CN109881091A - High-strength weather-resistant steel thin strip and production method thereof - Google Patents

High-strength weather-resistant steel thin strip and production method thereof Download PDF

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Publication number
CN109881091A
CN109881091A CN201910130666.1A CN201910130666A CN109881091A CN 109881091 A CN109881091 A CN 109881091A CN 201910130666 A CN201910130666 A CN 201910130666A CN 109881091 A CN109881091 A CN 109881091A
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strip
steel
production method
weathering steel
strength
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CN109881091B (en
Inventor
陈爱华
李化龙
刘新院
刘俭
施一新
马毅
刘玉君
吴荣洲
史华跃
郭海荣
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Institute Of Research Of Iron & Steel shagang jiangsu Province
Zhangjiagang Sino Us Ultra Thin Belt Technology Co ltd
Jiangsu Shagang Group Co Ltd
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Institute Of Research Of Iron & Steel shagang jiangsu Province
Zhangjiagang Sino Us Ultra Thin Belt Technology Co ltd
Jiangsu Shagang Group Co Ltd
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Priority to CN201910130666.1A priority Critical patent/CN109881091B/en
Publication of CN109881091A publication Critical patent/CN109881091A/en
Priority to PCT/CN2020/076116 priority patent/WO2020169075A1/en
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/20Ferrous alloys, e.g. steel alloys containing chromium with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/26Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Metal Rolling (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The invention relates to a high-strength weather-resistant steel thin strip and a production method thereof. The method comprises the following steps: smelting, wherein the steel comprises the following components in percentage by weight: c is less than or equal to 0.03, Si is 0.10-0.40, Mn is 1.50-2.00, P is less than or equal to 0.015, S is less than or equal to 0.003, Cr is less than or equal to 0.50, Cu is 0.20-1.00, Nb is 0.05-0.50, and the balance is iron and inevitable impurities; continuously casting thin strips, namely continuously casting the qualified smelted molten steel into casting strips with the thickness of 1.4-2.5mm by a pair of casting rolls rotating in opposite directions, wherein the superheat degree of the molten steel is controlled below 100 ℃; the cast strip is subjected to online hot rolling, the hot rolling reduction of 1 pass is 15-65%, and the temperature of the strip steel before entering a rolling mill is above 950 ℃; cooling and coiling, wherein the hot rolled strip steel is cooled to 450-650 ℃ through gas spray to obtain acicular ferrite and a small amount of pearlite structures, and then coiling the acicular ferrite and the small amount of pearlite structures by a coiling machine. The high-strength weather-resistant steel thin strip has the advantages of short production flow, low production cost, easiness in welding, good strip steel plate shape, high strength and the like, and can be widely applied to the fields of bridges, buildings, containers, railway carriages and the like.

Description

A kind of high-strength weathering steel strip and its production method
Technical field
The invention belongs to manufacture field of low alloy steel, more particularly to a kind of low cost, short route, easily welding, high intensity Weathering steel strip and its production method, can be applied to container, building, bridge and railcar etc. manufacture in.
Background technique
Weathering steel, also referred to as weather resisting steel, the alloying elements such as Chang Tianjia Cu, P, Cr, Ni, Mo, improve the resistance to of steel grade Atmospheric corrosion performance, so that its corrosion resistance for having had compared with straight carbon steel, with stainless steel than with low manufacturing cost. With the extensive use of weathering steel, higher requirements are also raised for intensity of the fields such as container, bridge, building to weathering steel, And 09CuPCrNi can only guarantee the intensity of 345MPa.In addition, plate shape is difficult since traditional hot continuous rolling is when thin slab product produces In control, producing thin gauge high-strength weathering steel has a very big difficulty, and production efficiency in the extreme under.Although in recent years There is the example using CSP continuous casting and rolling technique of sheet bar production thin gauge weathering steel, but it also has production cost higher, The relatively long disadvantage of production procedure.
Patent document CN101824581B discloses a kind of yield strength 450MPa grade high-strength weathering steel plate and its producer Method is produced using converter-CSP production technology, and using the method for Nb microalloying and controlled rolling and controlled cooling, high-strength to obtain The purpose of degree, Cr and Ni content is higher, and cost of alloy and production cost are higher.Patent document CN108103398A discloses one Kind 460MPa grade high-strength high durable steel plate and its production method are improved resistance to by a variety of microalloy elements such as addition Nb, Ti, B The intensity of steel is waited, while using pneumatic steelmaking, LF refining, sheet billet continuous casting, slab slow cooling, heating of plate blank, high-pressure water descaling, roughing The multi-pass processes such as rolling, finish rolling rolling, On-line Control cooling, production procedure is long and cumbersome, and steel plate thickness produced is thicker, Production cost and production efficiency are low.Patent document CN108570601A discloses a kind of low-carbon bainite weathering steel and its production Method improves the intensity of weathering steel by microalloy elements such as addition Mo and Ti, and controlling its microstructure is 95% or more Without austenite a small amount of on carbon bainite and crystal boundary and Cu-Ni Age-prrcipitation Phase, production technology is extremely complex, production difficulty compared with Greatly.Patent document CN109023048A discloses a kind of 460MPa level high-strength quake-proof fire-resistant and weather-resistant steel hot-rolled coil and its producer The production of weathering steel thin slab product is not implemented with a thickness of 6-16mm in method, the weather-proof strip of production.And in above patent document Weathering steel C content it is higher, belong to peritectic steel, in sheet billet continuous casting, since peritectic reaction occurs when molten steel solidification, be easy Steel slab surface cracks, and causes final steel plate cracked, influences plate surface quality, when rolling thin slab product, Such defect increases the production difficulty of weathering steel strip.Therefore, research and develop a kind of high-intensitive, inexpensive, easy to produce, high quality, The weather-proof steel product of thin gauge is the urgent need of vast application field.
Summary of the invention
For existing high-strength weathering steel strip production procedure is long, production difficulty is big, surface quality is poor, cost of alloy High, the problems such as production efficiency is low, welding performance is poor, the present invention provides a kind of novel high-strength weathering steel strips and its production Production procedure has been greatly shortened using sheet-band continuous casting and rolling technique in method, reduces production cost;It is mentioned using rapid cooling High band hardness of steel, has saved cost of alloy;And the design of C content is controlled, improve the welding performance of weathering steel and the company of avoiding The generation for casting crackle improves strip surface quality and welding performance, the surface quality for improving weathering steel.
To achieve the goals above, on the one hand, the invention also discloses a kind of production method of high-strength weathering steel strip, It follows the steps below:
1) it smelts
Ladle chemistry are as follows: C :≤0.03wt%, Si:0.10-0.40wt%, Mn:1.50-2.00wt%, P :≤ 0.015wt%, S :≤0.003wt%, Cr :≤0.50wt%, Cu:0.20-1.00wt%, Nb:0.05-0.50wt%, remaining For iron and inevitable impurity;
2) thin strap continuous casting
Qualified molten steel will be smelted and be casting continuously to form Cast Strip by the casting roll of a pair of of opposite direction rotating;
3) the online hot rolling in Cast Strip
Cast Strip is by 1 passage hot rolling at Thin Strip Steel;
4) it cools down and batches
Thin Strip Steel after hot rolling is cooling by aerosol, and batches in rolls through coiling machine.
The production method of a kind of high-strength weathering steel strip according to the present invention, it is preferable that Cast Strip is with a thickness of 1.4- 2.5mm。
A kind of production method of high-strength weathering steel strip according to the present invention, it is preferable that degree of superheat when molten steel continuous casting Control is at 100 DEG C or less.
The production method of a kind of high-strength weathering steel strip according to the present invention, it is preferable that 1 passage of hot-rolling mill is passed through in Cast Strip The drafts of hot rolling is 15-65%.
The production method of a kind of high-strength weathering steel strip according to the present invention, it is preferable that Cast Strip forms heat by hot rolling Rolling thin strip steel with a thickness of 0.7-2.0mm.
The production method of a kind of high-strength weathering steel strip according to the present invention, it is preferable that Cast Strip enters the temperature of hot-rolling mill Degree is at 950 DEG C or more.
The production method of a kind of high-strength weathering steel strip according to the present invention, it is preferable that the Thin Strip Steel after hot rolling passes through Aerosol is cooled to 450-650 DEG C.
A kind of production method of high-strength weathering steel strip according to the present invention, it is preferable that hot rolling thin strip after cooling Tissue be acicular ferrite and a small amount of pearlite.
The production method of a kind of high-strength weathering steel strip according to the present invention, it is preferable that the surrender of hot rolling thin strip is strong Degree is in 450MPa or more.
To achieve the goals above, on the other hand, the invention also discloses a kind of high-strength weathering steel strips, before use A kind of production method for the high-strength weathering steel strip stated is produced.
A kind of high-strength weathering steel strip according to the present invention, it is preferable that its yield strength in 450MPa or more, strip Microstructure is acicular ferrite and a small amount of pearlite.
To achieve the goals above, another aspect, the invention discloses a kind of high-strength weathering steel strip, the chemistry of steel at Dividing includes: C :≤0.03wt%, Si:0.10-0.40wt%, Mn:1.50-2.00wt%, P :≤0.015wt%, S :≤ 0.003wt%, Cr :≤0.50wt%, Cu:0.20-1.00wt%, Nb:0.05-0.50wt%, remaining is for iron and unavoidably Impurity.
Beneficial technical effect
Compared with prior art, the features of the present invention and beneficial technical effect include at least:
(1) considerably reduce the C content in weathering steel, reduce the transformation amount of peritectic reaction during molten steel solidification with And volume change during solid-state phase changes substantially increases the surface of Cast Strip to reduce the risk of Cast Strip crackle appearance The surface quality of quality and final Thin Strip Steel improves the bending property and service performance of weathering steel;
(2) C content in weathering steel is reduced, the welding performance of weathering steel in use is significantly improved;
(3) production technology for adding 1 passage hot rolling using thin strap continuous casting, so that high-strength weather-proof steel-making process significantly contracts Short, production cost is greatly lowered;
(4) production procedure is shortened, the production difficulty of high-strength weathering steel strip is reduced, so that high-strength weather-proof strip The production efficiency of steel increases significantly.
Detailed description of the invention
In order to illustrate more clearly of the technical solution of the embodiment of the present invention, is below made to the attached drawing of embodiment simple be situated between It continues.It should be evident that the accompanying drawings in the following description only designs some embodiments of the present invention, rather than limitation of the present invention.
Fig. 1 is the metallographic structure of high-strength weathering steel strip according to the present invention.
Specific embodiment
It, below will be to the embodiment of the present invention in order to keep the purposes, technical schemes and advantages of the embodiment of the present invention clearer Technical solution be clearly and completely described.Obviously, described embodiment is a part of the embodiments of the present invention, without It is whole embodiments.Based on described the embodiment of the present invention, those of ordinary skill in the art are being not necessarily to creative work Under the premise of every other embodiment obtained, shall fall within the protection scope of the present invention.
Unless otherwise defined, technical term or scientific term used in the disclosure should be tool in fields of the present invention The ordinary meaning for thering is the personage of general technical ability to be understood.
Embodiment 1
The present embodiment follows the steps below:
1) it smelts
Ladle chemistry are as follows: C:0.020wt%, Si:0.30wt%, Mn:1.80wt%, P:0.01wt%, S: 0.002wt%, Cr:0.40wt%, Cu:0.50wt%, Nb:0.10wt%, remaining is iron and inevitable impurity;
2) thin strap continuous casting
Qualified molten steel will be smelted and be casting continuously to form the Cast Strip with a thickness of 2.0mm by the casting roll of a pair of of opposite direction rotating;Molten steel The degree of superheat is 60 DEG C;
3) the online hot rolling in Cast Strip
Cast Strip is by 1 passage hot rolling at Thin Strip Steel, and hot rolling drafts is 50%, and strip is into the temperature before hot-rolling mill 980℃;
4) it cools down and batches
Hot-strip is cooled to 620 DEG C by the way that aerosol is cooling, and batches coiled.
It is 1.0mm by the obtained weathering steel strip thickness of above step, Mechanics Performance Testing, surrender is carried out to strip Intensity is 455MPa.
Embodiment 2
The present embodiment follows the steps below:
1) it smelts
Ladle chemistry are as follows: C:0.028wt%, Si:0.25wt%, Mn:1.60wt%, P:0.008wt%, S: 0.0022wt%, Cr:0.45wt%, Cu:0.90wt%, Nb:0.22wt%, remaining is iron and inevitable impurity;
2) thin strap continuous casting
Qualified molten steel will be smelted and be casting continuously to form the Cast Strip with a thickness of 2.4mm by the casting roll of a pair of of opposite direction rotating;Molten steel The degree of superheat is 40 DEG C;
3) the online hot rolling in Cast Strip
By 1 passage hot rolling at Thin Strip Steel, hot rolling drafts is 62.5% for Cast Strip, and strip is into the temperature before hot-rolling mill It is 1058 DEG C;
4) it cools down and batches
Hot-strip is cooled to 460 DEG C by the way that aerosol is cooling, and batches coiled.
It is 0.9mm by the obtained weathering steel strip thickness of above step, Mechanics Performance Testing, surrender is carried out to strip Intensity is 520MPa.
Embodiment 3
The present embodiment follows the steps below:
1) it smelts
Ladle chemistry are as follows: C:0.025wt%, Si:0.20wt%, Mn:1.40wt%, P:0.012wt%, S: 0.0023wt%, Cr:0.48wt%, Cu:0.70wt%, Nb:0.18wt%, remaining is iron and inevitable impurity;
2) thin strap continuous casting
Qualified molten steel will be smelted and be casting continuously to form the Cast Strip with a thickness of 1.6mm by the casting roll of a pair of of opposite direction rotating;Molten steel The degree of superheat is 20 DEG C;
3) the online hot rolling in Cast Strip
Cast Strip is by 1 passage hot rolling at Thin Strip Steel, and hot rolling drafts is 25%, and strip is into the temperature before hot-rolling mill 1020℃;
4) it cools down and batches
Hot-strip is cooled to 520 DEG C by the way that aerosol is cooling, and batches coiled.
It is 1.2mm by the obtained weathering steel strip thickness of above step, Mechanics Performance Testing, surrender is carried out to strip Intensity is 492MPa.
The above is only exemplary embodiment of the invention, protection scope and is not intended to limit the present invention, this hair Bright protection scope is determined by the attached claims.

Claims (12)

1. a kind of production method of high-strength weathering steel strip, which is characterized in that production method includes the following steps:
1) it smelts
Smelting obtains the molten steel of following ingredient: C :≤0.03wt%, Si:0.10-0.40wt%, Mn:1.50-2.00wt%, P: ≤ 0.015wt%, S :≤0.003wt%, Cr :≤0.50wt%, Cu:0.20-1.00wt%, Nb:0.05-0.50wt%, Yu Weitie and inevitable impurity;
2) thin strap continuous casting
Qualified molten steel will be smelted and be casting continuously to form Cast Strip by the casting roll of a pair of of opposite direction rotating;
3) the online hot rolling in Cast Strip
Cast Strip is by 1 passage hot rolling at Thin Strip Steel;
4) it cools down and batches
Thin Strip Steel after hot rolling is cooling by aerosol, and batches in rolls through coiling machine.
2. the production method of high-strength weathering steel strip as described in claim 1, which is characterized in that in step 2), Cast Strip is thick Degree is 1.4-2.5mm.
3. the production method of high-strength weathering steel strip as described in claim 1, which is characterized in that in step 2), molten steel connects Degree of superheat when casting is controlled at 100 DEG C or less.
4. the production method of high-strength weathering steel strip as described in claim 1, which is characterized in that in step 3), Cast Strip warp The drafts for crossing 1 passage hot rolling of hot-rolling mill is 15-65%.
5. the production method of high-strength weathering steel strip as described in claim 1, which is characterized in that in step 3), Cast Strip warp Cross hot rolling formed hot rolling thin strip with a thickness of 0.7-2.0mm.
6. the production method of high-strength weathering steel strip as described in claim 1, which is characterized in that in step 3), Cast Strip into Enter the temperature of hot-rolling mill at 950 DEG C or more.
7. the production method of high-strength weathering steel strip as described in claim 1, which is characterized in that in step 4), after hot rolling Thin Strip Steel be cooled to 450-650 DEG C by aerosol.
8. the production method of high-strength weathering steel strip as described in claim 1, which is characterized in that in step 4), after cooling Hot rolling thin strip tissue be acicular ferrite and a small amount of pearlite.
9. the production method of high-strength weathering steel strip as described in claim 1, which is characterized in that in step 4), hot rolled thin The yield strength of strip is in 450MPa or more.
10. a kind of high-strength weathering steel strip, which is characterized in that use the height as described in any one in claim 1-9 The production method of intensity weathering steel strip is produced.
11. high-strength weathering steel strip as claimed in claim 10, which is characterized in that the yield strength of Thin Strip Steel is in 450MPa More than, the microstructure of strip is acicular ferrite and a small amount of pearlite.
12. a kind of high-strength weathering steel strip, which is characterized in that the chemical component of steel includes: C :≤0.03wt%, Si:0.10- 0.40wt%, Mn:1.50-2.00wt%, P :≤0.015wt%, S :≤0.003wt%, Cr :≤0.50wt%, Cu:0.20- 1.00wt%, Nb:0.05-0.50wt%, remaining is iron and inevitable impurity.
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CN110983193A (en) * 2019-12-25 2020-04-10 江苏沙钢集团有限公司 800 MPa-grade high-strength steel based on thin strip casting and rolling and production method thereof
CN111041365A (en) * 2019-12-25 2020-04-21 江苏沙钢集团有限公司 500-700 MPa-level economical high-strength steel based on thin strip casting and rolling and production method thereof
CN111218607A (en) * 2020-04-16 2020-06-02 江苏沙钢集团有限公司 High-strength steel for seat sliding rail and method for producing high-strength steel based on thin strip casting
CN111215590A (en) * 2020-04-16 2020-06-02 江苏沙钢集团有限公司 Thin-gauge cold-rolled low-alloy high-strength steel and production method thereof based on double-roller casting rolling
WO2020169075A1 (en) * 2019-02-21 2020-08-27 江苏沙钢集团有限公司 High-strength weather-proof thin steel strip and production method therefor
CN112522595A (en) * 2019-09-19 2021-03-19 宝山钢铁股份有限公司 High-strength thin-specification fire-resistant weather-resistant steel plate/steel belt and production method thereof
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