JPS5835578A - Method for duplicating hologram - Google Patents

Method for duplicating hologram

Info

Publication number
JPS5835578A
JPS5835578A JP13498781A JP13498781A JPS5835578A JP S5835578 A JPS5835578 A JP S5835578A JP 13498781 A JP13498781 A JP 13498781A JP 13498781 A JP13498781 A JP 13498781A JP S5835578 A JPS5835578 A JP S5835578A
Authority
JP
Japan
Prior art keywords
resin
mold
hologram
base sheet
rays
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP13498781A
Other languages
Japanese (ja)
Inventor
Toshiji Fujita
藤田 利治
Yoshio Nagashima
長嶋 良夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toppan Inc
Original Assignee
Toppan Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toppan Printing Co Ltd filed Critical Toppan Printing Co Ltd
Priority to JP13498781A priority Critical patent/JPS5835578A/en
Publication of JPS5835578A publication Critical patent/JPS5835578A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03HHOLOGRAPHIC PROCESSES OR APPARATUS
    • G03H1/00Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
    • G03H1/02Details of features involved during the holographic process; Replication of holograms without interference recording

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Holo Graphy (AREA)

Abstract

PURPOSE:To duplicate a hologram of high precision with a small amount of energy in a short time, by using a liquid or semiliquid resin hardening upon absorbing radiation, especially UV rays without using a thermoplastic resin. CONSTITUTION:A UV hardenable resin 3 is placed between the patterned face 5 of a mold 4 made by plating a relief hologram with hickel or the like, and an opposite plate 1 made of UV transmitting glass or the like and a base sheet 2 in contact with the plate 1. Polyvinyl chloride or acrylic resin good in adhesion to the resin 3, small in absorption of UV rays, and almost equal to the resin 3 in reflective index is suitable for the base sheet 2. The resin 3 comprises a prepolymer having a radically polymerizable unsatd. group, an ethylenically unsatd. monomer, a polymerization initiatior, and an adjuvant. The resin 3 is sandwiched between the mold 4 and the sheet 2, pressed to enlarge it, and irradiated by UV rays from a UV lamp 6, thus permitting the resin 3 to be hardened in 2-5 sec without deforming, and separated from the mold 4.

Description

【発明の詳細な説明】 本発明はホログラムの複製方法に関するものである。ホ
ログラムは通常銀塩感材上に作られるが、ホログラムパ
ターンを凹凸で成形しても得られる。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for replicating a hologram. Holograms are usually made on silver salt photosensitive materials, but they can also be obtained by molding hologram patterns with irregularities.

すなわち、フォトレジストを塗布した乾板にホログラム
像を露光した後、現像して乾板上に凹凸像を得る。しか
るのち、こ・の像を形成している凹凸面上に銅を蒸着し
て、導電性を付与する。続いてこの銅面を負極としてニ
ッケルメッキを施す。取扱いに耐え得る厚さまでニッケ
ル層を電着した後にこれを感光剤面より剥離し、次いで
導電性を与えるために、蒸着した銅を溶解して取り除き
、ニッケルの面を露呈させ、成形用の型が得られる。
That is, a hologram image is exposed to light on a dry plate coated with photoresist, and then developed to obtain a concavo-convex image on the dry plate. Thereafter, copper is deposited on the uneven surface forming this image to impart electrical conductivity. Next, nickel plating is applied using this copper surface as a negative electrode. After a nickel layer is electrodeposited to a thickness that can withstand handling, it is peeled off from the photosensitive material surface, and then, in order to provide conductivity, the deposited copper is melted away to expose the nickel surface, which is then placed in a mold for molding. is obtained.

銅を除去した型の表面には前述の露光・現像により得ら
れた凹凸面が凹凸逆になって複製されている。
On the surface of the mold from which the copper has been removed, the uneven surface obtained by the above-mentioned exposure and development is duplicated with the unevenness reversed.

この面も、ホログラム像を形成することは、もちろんで
ある。
Of course, this surface also forms a hologram image.

この様にして得られた型によって多数のホログラムを複
製する方法は、従来は熱可塑性樹脂を素材とし、これに
加熱回圧の熱リサイクルを適用する方法に依っていた。
Conventionally, the method of replicating a large number of holograms using a mold obtained in this manner has relied on a method of using thermoplastic resin as a material and applying heat recycling by heating and pressure to the material.

例えば、0.2〜0.5龍の厚みの塩化ビニル樹脂を、
表面温度110〜130℃にした前記型に対し150〜
20019’dに加圧し、数秒から数10秒間この状態
を保ち、而る後に前記型及び対盤を冷却して常温にする
For example, vinyl chloride resin with a thickness of 0.2 to 0.5 mm,
150~150℃ for the above mold whose surface temperature was 110~130℃
Pressure is applied to 20019'd, this state is maintained for several seconds to several tens of seconds, and then the mold and counter plate are cooled to room temperature.

この際、当然成型された塩ビシートも常温になりている
ので、これを取り出すことによりホログラム複製版が得
られるのである。
At this time, the molded PVC sheet is naturally at room temperature, so by taking it out, a hologram reproduction plate can be obtained.

以上は、従来の熱リサイクルによる成型の一例で、素材
としては塩化ビニル樹脂に限らず、アク可能ではない。
The above is an example of conventional molding using heat recycling, and the material is not limited to vinyl chloride resin and is not acrylicable.

また前原の例のようにシート状にあらかじめ成形されて
いる樹脂を加圧成形するのではなく、熔融した樹脂を型
内に射出させるインジェクション成型による複製も可能
であった。
In addition, it was also possible to reproduce by injection molding, in which molten resin was injected into a mold, instead of pressure molding a sheet of resin as in Maehara's example.

これらの方法は、すべて熱により可塑性を付与された樹
脂を成型するものであるが、いずれの場合においても、
成形された複製物をとり出す時の温度は常温に近いもの
でなくてはならない。
All of these methods involve molding resin that has been given plasticity by heat, but in each case,
The temperature at which the molded replica is taken out must be close to room temperature.

従って型及び対盤は一回の成形毎に成形に必要な温度ま
で上昇させ、かつ一定の時間この温度を保ち、而る後に
常温近くまで冷却するという熱0・リサイクルによって
複製を行なっている。通常の場合このサイクルは2@〜
60秒を要している。
Therefore, duplication is performed by zero-heat recycling, in which the temperature of the mold and counter-plate is raised to the temperature required for molding each time, maintained at this temperature for a certain period of time, and then cooled to near room temperature. Normally this cycle is 2@~
It takes 60 seconds.

一方、ホログラムの回折格子は1 mm当り1000〜
3000本という極微細な間隔で形成されているため従
来の熱リサイクルによる成形では、型の凹凸を成形品に
完全に転写・複製することは困難で一般に型に対する成
形性は完全ではない。従って製品の収率も良くながった
On the other hand, the diffraction grating of a hologram is 1000 ~
Because they are formed at extremely fine intervals of 3,000 lines, it is difficult to completely transfer and replicate the unevenness of the mold onto the molded product using conventional thermal recycling molding, and the moldability against the mold is generally not perfect. Therefore, the product yield also improved.

このように、従来の加熱・押圧・冷却というプロセスに
従えば、成型時間と成型性という欠陥を担っており、ホ
ログラムを製造する上で大きな問題となっている。
As described above, if the conventional process of heating, pressing, and cooling is followed, it suffers from defects in molding time and moldability, which poses a major problem in manufacturing holograms.

本発明は、このような熱成形性の樹脂を使用せず、放射
線、特に紫外線を吸収して硬化するタイプの液状又は半
固体状の樹脂を用いて、ホログラム像を成形することを
可能ならしめた。本発明の方法によれば、加熱・押圧・
冷却工程を経て製造されたホログラム像に比べ、その製
造時間は著しく短縮され、製造に要するエネルギーも少
なくて済み、しかも極めて高精度に、成形(複製)でき
る等の効果を発揮するものである6 以下に本発明の一実施例を図面に基づいて説明する。
The present invention makes it possible to mold a hologram image by using a liquid or semi-solid resin that hardens by absorbing radiation, especially ultraviolet rays, without using such thermoformable resin. Ta. According to the method of the present invention, heating, pressing,
Compared to hologram images manufactured through a cooling process, the manufacturing time is significantly shorter, less energy is required for manufacturing, and they can be molded (duplicated) with extremely high precision.6 An embodiment of the present invention will be described below based on the drawings.

第1図は、本発明にががる成形方法を示す模式的説明図
である。例えば前述した工程により得られかつ紫外線吸
収の少ない材質例えば塩化ビニル樹脂、アクリル樹脂等
が適しており、更に加えて、硬化した樹脂層とほぼ等し
い屈折率をもっているものであることが好ましい。なお
、基材シートについては、紫外線を透過させることが前
提となるが、着色してあっても差支えない。この場合、
特殊な効果を求めることもできる。
FIG. 1 is a schematic explanatory diagram showing a molding method according to the present invention. For example, materials such as vinyl chloride resin, acrylic resin, etc. that are obtained by the above-mentioned process and have low ultraviolet absorption are suitable, and in addition, it is preferable that the material has a refractive index approximately equal to that of the cured resin layer. Note that the base sheet is required to transmit ultraviolet rays, but it may be colored. in this case,
You can also request special effects.

次に紫外線硬化型樹脂について一説明すると、その構成
は、ラジカル重合性の不飽和基を有するプレホリマート
エチレン硅の不飽和基をもっモノマーを主成分とし、そ
れに若干の重合開始剤と助剤を加えた構成で250〜3
8oW11Nの領域、特に360mk付近の紫外光を照
射することによりモノマーが線状ポリマー間を架橋して
、三次元の網目構造を形成するものである。このような
プレポリマーとしては、例えば、エポキシアクリレート
、つ・レタンアクリレート、等があり、七ツマ−の例と
しては、n−ブチルアクリレート・n−ブチルメタアク
リレート等がある。
Next, to explain about ultraviolet curable resin, its composition is mainly composed of monomers with unsaturated groups such as preformed ethylene silica having radically polymerizable unsaturated groups, and some polymerization initiators and auxiliary agents. 250-3 with the configuration including
By irradiating ultraviolet light in the 8oW11N region, particularly around 360mK, the monomer crosslinks the linear polymers to form a three-dimensional network structure. Examples of such prepolymers include epoxy acrylate, diurethane acrylate, and the like, and examples of hexamers include n-butyl acrylate and n-butyl methacrylate.

この様な紫外線硬化型樹脂(3)を第1図に示す様に配
置し、型(4)を下降又は対盤(1)及び基材シート(
2)を上昇させつつ、型(4)と基材シート(2)の間
に、紫外線硬化型樹脂をはさみつける形で押圧する。
The ultraviolet curable resin (3) is placed as shown in Figure 1, and the mold (4) is lowered or placed on the opposing plate (1) and the base sheet (
2) is pressed between the mold (4) and the base sheet (2) so that the ultraviolet curable resin is sandwiched between the mold (4) and the base sheet (2).

流動性の高い紫外線硬化型樹脂は基材シート上面に拡が
って5すく延ばされると同時に、上側の型(4)のパタ
ーン面(5)に接して拡がり、接面に於いて型(4)の
パターン(5)通りに埋まっていく。紫外線硬線硬化型
樹脂層の厚みは1〜70μmとし、好ましくは25μm
以下である。これは単に樹脂の節約だけでなく、より本
質的には成形後の変形を避け為でもある。紫外光の照射
は2 kWの超高圧水銀灯で照射距離25′ホの場合、
2〜5秒で良く、より強力な紫外光であれば1秒又はそ
れ以下にすることも可能である。
The highly fluid ultraviolet curable resin spreads on the top surface of the base sheet and is extended by 5 squares, and at the same time spreads in contact with the patterned surface (5) of the upper mold (4), and on the contact surface, it spreads into the patterned surface (5) of the mold (4). It fills up according to pattern (5). The thickness of the ultraviolet hard line curable resin layer is 1 to 70 μm, preferably 25 μm.
It is as follows. This is not only to save resin, but also to avoid deformation after molding. When irradiating ultraviolet light with a 2 kW ultra-high pressure mercury lamp and an irradiation distance of 25',
The time may be 2 to 5 seconds, and if the UV light is more intense, the time may be 1 second or less.

紫外線照射を完了した紫外線硬化型樹脂層は基材シー”
ト(2)に強固に接着し、型(4)のパターン(5)面
ν からは容易に剥離する。剥離された基材シート(2)と
紫外線硬化型樹脂(3)との合体は第2図に示されるよ
うな断面を呈するホログラムとなる。
After UV irradiation, the UV curable resin layer becomes the base material.
It firmly adheres to the pattern (2) and easily peels off from the pattern (5) surface ν of the mold (4). The peeled base sheet (2) and the ultraviolet curing resin (3) combine to form a hologram having a cross section as shown in FIG.

本発明は以上の如き構成で、この様な方法でホログラム
を作成すると、熱のリサイクルが不必要となり、そのた
めに成形時間が短縮され、大量複製が容易に行なえるよ
うになる。またその製品はその凹凸面を含む層つまり紫
外線硬化型樹脂層を完全架橋させた場合には、通常の熱
可塑性樹脂より硬度が高くなり、従ってスクラッチ強度
も従来の成形方法による製品に比べ数段向上している。
The present invention has the above-described configuration, and when a hologram is produced by such a method, there is no need to recycle heat, which shortens the molding time and facilitates mass duplication. In addition, when the layer containing the uneven surface, that is, the ultraviolet curable resin layer, is completely crosslinked, the product has a higher hardness than ordinary thermoplastic resin, and therefore has a much higher scratch resistance than products made using conventional molding methods. It's improving.

また、その凹凸面の複製精度も極めて良好であるが、こ
れは、紫外線硬化型樹脂が液状で型のパターンによくな
じみ、そのまま成形されるからである。
Furthermore, the reproduction accuracy of the uneven surface is extremely good, because the ultraviolet curable resin is liquid and blends well with the pattern of the mold, allowing it to be molded as is.

さらに、熱リサイクルによる成形の場合には、素材とな
る樹脂内に不純物あるいは固化樹脂等の混入が避けられ
ず、そのために不良品を生じるが本方法によれば、紫外
線硬化型樹脂は使用直前に濾過することが可能で微細な
混入物までも除去することができるので、欠陥の殆んど
ない成形面が得られる。
Furthermore, in the case of molding by thermal recycling, it is unavoidable that impurities or solidified resin etc. get mixed into the resin material, which results in defective products, but according to this method, the UV-curable resin is Since it can be filtered and even minute contaminants can be removed, a molded surface with almost no defects can be obtained.

なお用途によっては、本方法によって成形した面に真空
蒸着又はスパッタリング等によって金属薄膜を設けるこ
とも可能で、この場合、反射型のホログラムとなる。
Note that depending on the application, it is also possible to provide a thin metal film on the surface formed by this method by vacuum evaporation or sputtering, and in this case, a reflection type hologram is obtained.

本発明によるホログラムは、紫外線硬化型樹脂層(凹凸
はこの部分にある)と基材シートから成る2層構造であ
るが、上述のような長所を有する紫外線硬化型樹脂は、
かなり高価なものであるが、本発明では成形層に、ごく
薄い層としてのみ使用するものであるので、コスト的に
は十分見合うものである。
The hologram according to the present invention has a two-layer structure consisting of an ultraviolet curable resin layer (the unevenness is in this part) and a base sheet.
Although it is quite expensive, in the present invention it is used only as a very thin layer in the molding layer, so it is well worth the cost.

また、透過形ホログラフィ−として鑑賞する置台、2層
構造であるために、2層の境界部分で屈折が起こるわけ
であるが、紫外線硬化型樹脂層の屈折率1.50に対し
、基材シートの屈折率は例★ば塩どの場合t54、また
アクリル樹脂の場合1.49であり、実質的に問題にな
らない。
In addition, since the stand used for viewing transmission holography has a two-layer structure, refraction occurs at the boundary between the two layers. For example, the refractive index of ★ is t54 in the case of salt, and 1.49 in the case of acrylic resin, so it is not a substantial problem.

【図面の簡単な説明】[Brief explanation of drawings]

図面は本発明の一実施例を示すもので、第11!−は本
発明方法の模式的説明図、第2図は本発明ノ法により得
られたホログラムの断面を示す説明代である。 (1)・・・・・・・・・対振、  (2)・・・・・
・・・・基材シート(3)・・・・・・・・・・・紫外
線硬化型樹脂、  (4)・・・・・・・・型、(S)
・・・・・・・・・・・パターン特許出願人 几阻印211捗才△姓 第1図 を 第2図
The drawings show one embodiment of the present invention, and are shown in the 11th! - is a schematic explanatory diagram of the method of the present invention, and FIG. 2 is an illustration showing a cross section of a hologram obtained by the method of the present invention. (1)・・・・・・Counter vibration, (2)・・・・・・
...Base material sheet (3) ......Ultraviolet curing resin, (4) ......Mold, (S)
・・・・・・・・・Pattern patent applicant's name 211 result name △ surname 1st figure 2nd figure

Claims (1)

【特許請求の範囲】[Claims] ホログラムの型に於けるパターン面と基材シートとの間
に紫外線硬化型樹脂を置き、ノくター/面と基材、シー
トとを近接せしめ、紫外線硬化型樹脂をはさみつけつつ
両面から押圧し、ノくターン面及び基材シート面上に該
樹脂が十分に拡がった時点で基材シートを通して紫外線
を照射し、而る後硬化した紫外線硬化型樹脂層を基材シ
ートとともに型のパターン面から剥離してなるホログラ
ムの複製方法。
Place an ultraviolet curable resin between the patterned surface of the hologram mold and the base sheet, bring the nozzle surface, base material, and sheet close to each other, and press from both sides while sandwiching the ultraviolet curable resin. When the resin has sufficiently spread on the turn surface and the base sheet surface, ultraviolet rays are irradiated through the base sheet, and then the cured ultraviolet curable resin layer is exposed along with the base sheet from the patterned surface of the mold. A method of replicating a peeled hologram.
JP13498781A 1981-08-28 1981-08-28 Method for duplicating hologram Pending JPS5835578A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13498781A JPS5835578A (en) 1981-08-28 1981-08-28 Method for duplicating hologram

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13498781A JPS5835578A (en) 1981-08-28 1981-08-28 Method for duplicating hologram

Publications (1)

Publication Number Publication Date
JPS5835578A true JPS5835578A (en) 1983-03-02

Family

ID=15141273

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13498781A Pending JPS5835578A (en) 1981-08-28 1981-08-28 Method for duplicating hologram

Country Status (1)

Country Link
JP (1) JPS5835578A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60254175A (en) * 1984-05-31 1985-12-14 Dainippon Printing Co Ltd Hologram transfer sheet and its production
JPS60254174A (en) * 1984-05-31 1985-12-14 Dainippon Printing Co Ltd Duplicating method of hologram
JPS619681A (en) * 1984-06-25 1986-01-17 Dainippon Printing Co Ltd Hologram seal
US4758296A (en) * 1983-06-20 1988-07-19 Mcgrew Stephen P Method of fabricating surface relief holograms
US4906315A (en) * 1983-06-20 1990-03-06 Mcgrew Stephen P Surface relief holograms and holographic hot-stamping foils, and method of fabricating same
KR100337809B1 (en) * 2000-04-12 2002-05-23 임기택 The double width hologram a plastic shim production a method
US8974613B2 (en) 2007-09-28 2015-03-10 Ntn Corporation Method of quenching a ring-shaped article and apparatus therefor

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5040050A (en) * 1973-07-19 1975-04-12
JPS5122403A (en) * 1974-08-17 1976-02-23 Teac Corp

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5040050A (en) * 1973-07-19 1975-04-12
JPS5122403A (en) * 1974-08-17 1976-02-23 Teac Corp

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4758296A (en) * 1983-06-20 1988-07-19 Mcgrew Stephen P Method of fabricating surface relief holograms
US4906315A (en) * 1983-06-20 1990-03-06 Mcgrew Stephen P Surface relief holograms and holographic hot-stamping foils, and method of fabricating same
JPS60254175A (en) * 1984-05-31 1985-12-14 Dainippon Printing Co Ltd Hologram transfer sheet and its production
JPS60254174A (en) * 1984-05-31 1985-12-14 Dainippon Printing Co Ltd Duplicating method of hologram
JPS619681A (en) * 1984-06-25 1986-01-17 Dainippon Printing Co Ltd Hologram seal
KR100337809B1 (en) * 2000-04-12 2002-05-23 임기택 The double width hologram a plastic shim production a method
US8974613B2 (en) 2007-09-28 2015-03-10 Ntn Corporation Method of quenching a ring-shaped article and apparatus therefor
US9453268B2 (en) 2007-09-28 2016-09-27 Ntn Coproration Apparatus to quench a ring-shaped article
US9580765B2 (en) 2007-09-28 2017-02-28 Ntn Corporation Deformation correcting device

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