JPS55102528A - Preparation of carbonyl compound - Google Patents
Preparation of carbonyl compoundInfo
- Publication number
- JPS55102528A JPS55102528A JP964079A JP964079A JPS55102528A JP S55102528 A JPS55102528 A JP S55102528A JP 964079 A JP964079 A JP 964079A JP 964079 A JP964079 A JP 964079A JP S55102528 A JPS55102528 A JP S55102528A
- Authority
- JP
- Japan
- Prior art keywords
- vicinal diol
- catalyst
- oxidizing agent
- preparation
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE: To obtain the title compound economically in high yield and selectively by the oxidative decomposition of a vicinal diol with H2O2, hydroperoxides, peroxides or an O2-containing gas, in the presence of a catalyst comprising Ru or its compound.
CONSTITUTION: Preparation of an aldehyde (e.g. adipaldehyde, etc.), a ketone or a carboxylic acid by the oxidative decomposition of a vicinal diol (e.g. 1,2-cyclohexanediol, etc.) with an oxidizing agent, characterized in that said oxidizing agent is selected from hydrogen peroxide, hydroperoxides, peroxides and a gas containing molecular oxygen and the reaction is carried out in the presence of a catalyst comprising Ru or its compound (e.g. RuCl3, etc.). The catalyst is preferably used in an amount of 0.001W0.1 gram atom as the metal atom to one mole of the vicinal diol, and the oxidizing agent is preferably used in an amount of 10W0.1mol to one mole of the vicinal diol. The reaction is carried out at 0W150°C. A vicinal diol of alicyclic series or a saccharide is suitable as the vicinal diol.
COPYRIGHT: (C)1980,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP964079A JPS55102528A (en) | 1979-02-01 | 1979-02-01 | Preparation of carbonyl compound |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP964079A JPS55102528A (en) | 1979-02-01 | 1979-02-01 | Preparation of carbonyl compound |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS55102528A true JPS55102528A (en) | 1980-08-05 |
Family
ID=11725814
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP964079A Pending JPS55102528A (en) | 1979-02-01 | 1979-02-01 | Preparation of carbonyl compound |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS55102528A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1994021690A2 (en) * | 1993-03-25 | 1994-09-29 | Instituut Voor Agrotechnologisch Onderzoek (Ato-Dlo) | Method for the oxidation of vicinal diols, including carbohydrates |
WO2000053554A1 (en) * | 1999-03-09 | 2000-09-14 | Daicel Chemical Industries, Ltd. | Process for producing aldehydes |
JP2020066594A (en) * | 2018-10-24 | 2020-04-30 | 旭化成株式会社 | Method for producing dialdehyde |
-
1979
- 1979-02-01 JP JP964079A patent/JPS55102528A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1994021690A2 (en) * | 1993-03-25 | 1994-09-29 | Instituut Voor Agrotechnologisch Onderzoek (Ato-Dlo) | Method for the oxidation of vicinal diols, including carbohydrates |
NL9300540A (en) * | 1993-03-25 | 1994-10-17 | Inst Voor Agrotech Onderzoek | Method for oxidizing carbohydrates. |
WO1994021690A3 (en) * | 1993-03-25 | 1994-11-24 | Inst Voor Agrotech Onderzoek | Method for the oxidation of vicinal diols, including carbohydrates |
WO2000053554A1 (en) * | 1999-03-09 | 2000-09-14 | Daicel Chemical Industries, Ltd. | Process for producing aldehydes |
JP2020066594A (en) * | 2018-10-24 | 2020-04-30 | 旭化成株式会社 | Method for producing dialdehyde |
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