JP2021127372A - Cleaning agent composition - Google Patents

Abstract

To provide a cleaning agent composition that is highly antiseptic and superior in use feeling.SOLUTION: A cleaning agent composition of this invention includes: at least one of polyalcohols and saccharides (A); an anionic surface active agent (B); and an amphoteric surface active agent (C). Heat of fusion of the frozen cleaning agent composition is 130 mJ/mg or less, and the total of the contents of the (B) component and the (C) component in the cleaning agent composition is 10 mass% or more.SELECTED DRAWING: None

Description

The present disclosure relates to detergent compositions.

Preservatives such as paraben, benzoic acid, and salicylic acid are used in cosmetics such as detergent compositions. However, these preservatives may have an upper limit on the concentration used from the viewpoint of safety such as irritation.

As an alternative preservative, Patent Document 1 describes 1,2-alkanediol having 5 to 10 carbon atoms and the like.

Japanese Patent No. 3625214

However, according to the study of the present inventor, when the above-mentioned alkanediol or the like is applied mainly to a detergent composition as a preservative, foaming and the feel of the skin or hair at the time of washing are not good, and the product is used. It turned out that the feeling may not be good.

One aspect of the present disclosure provides a detergent composition having high antiseptic properties and excellent usability.

One aspect of the present disclosure is a detergent composition containing (A) at least one of polyhydric alcohols and saccharides, (B) an anionic surfactant, and (C) amphoteric surfactant. do. The heat of fusion of the frozen detergent composition is 130 mJ / mg or less, and the total content of the components (B) and (C) in the detergent composition is 10% by mass or more.

In one aspect of the present disclosure, the content of the component (A) in the detergent composition may be 20% by mass or more, and the content of the component (A) in the detergent composition is the detergent composition. It may be larger than the total content of the component (B) and the component (C) in the mixture.

In one aspect of the present disclosure, the component (A) may contain at least one of (A1) polyhydric alcohols and saccharides having an IOB value of 3.5 or higher, and (A) in the detergent composition. The ratio of the content of the component (A1) in the detergent composition to the content of the component may be 0.7 or more.

In one aspect of the present disclosure, the detergent composition may be used by being discharged in a liquid state and foamed.

According to one aspect of the present disclosure, a detergent composition having high antiseptic properties and excellent usability is provided.

The detergent composition of one aspect of the present disclosure contains at least one of (A) polyhydric alcohols and saccharides, (B) anionic surfactant, and (C) amphoteric surfactant. The heat of fusion of the frozen detergent composition is 130 mJ / mg or less, and the total content of the components (B) and (C) in the detergent composition is 10% by mass or more.

As described below, such a cleaning agent composition has high antiseptic properties and is excellent in usability.
The water contained in the detergent composition is roughly divided into bound water and free water according to the state. The bound water refers to water bound to other components in the detergent composition by hydrogen bonds or the like. On the other hand, free water refers to water that can move around freely without being bound by other components in the detergent composition. Of these, the water that can be used by microorganisms is free water, so if the content of free water is high, microorganisms are likely to grow.

The present inventor paid attention to the heat of fusion of the detergent composition as a parameter indicating the content of free water in the detergent composition. Free water freezes at 0 ° C or lower like simple water. On the other hand, since the bound water is retained by other components contained in the detergent composition, it is presumed that the bound water exists without freezing even at 0 ° C. or lower. Therefore, the heat of fusion of the detergent composition is considered to reflect the content of free water in the detergent composition. Therefore, it can be said that the lower the heat of fusion of the detergent composition, the smaller the content of free water in the detergent composition, and the higher the antiseptic property of the detergent composition.

Here, the component (A) interacts with water to reduce the content of free water in the detergent composition and improve the antiseptic property of the detergent composition. However, according to the study of the present inventor, it has been found that the detergent composition containing the component (A) may not have good foaming. In particular, in order to achieve the desired heat of fusion, it is preferable to contain the component (A) in a relatively large amount, and in that case, the foaming of the detergent composition tends to decrease.

On the other hand, by using the component (B) and the component (C) in combination and making the total content of the component (B) and the component (C) 10% by mass or more, a low heat of fusion can be achieved. It was found that good foaming can be obtained while achieving a heat of fusion of 130 mJ / mg or less.

Hereinafter, the detergent composition according to one aspect of the present disclosure will be described in detail.
[(A) component]
The component (A) reduces the content of free water in the detergent composition and improves the antiseptic property of the detergent composition. In addition, the component (A) also has a property of improving the feel of the skin or hair at the time of washing. For example, when the detergent composition is shampoo, the component (A) improves the flexibility of the hair when it is washed away. The improvement of the flexibility of the hair at the time of rinsing here means a state in which a moist feeling is given to the hair and the squeaky feeling, the tightness feeling, etc. of the hair are suppressed. In addition, since the component (A) is less irritating than preservatives such as paraben, benzoic acid, and salicylic acid, a mild detergent composition can be obtained as compared with the case of using these.

Specific examples of the polyhydric alcohols in the component (A) include a compound in which two or more hydrogen atoms of an aliphatic hydrocarbon are replaced with a hydroxy group, and two hydrogen atoms of an aliphatic hydrocarbon are replaced with a hydroxy group. Examples thereof include a dimer obtained by dehydration condensation of a compound glycol (for example, ethylene glycol, propylene glycol, etc.). Specific examples of the saccharide in the component (A) include monosaccharides, disaccharides, polysaccharides, liquid sugars, sugar alcohols and the like. In the present disclosure, the sugar alcohol refers to a sugar-derived compound produced by reducing the carbonyl group of aldose.

The detergent composition preferably contains at least one of the polyhydric alcohols and sugars having an IOB value of 3.5 or more among the components (A). Hereinafter, polyhydric alcohols or saccharides having an IOB value of 3.5 or more are referred to as a component (A1), and polyhydric alcohols or saccharides having an IOB value of less than 3.5 are referred to as a component (A2). According to the study by the present inventor, it has been found that the component (A1) is less likely to cause a decrease in foaming of the detergent composition than the component (A2).

Here, IOB is an abbreviation for Organic / Organic Balance (inorganic / organic ratio). The IOB value is a value of the ratio of the inorganic value of the compound to the organic value of the compound, and is an index showing the degree of polarity of the organic compound. Specifically, it is expressed as "IOB value = inorganic value / organic value". As for each of the inorganic value and the organic value of the compound, for example, the "organic value" is 20 for one carbon atom in the molecule, the "inorganic value" is 100 for one hydroxyl group, and so on. The "inorganic value" and "organic value" are set according to the functional group, and the "inorganic value" and "organic value" of all the atoms and functional groups in the organic compound are integrated. Calculated (see, for example, Yoshio Koda, "Organic Conceptual Diagram-Basics and Applications-", pp. 11-17, Sankyo Publishing, 1984). The IOB value of an organic compound is calculated using the integrated inorganic value and organic value.

Examples of the component (A1) include glycerin, diglycerin, sorbitol, maltitol, erythritol, xylitol, mannitol, glucose, maltose, sucrose, trehalose, honey and the like. Examples of the component (A2) include ethylene glycol, 1,3-butylene glycol, propylene glycol, isoprene glycol, diethylene glycol, dipropylene glycol and the like. Of these components, one type may be contained alone, or two or more types may be contained in combination.

The detergent composition may contain the component (A1) or the component (A2) alone, or may contain both the component (A1) and the component (A2). However, from the viewpoint of suppressing the decrease in foaming due to the component (A), the detergent composition preferably contains at least the component (A1).

When the detergent composition contains the component (A1), the ratio of the content of the component (A1) in the detergent composition to the total content of the component (A) in the detergent composition "(A1). / (A) ”is preferably 0.7 or more. When (A1) / (A) is 0.7 or more, the foaming of the detergent composition is less likely to decrease, and good foaming can be obtained. (A1) / (A) is more preferably 0.75 or more, still more preferably 0.8 or more.

The content of the component (A) in the detergent composition is preferably 15% by mass or more. When the content of the component (A) is 15% by mass or more, the heat of fusion is lowered, the antiseptic property of the detergent composition is further improved, and the effect of improving the feel of the skin or hair at the time of washing is also high. Specifically, the content of the component (A) is more preferably 20% by mass or more, further preferably 25% by mass or more, still more preferably 30% by mass or more. The content of the component (A) is not particularly limited in the upper limit, but is preferably 90% by mass or less, more preferably 70% by mass or less, and further preferably 50% by mass or less.

Further, the content of the component (A) is preferably larger than the total content of the components (B) and (C) in the detergent composition. This is because the component (A) tends to exert the effect of improving the feel of the skin or hair during washing. In particular, when the content of the component (A) is 20% by mass or more and the content of the component (A) is larger than the total content of the components (B) and (C), the cleaning agent The antiseptic property of the composition is further improved, and the effect of the component (A) on improving the feel of the skin or hair during washing is further improved.

[Component (B) and component (C)]
The component (B) and the component (C) are used in combination to improve the foaming of the detergent composition.
Examples of the component (B) include alkyl ether sulfates, alkyl sulfates, alkenyl ether sulfates, alkenyl sulfates, olefin sulfonates, alkane sulfonates, saturated or unsaturated fatty acid salts, alkyl or alkenyl ether carboxylic acids. Examples thereof include salts, α-sulfone fatty acid salts, N-acylamino acid type surfactants, phosphoric acid mono or diester type surfactants, sulfosuccinic acid esters, and derivatives thereof. Here, the N-acyl amino acid type surfactant is a salt of an amino acid having a saturated or unsaturated acyl group, and a salt of an analog of the same amino acid. Examples of the amino acid include glutamic acid, glycine, aspartic acid, alanine, phenylalanine, leucine, isoleucine, methionine, proline, tryptophan, valine, serine, N-methylglycine, N-methylalanine and the like. Examples of analogs of the amino acid include 2-aminoethanesulfonic acid and N-methyltaurine. The acidic amino acid and its analog may be any of D-form, L-form, and DL-form.

Examples of the counterion of the anion group of these surfactants include sodium ion, potassium ion, magnesium ion, monoethanolamine, triethanolamine and the like.

Specifically, examples of the alkyl ether sulfate include POE sodium lauryl ether sulfate. Examples of the alkyl sulfate include sodium lauryl sulfate, sodium cetyl sulfate and the like. Examples of the alkyl ether carboxylate include POE sodium lauryl ether acetate (for example, sodium laureth-4 carboxylate) and the like. Examples of the N-acylamino acid type surfactant include cocoyl glutamate triethanolamine, cocoyl methyl taurine sodium, lauroyl methyl alanine sodium, lauroyl aspartate sodium, lauroyl methyl taurine sodium, stearoyl glutamate sodium, myristoyl glutamate sodium, and palmitoyl proline sodium. And so on. Examples of the sulfosuccinate include lauryl disodium sulfosuccinate and the like.

Of these components (B), one type may be contained alone, or two or more types may be contained in combination. Of these components, the component (B) has a high effect of improving foaming, and can achieve both good foaming and a good feel of the skin or hair during washing. Therefore, alkyl ether carboxylate and N-acylate and N-acylate. At least one of the amino acid-type surfactants is preferable.

Examples of the component (C) include cocobetaine, lauramidopropyl betaine, cocamidopropyl betaine, sodium lauroamphoacetate, sodium cocoamphoacetate, coconut oil fatty acid amide propyl betaine, lauryldimethylaminoacetate betaine, sodium laurylaminopropionate and the like. Can be mentioned. Of these components (C), one may be contained alone, or two or more thereof may be contained in combination. Of these components, as the component (C), at least one of lauramidopropyl betaine and cocamidopropyl betaine is preferable because it has a high effect of improving foaming.

The total content of the component (B) and the component (C) in the detergent composition is 10% by mass or more. When the total content of the component (B) and the component (C) is 10% by mass or more, the foaming of the detergent composition is good. The total content of the component (B) and the component (C) is preferably 11% by mass or more, and more preferably 15% by mass or more. The total content of the component (B) and the component (C) is not particularly limited in the upper limit, but is preferably 50% by mass or less, more preferably 30% by mass or less, and further preferably 20% by mass. % Or less.

[Heat of fusion]
The heat of fusion of the detergent composition is 130 mJ / mg or less. When the heat of fusion of the detergent composition is 130 mJ / mg or less, the antiseptic property of the detergent composition is high.

In the present disclosure, the heat of fusion of the detergent composition is specifically used to supercool the detergent composition to −70 ° C. or lower and freeze it to dissolve the frozen detergent composition in a liquid state. The amount of heat consumed. A specific method for measuring the heat of fusion of the detergent composition will be described in detail in later examples.

The heat of fusion of the detergent composition is preferably 100 mJ / mg or less, more preferably 90 mJ / mg or less, and even more preferably 70 mJ / mg or less. The heat of fusion of the detergent composition is not particularly limited at the lower limit, but is preferably 5 mJ / mg or more, more preferably 10 mJ / mg or more, and further preferably 15 mJ / mg or more.

[Other ingredients]
The detergent composition may contain other components in addition to the above components, if necessary.
Examples of the other components include a solvent (excluding those contained in the component (A)), an oily component, a surfactant other than the components (B) and (C), a water-soluble polymer, and a pH adjuster. , Chelating agents, stabilizers, antioxidants, preservatives, amino acids, inorganic salts, animal and plant or microbial extracts, crude drug extracts, vitamins, fragrances, UV absorbers, dyes and the like. Of these other components, one type may be contained alone, or two or more types may be contained in combination.

The solvent can be added, for example, to bring the detergent composition into a desired property such as liquid. Examples of the solvent include water such as purified water and organic solvents. Examples of the organic solvent include ethanol, n-propanol, isopropanol, methyl cellosolve, ethyl cellosolve, methyl carbitol, ethyl carbitol, benzyl alcohol, benzyloxyethanol, silica skin alcohol, anis alcohol, p-methylbenzyl alcohol, α. Examples thereof include -dimethylphenethyl alcohol, α-phenylethanol, phenoxyisopropanol, 2-benzyloxyethanol, N-alkylpyrrolidone, alkylene carbonate and the like. Of these solvents, one type may be contained alone, or two or more types may be contained in combination.

Of these solvents, the detergent composition preferably contains water. The content of water in the detergent composition is preferably 20% by mass or more, more preferably 25% by mass or more, and further preferably 30% by mass or more. Even in a detergent composition containing a large amount of water as described above, high antiseptic properties can be obtained by containing the above component (A) and setting the heat of fusion of the detergent composition to 130 mJ / mg or less. Can be done. The upper limit of the water content is not particularly limited, but is preferably 90% by mass or less, more preferably 80% by mass or less, and further preferably 70% by mass or less. The water content referred to here refers to the total amount of water present in the composition regardless of aspects such as free water and bound water.

Examples of the oily component include fats and oils, waxes, hydrocarbons, higher fatty acids, higher alcohols, alkylglyceryl ethers, esters, silicones and the like.
Examples of fats and oils include Argania spinosa kernel oil, olive oil, camellia oil, shea butter, almond oil, saflower oil, sunflower oil, soybean oil, cottonseed oil, sesame oil, corn oil, rapeseed oil, rice bran oil, rice germ oil, etc. Grape seed oil, avocado oil, macadamia nut oil, castor oil, palm oil, evening primrose oil, apricot oil, persic oil, peach oil, palm oil, egg yolk oil and the like can be mentioned.

Examples of the wax include beeswax, candelilla wax, carnauba wax, jojoba oil, lanolin and the like.
Hydrocarbons include, for example, paraffin, olefin oligomer, polyisobutene, hydrogenated polyisobutene, mineral oil, squalane, polybutene, polyethylene, microcrystalline wax, vaseline, liquid paraffin, light isoparaffin, light liquid isoparaffin, isoparaffin, α-olefin oligomer, Examples include synthetic hydrocarbons.

Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, isostearic acid, 12-hydroxystearic acid, oleic acid, lanolin fatty acid and the like.

Higher alcohols include, for example, cetyl alcohol, 2-hexyldecanol, stearyl alcohol, isostearyl alcohol, cetostearyl alcohol, oleyl alcohol, araquil alcohol, behenyl alcohol, 2-octyldodecanol, lauryl alcohol, myristyl alcohol, decyltetradecanol. , Lanorin alcohol and the like.

Examples of the alkyl glyceryl ether include batyl alcohol, kimil alcohol, ceracyl alcohol, isostearyl glyceryl ether and the like.
Examples of the ester include diisopropyl adipate, isopropyl myristate, cetyl octanoate, isononyl isononanoate, octyldodecyl myristate, isopropyl palmitate, stearyl stearate, myristyl myristate, isotridecyl myristate, and 2-ethylhexyl palmitate. , Octyldodecyl ricinolate, cholesteryl / lanosteryl consisting of fatty acids having 10 to 30 carbon atoms, cetyl lactate, lanolin acetate, ethylene glycol di-2-ethylhexanoate, pentaerythritol fatty acid ester, dipentaerythritol fatty acid ester, capric acid Examples thereof include cetyl, glyceryl tricaprylate, diisostearyl malate, dioctyl succinate, diethoxyethyl succinate, cetyl 2-ethylhexanoate, and cured castor oil isostearate.

Examples of the silicone include dimethylpolysiloxane (dimethicone), methylphenylpolysiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, terminal hydroxyl group-modified dimethylpolysiloxane (dimethiconol), and a high degree of polymerization having an average degree of polymerization of 650 to 10000. Polymerized silicones, polyether-modified silicones (eg, (PEG / PPG / butylene / dimethicone) copolymers), betaine-modified silicones, alkyl-modified silicones, alkoxy-modified silicones, mercapto-modified silicones, carboxy-modified silicones, fluorine-modified silicones and the like can be mentioned.

Of these oily components, one type may be contained alone, or two or more types may be contained in combination.
Examples of the surfactant other than the component (B) and the component (C) include a nonionic surfactant and a cationic surfactant.

Examples of the nonionic surfactant include polyoxyalkylene alkyl ether, alkylene sorbitan fatty acid ester, alkylene alkyl glycol fatty acid ester, polyoxyalkylene fatty acid amide, aliphatic alkanolamide, alkyl glucoside and the like.

Examples of the polyoxyalkylene alkyl ether include POE (2) cetyl ether, POE (4) cetyl ether, POE (5) cetyl ether, POE (5.5) cetyl ether, POE (6) cetyl ether, and POE (7). ) Cetyl ether, POE (10) cetyl ether, POE (15) cetyl ether, POE (20) cetyl ether, POE (23) cetyl ether, POE (25) cetyl ether, POE (30) cetyl ether, POE (40) POE cetyl ether such as cetyl ether, POE (2) stearyl ether, POE (4) stearyl ether, POE (5) stearyl ether, POE (20) stearyl ether, POE stearyl ether such as POE (150) stearyl ether, POE ( 2) Behenyl ether, POE (3) Behenyl ether, POE (5) Behenyl ether, POE (6) Behenyl ether, POE (10) Behenyl ether, POE (20) Behenyl ether, POE (30) Behenyl ether, POE (150) ) POE behenyl ether such as behenyl ether, POE (2) oleyl ether, POE (3) oleyl ether, POE (7) oleyl ether, POE (10) oleyl ether, POE (15) oleyl ether, POE (20) oleyl ether , POE oleyl ether such as POE (50) oleyl ether, POE (2) lauryl ether, POE (3) lauryl ether, POE (4.2) lauryl ether, POE (9) lauryl ether, POE (10) lauryl ether, POE (21) lauryl ether, POE (25) lauryl ether and other POE lauryl ether, POE (2) myristyl ether, POE (3) myristyl ether and other POE myristyl ether, POE (2) octyldodecyl ether, POE (5) POE octyldodecyl ether such as octyldodecyl ether, POE (2) hexyldecyl ether, POE (4) POE hexyldecyl ether such as hexyldecyl ether, POE isostearyl ether such as POE (5) isostearyl ether, POE nonylphenyl ether , POE octylphenyl ether, POE (1) POP (4) cetyl ether, POE (10) POP (4) cetyl ether, POE (20) POP (4) cetyl ether, POE (20) POP (8) POE polyoxypropylene cetyl ether such as cetyl ether, POE polyoxypropylene decyltetradecyl ether such as POE (12) POP (6) decyltetradecyl ether, POE cetostearyl hydroxymillistyrene such as ceteares-60 millistyl glycol Examples include ether. In the compound name, POE is an abbreviation for polyoxyethylene, and POP is an abbreviation for polyoxypropylene. The number in parentheses after POE represents the number of moles of ethylene oxide added, and the number in parentheses after POP represents the number of moles of propylene oxide added.

Examples of the alkylene sorbitan fatty acid ester or the alkylene alkyl glycol fatty acid ester include monooleic acid POE sorbitan, monostearic acid POE sorbitan, monopalmitate POE sorbitan, monolauric acid POE sorbitan (for example, PEG-80 sorbitan laurate), and triolein. POE sorbitan acid, POE glycerin monostearate, POE glycerin monomyristate, POE sorbit tetraoleate, POE sorbit hexastearate, POE sorbit monolaurate, POE coconut oil fatty acid glycerin (eg, coconut oil fatty acid PEG-7 glyceryl), POE Solbit Mitsurou, Polyethylene Glycol Monooleate, Polyethylene Glycomonostearate, Polyethylene Glystearate, Polyethylene Glycolmonolaurate, Polyoleate Monooleate Glycerin, Prooleate Glycerin Monostearate, Self-Emulsifying Glycerin Monostearate, Sorbitane monooleate, sorbitan sesquioleate, sorbitan trioleate, sorbitan monostearate, sorbitan monopalmitate, sorbitan monolaurate, sucrose fatty acid ester, decaglyceryl monolaurate, decaglyceryl monooleate, decaglyceryl monooleate , Decaglyceryl monomyristate, POE-reduced lanolin and the like.

Examples of the polyoxyalkylene fatty acid amide or aliphatic alkanolamide include POE (2) lauric acid monoethanolamide, POE (3) lauric acid monoethanolamide, POE (5) lauric acid monoethanolamide, and POE (10) laurin. POE lauric acid monoethanolamide such as acid monoethanolamide, POE (15) lauric acid monoethanolamide, POE (2) coconut oil fatty acid monoethanolamide, POE (5) coconut oil fatty acid monoethanolamide, POE (10) coconut Examples thereof include POE coconut oil fatty acid monoethanolamide such as oil fatty acid monoethanolamide and POP myristic acid monoethanolamide such as POP (12) myristic acid monoethanolamide.

Examples of the alkyl glucoside include alkyl (C8 to 16) glucoside, polyoxyethylene methyl glucoside, and polyoxyethylene dioleate methyl glucoside.

Of these nonionic surfactants, one may be contained alone, or two or more thereof may be contained in combination.
Examples of the cationic surfactant include lauryltrimethylammonium chloride, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, alkyltrimethylammonium chloride, distearyldimethylammonium chloride, behenyltrimethylammonium chloride, distearyldimethylammonium chloride, and cetyltrimethyl bromide. Examples thereof include ammonium, stearyltrimethylammonium bromide, lanolin fatty acid aminopropylethyldimethylammonium, stearyltrimethylammonium saccharin, cetyltrimethylammonium saccharin, methacryloyloxyethyltrimethylammonium chloride, and behenyltrimethylammonium methylsulfate. Of these cationic surfactants, one may be contained alone, or two or more thereof may be contained in combination.

Examples of the water-soluble polymer include natural polymers, semi-synthetic polymers, synthetic polymers, and inorganic polymers.
Natural polymers include, for example, starch, guar gum, locust bean gum, quince seed, carrageenan, galactan, arabic gum, tragacanto gum, pectin, mannan, xanthan gum, dextran, succinoglucan, curdlan, hyaluronic acid, gelatin, casein, etc. Examples thereof include albumin, collagen, dextrin, and triglucopolysaccharide (pullulan).

Examples of the semi-synthetic polymer include crystalline cellulose, methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxyethyl cellulose dimethyldiallyl ammonium chloride, hydroxypropyl cellulose, carboxymethyl cellulose, sodium carboxymethyl cellulose, hydroxypropyl methyl cellulose, and cationized cellulose (for example, polyquaternium-4). , Polyquantanium-10), cationized guar gum, starch phosphate ester, propylene glycol alginate, alginate and the like.

Examples of the synthetic polymer include polyvinylcaprolactam, polyvinyl alcohol (PVA), polyvinylpyrrolidone (PVP), vinylpyrrolidone-vinyl acetate (VP / VA) copolymer, polyvinylbutyral, polyvinylmethyl ether, carboxyvinyl polymer, and polyacrylic acid. Soda, polyacrylamide, polyethylene oxide, polyurethane, ethylene oxide / propylene oxide block copolymer, acrylate / alkyl acrylate copolymer, polydimethylmethylene piperidinium chloride (eg, polyquaternium-6), itaconic acid and POE alkyl ether. Examples thereof include a copolymer composed of a semiester of methacrylic acid and an ester of POE alkyl ether, and at least one monomer selected from acrylic acid, methacrylic acid and alkyl esters thereof.

Examples of the inorganic polymer include bentonite, magnesium aluminum silicate, laponite, hectorite, and silicic anhydride.
Of these water-soluble polymers, only one type may be contained alone, or two or more types may be contained in combination.

Examples of the pH adjuster include inorganic acids, organic acids, salts thereof and the like. Examples of the inorganic acid include phosphoric acid, hydrochloric acid, nitric acid, sulfuric acid, boric acid and the like. Examples of phosphoric acid include orthophosphoric acid, polyphosphoric acid, pyrophosphoric acid, metaphosphoric acid and the like. Examples of the organic acid include citric acid, tartaric acid, lactic acid, malic acid, succinic acid, fumaric acid, maleic acid, pyrophosphate, gluconic acid, glucuronic acid and the like. Examples of the organic acid salt include sodium salt, potassium salt, ammonium salt and the like. Of these pH adjusters, one may be contained alone, or two or more thereof may be contained in combination.

Examples of the chelating agent include edetonic acid (ethylenediaminetetraacetic acid (EDTA)) and its salts, diethylenetriaminetetraacetic acid and its salts, hydroxyethanediphosphonic acid (etidronic acid, HEDP) and its salts. Examples of the hydroxyethanediphosphonic acid include tetrasodium hydroxyetanediphosphonate, disodium hydroxyethanediphosphonate, and sodium hydroxyethanediphosphonate. Of these chelating agents, one type may be contained alone, or two or more types may be contained in combination.

Examples of the stabilizer include phenacetin, 8-hydroxyquinoline, acetanilide, sodium pyrophosphate, barbituric acid, uric acid, tannic acid and the like. Of these stabilizers, one type may be contained alone, or two or more types may be contained in combination.

Examples of the antioxidant include ascorbic acid, sulfites and the like. Of these antioxidants, one may be contained alone, or two or more thereof may be contained in combination.
Examples of preservatives include salicylic acid, hinokithiol, potassium sorbate, benzoic acid, sodium benzoate, methyl paraoxybenzoate, propyl paraoxybenzoate, butyl paraoxybenzoate, phenoxyethanol, paraben, methylchloroisothiazolinone / methylisothiazo. Examples thereof include linone and 2-methyl-4-isothiazolin-3-one. Of these preservatives, one may be contained alone, or two or more thereof may be contained in combination. The amount of the preservative to be added to the detergent composition is preferably as small as possible from the viewpoint of safety such as irritation.

Examples of amino acids include threonine, theanine, taurine and the like. Of these amino acids, one type may be contained alone, or two or more types may be contained in combination.

Examples of the inorganic salt include sodium chloride, sodium carbonate and the like. Of these inorganic salts, one type may be contained alone, or two or more types may be contained in combination.

[Dosage form of detergent composition]
The dosage form of the detergent composition is not particularly limited. Examples of the dosage form of the detergent composition include liquids such as aqueous solutions and emulsions, gels, foams, and creams at 25 ° C. When the dosage form of the detergent composition is foamed, an aerosol container may be used or a non-aerosol container may be used. Examples of the non-aerosol container include a pump former container and a squeeze former container.

The detergent composition can be suitably used for a type of detergent composition that is discharged in a liquid state and used by foaming. The type of cleaning agent composition that is discharged in liquid form and used by whipping is different from, for example, the type of cleaning agent composition that is discharged and used in the form of foam from a former container, and is foamed without the help of a former container. There is a need. Therefore, a detergent composition of a type that is discharged in a liquid state and used by foaming is required to have particularly good foaming. The detergent composition in the present disclosure can realize good foaming even when it is discharged in a liquid state and used in foaming.

Further, in the type of cleaning agent composition used by being discharged from the former container in the form of foam, for example, when the cleaning agent composition is forcibly passed through the mesh in order to foam the cleaning agent composition in the former container. There is. Therefore, these types of cleaning agent compositions are required to have a relatively low viscosity in order to suppress the resistance when passing through the mesh, and as a result, the surfactant contained in the cleaning agent composition. There is a tendency to keep the amount of detergent small. On the other hand, since the detergent composition of the type that is discharged in liquid form and used by foaming does not have such a limitation, the content of the surfactant in the detergent composition can be relatively increased. Therefore, when the above-mentioned cleaning agent composition in the present disclosure is used as a type of cleaning agent composition which is discharged in a liquid state and used by foaming, the contents of the components (B) and (C) which are surfactants are contained. Can be relatively large. Needless to say, the above-mentioned cleaning agent composition in the present disclosure may be used as a type of cleaning agent composition which is discharged from a former container in the form of a foam.

[Use and usage of detergent composition]
The use of the cleansing composition is not particularly limited, and for example, it can be used as a cleansing composition for hair, a cleansing composition for the body, and the like. Specifically, the detergent composition can be used as, for example, shampoo, body shampoo, face wash, hand soap and the like. Of these, the detergent composition can be suitably used as a detergent composition for hair.

When the cleansing composition is a cleansing composition for hair, the cleansing composition may be applied to wet hair or dry hair. The cleansing composition is preferably applied to wet hair. The method of applying the detergent composition to the hair is not particularly limited, and a known method can be appropriately used. Examples of the coating method include coating with a hand comb, coating with a spray (spray), coating with a comb or a brush, and the like. The detergent composition is whipped according to a conventional method and then washed away with water, hot water or the like.

[Preparation of detergent composition]
The detergent compositions according to Examples 1 to 9 shown in Table 1 below and the detergent compositions according to Comparative Examples 1 to 6 shown in Table 2 below were prepared according to a conventional method. The numerical value indicating the content of each component in Tables 1 and 2 is mass%. DPG in Tables 1 and 2 is an abbreviation for dipropylene glycol.

[Evaluation of detergent composition]
The prepared detergent composition was measured and evaluated as follows.
(Measurement of heat of fusion)
The heat of fusion of the cleaning agent composition was measured using a differential scanning calorimeter (DSC) "DSC6220" (manufactured by SII Nanotechnology, Inc. (currently Hitachi High-Tech Science)). Specifically, the temperature is lowered at a rate of 5 ° C. per minute to cool to −70 ° C. to freeze the cleaning agent composition, and then the temperature is raised at a rate of 5 ° C. per minute to raise the cleaning agent. The composition was thawed. The heat of fusion was calculated based on the endothermic peak attributed to the heat of fusion observed in the obtained DSC curve, that is, the peak area of the endothermic peak having a peak at a temperature of 0 ° C. or lower. The results are shown in Tables 1 and 2.

(Antiseptic)
10 g of the detergent composition was aseptically dispensed into a sterilized vial. Pre Aspergillus adjusting the bacteria number (Aspergillus brasiliensis) was inoculated into a predetermined amount detergent composition was adjusted so that the number of bacteria is 10 ⁵ cfu / g, and the test solution.

0.1 mL of the obtained test solution was taken and smeared on GPLP agar medium with a spreader to confirm the number of surviving bacteria. The number of surviving bacteria was confirmed 28 days after inoculation of the bacteria. Those in which no bacteria were detected on the agar medium were evaluated as A, and those in which no bacteria were not detected were evaluated as B. The results are shown in Tables 1 and 2.

(Bubbling)
Twenty panelists were asked to wash their hair using the detergent composition. Of the 20 panelists, when the number of panelists who evaluated that the foaming was good when the detergent composition was whipped on the hair was 17 or more, it was evaluated as "very excellent: 5", and 13 to 16 people. Is "excellent: 4", 9 to 12 people are "good: 3", 5 to 8 people are "slightly bad: 2", and 4 or less people are "bad: 1". It was evaluated on a 5-point scale. The results are shown in Tables 1 and 2.

(Feeling when rinsing)
Twenty panelists were asked to wash their hair using the detergent composition. Of the 20 panelists, when the number of panelists who evaluated the flexibility of the hair when rinsing was 17 or more, it was rated as "very excellent: 5", and when it was 13 to 16, it was rated as "excellent: 4". , 9 to 12 people were evaluated as "good: 3", 5 to 8 people were evaluated as "slightly poor: 2", and 4 or less people were evaluated as "bad: 1" on a 5-point scale. The results are shown in Tables 1 and 2. The flexibility of the hair at the time of rinsing was judged based on whether or not the hair had a moist feeling and no squeaky or taut feeling.

[Discussion]
In Examples 1 to 9, the antiseptic property was high, and the usability was excellent from the viewpoint of foaming and the feel at the time of rinsing. In particular, comparing Examples 1 to 4, 6 and 7 in which the component (A) is the same, the content of the component (A) is 20% by mass or more, and the content of the component (A) is the component (B). In Examples 3, 4 and 6, which are larger than the total content of the component (C), the effect of improving the feel of the component (A) tends to be higher than in Examples 1, 2 and 7 which are not. Was there. Comparing Examples 3, 8 and 9 containing the same amount of the component (A), Example 3 in which the ratio of the content of the component (A1) to the content of the component (A) is 0.7 or more. , 9 tended to have better foaming than Example 8 which did not.

On the other hand, in Comparative Example 1 containing no component (A), the heat of fusion was not 130 mJ / mg or less, and the antiseptic property and the feel at the time of rinsing were not good. Even in Comparative Example 2 in which the heat of fusion was not 130 mJ / mg or less even though the component (A) was contained, the antiseptic property and the feel at the time of rinsing were not sufficient. Even if the component (A) was contained and the heat of fusion was 130 mJ / mg or less, foaming was not good in Comparative Example 3 in which the total content of the components (B) and (C) was not 10% by mass or more. .. In Comparative Example 4, in which the heat of fusion is not 130 mJ / mg or less and the total content of the components (B) and (C) is not 10% by mass or more, the antiseptic property, foaming, and feel at the time of rinsing are all good. It wasn't. Further, even if the heat of fusion is 130 mJ / mg or less and the total content of the component (B) and the component (C) is 10% by mass or more, Comparative Example 5 containing only the component (B) and ( C) In Comparative Example 6 containing only the component alone, foaming was not sufficient.

Claims (4)

Detergent composition
It contains (A) at least one of polyhydric alcohols and saccharides, (B) anionic surfactant, and (C) amphoteric surfactant.
The heat of fusion of the frozen detergent composition is 130 mJ / mg or less.
A cleaning agent composition in which the total content of the component (B) and the component (C) in the cleaning agent composition is 10% by mass or more. The content of the component (A) in the detergent composition is 20% by mass or more, and the content of the component (A) in the detergent composition is the content of the component (A) in the detergent composition. ) And the cleaning composition according to claim 1, which is larger than the total content of the component (C). The component (A) contains at least one of (A1) polyhydric alcohols and sugars having an IOB value of 3.5 or more.
The ratio of the content of the component (A1) in the detergent composition to the content of the component (A) in the detergent composition is 0.7 or more, according to claim 1 or 2. Detergent composition according to description. The cleaning agent composition according to any one of claims 1 to 3, which is discharged in a liquid state and used by foaming.