CN100584899C - Two-component polyurethane type termite-proof and insect-proof putty and its application - Google Patents
Two-component polyurethane type termite-proof and insect-proof putty and its application Download PDFInfo
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- CN100584899C CN100584899C CN200510024318A CN200510024318A CN100584899C CN 100584899 C CN100584899 C CN 100584899C CN 200510024318 A CN200510024318 A CN 200510024318A CN 200510024318 A CN200510024318 A CN 200510024318A CN 100584899 C CN100584899 C CN 100584899C
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- proof
- insect
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- termide
- polyurethane type
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- 229920002635 polyurethane Polymers 0.000 title claims abstract description 13
- 239000004814 polyurethane Substances 0.000 title claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 22
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 7
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 8
- 239000003960 organic solvent Substances 0.000 claims description 8
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- 239000002728 pyrethroid Substances 0.000 claims description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- 239000005892 Deltamethrin Substances 0.000 claims description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 3
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 3
- 229960002483 decamethrin Drugs 0.000 claims description 3
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 229920000180 alkyd Polymers 0.000 claims description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 7
- 241000256602 Isoptera Species 0.000 abstract description 5
- 239000002023 wood Substances 0.000 abstract description 4
- 238000000576 coating method Methods 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000010422 painting Methods 0.000 abstract 2
- 241001149932 Archaeognatha Species 0.000 abstract 1
- 239000012752 auxiliary agent Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000010453 quartz Substances 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000047 product Substances 0.000 description 7
- 239000003814 drug Substances 0.000 description 5
- 238000005034 decoration Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000001680 brushing effect Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 239000003171 wood protecting agent Substances 0.000 description 2
- 239000005946 Cypermethrin Substances 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 229960005424 cypermethrin Drugs 0.000 description 1
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
- Paints Or Removers (AREA)
Abstract
This invention discloses a two-group of polyurethane termite-proof and bug-proof putty. The filming matter, special bug-proof agent, coating auxiliary agent, quartz powder, talcum powder, disintagrated chalk, curing agent in the receipt are used in painting dressing process of furniture and plank floor to form termite and bug-proof putty film to prevent termite and other bristletail to erode carpentry. Its efficiency is high, decorating effect is good, and execution is convenient, it can be used to carpentry processing of modern wood furniture painting and home decorating.
Description
Technical field
The present invention relates to a kind of solvent-borne type woodwork coating, relate in particular to a kind of two-component polyurethane type termide-proof and insect-proof putty.
Background technology
At present, the timber termide-proof and insect-proof is handled mainly based on infusion method and squeegee process, is about to timber and is immersed in the solution that contains medicine, and the solution brushing that maybe will contain medicine is on wood surface.As Chinese patent) low temperature normal temperature quick-drying putty, 93107061.9 and the disclosed technology of document " MA series transparent woodenware priming paint and putty (" New Building Materials ", 2002,2) ".Not only do not have the termide-proof and insect-proof ability, and its shortcoming is that medicine easily runs off, duration of efficacy is short; Medicine is harmful, environmental pollution; Behind the solution of wood surface brushing medicine, influenced lacquer decorations effect to wood surface.Therefore, the termide-proof and insect-proof pesticide application technology of present timber or plank can not be applicable to the application and the decoration design for residence of modern wooden furniture.
Summary of the invention
The technical issues that need to address of the present invention are to disclose a kind of two-component polyurethane type termide-proof and insect-proof putty and application thereof, to overcome the defective that prior art exists.
Two-component polyurethane type termide-proof and insect-proof putty of the present invention is made up of host and solidifying agent, and the weight ratio of host and solidifying agent is 0.3～1: 1, wherein:
The component and the weight part of host comprise:
25～75 parts in the affixture of tolylene diisocyanate and TriMethylolPropane(TMP) or the tripolymer of tolylene diisocyanate or its mixture, 25～75 parts of organic solvents;
The affixture of said tolylene diisocyanate and TriMethylolPropane(TMP) (TMP) can adopt the commercially available prod, and as the product of Korea S Fine Chemical Co., Ltd or Bayer A.G, trade names are L-75; The tripolymer of said tolylene diisocyanate can adopt the commercially available prod, and as the product of Korea S Fine Chemical Co., Ltd or Bayer A.G, trade names are A-50;
Said organic solvent is selected from a kind of or its mixture in N-BUTYL ACETATE, vinyl acetic monomer or the toluene etc.;
The component and the parts by weight of said solidifying agent comprise:
26～38 parts of filmogens;
12～22 parts of organic solvents;
1～6 part of Zinic stearas;
0.50～4.00 part of insect-proof agent;
Organobentonite 1～4
22～52 parts of talcum powder.
Said filmogen is selected from a kind of or its mixture in Synolac, modified alkyd resin or the Malin's acid resin etc.;
Organic solvent is selected from a kind of or its mixture in vinyl acetic monomer, isopropylcarbinol or the dimethylbenzene etc.;
Said insect-proof agent is selected from pyrethroid, and Deltamethrin, effective cypermethrin or tetrabromo Cyano chrysanthemate can adopt the commercially available prod, as the product of Guangdong Province Insects Research Institute;
Organobentonite is a kind of anti-settling agent, adopts the commercially available prod, and as the product of Zhejiang Ward Industrial Co., Ltd., its trade names are BP-183;
The preferred fineness of said talcum powder is 800～1200 purpose products.
Preparation method of the present invention is very simple, and each component of host and each component of solidifying agent are mixed respectively, is uniformly dispersed, and promptly obtains said two-pack two-component polyurethane type termide-proof and insect-proof putty;
During use, be 0.3～1: 1 mixed, and adopt method well known in the art to coat on the timber products that needs construction to get final product according to the weight ratio of host and solidifying agent.
The present invention mainly utilizes filmogen in the prescription, pyrethroid special efficacy insect-proof agent, Zinic stearas, N-BUTYL ACETATE, talcum powder etc., in the coating process of woodworks such as wooden furniture, timber floor, form the termide-proof and insect-proof film, thereby stop termite and of the moth erosion of other moth woodenware.Have advantages such as termide-proof and insect-proof efficient height, decorative effect are good, easy construction, can be used as the application and the decoration design for residence of modern wooden furniture.After testing, termide-proof and insect-proof efficient is 1 grade.
Embodiment
Embodiment 1
Host: (weight part)
1. A-50 (tripolymer of tolylene diisocyanate) is 45 parts, and 2. N-BUTYL ACETATE is 55 parts
Solidifying agent:
1. Synolac is 30 parts, and 2. N-BUTYL ACETATE is 22 parts, and 3. Zinic stearas is 3 parts, and 4. the pyrethroid Deltamethrin is 2 parts, and 5. organobentonite is 3 parts, and 6. 1000 order talcum powder are 40 parts.
Each component of host and each component of solidifying agent are mixed respectively, be uniformly dispersed, promptly obtain said two-pack two-component polyurethane type termide-proof and insect-proof putty, during use, it according to the weight ratio of host and solidifying agent 0.3～1 mixed, coat on the timber products, adopt the method for GB/T 18260-2000 " wood preservative is to termite toxic effect test method " to detect, quality and technical index and harmful substance contents are as follows:
Annotate: 0 grade of expression performance is best, and 1 grade is taken second place, and 5 grades the poorest.
Embodiment 2
Host:
1. L-75 (TDI-TMP affixture) is 45 parts, and 2. N-BUTYL ACETATE is 55 parts
Solidifying agent
1. Synolac is 35 parts, and 2. N-BUTYL ACETATE is 20 parts, and 3. Zinic stearas is 6 parts, and 4. pyrethroid tetrabromo Cyano chrysanthemate is 2 parts, and 5. organobentonite is 2 parts, and 6. 1000 order talcum powder are 35 parts.
The preparation method is identical with embodiment 1 with constructional method, but the blending ratio of host and solidifying agent is 0.3～1: 1.Adopt the method for GB/T 18260-2000 " wood preservative is to termite toxic effect test method " to detect, quality and technical index and harmful substance contents are as follows:
Annotate: 0 grade of expression performance is best, and 1 grade is taken second place, and 5 grades the poorest.
Claims (5)
1. a two-component polyurethane type termide-proof and insect-proof putty is characterized in that, form by host and solidifying agent, wherein:
The component and the weight part of host comprise:
25～75 parts in the affixture of tolylene diisocyanate and TriMethylolPropane(TMP) or the tripolymer of tolylene diisocyanate or its mixture, 25～75 parts of organic solvents;
The organic solvent that adopts in the said host is selected from a kind of or its mixture in N-BUTYL ACETATE, vinyl acetic monomer or the toluene;
The component and the parts by weight of said solidifying agent comprise:
26～38 parts of filmogens;
12～22 parts of organic solvents;
1～6 part of Zinic stearas;
0.5～4 part of insect-proof agent;
1～4 part of organobentonite;
22～52 parts of talcum powder;
The weight ratio of host and solidifying agent is 0.3～1: 1.
Said filmogen is selected from a kind of or its mixture in Synolac, modified alkyd resin or the Malin's acid resin; The organic solvent that adopts in the said solidifying agent is selected from a kind of or its mixture in vinyl acetic monomer, isopropylcarbinol or the dimethylbenzene.
2. two-component polyurethane type termide-proof and insect-proof putty according to claim 1 is characterized in that said insect-proof agent is selected from pyrethroid.
3. two-component polyurethane type termide-proof and insect-proof putty according to claim 2 is characterized in that, pyrethroid is Deltamethrin or tetrabromo Cyano chrysanthemate.
4. two-component polyurethane type termide-proof and insect-proof putty according to claim 1 is characterized in that, said talcous fineness is 800～1200 orders.
5. according to the application of each described two-component polyurethane type termide-proof and insect-proof putty of claim 1～4, it is characterized in that, be used for the application of wooden furniture, timber floor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200510024318A CN100584899C (en) | 2005-03-10 | 2005-03-10 | Two-component polyurethane type termite-proof and insect-proof putty and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200510024318A CN100584899C (en) | 2005-03-10 | 2005-03-10 | Two-component polyurethane type termite-proof and insect-proof putty and its application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1831051A CN1831051A (en) | 2006-09-13 |
| CN100584899C true CN100584899C (en) | 2010-01-27 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200510024318A Active CN100584899C (en) | 2005-03-10 | 2005-03-10 | Two-component polyurethane type termite-proof and insect-proof putty and its application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100584899C (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101386691B (en) * | 2007-09-14 | 2011-04-27 | 上海富臣化工有限公司 | Woodware filler |
| CN102504682B (en) * | 2011-11-03 | 2013-02-13 | 佛山市万正涂料有限公司 | Polyurethane paint applied to woodworking and application thereof |
| CN102417703B (en) * | 2011-11-27 | 2013-04-24 | 石家庄市油漆厂 | Hydroxyl resin composition and solvent-free polyurethane putty containing composition |
| JP6797518B2 (en) * | 2015-10-02 | 2020-12-09 | 未来工業株式会社 | Manufacturing method of synthetic resin pipe |
| CN106614540A (en) * | 2016-10-14 | 2017-05-10 | 广州瑞丰生物科技有限公司 | Ant-killing agent |
-
2005
- 2005-03-10 CN CN200510024318A patent/CN100584899C/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN1831051A (en) | 2006-09-13 |
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| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 201700 No. 579, New District Road, Qingpu Industrial Park, Shanghai Co-patentee after: ZHANCHEN PAINT GROUP Co.,Ltd. Patentee after: Shanghai Vision Chemical Co.,Ltd. Co-patentee after: Beijing Zhanchen Chemical Co.,Ltd. Address before: 201700 No. 579, New District Road, Qingpu Industrial Park, Shanghai Co-patentee before: Shenzhen Zhanchenda Chemical Co.,Ltd. Patentee before: Shanghai Vision Chemical Co.,Ltd. Co-patentee before: Beijing Zhanchen Chemical Co.,Ltd. |
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| C56 | Change in the name or address of the patentee | ||
| CP03 | Change of name, title or address |
Address after: 8555 No. 201700 Shanghai city Qingpu District Songze Avenue Patentee after: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Patentee after: East Limited by Share Ltd exhibition materials Group Co. Patentee after: BEIJING ZHANCHEN NEW MATERIAL Co.,Ltd. Address before: 201700 No. 579, New District Road, Qingpu Industrial Park, Shanghai Patentee before: Shanghai Vision Chemical Co.,Ltd. Patentee before: ZHANCHEN PAINT GROUP Co.,Ltd. Patentee before: Beijing Zhanchen Chemical Co.,Ltd. |
|
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 8555 No. 201700 Shanghai city Qingpu District Songze Avenue Co-patentee after: China Zhanchen New Materials Group Co.,Ltd. Patentee after: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Co-patentee after: Beijing zhanchen Intelligent Property Management Co.,Ltd. Address before: 8555 No. 201700 Shanghai city Qingpu District Songze Avenue Co-patentee before: East Limited by Share Ltd exhibition materials Group Co. Patentee before: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Co-patentee before: BEIJING ZHANCHEN NEW MATERIAL Co.,Ltd. |
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| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200716 Address after: 8555 No. 201700 Shanghai city Qingpu District Songze Avenue Co-patentee after: Zhuhai zhanchen New Material Co.,Ltd. Patentee after: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Address before: 8555 No. 201700 Shanghai city Qingpu District Songze Avenue Co-patentee before: China Zhanchen New Materials Group Co.,Ltd. Patentee before: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Co-patentee before: Beijing zhanchen Intelligent Property Management Co.,Ltd. |