GB2311483A - Continuous extrusion of chocolate - Google Patents
Continuous extrusion of chocolate Download PDFInfo
- Publication number
- GB2311483A GB2311483A GB9615404A GB9615404A GB2311483A GB 2311483 A GB2311483 A GB 2311483A GB 9615404 A GB9615404 A GB 9615404A GB 9615404 A GB9615404 A GB 9615404A GB 2311483 A GB2311483 A GB 2311483A
- Authority
- GB
- United Kingdom
- Prior art keywords
- screw
- process according
- chocolate
- temperature
- fat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/02—Apparatus specially adapted for manufacture or treatment of sweetmeats or confectionery; Accessories therefor
- A23G3/0236—Shaping of liquid, paste, powder; Manufacture of moulded articles, e.g. modelling, moulding, calendering
- A23G3/0242—Apparatus in which the material is shaped at least partially by a die; Extrusion of cross-sections or plates, optionally the associated cutting device
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/04—Apparatus specially adapted for manufacture or treatment of cocoa or cocoa products
- A23G1/20—Apparatus for moulding, cutting, or dispensing chocolate
- A23G1/201—Apparatus not covered by groups A23G1/21 - A23G1/28
- A23G1/202—Apparatus in which the material is shaped at least partially by a die; Extrusion of cross-sections or plates, optionally with the associated cutting device
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G9/00—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
- A23G9/04—Production of frozen sweets, e.g. ice-cream
- A23G9/22—Details, component parts or accessories of apparatus insofar as not peculiar to a single one of the preceding groups
- A23G9/28—Details, component parts or accessories of apparatus insofar as not peculiar to a single one of the preceding groups for portioning or dispensing
- A23G9/281—Details, component parts or accessories of apparatus insofar as not peculiar to a single one of the preceding groups for portioning or dispensing at the discharge end of freezing chambers
- A23G9/285—Details, component parts or accessories of apparatus insofar as not peculiar to a single one of the preceding groups for portioning or dispensing at the discharge end of freezing chambers for extruding strips, cutting blocks and manipulating cut blocks
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Confectionery (AREA)
- Formation And Processing Of Food Products (AREA)
Description
1 - Continuous Extrusion of Chocolate 2311483 The present invention
relates to the extrusion of chocolate and more particularly to a process for the continuous extrusion of solid or semi- solid chocolate using a screw extruder.
In our co-pending EP-A-93114251.7, the entirety of which is hereby incorporated by reference, we describe a process for plastically extruding a fat-containing gonfectionery material which comprises feeding the fat containing confectionery material into an extruder and applying is pressure to the fat-containing confectionery material in a substantially solid or semi-solid nonpourable form upstream of a flow constriction whereby the temperature, pressure, contraction ratio and extrusion rate are such that the fatcontaining confectionery material is extruded and remains in a substantially solid or semi-solid nonpourable form to produce an axially homogeneous extruded product having a cross section that is of substantially the same profile as the die exit of the extruder, which is capable of retaining its shape and which has a temporary flexibility or plasticity enabling it to be physically manipulated, cut or plastically deformed before losing its flexibility or plasticity.
The temporary flexibility of the extruded fat-containing confectionery material obtained in the process of the above-mentioned co-pending patent application may last for up to 4 hours or more, e.g.from 1 second or less to 2 hours, e.g. from 10 seconds to 1 hour. During this period of temporary flexibility, the extruded fat-containing confectionery material may be cut cleanly and this is in contrast to fat-containing confectionery material extruded by a process as described in EP-A- 93114251 after the temporary flexibility has been lost, or to a normal set chocolate which has to be heated slightly for cutting otherwise it would shatter owing to its brittleness.
The extrusion process may be carried out batchwise or continuously and some examples of advantages of continuous extrusion are:
a) the extrusion rate is constant and uninterrupted, and b) coextrusion is simpler because the chocolate or fatcontaining confectionery material is extruded at a constant rate.
is c) continuous downstream cutting of the extruded flexible chocolate can be carried out in order to form sectioned pieces.
However, when carrying out continuous extrusion using a screw extruder, heat may be generated by the friction of the shear of the chocolate between the screw and the barrel wall. This heat tends to raise the temperature so that the chocolate melts and the liquefied fat of the melted chocolate acts as a lubricant causing the chocolate to slip against the barrel wall which prevents it extruding efficiently. It is important that the chocolate should stick sufficiently at the surface of the barrel wall and slip sufficiently at the surface of the extruder screw in order that the extruder can generate an extrusion pressure. It is equally important that the temperature at either surface is not sufficiently high to cause substantial melting of the chocolate.
We have found that, by careful control of the temperature of the barrel wall and of the screw, we can ensure that the chocolate remains in a substantially solid or semi-solid state with a suitable degree of slippage against the screw enabling an efficient extrusion through the barrel.
is According to the present invention, there is provided a process for the continuous extrusion of chocolate or a fatcontaining confectionery material using a screw extruder which comprises feeding the chocolate or fat-containing confectionery material into the screw extruder and generating a pressure to force the chocolate or fatcontaining confectionery material in a substantially solid or semi-solid nonpourable form upstream of a flow constriction whereby the temperature of the screw, the temperature of the. barrel wall, the screw speed, pressure, contraction ratio and extrusion rate are such that the chocolate or fat-containing confectionery material is extruded in a substantially solid or semi-solid nonpourable form to produce an axially homogeneous extruded product having a cross section that is of substantially the same profile as the die exit of the extruder, which is capable of retaining its shape and which has a temporary flexibility or plasticity enabling it to be physically manipulated, cut or plastically deformed before losing its flexibility or plasticity.
The chocolate material may be dark, milk or white chocolate. Fat containing confectionery materials may include sugar, milk derived components, and fat and solids from vegetable or cocoa sources in differing proportions having a moisture content less than 10%, more usually less than 5% by weight. They may be chocolate substitutes containing direct cocoa butter replacements, stearines, coconut oil, palm oil, butter or any mixture thereof; nut pastes such as peanut butter and fat; praline; confectioner's coatings used for covering cakes usually comprising chocolate analogues with cocoa butter replaced by a cheaper non-tempering fat; or "Caramac" sold by Nest16 comprising non-cocoa butter fats, sugar and milk.
is The temperature of the screw may be controlled, for instance, by a fluid such as water at the appropriate temperature flowing through the interior of the screw. For example, the fluid may enter at the upstream end and flow to the downstream end through one or more longitudinal channels and return through one or more longitudinal channels to the upstream end where it exits. The temperature of the barrel wall may be controlled, for instance, by a fluid such as water or glycol or a mixture thereof at the appropriate temperature flowing through a jacket surrounding the barrel wall.
The temperatures of the screw and the barrel wall may be controlled according to the type of fats present in the material being extruded. For example, fats having higher melting points usually require a warmer barrel wall and screw than fats having lower melting points. The degree of flexibility of the extruded product may be affected by the temperature and the melting point of the fats present in the material being extruded.
With regard to the screw temperature, if the temperature is too low the chocolate will adhere to the screw and will not advance along the screw whereas if the temperature is too high the chocolate melts causing blockages. Depending on the type of fats present in the material being extruded, the temperature of the the screw may be from 100 to 350C, and more usually from 150 to 300C.
With regard to the barrel wall temperature, if the temperature of the barrel wall is too high, the chocolate may melt and slip against the wall and may not extrude efficiently. Depending on the type of fats present in the material being extruded, the temperature of the barrel wall may be from -500 to +200C, more usually from -250 to +150C.
Often, the temperature of the barrel wall may conveniently be lower than the incoming chocolate or fat-containing confectionery material but, in some circumstances, the temperature of the barrel wall may be higher than the incoming chocolate or fat-containing confectionery material. The slippage of the fat-containing confectionery material against the barrel wall may also be reduced by roughening the barrel wall, e.g. by rifling such as forming longitudinal or spiral grooves in the wall. The spiral grooves preferably run in the opposite direction to the pitch of the screw. and preferably have a longer pitch than that of the screw.
Conveniently, the temperature of the screw is greater than the temperature of the barrel wall, for instance, by from 50 to 500C, preferably from 10 to 400C and more preferably from 120 to 30C.
In one advantageous embodiment the diameter of the screw root increases from the upstream to the downstream end while the pitch remains constant. In another advantageous embodiment the pitch of the screw decreases from the upstream to the downstream end while the diameter of the screw root remains constant.
The compression ratio of the screw may be from 1:1 to 5:1 and preferably from 1.5:1 to 3:1. Compression ratios above 5:1 may cause blockages of the material being extruded. The ratio of length to diameter of the screw may be, for instance, from 5:1 to 30:1 and preferably from 10:1 to 25:1.
The diameter of the screw may be, for example from 20 to 50Omm. The screw speed may be. for example, from 1 to 50Orpm. The actual screw diameter and screw speed may be selected by the person skilled in the art according to the requirements. The throughput depends on the screw speed and may be, for instance, from 1 to 5000kg/hr according to requirements.
If desired, two or more fat-based confectionery materials may be extruded in accordance with the process of the present invention. In addition, the chocolate or fatcontaining confectionery material may be co-extruded with is other food materials such as ice cream, sorbet, yoghurt, mousse, fondant, praline, marshmallow, nougat or jelly, etc., such being advantageous when the fat-containing confectionery material is extruded in a hollow or tubular form. Hence, in such embodiments, a multi-orifice die and/or associated equipment, as are known to those skilled in the art, may be employed.
If desired, a twin screw extruder may be used and may be either one using counter-rotating screws or one using corotating screws.
The temperature of the chocolate or fat-containing confectionery material as it is extruded may conveniently be from 150 to 280C, more usually from 18 to 250C, e.g. from 20' to 23C.
The present invention will now be further described by way of example only with reference to the accompanying drawing in which Figure 1 represents a schematic diagram of a continuous extrusion system.
Referring to Figure 1, the extruder generally designated 10 comprises a barrel 11 provided with a cooling jacket 12 having an inlet for cooling fluid 13 and an outlet for cooling fluid 14, an inlet for the feed material to be extruded 15, a die 16 having a circular cross-section and a diameter of 6. 5mm, and a screw 17 whose root diameter increases from the upstream end to the downstream end and provided with threads 18 whose pitch i"s constant from the upstream end to the downstream end. The screw 17 is provided with a channel 19 for heating fluid extending from the upstream end to the downstream end having an inlet 20 connected with a concentric channel 21 leading to an outlet for the heating fluid 22.
The operation of the above described single screw extruder will now be described in the following Examples.
Example 1
Milk chocolate buttons having a temperature of 22'C are fed into the barrel 11 of the extruder 10 through the feed inlet 15. The screw 17 has a diameter of 32mm, a length to diameter ratio of 24:1, a 2:1 compression ratio and a screw speed of 65rpm. A 50:50 mixture of water and glycol at SC flows through the cooling jacket 12 of the barrel and water at 200C flows through the channels 19 and 21 of the screw. As the screw rotates, the solid chocolate advances at a 1 rate of 15kg/hr and is extruded through the die 16 with a configuration conforming to that of the die and has a temporary flexibility which lasts for about 1 hour.
Example 2
Milk chocolate buttons having a temperature of 22C are fed into the barrel 11 of the extruder 10 through the feed inlet 15. The screw 17 has a diameter of SOmm, a length to diameter ratio of 20:1, a 2:1 compression ratio and a screw speed of 70rpm. A 50:50 mixture of water and glycol at -100C flows through the cooling jacket 12 of the barrel and water at 25C flows through the channels 19 and 21 of the screw. As the screw rotates, the solid-chocolate advances at a rate of 50kg/hr and is extruded at 21'C through the die 16 with a configuration conforming.to that of the die and has a temporary flexibility which lasts for about 1 hour.
Example 3
Milk chocolate buttons having a temperature of 220C are fed into the barrel 11 of the extruder 10 through the feed inlet 15. The screw 17 has a diameter of 90mm, a length to diameter ratio of 15:1, a 2:1 compression ratio and a screw is speed of 35rpm. Water at 50C flows through the cooling jacket 12 of the barrel and water at 200CIlows through the channels 19 and 21 of the screw. As the screw rotates, the solid chocolate advances at a rate of 280kg/hr and is extruded through the die 16 with.a configuration conforming to that of the die and has a temporary flexibility which lasts for about 1 hour.
35,
Claims (21)
- CLAIMS is 1. A process for the continuous extrusion of chocolate or a fat-containing confectionery material using a screw extruder which comprises feeding the chocolate or fatcontaining confectionery material into the screw extruder and generating a pressure to force the chocolate or fatcontaining confectionery material in a substantially solid or semisolid nonpourable form upstream of a flow constriction whereby the temperature of. the screw, the temperature of the barrel wall, the screw speed, pressure, contraction ratio and extrusion rate are such that the chocolate or fat-containing confectionery material is extruded in a substantially solid or semi-solid nonpourable form to produce an axially homogeneous extruded product having a cross section that is of substantially the same profile as the die exit of the extruder, which is capable of retaining its shape and which has a temporary flexibility or plasticity enabling it to be physically manipulated, cut or plastically deformed before losing its flexibility or plasticity.
- 2. A process according to claim 1 wherein the temperature of the screw is controlled by a fluid at the appropriate temperature flowing through the interior of the screw.
- 3. A process according to claim 2 wherein the fluid enters at the upstream end and flows to the downstream end through one or more longitudinal channels and returns through one or more longitudinal channels to the upstream end where it exits.
- 4. A process according to claim 1 wherein the temperature of the barrel wall is controlled by a fluid at the appropriate temperature flowing through a cooling jacket surrounding the wall of the barrel.
- 5. A process according to claim 1 wherein the temperature of the the screw is from 100 to 350C.
- 6. A process according to claim 1 wherein the temperature of the barrel wall is from -50' to +20C.
- 7. A process according to claim 1 wherein the temperature of the barrel wall is lower than the incoming chocolate or fat-containing confectionery material.
- 8. A process according to claim 1 wherein the temperature of the screw is greater than the temperature of the barrel by from 50 to 500C
- 9. A process according to claim 1 wherein the root diameter of the screw increases from the upstream to the downstream end while the pitch remains constant.
- 10. A process according to claim 1 wherein the pitch of the screw decreases from the upstream to the downstream end while the root diameter remains constant.
- 11. A process according to claim 1 wherein the pitch of the screw decreases from the upstream to the downstream end and the root diameter of the screw increases from the upstream to the downstream end.
- 12. A process according to claim 1 wherein the compression ratio of the screw is from 1:1 to 5:1. -
- 13. A process according to claim 1 wherein the ratio of length to diameter of the screw is from 5:1 to 30:1.
- 14. A process according to claim 1 wherein the diameter,of the screw is from 20 to 50Omm.11 -
- 15. A process according to claim 1 wherein the screw speed is from 1 to 50Orpm.
- 16. A process according to claim 1 wherein the barrel wall is roughened.
- 17. A process according to claim 1 wherein the throughput of the chocolate or a fat-containing confectionery material is from 1 to 5000kg/hr.
- 18. A process according to claim 1 wherein the chocolate or fatcontaining confectionery material may be co-extruded with another chocolate or fat-based confectionery material or another food material.
- 19. A process according to claim 18 wherein the other food material is ice cream, sorbet, yoghurt, mousse, fondant, praline, marshmallow, nougat, jelly or any other food material.
- 20. A process according to claim 1 wherein a twin screw extruder is used.
- 21. An extruded fat-containing confectionery material obtainable by a process according to any of the preceding claims.
Priority Applications (24)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97102515A EP0797922B1 (en) | 1996-03-26 | 1997-02-17 | Continuous extrusion of chocolate |
AT97102515T ATE217150T1 (en) | 1996-03-26 | 1997-02-17 | CONTINUOUS EXTRUSION OF CHOCOLATE MASSES |
DE69712397T DE69712397T2 (en) | 1996-03-26 | 1997-02-17 | Continuous extrusion of chocolate masses |
DK97102515T DK0797922T3 (en) | 1996-03-26 | 1997-02-17 | Continuous extrusion of chocolate |
PT97102515T PT797922E (en) | 1996-03-26 | 1997-02-17 | CONTINUOUS CHOCOLATE EXTRUSION |
ES97102515T ES2175204T3 (en) | 1996-03-26 | 1997-02-17 | CONTINUOUS CHOCOLATE EXTRUSION. |
IL12027697A IL120276A (en) | 1996-03-26 | 1997-02-20 | Continuous extrusion of chocolate |
NZ314293A NZ314293A (en) | 1996-03-26 | 1997-02-24 | Screw extruding chocolate or fat-containing confectionery in stable solid form but retaining temporary plasticity |
CA002198759A CA2198759C (en) | 1996-03-26 | 1997-02-27 | Continuous extrusion of chocolate |
BG101281A BG101281A (en) | 1996-03-26 | 1997-03-04 | Continuous chocolate extrusion |
SG9700718A SG90019A1 (en) | 1996-03-26 | 1997-03-13 | Continuous extrusion of chocolate |
NO971193A NO971193L (en) | 1996-03-26 | 1997-03-14 | Procedure for continuous extrusion of chocolate |
SK372-97A SK281971B6 (en) | 1996-03-26 | 1997-03-20 | Continuous extrusion of chocolate |
AU16489/97A AU717632B2 (en) | 1996-03-26 | 1997-03-24 | Continuous extrusion of chocolate |
BR9701456A BR9701456A (en) | 1996-03-26 | 1997-03-24 | Continuous chocolate extrusion |
PL97319133A PL182852B1 (en) | 1996-03-26 | 1997-03-24 | Method of continuously extruding chocolate or other fat containing confectionery material |
JP9071724A JPH104884A (en) | 1996-03-26 | 1997-03-25 | Continuous extrusion of chocolate |
TNTNSN97054A TNSN97054A1 (en) | 1996-03-26 | 1997-03-25 | CONTINUOUS CHOCOLATE EXTRUSION |
RU97104542/13A RU2181547C2 (en) | 1996-03-26 | 1997-03-25 | Method for continuous extrusion of chocolate or fat-containing confectionery material and material produced by method |
US08/823,602 US6051267A (en) | 1996-03-26 | 1997-03-25 | Screw-extrusion of chocolate and other fat-containing confectionery materials |
HU9700643A HUP9700643A3 (en) | 1996-03-26 | 1997-03-25 | Process for continuous producing of sweet industry product and prodact with this process |
CZ1997912A CZ295962B6 (en) | 1996-03-26 | 1997-03-26 | Process for continuous extrusion |
CN97104936A CN1065413C (en) | 1996-03-26 | 1997-03-26 | Continuous extrusion of chocolate |
TW086106724A TW414691B (en) | 1996-03-26 | 1997-05-20 | Continuous extrusion of chocolate |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9606285A GB2311481A (en) | 1996-03-26 | 1996-03-26 | Continuous extrusion of chocolate |
Publications (2)
Publication Number | Publication Date |
---|---|
GB9615404D0 GB9615404D0 (en) | 1996-09-04 |
GB2311483A true GB2311483A (en) | 1997-10-01 |
Family
ID=10790999
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB9606285A Withdrawn GB2311481A (en) | 1996-03-26 | 1996-03-26 | Continuous extrusion of chocolate |
GB9615404A Withdrawn GB2311483A (en) | 1996-03-26 | 1996-07-23 | Continuous extrusion of chocolate |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB9606285A Withdrawn GB2311481A (en) | 1996-03-26 | 1996-03-26 | Continuous extrusion of chocolate |
Country Status (4)
Country | Link |
---|---|
GB (2) | GB2311481A (en) |
IN (1) | IN183385B (en) |
TN (1) | TNSN97054A1 (en) |
ZA (1) | ZA972448B (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9825892D0 (en) * | 1998-11-27 | 1999-01-20 | Cadbury Schweppes Plc | Improvemnts in confectionery manufacture |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB429536A (en) * | 1934-03-19 | 1935-05-31 | Carl Ulrich Simonsen | Apparatus for producing hollow cylindrical or prismatic bodies from agricultural products |
GB994554A (en) * | 1962-06-20 | 1965-06-10 | Heinrich Flessner | Method of and apparatus for the production of a food from starch-containing material |
GB1491162A (en) * | 1974-01-08 | 1977-11-09 | Maschf Lalesse Bv | Preparation of expanded foodstuffs |
GB2051656A (en) * | 1979-06-01 | 1981-01-21 | Dorsey Mccomb Distributors Inc | Extrusion apparatus |
WO1983001729A1 (en) * | 1981-11-18 | 1983-05-26 | Cameron, William, Dougall, David | Method of making food coatings, fillers and pellets |
EP0122887A2 (en) * | 1983-03-17 | 1984-10-24 | Gaetano Piazzola | An electric thermal unit surrounded by a double air circulating interspace, for controllably heating cylinders in extruders, injection presses, and drawing machines for plastics, rubbers and the like |
US5439695A (en) * | 1992-09-29 | 1995-08-08 | Nestec S.A. | Isothermal preparation of chocolate products |
EP0603467B1 (en) * | 1992-09-29 | 1996-10-16 | Societe Des Produits Nestle S.A. | Extrusion process |
-
1996
- 1996-03-26 GB GB9606285A patent/GB2311481A/en not_active Withdrawn
- 1996-07-23 GB GB9615404A patent/GB2311483A/en not_active Withdrawn
-
1997
- 1997-02-26 IN IN393MA1997 patent/IN183385B/en unknown
- 1997-03-20 ZA ZA972448A patent/ZA972448B/en unknown
- 1997-03-25 TN TNTNSN97054A patent/TNSN97054A1/en unknown
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB429536A (en) * | 1934-03-19 | 1935-05-31 | Carl Ulrich Simonsen | Apparatus for producing hollow cylindrical or prismatic bodies from agricultural products |
GB994554A (en) * | 1962-06-20 | 1965-06-10 | Heinrich Flessner | Method of and apparatus for the production of a food from starch-containing material |
GB1491162A (en) * | 1974-01-08 | 1977-11-09 | Maschf Lalesse Bv | Preparation of expanded foodstuffs |
GB2051656A (en) * | 1979-06-01 | 1981-01-21 | Dorsey Mccomb Distributors Inc | Extrusion apparatus |
WO1983001729A1 (en) * | 1981-11-18 | 1983-05-26 | Cameron, William, Dougall, David | Method of making food coatings, fillers and pellets |
EP0122887A2 (en) * | 1983-03-17 | 1984-10-24 | Gaetano Piazzola | An electric thermal unit surrounded by a double air circulating interspace, for controllably heating cylinders in extruders, injection presses, and drawing machines for plastics, rubbers and the like |
US5439695A (en) * | 1992-09-29 | 1995-08-08 | Nestec S.A. | Isothermal preparation of chocolate products |
EP0603467B1 (en) * | 1992-09-29 | 1996-10-16 | Societe Des Produits Nestle S.A. | Extrusion process |
Also Published As
Publication number | Publication date |
---|---|
ZA972448B (en) | 1998-09-21 |
GB2311481A (en) | 1997-10-01 |
GB9615404D0 (en) | 1996-09-04 |
TNSN97054A1 (en) | 1999-12-31 |
GB9606285D0 (en) | 1996-05-29 |
IN183385B (en) | 1999-12-11 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |