GB964238A - High refractive index glass - Google Patents

High refractive index glass

Info

Publication number
GB964238A
GB964238A GB4675062A GB4675062A GB964238A GB 964238 A GB964238 A GB 964238A GB 4675062 A GB4675062 A GB 4675062A GB 4675062 A GB4675062 A GB 4675062A GB 964238 A GB964238 A GB 964238A
Authority
GB
United Kingdom
Prior art keywords
bao
oxides
tio2
added
high refractive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4675062A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cataphote Inc
Original Assignee
Cataphote Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cataphote Inc filed Critical Cataphote Inc
Publication of GB964238A publication Critical patent/GB964238A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/062Glass compositions containing silica with less than 40% silica by weight
    • C03C3/064Glass compositions containing silica with less than 40% silica by weight containing boron
    • C03C3/066Glass compositions containing silica with less than 40% silica by weight containing boron containing zinc
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/062Glass compositions containing silica with less than 40% silica by weight

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

A glass composition consists essentially of, by weight, 32 to 37% TiO2, 30% to 49% of at least one of the oxides BaO and ZnO not less than 30% being BaO, 3.5 to 4.5 of at least one of the oxides CaO and MgO, 0 to 2.5% of at least one of the oxides Na2O, K2O and Li2O, and 12% to 21% of at least one of the oxides SiO2, Al2O3 and B2O3. Fluorides may be added to assist in fluxing the glass. Melting must be effected in an oxidizing atmosphere and nitrates, for example, are preferably added to the batch materials to provide extra oxygen. The Ba, Ca and Na may be added as carbonates. The compositions of the invention have high refractive indices and surface tensions which make them particularly suitable for forming reflective glass beads and flakes. Their properties are compared with two prior art compositions: (1) 32.6% TiO2, 55.8% BaO, 11.6% B2O3 and (2) 37.8% TiO2, 37.2% BaO, 19.7% B2O3, 5.1% ZnO, both in per cent by weight.
GB4675062A 1962-01-24 1962-12-11 High refractive index glass Expired GB964238A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US16852862A 1962-01-24 1962-01-24

Publications (1)

Publication Number Publication Date
GB964238A true GB964238A (en) 1964-07-22

Family

ID=22611862

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4675062A Expired GB964238A (en) 1962-01-24 1962-12-11 High refractive index glass

Country Status (5)

Country Link
CH (1) CH417865A (en)
DE (1) DE1421853B2 (en)
DK (1) DK105078C (en)
GB (1) GB964238A (en)
NL (2) NL121577C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104860535A (en) * 2015-05-05 2015-08-26 江油市明瑞反光材料科技有限公司 Production process of large sizes and high refraction of glass beads

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2555633C2 (en) * 1975-12-08 1982-06-09 Minnesota Mining and Manufacturing Co., 55133 Saint Paul, Minn. Colorless transparent glass microspheres based on TiO 2 -BaO- (ZnO-SiO 2) having a relatively high refractive index and their use
DE102013105177A1 (en) 2013-05-21 2014-11-27 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Process for obtaining metallic fractions and metal-depleted material from metal-containing materials

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104860535A (en) * 2015-05-05 2015-08-26 江油市明瑞反光材料科技有限公司 Production process of large sizes and high refraction of glass beads

Also Published As

Publication number Publication date
DE1421853A1 (en) 1968-11-07
DK105078C (en) 1966-08-15
DE1421853B2 (en) 1970-04-09
CH417865A (en) 1966-07-31
NL121577C (en)
NL288052A (en)

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