CN106497698A - A kind of antimicrobial laundry liquid of zwitterion compounding - Google Patents
A kind of antimicrobial laundry liquid of zwitterion compounding Download PDFInfo
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- CN106497698A CN106497698A CN201610814205.2A CN201610814205A CN106497698A CN 106497698 A CN106497698 A CN 106497698A CN 201610814205 A CN201610814205 A CN 201610814205A CN 106497698 A CN106497698 A CN 106497698A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to a kind of antimicrobial laundry liquid of zwitterion compounding.The liquid detergent each component and content are respectively：Account for the dodecylbenzene sodium sulfonate (LAS) of weight 1.0% 9.6%, account for the polyoxyethylenated alcohol sodium sulfate (AES) of weight 1.0% 9.6%, account for the fatty alcohol-polyoxyethylene ether of weight 1.0% 8.0%, account for the Cocamidopropyl amine oxide of weight 1.0% 8.0%, account for the tetradecylmethyl dihydroxy ethyl ammonium bromide of weight 0.2% 1.0%, account for the sodium citrate of weight 2.0%, account for the sodium hydroxide of weight 0.01%, the sodium chloride for accounting for weight 3.0% and the essence for accounting for weight 0.1%.Liquid detergent of the present invention is that clean result is good and the significant zwitterion of antibacterial effect compounds liquid detergent.
Description
Technical field
The invention belongs to composition of detergent field, more particularly to a kind of antimicrobial laundry liquid of zwitterion compounding.
Background technology
At this stage, laundry article has become daily necessities, and as people's level of consumption is improved constantly, its demand is not yet
Disconnected increase, laundry article market has very big development potentiality.At present, the market with powder laundry detergent and liquid detergent is mainly
Main.Powder laundry detergent preparation process needs to add substantial amounts of auxiliary agent, and powder drying process is compared with power consumption, and dissolubility is poor.Phase
Than for, liquid detergent is then without disadvantages mentioned above, and which has, and compatibility is good, can dissolve complete, do not injure skin and medicated clothing etc.
Advantage.Therefore, increasing laundry user tends to use liquid detergent.
Yarn fabric is one of approach of microorganisms spreading, and people inevitably touch of all kinds in daily life
Microorganism, this causes the daily chemical products with antibacterial functions increasingly to be favored by people.At present, antimicrobial laundry liquid by
Gradually develop, which can suppress the microorganisms such as antibacterial growing on medicated clothing, for people's daily life health, healthy and resistance
Disconnected transmission of disease has important practical significance.It is well known that quaternary ammonium salt has certain antibacterial ability, but such chemical combination
Contain cation on thing molecular structure, easily charge interaction is produced with anion and produce flocculation or precipitate；Wash at present
Clothing liquid great majority adopt anion surfactant, add quaternary ammonium salt easily to make system unstable.
Although row insider explores the disinfecting washing liquid of cationic and anionic surfactant compound use at present,
Explore different formula still significant.
Content of the invention
It is an object of the invention to provide a kind of clean result is good and the significant zwitterion of antibacterial effect compounds liquid detergent.
The object of the present invention is achieved like this：
A kind of antimicrobial laundry liquid of zwitterion compounding, in addition to containing the acceptable composition of liquid detergent, also contains：
Account for liquid detergent weight 5%-12% by polyoxyethylenated alcohol sodium sulfate (AES) and DBSA
The anion surfactant that sodium (LAS) is constituted, and both weight ratios are 1:4-4:1；
Account for being made up of fatty alcohol-polyoxyethylene ether and Cocamidopropyl amine oxide for liquid detergent weight 5%-10%
Nonionic surfactant, and both weight ratios are 1:4-4:1；
Account for tetradecylmethyl dihydroxy ethyl ammonium bromide (TMDAB) cationic surface of liquid detergent weight 0.2%-1.0%
Activating agent；
Liquid detergent of the present invention, its component and its content percentage by weight are respectively：
Instant component and its content optimum percentage by weight are respectively：
The invention has the beneficial effects as follows：
Find through the test of a series of dirt-removing power and anti-microbial property test, as LAS, AES, TMDAB three in formula
Weight when being respectively 4%, 6%, 0.6% and 4%, 6%, 0.8%, the antibiotic property of liquid detergent and dirt-removing power are optimum.This
Bright there is provided a kind of clean result is good and the significant zwitterion of antibacterial effect compounds liquid detergent.
Description of the drawings
Fig. 1 is variation diagram of the active matter content of the present invention with TMDAB contents；
Fig. 2 is variation diagrams of the liquid detergent pH of the present invention with TMDAB contents；
Fig. 3 is liquid detergent foam height figure of the present invention；
Fig. 4 is the dirt-removing power figure of six liquid detergent samples of the invention, wherein (a) white carbon black soiled cotton；(b) albumen soiled cotton；(c)
Sebum soiled cotton；D () three kinds of dirt-removing powers collect.
Specific embodiment
With reference to embodiment, the present invention is described in further detail.
First to each component of antimicrobial laundry liquid of the present invention from making a simple illustration, then the compounding of component is said
Bright.
This patent adds the cationic surfactant tetradecane in the laundry liquid formulation of anionic surfactant system
Ylmethyl dihydroxy ethyl ammonium bromide, finds stable proportioning, then adds other components and is prepared into liquid detergent, then probe into each and matches somebody with somebody
The antibiotic property of side, dirt-removing power, stability and other indexs etc., obtain the laundry liquid formulation of better performances.
Embodiment
The formula of 1 six liquid detergents of table
The making step of liquid detergent is as follows：
70 DEG C of the deionized water is added in material kettle, then according to formulation ratio is by described detergent alkylate
Sodium sulfonate, poly alkyl alcohol ether sodium sulfate, fatty alcohol-polyoxyethylene ether, Cocamidopropyl amine oxide are added thereto, and stirring is
Even obtain solution 1；Treat that 1 temperature of solution is down to 40-45 DEG C, described tetradecylmethyl dihydroxy ethyl bromination is added according to proportioning
Ammonium and sodium chloride；Treat that temperature is down to 35 DEG C, sodium citrate, sodium hydroxide and essence is added according to proportioning.This process notes weighing
Accurately with the moisture for supplementing evaporation.
By taking the making of 2 liquid detergent of formula as an example：The deionized water (temperature is 70 DEG C) of 74.69kg is added to material kettle
In, it is subsequently adding the dodecylbenzene sodium sulfonate of 4.0kg, the poly alkyl alcohol ether sodium sulfate of 6.0kg, the fatty alcohol polyoxy of 5.0kg
The Cocamidopropyl amine oxide of vinyl Ether and 5.0kg, stirs；Treat that solution temperature is down to 40-45 DEG C, according to proportioning plus
Enter the tetradecylmethyl dihydroxy ethyl ammonium bromide and the sodium chloride of 3.0kg of 0.2kg；Treat that temperature is down to 35 DEG C, add 2.0kg's
The essence of sodium citrate, the sodium hydroxide of 0.01kg and 0.1kg.The making step of other formula liquid detergents is similar to formula 2.
First, research and method of testing：
Zwitterion compounds stability：Cationic surfactant tetradecylmethyl dihydroxy ethyl bromine by different proportion
Change ammonium and anion surfactant polyoxyethylenated alcohol sodium sulfate, dodecylbenzene sodium sulfonate and a certain amount of distilled water
Compounded, probed into its stability.
The preparation of liquid detergent:Select several formula of good stability from combination solution, add a certain amount of couplant,
PH adjusting agent, thickening agent, essence, deionized water etc., make liquid detergent.
Liquid detergent sense organ and the measure of physical and chemical index：Liquid detergent outward appearance and the measure of abnormal smells from the patient, and physical and chemical index i.e. heat is steady
Qualitative, pH, the measure of gross activity thing.
The measure of liquid detergent antibiotic property:Determined according to the method that QB/T2378 specifies, stock solution and mass fraction is respectively adopted
For 1% laundry liquor, measure to metal staphylococcuses and colibacillary antibiotic property.
5th, hard water is prepared according to the method for GB/T13174-2008 7.1, liquid detergent is matched somebody with somebody with the hard water for preparing and be diluted to rule
Determine the solution of concentration, GB/13174-2008 test dirt-removing powers are pressed with standard soiled cloth and Terg-O-Tometer.6th, liquid detergent foaming characteristic
Measure：According to the spumescence that the method for GB/T7462-94 tests each laundry liquid formulation, and the height of record start foam, really
Its frothing capacity fixed.
2nd, research and testing procedure：
1. outward appearance and abnormal smells from the patient：Sample of six formulation samples no less than 200ml is respectively measured, clean colourless tool plug is placed in wide
In mouth bottle, observed under non-direct projection optical condition；Respectively take appropriate sample to be differentiated with olfactory sensation in colourless tool wide mouthed bottle.
2. heat stability：Measure six formulation samples respectively each two groups no less than the sample of 100ml, be respectively placed in 250ml
Colourless tool plug wide mouth glass bottle in, a place 24h in the couveuse of (40 ± 2) DEG C, take out and recover to room temperature to observe；
Another places 24h in the refrigerator of (- 5 ± 2) DEG C, takes out and recovers to room temperature to observe.
3. gross activity thing：The measure of gross activity thing is determined by the A methods that GB/T13173-2008 specifies.
4.pH is determined：Carry out according to GB/T6368 prescriptive procedures.Test temperature is 25 DEG C, with the distillation that newly boils and cool down
It is 1% that water prepares the mass concentration of sample solution concentration, determines after mix homogeneously.
5. antibiotic property：Determined according to QB/T2378 regulations, stock solution is respectively adopted and the solution that mass fraction is 1%, effect
Time 20min, determines liquid detergent to escherichia coli (ATCC-8099) and gold-coloured staphylococci respectively using suspension quantitative method
(ATCC-6538) bacteriostasis rate, takes test bacterium solution 0.1ml and is added in 5.ml samples, mix homogeneously timing 20min, then takes mixed
Close liquid 0.5ml to be added in the sterilized PBS test tubes of 4.5ml.Liquid (or suitably 2-3 dilution factor of dilution is sampled after placing 10min
Diluent afterwards) in sterilizing plates, rotate plate makes which full and uniform to 1.0ml.Carry out being down flat after agar solidification plate, then by its
It is placed in constant temperature biochemical cultivation case at 37 DEG C after culture 48h, then takes out observation breeding colony situation.
6. dirt-removing power：Determine by GB/T13174-2008 regulations；Various soiled cottons needed for experiment are cut into 6cm × 6cm
Size test piece, four be one group.250mg/kg hard water need to be used during test, and sample solution concentration is the test solution 1L of 2g/L, with
30 DEG C and fixed rotating speed 120r/min of constant temperature stops after continuing 20min, and rinsing is once dried afterwards, determines the whiteness before and after washing
Value, the detergency for calculating each sample are compared.
7. frothing capacity：According to GB7462,0.25% solution for preparing sample with 2.5mmol/Ca2+ hard water is measured.
2.5mmol/Ca2+ hardness water used is prepared according to QB/T1325.
3rd, experimental result：
1. zwitterion compounds stability
As seen from Table 2, in LAS：In the case that AES is certain, with the raising of TMDAB ratios, compound system begins with
Muddy or precipitation occurs.Work as LAS:AES:TMDAB is 2:3:When 0.5 system do not have muddiness or precipitation occur, afterwards with
The increase of TMDAB amounts, system occur precipitated and separated phenomenon.Therefore, subsequent experimental chooses LAS:AES:TMDAB ratios are 2:3:
0、2:3:0.1、2:3:0.2、2:3:0.3、2:3:0.4、2:3:Six groups of 0.5 are prepared liquid detergent with other compositions and carry out next step
Explore.
2 LAS of table:AES:TMDAB different proportions and the relation of stability
2. heat stability
3 six kinds of LAS containing different proportion of table:AES:The heat stability of TMDAB liquid detergents
As can be seen from Table 3, the liquid detergent for being configured at a temperature of 40 DEG C and -5 DEG C has good stability, liquid detergent is described
Cold-resistant heat resistance is preferable.3. outward appearance and abnormal smells from the patient
Six samples for being configured are all not stratified, without obvious float or precipitation, are the uniform liquids of mechanical impurity.And
Free from extraneous odour, meets the standard of liquid detergent organoleptic indicator.
4 liquid detergent outward appearance of table and abnormal smells from the patient
4. the gross activity thing of liquid detergent
As seen from Figure 1, the active matter content of six samples is all between 15% and 18%, with TMDAB contents
Increase, active matter total content increases by a small margin.Plain edition liquid detergent requires that active matter content is between 15%-25% in formula,
Therefore, the active matter content of six samples used all reaches the physical and chemical index of plain edition liquid detergent active matter content.
5. the pH value of liquid detergent
As seen from Figure 2, the adding proportion of TMDAB does not interfere with system pH substantially.Plain edition liquid detergent is required 25
At DEG C, the pH value of the sample containing 1% mass fraction is less than or equal to 10.5, and therefore the pH value of six liquid detergents meets the requirements.
6. the frothing capacity of liquid detergent
5 foam of table tests effect
Knowable to above chart, the foam performance of six samples has reduction trend by a small margin, is generally more or less the same, sample
1 foam performance is somewhat good.The foam height of six samples is below 135mm, less than standard liquid detergent foam dynamic height, symbol
Close the development trend of liquid detergent.
7. the anti-microbial property of liquid detergent
As can be seen from Table 5 when thinner ratio is 1:When 0, the sterilizing rate of 2,3,4,5,6 pairs of gold-coloured staphylococcis of sample reaches
100%, higher to escherichia coli sterilizing rate is sample 4 and 6, and sterilizing rate reaches 90%；When thinner ratio is 1:When 100, for
Metal staphylococcuses, up to 100%, the sterilizing rate of sample 4 is up to 98% for the sterilizing rate of sample 5 and 6；For escherichia coli, sample 3,4
75% is reached with 6 sterilizing rate；Several liquid detergent samples compare colibacillary effect to the bactericidal effect of gold-coloured staphylococci
Good；As seen from the above analysis, the sterilizing rate of sample 2,3,4,5 and 6 illustrates that sample has sterilization between 70% to 90%
Effect, bactericidal effect preferably sample 4,5 and 6.The antibacterial effect of 6 liquid detergent of table
8. the dirt-removing power of liquid detergent
From fig. 4, it can be seen that six samples are more or less the same to the whiteness value after the process of white carbon black soiled cotton, the whiteness value after decontamination
All between 13.0, illustrate that six kinds of samples are more or less the same to the clean effect of white carbon black soiled cotton；Six samples are to the process of albumen soiled cotton
Whiteness value afterwards slightly decreases trend, clean effect preferably sample 1；Whiteness value after the process of sebum soiled cotton is also presented
The trend being gradually reduced, clean effect most preferably sample 1 for sebum soiled cotton.
The comprehensive above clean effect to white carbon black soiled cotton, albumen soiled cotton, three kinds of cortex soiled cotton is analyzed, generally, six samples
Product all have good clean effect, and wherein 1 dirt-removing power of sample is slightly good.
Claims (3)
1. a kind of antimicrobial laundry liquid of zwitterion compounding, in addition to containing the acceptable composition of liquid detergent, also contains：
Account for the moon being made up of polyoxyethylenated alcohol sodium sulfate and dodecylbenzene sodium sulfonate of liquid detergent weight 5%-12%
Ionic surface active agent, and both weight ratios are 1:4-4:1；
Account for liquid detergent weight 5%-10% by fatty alcohol-polyoxyethylene ether and Cocamidopropyl amine oxide constitute non-from
Sub- surfactant, and both weight ratios are 1:4-4:1；
The tetradecylmethyl dihydroxy ethyl bromination ammonium cationic surfactant of liquid detergent weight 0.2%-1.0% is accounted for, which is tied
Structure formula such as formula I；
2. liquid detergent according to claim 1, it is characterised in that its component and its content percentage by weight are respectively：
3. liquid detergent according to claim 2, it is characterised in that its component and its content percentage by weight are respectively：
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108384650A (en) * | 2018-02-12 | 2018-08-10 | 广州蓝月亮实业有限公司 | A kind of surface activator composition |
| CN110881463A (en) * | 2018-09-07 | 2020-03-17 | 中国科学院武汉植物园 | Method for preventing and treating fungal infection in haematococcus culture by using surfactant |
| CN111065721A (en) * | 2017-10-30 | 2020-04-24 | 花王株式会社 | Bactericidal detergent composition |
| CN112226289A (en) * | 2020-11-05 | 2021-01-15 | 浙江康满家日用品有限公司 | High-detergency antibacterial specific concentrated laundry detergent and preparation method thereof |
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| JP5628537B2 (en) * | 2010-03-18 | 2014-11-19 | 花王株式会社 | Cleaning composition for clothing |
| CN104306176A (en) * | 2014-09-23 | 2015-01-28 | 广州大学 | Quaternary ammonium salt type antibacterial hand washing solution |
| CN105400608A (en) * | 2015-11-27 | 2016-03-16 | 北京市创新精细化工有限责任公司 | Antibacterial laundry detergent |
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| JP5628537B2 (en) * | 2010-03-18 | 2014-11-19 | 花王株式会社 | Cleaning composition for clothing |
| CN103740492A (en) * | 2013-12-27 | 2014-04-23 | 天津天狮生物发展有限公司 | Concentrated washing solution and preparation method thereof |
| CN104306176A (en) * | 2014-09-23 | 2015-01-28 | 广州大学 | Quaternary ammonium salt type antibacterial hand washing solution |
| CN105400608A (en) * | 2015-11-27 | 2016-03-16 | 北京市创新精细化工有限责任公司 | Antibacterial laundry detergent |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111065721A (en) * | 2017-10-30 | 2020-04-24 | 花王株式会社 | Bactericidal detergent composition |
| CN111065721B (en) * | 2017-10-30 | 2021-10-26 | 花王株式会社 | Bactericidal detergent composition |
| CN108384650A (en) * | 2018-02-12 | 2018-08-10 | 广州蓝月亮实业有限公司 | A kind of surface activator composition |
| CN110881463A (en) * | 2018-09-07 | 2020-03-17 | 中国科学院武汉植物园 | Method for preventing and treating fungal infection in haematococcus culture by using surfactant |
| CN110881463B (en) * | 2018-09-07 | 2021-12-03 | 中国科学院武汉植物园 | Method for preventing and treating fungal infection in haematococcus culture by using surfactant |
| CN112226289A (en) * | 2020-11-05 | 2021-01-15 | 浙江康满家日用品有限公司 | High-detergency antibacterial specific concentrated laundry detergent and preparation method thereof |
| CN112226289B (en) * | 2020-11-05 | 2022-06-24 | 浙江康满家日用品有限公司 | Concentrated decontamination and antibacterial laundry detergent and preparation method thereof |
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| CN106497698B (en) | 2019-06-07 |
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