CN113861762A - UV glaze and preparation method thereof - Google Patents
UV glaze and preparation method thereof Download PDFInfo
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- CN113861762A CN113861762A CN202111196644.9A CN202111196644A CN113861762A CN 113861762 A CN113861762 A CN 113861762A CN 202111196644 A CN202111196644 A CN 202111196644A CN 113861762 A CN113861762 A CN 113861762A
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- photoinitiator
- glaze
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- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000002105 nanoparticle Substances 0.000 claims abstract description 31
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 16
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 16
- 239000004593 Epoxy Substances 0.000 claims abstract description 16
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 13
- 239000011574 phosphorus Substances 0.000 claims abstract description 13
- 239000003085 diluting agent Substances 0.000 claims abstract description 12
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 238000004506 ultrasonic cleaning Methods 0.000 claims description 9
- 238000001132 ultrasonic dispersion Methods 0.000 claims description 6
- 229910007696 ZnSnO4 Inorganic materials 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical group C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 3
- 239000012965 benzophenone Substances 0.000 claims description 3
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 3
- 229910052681 coesite Inorganic materials 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 229910052906 cristobalite Inorganic materials 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 229910052682 stishovite Inorganic materials 0.000 claims description 3
- 229910052905 tridymite Inorganic materials 0.000 claims description 3
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 claims description 2
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims description 2
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 claims description 2
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 9
- 239000003063 flame retardant Substances 0.000 abstract description 9
- 239000000853 adhesive Substances 0.000 abstract description 5
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 238000012360 testing method Methods 0.000 description 11
- 230000006872 improvement Effects 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 230000006378 damage Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910007717 ZnSnO Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229920000587 hyperbranched polymer Polymers 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D15/00—Woodstains
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to the technical field of glaze, in particular to UV glaze and a preparation method thereof, wherein the UV glaze comprises the following components, by mass, 45-60% of hyperbranched phosphorus-containing epoxy acrylic resin, 3-8% of inorganic nanoparticles, 1-2% of a first photoinitiator, 1.5-3% of a second photoinitiator, 30-45% of a reactive diluent and 0.8-1.6% of a leveling agent. The preparation method comprises the following steps: the preparation method comprises the steps of ultrasonically dispersing hyperbranched phosphorus-containing epoxy acrylic resin and a reactive diluent in 500-plus-850W ultrasonic wave for 30-40 minutes, adding inorganic nano particles, ultrasonically dispersing in 800-plus-1000W ultrasonic wave for 15-20 minutes to uniformly disperse the inorganic nano particles, adding a first photoinitiator, a second photoinitiator and a flatting agent, and ultrasonically dispersing in 800-plus-1000W ultrasonic wave for 10-15 minutes to obtain a finished product. The hyperbranched phosphorus-containing epoxy acrylic resin and the inorganic nano-particles are used, so that the flame retardant property is obviously improved. Meanwhile, the wear resistance and the adhesive force of UV glaze are increased. The curing speed is effectively improved through the compatibility of the first photoinitiator and the second photoinitiator.
Description
[ technical field ] A method for producing a semiconductor device
The invention relates to the technical field of glaze, in particular to UV glaze and a preparation method thereof.
[ background of the invention ]
Glaze is a translucent to transparent pigment colorant for woodware, and is formed by dissolving resin in an organic solvent, and the used organic solvent can volatilize into the air in the film forming process and cause harm to the environment and human health. The traditional glaze also has the problems of low drying speed, poor transparency and difficult coloring. The UV glaze mainly comprises oligomer, photoinitiator, reactive diluent and other auxiliary agents, and has the advantages of short curing time, low curing temperature and low volatile component. However, such products generally have the disadvantage of poor flame retardancy, are extremely flammable when exposed to fire, and are prone to property damage and personal safety hazards. Therefore, a UV glaze with good flame retardant property is needed to solve the defects of the existing products.
[ summary of the invention ]
The invention aims to provide UV glaze and a preparation method thereof, which are used for overcoming the defects in the prior art.
In order to achieve the purpose, the invention adopts the following technical scheme:
a UV glaze, characterized by: the composition comprises, by mass, 45-60% of hyperbranched phosphorus-containing epoxy acrylic resin, 3-8% of inorganic nanoparticles, 1-2% of a first photoinitiator, 1.5-3% of a second photoinitiator, 30-45% of an active diluent and 0.8-1.6% of a leveling agent.
As a further improvement of the invention, the UV glaze comprises, by mass, 51-58% of hyperbranched phosphorous epoxy acrylic resin, 4.2-6.5% of inorganic nanoparticles, 1-1.5% of a first photoinitiator, 2-3% of a second photoinitiator, 34-42% of a reactive diluent and 0.8-1.2% of a leveling agent.
As a further improvement of the invention, the inorganic nanoparticles are SiO2Nanoparticles, ZnSnO4At least one or a mixture of two of the nano-particles, wherein the average particle diameter of the inorganic nano-particles is 30-50 nm.
As a further improvement of the invention, the first photoinitiator is one or a mixture of two of 2, 2-dimethoxy-phenyl acetophenone and 1-hydroxycyclohexyl phenyl ketone, and the second photoinitiator is benzophenone.
As a further improvement of the invention, the reactive diluent is one or a mixture of more of tripropylene glycol diacrylate, trimethylolpropane triacrylate, hydroxyethyl acrylate, isobornyl acrylate and N-vinyl pyrrolidone.
As a further improvement of the invention, the levelling agent is a polyether siloxane copolymer.
A preparation method of UV glaze is characterized in that: the preparation method specifically comprises the steps of adding the hyperbranched phosphorus-containing epoxy acrylic resin and the reactive diluent into a beaker, carrying out ultrasonic dispersion in an ultrasonic cleaning machine with the power of 500 plus 850W for 30-40 minutes, adding the inorganic nanoparticles, carrying out ultrasonic dispersion in an ultrasonic cleaning machine with the power of 800 plus 1000W for 15-20 minutes to uniformly disperse the inorganic nanoparticles, adding the first photoinitiator, the second photoinitiator and the leveling agent, and carrying out ultrasonic dispersion in an ultrasonic cleaning machine with the power of 800 plus 1000W for 10-15 minutes to prepare the UV glaze.
Compared with the prior art, the invention has the beneficial effects that:
1. the hyperbranched phosphorus-containing epoxy acrylic resin is used as an oligomer, and the addition amount of the reactive diluent can be reduced by utilizing the advantages of low viscosity and high compatibility of the hyperbranched polymer. In addition, compared with epoxy acrylic resin, the phosphorus-containing epoxy acrylic resin is used, so that the flame retardant property is obviously improved. The hyperbranched phosphorus-containing epoxy acrylic resin can form an expanded carbon layer after being burnt during burning, so that the hyperbranched phosphorus-containing epoxy acrylic resin plays a role in blocking temperature and oxygen, and the flame retardant property is improved.
2. Inorganic nanoparticles also have a flame-retardant effect, ZnSnO4Zn and Sn ions in the catalyst have the function of catalyzing polymer to form carbon in the polymer combustion process, and SiO2The nano particles can form a barrier layer on the surface of the carbon layer during combustion, and the flame retardant property can be effectively improved under the combined action of the nano particles and the carbon layer. The addition of the inorganic nano-particles also increases the wear resistance and adhesive force of UV glaze.
3. The first photoinitiator and the second photoinitiator have different characteristic absorption wavelengths, and the curing speed is effectively improved through compatibility.
[ detailed description ] embodiments
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments. It is to be understood that the described embodiments are merely exemplary of the invention, and not restrictive of the full scope of the invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The reagents used in the following examples are, unless otherwise specified, commercially available in a conventional manner.
Example 1
Adding 550g of hyperbranched phosphorus-containing epoxy acrylic resin and 352g of trimethylolpropane triacrylate into a beaker, ultrasonically dispersing for 30-40 minutes in a 500-850W ultrasonic cleaning machine, and adding 24.5g of SiO with the average particle size of 30-50 nm2Nanoparticles and 24.5g ZnSnO with the average particle size of 30-50 nm4And ultrasonically dispersing the nano particles in an ultrasonic cleaning machine of 800-1000W for 15-20 minutes to uniformly disperse the inorganic nano particles, adding 10g of 1-hydroxycyclohexyl phenyl ketone, 30g of benzophenone and 9g of polyether siloxane copolymer, and ultrasonically dispersing in the ultrasonic cleaning machine of 800-1000W for 10-15 minutes to prepare the UV Grice.
Examples 2 to 8
The UV glaze of examples 2 to 8 was prepared in the same manner as in example 1, and the weight ratios of the components thereof are shown in Table 1.
TABLE 1 compositions of examples 2 to 8 and their mass ratios (g)
Remarking: in Table 1, the symbol "\" indicates none.
Example 9 Performance testing
Respectively carrying out performance test on the UV glaze prepared in the embodiments 1-8, wherein the test items comprise: hardness test, adhesion test, wear resistance test and flame retardant property test. The hardness test method is based on GB/T6739-2006 paint film hardness determination by color paint and varnish pencil method. The adhesive force test method is based on GB/T4893.4-2013 part 4 of furniture surface paint film physical and chemical property test, adhesive force cross cutting determination. The method for testing the wear resistance is based on GB/T4893.4-2013 part 8 of furniture surface paint film physical and chemical property test, namely a method for testing the wear resistance. The test method of the flame retardant property is based on GB/T8624 and 2012 'grading of the combustion performance of building materials and products'.
Table 2 results of flame retardancy test of examples 1 to 8
The hyperbranched phosphorus-containing epoxy acrylic resin is used as an oligomer, and SiO with the average particle size of 30-50 nm is added2Nanoparticles and ZnSnO4The nano particles improve the flame retardant property of UV glaze. SiO22Nanoparticles and ZnSnO4The addition of the nano particles also enhances the adhesive force and the wear resistance of the UV glaze.
Claims (7)
1. A UV glaze, characterized by: the composition comprises, by mass, 45-60% of hyperbranched phosphorus-containing epoxy acrylic resin, 3-8% of inorganic nanoparticles, 1-2% of a first photoinitiator, 1.5-3% of a second photoinitiator, 30-45% of an active diluent and 0.8-1.6% of a leveling agent.
2. A UV glaze according to claim 1 wherein: the UV glaze comprises, by mass, 51-58% of hyperbranched phosphorous epoxy acrylic resin, 4.2-6.5% of inorganic nanoparticles, 1-1.5% of a first photoinitiator, 2-3% of a second photoinitiator, 34-42% of a reactive diluent and 0.8-1.2% of a leveling agent.
3. A UV glaze according to claim 1 wherein: the inorganic nano-particles are at least one or a mixture of two of SiO2 nano-particles and ZnSnO4 nano-particles, and the average particle size of the inorganic nano-particles is 30-50 nm.
4. A UV glaze according to claim 1 wherein: the first photoinitiator is one or a mixture of two of 2, 2-dimethoxy-phenyl acetophenone and 1-hydroxycyclohexyl phenyl ketone, and the second photoinitiator is benzophenone.
5. A UV glaze according to claim 1 wherein: the active diluent is one or a mixture of more of tripropylene glycol diacrylate, trimethylolpropane triacrylate, hydroxyethyl acrylate, isobornyl acrylate and N-vinyl pyrrolidone.
6. A UV glaze according to claim 1 wherein: the leveling agent is polyether siloxane copolymer.
7. A preparation method of UV glaze is characterized in that: the preparation method specifically comprises the steps of adding the hyperbranched phosphorus-containing epoxy acrylic resin and the reactive diluent into a beaker, carrying out ultrasonic dispersion in an ultrasonic cleaning machine with the power of 500 plus 850W for 30-40 minutes, adding the inorganic nanoparticles, carrying out ultrasonic dispersion in an ultrasonic cleaning machine with the power of 800 plus 1000W for 15-20 minutes to uniformly disperse the inorganic nanoparticles, adding the first photoinitiator, the second photoinitiator and the leveling agent, and carrying out ultrasonic dispersion in an ultrasonic cleaning machine with the power of 800 plus 1000W for 10-15 minutes to prepare the UV glaze.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111196644.9A CN113861762A (en) | 2021-10-14 | 2021-10-14 | UV glaze and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111196644.9A CN113861762A (en) | 2021-10-14 | 2021-10-14 | UV glaze and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113861762A true CN113861762A (en) | 2021-12-31 |
Family
ID=78999599
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111196644.9A Pending CN113861762A (en) | 2021-10-14 | 2021-10-14 | UV glaze and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113861762A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101100583A (en) * | 2007-07-26 | 2008-01-09 | 常州光辉化工有限公司 | High-adhesion ultraviolet radiation polyurethane double-solidifying carpentry paint and preparation method thereof |
| US20120115975A1 (en) * | 2010-11-05 | 2012-05-10 | Kania Charles M | UV-Curable Coating Compositions, Multi-Component Composite Coatings, and Related Coated Substrates |
| CN105585942A (en) * | 2016-01-26 | 2016-05-18 | 湖南罗比特化学材料有限公司 | UV cured transparent and flame-retardant coating |
| CN106497362A (en) * | 2016-10-09 | 2017-03-15 | 三棵树涂料股份有限公司 | A kind of low abnormal smells from the patient easily rubs UV glazes and preparation method thereof |
| US20180134904A1 (en) * | 2015-05-21 | 2018-05-17 | Sun Chemical Corporation | Superhydrophobic uv curable coating |
| CN109096891A (en) * | 2018-08-16 | 2018-12-28 | 苏州达同新材料有限公司 | A kind of ultraviolet light solidification high rigidity woodwork coating and preparation method thereof |
-
2021
- 2021-10-14 CN CN202111196644.9A patent/CN113861762A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101100583A (en) * | 2007-07-26 | 2008-01-09 | 常州光辉化工有限公司 | High-adhesion ultraviolet radiation polyurethane double-solidifying carpentry paint and preparation method thereof |
| US20120115975A1 (en) * | 2010-11-05 | 2012-05-10 | Kania Charles M | UV-Curable Coating Compositions, Multi-Component Composite Coatings, and Related Coated Substrates |
| US20180134904A1 (en) * | 2015-05-21 | 2018-05-17 | Sun Chemical Corporation | Superhydrophobic uv curable coating |
| CN105585942A (en) * | 2016-01-26 | 2016-05-18 | 湖南罗比特化学材料有限公司 | UV cured transparent and flame-retardant coating |
| CN106497362A (en) * | 2016-10-09 | 2017-03-15 | 三棵树涂料股份有限公司 | A kind of low abnormal smells from the patient easily rubs UV glazes and preparation method thereof |
| CN109096891A (en) * | 2018-08-16 | 2018-12-28 | 苏州达同新材料有限公司 | A kind of ultraviolet light solidification high rigidity woodwork coating and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 欧育湘等: "《阻燃剂》", 30 September 2009, 国防工业出版社 * |
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Application publication date: 20211231 |
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