JP2006160589A - Admixture for plaster mortar and mortar composition containing the same - Google Patents

Admixture for plaster mortar and mortar composition containing the same Download PDF

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JP2006160589A
JP2006160589A JP2004358419A JP2004358419A JP2006160589A JP 2006160589 A JP2006160589 A JP 2006160589A JP 2004358419 A JP2004358419 A JP 2004358419A JP 2004358419 A JP2004358419 A JP 2004358419A JP 2006160589 A JP2006160589 A JP 2006160589A
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admixture
mortar
weight
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clay
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Yasuto Wakabayashi
康人 若林
Katsuhide Yomogida
勝英 蓬田
Masahiro Hayashi
昌宏 林
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Resonac Kenzai Corp
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Showa Denko Kenzai KK
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an admixture for plaster mortar, which is inexpensive, easy to obtain, and low-hazardous to a human body, and which shows a workability improvement effect equal or superior to that of asbestos or serpentine, and a mortar composition in which the admixture is blended. <P>SOLUTION: The admixture for plaster mortar comprises clay containing one sort or two or more sorts of clay minerals selected from the group consisting of kaolinite, halloysite, pyrophyllite, talc, chlorite, montmorillonite, muscobite, and vermiculite, and having a mean particle diameter of 0.3-30 μm, and a water-soluble polymer thickening agent of 0.3-10 pts.wt. to the clay of 100 pts.wt. Furthermore, the admixture for plaster mortar contains one sort or two or more sorts of inorganic materials selected from the group consisting of silica sand, a limestone fine powder, fly ash, a blast furnace slag powder, a sirasu balloon, and pearlite, in a ratio of 300 pts.wt. or less to the admixture for plaster mortar of 100 pts.wt. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、モルタルに混和し、コテ塗り作業性特にコテ伸び、コテ離れ、ダレにくさ、仕上げ美観を改善するために用いる左官モルタル用混和材、それを配合したモルタル組成物、及びこれを用いた施工方法に関する。   The present invention relates to a plastering mortar admixture used to improve the workability of troweling, especially trowel elongation, detachment, sag, and finishing aesthetics, and a mortar composition containing the same. It relates to the construction method.

左官モルタル用混和材は、コテ伸び、コテ滑り、コテ離れ等のコテ塗り作業性を改善すること、ダレを防止すること、仕上がり面をよりきれいにすること等を目的として用いられる。
従来は、左官モルタル用混和材として石綿が多用されており、これはコテ塗り作業性、ダレ防止、仕上がり等の面で非常に優れていた。しかし、人体に対する有害性の観点から、その利用が規制されるようになってきた。その後、蛇紋岩が、石綿の代替材料として広く使用されるようになり、このものもモルタルの作業性改善効果は優れていた。しかし、近年、蛇紋岩の多くにクリソタイルが含有しているという見方が公的に示され、これらも規制されることとなった。これに対し、有害性の低い石綿代替材料として、「水溶性ポリウレタン樹脂などの有機系混和剤」(特許文献1参照)、「石灰石粉末からなるセメント混和材」(特許文献2参照)、「石綿又は石綿含有蛇紋岩を焼成した混和材」(特許文献3参照)、などが提案されている。しかし、これらの石綿代替材料は、モルタルの作業性改善効果が十分ではなく、石綿や蛇紋岩の性能レベルに到達していないのが現状である。
The admixture for plastering mortar is used for the purpose of improving troweling workability such as trowel elongation, trowel slip, trowel separation, etc., preventing sagging, and making the finished surface cleaner.
Conventionally, asbestos has been widely used as an admixture for plastering mortar, and this was extremely excellent in terms of troweling workability, prevention of sagging, and finishing. However, its use has been regulated from the viewpoint of harm to the human body. After that, serpentine became widely used as an alternative material for asbestos, and this also had an excellent effect on improving the workability of mortar. However, in recent years, the view that chrysotile is contained in many serpentine has been publicly announced, and these have also been regulated. On the other hand, as an asbestos substitute material with low toxicity, “organic admixture such as water-soluble polyurethane resin” (see Patent Document 1), “cement admixture made of limestone powder” (see Patent Document 2), “asbestos” Or the admixture which baked the asbestos containing serpentine "(refer patent document 3), etc. are proposed. However, these asbestos substitute materials are not sufficiently effective in improving the workability of mortar and have not reached the performance level of asbestos and serpentine.

特開平08−245250号公報Japanese Patent Laid-Open No. 08-245250 特開2001−253736号公報JP 2001-253736 A 特開2004−075526号公報Japanese Patent Laid-Open No. 2004-075526

本発明は、安価であり、入手しやすく、且つ人体に対する有害性が低く、モルタルの作業性改善効果が石綿や蛇紋岩と同等あるいはそれ以上のレベルである左官モルタル用混和材の開発及びそれを配合したモルタル組成物を提供することを目的としている。   The present invention is a development of an admixture for plastering mortar that is inexpensive, easy to obtain, has low harmfulness to the human body, and has a workability improvement effect of mortar equivalent to or higher than that of asbestos and serpentine. The object is to provide a blended mortar composition.

本発明者は、上記課題を解決するために鋭意研究した結果、特定の粘土鉱物を含有し特定の粒子径を有したクレーと、水溶性高分子増粘剤を組み合わせることにより得た左官モルタル用混和材を使用することにより、モルタルの作業性が大きく改善できることを見出し、本発明に至った。   As a result of diligent research to solve the above problems, the present inventor has found that clay containing a specific clay mineral and having a specific particle diameter and a plaster mortar obtained by combining a water-soluble polymer thickener. It has been found that the workability of mortar can be greatly improved by using an admixture, and the present invention has been achieved.

すなわち、本発明は、
[1] カオリナイト、ハロイサイト、パイロフィライト、タルク、クロライト、モンモリロナイト、ムスコバイト、バーミキュライトからなる群から選ばれた1種または2種以上の粘土鉱物を含有するクレーで、平均粒子径が0.3〜30μmであるクレーと、水溶性高分子増粘剤をクレー100重量部に対し0.3〜10重量部配合したことを特徴とする左官モルタル用混和材、
[2] 水溶性高分子増粘剤が、メチルセルロース、ヒドロキシプロピルメチルセルロース、ヒドロキシエチルセルロース、ヒドロキシエチルエチルセルロース、キサンタンガム、グアーガム、カラギーナン、アルギン酸ソーダ、カゼイン、ポリオチレンオキサイド、ポリビニルアルコール、水溶性ポリウレタンから選ばれた1種または2種以上である上記[1]に記載の左官モルタル用混和材、
That is, the present invention
[1] Clay containing one or more clay minerals selected from the group consisting of kaolinite, halloysite, pyrophyllite, talc, chlorite, montmorillonite, muskovite, vermiculite and having an average particle size of 0 A plaster mortar admixture comprising 0.3 to 30 parts by weight of clay having a thickness of 3 to 30 μm and 100 parts by weight of a clay.
[2] The water-soluble polymer thickener was selected from methylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, hydroxyethylethylcellulose, xanthan gum, guar gum, carrageenan, sodium alginate, casein, polyoxylene oxide, polyvinyl alcohol, and water-soluble polyurethane. The admixture for plastering mortar according to the above [1], which is one type or two or more types,

[3] 上記[1]に記載の左官モルタル用混和材に対し、さらに珪砂、石灰石微粉末、フライアッシュ、高炉スラグ粉末、シラスバルーン、パーライトからなる群から選ばれた1種または2種以上の無機物質を左官モルタル用混和材100重量部に対し300重量部を超えない範囲で配合してなる上記[1]または[2]に記載の左官モルタル用混和材、
[4] 上記[1]〜[3]のいずれかに記載の左官モルタル用混和材を、モルタル組成物(水配合前の重量)100重量部に対し0.5〜10重量部を含む左官用モルタル組成物、
[5] 上記[4]に記載の左官用モルタル組成物を用いることを特徴とする左官施工方法、及び
[6] 上記[4]に記載の左官用モルタル組成物を用いた建築物又は建造物、を開発することにより上記の課題を解決した。
[3] One or more selected from the group consisting of silica sand, fine limestone powder, fly ash, blast furnace slag powder, shirasu balloon, and pearlite with respect to the admixture for plastering mortar described in [1] above. The admixture for plastering mortar according to the above [1] or [2], wherein an inorganic substance is blended in an amount not exceeding 300 parts by weight with respect to 100 parts by weight of the admixture for plastering mortar,
[4] The plastering mortar admixture according to any one of [1] to [3] above, containing 0.5 to 10 parts by weight with respect to 100 parts by weight of the mortar composition (weight before mixing with water). Mortar composition,
[5] A plastering method characterized by using the mortar composition for plastering according to [4] above, and [6] a building or building using the mortar composition for plastering according to [4] above By solving this problem, the above problems were solved.

実施例の左官モルタル用混和材は、プレーンモルタルに対しコテ塗り作業性が良くなり「コテ伸び」「コテ滑り」「コテ離れ」「ダレにくさ」「仕上げ美観」が大きく改善された。また、市販品B(蛇紋岩系混和材)、市販品C(フォーステライト質系混和材)に対してもコテ塗り作業性が優位であり、市販品A(石綿系混和材)と比較しても「ダレにくさ」の面で優位であった。
次に、モルタルのレオロジー特性に関して、実施例の左官モルタル用混和材は、プレーンモルタルおよび比較例の混和材に対して、塑性粘度が低く、降伏値が高くなる傾向にあった。塑性粘度が低いということは、コテ塗りの際に低い力で流動しやすいことを意味し、「コテ伸び」「コテ滑り」の良さに繋がっている。また、降伏値が高いということは、「ダレにくい」ということを示している。このように、レオロジー特性の面からも、作業性の良さが裏付けられるものと考えられる。
The admixture for plastering mortar of the example improved the ironing workability for plain mortar, and greatly improved the “iron elongation”, “iron slipping”, “iron separation”, “sagging” and “finishing aesthetics”. Also, the ironing workability is superior to the commercial product B (serpentine-based admixture) and the commercial product C (forsterite-based admixture), compared with the commercial product A (asbestos-based admixture). Was also dominant in terms of “sagging”.
Next, regarding the rheological properties of the mortar, the plastering mortar admixture of the example had a lower plastic viscosity and a higher yield value than the plain mortar and the admixture of the comparative example. The low plastic viscosity means that it is easy to flow with a low force during the application of the iron, which leads to good “elongation” and “iron sliding”. In addition, a high yield value indicates that “sag is difficult”. Thus, it is considered that good workability is supported also from the viewpoint of rheological characteristics.

さらに、実施例の左官モルタル用混和材は、プレーンモルタルと比較して付着強度が向上し、市販品に対しても遜色ない付着強度であった。
以上の試験結果から、本発明の左官モルタル用混和材は、石綿等の有害な成分を含有せず、かつモルタルのコテ塗り時において作業性、ダレ防止、仕上がり等の面で、従来の左官モルタル用混和材と比較して優位な性能を発揮できるものである。
Furthermore, the admixture for plastering mortars of the examples had improved adhesion strength compared to plain mortar, and had an adhesion strength comparable to that of commercially available products.
From the above test results, the admixture for plastering mortar of the present invention does not contain harmful components such as asbestos, and in terms of workability, sag prevention, finish, etc. when applying mortar iron, Compared with admixtures for use, it can exhibit superior performance.

以下、本発明の実施の形態について説明する。
本発明の左官モルタル用混和材に使用するクレーは、カオリナイト、ハロイサイト、パイロフィライト、タルク、クロライト、モンモリロナイト、ムスコバイト、バーミキュライトからなる群から選ばれた1種または2種以上の粘土系鉱物を含有する。これらクレーは、上記の粘土鉱物の含有量の高いものや他の鉱物が大量に共存して純度的に低いものもあるが、前記の粘度鉱物が少なくとも20%以上含有することが必要である。
本発明で使用できる上記クレーは、平均粒子径が0.3〜30μm内にあるものであり、好ましくは0.8〜15μmである。クレーの平均粒子径が30μmを超えると、左官モルタル用混和材として使用した際、コテ塗り時の作業性向上効果が極めて低くなる。また、クレーの平均粒子径が0.3μm未満であると、左官モルタル用混和材として使用した際、一定の流動性を得るために必要な混練水の量が多くなるため、モルタル硬化体の強度特性が低くなるという問題が生ずる。
Embodiments of the present invention will be described below.
The clay used for the plastering mortar admixture of the present invention is one or more clays selected from the group consisting of kaolinite, halloysite, pyrophyllite, talc, chlorite, montmorillonite, muskite, vermiculite. Contains minerals. Some of these clays have a high content of the above-mentioned clay minerals, and other clay minerals coexist in large quantities and have a low purity. However, the clay mineral needs to contain at least 20% or more.
The clay that can be used in the present invention has an average particle diameter of 0.3 to 30 μm, preferably 0.8 to 15 μm. When the average particle size of the clay exceeds 30 μm, the workability improvement effect during the application of the iron becomes extremely low when used as an admixture for plastering mortar. Moreover, when the average particle size of the clay is less than 0.3 μm, the amount of kneading water required to obtain a certain fluidity increases when used as an admixture for plastering mortar. There arises a problem that the characteristics are lowered.

本発明に用いる水溶性高分子増粘剤としては、メチルセルロース、ヒドロキシプロピルメチルセルロース、ヒドロキシエチルセルロース、ヒドロキシエチルエチルセルロース、カルボキシメチルセルロースナトリウム等のセルロースエーテル、アラビアガム、カラギーナン、キサンタンガム、グアーガム、ウェランガム、トラガントガム、ローカストビーンガム、カードラン、サクシノグルカン、アルギン酸塩、ゼラチン、コラーゲン、カゼイン等の天然系高分子、ポリエチレングリコール、ポリビニルアルコール、ポリビニルピロリドン、ポリアクリル酸ナトリウム、ポリアクリルアミド、高重合ポリエチレングリコール、水溶性ポリウレタン、ポリエチレンイミン等の合成高分子が挙げられる。
これらは単独で含有してもよいし、二種以上を組み合わせて含有してもよい。これらの中でも、メチルセルロース、ヒドロキシプロピルメチルセルロース、ヒドロキシエチルセルロース、ヒドロキシエチルエチルセルロース、カラギーナン、キサンタンガム、グアーガム、ローカストビーンガム、アルギン酸ソーダ、カゼイン、ポリオチレンオキサイド、ポリビニルアルコール、水溶性ポリウレタンが好ましい。
Examples of the water-soluble polymer thickener used in the present invention include methyl ether, cellulose ether such as hydroxypropylmethylcellulose, hydroxyethylcellulose, hydroxyethylethylcellulose, sodium carboxymethylcellulose, gum arabic, carrageenan, xanthan gum, guar gum, welan gum, tragacanth gum, locust bean. Natural polymers such as gum, curdlan, succinoglucan, alginate, gelatin, collagen, casein, polyethylene glycol, polyvinyl alcohol, polyvinyl pyrrolidone, sodium polyacrylate, polyacrylamide, highly polymerized polyethylene glycol, water-soluble polyurethane, Examples include synthetic polymers such as polyethyleneimine.
These may be contained alone or in combination of two or more. Among these, methyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl cellulose, hydroxyethyl ethyl cellulose, carrageenan, xanthan gum, guar gum, locust bean gum, sodium alginate, casein, polyoxynoxide, polyvinyl alcohol, and water-soluble polyurethane are preferable.

本発明に用いる水溶性高分子増粘剤の配合量は、特に限定されるものではないが、クレー100重量部に対し0.3〜10重量部が好ましく、0.5〜5重量部がさらに好ましい。配合量が0.3重量部未満ではコテ伸び、コテ滑りが悪くなる傾向にあり、10重量部を超えるとスラリーの粘性が高くなりコテ離れ性が悪くなる傾向にある。   The blending amount of the water-soluble polymer thickener used in the present invention is not particularly limited, but is preferably 0.3 to 10 parts by weight, more preferably 0.5 to 5 parts by weight with respect to 100 parts by weight of clay. preferable. If the blending amount is less than 0.3 parts by weight, the iron elongation and the iron slip tend to be poor, and if it exceeds 10 parts by weight, the viscosity of the slurry tends to be high and the iron releasability tends to be poor.

本発明の左官モルタル用混和材は、クレー、水溶性増粘剤以外に、珪砂、石灰石微粉末、フライアッシュ、高炉スラグ粉末、シラスバルーン、パーライトからなる群から選ばれた1種または2種以上の無機物質を左官モルタル用混和材100重量部に対し300重量部、好ましくは100重量部を超えない範囲で配合したものであっても良い。300重量部を超えた場合、左官モルタル用混和材として使用した際、コテ塗り時の作業性向上効果が極めて低くなる。
これらを配合することにより、モルタルの流動性、保水性の調整等に優れた効果があるので、左官モルタル用混和材として無機物質を添加することが好ましい。
The admixture for plastering mortar of the present invention is one or more selected from the group consisting of silica sand, limestone fine powder, fly ash, blast furnace slag powder, shirasu balloon, and pearlite, in addition to clay and water-soluble thickener. These inorganic substances may be blended in an amount not exceeding 300 parts by weight, preferably not exceeding 100 parts by weight per 100 parts by weight of the admixture for plastering mortar. When the amount exceeds 300 parts by weight, when used as an admixture for plastering mortar, the workability improvement effect at the time of ironing becomes extremely low.
By blending these, there is an excellent effect in adjusting the fluidity and water retention of the mortar. Therefore, it is preferable to add an inorganic substance as an admixture for plastering mortar.

このモルタル用混和材は、使用に際して川砂、山砂、海砂、砕砂、珪砂、軽量骨材等の細骨材、普通ポルトランドセメント、早強ポルトランドセメント、アルミナセメント等の水硬性セメント、セピオライト、ワラストナイト、ガラス繊維、ロックウール等の無機繊維質、パルプ、ビニロン繊維、ポリプロピレン繊維、ナイロン繊維等の有機繊維質、高性能減水剤、高性能AE減水剤、アクリルエマルジョン、エチレン酢酸ビニルエマルジョン、SBRラテックス等のポリマー混和剤、凝結遅延剤、硬化促進剤、膨張材、収縮低減剤、白華防止剤等のセメント混和剤等を併用することが可能である。   When used, this mortar admixture is used for fine sand aggregates such as river sand, mountain sand, sea sand, crushed sand, silica sand, lightweight aggregates, hydraulic cement such as ordinary Portland cement, early strength Portland cement, alumina cement, sepiolite, wax. Inorganic fiber such as lastnite, glass fiber, rock wool, organic fiber such as pulp, vinylon fiber, polypropylene fiber, nylon fiber, high-performance water reducing agent, high-performance AE water reducing agent, acrylic emulsion, ethylene vinyl acetate emulsion, SBR It is possible to use a polymer admixture such as latex, a setting retarder, a curing accelerator, an expansion material, a shrinkage reducing agent, a cement admixture such as a whitening inhibitor, and the like.

本発明の左官モルタル用混和材は、モルタル施工現場で調合するモルタル、いわゆる現場調合モルタルに混和することができる。また、予め工場で調合したモルタル、いわゆる既調合モルタルに混和することもできる。これらモルタルに対する混和方法は、特に限定されるものではなく、粉体混合する方法もあるし、加水した後にスラリーに添加混合する方法もあるが、いずれにせよモルタルに対して混和材が均一混合することが肝要である。   The admixture for plastering mortar of the present invention can be mixed with mortar prepared at a mortar construction site, so-called on-site preparation mortar. Moreover, it can also mix | blend with the mortar previously prepared at the factory, what is called a pre-prepared mortar. The mixing method for these mortars is not particularly limited, and there is a method of mixing powder, and there is also a method of adding to the slurry after adding water, but in any case, the admixture is uniformly mixed with the mortar. It is important.

本発明の左官モルタル用混和材のモルタルに対する配合量は、特に限定されるものではなく、対象モルタルの種類、下地状態、環境条件、塗り厚などにより種々変えることができるが、モルタル粉体100重量部に対して、0.5〜10重量部が好ましく、1〜5重量部がさらに好ましい。配合量が0.5重量部未満ではコテ塗り時の作業性向上効果が低く、10重量部を超えるとスラリーの粘性が高くなりコテ離れ性が悪くなる傾向にある。   The blending amount of the admixture for plastering mortar of the present invention with respect to the mortar is not particularly limited, and can be variously changed depending on the type of the target mortar, the ground condition, the environmental condition, the coating thickness, etc. 0.5 to 10 parts by weight is preferable with respect to parts, and 1 to 5 parts by weight is more preferable. If the blending amount is less than 0.5 parts by weight, the workability improvement effect at the time of ironing is low, and if it exceeds 10 parts by weight, the viscosity of the slurry tends to increase and the iron releasability tends to deteriorate.

以下、本発明を実施例により詳細に説明するが、本発明はこれらの実施例に限定されるものではない。   EXAMPLES Hereinafter, although an Example demonstrates this invention in detail, this invention is not limited to these Examples.

[実施例1〜11]
(表1、表2)の配合表のとおり材料を調合し、Vブレンダーで各材料が均一になるよう混合し、実施例1〜11の左官モルタル用混和材を調製した。
[Examples 1 to 11]
Materials were prepared as shown in the recipes in Tables 1 and 2, and each material was mixed with a V blender so as to be uniform to prepare admixtures for plastering mortars of Examples 1-11.

Figure 2006160589
Figure 2006160589

Figure 2006160589
Figure 2006160589

1)主成分:カオリナイト、平均粒径:4.9μm
2)主成分:ハロサイト、平均粒径:3.5μm
3)主成分:パイロフィライト、平均粒径:11.5μm
4)平均粒径:1.9μm
5)平均粒径:11.0μm
6)平均粒径:2.4μm
7)平均粒径:4.5μm
8)平均粒径:13.5μm
9)信越化学工業社「メトローズ 90SH−4000」
10)三晶社「KELZAN」
11)三晶社「メイプログアー」
12)三晶社「ゲニュービスコ」
13)住友精化社「PEO−8Z」
14)ブレーン比表面積:5700cm/g
15)ブレーン比表面積:4300cm/g
16)ブレーン比表面積:4200cm/g
1) Main component: Kaolinite, average particle size: 4.9 μm
2) Main component: halosite, average particle size: 3.5 μm
3) Main component: pyrophyllite, average particle size: 11.5 μm
4) Average particle size: 1.9 μm
5) Average particle size: 11.0 μm
6) Average particle size: 2.4 μm
7) Average particle size: 4.5 μm
8) Average particle size: 13.5μm
9) Shin-Etsu Chemical Co., Ltd. “Metros 90SH-4000”
10) Sankisha "KELZAN"
11) Sankisha “Maplogor”
12) Sankeisha “Geneus Bisco”
13) Sumitomo Seika Co., Ltd. “PEO-8Z”
14) Blaine specific surface area: 5700 cm 2 / g
15) Blaine specific surface area: 4300 cm 2 / g
16) Blaine specific surface area: 4200 cm 2 / g

[比較例1〜3]
モルタル用混和材の比較例1として市販品A(石綿系混和材)、比較例2として市販品B(蛇紋岩系混和材)、比較例3として市販品C(フォーステライト質系混和材:石綿を焼成したもの)を用意した。
[Comparative Examples 1-3]
Commercial product A (asbestos-based admixture) as comparative example 1 of mortar admixture, commercial product B (serpentine-based admixture) as comparative example 2, commercial product C (forsterite-based admixture: asbestos) as comparative example 3 Was fired).

パン型モルタルミキサーを用いて、(表3)の配合比率に従って、普通ポルトランドセメント、珪砂、実施例及び比較例の左官モルタル用混和材を空練りした後に水を加え(モルタルが適正な軟度となるように、水量を微調整した。)、約3分間練り混ぜてモルタルを調製した。なお、プレーンモルタルについては、(表2)の配合から左官モルタル用混和材を除いた配合で調製した。   Using a pan-type mortar mixer, according to the mixing ratio of (Table 3), ordinary Portland cement, silica sand, and the plastering mortar admixtures of Examples and Comparative Examples were kneaded and water was added (the mortar had an appropriate softness). The amount of water was finely adjusted so that the mortar was mixed) for about 3 minutes to prepare a mortar. In addition, about the plain mortar, it prepared with the mixing | blending which remove | excluded the admixture for plastering mortar from the mixing | blending of (Table 2).

Figure 2006160589
Figure 2006160589

調製したモルタルについて、JIS R 5201に準拠した方法によりフロー値を測定し、JIS R 6916に準拠した方法により付着強度を測定した。また、コテ塗り作業性を評価するために、コンクリート板(スパンクリートコーポレーション社製、スパンクリート)を垂直に立て、5mm厚でコテ塗りし、「コテ伸び」「コテ滑り」「コテ離れ」「ダレにくさ」「仕上げ美観」について官能評価を行った。さらに、モルタルのレオロジー特性を把握するために外筒回転式粘度計により、塑性粘度と降伏値を求めた。以上の結果を(表4,表5)に示す。   About the prepared mortar, the flow value was measured by the method based on JISR5201, and the adhesive strength was measured by the method based on JISR6916. In addition, in order to evaluate the ironing workability, a concrete board (Spancrete Corporation, Spancrete) is vertically set and coated with a 5mm thick iron. "Sensory evaluation was performed on" finished beauty ". Furthermore, in order to grasp the rheological characteristics of the mortar, the plastic viscosity and the yield value were obtained with an outer cylinder rotary viscometer. The above results are shown in (Tables 4 and 5).

Figure 2006160589
Figure 2006160589

Figure 2006160589
Figure 2006160589

評価基準…◎非常に良好,○良好,△:普通,×:不良
1)外筒回転式粘度計(共和科学社製、DPV−1)にて測定。
ローター:B、最高回転数:30rpm、測定時間:3分。
Evaluation criteria ... ◎ Very good, ○ Good, △: Normal, ×: Poor
1) Measured with an outer cylinder rotary viscometer (manufactured by Kyowa Kagaku Co., DPV-1).
Rotor: B, maximum rotation speed: 30 rpm, measurement time: 3 minutes.

本発明は、安価であり、入手しやすく、且つ石綿を含んでおらず人体に対する有害性が低く、モルタルのコテ塗り作業性、特にコテ伸び、コテ離れ、ダレにくさ、仕上げ美観を改善等、作業性改善効果が石綿や蛇紋岩と同等あるいはそれ以上のレベルである左官モルタル用混和材を開発すると共にそれを配合したモルタル組成物を提供することに成功した。   The present invention is inexpensive, easy to obtain, does not contain asbestos, has low harm to the human body, mortar troweling workability, especially trowel elongation, detachment of iron, difficulty of dripping, improved finish aesthetics, etc. We have succeeded in developing a plastering mortar admixture whose workability improving effect is equal to or higher than that of asbestos and serpentine and at the same time providing a mortar composition containing it.

Claims (6)

カオリナイト、ハロイサイト、パイロフィライト、タルク、クロライト、モンモリロナイト、ムスコバイト、バーミキュライトからなる群から選ばれた1種または2種以上の粘土鉱物を含有するクレーで、平均粒子径が0.3〜30μmであるクレーと、水溶性高分子増粘剤をクレー100重量部に対し0.3〜10重量部配合したことを特徴とする左官モルタル用混和材。 A clay containing one or more clay minerals selected from the group consisting of kaolinite, halloysite, pyrophyllite, talc, chlorite, montmorillonite, muskovite and vermiculite, with an average particle size of 0.3- A plastering mortar admixture comprising 0.3 to 10 parts by weight of 30 μm clay and a water-soluble polymer thickener based on 100 parts by weight of clay. 水溶性高分子増粘剤が、メチルセルロース、ヒドロキシプロピルメチルセルロース、ヒドロキシエチルセルロース、ヒドロキシエチルエチルセルロース、キサンタンガム、グアーガム、カラギーナン、アルギン酸ソーダ、カゼイン、ポリオチレンオキサイド、ポリビニルアルコール、水溶性ポリウレタンから選ばれた1種または2種以上である請求項1に記載の左官モルタル用混和材。 The water-soluble polymer thickener is selected from methyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl cellulose, hydroxyethyl ethyl cellulose, xanthan gum, guar gum, carrageenan, sodium alginate, casein, polyoxylene oxide, polyvinyl alcohol, water-soluble polyurethane, or The admixture for plastering mortar according to claim 1, wherein there are two or more kinds. 請求項1に記載の左官モルタル用混和材に対し、さらに珪砂、石灰石微粉末、フライアッシュ、高炉スラグ粉末、シラスバルーン、パーライトからなる群から選ばれた1種または2種以上の無機物質を左官モルタル用混和材100重量部に対し300重量部を超えない範囲で配合してなる請求項1または2に記載の左官モルタル用混和材。 The plastering mortar admixture according to claim 1 is further plastered with one or more inorganic substances selected from the group consisting of silica sand, limestone fine powder, fly ash, blast furnace slag powder, shirasu balloon, and pearlite. The admixture for plastering mortar according to claim 1 or 2, wherein the admixture is mixed in an amount not exceeding 300 parts by weight per 100 parts by weight of the admixture for mortar. 請求項1〜3のいずれか1項に記載の左官モルタル用混和材を、モルタル組成物(水配合前の重量)100重量部に対し0.5〜10重量部を含む左官用モルタル組成物。 A plastering mortar composition comprising the plastering mortar admixture according to any one of claims 1 to 3 in an amount of 0.5 to 10 parts by weight with respect to 100 parts by weight of the mortar composition (weight before mixing with water). 請求項4に記載の左官用モルタル組成物を用いることを特徴とする左官施工方法。 A plastering method using the plastering mortar composition according to claim 4. 請求項4に記載の左官用モルタル組成物を用いた建築物又は建造物。
A building or a building using the plastering mortar composition according to claim 4.
JP2004358419A 2004-12-10 2004-12-10 Admixture for plaster mortar and mortar composition containing the same Pending JP2006160589A (en)

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006213593A (en) * 2005-01-04 2006-08-17 Ube Ind Ltd Cement composition and hardened body obtained by including the same
KR100805936B1 (en) 2006-08-03 2008-02-21 조민주 built-in material for composition
JP2009078934A (en) * 2007-09-25 2009-04-16 Denki Kagaku Kogyo Kk Quick setting cement concrete, and spraying method
JP2009227481A (en) * 2008-03-19 2009-10-08 Ube Ind Ltd Hydraulic composition
KR101347084B1 (en) 2013-05-10 2014-01-03 주식회사 문영이엔씨 Formulation and application method of polymer repair mortar which is good at reducing crazing, by using dispersed rock wool
JP2014136665A (en) * 2013-01-17 2014-07-28 Akio Maru Expansion suppressing material, concrete and method of suppressing expansion of concrete
CN104446189A (en) * 2014-11-11 2015-03-25 河北银通建材有限责任公司 YT inorganic meshless active wall thermal insulation material
KR101512962B1 (en) * 2014-11-13 2015-04-21 (주)코메스코리아 Mortar Composition for Repair Section and Repair Method Section Using Thereof
JP2015117166A (en) * 2013-12-19 2015-06-25 太平洋マテリアル株式会社 Mortar composition
CN105859221A (en) * 2016-04-18 2016-08-17 浙江正裕科技股份有限公司 Dry-blended plastering mortar
CN105948561A (en) * 2016-04-21 2016-09-21 张伟 Wet-mixed mortar additive
WO2017103801A1 (en) * 2015-12-18 2017-06-22 Bawri Binod Kumar Environment friendly plaster composition
CN110357555A (en) * 2019-07-30 2019-10-22 杭州天翔新型建材股份有限公司 A kind of lightweight plastering gupsum and preparation method thereof
CN114873981A (en) * 2022-02-11 2022-08-09 广西良本新材料科技有限公司 Green environment-friendly sound insulation mortar and preparation process thereof

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* Cited by examiner, † Cited by third party
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JPH03257045A (en) * 1990-03-05 1991-11-15 Fujikawa Kenzai Kogyo Kk Admixture for plasterer
JPH0656495A (en) * 1992-08-03 1994-03-01 Nippon Steel Weld Prod & Eng Co Ltd Sealant for joint of stone material

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JPH03257045A (en) * 1990-03-05 1991-11-15 Fujikawa Kenzai Kogyo Kk Admixture for plasterer
JPH0656495A (en) * 1992-08-03 1994-03-01 Nippon Steel Weld Prod & Eng Co Ltd Sealant for joint of stone material

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006213593A (en) * 2005-01-04 2006-08-17 Ube Ind Ltd Cement composition and hardened body obtained by including the same
KR100805936B1 (en) 2006-08-03 2008-02-21 조민주 built-in material for composition
JP2009078934A (en) * 2007-09-25 2009-04-16 Denki Kagaku Kogyo Kk Quick setting cement concrete, and spraying method
JP2009227481A (en) * 2008-03-19 2009-10-08 Ube Ind Ltd Hydraulic composition
JP2014136665A (en) * 2013-01-17 2014-07-28 Akio Maru Expansion suppressing material, concrete and method of suppressing expansion of concrete
KR101347084B1 (en) 2013-05-10 2014-01-03 주식회사 문영이엔씨 Formulation and application method of polymer repair mortar which is good at reducing crazing, by using dispersed rock wool
JP2015117166A (en) * 2013-12-19 2015-06-25 太平洋マテリアル株式会社 Mortar composition
CN104446189A (en) * 2014-11-11 2015-03-25 河北银通建材有限责任公司 YT inorganic meshless active wall thermal insulation material
KR101512962B1 (en) * 2014-11-13 2015-04-21 (주)코메스코리아 Mortar Composition for Repair Section and Repair Method Section Using Thereof
WO2017103801A1 (en) * 2015-12-18 2017-06-22 Bawri Binod Kumar Environment friendly plaster composition
CN105859221A (en) * 2016-04-18 2016-08-17 浙江正裕科技股份有限公司 Dry-blended plastering mortar
CN105948561A (en) * 2016-04-21 2016-09-21 张伟 Wet-mixed mortar additive
CN110357555A (en) * 2019-07-30 2019-10-22 杭州天翔新型建材股份有限公司 A kind of lightweight plastering gupsum and preparation method thereof
CN114873981A (en) * 2022-02-11 2022-08-09 广西良本新材料科技有限公司 Green environment-friendly sound insulation mortar and preparation process thereof

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