JPH0725622B2 - Method for producing organic matter-containing fertilizer - Google Patents
Method for producing organic matter-containing fertilizerInfo
- Publication number
- JPH0725622B2 JPH0725622B2 JP23417989A JP23417989A JPH0725622B2 JP H0725622 B2 JPH0725622 B2 JP H0725622B2 JP 23417989 A JP23417989 A JP 23417989A JP 23417989 A JP23417989 A JP 23417989A JP H0725622 B2 JPH0725622 B2 JP H0725622B2
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- Prior art keywords
- fertilizer
- organic matter
- soybean
- granulation
- granular fertilizer
- Prior art date
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Description
【発明の詳細な説明】 [発明の分野] 本発明は、有機物を含有している化成肥料の製造方法に
関する。Description: FIELD OF THE INVENTION The present invention relates to a method for producing a chemical fertilizer containing an organic substance.
[発明の背景] 近年、肥料の高機能化のために、化成肥料に有機物を配
合することが行なわれている。最近では、さらに有機物
の配合割合を高くし、たとえば有機物を30重量%以上含
有する化成肥料が望まれている。一方、農作業の省力化
およびコスト低減の必要から、側条施肥、動力散布など
のような機械施肥が普及しつつあり、該機械施肥に適し
た流動性が高く、容易に粉化しない粒子硬度を有する肥
料が望まれる。BACKGROUND OF THE INVENTION In recent years, in order to enhance the functionality of fertilizers, compounding fertilizers with organic substances has been carried out. Recently, there has been a demand for a chemical fertilizer containing a higher proportion of organic substances, for example, containing 30% by weight or more of organic substances. On the other hand, because of the need for labor saving and cost reduction in agricultural work, side fertilization, mechanical fertilization such as power spraying is becoming widespread, and the fluidity suitable for the mechanical fertilization is high, and the particle hardness that does not easily powder is used. A fertilizer to have is desired.
有機物を含有する化成肥料は、一般に有機物と無機系化
成肥料とを適量配合し、混合機にてさらに水または無機
系化成肥料成分の塩(以下、肥料塩と略記することがあ
る)の水溶液などの水性媒体を加え、被造粒物(肥料粉
末)を相互に付着させた後、転動造粒機で造粒すること
により製造されている。An organic matter-containing chemical fertilizer is generally prepared by mixing an appropriate amount of an organic matter and an inorganic chemical fertilizer, and further using a mixer, an aqueous solution of water or a salt of an inorganic chemical fertilizer component (hereinafter sometimes abbreviated as a fertilizer salt). It is manufactured by adding the aqueous medium of (1), adhering the granules (fertilizer powder) to each other, and then granulating with a tumbling granulator.
上述の方法では、水または肥料塩水溶液が、転動造粒の
際に無機系化成肥料成分の一部を溶解することにより、
水性媒体による肥料成分粘着作用が増大する。そして、
上記増大した粘着作用により、化成肥料粉末が有機物を
取り込みながら相互に結合して、粒状化が進行する。In the above method, water or fertilizer salt aqueous solution, by dissolving a part of the inorganic chemical conversion fertilizer components during rolling granulation,
The adhesive action of the fertilizer component by the aqueous medium is increased. And
Due to the increased adhesive action, the chemical fertilizer powder binds with each other while taking in the organic matter, and the granulation proceeds.
ところが、有機物の配合量が増加して、例えば全体の30
重量%程度以上になると、相対的に無機系化成肥料成分
が減少するので、該無機系化成肥料成分が溶解して得ら
れる水性媒体の粘着性が充分に得られなくなることがあ
る。上記水性媒体の粘着性が不充分であると、造粒自体
が困難になったり、得られた造粒物の粒子硬度が低下
し、あるいは、造粒後の乾燥または機械施肥の際に粉化
しやすくなるという問題がある。However, the amount of organic substances added increased, for example,
When the content is more than about 10% by weight, the amount of the inorganic chemical fertilizer component is relatively decreased, so that the tackiness of the aqueous medium obtained by dissolving the inorganic chemical fertilizer component may not be sufficiently obtained. If the tackiness of the aqueous medium is insufficient, the granulation itself becomes difficult, or the particle hardness of the obtained granules decreases, or powdered during drying or mechanical fertilization after granulation. There is a problem that it becomes easier.
有機物の配合割合の高い肥料を粒状化する方法として
は、圧縮ロール、ブリケッティングロール、ペレタイザ
ーなどを用いて圧縮成形する方法が知られているが、圧
縮成形によって得られた粒子は、通常ペレット状である
ために流動性が低く、機械施肥が実施しにくい。As a method of granulating a fertilizer with a high organic compounding ratio, a method of compression molding using a compression roll, a briquetting roll, a pelletizer, etc. is known, but the particles obtained by compression molding are usually pellets. Since it is in a shape, it has low fluidity and is difficult to apply by mechanical fertilization.
なお、本明細書において、「粒状」とは、球状もしくは
球状に近く実質的に角ばった部分がない形状を意味し、
「ペレット状」とは、円盤状、円柱状、もしくは凸レン
ズ状であって角ばった部分が有ってもよい形状を意味す
る。In the present specification, the term "granular" means a spherical shape or a shape that is substantially spherical and has substantially no angular portion,
The “pellet shape” means a disk shape, a column shape, or a convex lens shape that may have angular portions.
そこで、有機物を多く含有する肥料に、さらにポリビニ
ルアルコール水溶液、リグニン液、または廃糖蜜液など
の粘着性を有する液体を添加し、上記液体を媒体として
転動造粒を行なうことが提案されている。上記液体を媒
体として使用すれば転動造粒が可能になるが、ポリビニ
ルアルコール水溶液を使用した場合にはポリビニルアル
コール自体が肥料原料に比べて高価であるために肥料製
造のコストが高くなり、リグニン液、または廃糖蜜液を
使用した場合には粒子硬度はある程度高くなるものの無
機物を多く付着結合して造粒し、得られた造粒物の有機
物の含有率が低下したり、粒度分布が広くなって比較的
大きな粒子が多くなる傾向がある。Therefore, it has been proposed to add a viscous liquid such as an aqueous polyvinyl alcohol solution, a lignin liquid, or a molasses liquid to a fertilizer containing a large amount of organic matter, and perform rolling granulation using the liquid as a medium. . Rolling granulation is possible by using the above liquid as a medium, but when polyvinyl alcohol aqueous solution is used, the cost of fertilizer production increases because the polyvinyl alcohol itself is expensive compared to the fertilizer raw material, and lignin is used. When liquid or molasses liquid is used, the particle hardness increases to a certain degree, but a large amount of inorganic substances are adhered and bound for granulation, resulting in a decrease in the content of organic substances in the granulated product or a wide particle size distribution. There is a tendency that the number of relatively large particles increases.
一方、特公昭64−11599号公報には、大豆から、豆乳、
豆腐などを製造する工程にて分離される大豆濾滓を粉状
肥料と混練することを特徴とする粒状肥料の製造方法が
開示されている。上記大豆濾滓は、水分を83%前後含有
する。On the other hand, Japanese Patent Publication No. 64-11599 discloses that soybeans, soy milk,
Disclosed is a method for producing granular fertilizer, which comprises kneading soybean cake separated in the step of producing tofu or the like with powdered fertilizer. The soybean cake contains about 83% of water.
上記公報の記載によれば、上記発明は造粒後の乾燥工程
における水分の蒸発量を節減することを目的として為さ
れたものであり、上述のように高含水率の大豆濾滓を粉
状肥料と混練することにより、大豆濾滓中の水分を造粒
媒体として有効に利用することができ、新たに水または
肥料塩の水溶液などを添加することなしに造粒すること
ができるとされている。According to the description of the above-mentioned publication, the above-mentioned invention is made for the purpose of reducing the evaporation amount of water in the drying step after granulation, and as described above, the soybean dregs having a high water content are powdered. By kneading with a fertilizer, the water in the soybean cake can be effectively used as a granulation medium, and it is said that granulation can be performed without adding water or an aqueous solution of fertilizer salt. There is.
しかしながら、本発明の検討によれば、上記公報に開示
された大豆濾滓を利用する方法では、有機物を含有する
化成肥料を造粒することはできるものの、充分な粒子硬
度が得られないことが判明した。そこで本発明者は、有
機物の配合割合の高い化成肥料の粒状成形に使用する造
粒媒体についてさらに検討を重ねた結果、大豆蛋白製造
工程で分離される大豆乳漿を利用することにより、機械
施肥に充分な硬度と流動性とを有する粒子が有利に得ら
れることを見出し、本発明を完成した。However, according to the study of the present invention, the method utilizing soybean cake disclosed in the above publication can granulate a chemical fertilizer containing an organic matter, but cannot obtain sufficient particle hardness. found. Therefore, the present inventor has further studied the granulation medium used for granular molding of the chemical fertilizer having a high organic compounding ratio, and as a result, by utilizing soybean whey separated in the soybean protein production process, mechanical fertilization is performed. The present invention has been completed by finding that particles having sufficient hardness and fluidity can be advantageously obtained.
[発明の目的] 本発明は、有機物の含有率が高く、機械施肥に適した硬
度と流動性とを有する肥料の製造方法を提供することを
目的とする。[Object of the Invention] An object of the present invention is to provide a method for producing a fertilizer having a high content of organic substances and having hardness and fluidity suitable for mechanical fertilization.
本発明は、また、大豆乳漿の新規な有効利用方法を提供
することをも目的とする。Another object of the present invention is to provide a novel method for effectively utilizing soybean whey.
[発明の要旨] 本発明は、乾燥基準で30〜90重量%の有機物を含有し、
有機物と化成肥料とからなる肥料粉末を、大豆乳漿と混
合した後成形し、乾燥することを特徴とする有機物含有
肥料の製造方法にある。SUMMARY OF THE INVENTION The present invention contains 30-90 wt% organic matter on a dry basis,
A method for producing an organic matter-containing fertilizer, which comprises mixing a fertilizer powder consisting of an organic matter and a chemical fertilizer with soybean whey, molding the mixture, and drying the mixture.
本発明の製造方法の好ましい態様は、以下の通りであ
る。Preferred embodiments of the production method of the present invention are as follows.
(1)上記大豆乳漿が、分離大豆蛋白の製造工程におい
て、豆乳を酸で処理することにより分離される乳漿であ
ることを特徴とする上記有機物含有肥料の製造方法。(1) The method for producing an organic matter-containing fertilizer, wherein the soybean whey is whey separated by treating soybean milk with an acid in the step of producing isolated soybean protein.
(2)上記大豆乳漿が、10〜50重量%の範囲にて固形分
を含んでいることを特徴とする上記有機物含有肥料の製
造方法。(2) The method for producing an organic matter-containing fertilizer, wherein the soybean whey contains a solid content in the range of 10 to 50% by weight.
(3)上記成形を転動造粒により行なうことを特徴とす
る上記有機物含有肥料の製造方法。(3) The method for producing an organic matter-containing fertilizer, wherein the molding is performed by rolling granulation.
(4)上記大豆乳漿に含まれる固形分の量が、上記肥料
粉末100重量部に対して、2〜30重量部の範囲となるよ
うに、大豆乳漿を添加することを特徴とする上記有機物
含有肥料の製造方法。(4) The soybean whey is added such that the amount of solids contained in the soybean whey is in the range of 2 to 30 parts by weight with respect to 100 parts by weight of the fertilizer powder. Method for producing organic matter-containing fertilizer.
(5)上記肥料粉末が、50〜80重量%の範囲にて有機物
を含有することを特徴とする上記有機物含有肥料の製造
方法。(5) The method for producing an organic matter-containing fertilizer, wherein the fertilizer powder contains organic matter in a range of 50 to 80% by weight.
(6)上記成形後の乾燥を70〜130℃の温度範囲にて、1
5分〜1時間行なうことを特徴とする上記有機物含有肥
料の製造方法。(6) Drying after molding in the temperature range of 70 to 130 ° C
The method for producing an organic matter-containing fertilizer, which is carried out for 5 minutes to 1 hour.
[発明の効果] 本発明の方法により、有機物の含有率が高く、硬度の高
い粒状肥料を工業的に有利な転動造粒法にて製造するこ
とができる。[Advantages of the Invention] By the method of the present invention, a granular fertilizer having a high organic content and a high hardness can be produced by a rolling granulation method which is industrially advantageous.
上記有機物含有粒状肥料は、球状もしくは球状に近い形
状に成形することができ、比較的狭い範囲の粒度分布の
粒子として得ることができるので、流動性に優れ機械施
肥に好適である。The organic matter-containing granular fertilizer can be molded into a spherical shape or a shape close to a spherical shape, and can be obtained as particles having a particle size distribution in a relatively narrow range. Therefore, it has excellent fluidity and is suitable for mechanical fertilization.
さらに、本発明の製造方法によれば、大豆蛋白の製造工
程において分離される大豆乳漿を有機物を含有する肥料
の粒状化に有効利用することができる。Further, according to the production method of the present invention, soybean whey separated in the production step of soybean protein can be effectively used for granulating a fertilizer containing an organic substance.
[発明の詳細な記述] 本発明の有機物含有肥料の製造方法は、乾燥基準で30〜
90重量%の有機物を含有し、有機物と化成肥料とからな
る肥料粉末を、大豆乳漿と混合した後成形し、乾燥する
ことを特徴とする。[Detailed Description of the Invention] The method for producing an organic matter-containing fertilizer of the present invention is 30 to 30 on a dry basis.
It is characterized in that a fertilizer powder containing 90% by weight of an organic matter and comprising an organic matter and a chemical fertilizer is mixed with soybean whey, then molded and dried.
有機物を土壌に施用することにより、次の様な各種効果
が得られることが知られている。It is known that the following various effects can be obtained by applying organic matter to soil.
(1)土壌改良効果が得られる。有機物の施用により、
土壌由来の微生物が増加し、病害が減少する。また、無
機肥料のみを施肥した場合には、SO4 2-、Cl-などの陰イ
オンが土壌中に残留する量が多くなるが、有機物を施用
することにより陰イオンの残留量が低減される。(1) A soil improving effect can be obtained. By applying organic substances,
Soil-derived microorganisms increase and diseases are reduced. In addition, when only fertilizing inorganic fertilizers, the amount of anions such as SO 4 2− and Cl − that remain in the soil increases, but by applying organic matter, the amount of remaining anions decreases. .
(2)肥効を緩効性にする。(2) Make the fertilizing effect slower.
(3)肥料による濃度障害の発生が少なくなり、発生し
た場合にも、回復が速くなる。(3) The concentration disorder due to the fertilizer is less likely to occur, and even if it occurs, the recovery is faster.
(4)農作物の色、味など品質向上に寄与する。特に、
その作物に適した、植物質または動物質の有機物を適量
配合するときに、効果が大きい。(4) Contribute to quality improvement such as color and taste of agricultural products. In particular,
The effect is great when an appropriate amount of plant matter or animal matter organic matter suitable for the crop is added.
上記有機物含有肥料の製造に用いられる有機物として、
例えば、菜種油粕、ひまし油粕、皮革粉、骨粉、魚粉な
どを挙げることができる。また、上記化成肥料として、
例えば、過燐酸石灰、燐安、硫安、塩安、尿素、塩化加
里、硫酸加里などの無機化成肥料を挙げることができ
る。As the organic matter used in the production of the organic matter-containing fertilizer,
For example, rapeseed oil meal, castor oil meal, leather powder, bone meal, fish meal and the like can be mentioned. In addition, as the above-mentioned chemical fertilizer,
Examples thereof include mineral chemical fertilizers such as lime superphosphate, ammonium phosphate, ammonium sulfate, ammonium chloride, urea, potassium chloride and potassium sulfate.
上記有機物と上記化成肥料とを混合して、上記有機物含
有肥料の原料となる肥料粉末とする。上記有機物と上記
化成肥料との混合は、上記原料となる肥料粉末が該有機
物を乾燥基準で30〜90重量%含有するよう行なうことが
必要であり、50〜80重量%含有するような割合で行なう
ことが好ましい。The organic matter and the chemical fertilizer are mixed to obtain fertilizer powder which is a raw material of the organic matter-containing fertilizer. Mixing of the organic matter and the chemical fertilizer, it is necessary that the fertilizer powder as the raw material contains the organic matter in an amount of 30 to 90% by weight on a dry basis, and at a rate such that it contains 50 to 80% by weight. It is preferable to carry out.
上記肥料粉末において、有機物の含有量が乾燥基準で90
重量%を超えるときには、造粒しにくくなり、かつ、充
分な硬度を有する粒子が得られにくくなる傾向があるの
で好ましくない。さらに造粒物中の化成肥料成分が相対
的に少なくなるので、充分な肥効を得るためには多量の
施肥が必要になるとの問題も生じる。また、上記肥料粉
末において、有機物の含有量が乾燥基準で30重量%より
少ないときには、有機物本来の性質が生かされず、前述
の有機物施用による各種の効果が得られにくくなるので
好ましくない。In the above fertilizer powder, the content of organic matter is 90 on a dry basis.
When it exceeds the weight%, it tends to be difficult to granulate and particles having sufficient hardness tend to be difficult to obtain, which is not preferable. Further, since the chemical fertilizer component in the granulated product is relatively small, there is a problem that a large amount of fertilizer is required to obtain a sufficient fertilizing effect. Further, in the fertilizer powder, when the content of the organic substance is less than 30% by weight on a dry basis, the original property of the organic substance is not utilized and it is difficult to obtain various effects by applying the organic substance described above, which is not preferable.
上記有機物含有肥料の原料として使用する肥料粉末(有
機物および化成肥料)は、タイラー標準篩10メッシュを
通過する(篩下)程度の粒度である。The fertilizer powder (organic matter and chemical fertilizer) used as a raw material for the above-mentioned organic matter-containing fertilizer has a particle size such that it passes through a Tyler standard sieve 10 mesh (under sieve).
上記大豆乳漿は、 (1)濃縮大豆蛋白の製造工程において、大豆から大豆
油を搾取して脱脂大豆を得たのち、該脱脂大豆を酸また
はアルコールで洗浄することによって得られる大豆乳
漿、または、 (2)分離大豆蛋白の製造工程において、大豆から大豆
油を搾取して脱脂大豆を得たのち、該脱脂大豆から水抽
出して豆乳を得、さらに該豆乳を酸で処理して分離され
る大豆乳漿を用いることができる。上記大豆乳漿は、従
来、家畜飼料の添加物に利用されているが、肥料もしく
は肥料の製造に有効に利用することは知られていない。The above-mentioned soybean whey is (1) soybean whey obtained by squeezing soybean oil from soybean to obtain defatted soybean in the step of producing concentrated soybean protein, and then washing the defatted soybean with acid or alcohol, Or (2) in the step of producing separated soybean protein, soybean oil is extracted from soybean to obtain defatted soybean, and then defatted soybean is extracted with water to obtain soybean milk, and the soybean milk is treated with an acid to be separated. Soybean whey that is used can be used. The soybean whey has hitherto been used as an additive for livestock feed, but it has not been known to be effectively used for fertilizers or fertilizer production.
上述の製造方法において使用する大豆乳漿は、上記のい
ずれの方法で得られた乳漿であってもよいが、後者の方
法で得られた乳漿であることが好ましい。The soybean whey used in the above-mentioned production method may be whey obtained by any of the above methods, but is preferably whey obtained by the latter method.
上記大豆乳漿は、20〜40重量%の範囲にて固形分を含ん
でいることが好ましい。大豆乳漿の固形分含有量が上記
の範囲よりも少ないときには、後述の成形工程におい
て、該大豆乳漿による粘着作用が不充分になることがあ
る。また、大豆乳漿の固形分含有量が上記の範囲を上回
るときには、成形工程において水または肥料塩水溶液を
添加することにより、該固形分含有量が上記の範囲とな
るように調節することができる。The soybean whey preferably contains solids in the range of 20 to 40% by weight. When the solid content of soybean whey is less than the above range, the adhesive action of the soybean whey may be insufficient in the molding step described below. When the solid content of soybean whey exceeds the above range, the solid content can be adjusted to be within the above range by adding water or an aqueous fertilizer salt solution in the molding step. .
上記大豆乳漿の組成の一例を第1表に示す。Table 1 shows an example of the composition of the soybean whey.
上述の製造方法においては、まず、上記有機物および上
記化成肥料を上述の範囲の割合にて混合し原料となる肥
料粉末の混合物とし、次いで、上記大豆乳漿と、該大豆
乳漿に含まれる固形分の量が、該肥料粉末混合物100重
量部に対して、通常2〜30重量部、好ましくは4〜20重
量部となるような範囲の量にて混合する。上記大豆乳漿
に含まれる固形分の量が、上述の範囲よりも少ないとき
には、後述の成形工程において転動造粒法を採用した場
合に、無機物が主に造粒され得られる粒状肥料の有機物
含有量が低くなることがある。 In the above-mentioned manufacturing method, first, the organic substance and the chemical fertilizer are mixed in the above-mentioned ratio to form a mixture of fertilizer powders as raw materials, and then the soybean whey and solids contained in the soybean whey. The amount is usually in the range of 2 to 30 parts by weight, preferably 4 to 20 parts by weight, based on 100 parts by weight of the fertilizer powder mixture. When the amount of solids contained in the soybean whey is less than the above range, when the rolling granulation method is adopted in the molding step described below, inorganic matter is mainly granulated and organic matter of granular fertilizer obtained. The content may be low.
上記混合操作は、バグミル、プランジャー、パドルミキ
サーなど従来公知の混合装置を用いて行なうことができ
る。The above mixing operation can be performed using a conventionally known mixing device such as a bag mill, a plunger, and a paddle mixer.
次に、上述の操作で調製した混合物を成形する。上記成
形操作において、使用する大豆乳漿に含まれる固形分
が、上述の範囲を超える場合には、水または肥料塩水溶
液を添加して調節してもよい。ただし、大豆乳漿を過剰
に用いたり、上記水または肥料塩水溶液の添加量が過剰
になると、造粒作用が過度に進行し、機械施肥に適した
粒子径よりも大きな粒状肥料が得られる傾向があるの
で、充分な注意が必要である。Next, the mixture prepared by the above operation is molded. In the above molding operation, when the solid content contained in the soybean whey used exceeds the above range, water or an aqueous fertilizer salt solution may be added to adjust the solid content. However, if too much soybean whey is used or if the amount of the above water or fertilizer salt solution is added excessively, the granulation action will proceed excessively, and a granular fertilizer larger than the particle size suitable for mechanical fertilization tends to be obtained. Therefore, be careful.
上記成形操作は、転動造粒法で行なうことにより、機械
施肥に適した粒状の肥料を容易に得ることができるので
好ましい。上記転動造粒は、パン型造粒機またはドラム
型造粒機などの従来公知の転動造粒装置を用いて行なう
ことができる。上記転動造粒の条件は、一回に供給され
る原料肥料粉末の量、大豆乳漿の固形分含有量、およ
び、大豆乳漿の供給量などによって、適宜選択すること
ができる。The above-mentioned molding operation is preferably performed by rolling granulation because a granular fertilizer suitable for mechanical fertilization can be easily obtained. The tumbling granulation can be carried out using a conventionally known tumbling granulator such as a pan granulator or a drum granulator. The conditions of the tumbling granulation can be appropriately selected depending on the amount of raw material fertilizer powder supplied at one time, the solid content of soybean whey, the supply amount of soybean whey, and the like.
上記成形操作は、圧縮成形法など従来公知の方法により
行なってもよい。The molding operation may be carried out by a conventionally known method such as a compression molding method.
上記成形操作ののち、得られた粒子を乾燥する。上記乾
燥処理は、円筒乾燥器(ロータリードライヤー)、バン
ド乾燥器、流動層乾燥器などを用いて行なうことができ
る。また、小規模に製造する場合には、箱型恒温乾燥機
を使用してもよい。上記乾燥処理は、70〜130℃の温度
範囲にて15分〜1時間行なうことが好ましい。After the above molding operation, the obtained particles are dried. The drying treatment can be performed using a cylindrical dryer (rotary dryer), a band dryer, a fluidized bed dryer or the like. In the case of manufacturing on a small scale, a box-type constant temperature dryer may be used. The above drying treatment is preferably carried out in the temperature range of 70 to 130 ° C. for 15 minutes to 1 hour.
造粒媒体として大豆乳漿を用い、上述の条件にて成形お
よび乾燥処理を行なうことにより、有機物を高い配合割
合にて含有する粒状肥料を有利に製造することができ
る。By using soybean whey as a granulating medium and performing molding and drying treatment under the above-mentioned conditions, it is possible to advantageously produce a granular fertilizer containing a high proportion of organic substances.
本発明の製造方法により、木屋式硬度計を用いて測定し
た平均粒子硬度が通常2kg以上、特に3〜4kgの範囲であ
り、粒度分布が比較的狭く、タイラー標準篩を用いて篩
分けしたときに5メッシュ篩の通過分(篩下)であって
12メッシュ篩の残分(篩上)として得られる粒子が、通
常、得られた粒子全体の55重量%以上である粒状の有機
物含有肥料を、工業的に有利に製造することができる。According to the production method of the present invention, the average particle hardness measured with a Kiya type hardness meter is usually 2 kg or more, particularly in the range of 3 to 4 kg, and the particle size distribution is relatively narrow, and when sieving is performed using a Tyler standard sieve. The amount passed through the 5 mesh sieve (under the sieve)
It is possible to industrially advantageously manufacture a granular organic matter-containing fertilizer in which the particles obtained as the residue of the 12-mesh screen (on the screen) are usually 55% by weight or more of the entire particles obtained.
本発明の製造方法により得られる上述の有機物含有肥料
は、 (1)該有機物含有肥料中の化成肥料成分含有量を高く
することができる。The above-mentioned organic matter-containing fertilizer obtained by the production method of the present invention can (1) increase the content of the chemical fertilizer component in the organic matter-containing fertilizer.
(2)無機物による速効的肥料効果と、有機物による緩
効的肥料効果および土壌改良効果との両面の効果が得ら
れる、 (3)上記の範囲の粒子硬度および粒度分布を有するの
で、機械施肥に好適であり、施肥回数の低減および省力
化が可能である、などの点で高機能化されている。(2) A fast fertilizing effect of an inorganic substance, a slow fertilizing effect of an organic substance, and a soil improving effect can be obtained. (3) Since it has a particle hardness and a particle size distribution within the above range, it is suitable for mechanical fertilization. It is suitable and highly functional in that it can reduce the number of times of fertilization and save labor.
次に、本発明の実施例を示す。Next, examples of the present invention will be described.
[実施例1] 蒸製骨粉、蒸製皮革粉、および、ひまし油粕を等重量混
合した有機質原料65重量部(乾燥基準)に、燐安7.9重
量部、硫安13.1重量部、および塩化加里14重量部を混合
して粉砕し、有機物を含有する化成肥料粉末を製造し
た。Example 1 65 parts by weight (dry basis) of an organic raw material obtained by mixing steamed bone powder, steamed leather powder, and castor oil meal in equal weight, 7.9 parts by weight of phosphorus ammonium, 13.1 parts by weight of ammonium sulfate, and 14 parts by weight of potassium chloride. The mixture was mixed and pulverized to produce a compound fertilizer powder containing organic matter.
上記有機物含有化成肥料粉末1kgを、分離大豆蛋白製造
工程にて分離された大豆乳漿100gと混合し、造粒用原料
を調製した。上記大豆乳漿は、固形分43重量%を含有し
ている。1 kg of the above-mentioned organic matter-containing chemical fertilizer powder was mixed with 100 g of soybean whey separated in the separated soybean protein manufacturing step to prepare a raw material for granulation. The soybean whey contains 43% by weight of solids.
上記造粒用原料を、内径50cm、高さ10cmのステンレスス
チール(SUS304)製回転制御機付きパン型造粒機に入
れ、さらに水180gを添加して、回転数15r.p.m.で回転し
ながら10〜15分間造粒操作を行なった。得られた粒状物
を高音箱型乾燥機に入れ、85℃に一昼夜保持して乾燥し
た。Put the above granulation raw material into a pan-type granulator with an inner diameter of 50 cm and a height of 10 cm and made of stainless steel (SUS304) with a rotation controller, add 180 g of water, and rotate at a rotation speed of 15 rpm for 10 minutes. Granulation operation was performed for ~ 15 minutes. The obtained granular material was placed in a high-pitched box type dryer and kept at 85 ° C. for one day to be dried.
乾燥後の粒状物をタイラー標準篩を用いて篩分けし、5
メッシュ篩の通過分であって12メッシュ篩の残分(以
下、5〜12メッシュと略記する)である粒子を有機物含
有粒状肥料として得た。上記肥料の有機物含有量は、該
肥料中の無機態N−P−Kおよび有機態N−P−Kのそ
れぞれを化学分析し、両者の分析値の比から算出した。
また、上記乾燥後の粒状物をタイラー標準篩を用いて篩
分けし、5メッシュ篩の通過分であって7メッシュ篩の
残分として得られた粒状物の中から任意に20粒を取り出
し、木屋式硬度計を用いて硬度を測定し、その平均値を
有機物含有粒状肥料の平均粒子硬度とした。The dried granules are sieved using a Tyler standard sieve and 5
Particles that passed through the mesh sieve and remained on the 12 mesh sieve (hereinafter abbreviated as 5 to 12 mesh) were obtained as organic matter-containing granular fertilizer. The organic matter content of the fertilizer was calculated by chemical analysis of each of the inorganic N-P-K and the organic N-P-K in the fertilizer, and the ratio of the analysis values of both.
Further, the dried granules are sieved using a Tyler standard sieve, and 20 granules are arbitrarily taken out from the granules obtained as a residue of the 7-mesh sieve, which is a passing portion of the 5-mesh sieve, The hardness was measured using a Kiya type hardness meter, and the average value was defined as the average particle hardness of the organic matter-containing granular fertilizer.
上記粒状肥料の粒度分布、有機物含有量、および、平均
粒子硬度を第2表に示す。Table 2 shows the particle size distribution, organic matter content, and average particle hardness of the above-mentioned granular fertilizer.
上記有機物含有粒状肥料は、肥料成分として、N−P−
Kが8−8−8となる規格を満足していた。The organic matter-containing granular fertilizer, as a fertilizer component, NP-
The K satisfies the standard of 8-8-8.
[実施例2] 実施例1で用いたものと同じ有機物含有化成肥料粉末1k
gを、実施例1で用いたものと同じ大豆乳漿200gと混合
して造粒用原料を調製し、造粒操作における水の添加量
を132gとしたこと以外は実施例1と同様にして、5〜12
メッシュの有機物含有粒状肥料を得た。上記有機物含有
粒状肥料の有機物含有量および平均粒子硬度を実施例1
と同様にして測定した。Example 2 Organic compound-containing chemical fertilizer powder 1k same as that used in Example 1
g was mixed with 200 g of the same soybean whey used in Example 1 to prepare a granulation raw material, and the same as in Example 1 except that the amount of water added in the granulation operation was 132 g. , 5-12
A granular fertilizer containing organic matter of mesh was obtained. The organic matter content and average particle hardness of the above organic matter-containing granular fertilizer were measured in Example 1
It measured similarly to.
上記粒状肥料の粒度分布、有機物含有量、および、平均
粒子硬度を第2表に示す。Table 2 shows the particle size distribution, organic matter content, and average particle hardness of the above-mentioned granular fertilizer.
上記有機物含有粒状肥料は、肥料成分として、N−P−
Kが8−8−8となる規格を満足していた。The organic matter-containing granular fertilizer, as a fertilizer component, NP-
The K satisfies the standard of 8-8-8.
[実施例3] 実施例1で用いたものと同じ有機物含有化成肥料粉末1k
gを、実施例1で用いたものと同じ大豆乳漿300gと混合
して造粒用原料を調製し、造粒操作における水の添加量
を60gとしたこと以外は実施例1と同様にして、5〜12
メッシュの有機物含有粒状肥料を得た。上記有機物含有
粒状肥料の有機物含有量および平均粒子硬度を実施例1
と同様にして測定した。[Example 3] The same organic matter-containing chemical fertilizer powder 1k as that used in Example 1
g was mixed with 300 g of the same soybean whey used in Example 1 to prepare a raw material for granulation, and the same as in Example 1 except that the amount of water added in the granulation operation was 60 g. , 5-12
A granular fertilizer containing organic matter of mesh was obtained. The organic matter content and average particle hardness of the above organic matter-containing granular fertilizer were measured in Example 1
It measured similarly to.
上記粒状肥料の粒度分布、有機物含有量、および、平均
粒子硬度を第2表に示す。Table 2 shows the particle size distribution, organic matter content, and average particle hardness of the above-mentioned granular fertilizer.
上記有機物含有粒状肥料は、肥料成分として、N−P−
Kが8−8−8となる規格を満足していた。The organic matter-containing granular fertilizer, as a fertilizer component, NP-
The K satisfies the standard of 8-8-8.
[実施例4] 実施例1で用いたものと同じ有機物含有化成肥料粉末1k
gを、実施例1で用いたものと同じ大豆乳漿400gと混合
して造粒用原料を調製し、造粒操作に水を全く添加しな
かった以外は実施例1と同様にして、5〜12メッシュの
有機物含有粒状肥料を得た。上記有機物含有粒状肥料の
有機物含有量および平均粒子硬度を実施例1と同様にし
て測定した。Example 4 Organic compound-containing chemical fertilizer powder 1k same as that used in Example 1
g was mixed with 400 g of the same soybean whey used in Example 1 to prepare a raw material for granulation, and the same as in Example 1 except that no water was added to the granulation operation. A ~ 12 mesh organic matter-containing granular fertilizer was obtained. The organic matter content and average particle hardness of the organic matter-containing granular fertilizer were measured in the same manner as in Example 1.
上記粒状肥料の粒度分布、有機物含有量、および、平均
粒子硬度を第2表に示す。Table 2 shows the particle size distribution, organic matter content, and average particle hardness of the above-mentioned granular fertilizer.
上記有機物含有粒状肥料は、肥料成分として、N−P−
Kが8−8−8となる規格を満足していた。The organic matter-containing granular fertilizer, as a fertilizer component, NP-
The K satisfies the standard of 8-8-8.
[比較例1] 実施例1で用いた大豆乳漿を、42%の固形分を含有する
廃糖蜜液100gに変え、造粒操作における水の添加量を20
4gとしたこと以外は実施例1と同様にして、5〜12メッ
シュの粒状肥料を得た。上記粒状肥料の有機物含有量お
よび平均粒子硬度を実施例1と同様にして測定した。[Comparative Example 1] The soybean whey used in Example 1 was changed to 100 g of molasses liquid containing 42% solid content, and the amount of water added in the granulation operation was 20.
A granular fertilizer of 5 to 12 mesh was obtained in the same manner as in Example 1 except that the amount was 4 g. The organic matter content and average particle hardness of the granular fertilizer were measured in the same manner as in Example 1.
上記粒状肥料の粒度分布、有機物含有量、および、平均
粒子硬度を第2表に示す。Table 2 shows the particle size distribution, organic matter content, and average particle hardness of the above-mentioned granular fertilizer.
[比較例2] 実施例1で用いた大豆乳漿を、42%の固形分を含有する
廃糖蜜液200gに変え、造粒操作における水の添加量を12
0gとしたこと以外は実施例1と同様にして、5〜12メッ
シュの粒状肥料を得た。上記粒状肥料の有機物含有量お
よび平均粒子硬度を実施例1と同様にして測定した。[Comparative Example 2] The soybean whey used in Example 1 was changed to 200 g of molasses liquid containing 42% solids, and the amount of water added in the granulation operation was 12
A granular fertilizer of 5 to 12 mesh was obtained in the same manner as in Example 1 except that the amount was 0 g. The organic matter content and average particle hardness of the granular fertilizer were measured in the same manner as in Example 1.
上記粒状肥料の粒度分布、有機物含有量、および、平均
粒子硬度を第2表に示す。Table 2 shows the particle size distribution, organic matter content, and average particle hardness of the above-mentioned granular fertilizer.
[比較例3] 実施例1で用いた大豆乳漿を、42%の固形分を含有する
廃糖蜜液300gに変え、造粒操作における水の添加量を40
gとしたこと以外は実施例1と同様にして、5〜12メッ
シュの粒状肥料を得た。上記粒状肥料の有機物含有量お
よび平均粒子硬度を実施例1と同様にして測定した。[Comparative Example 3] The soybean whey used in Example 1 was changed to 300 g of molasses liquid containing 42% solids, and the amount of water added in the granulation operation was 40 g.
A granular fertilizer of 5 to 12 mesh was obtained in the same manner as in Example 1 except that g was changed to g. The organic matter content and average particle hardness of the granular fertilizer were measured in the same manner as in Example 1.
上記粒状肥料の粒度分布、有機物含有量、および、平均
粒子硬度を第2表に示す。Table 2 shows the particle size distribution, organic matter content, and average particle hardness of the above-mentioned granular fertilizer.
[比較例4] 実施例1で用いた大豆乳漿を、42%の固形分を含有する
リグニン液300gに変え、造粒操作における水の添加量を
100gとしたこと以外は実施例1と同様にして、5〜12メ
ッシュの粒状肥料を得た。上記粒状肥料の有機物含有量
および平均粒子硬度を実施例1と同様にして測定した。[Comparative Example 4] The soybean whey used in Example 1 was changed to 300 g of a lignin solution containing 42% solid content, and the amount of water added in the granulation operation was changed.
A granular fertilizer of 5 to 12 mesh was obtained in the same manner as in Example 1 except that the amount was 100 g. The organic matter content and average particle hardness of the granular fertilizer were measured in the same manner as in Example 1.
上記粒状肥料の粒度分布、有機物含有量、および、平均
粒子硬度を第2表に示す。Table 2 shows the particle size distribution, organic matter content, and average particle hardness of the above-mentioned granular fertilizer.
[実施例5] 実施例1で用いたものと同じ有機質原料80重量部に、燐
安1.5重量部、硫安7.5重量部、および塩化加里11重量部
を混合して粉砕し、有機物を含有する化成肥料粉末を製
造した。 [Example 5] 80 parts by weight of the same organic raw material as used in Example 1 was mixed with 1.5 parts by weight of phosphorus ammonium, 7.5 parts by weight of ammonium sulfate, and 11 parts by weight of potassium chloride and pulverized to form a chemical compound containing an organic substance. Manure powder was produced.
上記有機物含有化成肥料粉末1kgを、実施例1で用いた
ものと同じ大豆乳漿100gと混合して造粒用原料を調製
し、造粒操作における水の添加量を284gとしたこと以外
は実施例1と同様にして、5〜12メッシュの有機物含有
粒状肥料を得た。上記有機物含有粒状肥料の有機物含有
量および平均粒子硬度を実施例1と同様にして測定し
た。1 kg of the above-mentioned organic matter-containing chemical fertilizer powder was mixed with 100 g of the same soybean whey used in Example 1 to prepare a raw material for granulation, except that the amount of water added in the granulation operation was 284 g. In the same manner as in Example 1, 5 to 12 mesh organic matter-containing granular fertilizer was obtained. The organic matter content and average particle hardness of the organic matter-containing granular fertilizer were measured in the same manner as in Example 1.
上記粒状肥料の粒度分布、有機物含有量、および、平均
粒子硬度を第3表に示す。Table 3 shows the particle size distribution, the organic substance content, and the average particle hardness of the granular fertilizer.
上記有機物含有粒状肥料は、肥料成分として、N−P−
Kが6−6−6となる規格を満足していた。The organic matter-containing granular fertilizer, as a fertilizer component, NP-
The K satisfies the standard of 6-6-6.
[実施例6] 実施例5で用いたものと同じ有機物含有化成肥料粉末1k
gを、実施例1で用いたものと同じ大豆乳漿200gと混合
して造粒用原料を調製し、造粒操作における水の添加量
を180gとしたこと以外は実施例1と同様にして、5〜12
メッシュの有機物含有粒状肥料を得た。上記有機物含有
粒状肥料の有機物含有量および平均粒子硬度を実施例1
と同様にして測定した。[Example 6] The same organic matter-containing chemical fertilizer powder 1k as that used in Example 5
g was mixed with 200 g of the same soybean whey used in Example 1 to prepare a granulation raw material, and the same as in Example 1 except that the amount of water added in the granulation operation was 180 g. , 5-12
A granular fertilizer containing organic matter of mesh was obtained. The organic matter content and average particle hardness of the above organic matter-containing granular fertilizer were measured in Example 1
It measured similarly to.
上記粒状肥料の粒度分布、有機物含有量、および、平均
粒子硬度を第3表に示す。Table 3 shows the particle size distribution, the organic substance content, and the average particle hardness of the granular fertilizer.
上記有機物含有粒状肥料は、肥料成分として、N−P−
Kが6−6−6となる規格を満足していた。The organic matter-containing granular fertilizer, as a fertilizer component, NP-
The K satisfies the standard of 6-6-6.
[実施例7] 実施例5で用いたものと同じ有機物含有化成肥料粉末1k
gを、実施例1で用いたものと同じ大豆乳漿300gと混合
して造粒用原料を調製し、造粒操作における水の添加量
を101gとしたこと以外は実施例1と同様にして、5〜12
メッシュの有機物含有粒状肥料を得た。上記有機物含有
粒状肥料の有機物含有量および平均粒子硬度を実施例1
と同様にして測定した。Example 7 Organic compound-containing chemical fertilizer powder 1k same as that used in Example 5
g was mixed with 300 g of the same soybean whey used in Example 1 to prepare a raw material for granulation, and the same as in Example 1 except that the amount of water added in the granulation operation was 101 g. , 5-12
A granular fertilizer containing organic matter of mesh was obtained. The organic matter content and average particle hardness of the above organic matter-containing granular fertilizer were measured in Example 1
It measured similarly to.
上記粒状肥料の粒度分布、有機物含有量、および、平均
粒子硬度を第3表に示す。Table 3 shows the particle size distribution, the organic substance content, and the average particle hardness of the granular fertilizer.
上記有機物含有粒状肥料は、肥料成分として、N−P−
Kが6−6−6となる規格を満足していた。The organic matter-containing granular fertilizer, as a fertilizer component, NP-
The K satisfies the standard of 6-6-6.
[実施例8] 実施例5で用いたものと同じ有機物含有化成肥料粉末1k
gを、実施例1で用いたものと同じ大豆乳漿400gと混合
して造粒用原料を調製し、造粒操作における水の添加量
を31gとしたこと以外は実施例1と同様にして、5〜12
メッシュの有機物含有粒状肥料を得た。上記有機物含有
粒状肥料の有機物含有量および平均粒子硬度を実施例1
と同様にして測定した。[Example 8] The same organic matter-containing chemical fertilizer powder 1k as that used in Example 5
g was mixed with 400 g of the same soybean whey used in Example 1 to prepare a granulation raw material, and the same as in Example 1 except that the amount of water added in the granulation operation was 31 g. , 5-12
A granular fertilizer containing organic matter of mesh was obtained. The organic matter content and average particle hardness of the above organic matter-containing granular fertilizer were measured in Example 1
It measured similarly to.
上記粒状肥料の粒度分布、有機物含有量、および、平均
粒子硬度を第3表に示す。Table 3 shows the particle size distribution, the organic substance content, and the average particle hardness of the granular fertilizer.
上記有機物含有粒状肥料は、肥料成分として、N−P−
Kが6−6−6となる規格を満足していた。The organic matter-containing granular fertilizer, as a fertilizer component, NP-
The K satisfies the standard of 6-6-6.
[実施例9] 実施例5で用いたものと同じ有機物含有化成肥料粉末1k
gを、実施例1で用いたものと同じ大豆乳漿500gと混合
して造粒用原料を調製し、造粒操作に水を全く添加しな
かった以外は実施例1と同様にして、5〜12メッシュの
有機物含有粒状肥料を得た。上記有機物含有粒状肥料の
有機物含有量および平均粒子硬度を実施例1と同様にし
て測定した。[Example 9] The same organic matter-containing chemical fertilizer powder 1k as that used in Example 5
g was mixed with 500 g of the same soybean whey used in Example 1 to prepare a raw material for granulation, and the same procedure as in Example 1 was repeated except that no water was added to the granulation operation. A ~ 12 mesh organic matter-containing granular fertilizer was obtained. The organic matter content and average particle hardness of the organic matter-containing granular fertilizer were measured in the same manner as in Example 1.
上記粒状肥料の粒度分布、有機物含有量、および、平均
粒子硬度を第3表に示す。Table 3 shows the particle size distribution, the organic substance content, and the average particle hardness of the granular fertilizer.
上記有機物含有粒状肥料は、肥料成分として、N−P−
Kが6−6−6となる規格を満足していた。The organic matter-containing granular fertilizer, as a fertilizer component, NP-
The K satisfies the standard of 6-6-6.
[比較例5] 実施例5で用いた大豆乳漿を、42%の固形分を含有する
廃糖蜜液100gに変え、造粒操作における水の添加量を31
6gとしたこと以外は実施例5と同様にして、5〜12メッ
シュの粒状肥料を得た。上記粒状肥料の有機物含有量お
よび平均粒子硬度を実施例1と同様にして測定した。[Comparative Example 5] The soybean whey used in Example 5 was changed to 100 g of molasses liquid containing 42% solids, and the amount of water added in the granulation operation was 31.
A granular fertilizer of 5 to 12 mesh was obtained in the same manner as in Example 5 except that the amount was 6 g. The organic matter content and average particle hardness of the granular fertilizer were measured in the same manner as in Example 1.
上記粒状肥料の粒度分布、有機物含有量、および、平均
粒子硬度を第3表に示す。Table 3 shows the particle size distribution, the organic substance content, and the average particle hardness of the granular fertilizer.
[比較例6] 実施例5で用いた大豆乳漿を、42%の固形分を含有する
廃糖蜜液200gに変え、造粒操作における水の添加量を16
8gとしたこと以外は実施例5と同様にして、5〜12メッ
シュの粒状肥料を得た。上記粒状肥料の有機物含有量お
よび平均粒子硬度を実施例1と同様にして測定した。[Comparative Example 6] The soybean whey used in Example 5 was changed to 200 g of molasses liquid containing 42% solid content, and the amount of water added in the granulation operation was 16
A granular fertilizer of 5 to 12 mesh was obtained in the same manner as in Example 5 except that the amount was 8 g. The organic matter content and average particle hardness of the granular fertilizer were measured in the same manner as in Example 1.
上記粒状肥料の粒度分布、有機物含有量、および、平均
粒子硬度を第3表に示す。Table 3 shows the particle size distribution, the organic substance content, and the average particle hardness of the granular fertilizer.
[比較例7] 実施例5で用いた大豆乳漿を、42%の固形分を含有する
廃糖蜜液300gに変え、造粒操作における水の添加量を96
gとしたこと以外は実施例5と同様にして、5〜12メッ
シュの粒状肥料を得た。上記粒状肥料の有機物含有量お
よび平均粒子硬度を実施例1と同様にして測定した。[Comparative Example 7] The soybean whey used in Example 5 was changed to 300 g of molasses liquid containing 42% solids, and the amount of water added in the granulation operation was 96.
A granular fertilizer of 5 to 12 mesh was obtained in the same manner as in Example 5 except that g was changed. The organic matter content and average particle hardness of the granular fertilizer were measured in the same manner as in Example 1.
上記粒状肥料の粒度分布、有機物含有量、および、平均
粒子硬度を第3表に示す。Table 3 shows the particle size distribution, the organic substance content, and the average particle hardness of the granular fertilizer.
[比較例8] 実施例5で用いた大豆乳漿を、42%の固形分を含有する
リグニン液300gに変え、造粒操作における水の添加量を
142gとしたこと以外は実施例5と同様にして、5〜12メ
ッシュの粒状肥料を得た。上記粒状肥料の有機物含有量
および平均粒子硬度を実施例1と同様にして測定した。[Comparative Example 8] The soybean whey used in Example 5 was changed to 300 g of a lignin solution containing 42% solids, and the amount of water added in the granulation operation was changed.
A granular fertilizer of 5 to 12 mesh was obtained in the same manner as in Example 5 except that the amount was 142 g. The organic matter content and average particle hardness of the granular fertilizer were measured in the same manner as in Example 1.
上記粒状肥料の粒度分布、有機物含有量、および、平均
粒子硬度を第3表に示す。Table 3 shows the particle size distribution, the organic substance content, and the average particle hardness of the granular fertilizer.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 山田 義範 山口県宇部市大字小串1988番地の7 宇部 化成肥料株式会社内 (72)発明者 松岡 照幸 大阪府大阪市北区曽根崎新地2丁目2番16 号 宇部興産株式会社内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Yoshinori Yamada 7 1988, Ogushi, Ube, Yamaguchi Prefecture, Ube Kasei Fertilizer Co., Ltd. (72) Inventor, Teruyuki Matsuoka 2-2-16 Sonezaki Shinchi, Kita-ku, Osaka City, Osaka Prefecture Ube Industries Co., Ltd.
Claims (1)
し、有機物と化成肥料とからなる肥料粉末を、大豆乳漿
と混合した後成形し、乾燥することを特徴とする有機物
含有肥料の製造方法。1. A fertilizer containing organic matter, which comprises 30 to 90% by weight of organic matter on a dry basis, is mixed with soybean whey, fertilizer powder consisting of organic matter and chemical fertilizer, is molded, and is then dried. Manufacturing method.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP23417989A JPH0725622B2 (en) | 1989-09-08 | 1989-09-08 | Method for producing organic matter-containing fertilizer |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP23417989A JPH0725622B2 (en) | 1989-09-08 | 1989-09-08 | Method for producing organic matter-containing fertilizer |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0397684A JPH0397684A (en) | 1991-04-23 |
JPH0725622B2 true JPH0725622B2 (en) | 1995-03-22 |
Family
ID=16966914
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP23417989A Expired - Lifetime JPH0725622B2 (en) | 1989-09-08 | 1989-09-08 | Method for producing organic matter-containing fertilizer |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0725622B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105152714A (en) * | 2015-08-25 | 2015-12-16 | 蚌埠海上明珠农业科技发展有限公司 | Special-purpose fertilizer for landscape flowers and plants and preparation method of special-purpose fertilizer |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03150284A (en) * | 1989-11-07 | 1991-06-26 | Fuji Oil Co Ltd | Fertilizer |
EP1937610A2 (en) | 2005-10-14 | 2008-07-02 | Archer-Daniels-Midland Company | Fertilizer compositions and methods of using |
CN103214301B (en) * | 2013-03-25 | 2016-05-11 | 广东中迅农科股份有限公司 | Granule of a kind of dichloro quinolinic acid and bensulfuron-methyl and preparation method thereof |
CN103772035B (en) * | 2014-01-21 | 2015-04-15 | 中国农业科学院农业资源与农业区划研究所 | Granular nitrogen fertilizer taking ammonium bicarbonate as main nitrogen source and preparation method thereof |
WO2016112492A1 (en) * | 2015-01-13 | 2016-07-21 | Xi'an Derun Biotechnology Co., Ltd. | A plasma preparation applied to plant disease control and growth promoting and its preparation method |
-
1989
- 1989-09-08 JP JP23417989A patent/JPH0725622B2/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105152714A (en) * | 2015-08-25 | 2015-12-16 | 蚌埠海上明珠农业科技发展有限公司 | Special-purpose fertilizer for landscape flowers and plants and preparation method of special-purpose fertilizer |
Also Published As
Publication number | Publication date |
---|---|
JPH0397684A (en) | 1991-04-23 |
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