CN101649165A - Ultraviolet curing pressure sensitive adhersive for polyethylene protective film and preparation method thereof - Google Patents
Ultraviolet curing pressure sensitive adhersive for polyethylene protective film and preparation method thereof Download PDFInfo
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- CN101649165A CN101649165A CN200910042244A CN200910042244A CN101649165A CN 101649165 A CN101649165 A CN 101649165A CN 200910042244 A CN200910042244 A CN 200910042244A CN 200910042244 A CN200910042244 A CN 200910042244A CN 101649165 A CN101649165 A CN 101649165A
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- Prior art keywords
- pressure sensitive
- protective film
- acrylate
- ultraviolet curing
- polyethylene protective
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- -1 polyethylene Polymers 0.000 title claims abstract description 55
- 239000004698 Polyethylene Substances 0.000 title claims abstract description 48
- 229920000573 polyethylene Polymers 0.000 title claims abstract description 48
- 230000001681 protective effect Effects 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 33
- 239000002904 solvent Substances 0.000 claims abstract description 18
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 37
- 229920000642 polymer Polymers 0.000 claims description 33
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 24
- 239000000178 monomer Substances 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 14
- 239000003999 initiator Substances 0.000 claims description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 10
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 8
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 8
- 239000012986 chain transfer agent Substances 0.000 claims description 8
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims description 8
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 8
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 6
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims description 5
- NLGDWWCZQDIASO-UHFFFAOYSA-N 2-hydroxy-1-(7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-yl)-2-phenylethanone Chemical compound OC(C(=O)c1cccc2Oc12)c1ccccc1 NLGDWWCZQDIASO-UHFFFAOYSA-N 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 5
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical group C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 5
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims description 5
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 5
- 239000012965 benzophenone Substances 0.000 claims description 5
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 239000003292 glue Substances 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 238000010992 reflux Methods 0.000 claims description 5
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 4
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 4
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 4
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 4
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 claims description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 claims description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 3
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 3
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims description 3
- FSAJWMJJORKPKS-UHFFFAOYSA-N octadecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C=C FSAJWMJJORKPKS-UHFFFAOYSA-N 0.000 claims description 3
- 239000003208 petroleum Substances 0.000 claims description 3
- 239000002023 wood Substances 0.000 claims description 3
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 claims description 2
- NQSLZEHVGKWKAY-UHFFFAOYSA-N 6-methylheptyl 2-methylprop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C(C)=C NQSLZEHVGKWKAY-UHFFFAOYSA-N 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- 238000005336 cracking Methods 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 claims description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 2
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 claims description 2
- ODUCDPQEXGNKDN-UHFFFAOYSA-N nitroxyl Chemical compound O=N ODUCDPQEXGNKDN-UHFFFAOYSA-N 0.000 claims description 2
- 230000002194 synthesizing effect Effects 0.000 claims description 2
- 238000010189 synthetic method Methods 0.000 claims description 2
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 claims description 2
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 claims description 2
- 238000001723 curing Methods 0.000 abstract description 11
- 239000000853 adhesive Substances 0.000 abstract 2
- 230000001070 adhesive effect Effects 0.000 abstract 2
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 238000000016 photochemical curing Methods 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 12
- 239000000758 substrate Substances 0.000 description 10
- 239000012528 membrane Substances 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 108010010803 Gelatin Proteins 0.000 description 3
- 238000003851 corona treatment Methods 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 229920000159 gelatin Polymers 0.000 description 3
- 239000008273 gelatin Substances 0.000 description 3
- 235000019322 gelatine Nutrition 0.000 description 3
- 235000011852 gelatine desserts Nutrition 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 238000000576 coating method Methods 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 241000863032 Trieres Species 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000003913 materials processing Methods 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
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Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
Abstract
The invention discloses an ultraviolet curing pressure sensitive adhersive for the polyethylene protective film and a preparation method thereof. The ultraviolet curing pressure sensitive adhersive comprises the following components by weight percent: 30-80% of acrylate prepolymer, 0.03-4.5% of photoinitiator, 0.2-2.5% of photocuring crosslinking agent, 3-25% of tackifier and 5-40% of solvent. Theultraviolet curing pressure sensitive adhersive disclosed in the invention has good adhesive force to the polyethylene film and can realize good balance among initital adhesive force, peeling strength and cohesive force.
Description
Technical field
The present invention relates to a kind of UV-light solidified pressure-sensitive and preparation method thereof, more particularly, the present invention relates to a kind of ultraviolet curing pressure sensitive adhersive for polyethylene protective film and preparation method thereof.
Background technology
Protective membrane is a kind of surface protection, wrapping material that are used to protect the commodity surface; it is attached to the surface of commodity such as each metalloid, aluminium-plastic panel, plastic plate, coated steel, stainless steel plate, aluminium section bar, stone material, glass, instrument, furniture; make it in manufacturing, transportation, secondary processing, storage and use, protect the surface, avoid commodity to be polluted, scratch and slow down the oxidation on commodity surface.The application of protective membrane, not only can improve product visual appearance, make things convenient for materials processing, also can improve simultaneously the utilization ratio of material, reduce production costs.Existing protective membrane is made up of substrate layer (being generally polyethylene film) and pressure-sensitive adhesive layer (being generally the polyacrylate(s) pressure sensitive adhesive); generally carry out suitability for industrialized production with coating method; promptly on the membranaceous base material that has made; the pressure-sensitive adhesive of coating emulsion attitude or solution state; add heat extraction solvent or dispersion agent then, batch and the film that is protected.
UV-light solidified pressure-sensitive is a kind of special pressure sensitive adhesive, has to solidify quick, advantages such as power consumption is low, heat-resisting water-tolerant, has now become both at home and abroad the competitively focus of research and development.At present existing a lot of bibliographical informations the prescription and preparation method thereof of UV-light solidified pressure-sensitive; as U.S. Pat 3661618, US4181752, US5183833, US4943461, US4223067; Japanese Patent JP62062833, JP01297483, JP200044889 and Chinese patent CN1560166, CN101451055 etc., but all do not relate to the application of UV-light solidified pressure-sensitive in polyethylene protective film.Because the special surface character of polyethylene film; the sticking power of general pressure sensitive adhesive on polyethylene film is poor; and owing to polyethylene protective film needs to tear off after finishing provide protection; therefore do not allow any pressure sensitive adhesive and remain in protected substrate surface, employed pressure sensitive adhesive could satisfy service requirements will reaching good balance aspect initial bonding strength, stripping strength and the force of cohesion.This shows, develop and a kind ofly be applicable to that the UV-light solidified pressure-sensitive of polyethylene protective film is very meaningful.
Summary of the invention
The object of the present invention is to provide a kind of ultraviolet curing pressure sensitive adhersive for polyethylene protective film.This UV-light solidified pressure-sensitive has good sticking power to polyethylene film, can realize the well balanced of initial bonding strength, stripping strength and force of cohesion.
Another object of the present invention is to provide the preparation method of described UV-light solidified pressure-sensitive.
The objective of the invention is to be achieved through the following technical solutions:
A kind of ultraviolet curing pressure sensitive adhersive for polyethylene protective film comprises following component by weight percentage:
Acrylate performed polymer 30～80%;
Light trigger 0.03～4.5%;
Photocured cross-linked dose 0.2～2.5%;
Tackifier 3～25%;
Solvent 5～40%.
Preferably, described ultraviolet curing pressure sensitive adhersive for polyethylene protective film comprises following component by weight percentage:
Acrylate performed polymer 40～70%;
Light trigger 0.5～3.0%;
Photocured cross-linked dose 0.5～2.0%;
Tackifier 6～20%;
Solvent 5～40%.
More preferably, described ultraviolet curing pressure sensitive adhersive for polyethylene protective film comprises following component by weight percentage:
Acrylate performed polymer 50～70%;
Light trigger 1.0～2.0%;
Photocured cross-linked dose 1.0～2.0%;
Tackifier 8～15%;
Solvent 15～40%.
Described light trigger is cracking type or hydrogen-capture-type light initiator, is selected from one or more the mixing in benzoin ether, thioxanthone, benzophenone, keto-amine, the phosphorous benzophenone.This light trigger is used for initiating methacrylates performed polymer and photocured cross-linked dose and reacts, if its consumption very little, pressure sensitive adhesive to hold viscous force too poor, be applied to the easy cull of polyethylene protective film; If its consumption is too big, then the wettability of pressure sensitive adhesive and initial bonding strength are all undesirable, and stripping strength is also lower.
Described photocured cross-linked dose is the mixture of trimethylolpropane trimethacrylate and Dipentaerythritol five acrylate, and both weight ratios are 1: 1～1: 4.This photocured cross-linked dose can provide excellent force of cohesion for pressure sensitive adhesive, be to guarantee that UV-light solidified pressure-sensitive is applied on the polyethylene protective film the not key factor of cull, if its consumption is very little, pressure sensitive adhesive to hold viscous force too poor, the easy cull of prepared polyethylene protective film; If its consumption is too big, then the wettability of pressure sensitive adhesive and initial bonding strength are too poor.
Described tackifier are selected from one or more the mixing in rosin, staybelite, rosin ester, hydrogenated wood rosin glycerol ester, terpine resin and the petroleum resin, wherein are preferably hydrogenated wood rosin glycerol ester.These tackifier are used to increase the wettability and the initial bonding strength of pressure sensitive adhesive, if its consumption very little, the wettability of pressure sensitive adhesive and initial bonding strength are too poor, and the sticking power on polyethylene film is also undesirable; If its consumption is too big, then pressure sensitive adhesive to hold viscous force too poor, be applied to the easy cull of polyethylene protective film.
Described acrylate performed polymer is the main component of pressure sensitive adhesive, if its consumption very little, pressure sensitive adhesive to hold viscous force too poor, be applied to the easy cull of polyethylene protective film; If its consumption is too big, then the initial bonding strength of pressure sensitive adhesive is relatively poor.In the present invention, described acrylate performed polymer comprises following component by weight percentage:
Soft monomer 25～45%;
Hard monomer 2～15%;
Function monomer 1～5%;
Chain-transfer agent 0.01～0.5%;
Initiator 0.05～1.0%;
Solvent 35～70%.
Preferably, described acrylate performed polymer comprises following component by weight percentage:
Soft monomer 30～40%;
Hard monomer 4～10%;
Function monomer 2～4.5%;
Chain-transfer agent 0.1～0.35%;
Initiator 0.2～0.6%;
Solvent 45～60%.
In acrylate performed polymer of the present invention, described soft monomer is selected from one or more the mixing in ethyl propenoate, butyl acrylate, Isooctyl acrylate monomer, Isooctyl methacrylate, lauryl acrylate and the octadecyl acrylate, wherein is preferably the mixture of ethyl propenoate, butyl acrylate and Isooctyl acrylate monomer.This soft monomer constitutes the soft chain segment of polymkeric substance, and for pressure sensitive adhesive provides suitable wettability and tack, if its consumption very little, the wettability of pressure sensitive adhesive and initial bonding strength are too poor; If its consumption is too big, then pressure sensitive adhesive to hold viscous force too poor, be not suitable for being applied on the polyethylene protective film.
In acrylate performed polymer of the present invention, described hard monomer is selected from one or more the mixing in methyl acrylate, methyl methacrylate, butyl methacrylate, vinylbenzene and the vinyl cyanide, wherein is preferably the mixture of methyl acrylate and methyl methacrylate.This hard monomer constitutes the hard segment of polymkeric substance, for pressure sensitive adhesive provides good force of cohesion and suitable stripping strength, if its consumption is very little, pressure sensitive adhesive to hold viscous force too poor; If its consumption is too big, then the wettability of pressure sensitive adhesive and initial bonding strength are too poor.
In acrylate performed polymer of the present invention, described function monomer is selected from one or more the mixing in vinylformic acid, methacrylic acid, Hydroxyethyl acrylate, hydroxyethyl methylacrylate, Propylene glycol monoacrylate, n-methylolacrylamide, acrylamide and the glycidyl methacrylate, wherein is preferably the mixture of vinylformic acid, Hydroxyethyl acrylate and glycidyl methacrylate.The adding of this function monomer makes pressure sensitive adhesive have good sticking power on polyethylene film.
In acrylate performed polymer of the present invention, described chain-transfer agent is selected from one or more the mixing in n-dodecyl mercaptan, uncle's lauryl mercaptan and the mercaptoethanol, wherein is preferably n-dodecyl mercaptan.This chain-transfer agent is used to control the molecular weight and the molecular weight distribution of performed polymer, and then the viscosity of control performed polymer, if its consumption very little, the molecular weight of pressure sensitive adhesive is too big, and gelatin viscosity is big, is inconvenient to be coated with; If its consumption is too big, then the molecular weight of pressure sensitive adhesive is too little, and it is too poor to hold viscous force, is applied to the easy cull of polyethylene protective film.
In acrylate performed polymer of the present invention, described initiator is Oxybenzene formyl or Diisopropyl azodicarboxylate.
In the present invention, described solvent is selected from one or more the mixing in dehydrated alcohol, Virahol and the ethyl acetate.In acrylate performed polymer of the present invention, solvent is mainly as polymer solvent and the viscosity that is used to regulate the acrylate performed polymer.And in UV-light solidified pressure-sensitive of the present invention, solvent is mainly used in gelatin viscosity and the spread of regulating pressure sensitive adhesive.
The preparation method of ultraviolet curing pressure sensitive adhersive for polyethylene protective film of the present invention may further comprise the steps:
1) acrylic ester synthesizing performed polymer;
2) acrylate performed polymer, light trigger, photocured cross-linked dose, tackifier and solvent are at room temperature stirred, make the pressure sensitive adhesive glue.
The synthetic method of described acrylate performed polymer is: soft monomer, hard monomer, function monomer, chain-transfer agent and part initiator are mixed; In the reactor of nitrogen protection, add a certain amount of said mixture and whole solvent, treat to add when temperature is increased to 75～85 ℃ the initiator of remainder; After the polyreaction 15～45 minutes, under reflux state, slowly drip the said mixture of residual content, dripped off in 1～4 hour; After dropwising, continued back flow reaction 15～45 minutes; Stopped reaction promptly obtains the acrylate performed polymer after the cooling.
UV-light solidified pressure-sensitive of the present invention has good sticking power to polyethylene film, can realize the well balanced of initial bonding strength, stripping strength and force of cohesion; Because its viscosity is less, be applicable to that net is coated with the production polyethylene protective film, have advantages such as solidify fast and power consumption is low.When ultraviolet curing pressure sensitive adhersive for polyethylene protective film of the present invention was 30% when solid content, gelatin viscosity was less than 800cps; The key technical indexes that it reached is as follows: tack: 〉=No. 4 balls; 180 ° of stripping strength:＞10N/m; Hold viscosity (25 ℃):＞48h does not come off.With adopting the polyethylene protective film of UV-light solidified pressure-sensitive preparation of the present invention to be attached to substrate surface, to place under the room temperature when tearing this protective membrane off after 6 months, no pressure sensitive adhesive remains in substrate surface.
Embodiment
Embodiment one:
11g butyl acrylate, 29g Isooctyl acrylate monomer, 6g methyl methacrylate, 1g vinylformic acid, 1g Hydroxyethyl acrylate, 1.5g glycidyl methacrylate, 0.3g n-dodecyl mercaptan and 0.4g benzoyl peroxide are mixed; In the reactor of nitrogen protection, add 5g said mixture and 50g ethyl acetate, treat to add when temperature is increased to 80 ℃ the 0.1g benzoyl peroxide; After the polyreaction 30 minutes, under reflux state, slowly drip the said mixture of residual content, in about 3 hours, drip off; After dropwising, continued back flow reaction 30 minutes; Stopped reaction promptly obtains the acrylate performed polymer after the cooling.
60g acrylate performed polymer, 1.5g benzoin ether, 0.5g trimethylolpropane trimethacrylate, 1.0g Dipentaerythritol five acrylate, 10g hydrogenated rosin glyceride and 27g ethyl acetate are at room temperature stirred, promptly make UV-light solidified pressure-sensitive glue of the present invention.
Being diluted to solid content with ethyl acetate is 30% o'clock, and the viscosity of prepared UV-light solidified pressure-sensitive is 650cps.
It is that spread is about 5g/m on the 80 μ m process polyethylene film of corona treatment that prepared UV-light solidified pressure-sensitive is evenly coated thickness
2, drying was carried out radiation crosslinking 3 minutes with the 1000W ultraviolet lamp again with except that desolvating in 5 minutes under 80 ℃, tested every performance technologies index of pressure sensitive adhesive according to following testing method:
Tack: the spin slope according to GB 4852-1984 stops method (DOW method), uses Pressuresensitive Tape initial cohesiveness tester to test;
180 ° of stripping strengths:, use the desktop tension testing machine to test according to GB/T 2792-1998;
Hold viscosity:, use adhesive tape confining force trier to test according to GB/T 4851-1988.
The test result of every performance technologies index is as follows:
Tack: No. 5 balls;
180 ° of stripping strength: 73N/m;
Hold viscosity:＞48h.
With adopting the polyethylene protective film of the prepared UV-light solidified pressure-sensitive preparation of present embodiment to be attached to the stainless steel plate substrate surface, to place under the room temperature when tearing this protective membrane off after 6 months, no pressure sensitive adhesive remains in substrate surface.
Embodiment two:
6g ethyl propenoate, 11g butyl acrylate, 18g Isooctyl acrylate monomer, 11g vinylbenzene, 0.5g methacrylic acid, 1g hydroxyethyl methylacrylate, 2g glycidyl methacrylate, uncle's 0.2g lauryl mercaptan and 0.3g benzoyl peroxide are mixed; In the reactor of nitrogen protection, add 5g said mixture and 50g Virahol, treat to add when temperature is increased to 80 ℃ the 0.1g benzoyl peroxide; After the polyreaction 30 minutes, under reflux state, slowly drip the said mixture of residual content, in about 3 hours, drip off; After dropwising, continued back flow reaction 30 minutes; Stopped reaction promptly obtains the acrylate performed polymer after the cooling.
60g acrylate performed polymer, 1g benzoin ether, 1g benzophenone, 0.5g trimethylolpropane trimethacrylate, 1.5g Dipentaerythritol five acrylate, 10g terpine resin and 26g Virahol are at room temperature stirred, promptly make UV-light solidified pressure-sensitive glue of the present invention.
Is 30% o'clock with isopropanol to solid content, and the viscosity of prepared UV-light solidified pressure-sensitive is 530cps.
It is that spread is about 5g/m on the 80 μ m process polyethylene film of corona treatment that prepared UV-light solidified pressure-sensitive is evenly coated thickness
2, drying was carried out radiation crosslinking 3 minutes with the 1000W ultraviolet lamp again with except that desolvating in 5 minutes under 80 ℃, according to every performance technologies index of embodiment one described testing method test pressure sensitive adhesive.Test result is as follows:
Tack: No. 4 balls;
180 ° of stripping strength: 37N/m;
Hold viscosity:＞48h.
With adopting the polyethylene protective film of the prepared UV-light solidified pressure-sensitive preparation of present embodiment to be attached to the stainless steel plate substrate surface, to place under the room temperature when tearing this protective membrane off after 6 months, no pressure sensitive adhesive remains in substrate surface.
Embodiment three:
18g octadecyl acrylate, 20g Isooctyl acrylate monomer, 8g vinyl cyanide, 1.5g vinylformic acid, 1g n-methylolacrylamide, 1.0g glycidyl methacrylate, 0.3g n-dodecyl mercaptan and 0.4g Diisopropyl azodicarboxylate are mixed; In the reactor of nitrogen protection, add 5g said mixture, 30g ethyl acetate and 20g dehydrated alcohol, treat to add when temperature is increased to 80 ℃ the 0.1g Diisopropyl azodicarboxylate; After the polyreaction 30 minutes, under reflux state, slowly drip the said mixture of residual content, in about 3 hours, drip off; After dropwising, continued back flow reaction 30 minutes; Stopped reaction promptly obtains the acrylate performed polymer after the cooling.
55g acrylate performed polymer, 1.5g benzoin ether, 0.5g trimethylolpropane trimethacrylate, 1.3g Dipentaerythritol five acrylate, 8g petroleum resin and 34g ethyl acetate are at room temperature stirred, promptly make UV-light solidified pressure-sensitive glue of the present invention.
Being diluted to solid content with ethyl acetate is 30% o'clock, and the viscosity of prepared UV-light solidified pressure-sensitive is 720cps.
It is that spread is about 5g/m on the 80 μ m process polyethylene film of corona treatment that prepared UV-light solidified pressure-sensitive is evenly coated thickness
2, drying was carried out radiation crosslinking 3 minutes with the 1000W ultraviolet lamp again with except that desolvating in 5 minutes under 80 ℃, according to every performance technologies index of embodiment one described testing method test pressure sensitive adhesive.Test result is as follows:
Tack: No. 4 balls;
180 ° of stripping strength: 65N/m;
Hold viscosity:＞48h.
With adopting the polyethylene protective film of the prepared UV-light solidified pressure-sensitive preparation of present embodiment to be attached to the stainless steel plate substrate surface, to place under the room temperature when tearing this protective membrane off after 6 months, no pressure sensitive adhesive remains in substrate surface.
Claims (13)
1, a kind of ultraviolet curing pressure sensitive adhersive for polyethylene protective film comprises following component by weight percentage:
Acrylate performed polymer 30～80%;
Light trigger 0.03～4.5%;
Photocured cross-linked dose 0.2～2.5%;
Tackifier 3～25%;
Solvent 5～40%.
2, ultraviolet curing pressure sensitive adhersive for polyethylene protective film according to claim 1 is characterized in that, described acrylate performed polymer comprises following component by weight percentage:
Soft monomer 25～45%;
Hard monomer 2～15%;
Function monomer 1～5%;
Chain-transfer agent 0.01～0.5%;
Initiator 0.05～1.0%;
Solvent 35～70%.
3, ultraviolet curing pressure sensitive adhersive for polyethylene protective film according to claim 2 is characterized in that: described soft monomer is selected from one or more the mixing in ethyl propenoate, butyl acrylate, Isooctyl acrylate monomer, Isooctyl methacrylate, lauryl acrylate and the octadecyl acrylate.
4, ultraviolet curing pressure sensitive adhersive for polyethylene protective film according to claim 2 is characterized in that: described hard monomer is selected from one or more the mixing in methyl acrylate, methyl methacrylate, butyl methacrylate, vinylbenzene and the vinyl cyanide.
5, ultraviolet curing pressure sensitive adhersive for polyethylene protective film according to claim 2 is characterized in that: described function monomer is selected from one or more the mixing in vinylformic acid, methacrylic acid, Hydroxyethyl acrylate, hydroxyethyl methylacrylate, Propylene glycol monoacrylate, n-methylolacrylamide, acrylamide and the glycidyl methacrylate.
6, ultraviolet curing pressure sensitive adhersive for polyethylene protective film according to claim 2 is characterized in that: described chain-transfer agent is selected from one or more the mixing in n-dodecyl mercaptan, uncle's lauryl mercaptan and the mercaptoethanol.
7, ultraviolet curing pressure sensitive adhersive for polyethylene protective film according to claim 2 is characterized in that: described initiator is benzoyl peroxide or Diisopropyl azodicarboxylate.
8, ultraviolet curing pressure sensitive adhersive for polyethylene protective film according to claim 1 is characterized in that: described light trigger is cracking type or hydrogen-capture-type light initiator; Be selected from one or more the mixing in benzoin ether, thioxanthone, benzophenone, keto-amine, the phosphorous benzophenone.
9, ultraviolet curing pressure sensitive adhersive for polyethylene protective film according to claim 1; it is characterized in that: the described photocured cross-linked dose of mixture for trimethylolpropane trimethacrylate and Dipentaerythritol five acrylate, both weight ratios are 1: 1～1: 4.
10, ultraviolet curing pressure sensitive adhersive for polyethylene protective film according to claim 1 is characterized in that: described tackifier are selected from one or more the mixing in rosin, staybelite, rosin ester, hydrogenated wood rosin glycerol ester, terpine resin and the petroleum resin.
11, ultraviolet curing pressure sensitive adhersive for polyethylene protective film according to claim 1 and 2 is characterized in that: described solvent is selected from one or more the mixing in dehydrated alcohol, Virahol and the ethyl acetate.
12, the preparation method of the described ultraviolet curing pressure sensitive adhersive for polyethylene protective film of claim 2 may further comprise the steps:
1) acrylic ester synthesizing performed polymer;
2) acrylate performed polymer, light trigger, photocured cross-linked dose, tackifier and solvent are at room temperature stirred, make the pressure sensitive adhesive glue.
13, preparation method according to claim 12 is characterized in that, the synthetic method of described acrylate performed polymer is: soft monomer, hard monomer, function monomer, chain-transfer agent and part initiator are mixed; In the reactor of nitrogen protection, add a certain amount of said mixture and whole solvent, treat to add when temperature is increased to 75～85 ℃ the initiator of remainder; After the polyreaction 15～45 minutes, under reflux state, slowly drip the said mixture of residual content, dripped off in 1～4 hour; After dropwising, continued back flow reaction 15～45 minutes; Stopped reaction promptly obtains the acrylate performed polymer after the cooling.
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Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4943461A (en) * | 1989-02-01 | 1990-07-24 | Minnesota Mining And Manufacturing Company | Radiation-curable pressure-sensitive adhesive having improved adhesion to plasticized vinyl substrates |
| US5183833A (en) * | 1989-11-02 | 1993-02-02 | Adco Products Inc. | Ultraviolet radiation photopolymerization of acrylic ester pressure sensitive adhesive formulation |
| CN1257101A (en) * | 1999-07-13 | 2000-06-21 | 国家淀粉及化学投资控股公司 | Pressure-sensitive adhesion agent capable of being solidifed by ultraviolet |
| CN1260316C (en) * | 2004-03-11 | 2006-06-21 | 刘萍 | UV solidifying pressure sensitive coating capable of stripping and preparation process thereof |
| KR100942363B1 (en) * | 2007-12-03 | 2010-02-12 | 제일모직주식회사 | UV Curable PSAPressure-Sensitive Adhesive Acrylic Binder Resin containing fluorine and Adhesive Tape Using the Same |
-
2009
- 2009-08-31 CN CN2009100422445A patent/CN101649165B/en active Active
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