Chalais et al., 1985 - Google Patents

Direct Clay‐Catalyzed Friedel‐Crafts Arylation and Chlorination of the Hydrocarbon Adamantane

Chalais et al., 1985

Document ID
278632210073730302
Author
Chalais S
Cornélis A
Gerstmans A
Kołodziejski W
Laszlo P
Mathy A
Métra P
Publication year
Publication venue
Helvetica chimica acta

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Snippet

Multiple chlorinations and arylations at the tertiary positions of adamantane are promoted by FeCl3‐doped K10 montmorillonite in CCl4 or in aromatic solvents. The process, remarkably easy to implement, can be tailored to selective formation of monosubstituted 1‐adamantyl …
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
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    • C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
    • C07C45/46—Friedel-Crafts reactions
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    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
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    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
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