CN103450795A - Ultraviolet-curing fireproof flame-retardant wood paint and preparation method thereof - Google Patents
Ultraviolet-curing fireproof flame-retardant wood paint and preparation method thereof Download PDFInfo
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- CN103450795A CN103450795A CN2013104221564A CN201310422156A CN103450795A CN 103450795 A CN103450795 A CN 103450795A CN 2013104221564 A CN2013104221564 A CN 2013104221564A CN 201310422156 A CN201310422156 A CN 201310422156A CN 103450795 A CN103450795 A CN 103450795A
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Abstract
The invention discloses an ultraviolet-curing fireproof flame-retardant wood paint and a preparation method thereof. Flame retardant mechanisms are introduced: the flame retardant performs the flame-retardant action through a plurality of mechanisms, including heat absorbing action, covering action, chain reaction inhibition, suffocation of non-inflammable gas and the like; the coating being combusted is converted into an expansion barrier layer; the carburization layer formed under the conditions of isolation of heat and air in the early combustion stage can isolate the substrate from flame, thereby protecting the substrate from combustion.
Description
Technical field
The present invention relates to the woodwork coating technical field, particularly relate to a kind of ultraviolet photo-curing fire protection flame retarding woodwork coating and preparation method thereof.
Background technology
The paint of furniture industry life-time service is mainly conventional solvent type PU, PE, NC etc., and by spraying application, efficiency is low, and cost is high, contaminate environment, affects workmen's health; In addition, the solvent based coating paint contains inflammable, explosive, organic volatile solvent (as hazardous substance such as toluene, acetone, vinyl acetic monomer solidifying agent) brings fire hazard to manufacturing concern simultaneously; Product after the solvent based coating film forming does not have the function of fire protection flame retarding, meets spark and very easily burns, and causes user's personal injury.
Summary of the invention
In order to overcome above-mentioned the deficiencies in the prior art, the invention provides a kind of ultraviolet photo-curing fire protection flame retarding woodwork coating and preparation method thereof to solve the shortcoming that conventional solvent type woodwork coating is inflammable, explosive, contain poisonous and harmful organic volatile solvent.
The object of the invention can be achieved through the following technical solutions:
A kind of ultraviolet photo-curing fire protection flame retarding woodwork coating following various starting material, consist of, and each part all has fixing weight:
| Sequence number | Material name | The component ratio |
| 1 | Aliphatic polyurethane vinylformic acid | 243g |
| 2 | Tripropylene glycol class diacrylate | 200g |
| 3 | Pentaerythritol triacrylate | 150g |
| 4 | Phenol aldehyde modified epoxy acrylic | 145g |
| 5 | Aluminium hydroxide | 100g |
| 6 | 1-hydroxyl alkane is the base benzophenone | 50g |
| 7 | Matting agent | 80g |
| 8 | Fire retardant | 10g |
| 9 | Dispersion agent | 5g |
| 10 | Anti-settling agent | 5g |
| 11 | The wax powder | 5g |
| 12 | Defoamer | 3g |
| 13 | Flow agent | 2g |
| 14 | Reactive amines | 2g |
As preferably, aliphatic polyurethane propylene prepolymer is containing 2 functional groups, and the prepolymer molecular weight is 20000-25000 dalton, sour viscosity 25000 ± 100cps/25 ℃, solid content 95-100%.
As preferably, phenol aldehyde modified epoxy acrylic prepolymer contains 2 functional groups, the prepolymer molecular weight in 20000-30000 dalton, epoxy acrylic viscosity at 20000 ± 100cps/25 ℃, solid content 95-100%.
As preferably, tripropylene glycol diacrylate is that reactive monomer contains 2 functional groups.
As preferably, pentaerythritol triacrylate is that reactive monomer contains 3 functional groups, solid content is 95-100%, contains sticking power and toughness that the OH hydroxyl bond increases paint film and base material.
As preferably, described aluminium hydroxide is selected the Powdered crystal of WA-400 model appearance white, fineness is 15um, inclusion Al (OH) 3 does not have, less on Light Curing impact, be applicable to being applied to photo-cured coating aluminium hydroxide as fire retardant, can be fire-retardant, and can prevent from being fuming, do not produce dropping, do not produce toxic gas.
As preferably, 1-hydroxyl alkane base benzophenone is cracking type free radical photo-initiation, white lens, and λ max is at 246nm, 280nm, 330nm.
As preferably, this woodwork coating needs following additive:
(1) flatting silica is selected OK500, be surface through organic process precipitated silica flatting silica, there is easy dispersion, extinction is good, transparency is good, increase slipping and suspension, the agglomerate grain is rolled into a ball big or small 3um, oil number, 260g/100m, proportion 1.9g/cm;
(2) fire retardant is selected vinylformic acid pentabromo-benzyl ester, it is a kind of use range wide spectrum additive flame retardant widely, white powder, its bromine content are high, Heat stability is good, anti-ultraviolet property is good, vinylformic acid pentabromo-benzyl ester (PBBA) has reactive thinner and fire retardant function concurrently, little on the photo-curing rate impact;
(3) dispersion agent is wettability TEGO685 dispersion agent, and wetting dispersing agent for radiation curable coating, is applicable to pigment concentrate slurry and common grinding, and is applicable to height and is admittedly disperseed containing in coating, carbon black and pigment dyestuff;
(4) anti-settling agent is Cabot CAB-O-SIL M-5, it is the non-processing type of a kind of medium surface-area aerosil, significantly the viscosity of enhance liquid system, Cabot CAB-O-SIL M-5 can obtain rheology control for liquid system, solid suspension, the effect of anti-rheology, can improve enhancement for solid system, Cabot CAB-O-SIL M-5 provides good unrestricted flow for the powder system and prevents the effects such as caking;
(5) the wax powder is selected the polytetrafluoroethylmodified modified wax of chemical 9610F, its fineness is 3um, active part 100%, fluorine content 10%, and the surface smoothness feel is provided, and paint film is had to scratch resistance, antifouling, wear-resisting effect, antiseized protection effect, water resistant and the waterproof ability of raising paint film;
(6) defoamer is that chemical BYK141 defoamer, chemical constitution have the good bubble effect that presses down for breaking bubble polymkeric substance and siloxane solution;
(7) flow agent is chemical TEGO450, Chemical Composition polyether siloxane copolymer 100% active substance content, improves the film coated surface scratch resistance and smooth feel is provided;
(8) reactive amines is chemical RAP115 reactive amine aided initiating, with the good consistency of acryloxy, low smell, can participate in again crosslinkedly, can not move, and there is stronger absorption λ max310nm ultraviolet region.
9. the preparation method of a ultraviolet photo-curing fire protection flame retarding woodwork coating comprises the following steps:
(1) first light trigger 1-hydroxyl alkane base benzophenone 50g and tripropylene glycol diacrylate 200g pentaerythritol triacrylate 150g are dropped in advance in the experiment cup and stir, control speed is 1000r/min; Stir and splash into successively after 10 minutes again: TEGO685 dispersion agent 5g, BYK141 defoamer 3g, flow agent 2g, reactive amines 2g, in cup, disperse after adding to stir in 5 minutes in advance; Add successively the more phenol aldehyde modified epoxy acrylic 145g of prepolymer and aliphatic urethane acrylate 243g, added the fast 1200r/min of rear control, disperse to stir 10 minutes;
(2) disperseed slowly to add successively powder in rear cup, then add TDE 10g, add antimonous oxide 100g, add flatting silica 80g, add wax powder 5g and anti-settling agent 5g, above powder is controlled fast 1500r/min after slowly adding successively in cup, disperses 45 minutes; Detecting paint liquid fineness is 25um, and paint fluid viscosity rotary viscosity is 800 ± 100mpas/25 ℃, ultraviolet curing energy: 380-450mj/cm 2.
As preferably, ultraviolet photo-curing coating need impel decomposition of initiator under the irradiation that be 260-450nm at ultraviolet wavelength, produces free radical, causes the resin reaction, the instantaneous solidification film forming.
With conventional solvent type coating, compare, ultraviolet photo-curing coating is containing organic solvent flashing, directly constructing operation application, the application mode: roller coat, showering, spraying, can mechanical application circulation painting operation, greatly improve enterprises production efficiency.
The present invention utilize bromide fire retardant and aluminium hydroxide noninflammable material introduce paint film after ultraviolet coating, film curing film forming to fire prevention, fire-retardant effect is clearly arranged, the family of manufacturing concern and end product is reduced to fire hazard, introduce fluorine-containing wax powder and reduce the coating surface frictional coefficient.
Embodiment
Below in conjunction with concrete 4 embodiment, the present invention is described in detail.
A kind of ultraviolet photo-curing fire protection flame retarding woodwork coating, the raw material of this ultraviolet photo-curing wood lacquer comprises following composition and weight.
| Sequence number | The starting material title | Deal is than example 1 | Deal is than example 2 | Deal is than example 3 | Deal is than example 4 |
| 1、 | Phenol aldehyde modified epoxy acrylic | 145g | 145g | 145g | 145g |
| 2、 | Aliphatic polyurethane vinylformic acid | 243g | 243g | 243g | 243g |
| 3、 | 1-hydroxyl alkane is the base benzophenone | 50g | 50g | 50g | 50g |
| 4、 | Tripropylene glycol class diacrylate | 200g | 223g | 257g | 284g |
| 5、 | Pentaerythritol triacrylate | 150g | 150g | 1500g | 150g |
| 6、 | Fire retardant | 10g | 7g | 3g | 1g |
| 7、 | Dispersion agent | 5g | 5g | 5g | 5g |
| 8、 | Defoamer | 3g | 3g | 3g | 3g |
| 9、 | Flow agent | 2g | 2g | 2g | 2g |
| 10、 | Reactive amines | 2g | 2g | 2g | 2g |
| 11、 | Anti-settling agent | 5g | 5g | 5g | 5g |
| 12、 | Aluminium hydroxide | ?100g | 80g | 50g | 25g |
| 13、 | Flatting silica | 80g | 80g | 80g | 80g |
| 14、 | The wax powder | 5g | 5g | 5g | 5g |
First light trigger 1-hydroxyl alkane base benzophenone 50g and tripropylene glycol diacrylate 200g pentaerythritol triacrylate 150g are dropped in advance in the experiment cup and stir, control speed is 1000r/min; Stir and splash into successively after 10 minutes again: TEGO685 dispersion agent 5g, BYK141 defoamer 3g, flow agent 2g, reactive amines 2g, in cup, disperse after adding to stir in 5 minutes in advance; Add successively the more phenol aldehyde modified epoxy acrylic 145g of prepolymer and aliphatic urethane acrylate 243g, added the fast 1200r/min of rear control, disperse to stir 10 minutes; Disperseed slowly to add successively powder in rear cup, then add TDE 10g, add antimonous oxide 100g, add flatting silica 80g, add wax powder 5g and anti-settling agent 5g, after above powder slowly adds in cup successively, control fast 1500r/min, disperse 45 minutes, obtain a kind of ultraviolet photo-curing fire protection flame retarding wood lacquer.
Use this ultraviolet ray coating operating procedure brain to comprise: roller coat, spraying, showering application.
The wide 40cm thickness of the long 30cm x of oak material specification 1.5cm, coating process are accompanied by lower form:
| Sequence number | Ultraviolet ray coating lacquer kind | Glue spread | The photocuring energy | Sanding |
| 1、 | UV compound type transparent putty priming paint | 25±2g/m2 | ≥120mj/cm2 | The sanding of 240# sand paper |
| 2、 | The UV transparent priming | 15±2g/m2 | ≥60mj/cm2 | Exempt from sanding |
| 3、 | The UV transparent priming | 15±2g/m2 | ≥120mj/cm2 | The 240# sanding |
| 4、 | The UV transparent priming | 15±2g/m2 | ≥60mj/cm2 | Exempt from sanding |
| 5、 | The UV transparent priming | 15±2g/m2 | ≥120mj/cm2 | The 240# sanding |
| 6、 | Ultraviolet curing fire protection flame retarding woodwork coating | 10±2g/m2 | ≥60mj/cm2 | Exempt from sanding |
| 7、 | Ultraviolet curing fire protection flame retarding woodwork coating | 10±2g/m2 | ≥460mj/cm2 | Complete solidifying |
One UV compound type transparent putty of above oak material technique application, 4 road UV transparent primings, 2 road ultraviolet photo-curing fire protection flame retarding woodwork coatings, same coating process have been done respectively 4 application example laboratory contrasts, and after film-forming, application sheet material is done following performance test.
(1) sticking power test: with drawing the pattern of lattice device at 100 1mmx1mm of coating surface of coated substrate, the scotch tape even die attach that the model of producing with Minnesota Mining and Manufacturing Company is 600 is attached on grid, then with the fastest speed, vertically uncover and observe the cut edge and whether have or not pull-away, as the depainting amount between 0-5%, be between 5B, 5-10% for 4B, between 10-20 for 3B, between 20-30 for 2B, between 30-50 for B, more than 50%, be 0B.
(2) hardness test: with reference to GB GB/T6739-1996 (hardness of film pencil assay method), with 3H Mitsubishi pencil, pencil sharper is held to pencil and made it with 400# waterproof abrasive paper, become an angle of 90 degrees to exposing cylindrical lead for retractable pencil 3mm length left and right (attention can not damage pen core), do not stop to draw circle with friction pen core end face on sand paper, be contained in that on special-purpose pencil hardness tester device, (load be applied on nib is 1KG until obtain the lead for retractable pencil that the end face flat edges is sharp keen (edge must not breakage and breach), the angle of pencil and level is 45 °) promote pencil to front slide 5mm length, draw altogether 5 (different positionss) again with eraser by plumbous trace wiped clean, see if there is the broken trace of paint film, seamless breaking as qualified.
(3) RCA wearability test: wear resistance is the degree that paint film is wear-resisting, and wear resistance is actually the embodiment of hardness of film, sticking power and force of cohesion combined effect, adopts the emery wheel abrasion instrument to measure the wear resistance of filming, and the higher explanation wear resistance of abradability is poorer.
(4) fixed temperature and humidity test: product is placed under the constant-temperature constant-humidity environment of 70 ± 2 ℃ of temperature, humidity 93 ± 2 and deposits 48h, placing 2h after having tested under normal temperature environment observes outward appearance and test paint film adhesion, criterion: product surface is qualified without variable color, crackle, bubble, peeling paint phenomenon.
(5) impact strength test: impact strength mean to film the cracking resistance that can stand when external impacts or resist with base material between the ability of separating, the impact strength of filming adopts impact tester to measure, and refers to the GB1732-79(shock-resistant assay method of filming).
(6) chemical resistance: chemical resistance refer to film the ability, the measuring method that stand chemical corrosion medium (acid, alkali, salt solution) will film invade in the regulation medium while reaching standard code after, take out that observing films and whether have or not peel off, the images such as bubble, variable color, loss of gloss.
(7) oxygen index method of fire protection flame retarding test material: the test portion of some amount size is put into to special container, by being full of nitrogen, start, progressively input oxygen, under different oxygen contents, with prescribed manner, light a fire, oxygen content in the time of just having made the interior test portion generation smooth combustion of container just is called the oxygen index of material, and oxygen index is higher, and the illustrative material flame retardancy is better.
(8) weathering resistance test: the weathering resistance test is paint film under field conditions (factors) or under simulating natural condition, coating weatherability and observe paint film whether the degree such as loss of gloss, variable color, efflorescence, crackle, bubble are arranged.
The examination criteria of a kind of ultraviolet photo-curing fire protection flame retarding woodwork coating after according to the making sheet of company standard regulation
Claims (10)
1. a ultraviolet photo-curing fire protection flame retarding woodwork coating, be comprised of following various starting material, and each part all have fixing weight, and its characteristics are:
。
2. ultraviolet photo-curing fire protection flame retarding woodwork coating according to claim 1, its characteristics are, described aliphatic polyurethane propylene prepolymer is containing 2 functional groups, and the prepolymer molecular weight is 20000-25000 dalton, sour viscosity 25000 ± 100cps/25 ℃, solid content 95-100%.
3. ultraviolet photo-curing fire protection flame retarding woodwork coating according to claim 1, its characteristics are, described phenol aldehyde modified epoxy acrylic prepolymer contains 2 functional groups, the prepolymer molecular weight in 20000-30000 dalton, epoxy acrylic viscosity at 20000 ± 100cps/25 ℃, solid content 95-100%.
4. ultraviolet photo-curing fire protection flame retarding woodwork coating according to claim 1, its characteristics are, described tripropylene glycol diacrylate is that reactive monomer contains 2 functional groups.
5. ultraviolet photo-curing fire protection flame retarding woodwork coating according to claim 1, its characteristics are, pentaerythritol triacrylate is that reactive monomer contains 3 functional groups, solid content is 95-100%, contains sticking power and toughness that the OH hydroxyl bond increases paint film and base material.
6. ultraviolet photo-curing fire protection flame retarding woodwork coating according to claim 1, its characteristics are, described aluminium hydroxide is selected the Powdered crystal of WA-400 model appearance white, fineness is 15um, inclusion Al (OH) 3 does not have, less on Light Curing impact, be applicable to being applied to photo-cured coating aluminium hydroxide as fire retardant, can be fire-retardant, and can prevent from being fuming, do not produce dropping, do not produce toxic gas.
7. ultraviolet photo-curing fire protection flame retarding woodwork coating according to claim 1, its characteristics are, and 1-hydroxyl alkane base benzophenone is cracking type free radical photo-initiation, white lens, and λ max is at 246nm, 280nm, 330nm.
8. ultraviolet photo-curing fire protection flame retarding woodwork coating according to claim 1, its characteristics are, this woodwork coating needs following additive:
(1) flatting silica is selected OK500, be surface through organic process precipitated silica flatting silica, there is easy dispersion, extinction is good, transparency is good, increase slipping and suspension, the agglomerate grain is rolled into a ball big or small 3um, oil number, 260g/100m, proportion 1.9g/cm;
(2) fire retardant is selected vinylformic acid pentabromo-benzyl ester, it is a kind of use range wide spectrum additive flame retardant widely, white powder, its bromine content are high, Heat stability is good, anti-ultraviolet property is good, vinylformic acid pentabromo-benzyl ester (PBBA) has reactive thinner and fire retardant function concurrently, little on the photo-curing rate impact;
(3) dispersion agent is wettability TEGO685 dispersion agent, and wetting dispersing agent for radiation curable coating, is applicable to pigment concentrate slurry and common grinding, and is applicable to height and is admittedly disperseed containing in coating, carbon black and pigment dyestuff;
(4) anti-settling agent is Cabot CAB-O-SIL M-5, it is the non-processing type of a kind of medium surface-area aerosil, significantly the viscosity of enhance liquid system, Cabot CAB-O-SIL M-5 can obtain rheology control for liquid system, solid suspension, the effect of anti-rheology, can improve enhancement for solid system, Cabot CAB-O-SIL M-5 provides good unrestricted flow for the powder system and prevents the effects such as caking;
(5) the wax powder is selected the polytetrafluoroethylmodified modified wax of chemical 9610F, its fineness is 3um, active part 100%, fluorine content 10%, and the surface smoothness feel is provided, and paint film is had to scratch resistance, antifouling, wear-resisting effect, antiseized protection effect, water resistant and the waterproof ability of raising paint film;
(6) defoamer is that chemical BYK141 defoamer, chemical constitution have the good bubble effect that presses down for breaking bubble polymkeric substance and siloxane solution;
(7) flow agent is chemical TEGO450, Chemical Composition polyether siloxane copolymer 100% active substance content, improves the film coated surface scratch resistance and smooth feel is provided;
(8) reactive amines is chemical RAP115 reactive amine aided initiating, with the good consistency of acryloxy, low smell, can participate in again crosslinkedly, can not move, and there is stronger absorption λ max310nm ultraviolet region.
9. the preparation method of a ultraviolet photo-curing fire protection flame retarding woodwork coating comprises the following steps:
(1) first light trigger 1-hydroxyl alkane base benzophenone 50g and tripropylene glycol diacrylate 200g pentaerythritol triacrylate 150g are dropped in advance in the experiment cup and stir, control speed is 1000r/min; Stir and splash into successively after 10 minutes again: TEGO685 dispersion agent 5g, BYK141 defoamer 3g, flow agent 2g, reactive amines 2g, in cup, disperse after adding to stir in 5 minutes in advance; Add successively the more phenol aldehyde modified epoxy acrylic 145g of prepolymer and aliphatic urethane acrylate 243g, added the fast 1200r/min of rear control, disperse to stir 10 minutes;
(2) disperseed slowly to add successively powder in rear cup, then add TDE 10g, add antimonous oxide 100g, add flatting silica 80g, add wax powder 5g and anti-settling agent 5g, above powder is controlled fast 1500r/min after slowly adding successively in cup, disperses 45 minutes; Detecting paint liquid fineness is 25um, and paint fluid viscosity rotary viscosity is 800 ± 100mpas/25 ℃, ultraviolet curing energy: 380-450mj/cm 2.
10. the preparation method of ultraviolet photo-curing fire protection flame retarding woodwork coating according to claim 9, its characteristics are, ultraviolet photo-curing coating need impel decomposition of initiator under the irradiation that be 260-450nm at ultraviolet wavelength, produce free radical, cause the resin reaction, the instantaneous solidification film forming.
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| CN104312423A (en) * | 2014-11-07 | 2015-01-28 | 广东希贵光固化材料有限公司 | UV (ultraviolet) curing flame-retardant coating |
| CN105131673A (en) * | 2015-09-14 | 2015-12-09 | 上海应用技术学院 | Ultraviolet curing flame retardant primer coating and preparation method thereof |
| CN105778752A (en) * | 2016-03-25 | 2016-07-20 | 无锡南理工科技发展有限公司 | Preparation method of photocuring flame resistant water-borne coating |
| CN105778751A (en) * | 2016-03-25 | 2016-07-20 | 无锡南理工科技发展有限公司 | Ultraviolet-curing flame-retardant water-based coating |
| CN107880767A (en) * | 2017-12-20 | 2018-04-06 | 广东德新科技孵化器有限公司 | A kind of scrubbable ultraviolet-cured furniture coating and preparation method thereof |
| CN108977055A (en) * | 2018-08-07 | 2018-12-11 | 太仓佩琦涂料有限公司 | Can ultraviolet identification photocuring fluorescence falsification preventing coating and preparation method thereof |
| CN111205762A (en) * | 2020-02-26 | 2020-05-29 | 成都迪泰化工有限公司 | Novel UV flame-retardant coating and preparation method thereof |
| CN116426206A (en) * | 2023-02-15 | 2023-07-14 | 湖北航天化学新材料科技有限公司 | Skin-feel coating with flame-retardant function, and preparation method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105131673A (en) * | 2015-09-14 | 2015-12-09 | 上海应用技术学院 | Ultraviolet curing flame retardant primer coating and preparation method thereof |
| CN105778752A (en) * | 2016-03-25 | 2016-07-20 | 无锡南理工科技发展有限公司 | Preparation method of photocuring flame resistant water-borne coating |
| CN105778751A (en) * | 2016-03-25 | 2016-07-20 | 无锡南理工科技发展有限公司 | Ultraviolet-curing flame-retardant water-based coating |
| CN107880767A (en) * | 2017-12-20 | 2018-04-06 | 广东德新科技孵化器有限公司 | A kind of scrubbable ultraviolet-cured furniture coating and preparation method thereof |
| CN108977055A (en) * | 2018-08-07 | 2018-12-11 | 太仓佩琦涂料有限公司 | Can ultraviolet identification photocuring fluorescence falsification preventing coating and preparation method thereof |
| CN111205762A (en) * | 2020-02-26 | 2020-05-29 | 成都迪泰化工有限公司 | Novel UV flame-retardant coating and preparation method thereof |
| CN116426206A (en) * | 2023-02-15 | 2023-07-14 | 湖北航天化学新材料科技有限公司 | Skin-feel coating with flame-retardant function, and preparation method and application thereof |
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Application publication date: 20131218 |