GB1055429A - Organic polymeric salts and lubricating oil compostitions containing such salts - Google Patents

Organic polymeric salts and lubricating oil compostitions containing such salts

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Publication number
GB1055429A
GB1055429A GB49817/63A GB4981763A GB1055429A GB 1055429 A GB1055429 A GB 1055429A GB 49817/63 A GB49817/63 A GB 49817/63A GB 4981763 A GB4981763 A GB 4981763A GB 1055429 A GB1055429 A GB 1055429A
Authority
GB
United Kingdom
Prior art keywords
sulphonic acid
salts
lubricating oil
salt
alkylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB49817/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB1055429A publication Critical patent/GB1055429A/en
Expired legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/36—Oxygen or sulfur atoms
    • C07D207/40—2,5-Pyrrolidine-diones
    • C07D207/404—2,5-Pyrrolidine-diones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. succinimide
    • C07D207/408—Radicals containing only hydrogen and carbon atoms attached to ring carbon atoms
    • C07D207/412—Acyclic radicals containing more than six carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/34—Introducing sulfur atoms or sulfur-containing groups
    • C08F8/36—Sulfonation; Sulfation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/46—Reaction with unsaturated dicarboxylic acids or anhydrides thereof, e.g. maleinisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/48—Isomerisation; Cyclisation
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/52—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms
    • C10M133/56—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/50—Chemical modification of a polymer wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/024—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings having at least two phenol groups but no condensed ring
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/402—Castor oils
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
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    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C10M2215/065—Phenyl-Naphthyl amines
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    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
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    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Lubricants (AREA)

Abstract

Lubricating oils include, as an additive providing stability, anti-sludge, wear-inhibiting, corrosion-inhibiting and detergent properties a minor proportion of a sulphonic acid salt of a succinimide base of the formula <FORM:1055429/C4-C5/1> wherein R is a C20- 500 polymerized alkylene or arylalkylene group and X is the residue, after the removal of a primary amino group, of an alkylene or arylene polyamine containing at least one primary amino group. In a modification, the additive may comprise a mixture of the salt together with the parent succinimide base. The sulphonic acid component of the salt may be aryl, alkylaryl or alkyl sulphonic acid or a sulphonation product of petroleum or aromatic extracts from lubricating oil or kerosene. The lubricating oil used may be a mineral oil, e.g. that obtained from a paraffinic and/or naphthenic crude, optionally blended with fatty oils and/or synthetic lubricating oils. The latter (unspecified) may be used as the sole lubricating oil. Other ingredients may also be included, e.g. alkylphenols, arylamines, dialkyl sulphides, phosphite, phosphate and phosphonate esters and salts and their thio-derivatives, P2S5-terpene reaction products and alkali metal salts thereof.ALSO:Oil soluble compounds suitable as lubricant additives comprise salts of an organic sulphonic acid and a succinimide of the general formula <FORM:1055429/C3/1> wherein R is a C20- 500 polymerized alkylene or arylalkylene group and X is the residue, after the removal of a primary amino group, of an alkylene or arylene polyamine containing at least one primary amino group. The basic component of the salt may be prepared by heating maleic anhydride with a polymer or copolymer of an alkylene and/or arylalkylene, e.g. polypropylene, polybutene, ethylene-isobutylene copolymer or ethylene-a -methylstyrene copolymer, so as to mono-alkylate the anhydride, and heating the substituted succinic anhydride so obtained with an appropriate polyamine, of which many examples are given, the preferred ones being tetraethylenepentamine, diethylamino-propylamine and dimethylamino-propylamine. The polymer base is then converted to the sulphonate salt form, for example by adding a sulphonic acid to a solution or suspension of the base in a suitable liquid medium or by adding the acid to a melt of the polymer base; not all the base need be neutralized by the sulphonic acid, for example only 10 to 50% by weight of the mixture need be in salt form. Sulphonic acids exemplified are benzene-, alkylbenzene-, naphthalene-, alkylnaphthalene-, naphthol-, alkyl-sulphonic acids and the sulphonation products of petroleum fractions and aromatic extracts from lubricating oil fractions or kerosene.
GB49817/63A 1962-12-19 1963-12-17 Organic polymeric salts and lubricating oil compostitions containing such salts Expired GB1055429A (en)

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US245682A US3189544A (en) 1962-12-19 1962-12-19 Non-ash-containing lubricating oil composition

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GB1055429A true GB1055429A (en) 1967-01-18

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US (1) US3189544A (en)
BE (1) BE641399A (en)
DE (1) DE1444910A1 (en)
FR (1) FR1377810A (en)
GB (1) GB1055429A (en)
NL (1) NL302077A (en)

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EP0017690A1 (en) * 1978-12-29 1980-10-29 Exxon Research And Engineering Company Oil-soluble sulfonated polyols and sulfonated polyolesters and their preparation
DE3132220A1 (en) * 1980-08-25 1982-05-13 Exxon Research and Engineering Co., 07932 Florham Park, N.J. LUBRICANT OIL WITH IMPROVED DISPERSITY IN DIESEL ENGINES
EP1707616A3 (en) * 2005-03-31 2010-01-27 Chevron Oronite Company LLC Fused-ring aromatic amine based wear and oxidation inhibitors for lubricants

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2449723A1 (en) * 1978-12-04 1980-09-19 Chevron Res DISPERSANT ADDITIVES FOR LUBRICATING OILS AND THEIR PREPARATION METHOD
EP0017690A1 (en) * 1978-12-29 1980-10-29 Exxon Research And Engineering Company Oil-soluble sulfonated polyols and sulfonated polyolesters and their preparation
DE3132220A1 (en) * 1980-08-25 1982-05-13 Exxon Research and Engineering Co., 07932 Florham Park, N.J. LUBRICANT OIL WITH IMPROVED DISPERSITY IN DIESEL ENGINES
EP1707616A3 (en) * 2005-03-31 2010-01-27 Chevron Oronite Company LLC Fused-ring aromatic amine based wear and oxidation inhibitors for lubricants
US8138130B2 (en) 2005-03-31 2012-03-20 Chevron Oronite Company Llc Fused-ring aromatic amine based wear and oxidation inhibitors for lubricants

Also Published As

Publication number Publication date
US3189544A (en) 1965-06-15
NL302077A (en)
BE641399A (en) 1964-06-17
DE1444910A1 (en) 1968-11-07
FR1377810A (en) 1964-11-06

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