Levason et al., 1985 - Google Patents

Synthesis and properties of alkali-metal tetraoxo-osmate (VII) compounds

Levason et al., 1985

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Document ID
10563004235136427004
Author
Levason W
Tajik M
Webster M
Publication year
Publication venue
Journal of the Chemical Society, Dalton Transactions

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The black compounds M [OsO4](M= Na, K, Rb, or Cs) have been prepared from OsO4 and MI in acetone. They are stable in dry air, but disproportionate immediately in aqueous acid solution to OsVIII and OsIV, and in basic solution to OsVIII and OsVI The ir and electronic …
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Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/60Optical properties, e.g. expressed in CIELAB-values
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/30Three-dimensional structures
    • C01P2002/32Three-dimensional structures spinel-type (AB2O4)
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/80Compositional purity

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