KR20160040783A - nitride-based semiconductor diode - Google Patents
nitride-based semiconductor diode Download PDFInfo
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- KR20160040783A KR20160040783A KR1020140134102A KR20140134102A KR20160040783A KR 20160040783 A KR20160040783 A KR 20160040783A KR 1020140134102 A KR1020140134102 A KR 1020140134102A KR 20140134102 A KR20140134102 A KR 20140134102A KR 20160040783 A KR20160040783 A KR 20160040783A
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 297
- 150000004767 nitrides Chemical class 0.000 title claims abstract description 149
- 238000000034 method Methods 0.000 claims description 28
- 239000000758 substrate Substances 0.000 claims description 24
- 230000000149 penetrating effect Effects 0.000 claims description 3
- 229910002704 AlGaN Inorganic materials 0.000 claims description 2
- 230000005684 electric field Effects 0.000 description 16
- JMASRVWKEDWRBT-UHFFFAOYSA-N Gallium nitride Chemical compound [Ga]#N JMASRVWKEDWRBT-UHFFFAOYSA-N 0.000 description 14
- 238000010586 diagram Methods 0.000 description 14
- 229910002601 GaN Inorganic materials 0.000 description 12
- 239000010931 gold Substances 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 11
- 230000004888 barrier function Effects 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- 239000011651 chromium Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000002019 doping agent Substances 0.000 description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 6
- 229910052737 gold Inorganic materials 0.000 description 6
- 229910052710 silicon Inorganic materials 0.000 description 6
- 239000010703 silicon Substances 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 229910052594 sapphire Inorganic materials 0.000 description 3
- 239000010980 sapphire Substances 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 208000012868 Overgrowth Diseases 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000002248 hydride vapour-phase epitaxy Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000001451 molecular beam epitaxy Methods 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/12—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/20—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only AIIIBV compounds
- H01L29/2003—Nitride compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66083—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by variation of the electric current supplied or the electric potential applied, to one or more of the electrodes carrying the current to be rectified, amplified, oscillated or switched, e.g. two-terminal devices
- H01L29/66196—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by variation of the electric current supplied or the electric potential applied, to one or more of the electrodes carrying the current to be rectified, amplified, oscillated or switched, e.g. two-terminal devices with an active layer made of a group 13/15 material
- H01L29/66204—Diodes
- H01L29/66212—Schottky diodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/86—Types of semiconductor device ; Multistep manufacturing processes therefor controllable only by variation of the electric current supplied, or only the electric potential applied, to one or more of the electrodes carrying the current to be rectified, amplified, oscillated or switched
- H01L29/861—Diodes
- H01L29/872—Schottky diodes
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- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Ceramic Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Manufacturing & Machinery (AREA)
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Abstract
The nitride-based semiconductor diode according to an embodiment includes a semiconductor structure including a first nitride-based semiconductor layer doped with a first type and a second nitride-based semiconductor layer doped with a second type, which are stacked alternately to each other; A first electrode layer in contact with a side surface of the first semiconductor layer and forming a Schottky junction with the first semiconductor layer and a second electrode layer electrically connected to the other side surface of the semiconductor structure opposite to the one side surface.
Description
This disclosure relates to a nitride based semiconductor diode.
BACKGROUND ART Due to the development of information and communication technology, there is an increasing demand for devices operating in a high-speed switching environment or a high-voltage environment. In particular, a power semiconductor device must withstand a high voltage in the reverse direction as a switching device and must flow a high current in the forward operation. Conventionally, silicon semiconductor devices have been widely used in the market as such power semiconductor devices. However, since the 2000s, since the material limitations of silicon have been encountered since the 2000s, there has been no significant improvement in the technology of achieving reduction in power loss or increasing cell density .
On the other hand, in order to overcome the material limitations, there has been an attempt to introduce gallium nitride (GaN) instead of silicon into a power semiconductor device. Specifically, a gallium nitride semiconductor device employing a III-V semiconductor material is capable of high-speed switching operation as compared with a conventional silicon semiconductor device, and is suitable for high-speed signal processing as well as being applied to a high voltage environment through high- It has attracted the attention of the industry because of its advantages.
Semiconductor devices such as Schottky barrier diodes, pn junction diodes, and MIS (Metal-Insulator-Semiconductor) transistors using GaN substrates have been proposed as examples of gallium nitride devices. In Korean Patent Publication No. 2010-007822, A Schottky barrier diode having improved withstand voltage is disclosed.
The embodiment of the present disclosure provides a nitride-based semiconductor diode having improved high-voltage characteristics when a reverse bias is applied between a first electrode layer and a second electrode layer.
An embodiment of the present disclosure provides a nitride based semiconductor diode with improved charge mobility when forward bias is applied.
A nitride based semiconductor diode according to one aspect is disclosed. Wherein the nitride semiconductor diode comprises a semiconductor structure including a first nitride semiconductor first layer doped with a first type and a second nitride semiconductor layer doped with a second type,
A first electrode layer in contact with one side surface of the semiconductor structure and forming a Schottky junction with the first semiconductor layer and a second electrode layer electrically connected to the other side surface of the semiconductor structure opposite to the one side surface, .
A nitride-based semiconductor diode according to another aspect is disclosed. The nitride based semiconductor diode includes a substrate, an insulating buffer layer formed on the substrate, a first nitride semiconductor first semiconductor layer doped with a first type staggeredly stacked on the buffer layer, and a second nitride semiconductor layer doped with a second type A first electrode layer formed in a first trench that penetrates at least a portion of the semiconductor structure toward a substrate and a second electrode layer disposed laterally spaced from the first electrode layer, And a second electrode layer formed inside the second trench penetrating in the direction of the first electrode. The first electrode layer is Schottky-bonded to the first semiconductor layer, and the second electrode layer is ohmic-bonded to the first semiconductor layer.
According to an embodiment of the present disclosure, a nitride-based first semiconductor layer doped with a first type and a nitride-based second semiconductor layer doped with a second type, which are stacked alternately, are applied between the first electrode layer and the second electrode layer . The depletion layer can be formed in the boundary region between the first semiconductor layer and the second semiconductor layer by performing the p-n junction between the first semiconductor layer and the second semiconductor layer.
The depletion layer can alleviate the concentration of an electric field in the nitride semiconductor diode when an electric field due to reverse bias is formed from the first electrode layer to the second electrode layer through the semiconductor structure. This makes it possible to provide a nitride semiconductor diode having higher breakdown voltage characteristics.
According to an embodiment of the present disclosure, a nitride-based third semiconductor layer having a different work function from that of the first semiconductor layer is interposed in the first semiconductor layer, and a nitride semiconductor layer between the first electrode layer and the second electrode layer The 2DEG layer can be formed in the semiconductor layer. The nitride semiconductor diode having improved charge mobility can be provided by allowing charge to be conducted through the 2DEG layer at the time of forward bias application.
The effects of the disclosed techniques described above are to illustrate any of the various effects derived from the configuration of one embodiment of the present disclosure and not to preclude other various effects that may be apparently derived from the configuration of the presented embodiments.
1 is a schematic diagram schematically showing a nitride-based semiconductor diode according to one comparative example of the present disclosure.
2 is a schematic diagram schematically showing a nitride-based semiconductor diode according to the first embodiment of the present disclosure;
3 is a schematic diagram schematically showing a depletion layer in a nitride semiconductor diode according to the first embodiment of the present disclosure;
4 is a schematic diagram schematically showing a nitride-based semiconductor diode according to a second embodiment of the present disclosure;
5 is a schematic diagram schematically showing a nitride-based semiconductor diode according to a third embodiment of the present disclosure;
6 is a schematic diagram schematically showing a nitride-based semiconductor diode according to a fourth embodiment of the present disclosure;
7 is a partial enlarged view of the nitride-based semiconductor diode of Fig.
8 is a schematic diagram schematically showing a nitride-based semiconductor diode according to a fifth embodiment of the present disclosure;
Embodiments of the present disclosure will now be described in more detail with reference to the accompanying drawings. However, the techniques disclosed in this disclosure are not limited to the embodiments described herein but may be embodied in other forms. In the drawings, the width, thickness, and the like of the components are enlarged in order to clearly illustrate the components of each device.
Where an element is referred to herein as being located on another element "above" or "below", it is to be understood that the element is directly on the other element "above" or "below" It means that it can be intervened. In this specification, the terms 'upper' and 'lower' are relative concepts set at the observer's viewpoint. When the viewer's viewpoint is changed, 'upper' may mean 'lower', and 'lower' It may mean.
Like numbers refer to like elements throughout the several views. It is to be understood that the singular forms "a", "an", and "the" include plural referents unless the context clearly dictates otherwise, and the terms "comprise" Or combinations thereof, and does not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, or combinations thereof.
Herein, the interfacial region between the first layer and the second layer means not only the interface between the first layer and the second layer but also the interfacial region between the first layer and the second layer adjacent to the interface, And the like.
In the present specification, the doping types of the first type and the second type mean different doping types, respectively. That is, the first type or the second type may be classified depending on the type of the dopant introduced into the semiconductor material layer. Specifically, the first type or the second type may be any one of n-type and p-type. When the first type is n-type, the second type may be p-type, and when the first type is p-type, the second type may be n-type. For example, when doping to n-type, silicon (Si) may be applied as a dopant, and dopant may be beryllium (Be), magnesium (Mg), calcium (Ca) , Iron (Fe), manganese (Mn), and the like.
In this specification, the n-type or p-type doping means that the p-type dopant is doped into the nitride-based semiconductor at a concentration of 1E17 / cm 3 or more, and the n-type dopant is implanted at a dose of about 1E16 / cm 3 or more. In addition, 'is doped with a high concentration of n-type or p-type' means by being in the nitride-based semiconductor, in the case of a p-type of about 1E20 / cm 3 or more, in the case of n-type dopant is about 1E19 / cm 3 or more is injected, a high concentration Lt; / RTI >
In this specification, the nitride-based semiconductor layer may include, for example, a nitride such as Al x In y Ga 1-xy N (0? X? 1, 0? Y? The nitride based semiconductor layer may be formed by a method such as Metal Organic Chemical Vapor Deposition (MOCVD), Molecular Beam Epitaxy or Hydride Vapor Phase Epitaxy Can be formed.
In this specification, the nitride-based semiconductor diode may be, for example, a Schottky barrier diode.
1 is a schematic diagram schematically showing a nitride-based semiconductor diode according to one comparative example of the present disclosure. More specifically, FIG. 1A schematically shows a depletion layer 110 'that occurs when the
One comparative example related to FIG. 1 was invented by the inventor of the present disclosure, but has a disadvantage relative to the embodiment of the present disclosure described later. The inventor of the present disclosure has completed the technique of the embodiment of the present disclosure in order to overcome the disadvantages of this comparative example. Hereinafter, first, the configuration of this comparative example will be described in detail.
Referring to FIG. 1, the
The nitride based
1 (a), a depletion layer is formed in the interface region between the
On the other hand, the electric field generated by the Schottky junction between the metal and the semiconductor may have a peak value at the interface between the
Referring to FIG. 1 (c), the voltage distribution in the
In the internal field distribution of the nitride semiconductor diode as shown in FIG. 1, as the reverse bias value increases, the peak electric field value increases at the interface of the Schottky barrier between the
2 is a schematic diagram schematically showing a nitride-based semiconductor diode according to the first embodiment of the present disclosure; 2 (a) schematically shows a structure in which the first and second semiconductor layers 112 and 114 and the
2 and 3, the
The nitride based
Referring to FIG. 2 (a), the
An electric field generated by the Schottky junction between the
In the internal electric field distribution of the nitride semiconductor diode as shown in FIG. 2, the electric field value increases as the reverse bias value increases. However, the electric field value does not have an extreme peak value in the nitride based semiconductor region. Thus, even when the reverse bias value increases, the resistance against the electric breakdown phenomenon can be larger than that of the nitride based
2 and 3, an operation method of the
When no bias is applied or a reverse bias is applied between the
At least a portion of the
4 is a schematic diagram schematically showing a nitride-based semiconductor diode according to a second embodiment of the present disclosure; Referring to FIG. 4, the
As the
The semiconductor structure 430 may be disposed on the insulating
In one embodiment, the
An insulating
The
The
In the
5 is a schematic diagram schematically showing a nitride-based semiconductor diode according to a third embodiment of the present disclosure; 5, the nitride-based
In one embodiment, if the
6 is a schematic diagram schematically showing a nitride-based semiconductor diode according to a fourth embodiment of the present disclosure; 7 is a partial enlarged view of the nitride-based semiconductor diode of Fig. 6 and 7, the nitride-based
The nitride-based
An energy banding phenomenon due to a difference in work function between the nitride constituting the
On the other hand, the
When no bias is applied between the
8 is a schematic diagram schematically showing a nitride-based semiconductor diode according to a fifth embodiment of the present disclosure; 8, the nitride-based
In one embodiment, when the
On the other hand, the constituent points of the third and fourth embodiments of the present disclosure can be applied to the second embodiment described above with reference to Fig. That is, the ELO process configuration using the nitride-based seed layer in the third embodiment or another nitride-based semiconductor layer insertion structure for forming the 2DEG layer in the fourth embodiment can be applied substantially the same as the second embodiment have.
While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims. It can be understood that
10 20 30 40 50 60: nitride semiconductor diodes,
110 112: first semiconductor layer, 110'112 ': depletion layer of the first semiconductor layer,
114: second semiconductor layer, 114 ': depletion layer of the second semiconductor layer
120: lower nitride based semiconductor layer, 130: first electrode layer,
140: upper electrode layer, 150: second electrode layer,
410: substrate, 420: insulating buffer layer,
421: a nitride-based seed layer
430: semiconductor structure, 431: first semiconductor layer, 432: second semiconductor layer,
440: insulating buffer layer, 450: insulating layer,
460: a first electrode layer, 470: a second electrode layer,
610: a nitride-based third semiconductor layer, 630: a semiconductor structure,
710: 2DEG layer.
Claims (18)
A first electrode layer in contact with a side surface of the semiconductor structure and forming a Schottky junction with the first semiconductor layer; And
And a second electrode layer electrically connected to the other side portion of the semiconductor structure located on the opposite side of the one side portion
Nitride based semiconductor diode.
The first semiconductor layer and the second semiconductor layer form a depletion layer by pn junction
Nitride based semiconductor diode.
When a bias is not applied between the first electrode layer and the second electrode layer, or when a reverse bias is applied,
Wherein all of the first semiconductor layer and the second semiconductor layer remain depleted
Nitride based semiconductor diode.
When a forward bias is applied between the first electrode layer and the second electrode layer, at least a part of the first semiconductor layer and the second semiconductor layer is recovered from the depleted state
Nitride based semiconductor diode.
The charge is conducted along a portion of the first semiconductor layer recovered from the depleted state
Nitride based semiconductor diode.
And a nitride-based third semiconductor layer interposed in the first semiconductor layer and having a work function different from that of the first semiconductor layer
Nitride based semiconductor diode.
Wherein the first semiconductor layer is a GaN layer,
The third semiconductor layer may be any one selected from an InN layer, an AlGaN layer, an InGaN layer, and an AlInGaN layer
Nitride based semiconductor diode.
And a 2DEG layer formed in an interface region between the first semiconductor layer and the third semiconductor layer
Nitride based semiconductor diode.
When no voltage is applied between the first electrode layer and the second electrode layer or when a reverse bias is applied, the 2DEG layer is disconnected from the interface region of the first electrode layer and the semiconductor structure
Nitride based semiconductor diode.
When a forward bias is applied between the first electrode layer and the second electrode layer,
The 2DEG layer disconnected in the interface region of the first electrode layer and the semiconductor structure is recovered and a charge is transferred between the first electrode layer and the second electrode layer
Nitride based semiconductor diode.
An insulating buffer layer formed on the substrate;
A semiconductor structure including a first nitride-based semiconductor layer doped with a first type and a second nitride-based semiconductor layer doped with a second type, the first nitride-based first semiconductor layer being staggered on the buffer layer;
A first electrode layer formed in a first trench penetrating at least a part of the semiconductor structure in a direction of a substrate; And
And a second electrode layer disposed in the second trench, the second electrode layer being spaced laterally from the first electrode layer and penetrating at least a portion of the semiconductor structure toward the substrate,
Wherein the first electrode layer is Schottky-bonded to the first semiconductor layer, and the second electrode layer is ohmic-bonded to the first semiconductor layer
Nitride based semiconductor diode.
The semiconductor structure
A plurality of pairs of the first semiconductor layer and the second semiconductor layer stacked alternately,
Nitride based semiconductor diode.
When no voltage is applied between the first electrode layer and the second electrode layer or when a reverse bias is applied,
All of the first semiconductor layer and the second semiconductor layer are maintained in a depleted state by the pn junction
Nitride based semiconductor diode.
At least a portion of the first semiconductor layer and the second semiconductor layer is recovered from the depleted state and a charged carrier is recovered from the recovered state when a forward bias is applied between the first electrode layer and the second electrode layer Wherein the first electrode layer and the second electrode layer are electrically connected to each other.
Nitride based semiconductor diode.
And a nitride-based third semiconductor layer inserted in the first semiconductor layer and having a different work function from the first semiconductor layer
Nitride based semiconductor diode.
And a 2DEG layer formed in an interface region between the first semiconductor layer and the third semiconductor layer
Nitride based semiconductor diode.
When no voltage is applied between the first electrode layer and the second electrode layer or when a reverse bias is applied, the 2DEG layer is disconnected from the interface region of the first electrode layer and the semiconductor structure
Nitride based semiconductor diode.
When a forward bias is applied between the first electrode layer and the second electrode layer,
The 2DEG layer disconnected in the interface region with the first electrode layer is recovered and a charge is transferred between the first electrode layer and the second electrode layer
Nitride based semiconductor diode.
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