FI65268C - Foerfarande foer framstaellning av organiska polymerer genom ultraviolettbestraolning av en vattenloesning av monomerer - Google Patents

Foerfarande foer framstaellning av organiska polymerer genom ultraviolettbestraolning av en vattenloesning av monomerer Download PDF

Info

Publication number: FI65268C
Authority: FI; Finland
Prior art keywords: solution; photopolymerization; irradiation; process according; monomers
Prior art date: 1978-06-09

Application number

FI791814A

Other languages

English (en)

Finnish (fi)

Swedish (sv)

Other versions

FI65268B (fi

FI791814A (fi

Inventor

Jean Boutin

Jean Neel

Original Assignee

Rhone Poulenc Ind

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-06-09

Filing date

1979-06-06

Publication date

1984-04-10

1979-06-06 Application filed by Rhone Poulenc Ind filed Critical Rhone Poulenc Ind

1979-12-10 Publication of FI791814A publication Critical patent/FI791814A/fi

1983-12-30 Publication of FI65268B publication Critical patent/FI65268B/fi

1984-04-10 Application granted granted Critical

1984-04-10 Publication of FI65268C publication Critical patent/FI65268C/fi

Links

239000000178 monomer Substances 0.000 claims description 36
239000000243 solution Substances 0.000 claims description 34
238000000034 method Methods 0.000 claims description 21
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
239000007864 aqueous solution Substances 0.000 claims description 15
239000000758 substrate Substances 0.000 claims description 10
238000006116 polymerization reaction Methods 0.000 claims description 8
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 7
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
239000001301 oxygen Substances 0.000 claims description 7
229910052760 oxygen Inorganic materials 0.000 claims description 7
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
238000001816 cooling Methods 0.000 claims description 5
230000005855 radiation Effects 0.000 claims description 5
239000007789 gas Substances 0.000 claims description 4
239000007787 solid Substances 0.000 claims description 4
238000004519 manufacturing process Methods 0.000 claims description 3
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 3
229920000620 organic polymer Polymers 0.000 claims description 3
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
125000004103 aminoalkyl group Chemical group 0.000 claims description 2
125000004432 carbon atom Chemical group C* 0.000 claims description 2
125000005395 methacrylic acid group Chemical group 0.000 claims 1
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
239000007788 liquid Substances 0.000 description 12
229920000642 polymer Polymers 0.000 description 10
239000011521 glass Substances 0.000 description 9
238000001914 filtration Methods 0.000 description 8
239000008394 flocculating agent Substances 0.000 description 7
238000002360 preparation method Methods 0.000 description 7
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
229910052757 nitrogen Inorganic materials 0.000 description 6
-1 acyl amide ester Chemical class 0.000 description 5
239000000203 mixture Substances 0.000 description 5
239000000843 powder Substances 0.000 description 5
241000234282 Allium Species 0.000 description 4
235000002732 Allium cepa var. cepa Nutrition 0.000 description 4
238000007922 dissolution test Methods 0.000 description 4
238000002474 experimental method Methods 0.000 description 4
230000003311 flocculating effect Effects 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 3
230000005587 bubbling Effects 0.000 description 3
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
239000002985 plastic film Substances 0.000 description 3
229920006255 plastic film Polymers 0.000 description 3
239000011148 porous material Substances 0.000 description 3
229920003169 water-soluble polymer Polymers 0.000 description 3
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
150000001252 acrylic acid derivatives Chemical class 0.000 description 2
150000003863 ammonium salts Chemical class 0.000 description 2
ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
239000011261 inert gas Substances 0.000 description 2
239000003999 initiator Substances 0.000 description 2
229910052753 mercury Inorganic materials 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
239000000546 pharmaceutical excipient Substances 0.000 description 2
239000005871 repellent Substances 0.000 description 2
238000002791 soaking Methods 0.000 description 2
238000003756 stirring Methods 0.000 description 2
238000009281 ultraviolet germicidal irradiation Methods 0.000 description 2
MSAHTMIQULFMRG-UHFFFAOYSA-N 1,2-diphenyl-2-propan-2-yloxyethanone Chemical compound C=1C=CC=CC=1C(OC(C)C)C(=O)C1=CC=CC=C1 MSAHTMIQULFMRG-UHFFFAOYSA-N 0.000 description 1
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical group [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical group CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 description 1
ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical class CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
244000028419 Styrax benzoin Species 0.000 description 1
235000000126 Styrax benzoin Nutrition 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical group [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
235000008411 Sumatra benzointree Nutrition 0.000 description 1
150000001447 alkali salts Chemical class 0.000 description 1
PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
150000004056 anthraquinones Chemical class 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical group C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 description 1
229960002130 benzoin Drugs 0.000 description 1
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
239000012965 benzophenone Substances 0.000 description 1
239000012267 brine Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
230000008021 deposition Effects 0.000 description 1
125000004985 dialkyl amino alkyl group Chemical group 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000008187 granular material Substances 0.000 description 1
235000019382 gum benzoic Nutrition 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
239000012535 impurity Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
229920006267 polyester film Polymers 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000005297 pyrex Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000007127 saponification reaction Methods 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
238000009736 wetting Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S522/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S522/903—Removal of residual monomer

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polymerisation Methods In General (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Separation Of Suspended Particles By Flocculating Agents (AREA)

FI791814A 1978-06-09 1979-06-06 Foerfarande foer framstaellning av organiska polymerer genom ultraviolettbestraolning av en vattenloesning av monomerer FI65268C (fi)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR7817857		1978-06-09
FR7817857A FR2428053A2 (fr)	1978-06-09	1978-06-09	Procede de photopolymerisation pour polymeres floculants

Publications (3)

Publication Number	Publication Date
FI791814A FI791814A (fi)	1979-12-10
FI65268B FI65268B (fi)	1983-12-30
FI65268C true FI65268C (fi)	1984-04-10

Family

ID=9209528

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
FI791814A FI65268C (fi)	1978-06-09	1979-06-06	Foerfarande foer framstaellning av organiska polymerer genom ultraviolettbestraolning av en vattenloesning av monomerer

Country Status (15)

Country	Link
US (1)	US4252625A (da)
EP (1)	EP0006777B1 (da)
JP (1)	JPS608681B2 (da)
AT (1)	AT369390B (da)
AU (1)	AU525520B2 (da)
BR (1)	BR7903567A (da)
CA (1)	CA1122920A (da)
DE (1)	DE2960983D1 (da)
DK (1)	DK154506C (da)
ES (1)	ES481385A1 (da)
FI (1)	FI65268C (da)
FR (1)	FR2428053A2 (da)
HU (1)	HU181491B (da)
NO (1)	NO153733C (da)
RO (1)	RO78267A (da)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2489336B1 (fr) *	1980-09-04	1985-09-13	Rhone Poulenc Spec Chim	Procede de preparation de polymeres ou copolymeres hydrosolubles a poids moleculaire eleve et a faible teneur en monomere(s) residuel(s), a partir de monomeres olefiniquement insatures
JPS60152504A (ja) *	1984-01-19	1985-08-10	Dai Ichi Kogyo Seiyaku Co Ltd	粘着性重合体の製法
CA1268732A (en) *	1984-12-27	1990-05-08	Akira Yada	Radiation-polymerizing water-soluble cast vinyl monomer layer and forming particles
JP2545951B2 (ja) *	1988-09-26	1996-10-23	東亞合成株式会社	光硬化性組成物
US5244934A (en) *	1991-06-07	1993-09-14	Takai Rubber Industries, Ltd.	Irradiation or thermal treatment of water-impregnated cross-linked poly-acrylic acid metal salt resin particles
US6262141B1 (en)	1999-10-06	2001-07-17	Cytec Technology Corporation	Process for the preparation of polymers having low residual monomer content

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB654026A (en) *	1948-10-22	1951-05-30	John Patrick Cavanagh	Polymeric compositions intended for moulding or extrusion
US2937163A (en) *	1955-03-07	1960-05-17	Dow Chemical Co	Water-soluble polymerization products and processes for producing the same
NL130574C (da) *	1966-06-25
US3912607A (en) *	1969-10-22	1975-10-14	Rhone Progil	Process for obtaining high molecular weight water-soluble acrylic polymers and copolymers using radiation
DE2009748A1 (de) *	1970-03-03	1971-09-16	Basf Ag	Verfahren zur Herstellung von wasser löslichen Polymerisaten
JPS5141160B2 (da) *	1974-08-13	1976-11-08
DE2545290A1 (de) *	1975-10-09	1977-04-21	Roehm Gmbh	Verfahren zum polymerisieren mittels uv-licht
DE2546279A1 (de) *	1975-10-16	1977-04-21	Bayer Ag	Verfahren und vorrichtung zum loesen von feststoffen in loesungsmitteln
FR2348227A1 (fr) *	1976-04-14	1977-11-10	Rhone Poulenc Ind	Perfectionnement aux procedes de preparation de polymeres acryliques hydrosolubles par photopolymerisation
JPS54155296A (en) *	1978-05-29	1979-12-07	Sanyo Chem Ind Ltd	Preparation of water-soluble polymer

1978
- 1978-06-09 FR FR7817857A patent/FR2428053A2/fr active Granted
1979
- 1979-05-30 EP EP79400341A patent/EP0006777B1/fr not_active Expired
- 1979-05-30 DE DE7979400341T patent/DE2960983D1/de not_active Expired
- 1979-06-06 FI FI791814A patent/FI65268C/fi not_active IP Right Cessation
- 1979-06-06 BR BR7903567A patent/BR7903567A/pt not_active IP Right Cessation
- 1979-06-06 HU HU79RO1024A patent/HU181491B/hu unknown
- 1979-06-07 AU AU47843/79A patent/AU525520B2/en not_active Ceased
- 1979-06-07 NO NO791906A patent/NO153733C/no unknown
- 1979-06-07 US US06/046,489 patent/US4252625A/en not_active Expired - Lifetime
- 1979-06-08 AT AT0414079A patent/AT369390B/de not_active IP Right Cessation
- 1979-06-08 CA CA329,387A patent/CA1122920A/fr not_active Expired
- 1979-06-08 JP JP54071332A patent/JPS608681B2/ja not_active Expired
- 1979-06-08 ES ES481385A patent/ES481385A1/es not_active Expired
- 1979-06-08 DK DK239479A patent/DK154506C/da not_active IP Right Cessation
- 1979-06-09 RO RO7997786A patent/RO78267A/ro unknown

Also Published As

Publication number	Publication date
BR7903567A (pt)	1980-01-22
FR2428053A2 (fr)	1980-01-04
FR2428053B2 (da)	1984-07-20
JPS608681B2 (ja)	1985-03-05
ATA414079A (de)	1982-05-15
DK239479A (da)	1979-12-10
FI65268B (fi)	1983-12-30
RO78267A (ro)	1982-04-12
CA1122920A (fr)	1982-05-04
EP0006777B1 (fr)	1981-10-14
NO153733B (no)	1986-02-03
AT369390B (de)	1982-12-27
JPS559687A (en)	1980-01-23
FI791814A (fi)	1979-12-10
HU181491B (en)	1983-07-28
DK154506C (da)	1989-04-10
US4252625A (en)	1981-02-24
ES481385A1 (es)	1979-11-16
NO153733C (no)	1986-05-14
NO791906L (no)	1979-12-11
AU525520B2 (en)	1982-11-11
EP0006777A1 (fr)	1980-01-09
AU4784379A (en)	1979-12-13
DK154506B (da)	1988-11-21
DE2960983D1 (en)	1981-12-24

Legal Events

Date	Code	Title	Description
2004-08-31	MM	Patent lapsed	Owner name: RHONE- POULENC INDUSTRIES

Publication	Publication Date	Title
FI63425B (fi)	1983-02-28	Foerfarande foer framstaellning av vattenloesliga hoegmolekylaera akrylpolymerer laempliga i synnerhet foer behandling av vatten
FI85153B (fi)	1991-11-29	Foerfarande foer framstaellning av vattenloesliga akrylpolymerer.
KR101612578B1 (ko)	2016-04-14	복합 반투막 및 그의 제조 방법
KR101580702B1 (ko)	2015-12-28	복합 분리막
FI69478C (fi)	1986-02-10	Foerfarande foer framstaellning av vattenloesliga akrylpolymerer eller -kopolymerer med hoeg molekylvikt och en ringa haltav restmonomer eller -monomerer
FI65268C (fi)	1984-04-10	Foerfarande foer framstaellning av organiska polymerer genom ultraviolettbestraolning av en vattenloesning av monomerer
CN106474568B (zh)	2021-04-30	表面改性金属及金属表面的改性方法
JP7319349B2 (ja)	2023-08-01	細胞培養基材
EP0167184A1 (en)	1986-01-08	Solid substrate which consists at least partically of a biologically or chemically active substance and is coated with a (meth)acrylic polmeric network as well as a process for providing said coated substrate
FI67714B (fi)	1985-01-31	Foerfarande foer framstaellning av vattenloesliga akrylpolymerer eller -sampolymerer med hoeg molekylvikt och mycket laog restmonomerhalt
FI65269C (fi)	1984-04-10	Foerfarande foer framstaellning av vattenloesliga polymerer oc deras anvaendning som flockningsmedel
KR101923014B1 (ko)	2018-11-28	복합 반투막 및 그 제조 방법
Daw et al.	1998	A comparative study of cell attachment to self assembled monolayers and plasma polymers
Liqun et al.	2000	Acetone-initiated photografting of methacrylic acid on low-density polyethylene film in water solvent
CN103145886B (zh)	2015-10-28	以液态二氧化碳为介质的聚合物微球的制备方法
JPS61221202A (ja)	1986-10-01	水溶性ビニル単量体の連続光重合方法
JP6064542B2 (ja)	2017-01-25	温度応答性を有する細胞培養基材の製造方法
JP2002003509A (ja)	2002-01-09	含水状重合体の製造方法
JP3964348B2 (ja)	2007-08-22	アクリル系重合体の製造方法およびその製造方法から得られるアクリル系重合体
JP3882553B2 (ja)	2007-02-21	水溶性重合体の製造方法
CN112210050B (zh)	2022-06-03	一种紫外光固化嵌段共聚物及其制备方法和用途
JPS56135505A (en)	1981-10-23	Production of water-soluble vinyl polymer
JP4016947B2 (ja)	2007-12-05	親水性重合体の製造方法
JP3711067B2 (ja)	2005-10-26	アクリル系重合体の連続製造方法
JP2002022940A (ja)	2002-01-23	光学フィルムの製造方法