Shchepin et al., 2005 - Google Patents
Reactions of zinc enolates formed from 1-aryl-2-bromo-2-phenylethanone or 2-bromoindanone and zinc, with dimethyl 2-(1-arylmethylene) malonatesShchepin et al., 2005
- Document ID
- 12961953588861850464
- Author
- Shchepin V
- Korzun A
- Vakhrin M
- Shurov S
- Silaichev P
- Ezhikova M
- Kodess M
- Publication year
- Publication venue
- Russian journal of general chemistry
External Links
Snippet
Zinc enolates formed from 1-aryl-2-bromo-2-phenylethanones and zinc react with dimethyl 2- (1-arylmethylene) malonates to afford dimethyl 2-(1, 3-diaryl-3-oxo-2-phenylpropyl) malonates. The latter react with cyclohexylamine, piperidine, or morpholine to give the …
- 239000011701 zinc 0 title abstract description 23
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2101/00—Systems containing only non-condensed rings
- C07C2101/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2101/14—The ring being saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
- C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
- C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2101/00—Systems containing only non-condensed rings
- C07C2101/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2101/16—The ring being unsaturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C-Si linkages
- C07F7/18—Compounds having one or more C-Si linkages as well as one or more C-O-Si linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
- C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2101/00—Systems containing only non-condensed rings
- C07C2101/06—Systems containing only non-condensed rings with a five-membered ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2101/00—Systems containing only non-condensed rings
- C07C2101/02—Systems containing only non-condensed rings with a three-membered ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
- C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/04—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C327/00—Thiocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6025516A (en) | Resolution of 2-hydroxy-3-amino-3-phenylpropionamide and its conversion to C-13 sidechain of taxanes | |
CA3106334C (en) | Method for preparing c-h acidic (meth)acrylates | |
ES2653613T3 (en) | Procedure for the preparation of phenyl carbamate derivatives | |
JPS62223175A (en) | Production of acrylic or methacrylic ester | |
JPS6323834A (en) | Malonic acid derivative | |
Koskinen et al. | Intramolecular cyclopropanation: stereospecific synthesis of (E)-and (Z)-1-aminocyclopropane-1-carboxylic acids | |
Holzapfel et al. | A simple cycloaddition approach to a racemate of the natural sweetener monatin | |
ES2401986T3 (en) | Intermediates for preparation of beta-santalol and derivatives thereof | |
Shchepin et al. | Reactions of zinc enolates formed from 1-aryl-2-bromo-2-phenylethanone or 2-bromoindanone and zinc, with dimethyl 2-(1-arylmethylene) malonates | |
JP3856850B2 (en) | Process for producing optically active aminoketone and aminoalcohol | |
JP5899556B2 (en) | Process for producing ω-bromoacetoacetic acid anilides | |
Mazurkiewicz et al. | Reaction of N-acyl-α-triphenylphosphonio-α-amino acid esters with organic bases: Mechanism of the base-catalyzed nucleophilic substitution of the triphenylphosphonium group | |
Kojima et al. | Synthesis of β‐monosubstituted α, β‐unsaturated amides with Z‐selectivity using diphenylphosphonoacetamides | |
Gimalova et al. | Reaction of 5-Allyl-2, 3, 5-trichloro-4, 4-dimethoxycyclopent-2-en-1-one with amino acids | |
Shakhmaev et al. | Iron-Catalyzed Synthesis of 2-[(2 E)-Hex-2-en-1-yl] cyclopentanone | |
JP3494465B2 (en) | Method for producing optically active α-amino acid derivative | |
RU2186760C2 (en) | METHOD OF SYNTHESIS OF α-ADAMANTYL-CONTAINING ALIPHATIC AND SATURATED AROMATIC KETONES | |
Ovsepyan et al. | 1, 5-Hydride shift in products of Stevens 3, 2-rearrangement of methyl (alkyl)(alkoxycarbonylmethyl)-(3-phenyl-2-propynyl) ammonium bromides | |
Yakubovich et al. | N-benzyl derivatives of valine esters | |
JP5072030B2 (en) | Cyclic α-hydroxy-α, β-unsaturated ketone compound and method for producing cyclopentenone compound | |
Zhchepin et al. | Reactions of 1-Aryl-2, 2-dibromobutan-1-ones with Zinc and Alkyl 6-Bromo-2-oxo-2-H-chromen-3-carboxylate | |
Shchepin et al. | Synthesis of Dimethyl 2-(2-Alkyl-1, 3-diaryl-3-oxopropyl) malonates and Their Reactions with Amines | |
JPS5932444B2 (en) | Improved Arndt-Eistelt synthesis method | |
EP1731495B1 (en) | Process for producing cyclopropane monoacetal derivative and intermediate therefor | |
Shchepin et al. | Synthesis of Alkyl 4-(1-Alkyl-2-aryl-2-oxoethyl)-5, 5-dimethyl-2-oxotetrahydrofuran-3-carboxylates |