JP6726812B2 - Soft chocolate - Google Patents
Soft chocolate Download PDFInfo
- Publication number
- JP6726812B2 JP6726812B2 JP2019566848A JP2019566848A JP6726812B2 JP 6726812 B2 JP6726812 B2 JP 6726812B2 JP 2019566848 A JP2019566848 A JP 2019566848A JP 2019566848 A JP2019566848 A JP 2019566848A JP 6726812 B2 JP6726812 B2 JP 6726812B2
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- Prior art keywords
- mass
- oil
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- fat
- chocolate
- Prior art date
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- 235000019861 non-lauric fat Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 235000014594 pastries Nutrition 0.000 description 1
- WTJKGGKOPKCXLL-RRHRGVEJSA-N phosphatidylcholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCCC=CCCCCCCCC WTJKGGKOPKCXLL-RRHRGVEJSA-N 0.000 description 1
- 150000008104 phosphatidylethanolamines Chemical class 0.000 description 1
- 150000003905 phosphatidylinositols Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 235000015108 pies Nutrition 0.000 description 1
- 235000012830 plain croissants Nutrition 0.000 description 1
- 239000001259 polydextrose Substances 0.000 description 1
- 235000013856 polydextrose Nutrition 0.000 description 1
- 229940035035 polydextrose Drugs 0.000 description 1
- 235000012434 pretzels Nutrition 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 235000012433 rusks Nutrition 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 235000020183 skimmed milk Nutrition 0.000 description 1
- 235000011888 snacks Nutrition 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 239000008347 soybean phospholipid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 235000012431 wafers Nutrition 0.000 description 1
- 235000012773 waffles Nutrition 0.000 description 1
- 235000019222 white chocolate Nutrition 0.000 description 1
- 235000019220 whole milk chocolate Nutrition 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/32—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
- A23G1/36—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds characterised by the fats used
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings, cooking oils
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings, cooking oils
- A23D9/007—Other edible oils or fats, e.g. shortenings, cooking oils characterised by ingredients other than fatty acid triglycerides
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/32—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/32—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
- A23G1/40—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds characterised by the carbohydrates used, e.g. polysaccharides
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/50—Cocoa products, e.g. chocolate; Substitutes therefor characterised by shape, structure or physical form, e.g. products with an inedible support
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/50—Cocoa products, e.g. chocolate; Substitutes therefor characterised by shape, structure or physical form, e.g. products with an inedible support
- A23G1/54—Composite products, e.g. layered laminated, coated, filled
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Confectionery (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
- Edible Oils And Fats (AREA)
Description
本開示は、焼成後も軟らかい食感が維持される、ソフトチョコレートに関する。 The present disclosure relates to soft chocolate that maintains a soft texture after baking.
チョコレートの食感は、焼成されることにより変化する。通常は、焼成により、チョコレートの表面は硬く変質する。そのため、焼成されたチョコレートは、手に取ってもべとつかないという利点がある。しかし、焼成により、チョコレートの食感も硬く変質してしまう。チョコレートを含むベーカリー生地を焼成することにより得られる、多くの焼成複合食品には、チョコレートの食感が焼成により変化しないことが求められる。特に、ベーカリー生地に包餡されたソフトチョコレートは、焼成後もソフトな食感を維持することが必要である。 The texture of chocolate changes as it is baked. Normally, the surface of chocolate is hardened and denatured by baking. Therefore, baked chocolate has the advantage that it is not sticky when picked up. However, baking causes the chocolate to have a hard texture and deteriorate. Many baked complex foods obtained by baking a bakery dough containing chocolate are required to have the texture of chocolate not changed by baking. In particular, soft chocolate wrapped in bakery dough needs to maintain a soft texture even after baking.
特開昭58−60944号公報には、0.1〜0.7重量%のHLB10以上の蔗糖脂肪酸エステルが配合されたチョコレートが開示されている。当該チョコレートは、焼菓子のドウに混入されて、焼成されても、その型崩れも、油滲みも、硬化も生じない。また、特開平11−225674号公報には、0.05〜1重量%のポリグリセリンオレイン酸モノエステル及び0.05〜1重量%のHLB5以下のポリグリセリンオレイン酸エステルが添加されたチョコレート類が開示されている。当該チョコレート類は、スナック菓子生地中に入れて焼成されても、その硬化により食感が損なわれることがない。 JP-A-58-60944 discloses a chocolate containing 0.1 to 0.7% by weight of HLB10 or more sucrose fatty acid ester. Even when the chocolate is mixed with the dough of baked confectionery and baked, its shape, oil bleeding, and hardening do not occur. Further, JP-A No. 11-225674 discloses chocolates to which 0.05 to 1% by weight of polyglycerin oleic acid monoester and 0.05 to 1% by weight of HLB5 or less polyglycerin oleic acid ester are added. It is disclosed. Even when the chocolates are put in a snack confectionery dough and baked, the hardening does not impair the texture.
しかしながら、上記特許文献に記載のチョコレートは、常温で固形のチョコレートである。そのため、この文献に開示の技術を常温で可塑性または流動性を有するソフトチョコレートに適用しても、得られる効果が乏しい。 However, the chocolate described in the above patent documents is a solid chocolate at room temperature. Therefore, even if the technique disclosed in this document is applied to soft chocolate having plasticity or fluidity at room temperature, the obtained effect is poor.
本開示の課題は、焼成複合食品生地に含まれて焼成されても、常温での可塑性または流動性を有するソフトチョコレートを提供することである。 An object of the present disclosure is to provide a soft chocolate having plasticity or fluidity at room temperature even when it is contained in a baked composite food material and baked.
本発明者らは、上記課題を解決すべく鋭意研究を行った。その結果、チョコレートに含まれる油脂が、特定の固体脂含有量(SFC)を有し、特定量のリン脂質を含有することにより、本課題が解決できることが見いだされた。これにより、本開示のソフトチョコレートが完成するに至った。 The present inventors have conducted earnest research to solve the above problems. As a result, it has been found that the fat and oil contained in chocolate has a specific solid fat content (SFC) and contains a specific amount of phospholipid, whereby this problem can be solved. This led to the completion of the soft chocolate of the present disclosure.
すなわち、本開示は、以下のソフトチョコレートおよび当該ソフトチョコレートを含有する焼成複合食品を提供する。
(1)油脂の連続相を有し、糖類を含有する、ソフトチョコレートであって、
前記油脂の固体脂含有量(SFC)が、10℃で4〜34%、20℃で2〜24%、および30℃で0〜4%であり、
0.25〜1.3質量%のリン脂質を含む、
前記ソフトチョコレート。
(2)さらに、ポリグリセリン縮合リシノレイン酸エステルを含む、(1)のソフトチョコレート。
(3)前記糖類が、乳糖を含有する、(1)または(2)のソフトチョコレート。
(4)(1)〜(3)の何れか1つのソフトチョコレートを含む、複合食品。
(5)包餡されたのち、焼成された(1)〜(3)の何れか1つのソフトチョコレートを含む焼成複合食品。That is, the present disclosure provides the following soft chocolate and a baked complex food containing the soft chocolate.
(1) A soft chocolate having a continuous phase of fats and oils and containing a saccharide,
The solid fat content (SFC) of the fat is 4 to 34% at 10°C, 2 to 24% at 20°C, and 0 to 4% at 30°C,
0.25 to 1.3% by weight of phospholipids,
The soft chocolate.
(2) The soft chocolate of (1), which further contains polyglycerin condensed ricinoleic acid ester.
(3) The soft chocolate according to (1) or (2), wherein the saccharide contains lactose.
(4) A complex food containing the soft chocolate according to any one of (1) to (3).
(5) A baked composite food product containing the soft chocolate of any one of (1) to (3), which is baked after being wrapped.
本開示によれば、焼成複合食品生地に含まれて焼成されても、常温での可塑性または流動性を有するソフトチョコレートを提供することができる。また、当該ソフトチョコレートを含む焼成複合食品生地、および、当該生地を焼成して得られる焼成複合食品、を提供することができる。 According to the present disclosure, it is possible to provide a soft chocolate having plasticity or fluidity at room temperature even if it is contained in a baked complex food dough and baked. It is also possible to provide a baked complex food dough containing the soft chocolate, and a baked composite food product obtained by baking the dough.
以下、本開示について順を追って記述する。
なお、本開示において特に説明のない場合、A(数値)〜B(数値)は、A(数値)以上B(数値)以下を意味する。Hereinafter, the present disclosure will be described step by step.
In the present disclosure, unless otherwise specified, A (numerical value) to B (numerical value) mean A (numerical value) or more and B (numerical value) or less.
本開示においてチョコレートとは、チョコレート類の表示に関する日本の公正競争規約(全国チョコレート業公正取引協議会)または法規に規定されているチョコレートに限定されない。本開示におけるチョコレートは、食用油脂、並びに、糖類を主原料とする。主原料には、必要に応じて、カカオ成分(カカオマス、ココアパウダーなど)、乳製品、香料、または乳化剤などが加えられる。かかるチョコレートは、チョコレートの製造工程(混合工程、微粒化工程、精練工程、成形工程、および、冷却工程など)の全部または一部を経て製造されうる。また、本開示におけるチョコレートは、ダークチョコレートおよびミルクチョコレートの他に、ホワイトチョコレートおよびカラーチョコレートも含む。 In the present disclosure, chocolate is not limited to the chocolate provided in Japan's Fair Competition Code (National Chocolate Industry Fair Trade Council) or the regulations for labeling chocolates. Chocolate in the present disclosure has edible oils and fats and sugars as main raw materials. If necessary, cacao ingredients (cocoa mass, cocoa powder, etc.), dairy products, flavors, emulsifiers, etc. are added to the main raw material. Such chocolate can be manufactured through all or part of the chocolate manufacturing steps (mixing step, atomizing step, refining step, molding step, cooling step, etc.). The chocolate in the present disclosure also includes white chocolate and color chocolate, as well as dark chocolate and milk chocolate.
本開示のソフトチョコレートは、上記チョコレートにおいて、油脂を連続相とし、チョコレートに含まれる油脂が、以下の固体脂含有量(SFC)を満たすチョコレートである。本開示のソフトチョコレートに含まれる油脂のSFCは、10℃で4〜34%、20℃で2〜24%、30℃で0〜4%であり、好ましくは、10℃で4〜28%、20℃で2〜14%、30℃で0〜3%であり、より好ましくは、10℃で4〜16%、20℃で3〜11%、30℃で0〜2%であり、さらに好ましくは、10℃で5〜12%、20℃で3〜9%、30℃で0〜2%である。本開示のソフトチョコレートに含まれる油脂のSFCが上記範囲内にあると、ソフトチョコレートは常温(15〜30℃)でソフトな食感を有する。なお、油脂のSFCは、IUPAC法2.150a Solid Content determination in Fats by NMRに準じて測定できる。 The soft chocolate of the present disclosure is a chocolate in which fat and oil are used as a continuous phase in the above chocolate, and the fat and oil contained in the chocolate satisfies the following solid fat content (SFC). SFC of fats and oils contained in the soft chocolate of the present disclosure is 4 to 34% at 10°C, 2 to 24% at 20°C, and 0 to 4% at 30°C, preferably 4 to 28% at 10°C. 2 to 14% at 20°C, 0 to 3% at 30°C, more preferably 4 to 16% at 10°C, 3 to 11% at 20°C, 0 to 2% at 30°C, and further preferably Is 5 to 12% at 10°C, 3 to 9% at 20°C, and 0 to 2% at 30°C. When the SFC of fats and oils contained in the soft chocolate of the present disclosure is within the above range, the soft chocolate has a soft texture at room temperature (15 to 30°C). The SFC of fats and oils can be measured according to IUPAC method 2.150a Solid Content determination in Fats by NMR.
本開示のソフトチョコレートの油脂含有量は、好ましくは25〜55質量%であり、より好ましくは25〜45質量%であり、さらに好ましくは27〜38質量%であり、ことさらに好ましくは28〜35質量%であり、最も好ましくは29〜34質量%である。なお、本開示におけるチョコレートに含まれる油脂は、配合される油脂以外に、含油原料(カカオマス、ココアパウダー、および全脂粉乳など)由来の油脂(ココアバター、および乳脂など)も含む。例えば、一般的に、カカオマスの油脂(ココアバター)含有量は、55質量%(含油率0.55)である。ココアパウダーの油脂(ココアバター)含有量は、11質量%(含油率0.11)である。全脂粉乳の油脂(乳脂)含有量は、25質量%(含油率0.25)である。そのため、チョコレートに含まれる油脂の含有量は、各原料のチョコレート中の配合量(質量%)に含油率を掛け合わせて得られる値を合計した値となる。 The fat content of the soft chocolate of the present disclosure is preferably 25 to 55 mass%, more preferably 25 to 45 mass%, further preferably 27 to 38 mass%, and further preferably 28 to 35 mass%. % By mass, and most preferably 29 to 34% by mass. In addition, the fats and oils contained in the chocolate in the present disclosure include fats and oils (cocoa butter, milk fats and the like) derived from oil-containing raw materials (such as cacao mass, cocoa powder, and whole milk powder) in addition to the fats and oils to be blended. For example, the content of oil and fat (cocoa butter) in cocoa mass is generally 55% by mass (oil content 0.55). The oil and fat (cocoa butter) content of the cocoa powder is 11% by mass (oil content 0.11). The fat and oil (milk fat) content of the whole milk powder is 25% by mass (oil content 0.25). Therefore, the content of fats and oils contained in chocolate is the sum of the values obtained by multiplying the blended amount (mass %) of each raw material in chocolate with the oil content.
本開示のソフトチョコレートに含まれる油脂は、上記SFCを満たす限り、特に限定されない。本開示のソフトチョコレートに含まれる油脂は、通常の食用油脂を使用できる。例えば、ココアバター、パーム油、パーム分別油、シア脂、シア分別油、サル脂、サル分別油、イリッペ脂、コクム脂、マンゴー脂、マンゴー分別油、大豆油、菜種油、綿実油、サフラワー油、ひまわり油、米油、コーン油、ゴマ油、オリーブ油、ヤシ油、パーム核油、牛脂、豚脂および乳脂などの動植物油脂、あるいは、これらに混合、分別、エステル交換、および水素添加など処理のうちの1種以上を適用することにより得られる加工油脂、の中から1種以上を選択して使用できる。 The fat and oil contained in the soft chocolate of the present disclosure is not particularly limited as long as it satisfies the above SFC. As the fats and oils contained in the soft chocolate of the present disclosure, ordinary edible fats and oils can be used. For example, cocoa butter, palm oil, palm fractionated oil, shea butter, shea fractionated oil, monkey fat, monkey fractionated oil, illipe fat, kokumu butter, mango fat, mango fractionated oil, soybean oil, rapeseed oil, cottonseed oil, safflower oil, Animal and vegetable oils such as sunflower oil, rice oil, corn oil, sesame oil, olive oil, coconut oil, palm kernel oil, beef tallow, lard and milk fat, or a mixture of these, fractionation, transesterification, and hydrogenation treatment One or more types can be selected and used from the processed fats and oils obtained by applying one or more types.
本開示のソフトチョコレートに含まれる油脂は、好ましくは、非ラウリン系油脂を分別処理した低融点部としての、油脂Aを含有する。ここで、非ラウリン系油脂とは、その油脂の構成脂肪酸の全量に占める炭素数16以上の脂肪酸の含有量が90質量%以上である油脂を意味する。非ラウリン系油脂の具体例としては、大豆油、菜種油、綿実油、ヒマワリ油、紅花油、コーン油、パーム油や、これらの混合油、これらの油脂の加工油脂(エステル交換油、分別油、及び水素添加油など)、および、これら混合油脂の加工油脂(エステル交換油、分別油、及び水素添加油など)が挙げられる。油脂Aは、好ましくはヨウ素価が62以上である。また、油脂Aは、好ましくは以下の(a)から(d)の条件を満たす。
(a)L3含有量が5質量%未満
(b)L2X含有量が10〜40質量%
(c)LX2含有量が45〜75質量%
(d)X3含有量が2〜22質量%
上記の(a)から(d)の条件において、L、X、L3、L2X、LX2およびX3は、それぞれ以下を意味する
L:炭素数16〜18の直鎖飽和脂肪酸
X:炭素数16〜18の直鎖不飽和脂肪酸
L3:Lが3分子結合しているトリグリセリド
L2X:Lが2分子、Xが1分子結合しているトリグリセリド
LX2:Lが1分子、Xが2分子結合しているトリグリセリド
X3:Xが3分子結合しているトリグリセリド
なお、油脂に含まれるトリグリセリドは、例えば、ガスクロマトグラフィー法(JAOCS,vol70,11,1111−1114(1993))に準じて測定できる。The fats and oils contained in the soft chocolate of the present disclosure preferably contain fats and oils A as a low melting point part obtained by fractionating non-lauric fats and oils. Here, the non-lauric oil/fat means an oil/fat in which the content of fatty acids having 16 or more carbon atoms in the total amount of constituent fatty acids of the oil/fat is 90% by mass or more. Specific examples of non-lauric oils and fats include soybean oil, rapeseed oil, cottonseed oil, sunflower oil, safflower oil, corn oil, palm oil and mixed oils thereof, processed oils and fats of these oils (ester exchange oil, fractionated oil, and Hydrogenated oils) and processed oils and fats of these mixed oils and fats (such as transesterified oils, fractionated oils and hydrogenated oils). The fat A preferably has an iodine value of 62 or more. The fat A preferably satisfies the following conditions (a) to (d).
(A) L3 content is less than 5 mass% (b) L2X content is 10 to 40 mass%
(C) LX2 content is 45 to 75% by mass
(D) X3 content of 2 to 22% by mass
Under the conditions (a) to (d) above, L, X, L3, L2X, LX2 and X3 mean the following, respectively: L: linear saturated fatty acid having 16 to 18 carbon atoms X: 16 to 18 carbon atoms Triglyceride L2X:L having 3 molecules of a linear unsaturated fatty acid L3:L bound thereto, 2 molecules of triglyceride LX2:L having 1 molecule bound thereto, 1 molecule of triglyceride L2:L, and triglyceride X3 having 2 molecules bound to X : Triglyceride in which 3 molecules of X are bonded The triglyceride contained in the fat or oil can be measured according to, for example, a gas chromatography method (JAOCS, vol70, 11, 1111-1114 (1993)).
上記油脂Aの1種または2種以上を用いることができる。油脂Aの具体例として、以下に説明する油脂A−1、油脂A−2、油脂A−3が挙げられる。油脂A−1は、パーム油、パーム分別油、あるいはそれらの混合油を分別して得られるヨウ素価が62以上である低融点部である。油脂A−1は、好ましくは、パーム油を2回以上分別して得られる低融点部(パームスーパーオレイン)である。分別方法は、例えば、通常、パーム油の分別に用いられる、乾式分別、乳化分別(湿式分別)、および溶剤分別のうちから、適宜選択される方法を適用することができる。 One or more of the above-mentioned fats and oils A can be used. Specific examples of the fat A include fat A-1, fat A-2, and fat A-3 described below. The oil/fat A-1 is a low melting point portion having an iodine value of 62 or more, which is obtained by fractionating palm oil, palm fractionated oil, or a mixed oil thereof. The oil/fat A-1 is preferably a low melting point portion (palm super olein) obtained by fractionating palm oil two or more times. As the fractionation method, for example, a method appropriately selected from dry fractionation, emulsification fractionation (wet fractionation), and solvent fractionation, which are usually used for fractionation of palm oil, can be applied.
上記油脂A−2は、原料としてのパーム系油脂を40質量%以上含むエステル交換油脂を単独で分別して得られる、ヨウ素価が62以上である低融点部である。あるいは、該エステル交換油脂40〜90質量%と、パーム系油脂10〜60質量%と、の混合油を分別して得られる、ヨウ素価が62以上である低融点部である。エステル交換方法としては、従来公知の方法を適用することができる。分別方法としては、上記と同様の方法を適用することができる。ここで、パーム系油脂の例としては、パーム油および、パーム油の加工油脂(エステル交換油、分別油、及び水素添加油など)挙げることができる。パーム系油脂の具体例としては、パーム油、パームオレイン、パームミッドフラクション、パームステアリン、および極度硬化パーム油を挙げられる。 The oil/fat A-2 is a low melting point part having an iodine value of 62 or more, which is obtained by separately separating a transesterified oil/fat containing 40% by mass or more of palm-based oil/fat as a raw material. Alternatively, it is a low melting point part having an iodine value of 62 or more, which is obtained by fractionating a mixed oil of 40 to 90 mass% of the transesterified oil and fat and 10 to 60 mass% of the palm oil and fat. As a transesterification method, a conventionally known method can be applied. A method similar to the above can be applied as the classification method. Here, examples of palm-based fats and oils include palm oil and processed fats and oils of palm oil (such as transesterified oil, fractionated oil, and hydrogenated oil). Specific examples of palm oils and fats include palm oil, palm olein, palm mid fraction, palm stearin, and extremely hardened palm oil.
上記油脂A−2の原料油脂である、分別前の上記エステル交換油脂は、好ましくは、その構成脂肪酸の全量に占めるパルミチン酸含有量が30〜50質量%、ステアリン酸含有量が10〜29質量%、オレイン酸含有量が20〜40質量%、そして、リノール酸とリノレン酸の含有量の合計が15質量%未満である。より好ましくは、その構成脂肪酸中のラウリン酸含有量が2質量%未満、パルミチン酸含有量が33〜47質量%、ステアリン酸含有量が13〜27質量%、オレイン酸含有量が23〜37質量%、そして、リノール酸とリノレン酸の含有量の合計が12質量%未満である。さらに好ましくは、その構成脂肪酸中のラウリン酸含有量が1質量%未満、パルミチン酸含有量が35〜45質量%、ステアリン酸含有量が15〜25質量%、オレイン酸含有量が25〜35質量%、そして、リノール酸とリノレン酸の合計含有量が10質量%未満である。 The transesterified oil and fat before fractionation, which is a raw material oil and fat of the oil and fat A-2, preferably has a palmitic acid content of 30 to 50% by mass and a stearic acid content of 10 to 29% by mass relative to the total amount of the constituent fatty acids. %, the oleic acid content is 20 to 40% by mass, and the total content of linoleic acid and linolenic acid is less than 15% by mass. More preferably, the lauric acid content of the constituent fatty acids is less than 2% by mass, the palmitic acid content is 33 to 47% by mass, the stearic acid content is 13 to 27% by mass, and the oleic acid content is 23 to 37% by mass. %, and the total content of linoleic acid and linolenic acid is less than 12% by mass. More preferably, the lauric acid content of the constituent fatty acids is less than 1% by mass, the palmitic acid content is 35 to 45% by mass, the stearic acid content is 15 to 25% by mass, and the oleic acid content is 25 to 35% by mass. %, and the total content of linoleic acid and linolenic acid is less than 10% by mass.
上記の、油脂A−1および油脂A−2の、LX2含有量に対するL2X含有量の質量比(L2X/LX2)は、好ましくは0.48〜0.92であり、より好ましくは0.50〜0.86である。 The mass ratio (L2X/LX2) of the L2X content to the LX2 content of the fats and oils A-1 and A-2 is preferably 0.48 to 0.92, more preferably 0.50 to 0.92. It is 0.86.
上記油脂A−3は、SX2を50質量%以上含有する油脂である。ここで、Sは、ステアリン酸を意味する。SX2は、Sが1分子、Xが2分子結合しているトリグリセリドを意味する。油脂A−3の具体例としては、カカオ代用脂の原料油脂としての、サル脂、シア脂、モーラー脂、マンゴー核油、アランブラッキア脂、あるいはペンタデスマ脂などのSOS(1,3−ジステアロイル−2−オレオイルグリセロール)を30質量%以上含有する油脂を分別して得られる低融点部が挙げられる。また、油脂は、既知の方法に基づいて、例えば、以下の方法により調製してもよい。この方法では、まず、1,3位選択性リパーゼ製剤を用いて、ハイオレイックヒマワリ油と、ステアリン酸エチルエステルと、の混合物のエステル交換反応が行われる。次いで、反応物から脂肪酸エチルエステルを蒸留により除去して、前述のSOSを30質量%以上含有する油脂が得られる。分別方法としては、上記と同様の方法を適用することができる。油脂A−3の、LX2含有量に対するL2X含有量の質量比(L2X/LX2)は、好ましくは0.10〜0.22であり、より好ましくは0.13〜0.20である。 The oil/fat A-3 is an oil/fat containing 50% by mass or more of SX2. Here, S means stearic acid. SX2 means a triglyceride in which one molecule of S and two molecules of X are bound. Specific examples of the oil/fat A-3 include SOS (1,3-distearoyl) such as monkey butter, shea butter, molar butter, mango kernel oil, alan brachia butter, and pentadesma butter as raw material fats and oils for cocoa substitute. (2-oleoyl glycerol) is included in the low melting point portion obtained by fractionating an oil or fat containing 30% by mass or more. The fats and oils may be prepared based on a known method, for example, by the following method. In this method, first, a transesterification reaction of a mixture of high oleic sunflower oil and stearic acid ethyl ester is performed using a 1,3-position selective lipase preparation. Then, the fatty acid ethyl ester is removed from the reaction product by distillation to obtain an oil and fat containing 30% by mass or more of the above SOS. A method similar to the above can be applied as the classification method. The mass ratio (L2X/LX2) of the L2X content to the LX2 content of the oil/fat A-3 is preferably 0.10 to 0.22, more preferably 0.13 to 0.20.
本開示のソフトチョコレートに含まれる油脂は、好ましくは、油脂Bを含有する。油脂Bのヨウ素価は、5以下であり、更に、油脂Bの構成脂肪酸の全量に占める炭素数16以上の飽和脂肪酸の含有量は、90質量%以上である。油脂Bは、好ましくは非ラウリン系の天然油脂の極度硬化油である。非ラウリン系の天然油脂の極度硬化油の例としては、大豆油、菜種油、綿実油、ヒマワリ油、紅花油、コーン油、パーム油、およびパーム分別油などの極度硬化油が挙げられる。非ラウリン系の天然油脂の極度硬化油は、好ましくは菜種油の極度硬化油であり、より好ましくはハイエルシン酸菜種油の極度硬化油である。 The oil and fat contained in the soft chocolate of the present disclosure preferably contains oil and fat B. The iodine value of the fat/oil B is 5 or less, and the content of the saturated fatty acid having 16 or more carbon atoms in the total amount of the constituent fatty acids of the fat/oil B is 90% by mass or more. The fat B is preferably a non-lauric natural fat/oil which is extremely hardened. Examples of non-lauric natural hardened oils are those of soybean oil, rapeseed oil, cottonseed oil, sunflower oil, safflower oil, corn oil, palm oil, and palm fractionated oil. The extremely hardened oil of non-lauric natural oil is preferably a hardened oil of rapeseed oil, and more preferably a hardened oil of rapeseed oil of hyersinic acid.
本開示のソフトチョコレートに含まれる油脂に占める上記油脂Aの含有量は、好ましくは60〜99質量%であり、より好ましくは70〜98質量%であり、さらに好ましくは80〜97質量%である。また、本開示のソフトチョコレートに含まれる油脂に占める上記油脂Bの含有量は、好ましくは0.3〜4質量%であり、より好ましくは0.5〜3質量%であり、さらに好ましくは0.7〜2質量%である。本開示のソフトチョコレートに含まれる油脂に占める油脂Aおよび/または油脂Bの含有量が上記範囲内にあると、焼成によるチョコレートのベーカリー生地への浸み込みが少ない。 The content of the above-mentioned fat/oil A in the fat/oil contained in the soft chocolate of the present disclosure is preferably 60 to 99% by mass, more preferably 70 to 98% by mass, and further preferably 80 to 97% by mass. .. Further, the content of the above-mentioned fat/oil B in the fat/oil contained in the soft chocolate of the present disclosure is preferably 0.3 to 4% by mass, more preferably 0.5 to 3% by mass, and further preferably 0. It is 7-2 mass %. When the content of the fats A and/or the fats B in the fats and oils contained in the soft chocolate of the present disclosure is within the above range, the chocolate is not soaked into the bakery dough by baking.
本開示のソフトチョコレートは、糖類を含有する。本開示のソフトチョコレートに含まれる糖類の例として、砂糖(ショ糖)、乳糖、ブドウ糖、麦芽糖、オリゴ糖、フラクトオリゴ糖、大豆オリゴ糖、ガラクトオリゴ糖、乳果オリゴ糖、パラチノースオリゴ糖、酵素糖化水飴、還元澱粉糖化物、異性化液糖、ショ糖結合水飴、はちみつ、還元糖ポリデキストロース、ラフィノース、ラクチュロース、還元乳糖、ソルビトール、キシロース、キシリトール、マルチトール、エリスリトール、マンニトール、およびトレハロースなどが挙げられる。また、糖類は、糖アルコールであってもよい。本開示のソフトチョコレートに含まれる糖類の含有量は、好ましくは20〜70質量%であり、より好ましくは30〜65質量%であり、さらに好ましくは35〜60質量%であり、ことさらに好ましくは40〜55質量%である。なお、本開示のソフトチョコレートに含まれる糖類には、糖類以外の原材料に含まれる糖類(例えば、粉乳に含まれる乳糖など)の量は含まれない。 The soft chocolate of the present disclosure contains sugar. Examples of sugars contained in the soft chocolate of the present disclosure include sugar (sucrose), lactose, glucose, maltose, oligosaccharides, fructooligosaccharides, soybean oligosaccharides, galactooligosaccharides, milk fruit oligosaccharides, palatinose oligosaccharides, enzymatic saccharified starch syrup. , Reduced starch saccharified product, isomerized liquid sugar, sucrose-bonded starch syrup, honey, reducing sugar polydextrose, raffinose, lactulose, reducing lactose, sorbitol, xylose, xylitol, maltitol, erythritol, mannitol, and trehalose. Further, the sugar may be sugar alcohol. The content of saccharides contained in the soft chocolate of the present disclosure is preferably 20 to 70% by mass, more preferably 30 to 65% by mass, further preferably 35 to 60% by mass, and further preferably It is 40 to 55 mass %. It should be noted that the sugars contained in the soft chocolate of the present disclosure do not include the amount of sugars contained in raw materials other than sugars (for example, lactose contained in milk powder).
本開示のソフトチョコレートは、好ましくは、糖類の1つとしてショ糖を含有する。本開示のチョコレートに含まれるショ糖の含有量は、好ましくは25〜55質量%であり、より好ましくは28〜50質量%であり、さらに好ましくは30〜46質量%である。また、本開示のソフトチョコレートは、好ましくは、糖類の1つとして乳糖を含有する。本開示のソフトチョコレートに含まれる乳糖の含有量は、好ましくは1〜20質量%であり、より好ましくは5〜16質量%であり、さらに好ましくは7〜13質量%である。本開示のソフトチョコレートに含まれるショ糖および/または乳糖の含有量が上記範囲内にあると、ソフトチョコレートは焼成複合食品生地に含まれて焼成された後にソフトな食感を維持できる。 The soft chocolate of the present disclosure preferably contains sucrose as one of the sugars. The content of sucrose contained in the chocolate of the present disclosure is preferably 25 to 55% by mass, more preferably 28 to 50% by mass, and further preferably 30 to 46% by mass. In addition, the soft chocolate of the present disclosure preferably contains lactose as one of the sugars. The content of lactose contained in the soft chocolate of the present disclosure is preferably 1 to 20% by mass, more preferably 5 to 16% by mass, and further preferably 7 to 13% by mass. When the content of sucrose and/or lactose contained in the soft chocolate of the present disclosure is within the above range, the soft chocolate can maintain a soft texture after being contained in the baked composite food dough and baked.
本開示のソフトチョコレートは、0.25〜1.3質量%のリン脂質を含有する。本開示のソフトチョコレートに含まれるリン脂質は、特に限定はされない。しかし、実用上は、レシチンに含まれるリン脂質が適用できる。レシチンは、動植物界に広く存在する界面活性能を有する数種のリン脂質の混合物である。レシチンは、工業的には、大豆あるいは菜種などの油糧種子、または、卵黄などの動物原料から得られる。例えば、大豆レシチンには、ホスファチジルコリン、ホスファチジルエタノ−ルアミン、ホスファチジルイノシト−ル、およびホスファチジルセリンなどのリン脂質が混合状態で含まれている。また、市販のレシチンは、一般的な粗製レシチン以外にも、これを脱油して得られる精製粉末レシチン、レシチンの成分を分画して得られる分画レシチン、レシチンに酵素を作用させて得られる酵素処理レシチン、あるいはレシチンを水素添加して得られる水素添加レシチンなども使用できる。 The soft chocolate of the present disclosure contains 0.25 to 1.3% by mass of phospholipid. The phospholipid contained in the soft chocolate of the present disclosure is not particularly limited. However, in practice, the phospholipid contained in lecithin can be applied. Lecithin is a mixture of several phospholipids with surface-active properties that are widely present in the animal and plant kingdoms. Lecithin is industrially obtained from oil seeds such as soybean or rapeseed, or animal raw materials such as egg yolk. For example, soy lecithin contains mixed phospholipids such as phosphatidylcholine, phosphatidylethanolamine, phosphatidylinositol, and phosphatidylserine. Further, commercially available lecithin, in addition to general crude lecithin, purified powdered lecithin obtained by deoiling it, fractionated lecithin obtained by fractionating the components of lecithin, obtained by reacting the enzyme with lecithin. The enzyme-treated lecithin as described above or hydrogenated lecithin obtained by hydrogenating lecithin can also be used.
本開示のソフトチョコレートに含まれるリン脂質としてレシチンを適用する場合、リン脂質の含有量が0.25〜1.3質量%となるように、レシチンの使用量を調整すればよい。例えば、リン脂質含有量が65質量%である粗製大豆レシチンを使用する場合、ソフトチョコレートに含まれる粗製大豆レシチンの含有量が1質量%であれば、ソフトチョコレートに含まれるリン脂質の含有量は、約0.65質量%である。本開示のソフトチョコレートに含まれるリン脂質の含有量は、好ましくは0.32〜0.84質量%であり、より好ましくは0.38〜0.54質量%であり、さらに好ましくは0.41〜0.52質量%である。本開示のソフトチョコレートに含まれるリン脂質の含有量が上記範囲内にあると、粗製レシチンを使用しても、チョコレートは風味がよく、焼成後もソフトな食感を維持する。 When lecithin is applied as the phospholipid contained in the soft chocolate of the present disclosure, the amount of lecithin used may be adjusted so that the phospholipid content is 0.25 to 1.3% by mass. For example, when using crude soybean lecithin having a phospholipid content of 65% by mass, the content of phospholipid contained in soft chocolate is 1% by mass if the content of crude soybean lecithin contained in soft chocolate is 1% by mass. , About 0.65% by mass. The content of phospholipids contained in the soft chocolate of the present disclosure is preferably 0.32 to 0.84% by mass, more preferably 0.38 to 0.54% by mass, and further preferably 0.41. Is 0.52% by mass. When the content of the phospholipids contained in the soft chocolate of the present disclosure is within the above range, the chocolate has a good flavor even if crude lecithin is used, and maintains a soft texture even after baking.
なお、粗製レシチンに含まれるリン脂質含有量は、例えば、アセトン不溶物含有量として求めることができる。レシチンのアセトン不溶物含量は、例えば、次のようにして求められる。試料2gをビーカーに計りとり、氷冷したアセトン300ミリリットルを加え、十分攪拌して30分間放置する。上澄み液を質量既知のガラス濾過器で吸引ろ過し、さらに氷冷したアセトン30ミリリットルで3回不溶物を洗浄して、不溶物の全量をガラス濾過器に移し入れる。ガラス濾過器に氷冷したアセトンを満たし、吸引した後、ガラス濾過機を減圧下で乾燥させ、質量を測定する。ガラス濾過機の質量の増加分が、アセトン不溶物の質量である。(不溶物の質量/試料採取量)×100がアセトン不溶物(質量%)となる。 The content of phospholipid contained in the crude lecithin can be calculated, for example, as the content of acetone insoluble matter. The acetone insoluble matter content of lecithin can be determined as follows, for example. 2 g of the sample is weighed in a beaker, 300 ml of ice-cooled acetone is added, sufficiently stirred and left for 30 minutes. The supernatant is suction-filtered with a glass filter of known mass, and the insoluble matter is washed three times with 30 ml of ice-cooled acetone, and the whole amount of the insoluble matter is transferred to the glass filter. The glass filter is filled with ice-cold acetone, and after suctioning, the glass filter is dried under reduced pressure and the mass is measured. The increase in the mass of the glass filter is the mass of the acetone insoluble matter. (Mass of insoluble matter/sampled amount)×100 is acetone insoluble matter (mass %).
本開示のソフトチョコレートは、さらに、ポリグリセリン縮合リシノレイン酸エステルを含有してもよい。本開示のソフトチョコレートに含まれるポリグリセリン縮合リシノレイン酸エステルの含有量は、好ましくは0.05〜0.4質量%であり、より好ましくは0.08〜0.3質量%であり、さらに好ましくは0.1〜0.2質量%である。本開示のソフトチョコレートに含まれるポリグリセリン縮合リシノレイン酸エステルの含有量が上記範囲内にあると、焼成後のチョコレートは、ソフトな食感を維持し、良好な艶を有する。 The soft chocolate of the present disclosure may further contain polyglycerin condensed ricinoleic acid ester. The content of polyglycerin condensed ricinoleic acid ester contained in the soft chocolate of the present disclosure is preferably 0.05 to 0.4% by mass, more preferably 0.08 to 0.3% by mass, and further preferably Is 0.1 to 0.2% by mass. When the content of the polyglycerin-condensed ricinoleic acid ester contained in the soft chocolate of the present disclosure is within the above range, the chocolate after baking maintains a soft texture and has a good luster.
本開示のソフトチョコレートは、油脂、糖質、およびリン脂質以外にも、チョコレートに一般的に配合される原料を使用することができる。具体的な原料の例として、全脂粉乳および脱脂粉乳などの乳製品、カカオマスおよびココアパウダーなどのカカオ成分、大豆粉、大豆蛋白、果実加工品、野菜加工品、抹茶粉末およびコーヒー粉末などの各種粉末、ガム類、澱粉類、ショ糖脂肪酸エステル、ポリグリセリン脂肪酸エステルおよびソルビタン脂肪酸エステルなどの乳化剤、酸化防止剤、着色料、および香料などが挙げられる。 The soft chocolate of the present disclosure can use raw materials generally blended with chocolate in addition to fats and oils, sugars, and phospholipids. Examples of specific raw materials include dairy products such as whole milk powder and skim milk powder, cocoa components such as cacao mass and cocoa powder, soybean powder, soy protein, processed fruits, processed vegetables, matcha powder and coffee powder. Examples include powders, gums, starches, emulsifiers such as sucrose fatty acid esters, polyglycerin fatty acid esters and sorbitan fatty acid esters, antioxidants, colorants, and flavors.
本開示のソフトチョコレートは、従来公知の方法により製造できる。本開示のソフトチョコレートは、例えば、油脂、糖類、カカオ成分、乳製品、並びに、レシチンなどの原材料を使用して、混合工程、微粒化工程(リファイニング)、精練工程(コンチング)、および、冷却工程などの、一部または全部を経て、製造することができる。精錬工程の後で、必要に応じて、テンパリング処理が行われてもよい。 The soft chocolate of the present disclosure can be produced by a conventionally known method. The soft chocolate of the present disclosure uses, for example, raw materials such as fats and oils, sugars, cacao components, dairy products, and lecithin, and a mixing step, an atomizing step (refining), a scouring step (conching), and a cooling step. It can be manufactured through some or all of the steps. After the refining process, a tempering process may be performed if necessary.
本開示のソフトチョコレートは、そのまま喫食されてもよい。しかし、本開示のソフトチョコレートは、その他の食品にトッピング、コーティング、あるいは包餡されてもよい。このようにして、本開示のソフトチョコレートを、複合食品の製造に適用することができる。本開示のソフトチョコレートと組み合わされる食品は、特に限定されない。しかし、好ましくは、ドライフルーツおよびナッツなどの乾燥食品、菓子およびパンなどのベーカリー食品である。ベーカリー食品の具体例としては、シュー菓子(エクレア、シュークリームなど)、パイ、およびワッフルなどの洋生菓子;ショートケーキ、ロールケーキ、デコレーションケーキ、トルテ、およびシフォンケーキなどのスポンジケーキ類;パウンドケーキ、フルーツケーキ、マドレーヌ、バウムクーヘン、およびカステラなどのバターケーキ類;ビスケット、クッキー、クラッカー、プレッツェル、ウェハース、サブレ、ラングドシャ、マカロン、およびラスクなどの焼菓子;食パン、菓子パン、フランスパン、シュトーレン、ブリオッシュ、ドーナツ、デニッシュ、およびクロワッサンなどのパン類、が挙げられる。 The soft chocolate of the present disclosure may be eaten as it is. However, the soft chocolate of the present disclosure may be topped, coated or included in other foods. In this way, the soft chocolate of the present disclosure can be applied to the production of complex food products. The food product combined with the soft chocolate of the present disclosure is not particularly limited. However, preferred are dry foods such as dried fruits and nuts, bakery foods such as confectionery and bread. Examples of bakery foods are Western confectionery such as puff pastry (eclairs, cream puffs), pies, and waffles; sponge cakes such as short cakes, roll cakes, decoration cakes, torte, and chiffon cakes; pound cakes, fruits. Butter cakes such as cakes, madeleines, Baumkuchen, and castella; baked goods such as biscuits, cookies, crackers, pretzels, wafers, sables, Langue de Chas, macaroons, and rusks; Examples include Danish and breads such as croissants.
本開示のソフトチョコレートは、また、ベーカリー食品の生地(ベーカリー生地)にトッピング、コーティング、あるいは包餡された状態で焼成されてもよい。このようにして、焼成複合食品に適用されてもよい。本開示のソフトチョコレートは、焼成複合食品生地に含まれて焼成されても、常温での可塑性または流動性を有する。本開示のソフトチョコレートは、好ましくは、ベーカリー生地に包餡されて、焼成される。本開示のソフトチョコレートが含まれる複合食品生地の焼成は、好ましくはソフトチョコレートの温度が70〜100℃程度に達するように、例えば、オーブン、マイクロ波、あるいは過加熱蒸気を用いて実施できる。例えば、本開示のソフトチョコレートが包餡されたベーカリー生地を、オーブンを使用して、例えば、160〜210℃、6〜15分間程度の条件で、好適に焼成できる。 The soft chocolate of the present disclosure may also be baked in a state of being topped, coated, or encased in a bakery food dough (bakery dough). In this way, it may be applied to baked complex food products. The soft chocolate of the present disclosure has plasticity or fluidity at room temperature even when it is contained in the baked complex food dough and baked. The soft chocolate of the present disclosure is preferably wrapped in a bakery dough and baked. The baking of the complex food dough containing the soft chocolate of the present disclosure can be carried out, for example, using an oven, a microwave, or overheated steam so that the temperature of the soft chocolate reaches about 70 to 100°C. For example, the bakery dough containing the soft chocolate of the present disclosure can be suitably baked using an oven under the conditions of, for example, 160 to 210° C. and 6 to 15 minutes.
次に、実施例および比較例を挙げ、本開示をさらに詳しく説明する。しかし、本開示はこれらに何ら制限されない。 Next, the present disclosure will be described in more detail with reference to Examples and Comparative Examples. However, the present disclosure is not limited thereto.
<使用油脂>
ソフトチョコレートの原料油脂として以下の油脂を使用した。
(油脂A−1)
2段分別パームオレイン(ヨウ素価:65.7、L3含有量:0.3質量%、L2X含有量:33.2質量%、LX2含有量:56.3質量%、X3含有量:7.8質量%)を油脂A−1として使用した。
(油脂A−2)
8.8質量部のハイオレイックヒマワリ油、48.4質量部のパームステアリン(ヨウ素価36)、18.8質量部の極度硬化大豆油、および24.0質量部のパーム油を混合した。得られた混合油(パルミチン酸含有量40.9質量%、ステアリン酸含有量20.0質量%、オレイン酸含有量30.6質量%、リノール酸含有量6.3質量%、リノレン酸含有量0.2質量%、およびトランス型脂肪酸含有量0質量%)を、ランダムエステル交換反応することにより、エステル交換油脂が得られた。エステル交換反応は、常法に従って行った。すなわち、十分に乾燥した原料油脂に対して、ナトリウムメトキシドを0.2質量%添加した。添加後、減圧下、120℃で0.5時間、攪拌しながら、反応を行った。得られたエステル交換油脂を、36〜38℃でドライ分別した。これにより、高融点部が除去され、低融点部が得られた。得られた低融点部を0〜2℃で溶剤分別(アセトン使用)した。これにより、高融点部が除去され、低融点部が得られた。得られた低融点部を脱臭処理して、油脂A−2(ヨウ素価:64.9、L3含有量:0.1質量%、L2X含有量:28.4質量%、LX2含有量:55.4質量%、X3含有量:10.9質量%)を得た。
(油脂A−3)
ハイオレイックヒマワリ油40質量部に、ステアリン酸エチルエステル60質量部を混合し、1,3位選択性リパーゼ製剤を添加してエステル交換反応を行った。ろ過処理によりリパーゼ製剤を除去し、得られた反応物を薄膜蒸留にかけ、反応物から脂肪酸エチルエステルを除去して蒸留残渣を得た。得られた蒸留残渣を乾式分別により高融点部を除去し、得られた低融点部からアセトン分別により2段目の高融点部を除去して低融点部を得た。得られた低融点部を常法によりアセトン除去および脱色、脱臭処理して、油脂A−3(ヨウ素価:64.0、L3含有量:0.3質量%、L2X含有量:11.3質量%、LX2含有量:68.0質量%、X3含有量:17.4質量%、SX2含有量:62.0質量%)を得た。
(油脂a−1)
パーム油(ヨウ素価:52.1、L3含有量:8.1質量%、L2X含有量:47.8質量%、LX2含有量:36.4質量%、X3含有量:4.8質量%)を油脂a−1として使用した。
(油脂a−2)
一段分別パームオレイン(ヨウ素価:56.4、L3含有量:1.4質量%、L2X含有量:49.1質量%、LX2含有量:41.5質量%、X3含有量:5.7質量%)を油脂a−2として使用した。
(油脂a−3)
一段分別パームオレインのランダムエステル交換油脂(ヨウ素価:56.3、L3含有量:10.7質量%、L2X含有量:36.5質量%、LX2含有量:37.8質量%、X3含有量:12.6質量%)を油脂a−3として使用した。
(油脂a−4)
菜種油(ヨウ素価:114、L3含有量:0.0質量%、L2X含有量:0.6質量%、LX2含有量:15.5質量%、X3含有量:82.0質量%)を油脂a−4として使用した。
(油脂B)
ハイエルシン酸菜種油の極度硬化油(横関油脂工業株式会社製)を油脂Bとして使用した。<Fat and oil used>
The following fats and oils were used as raw fats and oils of soft chocolate.
(Fat and oil A-1)
2-stage fractionated palm olein (iodine value: 65.7, L3 content: 0.3% by mass, L2X content: 33.2% by mass, LX2 content: 56.3% by mass, X3 content: 7.8) (% by mass) was used as fat A-1.
(Fat A-2)
8.8 parts by mass of high oleic sunflower oil, 48.4 parts by mass of palm stearin (iodine value 36), 18.8 parts by mass of extremely hardened soybean oil, and 24.0 parts by mass of palm oil were mixed. Obtained mixed oil (palmitic acid content 40.9 mass%, stearic acid content 20.0 mass%, oleic acid content 30.6 mass%, linoleic acid content 6.3 mass%, linolenic acid content 0.2 mass% and trans-fatty acid content of 0 mass%) were subjected to a random transesterification reaction to obtain a transesterified oil and fat. The transesterification reaction was performed according to a conventional method. That is, 0.2 mass% of sodium methoxide was added to the sufficiently dried raw material oil and fat. After the addition, the reaction was carried out under reduced pressure at 120° C. for 0.5 hours with stirring. The obtained transesterified oil and fat was dry fractionated at 36 to 38°C. As a result, the high melting point portion was removed and the low melting point portion was obtained. The obtained low melting point portion was subjected to solvent fractionation (using acetone) at 0 to 2°C. As a result, the high melting point portion was removed and the low melting point portion was obtained. The resulting low melting point portion was deodorized to give a fat A-2 (iodine value: 64.9, L3 content: 0.1% by mass, L2X content: 28.4% by mass, LX2 content: 55. 4% by mass, X3 content: 10.9% by mass) was obtained.
(Fat and oil A-3)
40 parts by mass of high oleic sunflower oil was mixed with 60 parts by mass of stearic acid ethyl ester, and a 1,3-position selective lipase preparation was added to carry out transesterification reaction. The lipase preparation was removed by filtration, and the obtained reaction product was subjected to thin film distillation to remove the fatty acid ethyl ester from the reaction product to obtain a distillation residue. The high melting point part was removed from the obtained distillation residue by dry fractionation, and the second melting point was removed from the obtained low melting point part by acetone fractionation to obtain a low melting point part. Acetone removal, decolorization, and deodorization treatment were performed on the obtained low-melting point portion by a conventional method to give a fat A-3 (iodine value: 64.0, L3 content: 0.3 mass %, L2X content: 11.3 mass %, LX2 content: 68.0% by mass, X3 content: 17.4% by mass, SX2 content: 62.0% by mass).
(Fat and oil a-1)
Palm oil (iodine value: 52.1, L3 content: 8.1% by mass, L2X content: 47.8% by mass, LX2 content: 36.4% by mass, X3 content: 4.8% by mass) Was used as fat and oil a-1.
(Fat and oil a-2)
Single-stage fractionation palm olein (iodine value: 56.4, L3 content: 1.4 mass%, L2X content: 49.1 mass%, LX2 content: 41.5 mass%, X3 content: 5.7 mass %) was used as fat and oil a-2.
(Fat and oil a-3)
Random transesterified oil and fat of 1-stage fractionated palm olein (iodine value: 56.3, L3 content: 10.7 mass%, L2X content: 36.5 mass%, LX2 content: 37.8 mass%, X3 content : 12.6 mass%) was used as the oil/fat a-3.
(Fat and oil a-4)
Rapeseed oil (iodine value: 114, L3 content: 0.0% by mass, L2X content: 0.6% by mass, LX2 content: 15.5% by mass, X3 content: 82.0% by mass) is a fat and oil a. It was used as -4.
(Fat B)
An extremely hardened oil of rapeseed oil of hyersinic acid (made by Yokozeki Yushi Kogyo Co., Ltd.) was used as fat B.
<ソフトチョコレートを包餡したクッキーの製造>
表1、2、および3の配合にしたがって、原材料を混合し、常法にしたがって、微粒化(リファイニング)、および精練(コンチング)の各工程を経ることにより、例1から例15の融液状のチョコレートを得た。例1から例15の融液状のチョコレートを冷凍庫で固化させた。次いで、30質量部の砂糖、70質量部のマーガリン、100質量部の薄力粉、および0.5質量部のベーキングパウダーを混合してクッキー生地を調製した。10gずつに分割したクッキー生地を、冷蔵庫で2時間以上保持した後、室温に戻した。10gのクッキー生地に、4gの冷凍庫で固化させたソフトチョコレートを包餡した。ソフトチョコレートを包餡したクッキー生地を天板に並べ、コンベクションオーブンで、180℃で7分間、焼成した。<Production of cookies containing soft chocolate>
The raw materials are mixed according to the formulations of Tables 1, 2, and 3, and the molten liquid of Examples 1 to 15 is obtained by the steps of atomizing (refining) and refining (conching) according to a conventional method. Got chocolate. The melted chocolates of Examples 1 to 15 were solidified in a freezer. Next, 30 parts by mass of sugar, 70 parts by mass of margarine, 100 parts by mass of soft flour, and 0.5 parts by mass of baking powder were mixed to prepare a cookie dough. The cookie dough divided into 10 g portions was held in the refrigerator for 2 hours or more, and then returned to room temperature. 10 g of cookie dough was embedded with 4 g of soft chocolate solidified in a freezer. The cookie dough containing soft chocolate was placed on a top plate and baked in a convection oven at 180° C. for 7 minutes.
<ソフトチョコレートに含まれる油脂のSFC測定>
ソフトチョコレートの原材料としての、ココアパウダーは、ココアバターを11質量%含有する。また、同じく原料としての全脂粉乳は、乳脂肪を25質量%含有する。この原材料配合から、ソフトチョコレートに含まれる油脂の組成を計算した。その計算結果にしたがって、調製された油脂の、SFCを測定した。例えば、93.6質量部の油脂A−1と、6.4質量部のココアバターと、が混合されて、例1のソフトチョコレートに含まれる油脂が調製される。<SFC measurement of fats and oils contained in soft chocolate>
Cocoa powder as a raw material for soft chocolate contains 11% by mass of cocoa butter. Similarly, the whole milk powder as a raw material contains 25% by mass of milk fat. The composition of the fats and oils contained in the soft chocolate was calculated from this raw material composition. According to the calculation result, SFC of the prepared oil and fat was measured. For example, 93.6 parts by mass of the oil/fat A-1 and 6.4 parts by mass of cocoa butter are mixed to prepare the oil/fat contained in the soft chocolate of Example 1.
<ソフトチョコレート包餡クッキーの評価>
3名の職人歴5年以上の菓子職人が、焼成後23℃に静置された例1から例15のクッキーに包餡されたソフトチョコレートを、以下の基準にしたがって、総合的に評価した。評価結果を、表1、2、および3に示した。<Evaluation of soft chocolate wrapping cookies>
Three confectioners with a history of 5 years or more as craftsmen comprehensively evaluated the soft chocolate contained in the cookies of Examples 1 to 15 that were left standing at 23° C. after baking according to the following criteria. The evaluation results are shown in Tables 1, 2 and 3.
<クッキーに包餡焼成されたソフトチョコレートの評価基準>
焼成後ソフトチョコレートの物性評価
(23℃でのソフトソフトチョコレート包餡クッキー割断面の観察評価)
◎◎:ゆるい流動性があり、かつ、光沢があり、非常に良好
◎ :ゆるい流動性があり、良好
○ :非常にソフトで可塑性があり、良好
△ :ソフトで可塑性がある
▲ :可塑性を有するが、やや硬い
× :可塑性を有するが、硬い、または、やわらか過ぎて流れ出る
クッキーに包餡焼成されたソフトチョコレートの風味評価
◎◎:異味異臭がなく、非常に良好
◎ :異味異臭がなく、良好
○ :異味異臭がほとんど感じられない
△ :異味異臭をやや感じる
▲ :異味異臭を感じる
× :異味異臭を強く感じる
クッキーに包餡焼成されたソフトチョコレートの口どけ評価
◎◎:滑らかで融け残りがなく、非常に良好
◎ :滑らかで融け残りがなく、良好
○ :融け残りがなく、良好
△ :わずかに融け残りを感じる
▲ :やや融け残りを感じる
× :融け残りを感じる<Evaluation criteria for soft chocolate baked in cookies>
Evaluation of physical properties of soft chocolate after baking (observation of soft soft chocolate encased cookie cracked section at 23°C)
◎ ◎: Loose fluidity and gloss, and very good ◎: Loose fluidity, good ○: Very soft and plastic, good △: Soft and plastic ▲: Plastic However, it is somewhat hard x: It has plasticity, but it is hard or too soft and flows out.
Flavor evaluation of soft chocolate baked in cookie
◎ ◎: Very good with no off-flavours ◎: Good with no off-flavours ◯: Almost no off-flavours are felt △: Some off-flavours are felt ▲: Off-flavours are strongly felt ×: Off-flavours are strongly felt
Evaluation of mouthfeel of soft chocolate baked in cookies
◎ ◎: Smooth and no unmelting, very good ◎: Smooth, no unmelting, good ○: No melting, good △: Slight unmelting ▲: Some unmelting ×: Unmelting Feel
Claims (7)
前記油脂が、条件(a)から(d)を満たすヨウ素価が62以上の油脂A、を含有し、
前記油脂の固体脂含有量(SFC)が、10℃で4〜34%、20℃で2〜24%、および30℃で0〜4%であり、
0.32〜0.84質量%のリン脂質を含む、
前記ソフトチョコレート
(ただし、条件(a)から(d)は、
(a)L3含有量が5質量%未満、
(b)L2X含有量が10〜40質量%、
(c)LX2含有量が45〜75質量%、
(d)X3含有量が2〜22質量%、
であり、L、X、L3、L2X、LX2およびX3は、
L:炭素数16〜18の直鎖飽和脂肪酸、
X:炭素数16〜18の直鎖不飽和脂肪酸、
L3:Lが3分子結合しているトリグリセリド、
L2X:Lが2分子、Xが1分子結合しているトリグリセリド、
LX2:Lが1分子、Xが2分子結合しているトリグリセリド、
X3:Xが3分子結合しているトリグリセリド、
を意味する)。 A soft chocolate having a continuous phase of fats and oils and containing sugars,
The oil or fat contains an oil or fat A having an iodine value of 62 or more, which satisfies the conditions (a) to (d),
The solid fat content (SFC) of the fat is 4 to 34% at 10°C, 2 to 24% at 20°C, and 0 to 4% at 30°C,
Containing 0.32-0.84% by weight of phospholipids,
The soft chocolate
(However, the conditions (a) to (d) are
(A) L3 content is less than 5% by mass,
(B) L2X content is 10 to 40% by mass,
(C) LX2 content is 45 to 75% by mass,
(D) X3 content of 2 to 22% by mass,
And L, X, L3, L2X, LX2 and X3 are
L: straight chain saturated fatty acid having 16 to 18 carbon atoms,
X: a linear unsaturated fatty acid having 16 to 18 carbon atoms,
L3: triglyceride in which three molecules of L are bound,
L2X: triglyceride in which two molecules of L and one molecule of X are bonded,
LX2: triglyceride in which one molecule of L and two molecules of X are bound,
X3: triglyceride in which 3 molecules of X are bound,
Means) .
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JP2018070528 | 2018-04-02 | ||
JP2018070528 | 2018-04-02 | ||
PCT/JP2019/013828 WO2019194081A1 (en) | 2018-04-02 | 2019-03-28 | Soft chocolate |
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JP7460277B2 (en) * | 2020-03-26 | 2024-04-02 | 日清オイリオグループ株式会社 | chocolate |
JP7577408B2 (en) | 2020-09-29 | 2024-11-05 | 日清オイリオグループ株式会社 | Oil and fat composition for chocolate and chocolate for freezing |
JP7577407B2 (en) | 2020-09-29 | 2024-11-05 | 日清オイリオグループ株式会社 | Oil and fat composition for chocolate and chocolate for freezing |
CN112913955A (en) * | 2021-03-11 | 2021-06-08 | 廊坊维朗妮卡食品有限公司 | Plastic chocolate product and preparation method thereof |
WO2024203270A1 (en) * | 2023-03-29 | 2024-10-03 | 不二製油グループ本社株式会社 | Oil/fat for chocolate products |
JP7544170B1 (en) | 2023-03-29 | 2024-09-03 | 不二製油株式会社 | Fats and oils for chocolate |
JP7544171B1 (en) | 2023-03-29 | 2024-09-03 | 不二製油株式会社 | Fats and oils for chocolate |
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JPS5860944A (en) | 1981-10-05 | 1983-04-11 | Lotte Co Ltd | Chocolate resistant to baking temperature and baked cake containing the same |
JP3369949B2 (en) | 1998-02-13 | 2003-01-20 | 明治製菓株式会社 | Chocolate with reduced curing by baking and composite confectionery using it |
KR102209298B1 (en) * | 2013-03-12 | 2021-01-28 | 후지세유 그룹 혼샤 가부시키가이샤 | Chocolate-like food product for baking, and method for manufacturing same |
JP6466089B2 (en) * | 2014-06-16 | 2019-02-06 | 日清オイリオグループ株式会社 | chocolate |
JP6317288B2 (en) * | 2014-07-07 | 2018-04-25 | 富士フイルム株式会社 | Beverage composition |
WO2016047453A1 (en) * | 2014-09-24 | 2016-03-31 | 日清オイリオグループ株式会社 | Heat-resistant chocolate and method for manufacturing same |
JP6572531B2 (en) * | 2014-10-28 | 2019-09-11 | 不二製油株式会社 | Chocolates for bakery products and methods for producing bakery products |
JP6830754B2 (en) * | 2015-10-06 | 2021-02-17 | 株式会社Adeka | Oil composition for baked chocolate |
JP6212676B1 (en) * | 2015-12-24 | 2017-10-11 | 日清オイリオグループ株式会社 | Baked chocolate and method for producing the same |
JP6225296B1 (en) * | 2016-01-29 | 2017-11-01 | 日清オイリオグループ株式会社 | Baked chocolate |
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JPWO2019194081A1 (en) | 2020-04-30 |
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