CN108031138A - A kind of krypton xenon concentration tower bottom heat of evaporation source system - Google Patents

A kind of krypton xenon concentration tower bottom heat of evaporation source system Download PDF

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Publication number
CN108031138A
CN108031138A CN201711339313.XA CN201711339313A CN108031138A CN 108031138 A CN108031138 A CN 108031138A CN 201711339313 A CN201711339313 A CN 201711339313A CN 108031138 A CN108031138 A CN 108031138A
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CN
China
Prior art keywords
nitrogen
electric heater
evaporator
towe
temperature
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Pending
Application number
CN201711339313.XA
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Chinese (zh)
Inventor
周丽
凝晶
张敏
孙国华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHEJIANG XINRUI AIR SEPARATION EQUIPMENT CO Ltd
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ZHEJIANG XINRUI AIR SEPARATION EQUIPMENT CO Ltd
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Publication date
Application filed by ZHEJIANG XINRUI AIR SEPARATION EQUIPMENT CO Ltd filed Critical ZHEJIANG XINRUI AIR SEPARATION EQUIPMENT CO Ltd
Priority to CN201711339313.XA priority Critical patent/CN108031138A/en
Publication of CN108031138A publication Critical patent/CN108031138A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14Fractional distillation or use of a fractionation or rectification column
    • B01D3/32Other features of fractionating columns ; Constructional details of fractionating columns not provided for in groups B01D3/16 - B01D3/30
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/42Regulation; Control
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H7/00Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release
    • F24H7/02Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release the released heat being conveyed to a transfer fluid
    • F24H7/04Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release the released heat being conveyed to a transfer fluid with forced circulation of the transfer fluid
    • F24H7/0408Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release the released heat being conveyed to a transfer fluid with forced circulation of the transfer fluid using electrical energy supply
    • F24H7/0416Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release the released heat being conveyed to a transfer fluid with forced circulation of the transfer fluid using electrical energy supply the transfer fluid being air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H9/00Details
    • F24H9/18Arrangement or mounting of grates or heating means
    • F24H9/1854Arrangement or mounting of grates or heating means for air heaters
    • F24H9/1863Arrangement or mounting of electric heating means
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H9/00Details
    • F24H9/20Arrangement or mounting of control or safety devices
    • F24H9/2064Arrangement or mounting of control or safety devices for air heaters
    • F24H9/2071Arrangement or mounting of control or safety devices for air heaters using electrical energy supply

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)

Abstract

A kind of krypton xenon concentration tower bottom heat of evaporation source system, krypton xenon concentration tower bottom is installed on including one and is immersed in bottom of towe evaporator in liquid oxygen and liquid krypton xenon mixture, being made of coil exchanger, employed nitrogen as in the coil pipe of the bottom of towe evaporator as heat transferring medium, the nitrogen of air drying is entered in electric heater by regulating valve, after electric heater is heated to design temperature, make heat source in into bottom of towe evaporator, Nitrogen pipe network is returned after going out bottom of towe evaporator;The thermic load of the bottom of towe evaporator is realized by the flow for adjusting nitrogen and the temperature for going out electric heater;Heat exchanger tube in the bottom of towe evaporator is divided into four layers, is respectively wound around central tube outer layer;The electric heater is configured with the power regulating cabinet of adjustable electric heater capacity;The nitrogen of the bottom of towe evaporator returns to outlet and is provided with low-temperature sensor and is connected on the low temperature alarm of peripheral hardware, the low temperature alarm connection regulating valve, and control valve opening when less than 0 DEG C so that return to Nitrogen pipe network for room temperature when nitrogen goes out evaporator, reduce diffusing for nitrogen.

Description

A kind of krypton xenon concentration tower bottom heat of evaporation source system
Technical field
The present invention relates to the krypton xenon concentration tower vapo(u)rization system in a kind of rare gas krypton xenon extraction process, belong to low temperature Technical field of rectification.
Background technology
At present, the extraction of krypton xenon-133 gas is all different from the boiling point of remaining component using krypton xenon component, takes multiple rectifying Method, krypton-xenon concentrate is extracted from oxygen.Oxygen containing krypton xenon component(0.2%Kr+Xe)Concentrated into krypton xenon Tower, concentration tower top set condenser, and bottom sets evaporator, oxygen rectifying in tower, and high-purity oxygen evaporation is arranged from tower top Go out, krypton xenon accumulates in tower bottom and discharged as 99%Kr+Xe concentrates as product outside tower.
Krypton xenon concentration tower bottom evaporator uses two ways at present, and one kind uses built-in electric heater pattern, and one kind is adopted With gas heater pattern.Using the evaporator of electric heater pattern, heat of evaporation Load Regulation is more flexible, but shortcoming is that electricity adds Heat pipe is easily bad, and it is more difficult to be replaced in tower, and heat medium is liquid oxygen, and the inside is in addition to krypton xenon component, also containing big Hydrocarbon is measured, there are certain security risk.Using the evaporator of gas heater pattern, Reliability comparotive is high, still The adjusting of thermic load is mainly by the flow for adjusting gas, and regulating effect is poor, and degree of regulation is not also high.
The content of the invention
It is an object of the invention to overcome the shortcomings of the prior art, and provide a kind of compact-sized, regulative mode spirit Living, degree of regulation is high, safe and reliable, and installation, safeguard and replace advantageously krypton xenon concentration tower vapo(u)rization system.
The purpose of the present invention is come what is completed, a kind of krypton xenon concentrates tower bottom heat of evaporation source system by following technical solution System, including one be installed on krypton xenon concentration tower bottom and be immersed in it is in liquid oxygen and liquid krypton xenon mixture, by coil exchanger structure Into bottom of towe evaporator, employ nitrogen as in the coil pipe of the bottom of towe evaporator and passed through for heat transferring medium, the nitrogen of air drying Valve is overregulated to enter in electric heater, after electric heater is heated to design temperature, into bottom of towe evaporator in make heat source, Nitrogen pipe network is returned after going out bottom of towe evaporator;The thermic load of the bottom of towe evaporator is added by adjusting the flow of nitrogen and going out electricity The temperature of hot device is realized.
As preferred:Heat exchanger tube in the bottom of towe evaporator is divided into four layers, is respectively wound around central tube outer layer;It is described Electric heater is configured with the power regulating cabinet of adjustable electric heater capacity;The nitrogen return outlet of the bottom of towe evaporator is provided with low Temperature sensor and the low temperature alarm for being connected on peripheral hardware, low temperature alarm connection regulating valve, and adjusted when less than 0 DEG C Valve opening so that return to Nitrogen pipe network for room temperature when nitrogen goes out evaporator, reduce diffusing for nitrogen.
As preferred:Bottom of towe evaporator is immersed in the liquid oxygen and liquid krypton xenon mixture of krypton xenon concentration tower bottom, and in krypton The bottom of towe of xenon concentration tower sets low liquid level warning interlocking gear, and the low liquid level warning interlocking gear and electric heater are chain, and Liquid level is less than directly chain closing electric heater during linkage value, prevents bottom of towe liquid mistake less than design minimum alarm, liquid level Dry combustion method caused by few;The electric heater outlet is provided with temperature interlocking mechanism, prevents from entering the nitrogen temperature in bottom of towe evaporator Height is spent, protects the safe for operation of electric heater.
The present invention is mainly added by bottom of towe evaporator, electric heater and regulating valve system three parts, nitrogen by electric heater Heat arrives certain temperature, enters back into bottom of towe evaporator and exchanges heat;In this vapo(u)rization system, evaporator can be entered by adjusting Nitrogen flow adjust thermic load, the temperature of electric heater can also be gone out by adjusting nitrogen and adjust thermic load.
Nitrogen makees heat source by making heat source after heating, with nitrogen at room, adds the temperature difference, reduces heat exchange area;Nitrogen Adjustable temperature range after heating is big and degree of regulation is high, and the regulative mode than passing contracting is more flexible;Nitrogen is changed by gas coil pipe Hot device transmits heat, more more reliable than directly in bottom of towe installation electric heater.
The regulating valve system includes regulating valve and bottom of towe liquid-filled thermometer, goes out vaporizer nitrogen thermometer composition;Pass through Adjust into the nitrogen amount of bottom of towe evaporator to adjust the thermic load of evaporator.
The present invention can solve the shortcomings that gas heater degree of regulation is not high, can be with 0 by the power regulating cabinet of electric heater ~ 100% power is adjusted, and degree of regulation can reach within ± 1 DEG C, and adjusts the linear energy of line very well, can be more advantageous to reality Operation.
The present invention has compact-sized, and regulative mode is flexible, and degree of regulation is high, safe and reliable, and installation, safeguard and more Change the features such as more convenient.
Brief description of the drawings
Fig. 1 is the structure principle chart of system of the present invention.
Label in figure mainly includes: V2801:Regulating valve;EH2801:Electric heater;K2801:Evaporator;C2801: Krypton xenon concentration tower, LT2801:Evaporator liquid level gauge;TE2801:Nitrogen goes out outlet temperature of electric heater meter;TE2803:Evaporator Bottom liquid temperature;TE2804:Nitrogen goes out evaporator outlet temperature;TC2802:Electric heater temperature controller;UZ2802:Electrical heating Start-stop logic.
Embodiment
Below in conjunction with attached drawing, the present invention will be described in detail:Shown in Fig. 1, a kind of krypton xenon concentration tower of the present invention Heat source system is evaporated in bottom, including one be installed on krypton xenon concentration tower bottom and be immersed in it is in liquid oxygen and liquid krypton xenon mixture, by The bottom of towe evaporator K2801 that coil exchanger is formed, employs nitrogen as to change in the coil pipe of the bottom of towe evaporator K2801 Thermal medium, the nitrogen of air drying are entered in electric heater EH2801 by regulating valve V2801, are heated to by electric heater After design temperature, into bottom of towe evaporator K2801 in make heat source, return to Nitrogen pipe network after going out bottom of towe evaporator;The bottom of towe is steamed The thermic load of hair device K2801 is realized by adjusting the flow of nitrogen and going out the temperature of electric heater EH2801.
Shown in figure, the heat exchanger tube in bottom of towe evaporator K2801 of the present invention is divided into four layers, is respectively wound around center Cylinder outer layer;The electric heater EH2801 is configured with the power regulating cabinet of adjustable electric heater capacity;The bottom of towe evaporator K2801 Nitrogen return to outlet and be provided with low-temperature sensor and be connected on the low temperature alarm of peripheral hardware, low temperature alarm connection is adjusted Valve V2801 is saved, and V2801 valve openings are adjusted when less than 0 DEG C so that Nitrogen pipe network is returned for room temperature when nitrogen goes out evaporator, Reduce diffusing for nitrogen.
Bottom of towe evaporator K2801 of the present invention is immersed in the liquid oxygen and liquid krypton xenon mixture of krypton xenon concentration tower bottom In, and low liquid level warning interlocking gear LIAS2801, the low liquid level warning interlocking gear are set in the bottom of towe of krypton xenon concentration tower LIAS2801 and electric heater EH2801 are chain, and in liquid level less than design minimum alarm, liquid level is less than straight during linkage value Lock closes electric heater EH2801 in succession, prevents the very few caused dry combustion method of bottom of towe liquid;The electric heater EH2801 outlets are set Temperature interlocking mechanism TIAS2801 is equipped with, prevents that the nitrogen temperature into bottom of towe evaporator K2801 is excessive, protects electric heater EH2801's is safe for operation.
Embodiment:Nitrogen is entered in electric heater EH2801 by regulating valve V2801, is heated to set by electric heater After 100 DEG C of constant temperature degree, into bottom of towe evaporator K2801 in make heat source, return to Nitrogen pipe network after going out bottom of towe evaporator.Evaporator Thermic load can adjust the flow of nitrogen and go out the temperature TI2801 of electric heater to realize;Nitrogen return pipe net temperature should be 0 More than DEG C, realized by adjusting the flow of V2801 adjusting nitrogen.
Bottom of towe evaporator K2801 uses coil exchanger, and heat exchanger tube is divided into four layers, is respectively wound around central tube outer layer, Heat transferring medium in coil pipe uses nitrogen, and heat exchange coil is immersed in liquid oxygen and liquid krypton xenon mixture.The thermic load Q of evaporator= KA △ t, load of heat are mainly influenced be subject to three heat transfer coefficient, heat transfer area, heat transfer temperature difference aspects.Pass through regulating valve V2801 adjusts the nitrogen flow into evaporator, increases nitrogen flow, improves nitrogen flow rate, can increase on the inside of evaporator Heat transfer coefficient k, under conditions of the temperature difference and heat exchange area are certain, thus it is possible to vary the thermic load of evaporator.In nitrogen flow flow velocity In the case of certain, by adjusting electric heater EH2801 power regulating cabinets, the power of electric heater can be adjusted, so as to reach change Nitrogen goes out the temperature TI2801 of electric heater.Nitrogen is improved into after the temperature of evaporator, the full conjunction temperature TI2803 of liquid is constant, Heat transfer temperature difference can so be increased to change the thermic load of evaporator.
It is gas at normal temperature into the nitrogen in evaporator when general krypton xenon concentration tower bottom evaporator uses gas heater, By the liquid cooling of bottom of towe, generally low-temperature condition when going out evaporator, this part cryogenic gas can not generally recycle cold, it is necessary to Diffuse to air, cause waste.In the present invention is high-temperature gas into the nitrogen in evaporator, goes out evaporator set temperature TIA2804, can set low-temperature warning, V2801 valve openings be adjusted during less than 0 DEG C so that nitrogen returns when going out evaporator for room temperature Nitrogen pipe network is returned, reduces diffusing for nitrogen.
Bottom of towe sets low liquid level warning chain LIAS2801, chain with electric heater, when liquid level is less than design minimum Alarm, liquid level are less than directly chain closing electric heater during linkage value, prevent the very few caused dry combustion method of bottom of towe liquid.Electric heater Set temperature interlocking TIAS2801 is exported, can prevent that the nitrogen temperature into evaporator is excessive, and protect electrical heating EH2801's is safe for operation.
The present invention can solve the shortcomings that gas heater degree of regulation is not high, can be with 0 by the power regulating cabinet of electric heater ~ 100% power is adjusted, and degree of regulation can reach within ± 1 DEG C, and adjusts the linear energy of line very well, can be more advantageous to reality Operation;Structure type and regulative mode of the invention is flexible, degree of regulation is high, and electric heater is independently placed on outside ice chest, more Add securely and reliably, installation and maintenance are replaced and all more facilitated.

Claims (3)

1. a kind of krypton xenon concentration tower bottom heat of evaporation source system, including one be installed on krypton xenon concentration tower bottom and be immersed in liquid oxygen and Bottom of towe evaporator in liquid krypton xenon mixture, being made of coil exchanger(K2801), it is characterised in that the bottom of towe is steamed Send out device(K2801)Coil pipe in employ nitrogen as and pass through regulating valve for heat transferring medium, the nitrogen of air drying(V2801)Enter Electric heater(EH2801)In, after electric heater is heated to design temperature, into bottom of towe evaporator(K2801)It is interior to make heat Source, Nitrogen pipe network is returned after going out bottom of towe evaporator;The bottom of towe evaporator(K2801)Thermic load by adjusting the flow of nitrogen And go out electric heater(EH2801)Temperature realize.
2. krypton xenon concentration tower bottom heat of evaporation source system according to claim 1, it is characterised in that the bottom of towe evaporation Device(K2801)In heat exchanger tube be divided into four layers, be respectively wound around central tube outer layer;The electric heater(EH2801)Being configured with can Adjust the power regulating cabinet of electric heater capacity;The bottom of towe evaporator(K2801)Nitrogen return outlet be provided with low-temperature sensor And the low temperature alarm of peripheral hardware is connected on, low temperature alarm connection regulating valve(V2801), and adjusted when less than 0 DEG C Valve(V2801)Aperture so that return to Nitrogen pipe network for room temperature when nitrogen goes out evaporator, reduce diffusing for nitrogen.
3. krypton xenon concentration tower bottom heat of evaporation source system according to claim 1, it is characterised in that bottom of towe evaporator (K2801)It is immersed in the liquid oxygen and liquid krypton xenon mixture of krypton xenon concentration tower bottom, and it is low in the bottom of towe setting of krypton xenon concentration tower Liquid level warning interlocking gear(LIAS2801), the low liquid level warning interlocking gear(LIAS2801)With electric heater(EH2801)Even Lock, and it is less than directly chain closing electric heater during linkage value less than design minimum alarm, liquid level in liquid level(EH2801), Prevent the very few caused dry combustion method of bottom of towe liquid;The electric heater(EH2801)Outlet is provided with temperature interlocking mechanism (TIAS2801), prevent from entering bottom of towe evaporator(K2801)Interior nitrogen temperature is excessive, protects electric heater(EH2801)Fortune Row safety.
CN201711339313.XA 2017-12-14 2017-12-14 A kind of krypton xenon concentration tower bottom heat of evaporation source system Pending CN108031138A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109224491A (en) * 2018-10-31 2019-01-18 浙江新锐空分设备有限公司 Pure krypton xenon tower bottom evaporates heating system in a kind of krypton xenon refining plant

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GB432644A (en) * 1933-02-09 1935-07-31 Air Liquide Process for manufacturing krypton and xenon from atmospheric air
DE1941767A1 (en) * 1968-08-20 1970-02-26 Siderurgie Fse Inst Rech Water supply to a cooling system
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CN206489820U (en) * 2016-05-26 2017-09-12 天津市睿智天成科技发展有限公司 A kind of quaternity rectifying training set
CN106437900A (en) * 2016-08-30 2017-02-22 郭远军 Biomass heat energy power system based on pressurized condensation
CN208785799U (en) * 2017-12-14 2019-04-26 浙江新锐空分设备有限公司 Tower bottom heat of evaporation source system is concentrated in krypton xenon

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109224491A (en) * 2018-10-31 2019-01-18 浙江新锐空分设备有限公司 Pure krypton xenon tower bottom evaporates heating system in a kind of krypton xenon refining plant

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