dimethyl-1,2,3,4,5,6,7,8-octahydronaphthalene-2-carbaldehyde; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-5-yl isobutyrate; (5R,6R)-3,6-dimethyl-5-(prop-1-en-2-yl)-6-vinyl-4,5,6,7-tetrahydrobenzofuran; (4-isopropylphenyl)methanol; 1-(benzofuran-2-yl)ethan-1-one; 2-(3-phenylpropyl)pyridine; dodecanenitrile; (E)-cycloheptadec-9-en-1-one; 3-(4-methylcyclohex-3-en-1-yl)but-3-en-1-yl acetate; 3-(4-methylcyclohex-3-en-1-yl)butan-1-ol; (E)-3-methyl-5-phenylpent-2-enenitrile; (E)-2-(2,6-dimethylhepta-1,5-dien-1-yl)-4-methyl-1,3-dioxolane; (E)-1,1-dimethoxy-3,7-dimethylocta-2,6-diene; (E)-1,1-diethoxy-3,7-dimethylocta-2,6-diene; (E)-3,7-dimethylocta-1,3,6-triene; (1R,4R,6S)-1-methyl-4-(prop-1-en-2-yl)-7-oxabicyclo[4.1.0]heptane; (E)-oxacycloheptadec-11-en-2-one; (Z)-non-6-en-1-ol; (1R,5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-ol; (Z)-dec-4-enal; (E)-hex-3-en-1-yl(E)-hex-3-enoate; (Z)-hex-3-en-1-yl 2-hydroxybenzoate; (Z)-hex-3-en-1-yl benzoate; (Z)-hex-3-en-1-yl 2-methylbutanoate; (3Z,6Z)-nona-3,6-dien-1-ol; cinnamyl propionate; cinnamyl isobutyrate; cinnamyl formate; cinnamyl cinnamate; cinnamyl acetate; (E)-3-phenylprop-2-en-1-ol; hexadecan-1-ol; (E)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)hepta-1,6-dien-3-one; 2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)butanal; (3aR,5aR,9aR,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan; 1,6-dioxacycloheptadecan-7-one; 1-(6-(tert-butyl)-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl)ethan-1-one; (3R,3aR,6S,7S,8aS)-6-methoxy-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulene; (3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-3-yl formate; (3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-yl acetate; (4Z,8Z)-1,5,9-trimethyl-13-oxabicyclo[10.1.0]trideca-4,8-diene; (3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-ol; 5-methyl-1-(2,2,3-trimethylcyclopent-3-en-1-yl)-6-oxabicyclo[3.2.1]octane; 5-methyl-1-(2,2,3-trimethylcyclopent-3-en-1-yl)-6-oxabicyclo[3.2.1]octane; 1,1,2,3,3-pentamethyl-1,2,3,5,6,7-hexahydro-4H-inden-4-one; (Z)-4,11,11-trimethyl-8-methylenebicyclo[7.2.0]undec-3-en-5-yl acetate; (1S,2S,5R,8S)-4,4,8-trimethyltricyclo[6.3.1.02,5]dodecan-1-ol; 2-methyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-yl acetate; octanenitrile; octan-1-ol; octanoic acid; decanoic acid; decanal; 3-(4-methoxyphenyl)-2-methylpropanal; 1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione; 2,2-dimethyl-3-methylenebicyclo[2.2.1]heptane; ethyl 2-methyl-4-oxo-6-pentylcyclohex-2-ene-1-carboxylate; 2,6-di-tert-butyl-4-methylphenol; butyl stearate; 1-butoxy-1-oxopropan-2-yl butyrate; butyl undec-10-enoate; 2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)butan-1-ol; 3-(4-(tert-butyl)phenyl)propanal; (1S,2S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate; 1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl acetate; 2-ethoxy-2,6,6-trimethyl-9-methylenebicyclo[3.3.1]nonane; (ethoxymethoxy)cyclododecane; (E)-1-methyl-4-(6-methylhept-5-en-2-ylidene)cyclohex-1-ene; 3,3,6,7-tetramethyloctahydro-2H-chromene; (5R,10R)-6,10-dimethyl-2-(propan-2-ylidene)spiro[4.5]dec-6-en-8-one; 1-methyl-4-(prop-1-en-2-yl)cyclohexyl acetate; 1-methyl-4-(prop-1-en-2-yl)cyclohexan-1-ol; (2Z,6E)-2,6-dimethyl-10-methylenedodeca-2,6,11-trienal; (R)-3-methylene-6-((S)-6-methylhept-5-en-2-yl)cyclohex-1-ene; (4aR,7R,8aS)-4a-methyl-1-methylene-7-(prop-1-en-2-yl)decahydronaphthalene; (Z)-2-methyl-5-((1S,2R,4R)-2-methyl-3-methylenebicyclo[2.2.1]heptan-2-yl)pent-2-en-1-ol; 6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane; 2-ethoxynaphthalene; (1S,4R,7R)-1,4,9,9-tetramethyl-1,2,3,4,5,6,7,8-octahydro-4,7-methanoazulene; (1aS,5aR,9aR)-1a,5,5,7-tetramethyl-1a,2,3,4,5,5a,8,9-octahydrobenzo[1,7]cyclohepta[1,2-b]oxirene; (R)-3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzo[7]annulene; (1S,4S)-1,4-dimethyl-7-(propan-2-ylidene)-1,2,3,4,5,6,7,8-octahydroazulene; (2,2-dimethoxyethyl)benzene; (E)-7,11-dimethyl-3-methylenedodeca-1,6,10-triene; (1R,2S,6S,7S,8S)-8-isopropyl-1-methyl-3-methylenetricyclo[4.4.0.02,7]decane; (3R,3aS,7S,8aS)-3,8,8-trimethyl-6-methyleneoctahydro-1H-3a,7-methanoazulene; (1R,9S,Z)-4,11,11-trimethyl-8-methylenebicyclo[7.2.0]undec-4-ene; (S)-4-methyl-1-((S)-6-methylhept-5-en-2-yl)cyclohex-3-en-1-ol; (Z)-4-(2,2,6-trimethyl-7-oxabicyclo[4.1.0]heptan-1-yl)but-3-en-2-one; 4-methoxy-7H-furo[3,2-g]chromen-7-one; 2-methyl-4-phenylbutan-2-ol; benzyl dodecanoate; 2-methyl-1-phenylpropan-2-ol; benzyl cinnamate; benzyl benzoate; benzophenone; 7-isopentyl-2H-benzo[b][1,4]dioxepin-3(4H)-one; 2′-isopropyl-1,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,4′-[1,3]dioxane]/A; 4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbonitrile; methyl(E)-2-((7-hydroxy-3,7-dimethyloctylidene)amino)benzoate; 4-methoxybenzyl 2-phenylacetate; methyl(E)-octa-4,7-dienoate; pentyl(Z)-3-phenylacrylate; (3aR,5aS,9aS,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan; (4aR,5R,7aS,9R)-2,2,5,8,8,9a-hexamethyloctahydro-4H-4a,9-methanoazuleno[5,6-d][1,3]dioxole; 2,5,5-trimethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-ol; 2,5,5-trimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-ol; 1-((2-(tert-butyl)cyclohexyl)oxy)butan-2-ol; (3S,5aR,7aS,11aS,11bR)-3,8,8,11a-tetramethyldodecahydro-5H-3,5a-epoxynaphtho[2,1-c]oxepine; 2,2,6,6,7,8,8-heptamethyldecahydro-2H-indeno[4,5-b]furan; 2,2,7,7,8,9,9-heptamethyldecahydroindeno[4,3a-b]furan; 2-(sec-butyl)-1-vinylcyclohexyl acetate; (1S,4R,5R)-1-isopropyl-4-methylbicyclo[3.1.0]hexan-3-one; (4R,4aS)-4,4a-dimethyl-6-(propan-2-ylidene)-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one; 2-(4-methylcyclohex-3-en-1-yl)propan-2-yl propionate; (2Z,6E,9E)-2,6,10-trimethyldodeca-2,6,9,11-tetraenal; (2R,4aR,8aR)-4a,8-dimethyl-2-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,8a-octahydronaphthalene; 1,7-dimethyl-7-(4-methylpent-3-en-1-yl)tricyclo[2.2.1.02,6]heptane; (E)-5-(2,3-dimethyltricyclo[2.2.1.02,6]heptan-3-yl)-2-methylpent-2-en-1-ol; (1R,3aS,7S,8aR)-1,4,9,9-tetramethyl-2,3,6,7,8,8a-hexahydro-1H-3a,7-methanoazulene; 1-(5,5-dimethylcyclohex-1-en-1-yl)pent-4-en-1-one; (1S,4aS,8aR)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene; (R,Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)pent-1-en-3-one; 1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene; (Z)-4-(2,5,6,6-tetramethylcyclohex-2-en-1-yl)but-3-en-2-one; (1Z,4E,8Z)-2,6,6,9-tetramethylcycloundeca-1,4,8-triene; (4aR,8S,9aS)-3,5,5,8-tetramethyl-9-methylene-2,4a,5,6,7,8,9,9a-octahydro-1H-benzo[7]annulene; (1aR,4R,4aR,7bS)-1,1,4,7-tetramethyl-1a,2,3,4,4a,5,6,7b-octahydro-1H-cyclopropa[e]azulene; 1,4-dimethyl-7-(prop-1-en-2-yl)-1,2,3,4,5,6,7,8-octahydroazulene; (3E,6E)-3,7,11-trimethyldodeca-1,3,6,10-tetraene; 7,7-dimethyl-2-methylenebicyclo[2.2.1]heptane; 2-((2R,4aR,8aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)propan-2-ol; (R)-1-methyl-4-(6-methylhept-5-en-2-yl)benzene; (3aR,3bR,4S,7R,7aS)-4-isopropyl-7-methyl-3a,3b,4,5,6,7-hexahydro-1H-cyclopenta[1,3]cyclopropa[1,2]benzene; (1aS,2aR,3R,5aS,7R,7aR)-3,6,6,7a-tetramethyloctahydro-2H-2a,7-methanoazuleno[5,6-b]oxirene; (1R,4S,4aR,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol; (1S,4aR,8aR)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene; (R)-2-((R)-4-methylcyclohex-3-en-1-yl)hex-5-en-2-ol; (Z)-1-methyl-4-(6-methylhepta-2,5-dien-2-yl)cyclohex-1-ene; 2,6-dimethyl-6-(4-methylpent-3-en-1-yl)bicyclo[3.1.1]hept-2-ene; (E)-2-benzylideneheptan-1-ol; (E)-2-benzylideneheptyl acetate; (Z)-(2-(diethoxymethyl)hept-1-en-1-yl)benzene; (E)-2-benzylideneheptanal; (1S,4aR,8aS)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene; (3R,5aS,9aR)-2,2,5a,9-tetramethyl-3,4,5,5a,6,7-hexahydro-2H-3,9a-methanobenzo[b]oxepine; 1-methyl-4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde; 1-phenylpentan-2-ol; 3-methyl-1-phenylpentan-3-ol; 2,3,4-trimethoxybenzaldehyde; 2,4,5-trimethoxybenzaldehyde; 2,4,6-trimethoxybenzaldehyde; Trans,Trans-2,4-Nonadienal; 2,6,10-trimethylundecanal; alpha-4-Dimethyl benzenepropanal; allyl 3-cyclohexylpropanoate; allyl 2-(isopentyloxy)acetate; (1aR,4aS,7R,7aR,7bS)-1,1,7-trimethyl-4-methylenedecahydro-1H-cyclopropa[e]azulene; (E)-undec-9-enal; methyl(E)-2-(((3,5-dimethylcyclohex-3-en-1-yl)methylene)amino)benzoate; 2,6,10-trimethylundec-9-enal; (7,7,8,8-tetramethyloctahydro-2,3b-methanocyclopenta[1,3]cyclopropa[1,2]benzen-4-yl)methyl acetate; nonyl acetate; (2-(1-propoxyethoxy)ethyl)benzene; 1-(1-propoxyethoxy)propane; ((1-(2-methoxyethoxy)ethoxy)methyl)benzene; (Z)-2-(4-methylbenzylidene)heptanal; dec-9-enal; (Z)-oxacycloheptadec-8-en-2-one; 7-methoxy-2H-chromen-2-one; (2S,4aR,8aR)-4a,8-dimethyl-2-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,8a-octahydronaphthalene; 2-((2S,4aR,8aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)propan-2-ol; 1-(3,5,5,6,8,8-hexamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)ethan-1-one; 6-isopropylquinoline; 3-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal; 6,10,14-trimethylpentadecan-2-one; 2-methyl-5-(prop-1-en-2-yl)-2-vinyltetrahydrofuran; (E)-cyclohexadec-5-en-1-one; 1-isopropyl-4-methylcyclohex-3-en-1-ol; 1-phenylpent-4-en-1-one; 1-isopropyl-4-methylcyclohex-3-en-1-ol; 3,6-dimethyl-4,5,6,7-tetrahydrobenzofuran; 4-(4-methoxyphenyl)butan-2-one; (1aR,2S,4aS)-2,4a,8,8-tetramethyloctahydrocyclopropa[d]naphthalen-3(1H)-one; (E)-3-propylideneisobenzofuran-1(3H)-one; (Z)-dodec-2-enal; 3-methyl-5-phenylpentanal; (E)-hex-3-en-1-yl 3-methylbutanoate; 3,6-dimethyloctan-3-yl acetate; 3,4,5-trimethoxybenzaldehyde; 3-(4-isopropylphenyl)propanal; (Z)-undec-2-enenitrile; (E)-undec-2-enal; (2E,6E)-nona-2,6-dienal; phenethyl butyrate; (Z)-3-(furan-2-yl)-2-phenylacrylaldehyde; 2-phenoxyethan-1-ol; (Z)-non-2-enal; nonan-2-ol; nonan-2-one; 2-isobutylquinoline; (E)-2-hexylidenecyclopentan-1-one; 2-heptyltetrahydrofuran; (E)-dec-2-enal; (2E,6E)-nona-2,6-dienal; (2E,6E)-nona-2,6-dien-1-ol; 2,6-dimethyloctanal; decan-1-ol; (E)-hept-1-en-1-yl acetate; undec-10-en-1-ol; undec-10-enal; 2-((2R,4aS)-4a,8-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-yl)propan-2-ol; 1-isopropyl-4-methyl-7-thiabicyclo[2.2.1]heptane; (3E,5Z)-undeca-1,3,5-triene; 3,7-dimethyloct-6-en-3-ol; 1,3,3-trimethylbicyclo[2.2.1]heptan-2-yl acetate; 1,1,2,3,3-pentamethyl-2,3-dihydro-1H-indene; (Z)-6,10-dimethylundeca-5,9-dien-2-yl acetate; (Z)-dodec-3-enal; (S)-5-heptyldihydrofuran-2(3H)-one; (R)-5-heptyldihydrofuran-2(3H)-one; (E)-6,10-dimethylundeca-5,9-dien-2-yl acetate; (Z)-3-methyl-5-phenylpent-2-enenitrile; (2S,5S,6S)-2,6,10,10-tetramethyl-1-oxaspiro[4.5]decan-6-ol; (2E)-3-methyl-5-phenyl-2-pentenenitrile; (1S,2S,5S)-2-methyl-5-(prop-1-en-2-yl)cyclohexan-1-ol; (2S,5R)-2-isopropyl-5-methylcyclohexan-1-one; (R,E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol; 2-(8-isopropyl-6-methylbicyclo[2.2.2]oct-5-en-2-yl)-1,3-dioxolane; (E)-4-(2,2-dimethyl-6-methylenecyclohexyl)-3-methylbut-3-en-2-one; 3-(3-isopropylphenyl)butanal; 3-(1-ethoxyethoxy)-3,7-dimethylocta-1,6-diene; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl propionate; 2-((3S,3aS,5R)-3,8-dimethyl-1,2,3,3a,4,5,6,7-octahydroazulen-5-yl)propan-2-ol; benzyl 2-phenylacetate; 2-hydroxy-1,2-diphenylethan-1-one; (E)-1,2,4-trimethoxy-5-(prop-1-en-1-yl)benzene; 3-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2,2-dimethylpropanal; 2-methyl-5-(6-methylhept-5-en-2-yl)bicyclo[3.1.0]hex-2-ene; 1-(1,1,2,3,3,6-hexamethyl-2,3-dihydro-1H-inden-5-yl)ethan-1-one; 2-(m-tolyl)ethan-1-ol; (3E,6E)-nona-3,6-dien-1-ol; (E)-tridec-2-enal; (1R,4S,4aS,6R,8aS)-4,8a,9,9-tetramethyloctahydro-1,6-methanonaphthalen-1(2H)-ol; p-tolyl isobutyrate; p-tolyl hexanoate; 5-hexyl-4-methyldihydrofuran-2(3H)-one; ethyl(2Z,4E)-deca-2,4-dienoate; 2,4-dimethyl-6-phenyl-3,6-dihydro-2H-pyran; 2-cyclohexylidene-2-phenylacetonitrile; 4-(prop-1-en-2-yl)cyclohex-1-ene-1-carbaldehyde; (4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)methyl acetate; (4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)methanol; (2-isopropoxyethyl)benzene; 2-cyclohexylhepta-1,6-dien-3-one; (2-(cyclohexyloxy)ethyl)benzene; phenethyl 2-methylbutanoate; 2-phenylethan-1-ol; phenethyl 2-phenylacetate; 3-methyl-5-phenylpentan-1-ol; phenyl benzoate; phenethyl benzoate; 2-benzyl-1,3-dioxolane; 2-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acetaldehyde; 6,6-dimethyl-2-methylenebicyclo[3.1.1]heptan-3-ol; 4-(benzo[d][1,3]dioxol-5-yl)butan-2-one; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl pivalate; (4aR,8aS)-7-methyloctahydro-1,4-methanonaphthalen-6(2H)-one; 4-isopropyl-1-methylcyclohex-3-en-1-ol; (E)-3,3-dimethyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol; 1-methyl-4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde; propane-1,2-diol; p-tolyl 2-phenylacetate; Ethyl 2,4,7-decatrienoate; 2-benzyl-4,4,6-trimethyl-1,3-dioxane; 2,4-dimethyl-4-phenyltetrahydrofuran; (2R,4a′R,8a′R)-3,7′-dimethyl-3′,4′,4a′,5′,8′,8a′-hexahydro-1′H-spiro[oxirane-2,2′-[1,4]methanonaphthalene]; (Z)-6-ethylideneoctahydro-2H-5,8-methanochromene; 2-((S)-1-((S)-3,3-dimethylcyclohexyl)ethoxy)-2-oxoethyl propionate; methyl 2,2-dimethyl-6-methylenecyclohexane-1-carboxylate; 2-methyl-5-phenylpentan-1-ol; 4-methyl-2-phenyl-3,6-dihydro-2H-pyran; (1S,3R,5S)-1-isopropyl-4-methylenebicyclo[3.1.0]hexan-3-ol; 5-allylbenzo[d][1,3]dioxole; 2,2,7,9-tetramethylspiro(5.5)undec-8-en-1-one; 3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pentan-2-ol; (Z)-2-ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol; (E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol; 5-methoxyoctahydro-1H-4,7-methanoindene-2-carbaldehyde; 5-methoxyoctahydro-1H-4,7-methanoindene-2-carbaldehyde; 1-(3-hydroxy-3-methylpent-4-en-1-yl)-2,5,5,8a-tetramethyldecahydronaphthalen-2-ol; (4aR,6aS,10aS,10bR)-3,4a,7,7,10a-pentamethyl-4a,5,6,6a,7,8,9,10,10a,10b-decahydro-1H-benzo[f]chromene; (4aR,8aR)-4a,8-dimethyl-2-(propan-2-ylidene)-1,2,3,4,4a,5,6,8a-octahydronaphthalene; 2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-methylpropyl cyclopropanecarboxylate; 3-(4-isobutylphenyl)-2-methylpropanal; (1aR,4aR,7S,7aR,7bR)-1,1,7-trimethyl-4-methylenedecahydro-1H-cyclopropa[e]azulen-7-ol; (1R,3R,6R)-2′,2′,3,7,7-pentamethylspiro[bicyclo[4.1.0]heptane-2,5′-[1,3]dioxane]; 2-methyl-1,5-dioxaspiro[5.5]undecane; 1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-1-one; 2-(4-methylthiazol-5-yl)ethan-1-ol; 2-(heptan-3-yl)-1,3-dioxolane; (Z)-dodec-4-enal; (1S,4S,4aR,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol; (1S,4S,4aR,8aS)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol; 3-methyl-2-pentylcyclopentan-1-one; 2,6,10,10-tetramethyl-1-oxaspiro[4.5]dec-6-ene; 2-(2-mercaptopropan-2-yl)-5-methylcyclohexan-1-one; (1aR,4aS)-2,4a,8,8-tetramethyl-1,1a,4,4a,5,6,7,8-octahydrocyclopropa[d]naphthalene; 1-isopropyl-2-methoxy-4-methylbenzene; 1-(2,2,6-trimethylcyclohexyl)hexan-3-ol; (2Z,4E)-nona-2,4-dienal; (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol; (2E,6Z)-nona-2,6-dienal; (Z)-dec-2-enal; (E)-non-2-enal; (3E,6Z)-nona-3,6-dien-1-ol; (E)-dec-4-enal; (Z)-oxacycloheptadec-8-en-2-one; (Z)-3,7-dimethylocta-1,3,6-triene; (Z)-3,7-dimethylocta-1,3,6-triene; (E)-3,7-dimethylocta-2,6-dien-1-ol; methyl 2-((1S,2S)-3-oxo-2-pentylcyclopentyl)acetate; 7-(1,1-Dimethylethyl)-2H-1,5-benzodioxepin-3(4H)-one; (1R-(1alpha,3alpha,4aalpha))-2,3,4,4a,5,6-hexahydro-2,2-dimethyl-1,3-methanonaphthalen-7(1H)-one; tridecan-1-ol; triethyl 2-hydroxypropane-1,2,3-tricarboxylate; methyl 2-((1-hydroxy-3-phenylbutyl)amino)benzoate; 1-((2E,5Z,9Z)-2,6,10-trimethylcyclododeca-2,5,9-trien-1-yl)ethan-1-one; decahydro-2,6,6,7,8,8-hexamethyl-2h-indeno(4,5-b)furan; 13-methyl oxacyclopentadec-10-en-2-one; undecanal; (E)-4-methyldec-3-en-5-ol; (3R,4aS,5R)-4a,5-dimethyl-3-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,7-octahydronaphthalene; 2-((2R,8R,8aS)-8,8a-dimethyl-1,2,3,4,6,7,8,8a-octahydronaphthalen-2-yl)propan-2-ol; 4-formyl-2-methoxyphenyl isobutyrate; (Z)-2-methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-enal; methyl 2,4-dihydroxy-3,6-dimethylbenzoate; 1-methoxy-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoindene; methyl(Z)-2-((3-(4-(tert-butyl)phenyl)-2-methylpropylidene)amino)benzoate; (Z)-hex-3-en-1-yl isobutyrate; 2,4,6-trimethyl-4-phenyl-1,3-dioxane; 1-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-methanoazulen-5-yl)ethan-1-one; methyl(Z)-2-(((2,4-dimethylcyclohex-3-en-1-yl)methylene)amino)benzoate; 4,8-dimethyl-2-(propan-2-ylidene)-1,2,3,3a,4,5,6,8a-octahydroazulen-6-ol; 4,8-dimethyl-2-(propan-2-ylidene)-1,2,3,3a,4,5,6,8a-octahydroazulen-6-yl acetate; decahydro-3H-spiro[furan-2,5′-[4,7]methanoindene]; (2Z,6E)-nona-2,6-dienenitrile; (Z)-cyclooct-4-en-1-yl methyl carbonate; (1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7-tetramethyldecahydro-1H-cyclopropa[e]azulen-4-ol; 3,5,5,6,7,8,8-heptamethyl-5,6,7,8-tetrahydronaphthalene-2-carbonitrile; (1S,2S,3S,5R)-2,6,6-trimethylspiro[bicyclo[3.1.1]heptane-3,1′-cyclohexan]-2′-en-4′-one; 1′,1′,5′,5′-tetramethylhexahydro-2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene]; (2′S,4a′S,8a′S)-1′,1′,5′,5′-tetramethylhexahydro-2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene]; 4-(4-hydroxy-3-methoxyphenyl)butan-2-one; (1R,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,7,8,8a-hexahydronaphthalene; 2,4-dimethyl-2-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-1,3-dioxolane; 3a,5,6,7,8,8b-hexahydro-2,2,6,6,7,8,8-heptamethyl-4H-indeno(4,5-d)-1,3-dioxole; 2,4-dimethyl-4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine; (1-methyl-2-((1,2,2-trimethylbicyclo[3.1.0]hexan-3-yl)methyl)cyclopropyl)methanol; 2-(cyclohexyloxy)-1,7,7-trimethylbicyclo[2.2.1]heptane; 4-((2R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)cyclohexan-1-ol; 8,8-di(1H-indol-1-yl)-2,6-dimethyloctan-2-ol; (7,7,8,8-tetramethyloctahydro-2,3b-methanocyclopenta[1,3]cyclopropa[1,2]benzen-4-yl)methanol; 8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl propionate; (E)-4-((3aR,4R,7R,7aR)-1,3a,4,6,7,7a-hexahydro-5H-4,7-methanoinden-5-ylidene)-3-methylbutan-2-ol; (3R,3aR,6S,7S,8aS)-6-methoxy-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulene; (1R,2S,6S,7S,8S)-8-isopropyl-1-methyl-3-methylenetricyclo[4.4.0.02,7]decane; 2′-isopropyl-1,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,4′-[1,3]dioxane]; (4aR,5R,7aS,9R)-2,2,5,8,8,9a-hexamethyloctahydro-4H-4a,9-methanoazuleno[5,6-d][1,3]dioxole; (3S,5aR,7aS,11aS,11bR)-3,8,8,11a-tetramethyldodecahydro-5H-3,5a-epoxynaphtho[2,1-c]oxepine; 2,2,6,6,7,8,8-heptamethyldecahydro-2H-indeno[4,5-b]furan; (1aS,2aR,3R,5aS,7R,7aR)-3,6,6,7a-tetramethyloctahydro-2H-2a,7-methanoazuleno[5,6-b]oxirene; (7,7,8,8-tetramethyloctahydro-2,3b-methanocyclopenta[1,3]cyclopropa[1,2]benzen-4-yl)methyl acetate; 1-(3-hydroxy-3-methylpent-4-en-1-yl)-2,5,5,8a-tetramethyldecahydronaphthalen-2-ol; decahydro-2,6,6,7,8,8-hexamethyl-2h-indeno(4,5-b)furan; 4,5-epoxy-4,11,11-trimethyl-8-methylenebicyclo(7.2.0)undecane; 1,3,4,6,7,8alpha-hexahydro-1,1,5,5-tetramethyl-2H-2,4alpha-methanophtalen-8(5H)-one, more preferably said malodor reduction materials are selected from the group consisting of 3-methoxy-7,7-dimethyl-10-methylenebicyclo[4.3.1]decane; 2,4a,5,8a-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-yl formate; 2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a-octahydronaphthalen-1-ol; (4R,4aS,6R)-4,4a-dimethyl-6-(prop-1-en-2-yl)-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one; ((3S,3aR,6R,8aS)-7,7-dimethyl-8-methyleneoctahydro-1H-3a,6-methanoazulen-3-yl)methanol; 4,9-dimethoxy-7H-furo[3,2-g]chromen-7-one; (E)-cyclohexadec-8-en-1-one; (Z)-1-(benzyloxy)-2-methoxy-4-(prop-1-en-1-yl)benzene; 1-((2S,3S)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yl)ethan-1-one; (1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate; 2,3-dihydro-3,3-dimethyl-1H-indene-5-propanal; 3-(3,3-dimethyl-2,3-dihydro-1H-inden-5-yl)propanal; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl acetate; 2-((2R,4aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-yl)propan-2-ol; 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopenta[g]isochromene; (Z)-6-ethylideneoctahydro-2H-5,8-methanochromen-2-one; 8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl acetate; octahydro-1H-4,7-methanoinden-5-yl acetate; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl butyrate; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-5-yl isobutyrate; (5R,6R)-3,6-dimethyl-5-(prop-1-en-2-yl)-6-vinyl-4,5,6,7-tetrahydrobenzofuran; (E)-cycloheptadec-9-en-1-one; (3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-3-yl formate; (3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-yl acetate; (3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-ol; 5-methyl-1-(2,2,3-trimethylcyclopent-3-en-1-yl)-6-oxabicyclo[3.2.1]octane; (Z)-4,11,11-trimethyl-8-methylenebicyclo[7.2.0]undec-3-en-5-yl acetate; (1S,2S,5R,8S)-4,4,8-trimethyltricyclo[6.3.1.02,5]dodecan-1-ol; (1S,2S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate; (Z)-2-methyl-5-((1S,2R,4R)-2-methyl-3-methylenebicyclo[2.2.1]heptan-2-yl)pent-2-en-1-ol; (1S,4R,7R)-1,4,9,9-tetramethyl-1,2,3,4,5,6,7,8-octahydro-4,7-methanoazulene; (1aS,5aR,9aR)-1a,5,5,7-tetramethyl-1a,2,3,4,5,5a,8,9-octahydrobenzo[1,7]cyclohepta[1,2-b]oxirene; (2,2-dimethoxyethyl)benzene; (3R,3aS,7S,8aS)-3,8,8-trimethyl-6-methyleneoctahydro-1H-3a,7-methanoazulene; 4-methoxybenzyl 2-phenylacetate; 2,2,7,7,8,9,9-heptamethyldecahydroindeno[4,3a-b]furan; (4R,4aS)-4,4a-dimethyl-6-(propan-2-ylidene)-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one; (E)-5-(2,3-dimethyltricyclo[2.2.1.02,6]heptan-3-yl)-2-methylpent-2-en-1-ol; (1R,3aS,7S,8aR)-1,4,9,9-tetramethyl-2,3,6,7,8,8a-hexahydro-1H-3a,7-methanoazulene; (1aR,4R,4aR,7bS)-1,1,4,7-tetramethyl-1a,2,3,4,4a,5,6,7b-octahydro-1H-cyclopropa[e]azulene; 2-((2R,4aR,8aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)propan-2-ol; (3aR,3bR,4S,7R,7aS)-4-isopropyl-7-methyl-3a,3b,4,5,6,7-hexahydro-1H-cyclopenta[1,3]cyclopropa[1,2]benzene; (3R,5aS,9aR)-2,2,5a,9-tetramethyl-3,4,5,5a,6,7-hexahydro-2H-3,9a-methanobenzo[b]oxepine; (1aR,4aS,7R,7aR,7bS)-1,1,7-trimethyl-4-methylenedecahydro-1H-cyclopropa[e]azulene; 2-((2S,4aR,8aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)propan-2-ol; 1-(3,5,5,6,8,8-hexamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)ethan-1-one; (E)-cyclohexadec-5-en-1-one; (1aR,2S,4aS)-2,4a,8,8-tetramethyloctahydrocyclopropa[d]naphthalen-3(1H)-one; 2-((2R,4aS)-4a,8-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-yl)propan-2-ol; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl propionate; 1-(1,1,2,3,3,6-hexamethyl-2,3-dihydro-1H-inden-5-yl)ethan-1-one; (1R,4S,4aS,6R,8aS)-4,8a,9,9-tetramethyloctahydro-1,6-methanonaphthalen-1(2H)-ol; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-ylpivalate; (2R,4a′R,8a′R)-3,7′-dimethyl-3′,4′,4a′,5′,8′,8a′-hexahydro-1′H-spiro[oxirane-2,2′-[1,4]methanonaphthalene]; 2,2,7,9-tetramethylspiro(5.5)undec-8-en-1-one; (Z)-2-ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol; 5-methoxyoctahydro-1H-4,7-methanoindene-2-carbaldehyde; (4aR,6aS,10aS,10bR)-3,4a,7,7,10a-pentamethyl-4a,5,6,6a,7,8,9,10,10a,10b-decahydro-1H-benzo[f]chromene; (1aR,4aR,7S,7aR,7bR)-1,1,7-trimethyl-4-methylenedecahydro-1H-cyclopropa[e]azulen-7-ol; 1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-1-one; (1aR,4aS)-2,4a,8,8-tetramethyl-1,1a,4,4a,5,6,7,8-octahydrocyclopropa[d]naphthalene; (1R-(1alpha,3alpha,4aalpha))-2,3,4,4a,5,6-hexahydro-2,2-dimethyl-1,3-methanonaphthalen-7(1H)-one; 2-((2R,8R,8aS)-8,8a-dimethyl-1,2,3,4,6,7,8,8a-octahydronaphthalen-2-yl)propan-2-ol; 1-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-methanoazulen-5-yl)ethan-1-one; methyl(Z)-2-(((2,4-dimethylcyclohex-3-en-1-yl)methylene)amino)benzoate; 4,8-dimethyl-2-(propan-2-ylidene)-1,2,3,3a,4,5,6,8a-octahydroazulen-6-yl acetate; decahydro-3H-spiro[furan-2,5′-[4,7]methanoindene]; (1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7-tetramethyldecahydro-1H-cyclopropa[e]azulen-4-ol; 3,5,5,6,7,8,8-heptamethyl-5,6,7,8-tetrahydronaphthalene-2-carbonitrile; (1S,2S,3S,5R)-2,6,6-trimethylspiro[bicyclo[3.1.1]heptane-3,1′-cyclohexan]-2′-en-4′-one; 1′,1′,5′,5′-tetramethylhexahydro-2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene]; (2′S,4a′S,8a′S)-1′,1′,5′,5′-tetramethylhexahydro-2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene]; (7,7,8,8-tetramethyloctahydro-2,3b-methanocyclopenta[1,3]cyclopropa[1,2]benzen-4-yl)methanol; 4,5-epoxy-4,11,11-trimethyl-8-methylenebicyclo(7.2.0)undecane; 1,3,4,6,7,8alpha-hexahydro-1,1,5,5-tetramethyl-2H-2,4alpha-methanophtalen-8(5H)-one, most preferably said malodor reduction materials are selected from the group consisting of (E)-cyclohexadec-5-en-1-one; 2,2,7,7,8,9,9-heptamethyldecahydroindeno[4,3a-b]furan; 2,3-dihydro-3,3-dimethyl-1H-indene-5-propanal; 3-(3,3-dimethyl-2,3-dihydro-1H-inden-5-yl)propanal; 4,5-epoxy-4,11,11-trimethyl-8-methylenebicyclo(7.2.0)undecane; 1,3,4,6,7,8alpha-hexahydro-1,1,5,5-tetramethyl-2H-2,4alpha-methanophtalen-8(5H)-one and mixtures thereof.

6. An antiperspirant and/or deodorant composition according to any preceding claim, said composition comprising one or more perfume raw materials.

7. An antiperspirant and/or deodorant composition according to any preceding claim wherein, said sum total of malodor reduction materials has an average boiling point, based on the weight percent of each malodor reduction material in said sum total of malodor reduction materials, of from about 160° C. to about 400° C., preferably from about 180° C. to about 400° C.; preferably 25%, more preferably 50%, more preferably 75%, most preferably each of said malodor reduction materials in said sum total of malodor reduction materials has a of from about 160° C. to about 400° C., preferably from about 180° C. to about 400° C.

8. An antiperspirant and/or deodorant composition according to any preceding claim wherein, said combination of said sum total of malodor reduction materials and said one or more perfume raw materials combined has an average boiling point, based on the weight percent of each malodor reduction material in said sum total of malodor reduction materials, of from about 160° C. to about 400° C., preferably from about 180° C. to about 400° C.; preferably 25%, more preferably 50%, more preferably 75%, most preferably each of said malodor reduction materials in said sum total of malodor reduction materials and each of said one or more perfume raw materials has a boiling point of from about 160° C. to about 400° C., preferably from about 180° C. to about 400° C.

9. An antiperspirant and/or deodorant composition according to any preceding claim wherein, the ratio of said one or more perfume raw materials to said sum total of malodor reduction material being from about 500:1 to about 1:1, preferably from about 50:1 to about 1:1, more preferably from about 20:1 to about 1:1, most preferably from about 2:1 to about 1:1.

10. An antiperspirant and/or deodorant composition according to any preceding claim, wherein less than 10%, preferably less than 5%, more preferably less than 1% of said malodor reduction materials and said one or more perfume raw materials, based on total combined weight of malodor reduction materials and said one or more perfume raw materials comprise an ionone moiety.

11. An antiperspirant and/or deodorant composition according to any preceding claim, wherein said malodor reduction materials are not a material selected from the group consisting of geranyl nitrile; helional; nonanal; linalool; (S)-(+)-linalool; (R)-(−)-linalool; nerol; tetrahydrolinalool; 2-phenylethyl acetate; eugenol; ethyl linalool; allyl heptoate; agrumen nitrile; citronitrile; 2,2-dimethyl-3-(m-tolyl)propan-1-ol; 2-methyl-5-phenylpentan-1-ol; dodecanenitrile; 2-heptylcyclopentan-1-one; methyl nonyl acetaldehyde; 3-(2-ethylphenyl)-2,2-dimethylpropanal; (Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en-1-one; (R,E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol; 4-(tert-butyl)cyclohexyl acetate; 1-cyclohexylethyl(E)-but-2-enoate; allyl 2-(cyclohexyloxy)acetate; alpha terpinyl acetate; beta terpinyl acetate; gamma terpinyl acetate; methyl dodecyl ether; 2,4-dimethyl-4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine; cinnamyl isobutyrate; (E)-2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-2-enal; gamma methyl ionone; ethyl 2,3,6-trimethyl cyclohexyl carbonate ethyl 2,3,6-trimethyl cyclohexyl carbonate; Citral diethyl acetal; Dimethoxycyclododecane; 1-((2S,3S)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yl)ethan-1-one; oxacyclohexadecan-2-one; 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopenta[g]isochromene; Ethylene brassylate; Methyl(Z)-2-((3-(4-(tert-butyl)phenyl)-2-methylpropylidene)amino)benzoate; 4,7-Methano-1H-inden-5-ol, 3a,4,5,6,7,7a-hexahydro-, 5-acetate; cedryl methyl ether; vetivert acetate; 1-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-methanoazulen-5-yl)ethan-1-one; Benzophenone; Farnesol; trans,trans-farnesol; 3-(3-isopropylphenyl)butanal; 2,6,10-trimethylundec-9-enal; 3-(4-(tert-butyl)phenyl)propanal; 3-(4-isopropylphenyl)-2-methylpropanal; Citronellal (1); Citronellal (d); (E)-4,8-dimethyldeca-4,9-dienal; Pino Acetaldehyde; 3-(4-(tert-butyl)phenyl)-2-methylpropanal; Cinnamic aldehyde; Citral; Geranial; MethoxyMelonal; o-methoxycinnamaldehyde; (E)-4-((3aS,7aS)-octahydro-5H-4,7-methanoinden-5-ylidene)butanal; Methyl Octyl Acetaldehyde; 3-(4-methoxyphenyl)-2-methylpropanal; 5-methoxyoctahydro-1H-4,7-methanoindene-2-carbaldehyde; Iso Cyclocitral; Octanal; 2-Undecenal; 10-Undecenal; Trans-trans-2,6-Nonadienal; Trans-2,cis-6-nondienal; Heliotropin; Hexyl Cinnamic aldehyde; p-methyl-alpha-pentylcinnamaldehyde; Alpha-methyl cinnamaldehyde; 3,4-dimethoxybenzaldehyde; Myrtenal; Perillaldehyde; Maceal; Methyl palmitate; Methyl iso eugenol and mixtures thereof.

12. An antiperspirant and/or deodorant composition according to any preceding claim, said composition being a antiperspirant composition, said antiperspirant composition comprising a total of, based on total antiperspirant composition weight, from about 0.1% to about 7% of one or more of said malodor reduction materials and, optionally, from about 1% to about 25% of an aluminum salt antiperspirant active.

13. An antiperspirant and/or deodorant composition according to any preceding claim, said composition being anhydrous antiperspirant composition, said anhydrous antiperspirant composition comprising a total of, based on total antiperspirant composition weight, from about 0.1% to about 7% of one or more of said malodor reduction materials and from about 1% to about 25% of an antiperspirant actives selected from the group consisting of astringent metallic salts, preferably inorganic and organic salts of aluminum, zirconium and zinc, as well as mixtures thereof, more preferably aluminum halides, aluminum chlorohydrate, aluminum hydroxyhalides, zirconyl oxyhalides, zirconyl hydroxyhalides, and mixtures thereof.

14. An antiperspirant and/or deodorant composition according to any preceding claim, said composition comprising an adjunct ingredient selected from the group consisting of clay mineral powders, pearl pigments, organic powders, emulsifiers, distributing agents, pharmaceutical active, topical active, preservatives, surfactants and mixtures thereof.

15. A deodorant method of controlling malodors comprising: contacting a situs comprising a malodor and/or a situs that will become malodorous with a care antiperspirant and/or deodorant composition selected from the group consisting of the antiperspirant and/or deodorant composition of claims 1 to 14.

16. The method of claim 15 wherein, said situs comprises an underarm and said contacting step comprises contacting said underarm with a sufficient amount of Applicants' antiperspirant and/or deodorant composition containing said sum of malodor reduction materials to provide said underarm with a level of malodor reduction materials of at least 0.0001 mg of malodor reduction material per underarm, preferably from about 0.0001 mg of malodor reduction material per underarm to about 10 mg of malodor reduction material per underarm, more preferably from about 0.001 mg of malodor reduction material per underarm about 5 mg of malodor reduction material per underarm, most preferably from about 0.01 of malodor reduction material per underarm to about 0.2 mg of malodor reduction material per underarm.