ES2194505T3 - Proceso de dos fases para la produccion de 1,3-propanodiol por hidrogenacion catalitica de 3-hidroxipropanal. - Google Patents

Proceso de dos fases para la produccion de 1,3-propanodiol por hidrogenacion catalitica de 3-hidroxipropanal.

Info

Publication number
ES2194505T3
ES2194505T3 ES99945373T ES99945373T ES2194505T3 ES 2194505 T3 ES2194505 T3 ES 2194505T3 ES 99945373 T ES99945373 T ES 99945373T ES 99945373 T ES99945373 T ES 99945373T ES 2194505 T3 ES2194505 T3 ES 2194505T3
Authority
ES
Spain
Prior art keywords
hydrogenation
stage
temperature
hydroxypropanal
hydroxipropanal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES99945373T
Other languages
English (en)
Inventor
Thomas Haas
Bernd Jaeger
Joerg Sauer
Willi Hofen
Rudolf Vanheertum
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Application granted granted Critical
Publication of ES2194505T3 publication Critical patent/ES2194505T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Proceso de producción de 1, 3-propanodiol mediante la hidrogenación catalítica de una solución acuosa de 3-hidroxipropanal, comprendiendo dicho proceso los pasos de: pasar la solución de 3-hidroxipropanal a una primera etapa de hidrogenación e hidrogenar a una temperatura de 30°C a 80°C hasta ser alcanzada una conversión del 3-hidroxipropanal de al menos un 70 % en presencia de un primer catalizador de hidrogenación, comprendiendo el primer catalizador de hidrogenación un primer metal soportado en una fase de óxido; y pasar la solución de reacción obtenida de la primera etapa de hidrogenación a una segunda etapa de hidrogenación e hidrogenar a una temperatura de 80°C a 180°C hasta ser alcanzada una conversión del 3-hidroxipropanal de hasta un 100 % en presencia de un segundo catalizador de hidrogenación que comprende un segundo metal sobre un soporte de carbón activado, siendo la temperatura de hidrogenación de la segunda etapa superior a la temperatura de hidrogenación de la primera etapa.
ES99945373T 1998-09-04 1999-09-01 Proceso de dos fases para la produccion de 1,3-propanodiol por hidrogenacion catalitica de 3-hidroxipropanal. Expired - Lifetime ES2194505T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US9923598P 1998-09-04 1998-09-04

Publications (1)

Publication Number Publication Date
ES2194505T3 true ES2194505T3 (es) 2003-11-16

Family

ID=22273782

Family Applications (1)

Application Number Title Priority Date Filing Date
ES99945373T Expired - Lifetime ES2194505T3 (es) 1998-09-04 1999-09-01 Proceso de dos fases para la produccion de 1,3-propanodiol por hidrogenacion catalitica de 3-hidroxipropanal.

Country Status (16)

Country Link
US (1) US6297408B1 (es)
EP (1) EP1109767B1 (es)
JP (1) JP4328026B2 (es)
KR (1) KR20010073116A (es)
CN (1) CN1178884C (es)
AR (1) AR021793A1 (es)
AT (1) ATE235449T1 (es)
AU (1) AU5798199A (es)
BR (1) BR9913475A (es)
CA (1) CA2339503A1 (es)
DE (1) DE69906316T2 (es)
ES (1) ES2194505T3 (es)
ID (1) ID28941A (es)
TR (1) TR200100678T2 (es)
TW (1) TW575543B (es)
WO (1) WO2000014041A1 (es)

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US20080103217A1 (en) * 2006-10-31 2008-05-01 Hari Babu Sunkara Polyether ester elastomer composition
US7785507B2 (en) 2004-04-30 2010-08-31 E. I. Du Pont De Nemours And Company Spinning poly(trimethylene terephthalate) yarns
US7074969B2 (en) * 2004-06-18 2006-07-11 E.I. Du Pont De Nemours And Company Process for preparation of polytrimethylene ether glycols
US20060041039A1 (en) 2004-08-20 2006-02-23 Gyorgyi Fenyvesi Fluorescent poly(alkylene terephthalate) compositions
US7396896B2 (en) * 2004-12-21 2008-07-08 E.I. Dupont De Nemours And Company Poly(trimethylene terephthalate) composition and shaped articles prepared therefrom
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US7629396B2 (en) 2005-02-23 2009-12-08 E.I. Du Pont De Nemours And Company Silicon-containing polytrimethylene homo- for copolyether composition
US20060189711A1 (en) * 2005-02-23 2006-08-24 Ng Howard C Silicon-containing polytrimethylene homo- or copolyether composition
US7244790B2 (en) * 2005-05-02 2007-07-17 E.I. Du Pont De Nemours And Company Thermoplastic elastomer blend, method of manufacture and use thereof
US20060247378A1 (en) * 2005-05-02 2006-11-02 Sunkara Hari B Thermoplastic elastomer blend, method of manufacture and use thereof
US7157607B1 (en) 2005-08-16 2007-01-02 E. I. Du Pont De Nemours And Company Manufacture of polytrimethylene ether glycol
US7161045B1 (en) 2005-08-16 2007-01-09 E. I. Du Pont De Nemours And Company Process for manufacture of polytrimethylene ether glycol
US7357985B2 (en) * 2005-09-19 2008-04-15 E.I. Du Pont De Nemours And Company High crimp bicomponent fibers
US20070129524A1 (en) * 2005-12-06 2007-06-07 Sunkara Hari B Thermoplastic polyurethanes comprising polytrimethylene ether soft segments
US7666501B2 (en) * 2005-12-07 2010-02-23 E. I. Du Pont De Nemours And Company Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) bi-constituent filaments
US20070128459A1 (en) * 2005-12-07 2007-06-07 Kurian Joseph V Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) films
US20070129503A1 (en) * 2005-12-07 2007-06-07 Kurian Joseph V Poly(trimethylene terephthalate)/poly(alpha-hydroxy acid) molded, shaped articles
US7388115B2 (en) * 2006-01-20 2008-06-17 E. I. Du Pont De Nemours And Company Manufacture of polytrimethylene ether glycol
US7164046B1 (en) 2006-01-20 2007-01-16 E. I. Du Pont De Nemours And Company Manufacture of polytrimethylene ether glycol
US20070203371A1 (en) * 2006-01-23 2007-08-30 Sunkara Hari B Process for producing polytrimethylene ether glycol
TW200732292A (en) * 2006-02-01 2007-09-01 Shell Int Research A method of treating an aldehyde mixture, use of the treated aldehyde, and an alcohol
US20080039582A1 (en) * 2006-07-28 2008-02-14 Hari Babu Sunkara Polytrimethylene ether-based polyurethane ionomers
US7531593B2 (en) * 2006-10-31 2009-05-12 E.I. Du Pont De Nemours And Company Thermoplastic elastomer blend composition
US20080108845A1 (en) * 2006-11-07 2008-05-08 Hari Babu Sunkara Polytrimethylene ether glycol esters
US20080135662A1 (en) * 2006-12-06 2008-06-12 Chang Jing C Melt-spun elastoester multifilament yarns
EP1939243A1 (en) * 2006-12-28 2008-07-02 Borealis Technology Oy Activated carbon as a means to reduce taste and odour from plastic materials
US7714174B2 (en) * 2007-03-27 2010-05-11 E. I. Du Pont De Nemours And Company Lower-color polytrimethylene ether glycol using hydride compounds
WO2009029482A1 (en) * 2007-08-24 2009-03-05 E. I. Du Pont De Nemours And Company Lubrication oil compositions
US8703681B2 (en) 2007-08-24 2014-04-22 E I Du Pont De Nemours And Company Lubrication oil compositions
CN101802149A (zh) * 2007-08-24 2010-08-11 纳幕尔杜邦公司 润滑油组合物
MX2010002157A (es) * 2007-08-24 2010-03-18 Du Pont Composiciones de aceite de lubricacion.
CA2696369A1 (en) * 2007-08-24 2009-03-05 E.I. Du Pont De Nemours And Company Lubrication oil compositions
US7919017B2 (en) * 2007-11-12 2011-04-05 E. I. Du Pont De Nemours And Company Electrical insulation fluids for use in electrical apparatus
US20090163742A1 (en) * 2007-12-19 2009-06-25 Stephen Blake Mullin Heterogeneous promotion of oxirane hydroformylation
KR20100116623A (ko) * 2008-02-19 2010-11-01 캐보트 코포레이션 메조기공성 탄소 블랙 및 그의 제조 방법
US9017837B2 (en) * 2008-02-19 2015-04-28 Cabot Corporation High surface area graphitized carbon and processes for making same
JP2010126448A (ja) * 2008-11-25 2010-06-10 Showa Denko Kk β，γ−不飽和アルコールの水素化反応による飽和アルコールの製造方法
US20100267994A1 (en) * 2009-04-16 2010-10-21 E. I. Du Pont De Nemours And Company Processes for preparing polytrimethylene glycol using ion exchange resins
US20110207972A1 (en) * 2010-02-23 2011-08-25 Battelle Memorial Institute Catalysts and processes for the hydrogenolysis of glycerol and other organic compounds for producing polyols and propylene glycol
US8247526B2 (en) 2010-12-20 2012-08-21 E I Du Pont De Nemours And Company Process for the preparation of polyalkylene ether glycol
US8729316B2 (en) * 2011-02-16 2014-05-20 Halocarbon Products Corporation Process for preparing fluorinated diols
WO2012148849A2 (en) 2011-04-26 2012-11-01 E. I. Du Pont De Nemours And Company Processes for preparing polytrimethylene ether glycol
US8759559B2 (en) 2012-04-18 2014-06-24 E I Du Pont De Nemours And Company Processes for preparing polytrimethylene ether glycol esters
JP6959926B2 (ja) 2016-01-07 2021-11-05 ハルドール・トプサー・アクチエゼルスカベット 糖からエチレングリコールを製造する方法
WO2017118686A1 (en) * 2016-01-07 2017-07-13 Haldor Topsøe A/S Process for the preparation of ethylene glycol from sugars

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DE3926136A1 (de) * 1989-08-08 1991-02-14 Degussa Verfahren zur herstellung von 1,3-propandiol
DE4132663C2 (de) * 1991-10-01 1993-10-14 Degussa Verfahren zum Herstellen von 1,3-Propandiol durch Hydrieren von Hydroxypropionaldehyd
DE4218282A1 (de) * 1992-06-03 1993-12-09 Degussa Verfahren zur Herstellung von 1,3-Propandiol
DE19703383A1 (de) * 1997-01-30 1998-08-06 Degussa Verfahren zur Herstellung von 1,3-Propandiol

Also Published As

Publication number Publication date
DE69906316T2 (de) 2003-12-11
WO2000014041A1 (en) 2000-03-16
AR021793A1 (es) 2002-08-07
JP4328026B2 (ja) 2009-09-09
US6297408B1 (en) 2001-10-02
AU5798199A (en) 2000-03-27
CN1315932A (zh) 2001-10-03
JP2003510246A (ja) 2003-03-18
BR9913475A (pt) 2001-08-14
KR20010073116A (ko) 2001-07-31
DE69906316D1 (de) 2003-04-30
TR200100678T2 (tr) 2001-09-21
EP1109767B1 (en) 2003-03-26
CA2339503A1 (en) 2000-03-16
ATE235449T1 (de) 2003-04-15
TW575543B (en) 2004-02-11
ID28941A (id) 2001-07-19
CN1178884C (zh) 2004-12-08
EP1109767A1 (en) 2001-06-27

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