CN109988967A - A kind of novel welding material and preparation method thereof - Google Patents

A kind of novel welding material and preparation method thereof Download PDF

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Publication number
CN109988967A
CN109988967A CN201910174520.7A CN201910174520A CN109988967A CN 109988967 A CN109988967 A CN 109988967A CN 201910174520 A CN201910174520 A CN 201910174520A CN 109988967 A CN109988967 A CN 109988967A
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Prior art keywords
temperature
welding material
obtains
steel
time
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CN201910174520.7A
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Chinese (zh)
Inventor
李兴会
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China University of Mining and Technology CUMT
Jiangsu Province Xuzhou Technician Institute
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Jiangsu Province Xuzhou Technician Institute
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Priority to CN201910174520.7A priority Critical patent/CN109988967A/en
Publication of CN109988967A publication Critical patent/CN109988967A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3053Fe as the principal constituent
    • B23K35/308Fe as the principal constituent with Cr as next major constituent
    • B23K35/3086Fe as the principal constituent with Cr as next major constituent containing Ni or Mn
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/06Deoxidising, e.g. killing
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/10Handling in a vacuum
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
    • C21D8/065Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B9/00General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
    • C22B9/16Remelting metals
    • C22B9/18Electroslag remelting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/58Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Nonmetallic Welding Materials (AREA)
  • Arc Welding In General (AREA)

Abstract

The present invention relates to a kind of novel welding materials, by weight percentage, it is characterised in that: its chemical component includes: C≤0.03%, Mn≤2%, Si≤1%, p≤0.03%, S≤0.02%, Cr 22.0~23.0%, Ni 4.5~6.5%, Mo3.0~3.5%, N0.14~0.2%.The present invention has the advantage that in manufacturing process, it adds rare earth material and controls the additional amount of copper, make it have better mechanics and corrosion resistant welding material, to improve lumber recovery, there is good resistance to spot corrosion in Seawater, slit and corrosion resistant, resistance to vacuole and erosion corrosion and high fatigue strength, general corrosion resistance performance is also preferable in many circumstances.

Description

A kind of novel welding material and preparation method thereof
Technical field
The present invention relates to welding fields, more particularly to a kind of novel welding material and preparation method thereof.
Background technique
The production technology multiplicity of existing welding material is material needed for direct synthesis, gained under such production model mostly Welding material performance is single.For under different welding requirements, welding material requires what de novo formation reprocessing program was wanted, Technique is very cumbersome, and the performance reproducibility of welding material is poor.
Summary of the invention
The present invention is to solve overcome the above technological deficiency, a kind of novel welding material and preparation method thereof is provided.
In order to solve the above technical problems, technical solution provided by the invention are as follows: a kind of novel welding material, with weight percent Than meter, chemical component includes: C≤0.03%, Mn≤2%, Si≤1%, p≤0.03%, S≤0.02%, and Cr22.0~ 23.0%, Ni4.5~6.5%, Mo3.0~3.5%, N0.14~0.2%.
A kind of novel welding material production method, it is characterised in that: comprise the steps of:
Step 1: according to aforementioned proportion, first launch Mi, Cr melting at 1600-1650 DEG C and melt, afterwards plus pure Ni, fusing After, then plus Mo;
Step 2: vacuum induction melting uses 2 refinery practices after to be melted;For the first time refining (1530~ 1560) at a temperature of ± 5 DEG C, vacuum degree control refines 10~20 minutes in 1~6Pa;2nd refining is in (1530~1560) At a temperature of ± 5 DEG C, vacuum degree control is refined 10 minutes in 0.1~0.02Pa, is segregated with control composition, then carries out electromagnetism Stirring, is added in the process plus Ti, alkene soil carry out deoxidation slag making;
Step 3: by being uniformly poured by the molten steel of 2 vacuum induction meltings using thread middling speed, the duration of pouring is 12~ 18 seconds, pouring temperature controlled temperature and obtains resmelting electrode stick for the first time to ± 5 DEG C of (1530~1560);
Step 4: electroslag remelting obtains steel ingot;
Step 5: forging steel billet, is forged into the square billet that section side length is 40~80mm for the steel ingot that electroslag remelting obtains, leads to Cross and carry out finishing after ultrasonic examination, penetrant inspection again, by the steel billet after finishing 850~1160 DEG C at a temperature of by square billet heat The round bar for rolling into 8~φ of φ 14mm, 1070 ± 10 DEG C at a temperature of soaking time 30~60 minutes, then carry out water quenching, circle Bar steel wire obtains the austenitic stainless steel wires material blank of meta-stable by solution heat treatment;
Step 6: it is drawn into silk, austenitic stainless steel wires material blank is more with each time 40~70% degree of deformation progress Secondary drawing, the drawing deformation degree control of last time obtain stainless steel welding material 20~40%.
In 4th step the electroslag quantity of slag proportion are as follows: aluminium powder 25g, alumdum 230g, lime 100g, magnesium powder 100g, Fluorspar Powder 1240g, titanium dioxide 25g.
The present invention has the advantage that in manufacturing process, addition rare earth material and the additional amount for controlling copper are made it have more Good mechanics and corrosion resistant welding material has good resistance to spot corrosion to improve lumber recovery in Seawater, and resistance to gap is rotten Erosion, resistance to vacuole and erosion corrosion and high fatigue strength, general corrosion resistance performance is also preferable in many circumstances.
Specific embodiment
The present invention is described in further detail below.
A kind of novel welding material, by weight percentage, it is characterised in that: its chemical component includes: C≤0.03%, Mn≤2%, Si≤1%, p≤0.03%, S≤0.02%, Cr 22.0~23.0%, Ni 4.5~6.5%, Mo3.0~ 3.5%, N0.14~0.2%.
A kind of novel welding material production method comprising the steps of:
Step 1: according to aforementioned proportion, first launch Mi, Cr melting at 1600-1650 DEG C and melt, afterwards plus pure Ni, fusing After, then plus Mo;
Step 2: vacuum induction melting uses 2 refinery practices after to be melted;For the first time refining (1530~ 1560) at a temperature of ± 5 DEG C, vacuum degree control refines 10~20 minutes in 1~6Pa;2nd refining is in (1530~1560) At a temperature of ± 5 DEG C, vacuum degree control is refined 10 minutes in 0.1~0.02Pa, is segregated with control composition, then carries out electromagnetism Stirring, is added in the process plus Ti, alkene soil carry out deoxidation slag making;
Step 3: by being uniformly poured by the molten steel of 2 vacuum induction meltings using thread middling speed, the duration of pouring is 12~ 18 seconds, pouring temperature controlled temperature and obtains resmelting electrode stick for the first time to ± 5 DEG C of (1530~1560);
Step 4: electroslag remelting obtains steel ingot;
Step 5: forging steel billet, is forged into the square billet that section side length is 40~80mm for the steel ingot that electroslag remelting obtains, leads to Cross and carry out finishing after ultrasonic examination, penetrant inspection again, by the steel billet after finishing 850~1160 DEG C at a temperature of by square billet heat The round bar for rolling into 8~φ of φ 14mm, 1070 ± 10 DEG C at a temperature of soaking time 30~60 minutes, then carry out water quenching, circle Bar steel wire obtains the austenitic stainless steel wires material blank of meta-stable by solution heat treatment;
Step 6: it is drawn into silk, austenitic stainless steel wires material blank is more with each time 40~70% degree of deformation progress Secondary drawing, the drawing deformation degree control of last time obtain stainless steel welding material 20~40%.
In 4th step the electroslag quantity of slag proportion are as follows: aluminium powder 25g, alumdum 230g, lime 100g, magnesium powder 100g, Fluorspar Powder 1240g, titanium dioxide 25g.
Embodiment 1: by weight percentage, C:0.01%, Mn:0.5%, Si:0.3%, p:0.01%, S:0.01%, Cr:22%, Ni:4.5%, Mo:3.0%, N:0.14%.
Embodiment 2: by weight percentage, C:0.02%, Mn:1%, Si:0.6%, p:0.02%, S:0.15%, Cr: 22.5%, Ni:5%, Mo:3.2%, N:0.18%.
Embodiment 1: by weight percentage, C:0.03%, Mn:2%, Si:1%, p:0.03%, S:0.02%, Cr: 23%, Ni:6.5%, Mo:3.5%, N:0.2%.
The present invention and its embodiments have been described above, it is this description it is no restricted, shown in also only this One of embodiment of invention, actual structure is not limited to this.All in all if those skilled in the art by It is enlightened, and without departing from the spirit of the invention, not inventively designs knot similar with the technical solution Structure mode and embodiment, are within the scope of protection of the invention.

Claims (3)

1. a kind of novel welding material, by weight percentage, it is characterised in that: its chemical component includes: C≤0.03%, Mn ≤ 2%, Si≤1%, p≤0.03%, S≤0.02%, Cr22.0~23.0%, Ni 4.5~6.5%, Mo3.0~3.5%, N0.14~0.2%.
2. a kind of novel welding material production method, it is characterised in that: comprise the steps of:
Step 1: first launching Mi, Cr melting at 1600-1650 DEG C according to aforementioned proportion and melting, afterwards plus pure Ni, fusing terminate Afterwards, then plus Mo;
Step 2: vacuum induction melting uses 2 refinery practices after to be melted;Refining is in (1530~1560) for the first time At a temperature of ± 5 DEG C, vacuum degree control refines 10~20 minutes in 1~6Pa;2nd refining is ± 5 DEG C of (1530~1560) At a temperature of, vacuum degree control is refined 10 minutes in 0.1~0.02Pa, is segregated with control composition, then carries out electromagnetic agitation, It is added in the process plus Ti, alkene soil carries out deoxidation slag making;
Step 3: the duration of pouring is 12~18 by being uniformly poured by the molten steel of 2 vacuum induction meltings using thread middling speed Second, pouring temperature controls temperature and obtains resmelting electrode stick for the first time to ± 5 DEG C of (1530~1560);
Step 4: electroslag remelting obtains steel ingot;
Step 5: forging steel billet, is forged into the square billet that section side length is 40~80mm for the steel ingot that electroslag remelting obtains, by super Finishing is carried out after sonic flaw detection, penetrant inspection again, by the steel billet after finishing 850~1160 DEG C at a temperature of square billet is rolled into The round bar of 8~φ of φ 14mm, 1070 ± 10 DEG C at a temperature of soaking time 30~60 minutes, then carry out water quenching, round bar steel Silk obtains the austenitic stainless steel wires material blank of meta-stable by solution heat treatment;
Step 6: being drawn into silk, austenitic stainless steel wires material blank is repeatedly drawn with each time 40~70% degree of deformation It pulls out, the drawing deformation degree control of last time obtains stainless steel welding material 20~40%.
3. a kind of novel welding material production method according to claim 2, it is characterised in that: in the 4th step Electroslag quantity of slag proportion are as follows: aluminium powder 25g, alumdum 230g, lime 100g, magnesium powder 100g, Fluorspar Powder 1240g, titanium dioxide 25g.
CN201910174520.7A 2019-03-04 2019-03-04 A kind of novel welding material and preparation method thereof Pending CN109988967A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110860818A (en) * 2019-11-29 2020-03-06 哈尔滨焊接研究院有限公司 Low-nickel nitrogen-containing austenitic stainless steel welding wire and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3726668A (en) * 1969-11-29 1973-04-10 Boehler & Co Ag Geb Welding filling material
JPH02295678A (en) * 1989-05-02 1990-12-06 Nippon Steel Corp Method for welding duplex stainless steels excellent in pitting corrosion resistance of weld metal part
CN1125965A (en) * 1993-06-21 1996-07-03 桑德维克公司 Ferritic-austenitic stainless steel and use of the steel
CN1426491A (en) * 2000-04-28 2003-06-25 艾略特涡轮机械公司 Welding method, filler metal composition and article made therefrom
CN101913037A (en) * 2010-09-15 2010-12-15 江苏立新合金实业总公司 Super diphase stainless steel welding material and production method thereof
CN102251191A (en) * 2011-07-21 2011-11-23 重庆仪表材料研究所 Martensite stainless steel and preparation method for flat strip of martensite stainless steel

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3726668A (en) * 1969-11-29 1973-04-10 Boehler & Co Ag Geb Welding filling material
JPH02295678A (en) * 1989-05-02 1990-12-06 Nippon Steel Corp Method for welding duplex stainless steels excellent in pitting corrosion resistance of weld metal part
CN1125965A (en) * 1993-06-21 1996-07-03 桑德维克公司 Ferritic-austenitic stainless steel and use of the steel
CN1426491A (en) * 2000-04-28 2003-06-25 艾略特涡轮机械公司 Welding method, filler metal composition and article made therefrom
CN101913037A (en) * 2010-09-15 2010-12-15 江苏立新合金实业总公司 Super diphase stainless steel welding material and production method thereof
CN102251191A (en) * 2011-07-21 2011-11-23 重庆仪表材料研究所 Martensite stainless steel and preparation method for flat strip of martensite stainless steel

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110860818A (en) * 2019-11-29 2020-03-06 哈尔滨焊接研究院有限公司 Low-nickel nitrogen-containing austenitic stainless steel welding wire and preparation method thereof

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Application publication date: 20190709