CN111015840A - Preparation method of environment-friendly impregnated paper facing artificial board - Google Patents
Preparation method of environment-friendly impregnated paper facing artificial board Download PDFInfo
- Publication number
- CN111015840A CN111015840A CN201911297109.5A CN201911297109A CN111015840A CN 111015840 A CN111015840 A CN 111015840A CN 201911297109 A CN201911297109 A CN 201911297109A CN 111015840 A CN111015840 A CN 111015840A
- Authority
- CN
- China
- Prior art keywords
- impregnated paper
- artificial board
- paper
- parts
- environment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27D—WORKING VENEER OR PLYWOOD
- B27D1/00—Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27D—WORKING VENEER OR PLYWOOD
- B27D1/00—Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring
- B27D1/04—Joining wood veneer with any material; Forming articles thereby; Preparatory processing of surfaces to be joined, e.g. scoring to produce plywood or articles made therefrom; Plywood sheets
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/10—Homopolymers or copolymers of methacrylic acid esters
- C09J133/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/21—Paper; Textile fabrics
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Laminated Bodies (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
A method for preparing an environment-friendly impregnated paper veneer artificial board comprises base paper printed with an ink pattern layer, an emulsion type transparent upper primer layer and a lower primer layer attached to the upper and lower surfaces of the base paper, an emulsion type transparent surface adhesive attached to the surface of the upper primer layer of the base paper and an artificial board taking impregnated paper as a veneer material. The environment-friendly impregnated paper adhesive disclosed by the invention has the advantages that the emulsion type impregnating solution is used for replacing the traditional formaldehyde glue as the primer and the face glue, so that the prepared impregnated paper and the artificial board with the veneer thereof not only have long-term environment-friendly performance, but also have safe and low-pollution preparation process, low raw material cost, high transmittance of a product glue film, excellent wear resistance and wide application range, and have huge social and economic values.
Description
Technical Field
The invention relates to the technical field of artificial veneers, in particular to an environment-friendly impregnated paper veneer artificial plate and a preparation method thereof.
Background
In recent years, as people pursue green and healthy life increasingly, interior decoration tends to be made of wood decoration materials, including various artificial boards, and the wood decoration materials need to be subjected to necessary surface decoration in most cases. Resin impregnated paper (referred to as "impregnated paper") is a kind of facing material of artificial board, which accounts for the largest total consumption of decorative materials in the world, and is obtained by impregnating plain color paper or printing decorative paper with appropriate resin and then drying to a certain degree, and not only has a certain resin adhesive, but also can be glued with artificial board base materials after hot pressing, and is commonly used for facing various boards such as fiber boards, plywood boards or shaving boards. Compared with other facing materials, the impregnated paper has the advantages of simple operation process, beautiful patterns, low price, excellent surface performance and the like. At present, the glue solution commonly used for impregnated paper is melamine formaldehyde resin, urea formaldehyde resin and phenolic resin (collectively called as 'three-aldehyde glue'), has the problems of short storage period and serious release of formaldehyde and other Volatile Organic Compounds (VOCs), and poses great threat to human health and ecological environment. The emulsion type impregnating solution has the advantages of good storage stability (the storage period is up to 1 year or longer), cost saving and resource waste reduction, and the system generally takes water as a solvent, does not volatilize formaldehyde or toxic organic solvents, can keep the concentration of the impregnating solution stable, is safe and environment-friendly, is easy to regulate and control the reaction temperature, and can effectively avoid the influence caused by the formaldehyde-formaldehyde glue.
Disclosure of Invention
The technical problem to be solved is as follows: in order to overcome the defects and shortcomings in the prior art, the invention aims to provide the environment-friendly impregnated paper veneer artificial board which is good in wear resistance, the impregnated paper is tightly attached to an artificial board, glue solution used by the impregnated paper is safe, environment-friendly and easy to store, the transparency of a glue layer is high, the preparation process is safe and simple, the cost is low, and the environment-friendly impregnated paper veneer artificial board conforms to the environment-friendly idea advocated at present.
The technical scheme is as follows: a preparation method of an environment-friendly impregnated paper facing artificial board is characterized by comprising the following steps: the artificial board comprises base paper printed with an ink pattern layer, an emulsion type transparent upper primer layer and a lower primer layer attached to the upper surface and the lower surface of the base paper, an emulsion type transparent surface adhesive attached to the surface of the base paper upper primer layer and an artificial board taking impregnated paper as a facing material, wherein the lower primer layer of the impregnated paper is attached to the surface of the artificial board, and the facing artificial board is prepared by sequentially laminating the base paper impregnated primer, the base paper impregnated surface adhesive and the impregnated paper through hot pressing.
The base paper has a mass of 65 to 130g/m2The mass of the impregnated paper pasted with the base glue and the surface glue is 130-500 g/m2。
The upper bottom glue layer and the lower bottom glue layer of the impregnated paper are both (methyl) acrylate post-crosslinking emulsion, and the impregnated paper is prepared by uniformly stirring a main monomer and a post-crosslinking monomer, dispersing the main monomer and the post-crosslinking monomer in a non-reactive emulsifier aqueous solution, and then reacting under the action of an initiator, wherein the main monomer is C3～C18The amount of the acrylate or/and methacrylate is 100 parts, the post-crosslinking monomer is a double-bond type small molecular compound monomer which carries hydroxyl, carboxyl, amino and amido terminals and is easily activated by heat to generate chemical bonding, the amount is 1-50 parts, the amount of the emulsifier is 0.5-30 parts, the amount of water is 100-10000 parts, and the amount of the initiator is 0.01-10 parts.
The impregnated paper surface adhesive layer is inorganic particle modified (methyl) acrylate direct crosslinking type emulsion and is prepared from 100 parts of main monomers, 0.5-45 parts of direct crosslinking monomers with the number of double bonds being more than or equal to 2, 1-50 parts of emulsifiers, 100-10000 parts of water and 0.01-10 parts of initiators, wherein the inorganic particles are one or a mixture of more of micron-sized or nano-sized silicon dioxide, nano-sized or micro-sized aluminum oxide, nano-sized or micro-sized titanium dioxide and carbon nano tubes, and the modification mode is chemical copolymerization or physical blending.
The basic hot pressing condition of the lower surface of the impregnated paper attached to the artificial board is that the hot pressing temperature is 80-300 ℃, the hot pressing time is 1-50 min, the hot pressing pressure is 0.1-50 MPa, and the artificial board base material is one of a high-medium low-density fiberboard, a high-medium low-density shaving board and a plywood.
Has the advantages that:
1. the primer and the surface glue for impregnation are emulsion type impregnation glue, are easy to prepare, have long storage period and do not volatilize formaldehyde and toxic organic solvents.
2. The upper and lower bottom glue layers and the surface glue layer of the impregnated paper have high transparency, the ornamental value of the original pattern of the paper is basically not influenced, the impregnated amount of the paper is high, the artificial board is tightly attached, and the obtained facing artificial board has good wear resistance.
Detailed Description
The effects of the present invention will be further illustrated by the following specific examples:
the embodiments are implemented on the premise of the technical scheme of the invention, and the technical means used is conventional means well known to those skilled in the art, and the technical scheme is not to be construed as limiting the invention.
Example 1:
the primer and face glue formulations are shown in the table below.
TABLE 1 basic formula of base glue and face glue for impregnated paper
The primer preparation process comprises the following steps: uniformly mixing a main monomer and a post-crosslinking monomer according to the dosage shown in the table 1, adding the main monomer and the post-crosslinking monomer into an aqueous solution containing an emulsifier, performing high-speed dispersion to obtain a pre-emulsion 1, adding the pre-emulsion 1 into a four-neck flask containing a stirring rod, a spherical condenser tube and a thermometer, raising the reaction temperature, keeping the temperature for 30min, adding an aqueous initiator solution for polymerization to obtain a target emulsion 1, and mixing a small amount of phthalic anhydride into the emulsion 1 to obtain a primer for dipping.
The preparation process of the face glue comprises the following steps: the preparation process of the emulsion is basically the same as that of the primer, the target emulsion 2 is obtained by emulsion polymerization according to the above dosage, and then the micron SiO is added into the emulsion 2 while stirring2To obtain the surface glue for impregnation.
Preparing an impregnated paper veneer artificial board: the base paper is immersed into the primer and dried to enable the glue solution to be attached to the surface of the base paper, the water content of the base paper is evaporated, the degree of pre-curing of the paper reaches about 10%, then the surface glue is applied to the surface of the upper primer layer of the paper, the water content of the paper is dried to obtain impregnated paper, then the impregnated paper is placed on the surface of a medium-density fiberboard and placed on a press to be hot-pressed for 5min at 200 ℃ and 1.5MPa to obtain the impregnated paper veneer artificial board, and the abrasion value of the decorative layer of the impregnated paper product is 27 mg/r.
Claims (4)
1. A preparation method of an environment-friendly impregnated paper facing artificial board is characterized by comprising the following steps: the artificial board comprises base paper printed with an ink pattern layer, an emulsion type transparent upper primer layer and a lower primer layer attached to the upper surface and the lower surface of the base paper, an emulsion type transparent surface adhesive attached to the surface of the base paper upper primer layer and an artificial board taking impregnated paper as a facing material, wherein the lower primer layer of the impregnated paper is attached to the surface of the artificial board, and the facing artificial board is prepared by sequentially laminating the base paper impregnated primer, the base paper impregnated surface adhesive and the impregnated paper through hot pressing.
The base paper has a mass of 65 to 130g/m2The mass of the impregnated paper pasted with the base glue and the surface glue is 130-500 g/m2。
2. The environment-friendly impregnated paper veneer artificial board according to claim 1, wherein: the upper bottom glue layer and the lower bottom glue layer of the impregnated paper are both (methyl) acrylate post-crosslinking emulsion, and the impregnated paper is prepared by uniformly stirring a main monomer and a post-crosslinking monomer, dispersing the main monomer and the post-crosslinking monomer in a non-reactive emulsifier aqueous solution, and then reacting under the action of an initiator, wherein the main monomer is C3～C18The amount of the acrylate or/and methacrylate is 100 parts, the post-crosslinking monomer is a double-bond type small molecular compound monomer which carries hydroxyl, carboxyl, amino and amido terminals and is easily activated by heat to generate chemical bonding, the amount is 1-50 parts, the amount of the emulsifier is 0.5-30 parts, the amount of water is 100-10000 parts, and the amount of the initiator is 0.01-10 parts.
3. The environment-friendly impregnated paper veneer artificial board according to claim 1, wherein: the impregnated paper surface adhesive layer is inorganic particle modified (methyl) acrylate direct crosslinking type emulsion and is prepared from 100 parts of main monomers, 0.5-45 parts of direct crosslinking monomers with the number of double bonds being more than or equal to 2, 1-50 parts of emulsifiers, 100-10000 parts of water and 0.01-10 parts of initiators, wherein the inorganic particles are one or a mixture of more of micron-sized or nano-sized silicon dioxide, nano-sized or micro-sized aluminum oxide, nano-sized or micro-sized titanium dioxide and carbon nano tubes, and the modification mode is chemical copolymerization or physical blending.
4. The environment-friendly impregnated paper veneer artificial board according to claim 1, wherein: the basic hot pressing condition of the lower surface of the impregnated paper attached to the artificial board is that the hot pressing temperature is 80-300 ℃, the hot pressing time is 1-50 min, the hot pressing pressure is 0.1-50 MPa, and the artificial board base material is one of a high-medium low-density fiberboard, a high-medium low-density shaving board and a plywood.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911297109.5A CN111015840A (en) | 2019-12-16 | 2019-12-16 | Preparation method of environment-friendly impregnated paper facing artificial board |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911297109.5A CN111015840A (en) | 2019-12-16 | 2019-12-16 | Preparation method of environment-friendly impregnated paper facing artificial board |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111015840A true CN111015840A (en) | 2020-04-17 |
Family
ID=70209625
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911297109.5A Pending CN111015840A (en) | 2019-12-16 | 2019-12-16 | Preparation method of environment-friendly impregnated paper facing artificial board |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111015840A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111923540A (en) * | 2020-10-13 | 2020-11-13 | 广东天安高分子科技有限公司 | Wear-resistant and yellowing-resistant decorative material and preparation method thereof |
| CN115058202A (en) * | 2022-07-05 | 2022-09-16 | 湖南林特科技有限公司 | Preparation method of novel formaldehyde-free impregnated membrane paper |
| CN116239963A (en) * | 2021-10-20 | 2023-06-09 | 福建友谊胶粘带集团有限公司 | Heat conduction adhesive tape and preparation method thereof |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1388289A (en) * | 2002-06-24 | 2003-01-01 | 华南理工大学 | Engine filter paper dipping agent |
| CN101230553A (en) * | 2008-01-08 | 2008-07-30 | 牡丹江恒丰纸业股份有限公司 | Automobile industry filter paper impregnation emulsion and method for modifying the same by using polymerizable emulsifier |
| CN101864024A (en) * | 2010-06-13 | 2010-10-20 | 浙江大学 | Polyacrylic ester coating adhesive emulsion and preparation method thereof |
| CN106381763A (en) * | 2016-08-30 | 2017-02-08 | 昆明振楚工贸有限公司 | Resin impregnated paper overlaid wood-based plate and manufacturing method thereof |
| CN106515180A (en) * | 2016-11-05 | 2017-03-22 | 广东耀东华装饰材料科技有限公司 | Manufacturing process of environment-friendly resin impregnated paper overlaid fiberboard |
| CN107686531A (en) * | 2017-09-26 | 2018-02-13 | 珠海菲伯过滤材料有限公司 | A kind of air filter paper polyacrylate dispersion and its preparation method and application |
| CN109320651A (en) * | 2018-09-29 | 2019-02-12 | 中国林科院林产化工研究所南京科技开发总公司 | A kind of super-hydrophobic polypropylene acid esters multiple emulsion and its preparation method and application |
| CN109355968A (en) * | 2018-10-11 | 2019-02-19 | 广东福美新材料科技有限公司 | A kind of wearable environment protection type impregnated paper and preparation method thereof |
| CN109836527A (en) * | 2017-11-24 | 2019-06-04 | 浙江信豪科技有限公司 | A kind of automobile air filter paper environmental protection type resin lotion and preparation method |
| CN110092866A (en) * | 2018-01-27 | 2019-08-06 | 浙江信豪科技有限公司 | A kind of automobile engine oil filter paper thermosetting resin lotion and preparation method thereof |
-
2019
- 2019-12-16 CN CN201911297109.5A patent/CN111015840A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1388289A (en) * | 2002-06-24 | 2003-01-01 | 华南理工大学 | Engine filter paper dipping agent |
| CN101230553A (en) * | 2008-01-08 | 2008-07-30 | 牡丹江恒丰纸业股份有限公司 | Automobile industry filter paper impregnation emulsion and method for modifying the same by using polymerizable emulsifier |
| CN101864024A (en) * | 2010-06-13 | 2010-10-20 | 浙江大学 | Polyacrylic ester coating adhesive emulsion and preparation method thereof |
| CN106381763A (en) * | 2016-08-30 | 2017-02-08 | 昆明振楚工贸有限公司 | Resin impregnated paper overlaid wood-based plate and manufacturing method thereof |
| CN106515180A (en) * | 2016-11-05 | 2017-03-22 | 广东耀东华装饰材料科技有限公司 | Manufacturing process of environment-friendly resin impregnated paper overlaid fiberboard |
| CN107686531A (en) * | 2017-09-26 | 2018-02-13 | 珠海菲伯过滤材料有限公司 | A kind of air filter paper polyacrylate dispersion and its preparation method and application |
| CN109836527A (en) * | 2017-11-24 | 2019-06-04 | 浙江信豪科技有限公司 | A kind of automobile air filter paper environmental protection type resin lotion and preparation method |
| CN110092866A (en) * | 2018-01-27 | 2019-08-06 | 浙江信豪科技有限公司 | A kind of automobile engine oil filter paper thermosetting resin lotion and preparation method thereof |
| CN109320651A (en) * | 2018-09-29 | 2019-02-12 | 中国林科院林产化工研究所南京科技开发总公司 | A kind of super-hydrophobic polypropylene acid esters multiple emulsion and its preparation method and application |
| CN109355968A (en) * | 2018-10-11 | 2019-02-19 | 广东福美新材料科技有限公司 | A kind of wearable environment protection type impregnated paper and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111923540A (en) * | 2020-10-13 | 2020-11-13 | 广东天安高分子科技有限公司 | Wear-resistant and yellowing-resistant decorative material and preparation method thereof |
| CN116239963A (en) * | 2021-10-20 | 2023-06-09 | 福建友谊胶粘带集团有限公司 | Heat conduction adhesive tape and preparation method thereof |
| CN116239963B (en) * | 2021-10-20 | 2024-05-28 | 福建友谊胶粘带集团有限公司 | Heat conduction adhesive tape and preparation method thereof |
| CN115058202A (en) * | 2022-07-05 | 2022-09-16 | 湖南林特科技有限公司 | Preparation method of novel formaldehyde-free impregnated membrane paper |
| CN115058202B (en) * | 2022-07-05 | 2023-12-05 | 湖南林特科技有限公司 | Preparation method of formaldehyde-free impregnated paper |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111015840A (en) | Preparation method of environment-friendly impregnated paper facing artificial board | |
| CN105291540B (en) | Preparation method of environment-friendly ecological plate | |
| CN102516436B (en) | Room-temperature self-crosslinkable styrene-acrylic emulsion resistant to ethanol dilution and preparation method for same | |
| CN104479596B (en) | Water-based environment-friendly plate splicing adhesive and preparation method thereof | |
| CN105397873B (en) | A kind of environmental and ecological plate of high color fastness and preparation method | |
| CN111496948B (en) | Impregnated bond paper facing formaldehyde-free artificial board and preparation method thereof | |
| CN104962219A (en) | Water-based zero-formaldehyde adhesive for plywoods | |
| CN104178017A (en) | Optical-thermal double-solidified baikeding for tinplate and coating method thereof | |
| CN102653667B (en) | Water-soluble non-formaldehyde wood adhesive and method for preparing same | |
| CN110606910A (en) | Odorless pure acrylic emulsion for bi-component plate alignment adhesive and preparation method thereof | |
| CN104151920A (en) | Water-based polishing printing ink for online polishing printing and preparation method | |
| CN112301797A (en) | Weather-resistant decorative paper and preparation method thereof | |
| CN110804381A (en) | Primer liquid suitable for printing non-absorbent printing medium by using water-based pigment ink, preparation method and application | |
| CN101314699B (en) | Water-based adhesion agent and preparation thereof | |
| CN112898881A (en) | Antibacterial and mildew-proof UV-LED gloss oil and preparation method thereof | |
| CN108913012A (en) | Ultraviolet light solidifies high resistant matt floor paint and preparation method thereof | |
| CN115058202B (en) | Preparation method of formaldehyde-free impregnated paper | |
| CN108587313A (en) | Water-based flexo printing ultraviolet curing ink binder and preparation method thereof | |
| CN106590482B (en) | A kind of waterglass base interpenetrating polymer networks structure bamboo adhesive for wood and preparation method thereof | |
| FI116678B (en) | Phenolic resole veneer resin, process and manufacture | |
| CN111440477A (en) | Improved composite printing ink and preparation method thereof | |
| CN107099011B (en) | Graphene amine aldehyde resin for impregnation and preparation method and application thereof | |
| CN113072865A (en) | Flame-retardant UV-LED coating gloss oil and preparation method thereof | |
| CN112159502A (en) | Preparation method of formaldehyde-free glue for impregnated paper | |
| CN106749845A (en) | Acrylate resin composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20200417 |
|
| WD01 | Invention patent application deemed withdrawn after publication |