JPS6390567A - Resin composition - Google Patents
Resin compositionInfo
- Publication number
- JPS6390567A JPS6390567A JP23748586A JP23748586A JPS6390567A JP S6390567 A JPS6390567 A JP S6390567A JP 23748586 A JP23748586 A JP 23748586A JP 23748586 A JP23748586 A JP 23748586A JP S6390567 A JPS6390567 A JP S6390567A
- Authority
- JP
- Japan
- Prior art keywords
- electrically conductive
- rubber
- resin composition
- plastic
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011342 resin composition Substances 0.000 title claims abstract description 7
- 229910052751 metal Inorganic materials 0.000 claims abstract description 7
- 150000001875 compounds Chemical class 0.000 claims abstract description 6
- 229920001971 elastomer Polymers 0.000 claims abstract description 6
- 239000002184 metal Substances 0.000 claims abstract description 6
- 239000004033 plastic Substances 0.000 claims abstract description 6
- 229920003023 plastic Polymers 0.000 claims abstract description 6
- 239000005060 rubber Substances 0.000 claims abstract description 6
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 5
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 5
- 239000010419 fine particle Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 abstract description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract description 6
- 238000002156 mixing Methods 0.000 abstract description 4
- 239000002341 toxic gas Substances 0.000 abstract description 4
- -1 aluminum compound Chemical class 0.000 abstract description 3
- 229910052802 copper Inorganic materials 0.000 abstract description 3
- 229910052759 nickel Inorganic materials 0.000 abstract description 3
- 229910052709 silver Inorganic materials 0.000 abstract description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 abstract description 3
- 229910001887 tin oxide Inorganic materials 0.000 abstract description 3
- 239000011787 zinc oxide Substances 0.000 abstract description 3
- 229910045601 alloy Inorganic materials 0.000 abstract description 2
- 239000000956 alloy Substances 0.000 abstract description 2
- 229910052782 aluminium Inorganic materials 0.000 abstract description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 abstract description 2
- 239000002216 antistatic agent Substances 0.000 abstract description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 abstract description 2
- 239000000835 fiber Substances 0.000 abstract description 2
- 239000011888 foil Substances 0.000 abstract description 2
- 229910052737 gold Inorganic materials 0.000 abstract description 2
- 229920001903 high density polyethylene Polymers 0.000 abstract description 2
- 239000004700 high-density polyethylene Substances 0.000 abstract description 2
- 229910052742 iron Inorganic materials 0.000 abstract description 2
- 229920001684 low density polyethylene Polymers 0.000 abstract description 2
- 239000004702 low-density polyethylene Substances 0.000 abstract description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 abstract description 2
- 239000000347 magnesium hydroxide Substances 0.000 abstract description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 abstract description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- 229910001111 Fine metal Inorganic materials 0.000 abstract 2
- 239000002923 metal particle Substances 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001454 anthracenes Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は、導電性で、且つ色調が非黒色系で、更に難燃
性である樹脂組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a resin composition that is electrically conductive, has a non-black color tone, and is flame retardant.
〈従来の技術〉
従来、導電性の組成物を得るには、ゴム、プラスチック
に導電性付与剤として、無機系や有機系の化合物添加剤
を添加している。又、難燃性を得るためには、一般にハ
ロゲン系難燃剤と各種難燃剤を併用して配合することが
多い。<Prior Art> Conventionally, in order to obtain a conductive composition, an inorganic or organic compound additive is added to rubber or plastic as a conductivity imparting agent. Furthermore, in order to obtain flame retardancy, halogen-based flame retardants and various flame retardants are generally used in combination.
〈発明が解決しようとする問題点〉
ところが、導電性付与剤として、最もポビラーな添加剤
としてはカーボンブラックがあり、これにより得られる
色調は黒色あるため、その用途が！ＩＪＩＩされる。例
えば、組成物を色分けして使用すること等は不可能であ
る。又、カーボンブランク以外のものとして、銀、ニッ
ケル、銅等の金属微粒子、或いは特殊導電性酸化亜鉛や
酸化錫（不純物をドープして導電性を与えもの）を添加
した場合には、ハロゲン系の難燃剤と化学反応を起こし
て、導電効果が棄損される。<Problems to be Solved by the Invention> However, as a conductivity imparting agent, carbon black is the most volatile additive, and the color tone obtained with it is black, so its use is limited! IJII will be done. For example, it is impossible to use different compositions by color. In addition, when adding metal fine particles such as silver, nickel, or copper, or special conductive zinc oxide or tin oxide (doped with impurities to give conductivity) other than carbon blank, halogen-based It causes a chemical reaction with flame retardants and the conductive effect is lost.
更に、このハロゲン系の難燃剤が含有されている場合に
は、燃焼時、多量の有害ガス（例えばハロゲンガス）が
放出され、人畜に有害であるのみならず、使用機器の金
属腐食等を起こす恐れがある。Furthermore, if this halogen-based flame retardant is contained, a large amount of harmful gas (e.g. halogen gas) is released during combustion, which is not only harmful to humans and animals, but also causes metal corrosion of the equipment used. There is a fear.
僅かに、有機系の導電性付与剤の場合、例えばポリアニ
リン、アントラセン化合物が挙げられ、非黒色物を得る
ことができるが、この付与剤にあっても、燃焼時、やは
り有害ガスを放出するという問題がある。In the case of organic conductivity-imparting agents, for example polyaniline and anthracene compounds, non-black materials can be obtained, but even these agents still emit harmful gases when burned. There's a problem.
つまり、従来の組成物には、導電性、非黒色、非有害ガ
ス発生（安全性）のすべてを満足させるものが得られて
いない。In other words, conventional compositions have not been able to satisfy all of the requirements of conductivity, non-black color, and non-toxic gas generation (safety).
本発明は、このような実情に鑑みてなされたもので、上
記導電性、非黒色、非有害ガス発生（安全性）のすべて
の点を満足させた樹脂組成物を提供せんとするものであ
る。The present invention has been made in view of these circumstances, and aims to provide a resin composition that satisfies all of the above-mentioned electrical conductivity, non-black color, and non-toxic gas generation (safety). .
く問題点を解決するための手段及びその作用〉か−る本
発明の特徴とする点は、 ゴム、プラスチック１００重
量部と、導電性金属酸化物又は／及び金属微粒子５０〜
２００重量部と、無機含水化合物２０〜２００重量部と
からなる樹脂組成物にある。100 parts by weight of rubber or plastic, and 50 to 50 parts of conductive metal oxide or/and metal fine particles.
200 parts by weight, and 20 to 200 parts by weight of an inorganic hydrous compound.
ここで、導電性付与剤の金属酸化物としては、酸化亜鉛
、酸化錫等に微量のアルミ化合物をドープして導電性を
持たせたものが挙げられる。又。Here, examples of the metal oxide of the conductivity imparting agent include zinc oxide, tin oxide, etc. doped with a trace amount of an aluminum compound to impart conductivity. or.
金属微粒子としては、金、銀、銅、ニッケル、鉄或いは
これらの金属元素を含有してなる合金の粉末、繊維、箔
等が挙げられる。そして、その配合量は５０〜２００重
量部が好ましい。つまり、５０重量部未満では、十分な
導電性が得られず、２００重量部を越えると、物理特性
が低下し、且つ成形性が劣悪となるからである。Examples of the metal fine particles include powders, fibers, and foils of gold, silver, copper, nickel, iron, or alloys containing these metal elements. The blending amount thereof is preferably 50 to 200 parts by weight. That is, if it is less than 50 parts by weight, sufficient electrical conductivity cannot be obtained, and if it exceeds 200 parts by weight, the physical properties will deteriorate and the moldability will become poor.
尚、本発明では、必要により、帯電防止剤や界面活性剤
を添加することができる。In the present invention, an antistatic agent or a surfactant may be added if necessary.
上記無機含水化合物としは、特に限定されないが、実用
的には、水酸化アルミニウム、水酸化マグネシウム、水
酸化カルシウム、塩基性炭酸マグネシウムが好ましく、
組成物中にあって難燃作用を発揮する。そして、その配
合量は２０〜２００重量部が好ましい。つまり、２０重
量部未満では、十分な難燃効果が得られず、２００重量
部を越えると、物理特性の低下、成形加工性の低下等の
弊害がでるからである。勿論、この範囲での配合の場合
、無機含水化合物によって、導電性が損なわれることは
なかった。The above-mentioned inorganic hydrous compound is not particularly limited, but for practical purposes, aluminum hydroxide, magnesium hydroxide, calcium hydroxide, and basic magnesium carbonate are preferable.
It is present in the composition and exhibits a flame retardant effect. The blending amount thereof is preferably 20 to 200 parts by weight. That is, if it is less than 20 parts by weight, a sufficient flame retardant effect cannot be obtained, and if it exceeds 200 parts by weight, adverse effects such as deterioration of physical properties and deterioration of moldability will occur. Of course, in the case of blending within this range, the conductivity was not impaired by the inorganic hydrous compound.
このように本発明の樹脂組成物には、ハロゲン系難燃剤
が添加されていないため、有害ガスの発生はなく、又導
電性付与剤としてカーボンブランクが使用されていない
ため、導電性で、且つ非黒色の組成物が得られる。In this way, the resin composition of the present invention does not contain any halogenated flame retardants, so no harmful gases are generated, and since no carbon blank is used as a conductivity imparting agent, it is conductive and A non-black composition is obtained.
又、本発明で使用されるゴム、プラスチックとしては、
低密度ポリエチレン、高密度ポリエチレン、ＥＶＡ、Ｅ
ＥＡ、、ＥＰＴ、ポリプロピレン、α−オレフィン共重
合体、ポリスチレン及びこれらの共重合体、ブチルゴム
、アクリルゴム等の合成ゴム、天然ゴム等が挙げられる
。更に、必要に応じて、他の添加剤、例えば通常よく用
いられる軟化剤、滑剤等の加工助剤、発泡剤等を添加す
ることができる。In addition, the rubber and plastic used in the present invention include:
Low density polyethylene, high density polyethylene, EVA, E
Examples include EA, EPT, polypropylene, α-olefin copolymers, polystyrene and copolymers thereof, synthetic rubbers such as butyl rubber and acrylic rubber, and natural rubber. Furthermore, other additives such as commonly used processing aids such as softeners and lubricants, foaming agents, etc. can be added as necessary.
〈実施例〉
以下に示した各表の組成物を作成し、その特性を測定し
た。尚、導電性（体積抵抗率：Ω・Ｃｍ）はホイートス
トンブリッジにより測定し、又難燃性（自己消火性）は
酸素測定装置で大気中での燃焼の可否を調べて行った。<Example> Compositions shown in each table below were prepared and their properties were measured. The conductivity (volume resistivity: Ω·Cm) was measured using a Wheatstone bridge, and the flame retardancy (self-extinguishing property) was measured using an oxygen measuring device to determine whether or not it could burn in the atmosphere.
又、各表において、配合比は重量部数による。自己消火
性において、○は消火を示し、×は燃焼を示す。In addition, in each table, the compounding ratio is based on parts by weight. Regarding self-extinguishing properties, ○ indicates extinguishing, and × indicates combustion.
第 ４ 表 （実施例１１〜１２、比較例６）＊９ ニ
ブラスチック用帯電防止剤、丸菱油化社製 、又、上記
実施例１及び１２の組成物に赤色顔料（ウオッチングレ
ッド１％）を配合したところ、各特性には全（変化がな
く、色調のみが赤となった。Table 4 (Examples 11-12, Comparative Example 6) ), there was no change in all of the properties, and only the color became red.
〈発明の効果〉
以上の説明から明らかなように本発明によれば、導電性
、非黒色、非有害ガス発生（安全性）のすべての点を満
足させた樹脂組成物を提供することができる。<Effects of the Invention> As is clear from the above description, according to the present invention, it is possible to provide a resin composition that satisfies all aspects of conductivity, non-black color, and non-toxic gas generation (safety). .
り、・１１．・／′ −一し・11.・／′ -Ichishi
Claims (1)
又は／及び金属微粒子５０〜２００重量部と、無機含水
化合物２０〜２００重量部とからなる樹脂組成物。A resin composition comprising 100 parts by weight of rubber or plastic, 50 to 200 parts by weight of a conductive metal oxide or/and metal fine particles, and 20 to 200 parts by weight of an inorganic hydrous compound.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23748586A JPS6390567A (en) | 1986-10-06 | 1986-10-06 | Resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23748586A JPS6390567A (en) | 1986-10-06 | 1986-10-06 | Resin composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6390567A true JPS6390567A (en) | 1988-04-21 |
Family
ID=17016023
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23748586A Pending JPS6390567A (en) | 1986-10-06 | 1986-10-06 | Resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6390567A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20040046039A (en) * | 2002-11-26 | 2004-06-05 | 김경용 | resin composition with gold dust, method of manufacturing the same and it's use |
-
1986
- 1986-10-06 JP JP23748586A patent/JPS6390567A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20040046039A (en) * | 2002-11-26 | 2004-06-05 | 김경용 | resin composition with gold dust, method of manufacturing the same and it's use |
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