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    Chapter 9 Problem Statements

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    Rashef Mahbub
    This document contains 4 chemistry problems related to mixtures and their properties. Problem 1 asks about calculating volumes needed to make an antifreeze solution with given composition and volume. Problem 2 asks about determining expressions for partial molar enthalpies of a binary liquid system given information about one component. Problem 3 asks about determining expressions for partial molar enthalpies given an equation relating molar enthalpy to composition. Problem 4 provides information about streams in a flow process and asks about calculating entropy changes.

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    Chapter 9 Problem Statements

    Uploaded by

    Rashef Mahbub
    348 views1 page
    This document contains 4 chemistry problems related to mixtures and their properties. Problem 1 asks about calculating volumes needed to make an antifreeze solution with given composition and volume. Problem 2 asks about determining expressions for partial molar enthalpies of a binary liquid system given information about one component. Problem 3 asks about determining expressions for partial molar enthalpies given an equation relating molar enthalpy to composition. Problem 4 provides information about streams in a flow process and asks about calculating entropy changes.

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    Thermo problem

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    This document contains 4 chemistry problems related to mixtures and their properties. Problem 1 asks about calculating volumes needed to make an antifreeze solution with given composition and volume. Problem 2 asks about determining expressions for partial molar enthalpies of a binary liquid system given information about one component. Problem 3 asks about determining expressions for partial molar enthalpies given an equation relating molar enthalpy to composition. Problem 4 provides information about streams in a flow process and asks about calculating entropy changes.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    348 views1 page

    Chapter 9 Problem Statements

    Uploaded by

    Rashef Mahbub
    This document contains 4 chemistry problems related to mixtures and their properties. Problem 1 asks about calculating volumes needed to make an antifreeze solution with given composition and volume. Problem 2 asks about determining expressions for partial molar enthalpies of a binary liquid system given information about one component. Problem 3 asks about determining expressions for partial molar enthalpies given an equation relating molar enthalpy to composition. Problem 4 provides information about streams in a flow process and asks about calculating entropy changes.

    Copyright:

    © All Rights Reserved
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    Download as pdf or txt
    of 1

    CPB 412/512

    Chaper 9 Problem Statements

    Chapter 9: Properties of Mixtures

    Problem 1. The need arises in the laboratory for 2,000 cm3 of antifreeze solution consisting of 30 mol %
    methanol in water. What volumes of pure methanol and of pure water at 25 ◦C must be mixed to form the
    2,000 cm3 of antifreeze, also at 25 ◦C? Partial molar volumes for methanol and water in a 30 mol % methanol
    solution and their pure species molar volumes, both at 25 ◦C, are:
    Methanol(1) V¯1 = 38.632cm3/mol V1 = 40.727cm3/mol
    Water(2) V¯2 = 17.765cm3/mol V2 = 18.068cm3/mol

    Problem 2. We have a binary liquid system of species 1 and 2 at fixed T and P . The partial molar volume
    of species 1 is represented by the equation:
    H̄1 = 420 − 60x21 + 40x31
    where H̄1 is in J/mol. Additionally, we know that the pure component molar enthalpy of species 2 is:
    H2 = 600 J/mol
    Using only the provided information, can you determine expressions for H̄2 and H as functions of x1? If so,
    what are they?

    Problem 3. The molar enthalpy of a binary liquid system of species 1 and 2 at fixed T and P is represented
    by the equation:
    H = 400x1 + 600x2 + x1x2(40x1 + 20x2)

    where H is in J/mol. Determine expressions for H̄1 and H̄2 as functions of x1, numerical values for the pure-
    ∞ ∞
    species enthalpies H1 and H2, and numerical values for the partial enthalpies at infinite dilution H̄1 and H̄2 .

    Problem 4. (Matsoukas Problem 9.10) A flow process is used to split a mixture of carbon monoxide (1)
    and ethane (2) (stream A) into two streams, B and C. Information about the inlet and outlet streams is
    shown in the table below.
    a) Fill out the table.
    b) Calculate the entropy change for this process.
    A (inlet) B (outlet) C (outlet)
    Molar flow (mol/s) 100
    Mol fraction of CO 0.5 0.1 0.9
    P (bar) 100 50 1
    T (◦C) 25 0 25
    S1ig (J/mol·K)
    S2ig (J/mol·K)
    S R (J/mol·K) –3.1 –30 0
    S (J/mol·K)
    Reference states for both components: ideal-gas state at 50 bar, 25 ◦C. Ideal-gas heat capacities: CPig,1 =
    30 J/(mol · K); CPig,2 = 60 J/(mol · K).

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