JPH0466601A - Manufacture of fine metal balls - Google Patents

Manufacture of fine metal balls

Info

Publication number
JPH0466601A
JPH0466601A JP2179263A JP17926390A JPH0466601A JP H0466601 A JPH0466601 A JP H0466601A JP 2179263 A JP2179263 A JP 2179263A JP 17926390 A JP17926390 A JP 17926390A JP H0466601 A JPH0466601 A JP H0466601A
Authority
JP
Japan
Prior art keywords
metal
metal wire
core tube
furnace core
furnace
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2179263A
Other languages
Japanese (ja)
Inventor
Tadakatsu Maruyama
忠克 丸山
Takahide Ono
恭秀 大野
Osamu Kitamura
修 北村
Tomohiro Uno
智裕 宇野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP2179263A priority Critical patent/JPH0466601A/en
Priority to PCT/JP1990/001591 priority patent/WO1991008850A1/en
Priority to KR1019910700856A priority patent/KR960000332B1/en
Priority to EP91900363A priority patent/EP0457920B1/en
Priority to DE69032249T priority patent/DE69032249T2/en
Publication of JPH0466601A publication Critical patent/JPH0466601A/en
Priority to US08/596,694 priority patent/US5761779A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/74Apparatus for manufacturing arrangements for connecting or disconnecting semiconductor or solid-state bodies and for methods related thereto
    • H01L2224/741Apparatus for manufacturing means for bonding, e.g. connectors
    • H01L2224/742Apparatus for manufacturing bump connectors

Landscapes

  • Powder Metallurgy (AREA)
  • Wire Processing (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)

Abstract

PURPOSE:To finely spheroidize metal wire pieces by freely dropping the metal wire pieces in a furnace core tube vertically set in heating means, heating the metal wire pieces to the temp. having m.p. of the above wire pieces or higher and melting. CONSTITUTION:The metal wire pieces 10 of fine metal wire are dropped from above the furnace core tube 2 and come in the furnace core tube 2. The metal wire piece 10 drops in the furnace core tube 2 and at the time of coming in a heating furnace 4 the temp. thereof is rapidly started to raise. Then, when the temp. of metal wire piece becomes higher than the m.p. thereof, this is melted. Generally, as the molten metal has large surface tension, this is naturally changed to the spherical shape in the molten state. Therefore, this molten metal is changed to the spherical shape during passing through the heating furnace 4, but at the time of coming out from the heating furnace 4, the temp. thereof is rapidly dropped and this metal is started to solidify. At least, the metal balls are dropped to a cover 6 and the fine metal balls 20 having uniform and beautiful spherical shape after solidifying can be obtd.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、ICチップの電極とTABテープのリード等
との間を接合する際に接合部材として利用される微細金
属球を製造するための方法に関するものである。
[Detailed Description of the Invention] [Industrial Application Field] The present invention is a method for manufacturing fine metal balls used as a joining member when joining between an electrode of an IC chip and a lead of a TAB tape, etc. It is about the method.

〔従来の技術〕[Conventional technology]

ICチップの電極と外部リードとの接続には多様な方法
が採用されている。
Various methods are used to connect the electrodes of the IC chip and external leads.

配線用の極細ワイヤー(ボンディングワイヤー)を用い
て接続する方法もあるが、チップの電極とリードとの間
にバンブと呼ばれる金属突起を挟んで熱圧着する方法も
広く行われるようになっている。
There is a method of connecting using ultra-thin wiring wire (bonding wire), but a method of thermocompression bonding by sandwiching a metal protrusion called a bump between the chip electrode and the lead is also becoming widely used.

T A B (Tape Automated Bon
ding)法は後者の代表として注目されている技術で
ある。この方法は、予めICチップの電極部か、もしく
はTABテープ上のリード先端部のいずれかにバンブを
形成しておき、次にICチップ電極部とリードを有する
TABテープとをバンブを介して重ね合わせて両者を接
合するものである。またTAB法以外にフリップチップ
法においても、バンブが使用されている。
T A B (Tape Automated Bon
ding) method is a technique that is attracting attention as a representative of the latter. In this method, a bump is formed in advance on either the electrode part of the IC chip or the lead tip part on the TAB tape, and then the IC chip electrode part and the TAB tape having the lead are stacked with the bump interposed therebetween. The two are then joined together. In addition to the TAB method, bumps are also used in the flip chip method.

このような用途に提供されるバンブのこれまでの作り方
は、メツキによる方法が主であった。すなわち、ICチ
ップの電極部にバンブとなる金属(主に高純度の金)を
直接メツキして形成する力\または一旦ガラス基盤上等
にメツキによって形成したバンブをTABテープ側のリ
ード先端部に転写する方法が主流となっている。
Up until now, the method of making bamboo provided for such uses has mainly been the method of making bamboo sticks. In other words, the force is applied by directly plating the metal (mainly high-purity gold) that will become the bump on the electrode part of the IC chip, or by applying the force to form the bump once formed by plating on the glass substrate etc. to the lead tip on the TAB tape side. The mainstream method is transcription.

しかしながら、メツキによる方法は設備が大きくなる上
に、バンブとして使用する金属の組成にも制約を受ける
という欠点がある。また特にICチップの電極部に直接
メツキしてバンブを形成する場合には、ICチップその
ものがメツキ工程を通過することになって、ICチップ
の歩留まりが悪化するという問題がある。
However, the method using plating has the disadvantage that it requires large equipment and is also subject to restrictions on the composition of the metal used as the bump. In addition, particularly when forming bumps by directly plating the electrode portions of IC chips, there is a problem that the IC chips themselves have to go through the plating process, which deteriorates the yield of the IC chips.

これらの欠点を解消する方法として、メツキによらない
バンブ形成方法も考えられるようになってきた。本出願
人は先に、バンブ用の素材となる金属を微細線に加工し
、この金属線を定尺切断した後、互いの間隔を隔てた状
態で溶融・凝固させ、表面張力を利用して球形状のバン
ブを得る方法について出願した(特願平1−32029
6号)、この方法で作られた球形状のバンブは、リード
先端部等に熱圧着して使用される(特願平1−2349
17号)。
As a method to overcome these drawbacks, bump forming methods that do not involve plating have come to be considered. The applicant first processed the metal that would be the material for the bump into fine wires, cut the metal wires to a specified length, melted and solidified them at intervals, and made the metal wires by using surface tension. An application was filed regarding a method for obtaining spherical bumps (Patent Application No. 1-32029).
No. 6), the spherical bump made by this method is used by thermocompression bonding to the tip of the lead, etc. (Japanese Patent Application No. 1-2349)
No. 17).

任意の金属線片を溶融してバンブとする新しい方法によ
れば、接合用部材としてふされしい特性を持った任意の
金属をバンブとして使用する可能性が太き(広がったこ
とになる。すなわち、金)他に銅や銀、並びにそれらを
ベースとする各種の合金を、容品にバンブとして成形す
ることができるようになったわけである。
According to the new method of melting any piece of metal wire to make a bump, the possibility of using any metal with properties suitable for a joining member as a bump has been widened. In addition to copper, silver, and various alloys based on them, it became possible to mold containers into bumps.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

従来の微細金属球の製造方法では、所定長さに切断した
金属線片を坩堝中に一定の間隔をとって配置した後、溶
融していた。これは、お互いの金属線片が接触したまま
、又は余りに近い位置に置かれたまま溶融工程に入ると
、溶融時にこれらの金属線片が合体してしまう戊がある
からである。
In a conventional method for producing fine metal balls, pieces of metal wire cut into predetermined lengths are placed in a crucible at regular intervals and then melted. This is because if the metal wire pieces enter the melting process while remaining in contact with each other or placed too close to each other, these metal wire pieces may coalesce during melting.

この方法においては、金属線片がすべて一定の長さを有
すれば、均一なサイズの微細金属球を形成することがで
きた。しかしながら、この金属線片は長くても2〜3m
mという微小なものなので、金属線片の配列作業及び微
細金属球の回収作業に手間がかかるという問題があった
In this method, if all the metal wire pieces had a certain length, fine metal spheres of uniform size could be formed. However, this metal wire piece is 2 to 3 meters long at most.
Since the particles are as small as m, there is a problem in that arranging the metal wire pieces and collecting the fine metal balls takes time and effort.

本発明は上記事情に基づいてなされたものであり、簡易
な装置により、作業能率の向上を図ることができる微細
金属球の製造方法を提供することを目的とするものであ
る。
The present invention has been made based on the above-mentioned circumstances, and an object of the present invention is to provide a method for manufacturing fine metal balls that can improve work efficiency using a simple device.

(課題を解決するための手段〕 上記の目的を達成するための本発明に係る微細金属球の
製造方法は、加熱手段において縦に配置された炉芯管内
を、金属線片を自由落下させ、前記金属線片に用いてい
る金属の融点以上の温度に前記金属線片を加熱して溶融
することにより、前記金属線片を球状化することを特徴
とするものである。
(Means for Solving the Problems) A method for manufacturing fine metal spheres according to the present invention to achieve the above object includes the steps of: freely falling a piece of metal wire through a furnace core tube arranged vertically in a heating means; The method is characterized in that the metal wire piece is spheroidized by heating and melting the metal wire piece to a temperature equal to or higher than the melting point of the metal used in the metal wire piece.

そして、前記炉芯管の下端に蓋を設けることが望ましい
Further, it is desirable to provide a lid at the lower end of the furnace core tube.

〔作用〕[Effect]

本発明は前記の構成によりて、炉芯管の中を自由落下す
る金属線片を、加熱手段によりその金属線片に用いてい
る金属の融点以上の温度に加熱して溶融する。溶融状態
の金属は表面張力が大きく、自ら球状化するので、金属
線片は炉芯管の中を落下中に球状に変形され、微細金属
球となる。
In the present invention, with the above-described configuration, a piece of metal wire that freely falls inside the furnace core tube is heated and melted by a heating means to a temperature higher than the melting point of the metal used for the piece of metal wire. Metal in a molten state has a large surface tension and spheroidizes itself, so the metal wire pieces are deformed into a spherical shape while falling through the furnace core tube and become fine metal balls.

また、炉芯管の下端に蓋を設けることにより、管内に上
昇気流が発生するのを防止することができる。
Furthermore, by providing a lid at the lower end of the furnace core tube, it is possible to prevent rising air current from occurring within the tube.

〔実施例〕〔Example〕

以下に本発明の一実施例を添付図面を参照して説明する
0図面は本発明の一実施例である微細金属球の製造方法
において使用する装置の概略図である0本実施例、にお
いでは、線径25μm、長さ0.55mmの金線片(金
属線片)を使用しており、直径が80μmの金球(微細
金属球)を製造する。
An embodiment of the present invention will be described below with reference to the accompanying drawings.The drawing is a schematic diagram of an apparatus used in a method for producing fine metal balls, which is an embodiment of the present invention. A gold wire piece (metal wire piece) with a wire diameter of 25 μm and a length of 0.55 mm is used to produce a gold ball (fine metal ball) with a diameter of 80 μm.

図面に示す装置は、金属線片1oの落下路である炉芯管
2と、金属線片10を溶融するための加熱炉4と、形成
された微細金属球20を回収するIF5とからなる。炉
芯管2には、内径約5mm、長さ約1000mmの石英
ガラスを使用し、加熱炉4としては長さ500mmの縦
型環状電気炉を用いた。加熱炉4は下端近傍において最
高温度を有するような温度分布を持たせた。加熱炉4内
の最高温度は1300℃である。加熱炉4の最高温度を
金の融点よりも高く設定しているのは、以下に説明する
ように、できるだけ短い炉芯管2によって、自由落下す
る金属線片を確実に融点以上の温度に加熱するためであ
る。![6は石英ガラスで形成され、炉芯管2の下端に
はめ込まれている。
The apparatus shown in the drawings includes a furnace core tube 2 which is a fall path for the metal wire piece 1o, a heating furnace 4 for melting the metal wire piece 10, and an IF 5 for collecting the formed fine metal spheres 20. The furnace core tube 2 was made of quartz glass with an inner diameter of about 5 mm and a length of about 1000 mm, and the heating furnace 4 was a vertical annular electric furnace with a length of 500 mm. The heating furnace 4 had a temperature distribution such that the highest temperature was near the lower end. The maximum temperature inside the heating furnace 4 is 1300°C. The reason why the maximum temperature of the heating furnace 4 is set higher than the melting point of gold is to ensure that the freely falling metal wire pieces are heated to a temperature above the melting point by using the shortest possible furnace core tube 2, as explained below. This is to do so. ! [6 is made of quartz glass and fitted into the lower end of the furnace core tube 2.

蓋6は高温の加熱炉4によって生ずる上昇気流を防ぐと
ともに、固化した微細金属球を回収するためのものであ
る。加熱炉4とM6との間隔は約2QQmmである。尚
、炉芯管2の内部は通常の大気雰囲気を用いている。
The lid 6 is used to prevent rising air currents generated by the high-temperature heating furnace 4 and to collect the solidified fine metal balls. The distance between the heating furnace 4 and M6 is approximately 2QQmm. Note that a normal atmospheric atmosphere is used inside the furnace core tube 2.

微細金属線の切断装置(不図示)で切断された金属線片
lOは、炉芯管2の上方から落下され、炉芯管2に入る
。金属線片10は炉芯管2内を落下し、加熱炉4に入る
と、温度が急激に上昇し始める。そして、金属線片は温
度がその金属の融点より高くなったときに溶融する。一
般に溶融金属は表面張力が大きいので、溶融状態では自
ら球形状に変化する。したがって、この溶融金属は加熱
炉4内を通過中に球形状に変化するが、加熱炉4を出る
と温度が急に下がり、この金属は凝固しはじめる。最後
に金属球が蓋6に落ち、固化した微細金属球20が得ら
れる。
The metal wire piece lO cut by a fine metal wire cutting device (not shown) is dropped from above the furnace core tube 2 and enters the furnace core tube 2. When the metal wire piece 10 falls through the furnace core tube 2 and enters the heating furnace 4, its temperature begins to rise rapidly. The piece of metal wire then melts when the temperature rises above the melting point of the metal. Generally, molten metal has a large surface tension, so it changes into a spherical shape by itself in the molten state. Therefore, this molten metal changes into a spherical shape while passing through the heating furnace 4, but when it exits the heating furnace 4, the temperature suddenly drops and the metal begins to solidify. Finally, the metal spheres fall into the lid 6, and solidified fine metal spheres 20 are obtained.

本発明者等が上記の装置及び金属線片を用いて実際に試
験を行ったところ、均一で綺麗な球形状の微細金属球を
得ることができた。
When the present inventors actually conducted tests using the above-mentioned apparatus and metal wire pieces, they were able to obtain fine metal spheres with a uniform and beautiful spherical shape.

このように、本実施例の微細金属の製造方法においては
、金属線片を搬送するための装置を設けることなく、金
属線片を炉芯管に入れるだけで微細金属球の回収工程ま
で一度に行なうことができるので、作業能率の向上と、
量産性の向上を図ることが可能になる。さらに、本実施
例の装置に、たとえば微細金属線を一定の間隔で一本毎
に切断する装置を本実施例の炉芯管の上部に備えること
により、微細金属線の切断工程、切断された金属線片の
球状化工程及び微細金属球の回収工程を連続して行うこ
とができる。
In this way, in the method for producing fine metal of this embodiment, the process of collecting fine metal balls can be completed all at once by simply putting the metal wire pieces into the furnace core tube, without providing any equipment for conveying the metal wire pieces. This improves work efficiency and
It becomes possible to improve mass productivity. Furthermore, by equipping the apparatus of this embodiment with a device for cutting fine metal wires one by one at regular intervals on the upper part of the furnace core tube of this embodiment, the cutting process of fine metal wires can be easily performed. The step of spheroidizing the metal wire piece and the step of collecting the fine metal spheres can be performed continuously.

また、本実施例の微細金属の製造方法では、従来取り上
げられなかった金属や合金にも適用することができるの
で、バンブとして適切な組成の微細金属球を能率良く製
造することができる。
Furthermore, the method for producing fine metals of this embodiment can be applied to metals and alloys that have not been considered in the past, so that fine metal spheres having an appropriate composition as bumps can be efficiently produced.

尚、上記の実施例においては、金線片を用いて金球を製
造する場合について説明したが、本発明はこれに限定さ
れるものではなく、バンプに相応しい他の金属を使用し
てもよい。一般に、金属線片の落下初期速度から、加熱
炉内の通過速度を知ることができる。また、金属線片の
大きさとその金属の融点から、必要な加熱炉の長さと最
高温度とが決まる。したがって、他の金属を用いて微細
金属球を製造する場合には炉芯管と加熱炉の大きさ、加
熱炉の温度等を変更する必要がある。また、金属によっ
ては、高温の加熱炉内において化学反応が起こらないよ
うに炉芯管内を特定のガス雰囲気で置換する必要もある
In addition, in the above embodiment, a case was explained in which a gold ball was manufactured using a piece of gold wire, but the present invention is not limited to this, and other metals suitable for the bump may be used. . Generally, the passing speed in the heating furnace can be determined from the initial falling speed of the metal wire piece. Further, the required length and maximum temperature of the heating furnace are determined from the size of the metal wire piece and the melting point of the metal. Therefore, when manufacturing fine metal balls using other metals, it is necessary to change the size of the furnace core tube and heating furnace, the temperature of the heating furnace, etc. Furthermore, depending on the metal, it may be necessary to replace the inside of the furnace core tube with a specific gas atmosphere to prevent chemical reactions from occurring in the high-temperature heating furnace.

また、上記の実施例では、炉芯管の下端部に蓋を被せた
場合について説明したが、本発明はこれに限定されるも
のではなく、たとえば蓋を用いずに、炉芯管の下端部を
テーパー状に加工し、下端の開口孔より微細金属球を回
収するようにしてもよい、これにより、たとえば炉芯管
の下方にベルトコンベア等を配置し、微細金属球を連続
的に回収することも可能になる。
Further, in the above embodiment, a case has been described in which the lower end of the furnace core tube is covered with a lid, but the present invention is not limited to this. It is also possible to process the tube into a tapered shape so that the fine metal balls can be collected through an opening at the bottom end.In this way, for example, a belt conveyor or the like can be placed below the furnace core tube to continuously collect the fine metal balls. It also becomes possible.

〔発明の効果〕〔Effect of the invention〕

以上説明したように本発明によれば、自由落下する金属
線片を加熱手段を用いて溶融し、溶融金属の大きな表面
張力を利用することによって、容易に微細金属球を製造
することができるので、部品な装置により作業能率の向
上を図り、量産性の向上を図ることができる微細金属球
の製造方法を提供することができる。
As explained above, according to the present invention, fine metal balls can be easily manufactured by melting freely falling pieces of metal wire using heating means and utilizing the large surface tension of the molten metal. Accordingly, it is possible to provide a method for manufacturing fine metal balls that can improve work efficiency and mass productivity using a component-based device.

【図面の簡単な説明】[Brief explanation of the drawing]

添付図面は本発明の一実施例である微細金属球の製造方
法において使用する装置の概略図である。 2・・・炉芯管、4・・・加熱炉、 6・・・蓋、10・・・金属線片、 20・・・微細金属球。
The accompanying drawing is a schematic diagram of an apparatus used in a method for manufacturing fine metal spheres, which is an embodiment of the present invention. 2... Furnace core tube, 4... Heating furnace, 6... Lid, 10... Metal wire piece, 20... Fine metal ball.

Claims (2)

【特許請求の範囲】[Claims] (1)加熱手段において縦に配置された炉芯管内を、金
属線片を自由落下させ、前記金属線片に用いている金属
の融点以上の温度に前記金属線片を加熱して溶融するこ
とにより、前記金属線片を球状化することを特徴とする
微細金属球の製造方法。
(1) A piece of metal wire is allowed to fall freely in a furnace core tube arranged vertically in a heating means, and the piece of metal wire is heated to a temperature higher than the melting point of the metal used for the piece of metal wire to melt it. A method for producing fine metal spheres, characterized in that the metal wire piece is spheroidized by:
(2)前記炉芯管の下端に蓋を設けた請求項1記載の微
細金属球の製造方法。
(2) The method for manufacturing fine metal balls according to claim 1, wherein a lid is provided at the lower end of the furnace core tube.
JP2179263A 1989-12-07 1990-07-06 Manufacture of fine metal balls Pending JPH0466601A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2179263A JPH0466601A (en) 1990-07-06 1990-07-06 Manufacture of fine metal balls
PCT/JP1990/001591 WO1991008850A1 (en) 1989-12-07 1990-12-06 Method of manufacturing minute metallic balls uniform in size
KR1019910700856A KR960000332B1 (en) 1989-12-07 1990-12-06 Method of manufacturing minute metallic balls or minute alloy balls
EP91900363A EP0457920B1 (en) 1989-12-07 1990-12-06 Method of manufacturing minute metallic balls uniform in size
DE69032249T DE69032249T2 (en) 1989-12-07 1990-12-06 METHOD FOR PRODUCING TINY METALLIC BALLS OF EVEN SIZE
US08/596,694 US5761779A (en) 1989-12-07 1996-02-05 Method of producing fine metal spheres of uniform size

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2179263A JPH0466601A (en) 1990-07-06 1990-07-06 Manufacture of fine metal balls

Publications (1)

Publication Number Publication Date
JPH0466601A true JPH0466601A (en) 1992-03-03

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP2179263A Pending JPH0466601A (en) 1989-12-07 1990-07-06 Manufacture of fine metal balls

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Country Link
JP (1) JPH0466601A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6911618B1 (en) 2004-02-03 2005-06-28 Hitachi Metals, Ltd. Method of producing minute metal balls

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63111101A (en) * 1986-10-30 1988-05-16 Daido Steel Co Ltd Spheroidizing method for metal or alloy powder
JPS63130701A (en) * 1986-11-20 1988-06-02 Aisin Seiki Co Ltd Production of metallic grain
JPH03281707A (en) * 1990-03-29 1991-12-12 Tatsuta Electric Wire & Cable Co Ltd Manufacture of fine lead balls
JPH03281705A (en) * 1990-03-29 1991-12-12 Tatsuta Electric Wire & Cable Co Ltd Manufacture of fine copper balls
JPH03281708A (en) * 1990-03-29 1991-12-12 Tatsuta Electric Wire & Cable Co Ltd Manufacture of fine lead balls
JPH03281706A (en) * 1990-03-29 1991-12-12 Tatsuta Electric Wire & Cable Co Ltd Manufacture of fine copper balls
JPH0426704A (en) * 1990-05-22 1992-01-29 Tatsuta Electric Wire & Cable Co Ltd Manufacture of fine gold ball
JPH0426701A (en) * 1990-05-21 1992-01-29 Tatsuta Electric Wire & Cable Co Ltd Manufacture of fine gold ball

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63111101A (en) * 1986-10-30 1988-05-16 Daido Steel Co Ltd Spheroidizing method for metal or alloy powder
JPS63130701A (en) * 1986-11-20 1988-06-02 Aisin Seiki Co Ltd Production of metallic grain
JPH03281707A (en) * 1990-03-29 1991-12-12 Tatsuta Electric Wire & Cable Co Ltd Manufacture of fine lead balls
JPH03281705A (en) * 1990-03-29 1991-12-12 Tatsuta Electric Wire & Cable Co Ltd Manufacture of fine copper balls
JPH03281708A (en) * 1990-03-29 1991-12-12 Tatsuta Electric Wire & Cable Co Ltd Manufacture of fine lead balls
JPH03281706A (en) * 1990-03-29 1991-12-12 Tatsuta Electric Wire & Cable Co Ltd Manufacture of fine copper balls
JPH0426701A (en) * 1990-05-21 1992-01-29 Tatsuta Electric Wire & Cable Co Ltd Manufacture of fine gold ball
JPH0426704A (en) * 1990-05-22 1992-01-29 Tatsuta Electric Wire & Cable Co Ltd Manufacture of fine gold ball

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6911618B1 (en) 2004-02-03 2005-06-28 Hitachi Metals, Ltd. Method of producing minute metal balls

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