GB1044810A - Organic phosphinodithioate-amine reaction products - Google Patents

Organic phosphinodithioate-amine reaction products

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Publication number
GB1044810A
GB1044810A GB14497/64A GB1449764A GB1044810A GB 1044810 A GB1044810 A GB 1044810A GB 14497/64 A GB14497/64 A GB 14497/64A GB 1449764 A GB1449764 A GB 1449764A GB 1044810 A GB1044810 A GB 1044810A
Authority
GB
United Kingdom
Prior art keywords
hydrocarbon
substituted hydrocarbon
radical
phosphinodithioate
valence
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB14497/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lubrizol Corp
Original Assignee
Lubrizol Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US280452A external-priority patent/US3351647A/en
Application filed by Lubrizol Corp filed Critical Lubrizol Corp
Publication of GB1044810A publication Critical patent/GB1044810A/en
Expired legal-status Critical Current

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    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
    • C07F9/165—Esters of thiophosphoric acids
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    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
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    • C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04—Phosphate esters
    • C10M137/08—Ammonium or amine salts
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    • C10M137/12—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having a phosphorus-to-carbon bond
    • C10M137/14—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having a phosphorus-to-carbon bond containing sulfur
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  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
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  • Biochemistry (AREA)
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  • Lubricants (AREA)

Abstract

Lubricating compositions, gasoline and fuel oils, contain N- and P-containing products of unknown structure but of general formula <FORM:1044810/C4-C5/1> where R is a hydrocarbon, substituted hydrocarbon or heterocyclic radical; M is Zn, Ca, Cu, Ni, Co, Cr, Pb or Cd; A, B and C are each H or a hydrocarbon or substituted hydrocarbon radical and 2 or 3 may be linked together; x is the valence of M; and y is 0.5 to 6. Suitable lubricating oils include animal, mineral, vegetable and synthetic ester oils. Other lubricant ingredients include phenyl betanaphthylamine, naphthenic, sulphonic and phosphorus acid salts as detergents, triethylene-tetramine/alkenylsuccinic anhydride, acrylate polymers and copolymers, siloxanes, phenol/formaldehyde/amine condensates, 4-methyl-2,6-di-tert-butylphenol, N,N1-sec-butyl-phenylene-diamine, phenates, amines, benzyl thiocyanates, chlorinated paraffins, ethers and phenols, fatty acids and esters, polybutene.ALSO:The invention comprises N- and P-containing products of unknown structure but of general formula <FORM:1044810/C2/1> where R is a hydrocarbon, substituted hydrocarbon or heterocyclic radical; M is Zn, Ca, Cu, Ni, Co, Cr, Pb or Cd; A, B and C are each H or a hydrocarbon or substituted hydrocarbon radical and 2 or 3 may be linked together; x is the valence of M; and z is 0.5-6. They may be prepared by reacting a metal (M) phospinodithioate with the amine N.ABC or by first forming a complex of an inorganic M salt with N.ABC followed by double decomposition with the Na or K phosphinodithioate.
GB14497/64A 1963-05-14 1964-04-08 Organic phosphinodithioate-amine reaction products Expired GB1044810A (en)

Applications Claiming Priority (2)

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US280452A US3351647A (en) 1963-05-14 1963-05-14 Nitrogen, phosphorus and metal containing composition
US640761A US3396109A (en) 1963-05-14 1967-01-26 Lubricants containing reaction product of a metal phosphinodithioate with an amine

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GB1044810A true GB1044810A (en) 1966-10-05

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GB14497/64A Expired GB1044810A (en) 1963-05-14 1964-04-08 Organic phosphinodithioate-amine reaction products

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US (1) US3396109A (en)
FR (1) FR1396093A (en)
GB (1) GB1044810A (en)

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US4721802A (en) * 1983-01-07 1988-01-26 The Lubrizol Corporation Dithiophosphorus/amine salts
US4772739A (en) * 1984-02-14 1988-09-20 The Lubrizol Corporation Nitrogen- and phosphorus-containing compositions and aqueous systems containing same
US4774351A (en) * 1983-01-07 1988-09-27 The Lubrizol Corporation Aqueous fluids compositions containing dithiophosphorus/amine salts

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US4618450A (en) * 1984-11-07 1986-10-21 The Lubrizol Corporation Aqueous systems containing amino sulfonic acid derivatives of carboxylic acids
US4746450A (en) * 1986-12-08 1988-05-24 Basf Corporation Functional fluids and concentrates thickened with associative polyether thickeners containing certain primary amines
US5152908A (en) * 1987-05-07 1992-10-06 Tipton Craig D Gear lubricant package containing a synergistic combination of components
US4795583A (en) * 1987-12-28 1989-01-03 Ethyl Petroleum Additives, Inc. Shift-feel durability enhancement
US6667282B2 (en) 2001-05-31 2003-12-23 Crompton Corporation Alkyl hydrazide additives for lubricants
US6559107B2 (en) 2001-05-31 2003-05-06 Crompton Corporation Thiadiazolidine additives for lubricants
US6551966B2 (en) 2001-06-01 2003-04-22 Crompton Corporation Oxadiazole additives for lubricants
US6566311B1 (en) 2001-11-30 2003-05-20 Uniroyal Chemical Company, Inc. 1,3,4-oxadiazole additives for lubricants
US6706671B2 (en) 2001-11-30 2004-03-16 Uniroyal Chemical Company, Inc. Alkyl-succinhydrazide additives for lubricants
US6559106B1 (en) 2001-11-30 2003-05-06 Uniroyal Chemical Company, Inc. Tri-glycerinate vegetable oil-succinhydrazide additives for lubricants
US6887835B1 (en) 2002-07-09 2005-05-03 Crompton Corporation Silane additives for lubricants and fuels
US7399734B2 (en) * 2003-07-22 2008-07-15 Crompton Corporation Polysiloxane additives for lubricants and fuels
US7442673B2 (en) * 2003-08-15 2008-10-28 Crompton Corporation Reaction products of mercaptobenzothiazoles, mercaptothiazolines, and mercaptobenzimidazoles with epoxides as lubricant additives
US7696136B2 (en) * 2004-03-11 2010-04-13 Crompton Corporation Lubricant compositions containing hydroxy carboxylic acid and hydroxy polycarboxylic acid esters
US7485605B2 (en) * 2004-10-26 2009-02-03 Crompton Corporation Lubricant and fuel compositions containing 2-(S(N)-mercaptobenzothiazole)succinic and methylene succinate esters
US7541319B2 (en) * 2004-10-26 2009-06-02 Chemtura Corporation 1,3-dithiolane-2-thione additives for lubricants and fuels
US7521401B2 (en) * 2004-11-23 2009-04-21 Chemtura Corporation Dithiocarbamyl β-hydroxy fatty acid esters as additives for lubricants and fuels
US8017805B2 (en) * 2005-10-11 2011-09-13 Chemtura Corporation Diaromatic amines
US7846884B2 (en) * 2005-11-29 2010-12-07 Chemtura Corporation Lubricating oil compositions
US7704929B2 (en) * 2006-01-04 2010-04-27 Chemtura Corporation Diaromatic amine derivatives as antioxidants
US7879934B2 (en) * 2007-08-16 2011-02-01 Chemtura Corporation Rubber compositions
US10955009B2 (en) 2018-04-03 2021-03-23 Borgwarner Inc. Clutch pack having different clutch plate materials

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US2765277A (en) * 1951-11-21 1956-10-02 Exxon Research Engineering Co Lubricating oil additives
US2841552A (en) * 1955-06-30 1958-07-01 Standard Oil Co Lubricating oil composition
US2907713A (en) * 1955-09-08 1959-10-06 Standard Oil Co Lubricating oil composition
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4721802A (en) * 1983-01-07 1988-01-26 The Lubrizol Corporation Dithiophosphorus/amine salts
US4774351A (en) * 1983-01-07 1988-09-27 The Lubrizol Corporation Aqueous fluids compositions containing dithiophosphorus/amine salts
US4772739A (en) * 1984-02-14 1988-09-20 The Lubrizol Corporation Nitrogen- and phosphorus-containing compositions and aqueous systems containing same
US5041598A (en) * 1984-02-14 1991-08-20 The Lubrizol Corporation Nitrogen- and phosphorus-containing compositions and aqueous systems containing same

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FR1396093A (en) 1965-04-16
US3396109A (en) 1968-08-06

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