Lasa et al., 2005 - Google Patents

Chiral-at-metal ruthenium (II) complexes as catalysts in the asymmetric cyclopropanation reaction

Lasa et al., 2005

View PDF
Document ID
9913401408164036610
Author
Lasa M
López P
Cativiela C
Carmona D
Oro L
Publication year
Publication venue
Journal of Molecular Catalysis A: Chemical

External Links

Snippet

A family of five-and six-coordinate chiral-at-metal ruthenium complexes has been examined as catalysts in the asymmetric cyclopropanation reaction of styrene with ethyl diazoacetate. With complexes 5 and 6, good cis-diastereoselectivity and enantioselectivity up to 74% were …
Continue reading at www.academia.edu (PDF) (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B43/00—Formation or introduction of functional groups containing nitrogen
    • C07B43/04—Formation or introduction of functional groups containing nitrogen of amino groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds

Similar Documents

Publication Publication Date Title
Li et al. Asymmetric synthesis of allylic compounds via hydrofunctionalisation and difunctionalisation of dienes, allenes, and alkynes
Weber Phosphorus heterocycles: From laboratory curiosities to ligands in highly efficient catalysts
Masdeu-Bultó et al. Chiral thioether ligands: coordination chemistry and asymmetric catalysis
McCarthy et al. Axially chiral bidentate ligands in asymmetric catalysis
Mršić et al. Asymmetric Hydrogenation of Quinolines Catalyzed by Iridium Complexes of Monodentate BINOL‐Derived Phosphoramidites
Yang et al. Palladium catalyzed asymmetric hydrophosphination of α, β-and α, β, γ, δ-unsaturated malonate esters–efficient control of reactivity, stereo-and regio-selectivity
Ohta et al. BINAP-Ru (II) and BINAP-Rh (I)-catalyzed asymmetric hydrogenation of olefins without heteroatom-functionalities
Ortiz et al. Enantioselective metal-catalyzed reductive coupling of alkynes with carbonyl compounds and imines: convergent construction of allylic alcohols and amines
Akotsi et al. Versatile precursor to ruthenium‐bis (phosphine) hydrogenation catalysts
Margalef et al. The application of pyranoside phosphite-pyridine ligands to enantioselective Ir-catalyzed hydrogenations of highly unfunctionalized olefins
Faller et al. Ruthenium catalyzed enyne cycloisomerizations and hydroxycyclizations with skeletal rearrangement
Michelet et al. Alkoxy-and hydroxycyclization of enynes catalyzed by Pd (II) and Pt (II) catalysts
EP2619162A1 (en) Method for producing alcohol and/or amine from amide compound
Lasa et al. Chiral-at-metal ruthenium (II) complexes as catalysts in the asymmetric cyclopropanation reaction
Källström et al. Asymmetric hydrogenation of tri-substituted alkenes with Ir-NHC-thiazole complexes
Kato et al. Synthesis of DPPP-and DPPPEN-Type Bidentate Ligands by Ring-Opening Diphosphination of Methylene-and Vinylcyclopropanes under Visible-Light-Promoted Photoredox Catalysis
Zhou et al. Synthesis of novel BINOL-derived chiral bisphosphorus ligands and their application in catalytic asymmetric hydrogenation
Hashmi et al. On the Enantioselective Rhodium‐Catalyzed Enyne Cyclization
Sun et al. A New Chiral P, N‐Ligand Derived from 1‐Phenylphospholane‐2‐carboxylic Acid (Phenyl‐P‐proline) for Palladium‐Catalyzed Asymmetric Allylic Substitution Reactions
Englert et al. Conformationally Constrained Diphosphines Derived from (η6-(S)-1-(dimethylamino) indane) Cr (CO) 3: Synthesis and Application in Enantioselective Hydrogenation
Hilt et al. An iron-catalysed chemo-and regioselective tetrahydrofuran synthesis
Ardizzoia et al. New copper (I) and silver (I) triazolato-complexes: Synthesis, reactivity and catalytic activity in olefin cyclopropanation
Castarlenas et al. C H activation of methyl vinyl ketone in Ir (acac){η2-CH2 CHC (O) CH3}(PCy3)
Okamoto et al. A new approach to switching of enantioselectivity in NHC–Cu-catalyzed conjugate addition of alkylzincs to cyclic enones
Zhu et al. Palladium‐catalyzed selective alkoxycarbonylation of N‐vinylphthalimide