TWI489625B - Organic light-emitting display panel and method for manufacturing the same - Google Patents
Organic light-emitting display panel and method for manufacturing the same Download PDFInfo
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本發明係關於一種有機發光顯示面板及其製作方法,尤指一種頂面發光型有機發光顯示面板及其製作方法。The present invention relates to an organic light emitting display panel and a manufacturing method thereof, and more particularly to a top surface light emitting organic light emitting display panel and a manufacturing method thereof.
近年來,有機發光顯示面板(organic light-emitting display,OLED)已漸漸成為熱門的新興平面顯示器,由於具有自發光、廣視角、反應時間快、高發光效率、低操作電壓、面板厚度薄、可製作成可撓曲性面板以及製程簡單等優點,因此已廣泛地應用於各種平面顯示產品上。In recent years, organic light-emitting display (OLED) has gradually become a popular emerging flat panel display, which has self-luminous, wide viewing angle, fast response time, high luminous efficiency, low operating voltage, and thin panel thickness. It has been made into a flexible panel and has a simple process, so it has been widely used in various flat display products.
傳統有機發光顯示面板係包含有複數個有機發光二極體作為顯示畫素,以顯示出畫面。其中,各有機發光二極體係由一陽極、一發光層以及一陰極所構成,且陽極、發光層與陰極係依序堆疊於基板上。並且,為了降低有機發光二極體的發光能障,陽極係使用高功函數之材料,且陰極係使用低功函數之材料。然而,一般具有低功函數以及高導電率之材料係為金屬材料,且為了不增加陰極的電阻值,由金屬材料所構成之陰極因具有一定厚度而不具有透光性。因此,傳統大尺寸之有機發光顯示面板係將發光層所產生之光線從陽極射出,即所謂的底面發光有機發光顯示面板。A conventional organic light emitting display panel includes a plurality of organic light emitting diodes as display pixels to display a picture. The organic light emitting diode system is composed of an anode, a light emitting layer and a cathode, and the anode, the light emitting layer and the cathode are sequentially stacked on the substrate. Further, in order to reduce the luminescence energy barrier of the organic light-emitting diode, the anode is made of a material having a high work function, and the cathode is made of a material having a low work function. However, a material generally having a low work function and a high electrical conductivity is a metal material, and in order not to increase the resistance value of the cathode, the cathode composed of the metal material has a certain thickness and is not translucent. Therefore, the conventional large-sized organic light-emitting display panel emits light generated by the light-emitting layer from the anode, that is, a so-called bottom-surface light-emitting organic light-emitting display panel.
不過,用於驅動有機發光二極體之薄膜電晶體係與有機發光二極體形成於同一基板上,且介於有機發光二極體與基板之間,因此底面發光有機發光顯示面板的畫素開口率會受限於薄膜電晶體的大小與數量,而無法提升。此外,為了有效地控制驅動有機發光二極體的電流大小,使有機發光二極體所產生的畫素灰階更明顯,用於驅動單一有機發光二極體之薄膜電晶體的數量亦相對地增加。如此一來,隨著有機發光顯示面版的尺寸縮小,畫素開口率會大幅地降低。因此,目前已有發展出頂面發光之有機發光顯示面板,以避免薄膜電晶體的數量影響畫素開口率。However, the thin film electro-crystal system for driving the organic light-emitting diode and the organic light-emitting diode are formed on the same substrate and interposed between the organic light-emitting diode and the substrate, so the pixel of the bottom-emitting organic light-emitting display panel The aperture ratio is limited by the size and number of thin film transistors and cannot be increased. In addition, in order to effectively control the magnitude of the current driving the organic light emitting diode, the pixel gray scale generated by the organic light emitting diode is more obvious, and the number of thin film transistors for driving the single organic light emitting diode is relatively increase. As a result, as the size of the organic light-emitting display panel is reduced, the aperture ratio of the pixel is greatly reduced. Therefore, an organic light-emitting display panel having a top surface light emission has been developed to prevent the number of thin film transistors from affecting the aperture ratio of the pixel.
傳統頂面發光型之有機發光顯示面板會於形成有薄膜電晶體以及有機發光二極體之陣列基板上覆蓋一彩色濾光片基板,以保護有機發光二極體,並提升有機發光顯示面板所產生光線顏色的色域。然而,在結合彩色濾光片基板與陣列基板的過程中,空氣中的微粒容易會附著於陣列基板上,使得微粒容易被夾在彩色濾光片基板與陣列基板之間。再者,彩色濾光片基板與陣列基板之間的間隙(cell gap)僅約略為3.8微米,但空氣中的微粒大小約略介於5微米與10微米之間,因此在結合彩色濾光片基板與陣列基板時,微粒容易朝有機發光二極體突出,而壓壞有機發光二極體。The conventional top-emitting organic light-emitting display panel covers a color filter substrate on the array substrate on which the thin film transistor and the organic light-emitting diode are formed to protect the organic light-emitting diode and enhance the organic light-emitting display panel. The color gamut that produces the color of the light. However, in the process of combining the color filter substrate and the array substrate, particles in the air are likely to adhere to the array substrate, so that the particles are easily sandwiched between the color filter substrate and the array substrate. Furthermore, the cell gap between the color filter substrate and the array substrate is only about 3.8 micrometers, but the particle size in the air is approximately between 5 micrometers and 10 micrometers, so the color filter substrate is combined. When it is combined with the array substrate, the particles easily protrude toward the organic light-emitting diode, and the organic light-emitting diode is crushed.
有鑑於此,提供具有大於微粒大小之單元間隙的有機發光顯示面板,以避免有機發光二極體受到損壞,實為業界努力之目標。In view of this, it is an industry goal to provide an organic light-emitting display panel having a cell gap larger than the particle size to avoid damage of the organic light-emitting diode.
本發明之主要目的之一在於提供一種有機發光顯示面板及其製作方法,以避免有機發光二極體因空氣中微粒位於彩色濾光片基板與陣列基板之間的間隙所受到之損壞。One of the main objects of the present invention is to provide an organic light emitting display panel and a method of fabricating the same, which can prevent damage of the organic light emitting diode due to the gap between the color filter substrate and the array substrate.
為達上述之目的,本發明提供一種有機發光顯示面板之製作方法。首先,提供一第一基板,具有一第一內表面。然後,於第一內表面的第一基板上形成一黑色矩陣,且黑色矩陣具有至少一顯示開口,分別暴露出第一基板。接著,於第一內表面的第一基板上形成一圖案化彩色濾光層,具有至少一第一區塊與一第二區塊,第一區塊覆蓋於顯示開口之第一基板上,第二區塊設置在黑色矩陣上。隨後,於第一內表面的第一基板上形成一第一保護層,覆蓋圖案化彩色濾光層與黑色矩陣,且第一保護層具有一第一凹陷,其中第一凹陷位於圖案化彩色濾光層的第一區塊的上方,且對準顯示開口。接下來,於第一保護層上形成一第一間隙物,且第一間隙物位於圖案化彩色濾光層的第二區塊上方。最後,組裝第一基板與一第二基板,第二基板具有一第二內表面,面向第一基板的第一內表面,第二基板具有一有機發光顯示元件,設置在第二內表面的第二基板上,且對準顯示開口。To achieve the above object, the present invention provides a method of fabricating an organic light emitting display panel. First, a first substrate is provided having a first inner surface. Then, a black matrix is formed on the first substrate of the first inner surface, and the black matrix has at least one display opening respectively exposing the first substrate. Forming a patterned color filter layer on the first substrate of the first inner surface, having at least one first block and a second block, the first block covering the first substrate of the display opening, The second block is placed on the black matrix. Subsequently, a first protective layer is formed on the first substrate of the first inner surface, covering the patterned color filter layer and the black matrix, and the first protective layer has a first recess, wherein the first recess is located in the patterned color filter Above the first block of the light layer, and aligned with the display opening. Next, a first spacer is formed on the first protective layer, and the first spacer is located above the second block of the patterned color filter layer. Finally, the first substrate and the second substrate are assembled, the second substrate has a second inner surface facing the first inner surface of the first substrate, and the second substrate has an organic light emitting display element disposed on the second inner surface On the two substrates, and aligned with the display opening.
為達上述之目的,本發明提供一種有機發光顯示面板,其包含有一第一基板、一黑色矩陣、一圖案化彩色濾光層、一第一保護層、一第一間隙物、一第二基板以及一有機發光顯示元件。第一基板具 有一第一內表面。黑色矩陣設置於第一內表面的第一基板上,且黑色矩陣具有至少一顯示開口。圖案化彩色濾光層具有至少一第一區塊與一第二區塊,第一區塊覆蓋於顯示開口之第一基板上,第二區塊設置在黑色矩陣上。第一保護層覆蓋於圖案化彩色濾光層與黑色矩陣上,且第一保護層具有一第一凹陷,位於圖案化彩色濾光層之第一區塊的上方,且對準顯示開口。第一間隙物設置於第一保護層上,且第一間隙物位於圖案化彩色濾光層的第二區塊上方。第二基板跟第一基板相對設置,第二基板具有一第二內表面,面向第一基板的第一內表面。有機發光顯示元件設置在第二內表面的第二基板上,且對準顯示開口。To achieve the above objective, the present invention provides an organic light emitting display panel including a first substrate, a black matrix, a patterned color filter layer, a first protective layer, a first spacer, and a second substrate. And an organic light emitting display element. First substrate There is a first inner surface. The black matrix is disposed on the first substrate of the first inner surface, and the black matrix has at least one display opening. The patterned color filter layer has at least one first block and a second block, the first block covers the first substrate of the display opening, and the second block is disposed on the black matrix. The first protective layer covers the patterned color filter layer and the black matrix, and the first protective layer has a first recess located above the first block of the patterned color filter layer and aligned with the display opening. The first spacer is disposed on the first protective layer, and the first spacer is located above the second block of the patterned color filter layer. The second substrate is disposed opposite to the first substrate, and the second substrate has a second inner surface facing the first inner surface of the first substrate. The organic light emitting display element is disposed on the second substrate of the second inner surface and aligned with the display opening.
本發明之有機發光顯示面板於第一保護層對應顯示開口之位置具有第一凹陷,且有機發光顯示元件亦對應顯示開口設置,藉此可加大第一凹陷之底部與有機發光顯示元件之間的間隙,使得在結合彩色濾光片基板與陣列基板時,微粒不會朝有機發光顯示元件突出,而可避免有有機發光顯示元件受到損壞。The organic light emitting display panel of the present invention has a first recess at a position corresponding to the display opening of the first protective layer, and the organic light emitting display element is also disposed corresponding to the display opening, thereby increasing the bottom of the first recess and the organic light emitting display element The gap is such that when the color filter substrate and the array substrate are combined, the particles do not protrude toward the organic light-emitting display element, and the organic light-emitting display element can be prevented from being damaged.
請參考第1圖至第8圖,第1圖至第8圖為本發明一第一實施例之有機發光顯示面板之製作方法示意圖,其中第5圖與第6圖分別為第7圖沿著剖面線AA’與剖面線BB’之剖面示意圖,且第8圖為本發明第一實施例之有機發光顯示面板之剖面示意圖。本發明之有機發光顯示面板可由複數個畫素結構所構成,但為了簡化說明, 以下以有機發光顯示面板的單一畫素結構為例來作描述,但不以此為限。首先,如第1圖所示,提供一第一基板12,例如:玻璃、強化玻璃、塑膠、藍寶石或石英等透明基板,且可為硬質基板、軟性基板或是可撓性基板,且第一基板12具有一第一內表面12a。然後,進行一微影製程,於第一內表面12a的第一基板12上形成一黑色矩陣14,且黑色矩陣14具有至少一顯示開口14a,分別暴露出第一基板12。本實施例之黑色矩陣14可用於遮蔽彩色濾光片基板與陣列基板中之不透光元件,例如金屬圖案層以及主動元件等。Please refer to FIG. 1 to FIG. 8 . FIG. 1 to FIG. 8 are schematic diagrams showing a method for fabricating an organic light emitting display panel according to a first embodiment of the present invention, wherein FIG. 5 and FIG. 6 respectively show FIG. A cross-sectional view of a section line AA' and a section line BB', and FIG. 8 is a schematic cross-sectional view of the organic light-emitting display panel according to the first embodiment of the present invention. The organic light emitting display panel of the present invention may be composed of a plurality of pixel structures, but for simplicity of explanation, The following is an example of a single pixel structure of an organic light emitting display panel, but is not limited thereto. First, as shown in FIG. 1 , a first substrate 12 such as a transparent substrate such as glass, tempered glass, plastic, sapphire or quartz is provided, and may be a rigid substrate, a flexible substrate or a flexible substrate, and the first The substrate 12 has a first inner surface 12a. Then, a lithography process is performed to form a black matrix 14 on the first substrate 12 of the first inner surface 12a, and the black matrix 14 has at least one display opening 14a exposing the first substrate 12, respectively. The black matrix 14 of this embodiment can be used to shield the color filter substrate from the opaque elements in the array substrate, such as metal pattern layers and active components.
接著,如第2圖所示,進行另一微影製程,於第一內表面12a之第一基板12與黑色矩陣14上形成一圖案化彩色濾光層16,其中圖案化彩色濾光層16具有至少一第一區塊16a與一第二區塊16b。並且,第一區塊16a覆蓋於顯示開口14a之第一基板12上,並延伸至部分黑色矩陣14上,以完全遮蔽顯示開口14a,且第二區塊16b設置在黑色矩陣14上。圖案化彩色濾光層16之第一區塊16a具有一特定顏色,以用於決定經過此第一區塊16a之出光顏色。Next, as shown in FIG. 2, another lithography process is performed to form a patterned color filter layer 16 on the first substrate 12 and the black matrix 14 of the first inner surface 12a, wherein the color filter layer 16 is patterned. There are at least one first block 16a and one second block 16b. Also, the first block 16a covers the first substrate 12 of the display opening 14a and extends over the partial black matrix 14 to completely shield the display opening 14a, and the second block 16b is disposed on the black matrix 14. The first block 16a of the patterned color filter layer 16 has a particular color for determining the color of light exiting through the first block 16a.
隨後,如第3圖所示,於第一內表面12a的第一基板12上形成一第一保護層18,覆蓋圖案化彩色濾光層16與黑色矩陣14,且第一保護層18具有一第一凹陷18a,其中第一凹陷18a位於圖案化彩色濾光層16的第一區塊16a的上方,且對準顯示開口14a。並且,第一保護層18具有一厚部18b、一薄部18c以及一間隙物部18d,使厚部18b、薄部18c與間隙物部18d形成第一凹陷18a,且薄部 18c位於第一凹陷18a之底部。於本實施例中,形成第一保護層18之步驟係先於第一基板12與黑色矩陣14上覆蓋一保護材料層,例如:光阻材料,包括負型光阻材料或是正型光阻材料。然後利用一半色調光罩(half-tone mask)或一灰階光罩(gray-tone mask),將半透光的部分對準顯示開口14a之位置,亦即欲形成第一凹陷18a之位置,並搭配進行另一微影製程,以移除部分光阻材料,並同時形成具有厚部18b、薄部18c與間隙物部18d之第一保護層18。藉此,位於圖案化彩色濾光層16的第一區塊16a上仍有薄部18c覆蓋,而不會於後續其他製程受到破壞。本發明製作第一保護層之材料並不限於上述,且本發明形成第一保護層之方法亦不限於此。於本發明之變化實施例中,第一保護層18之材料亦可以是可顯影的有機材料,直接進型曝光與顯影的步驟,形成同時形成具有厚部18b、薄部18c與間隙物部18d之第一保護層18。於本發明之其他實施例中,第一保護層18之材料亦可為有機材料,且形成第一保護層之步驟也可以將保護材料層之厚度蝕刻或研磨至與厚部的厚度相同,以先形成厚部,然後進行另一微影製程,於保護材料層上蝕刻出第一凹陷,以形成薄部。此外,本實施例之第一凹陷18a具有一深度,可介於1微米至3微米之間,且第一保護層18具有一厚度T,可介於1微米至30微米之間,其中薄部之第一厚度T1可介於1微米至2微米之間,間隙物部之第二厚度T2可介於2微米至6微米之間,且厚部之第三厚度T3可介於4微米至30微米之間,但本發明不限於此。並且,第一凹陷之深度可透過控制微影製程之曝光能量來調整。Then, as shown in FIG. 3, a first protective layer 18 is formed on the first substrate 12 of the first inner surface 12a, covering the patterned color filter layer 16 and the black matrix 14, and the first protective layer 18 has a The first recess 18a, wherein the first recess 18a is located above the first block 16a of the patterned color filter layer 16, and is aligned with the display opening 14a. Moreover, the first protective layer 18 has a thick portion 18b, a thin portion 18c, and a spacer portion 18d, so that the thick portion 18b, the thin portion 18c and the spacer portion 18d form the first recess 18a, and the thin portion 18c is located at the bottom of the first recess 18a. In this embodiment, the step of forming the first protective layer 18 is preceded by the first substrate 12 and the black matrix 14 overlying a protective material layer, such as a photoresist material, including a negative photoresist material or a positive photoresist material. . Then, the half-transmissive portion is aligned with the position of the display opening 14a by using a half-tone mask or a gray-tone mask, that is, the position of the first recess 18a is to be formed. And performing another lithography process to remove part of the photoresist material and simultaneously forming the first protective layer 18 having the thick portion 18b, the thin portion 18c and the spacer portion 18d. Thereby, the thin portion 18c is still covered on the first block 16a of the patterned color filter layer 16 without being damaged in subsequent processes. The material for forming the first protective layer of the present invention is not limited to the above, and the method of forming the first protective layer of the present invention is not limited thereto. In a modified embodiment of the present invention, the material of the first protective layer 18 may also be a developable organic material, and the steps of direct exposure and development are formed simultaneously to form the thick portion 18b, the thin portion 18c and the spacer portion 18d. The first protective layer 18. In other embodiments of the present invention, the material of the first protective layer 18 may also be an organic material, and the step of forming the first protective layer may also etch or grind the thickness of the protective material layer to the same thickness as the thick portion. A thick portion is formed first, and then another lithography process is performed to etch a first recess on the protective material layer to form a thin portion. In addition, the first recess 18a of the embodiment has a depth of between 1 micrometer and 3 micrometers, and the first protective layer 18 has a thickness T, which may be between 1 micrometer and 30 micrometers, wherein the thin portion The first thickness T1 may be between 1 micrometer and 2 micrometers, the second thickness T2 of the spacer portion may be between 2 micrometers and 6 micrometers, and the third thickness of the thick portion T3 may be between 4 micrometers and 30 micrometers. Between microns, but the invention is not limited thereto. Moreover, the depth of the first recess can be adjusted by controlling the exposure energy of the lithography process.
接著,如第4圖所示,於第一保護層18上選擇性的覆蓋一第二保護層20,例如:氮化矽、氧化矽、氮氧化矽或是其他的有機材質。隨後,於間隙物部18d上形成一金屬圖案層22,例如:網格狀金屬圖案。金屬圖案層22的製作方式例如是將導電粒子,例如:銀粒子、鋁粒子、銅粒子、銦錫氧化物粒子等導電粒子,溶解於一溶劑中,例如:負型光阻溶劑,以形成一溶液,並將溶液塗佈於第二保護層20上。然後,進行一曝光製程,將位於圖案化彩色濾光層16之第二區塊16b上之部分溶液固化,而其他部份未固化。接著,進行一顯影製程,以移除未固化之溶液。隨後,烘烤位於圖案化彩色濾光層16之第二區塊16b上之固化溶液,以移除固化溶液中之溶劑,並於間隙物部18d上形成金屬圖案層22,例如:網格狀金屬圖案。值得注意的是,本實施例於形成金屬圖案層22之前係先於第一保護層18上覆蓋第二保護層20,使得金屬圖案層22可與第二保護層20有較佳的黏著度,以避免金屬圖案層22因與第一保護層18之間的黏著度較差而產生剝落的情況。Next, as shown in FIG. 4, a second protective layer 20, such as tantalum nitride, hafnium oxide, hafnium oxynitride or other organic material, is selectively coated on the first protective layer 18. Subsequently, a metal pattern layer 22, for example, a grid-like metal pattern, is formed on the spacer portion 18d. The metal pattern layer 22 is formed by, for example, dissolving conductive particles such as silver particles, aluminum particles, copper particles, or indium tin oxide particles in a solvent such as a negative resist solvent to form a metal. The solution is applied to the second protective layer 20. Then, an exposure process is performed to cure a portion of the solution on the second block 16b of the patterned color filter layer 16 while the other portions are not cured. Next, a development process is performed to remove the uncured solution. Subsequently, the solidified solution on the second block 16b of the patterned color filter layer 16 is baked to remove the solvent in the solidified solution, and a metal pattern layer 22 is formed on the spacer portion 18d, for example, a grid shape Metal pattern. It should be noted that, before the formation of the metal pattern layer 22, the present embodiment covers the second protective layer 20 before the first protective layer 18, so that the metal pattern layer 22 can have a better adhesion to the second protective layer 20. The peeling of the metal pattern layer 22 due to the poor adhesion to the first protective layer 18 is avoided.
接下來,如第5圖、第6圖與第7圖所示,於第二保護層20與金屬圖案層22上形成一第一間隙物24,金屬圖案層22可用於輔助墊高第一間隙物24,第一間隙物24的材質例如:光阻材料,其中第一間隙物24沿一第一方向D1係覆蓋金屬圖案層22,但沿垂直第一方向之一第二方向D2僅覆蓋部分金屬圖案層22,且暴露出部分金屬圖案層22。然後,於第二保護層20、金屬圖案層22與第一間 隙物24上覆蓋一透明電極層26,且透明電極層26可與暴露出之部分金屬圖案層22相接觸,而彼此電性連接,此設計可以增加第一間隙物24與透明電極層26的可接觸面積。至此已完成本實施例之彩色濾光片基板27。於本實施例中,第一間隙物24具有一高度,介於1微米至10微米之間,但不限於此。Next, as shown in FIG. 5, FIG. 6 and FIG. 7, a first spacer 24 is formed on the second protective layer 20 and the metal pattern layer 22, and the metal pattern layer 22 can be used to assist in the first gap. The material of the first spacer 24 is, for example, a photoresist material, wherein the first spacer 24 covers the metal pattern layer 22 along a first direction D1, but covers only a portion along a second direction D2 of the vertical first direction. The metal pattern layer 22 is exposed and a portion of the metal pattern layer 22 is exposed. Then, in the second protective layer 20, the metal pattern layer 22 and the first The gap 24 is covered with a transparent electrode layer 26, and the transparent electrode layer 26 is in contact with the exposed portion of the metal pattern layer 22, and is electrically connected to each other. This design can increase the first spacer 24 and the transparent electrode layer 26. Contactable area. The color filter substrate 27 of this embodiment has been completed up to this point. In the present embodiment, the first spacer 24 has a height of between 1 micrometer and 10 micrometers, but is not limited thereto.
然後,如第8圖所示,提供一第二基板28,例如:玻璃、塑膠或石英等透明基板,並不限於此。具有一第二內表面28a,且於第二基板28之第二內表面28a上形成一有機發光顯示元件30。至此已完成本實施例之陣列基板32。隨後,以第二基板28之第二內表面28a面向第一基板12之第一內表面12a的方式,組裝第一基板12與第二基板28,並將有機發光顯示元件30對準顯示開口14a,使有機發光顯示元件30所產生的光線可從顯示開口14a經過圖案化彩色濾光層16射出顯示開口14a,以形成本實施例之有機發光顯示面板10。Then, as shown in FIG. 8, a second substrate 28 such as a transparent substrate such as glass, plastic or quartz is provided, and is not limited thereto. A second inner surface 28a is formed, and an organic light emitting display element 30 is formed on the second inner surface 28a of the second substrate 28. The array substrate 32 of this embodiment has been completed so far. Subsequently, the first substrate 12 and the second substrate 28 are assembled with the second inner surface 28a of the second substrate 28 facing the first inner surface 12a of the first substrate 12, and the organic light emitting display element 30 is aligned with the display opening 14a. The light generated by the organic light-emitting display element 30 can be emitted from the display opening 14a through the patterned color filter layer 16 to form the display opening 14a to form the organic light-emitting display panel 10 of the present embodiment.
於本實施例中,形成有機發光顯示元件30之步驟說明如下,但不以此為限。首先,於第二基板28之第二內表面28a上形成一主動元件層34,其中主動元件層34包含有一主動元件48,例如:薄膜電晶體,以及一平坦層50,覆蓋於主動元件48與第二基板28上,並具有一穿孔50a暴露出主動元件48之一電極。然後,於主動元件層34之平坦層50上形成一第一電極36,並透過平坦層50之穿孔50a電性連接至主動元件48之電極,其中第一電極36可由例如金 屬等具有反射特性與高功函數之導電材料所構成,且第一電極36之位置係對應彩色濾光片基板27之顯示開口14設置。隨後,於主動元件層34與第一電極36上形成一擋牆38,且擋牆38具有一開口38a,暴露出第一電極36,其中擋牆38係由一絕緣材料所構成。接著,於擋牆38上形成一第二間隙物40,例如:光阻材料,且依序於暴露出之第一電極36上覆蓋一發光層42與第二電極44,其中發光層42與第二電極44延伸至覆蓋於擋牆38與第二間隙物40上,因此第二電極44可具有一第二凹陷44a,對準開口38a。In the embodiment, the steps of forming the organic light emitting display element 30 are as follows, but are not limited thereto. First, an active device layer 34 is formed on the second inner surface 28a of the second substrate 28. The active device layer 34 includes an active device 48, such as a thin film transistor, and a flat layer 50 covering the active device 48. The second substrate 28 has a through hole 50a exposing one of the electrodes of the active element 48. Then, a first electrode 36 is formed on the flat layer 50 of the active device layer 34, and is electrically connected to the electrode of the active device 48 through the through hole 50a of the flat layer 50, wherein the first electrode 36 can be made of, for example, gold. It is composed of a conductive material having a reflection characteristic and a high work function, and the position of the first electrode 36 is disposed corresponding to the display opening 14 of the color filter substrate 27. Subsequently, a retaining wall 38 is formed on the active device layer 34 and the first electrode 36, and the retaining wall 38 has an opening 38a exposing the first electrode 36, wherein the retaining wall 38 is formed of an insulating material. Then, a second spacer 40 is formed on the retaining wall 38, for example, a photoresist material, and the exposed first electrode 36 is covered with a light emitting layer 42 and a second electrode 44, wherein the light emitting layer 42 and the first layer The two electrodes 44 extend to cover the retaining wall 38 and the second spacer 40, so that the second electrode 44 can have a second recess 44a aligned with the opening 38a.
再者,第一電極36、第二電極44與位於其間之發光層42構成一有機發光二極體46,用於產生一白色光,並對準顯示開口14a設置,使白色光可直接朝上射向圖案化彩色濾光層16之第一區塊16a,並於有機發光顯示面板10之外側顯示出具有圖案化彩色濾光層16之顏色的光線。第一電極36因具有高功函數而可作為有機發光二極體46之陽極,且透過平坦層50之穿孔50a電性連接至主動元件48之電極,以藉由主動元件48來控制有機發光二極體46所產生光線之灰階。第二電極44則可由具有低功函數之透明導電材料所構成,例如:具有一定薄度而可呈現透明狀態之銀或鎂,而可作為有機發光二極體46之陰極。此外,發光層42係由可產生白色光之有機發光材料所構成,例如:有機發光材料係為紅光、綠光與藍光有機發光材料堆疊而成,或者有機發光材料係為藍光有機發光材料,並搭配黃色螢光粉,使得有機發光二極體46可產生白色光。值得一提的是,本實施例之第一電極36係由具有反射特性之導電材料 所構成,且第二電極44係由透明導電材料所構成,因此位於第一電極36與第二電極44之間的發光層42所產生之光線不僅可從第二電極44射出,並可受到第一電極36之反射,而往第二電極44射出,以有效地提升光利用率。由此可知,本實施例之有機發光顯示面板係為一頂面發光型有機發光顯示面板。本發明之有機發光二極體並不限僅由第一電極、發光層以及第二電極所構成,而亦可包含有電子注入層與電洞注入層,但不以此為限。Furthermore, the first electrode 36, the second electrode 44 and the light-emitting layer 42 located therebetween constitute an organic light-emitting diode 46 for generating a white light and arranged in alignment with the display opening 14a so that the white light can be directly directed upward. The light is directed to the first block 16a of the patterned color filter layer 16 and the light having the color of the patterned color filter layer 16 is displayed on the outer side of the organic light-emitting display panel 10. The first electrode 36 can serve as an anode of the organic light emitting diode 46 because of having a high work function, and is electrically connected to the electrode of the active device 48 through the through hole 50a of the flat layer 50 to control the organic light emitting device 2 by the active device 48. The gray level of the light produced by the polar body 46. The second electrode 44 may be composed of a transparent conductive material having a low work function, for example, silver or magnesium having a certain degree of thinness to exhibit a transparent state, and serving as a cathode of the organic light-emitting diode 46. In addition, the luminescent layer 42 is composed of an organic luminescent material that can generate white light, for example, the organic luminescent material is a red, green, and blue organic luminescent material stacked, or the organic luminescent material is a blue organic luminescent material. And with the yellow fluorescent powder, the organic light-emitting diode 46 can generate white light. It is worth mentioning that the first electrode 36 of the embodiment is made of a conductive material having reflective properties. The second electrode 44 is composed of a transparent conductive material, so that the light generated by the light-emitting layer 42 between the first electrode 36 and the second electrode 44 can be emitted not only from the second electrode 44 but also from the second electrode 44. The reflection of an electrode 36 is emitted toward the second electrode 44 to effectively enhance light utilization. Therefore, the organic light emitting display panel of the present embodiment is a top surface light emitting type organic light emitting display panel. The organic light-emitting diode of the present invention is not limited to the first electrode, the light-emitting layer, and the second electrode, but may include an electron injection layer and a hole injection layer, but is not limited thereto.
值得注意的是,於組裝陣列基板32與彩色濾光片基板27時,第二間隙物40係對應第一間隙物24設置,使覆蓋於第二間隙物40上之第二電極44與覆蓋於第一間隙物24上之透明電極層26相接觸,並彼此電性連接。藉此,本實施例之有機發光顯示面板10的第二電極44可有效地透過透明電極層26以及金屬圖案層22電性連接至週邊驅動元件,以避免因過薄而與週邊驅動元件之間有過大的電阻。另外,第二間隙物40、第一間隙物24與金屬圖案層22堆疊於第一保護層18與擋牆38之間,且第二凹陷44a對準第一凹陷18a設置,使第一凹陷18a之底部與有機發光顯示元件30之間可具有一間隙H,介於5微米至30微米之間,使對應顯示開口14a之間隙H可大於空氣中的微粒大小。藉此,在結合彩色濾光片基板27與陣列基板32時,微粒不會朝有機發光二極體46突出,而可避免有機發光二極體受到損壞。It should be noted that when the array substrate 32 and the color filter substrate 27 are assembled, the second spacer 40 is disposed corresponding to the first spacer 24, so that the second electrode 44 covering the second spacer 40 is covered with The transparent electrode layers 26 on the first spacers 24 are in contact with each other and are electrically connected to each other. Therefore, the second electrode 44 of the organic light-emitting display panel 10 of the present embodiment can be electrically connected to the peripheral driving component through the transparent electrode layer 26 and the metal pattern layer 22 to avoid being too thin and between the peripheral driving components. There is too much resistance. In addition, the second spacer 40, the first spacer 24 and the metal pattern layer 22 are stacked between the first protective layer 18 and the retaining wall 38, and the second recess 44a is disposed in alignment with the first recess 18a, so that the first recess 18a There may be a gap H between the bottom and the organic light-emitting display element 30, between 5 micrometers and 30 micrometers, so that the gap H corresponding to the display opening 14a may be larger than the particle size in the air. Thereby, when the color filter substrate 27 and the array substrate 32 are combined, the particles do not protrude toward the organic light-emitting diode 46, and the organic light-emitting diode can be prevented from being damaged.
本發明之有機發光顯示面板及其製作方法並不以上述實施例為 限。下文將繼續揭示本發明之其它實施例或變化形,然為了簡化說明並突顯各實施例或變化形之間的差異,下文中使用相同標號標注相同元件,並不再對重覆部分作贅述。The organic light emitting display panel of the present invention and the manufacturing method thereof are not the same as the above embodiment limit. The other embodiments and variations of the present invention are described in the following, and the same reference numerals will be used to refer to the same elements, and the repeated parts will not be described again.
請參考第9圖至第11圖,且一併參考第1圖至第3圖。第9圖至第11圖為本發明一第二實施例之有機發光顯示面板之製作方法示意圖,其中第11圖為本發明第二實施例之有機發光顯示面板之剖面示意圖。本實施例之製作方法於形成第一保護層18之步驟以前係與第一實施例之製作方法相同,如第1圖至第3圖所示,因此在此不再贅述。接著,如第8圖所示,相較於第一實施例,本實施例之製作方法於形成第一保護層18之後係直接於第一保護層18之間隙物部18d上形成金屬圖案層22,而未形成有第二保護層。並且,本實施例之第一保護層18之材料可選擇與金屬圖案層22有較佳黏著度之材料。然後,如第10圖所示,於金屬圖案層22上形成第一間隙物102。隨後,於第一保護層18、金屬圖案層22與第一間隙物102上覆蓋透明電極層26。至此已完成本實施例之彩色濾光片基板104。於本實施例中,本實施例之第一間隙物102與第一實施例之第一間隙物之差異在於本實施例之第一間隙物102僅設置於金屬圖案層22上,而未延伸至金屬圖案層22之兩側,使金屬圖案層22之側邊被暴露出。因此,透明電極層26可與較多部分之金屬圖案層22電性連接,進而可更有效地降低透明電極層26電性連接至週邊驅動元件。最後,如第11圖所示,提供一陣列基板106,並組裝陣列基板106與彩色濾光片基板104,以形成本實施例之有機發光顯示面 板100。於本實施例中,陣列基板106並未包含有第二間隙物,但不限於此。於本發明之其他實施例中,陣列基板亦可包含有第二間隙物。Please refer to Figures 9 to 11 and refer to Figures 1 to 3 together. 9 to 11 are schematic views showing a method of fabricating an organic light emitting display panel according to a second embodiment of the present invention, wherein FIG. 11 is a cross-sectional view showing an organic light emitting display panel according to a second embodiment of the present invention. The manufacturing method of the present embodiment is the same as the manufacturing method of the first embodiment before the step of forming the first protective layer 18, as shown in FIGS. 1 to 3, and thus will not be described herein. Next, as shown in FIG. 8, the manufacturing method of the present embodiment forms the metal pattern layer 22 directly on the interstitial portion 18d of the first protective layer 18 after forming the first protective layer 18 as compared with the first embodiment. And no second protective layer is formed. Moreover, the material of the first protective layer 18 of the present embodiment may be selected from materials having a better adhesion to the metal pattern layer 22. Then, as shown in FIG. 10, the first spacers 102 are formed on the metal pattern layer 22. Subsequently, the transparent electrode layer 26 is covered on the first protective layer 18, the metal pattern layer 22 and the first spacer 102. The color filter substrate 104 of this embodiment has been completed so far. In the present embodiment, the difference between the first spacer 102 of the embodiment and the first spacer of the first embodiment is that the first spacer 102 of the embodiment is disposed only on the metal pattern layer 22 and does not extend to The sides of the metal pattern layer 22 are exposed such that the sides of the metal pattern layer 22 are exposed. Therefore, the transparent electrode layer 26 can be electrically connected to a portion of the metal pattern layer 22, thereby more effectively reducing the transparent connection of the transparent electrode layer 26 to the peripheral driving element. Finally, as shown in FIG. 11, an array substrate 106 is provided, and the array substrate 106 and the color filter substrate 104 are assembled to form the organic light emitting display surface of the embodiment. Board 100. In the embodiment, the array substrate 106 does not include the second spacer, but is not limited thereto. In other embodiments of the invention, the array substrate may also include a second spacer.
請參考第12圖至第13圖,且一併參考第1圖至第3圖。第12圖至第13圖為本發明一第三實施例之有機發光顯示面板之製作方法示意圖,其中第13圖為本發明第三實施例之有機發光顯示面板之剖面示意圖。本實施例之製作方法於形成第一保護層18之步驟以前係與第一實施例之製作方法相同,如第1圖至第3圖所示,因此在此不再贅述。接著,如第11圖所示,相較於第一實施例,本實施例之製作方法於形成第一保護層18之後係直接於第一保護層18之間隙物部18d上形成第一間隙物202,而未形成有第二保護層與金屬圖案層。至此已完成本實施例之彩色濾光片基板204。最後,如第12圖所示,提供一陣列基板206,並組裝陣列基板206與彩色濾光片基板204,以形成本實施例之有機發光顯示面板200。於本實施例中,陣列基板206並未包含有第二間隙物,但不限於此。於本發明之其他實施例中,陣列基板亦可包含有第二間隙物。Please refer to Figures 12 to 13, and refer to Figures 1 to 3 together. 12 to 13 are schematic views showing a method of fabricating an organic light emitting display panel according to a third embodiment of the present invention, and FIG. 13 is a cross-sectional view showing an organic light emitting display panel according to a third embodiment of the present invention. The manufacturing method of the present embodiment is the same as the manufacturing method of the first embodiment before the step of forming the first protective layer 18, as shown in FIGS. 1 to 3, and thus will not be described herein. Next, as shown in FIG. 11, the manufacturing method of the present embodiment forms a first spacer directly on the spacer portion 18d of the first protective layer 18 after forming the first protective layer 18, as compared with the first embodiment. 202, and no second protective layer and metal pattern layer are formed. The color filter substrate 204 of this embodiment has been completed so far. Finally, as shown in FIG. 12, an array substrate 206 is provided, and the array substrate 206 and the color filter substrate 204 are assembled to form the organic light-emitting display panel 200 of the present embodiment. In the embodiment, the array substrate 206 does not include the second spacer, but is not limited thereto. In other embodiments of the invention, the array substrate may also include a second spacer.
綜上所述,本發明之有機發光顯示面板於第一保護層對應顯示開口之位置具有第一凹陷,且有機發光二極體亦對應顯示開口設置,藉此可加大第一凹陷之底部與有機發光顯示元件之間的間隙,使得在結合彩色濾光片基板與陣列基板時,微粒不會朝有機發光二極體突出,而可避免有機發光二極體受到損壞。In summary, the organic light emitting display panel of the present invention has a first recess at a position corresponding to the display opening of the first protective layer, and the organic light emitting diode is also disposed corresponding to the display opening, thereby increasing the bottom of the first recess and The gap between the organic light-emitting display elements is such that when the color filter substrate and the array substrate are combined, the particles do not protrude toward the organic light-emitting diode, and the organic light-emitting diode can be prevented from being damaged.
以上所述僅為本發明之較佳實施例,凡依本發明申請專利範圍所做之均等變化與修飾,皆應屬本發明之涵蓋範圍。The above are only the preferred embodiments of the present invention, and all changes and modifications made to the scope of the present invention should be within the scope of the present invention.
10‧‧‧有機發光顯示面板10‧‧‧Organic display panel
12‧‧‧第一基板12‧‧‧First substrate
12a‧‧‧第一內表面12a‧‧‧First inner surface
14‧‧‧黑色矩陣14‧‧‧Black matrix
14a‧‧‧顯示開口14a‧‧‧Show opening
16‧‧‧圖案化彩色濾光層16‧‧‧ patterned color filter
16a‧‧‧第一區塊16a‧‧‧First block
16b‧‧‧第二區塊16b‧‧‧Second block
18‧‧‧第一保護層18‧‧‧First protective layer
18a‧‧‧第一凹陷18a‧‧‧first depression
18b‧‧‧厚部18b‧‧‧Thick
18c‧‧‧薄部18c‧‧‧
18d‧‧‧間隙物部18d‧‧‧Interstance
20‧‧‧第二保護層20‧‧‧Second protective layer
22‧‧‧金屬圖案層22‧‧‧metal pattern layer
24‧‧‧第一間隙物24‧‧‧First gap
26‧‧‧透明電極層26‧‧‧Transparent electrode layer
27‧‧‧彩色濾光片基板27‧‧‧Color filter substrate
28‧‧‧第二基板28‧‧‧second substrate
28a‧‧‧第二內表面28a‧‧‧Second inner surface
30‧‧‧有機發光顯示元件30‧‧‧Organic light-emitting display elements
32‧‧‧陣列基板32‧‧‧Array substrate
34‧‧‧主動元件層34‧‧‧Active component layer
36‧‧‧第一電極36‧‧‧First electrode
38‧‧‧擋牆38‧‧‧Retaining wall
38a‧‧‧開口38a‧‧‧ Opening
40‧‧‧第二間隙物40‧‧‧Second spacer
42‧‧‧發光層42‧‧‧Lighting layer
44‧‧‧第二電極44‧‧‧second electrode
44a‧‧‧第二凹陷44a‧‧‧second depression
46‧‧‧有機發光二極體46‧‧‧Organic Luminescent Diodes
48‧‧‧主動元件48‧‧‧Active components
50‧‧‧平坦層50‧‧‧flat layer
50a‧‧‧穿孔50a‧‧‧Perforation
100‧‧‧有機發光顯示面板100‧‧‧Organic display panel
102‧‧‧第一間隙物102‧‧‧ first spacer
104‧‧‧彩色濾光片基板104‧‧‧Color filter substrate
106‧‧‧陣列基板106‧‧‧Array substrate
200‧‧‧有機發光顯示面板200‧‧‧Organic display panel
202‧‧‧第一間隙物202‧‧‧First gap
204‧‧‧彩色濾光片基板204‧‧‧Color filter substrate
206‧‧‧陣列基板206‧‧‧Array substrate
D1‧‧‧第一方向D1‧‧‧ first direction
D2‧‧‧第二方向D2‧‧‧ second direction
T1‧‧‧第一厚度T1‧‧‧first thickness
T2‧‧‧第二厚度T2‧‧‧second thickness
T3‧‧‧第三厚度T3‧‧‧ third thickness
H‧‧‧間隙H‧‧‧ gap
第1圖至第8圖為本發明一第一實施例之有機發光顯示面板之製作方法示意圖。1 to 8 are schematic views showing a method of fabricating an organic light emitting display panel according to a first embodiment of the present invention.
第9圖至第11圖為本發明一第二實施例之有機發光顯示面板之製作方法示意圖。9 to 11 are schematic views showing a method of fabricating an organic light emitting display panel according to a second embodiment of the present invention.
第12圖至第13圖為本發明一第三實施例之有機發光顯示面板之製作方法示意圖。12 to 13 are schematic views showing a method of fabricating an organic light emitting display panel according to a third embodiment of the present invention.
10‧‧‧有機發光顯示面板10‧‧‧Organic display panel
12‧‧‧第一基板12‧‧‧First substrate
12a‧‧‧第一內表面12a‧‧‧First inner surface
14‧‧‧黑色矩陣14‧‧‧Black matrix
14a‧‧‧顯示開口14a‧‧‧Show opening
16‧‧‧圖案化彩色濾光層16‧‧‧ patterned color filter
16a‧‧‧第一區塊16a‧‧‧First block
16b‧‧‧第二區塊16b‧‧‧Second block
18‧‧‧第一保護層18‧‧‧First protective layer
18a‧‧‧第一凹陷18a‧‧‧first depression
18b‧‧‧厚部18b‧‧‧Thick
18c‧‧‧薄部18c‧‧‧
18d‧‧‧間隙物部18d‧‧‧Interstance
20‧‧‧第二保護層20‧‧‧Second protective layer
22‧‧‧金屬圖案層22‧‧‧metal pattern layer
24‧‧‧第一間隙物24‧‧‧First gap
26‧‧‧透明電極層26‧‧‧Transparent electrode layer
27‧‧‧彩色濾光片基板27‧‧‧Color filter substrate
28‧‧‧第二基板28‧‧‧second substrate
28a‧‧‧第二內表面28a‧‧‧Second inner surface
30‧‧‧有機發光顯示元件30‧‧‧Organic light-emitting display elements
32‧‧‧陣列基板32‧‧‧Array substrate
34‧‧‧主動元件層34‧‧‧Active component layer
36‧‧‧第一電極36‧‧‧First electrode
38‧‧‧擋牆38‧‧‧Retaining wall
38a‧‧‧開口38a‧‧‧ Opening
40‧‧‧第二間隙物40‧‧‧Second spacer
42‧‧‧發光層42‧‧‧Lighting layer
44‧‧‧第二電極44‧‧‧second electrode
44a‧‧‧第二凹陷44a‧‧‧second depression
46‧‧‧有機發光二極體46‧‧‧Organic Luminescent Diodes
48‧‧‧主動元件48‧‧‧Active components
50‧‧‧平坦層50‧‧‧flat layer
50a‧‧‧穿孔50a‧‧‧Perforation
T1‧‧‧第一厚度T1‧‧‧first thickness
T2‧‧‧第二厚度T2‧‧‧second thickness
T3‧‧‧第三厚度T3‧‧‧ third thickness
H‧‧‧間隙H‧‧‧ gap
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