WO2020078839A1

WO2020078839A1 - Active substance combinations

Info

Publication number: WO2020078839A1
Application number: PCT/EP2019/077567
Authority: WO
Inventors: Arnd Voerste; Silvia Cerezo-Galvez; Marita JOHN; Stefan Herrmann; Leonardo Pitta; Holger Weckwert
Original assignee: Bayer Aktiengesellschaft
Priority date: 2018-10-16
Filing date: 2019-10-11
Publication date: 2020-04-23
Also published as: AR116728A1

Abstract

The invention relates to active substance combinations that contain known compounds of formula (I) and one or more other active substances and are suitable for controlling animal pests.

Description

Active ingredient combinations

The present application relates to mixtures of the compound of the formula (I) below with at least one further active ingredient or product, which is an insecticide or an acaricide or a nematicide. These mixtures (combinations of active ingredients) are suitable for controlling animal pests.

The compound of formula (I) and processes for its preparation are known from WO 2018/011111 A1, where their use for controlling animal pests is also described. However, the effectiveness and / or breadth of activity and / or the plant tolerance of this compound, in particular with respect to crop plants, is not always sufficient.

It has now been found that active substance combinations (synonymous with “active substance combinations” in the present application are the terms “active substance mixtures” and “mixtures”) containing the compound of the formula (I) and one or more active substances or products from the groups described below are synergistically effective and are suitable for controlling animal pests.

The present invention thus relates to active compound combinations comprising the compound of the formula (I)

and one or more active ingredients or products from the groups described below.

In one embodiment, the active compound combinations according to the invention contain, in addition to the compound of the formula (I), one or more mixing partners from the groups described below.

The active ingredients mentioned here with their "common name" are known and described, for example, in the Pesticide Manual ("The Pesticide Manual" 14th Ed., British Crop Protection Council 2006) or can be researched on the Internet (e.g. http: // www.alanwood.net/pesticides ).

If the short form of the “common name” of an active ingredient is used in the description, all common derivatives, such as the esters and salts, and isomers, in particular optical isomers, are thus included, in particular the commercially available form or forms. Will be with the "common name" Designated ester or salt, this also includes all other common derivatives such as other esters and salts, the free acids and neutral compounds, and isomers, in particular optical isomers, in particular the commercially available form or forms. The chemical compound names given indicate at least one of the compounds included in the “common name”, often a preferred compound.

(1) Acetylcholinesterase (AChE) inhibitors, preferably carbamates selected from Alanycarb, Aldicarb, Bendiocarb, Benfuracarb, Butocarboxim, Butoxycarboxim, Carbaryl, Carbofuran, Carbosulfan, Ethiofencarb, Fenobucarb, Formetanate, Furathiocomyl, Isocarbyl, Isoprocarb, Isoparboc Pirimicarb, Propoxur, Thiodicarb, Thiofanox, Triazamate, Trimethacarb, XMC and Xylylcarb, or Organophosphate selected from Acephat, Azamethiphos, Azinphos-ethyl, Azinphos-methyl, Cadusafos, Chlorethoxyfos, Chlorfenvinphos, Chlormephos-Methylophifos, Chlorpyrosfos, Chlorpyrosfos, Chlorpyrosfos S-methyl, diazinon, dichlorvos / DDVP, dicrotophos, dimethoate, dimethylvinphos, disulfoton, EPN, ethion, ethoprophos, famphur, fenamiphos, fenitrothion, fenthion, fosthiazate, heptenophos, imicyafos, isofenphos, isopropothio-x (meth , Malathion, Mecarbam, Methamidophos, Methidathion, Mevinphos, Monocrotophos, Naled, Omethoate, Oxydemeton-methyl, Parathion-methyl, Phe nthoat, Phorat, Phosalon, Phosmet, Phosphamidon, Phoxim, Pirimiphos-methyl, Profenofos, Propetamphos, Prothiofos, Pyraclofos, Pyridaphenthion, Quinalphos, Sulfotep, Tebupirimfos, Temephos, Terbufos, Tetrachlorvinphiclionophosiazonos, Thi.

(2) GABA-controlled chloride channel blockers, preferably cyclodiene organochlorines selected from chlordane and endosulfan, or phenylpyrazoles (fiprols) selected from ethiprol and fipronil.

(3) sodium channel modulators, preferably pyrethroids selected from acrinathrin, allethrin, d-cis-trans-allethrin, d-trans-allethrin, bifenthrin, bioallethrin, bioallethrin-S-cyclopentenyl isomer, bioresmethrin, cycloprothrin, cyfluthrin, beta -Cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin [(lR) -trans-isomerin], deltamine, deltamine (lR) -isomer], esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, flumethrin, tau-fluvalinate, halfenprox, imiprothrin, kadethrin, momfluorothrin, permethrin, phenothrin [(lR) -transethrine, pyrethrin, pyrethrin , Resmethrin, silafluofen, tefluthrin, tetramethrin, tetramethrin [(IR) isomer], tralomethrin and transfluthrin, or DDT or methoxy chlorine.

(4) Competitive modulators of the nicotinic acetylcholine receptor (nAChR), preferably selected from neonicotinoids include acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam, or nicotine, or Sufoximine selected from sulfoxaflor, or butenolides selected from Flupyradifurone. (5) Allosteric modulators of the nicotinic acetylcholine receptor (nAChR), preferably Spinosyne selected from Spinetoram and Spinosad.

(6) Allosteric modulators of the glutamate-dependent chloride channel (GluCl), preferably avermectine / milbemycine selected from abamectin, emamectin benzoate, lepimectin and milbemectin.

(7) Juvenile hormone mimetics, preferably juvenile hormone analogs selected from hydroprene, kinoprene and methoprene, or fenoxycarb or pyriproxyfen.

(8) Various non-specific (multi-site) inhibitors, preferably alkyl halides selected from methyl bromide and other alkyl halides, or chloropicrin or sulfuryl fluoride or borax or Brechweinstein or methyl isocyanate producers selected from diazomet and metam.

(9) TRPV channel modulators of chordotonic organs selected from pymetrozine and pyrifluquinazone.

(10) Mite growth inhibitors selected from clofentezine, hexythiazox, diflovidazine and etoxazole.

(11) Microbial disruptors of the insect gut membrane selected from Bacillus thuringiensis subspecies israelensis, Bacillus sphaericus, Bacillus thuringiensis subsp aizawai, Bacillus thuringiensis subsp kurstaki, Bacillus thuringiensis subspecies tenebrionis and Bt plant proteins selected from CrylAb, CrylAc, CrylFa, CrylA.105, Cry2Ab, VIP3A , mCry3A, Cry3Ab, Cry3Bb and Cry34Ab 1/35 Abi.

(12) Inhibitors of mitochondrial ATP synthase, preferably ATP disruptors selected from diafenthiuron, or organotin compounds selected from azocyclotin, cyhexatin and fenbutatin oxide, or propargite or tetradifone.

(13) Decouplers of oxidative phosphorylation by disturbing the proton gradient selected from chlorfenapyr, DNOC and sulfluramide.

(14) Blockers of the nicotinic acetylcholine receptor channel selected from bensultap, cartap hydrochloride, thiocyclam and thiosultap sodium.

(15) Chitin biosynthesis inhibitors, type 0, selected from bistrifluron, chlorofluorosuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, fufenuron, novaluron, noviflumuron, teflubenzuron and triflumuron.

(16) Inhibitors of chitin biosynthesis, type 1 selected from buprofezin.

(17) Molting disruptor (especially for dipteras, ie two-winged birds) selected from cyromazine. (18) Ecdysone receptor agonists selected from chromafenozide, halofenozid, methoxyfenozid and tebufenozid.

(19) Octopamine receptor agonists selected from Amitraz.

(20) Mitochondrial complex III electron transport inhibitors selected from hydramethylnon, acequinocyl and fluacrypyrim.

(21) Mitochondrial complex I electron transport inhibitors, preferably METI acaricides selected from fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad and tolfenpyrad, or Rotenon (Derris).

(22) Blocker of the voltage-dependent sodium channel selected from indoxacarb and metaflumizone.

(23) Inhibitors of acetyl-CoA carboxylase, preferably tetronic and tetramic acid derivatives selected from spirodiclofen, spiromesifen and spirotetramate.

(24) Inhibitors of mitochondrial complex IV electron transport, preferably phosphines selected from aluminum phosphide, calcium phosphide, phosphine and zinc phosphide, or cyanides selected from calcium cyanide, potassium cyanide and sodium cyanide.

(25) Inhibitors of mitochondrial complex II electron transport, preferably beta-ketonitrile derivatives selected from cyenopyrafen and cyflumetofen, or carboxanilides selected from pyflubumide.

(28) Ryanodine receptor modulators, preferably diamides selected from chlorantraniliprole, cyantraniliprole and flubendiamide.

(29) Modulators of chordotonic organs (with undefined target structure) selected from flonicamide.

(30) further active ingredients selected from acynonapyr, afidopyropen, afoxolaner, azadirachtin,

Benclothiaz, benzoximate, benzpyrimoxane, bifenazate, broflanilide, bromopropylate, quinomethionate, chloroprallethrin, cryolite, cyclaniliprole, cycloxapride, cyhalodiamid, dicloromezotiaz, dicofol, epsilon-metofluthrin, epsilonifluonomolonulfonolonomolonoxin fluopyram, Flupyrimin, fluralaner, Fluxametamid, Fufenozid, Guadipyr, Heptafluthrin, Imidaclothiz, iprodione, kappa bifenthrin, kappa tefluthrin, Fotilaner, Meperfluthrin, Oxazosulfyl, Paichongding, pyridalyl, Pyrifluquinazon, Pyriminostrobin, Spirobudiclofen, Spiropidion, Tetramethylfluthrin, Tetraniliprole, Tetrachlorantraniliprol, Tigolan, tioxazafen, thiofluoximate, triflumezopyrim and iodomethane; further preparations based on Bacillus firmus (1-1582, BioNeem, Votivo), as well as the following compounds: 1- {2-fluoro-4-methyl-5- [(2,2,2-trifluoroethyl) sulfinyl] phenyl} - 3- (trifluoromethyl) - 1 H-1, 2,4-triazol-5-amine (known from W02006 / 043635) (CAS 885026-50-6), {l '- [(2E) -3- (4-chlorophenyl) prop-2-en-l-yl] -5-fluorospiro [mdol-3,4 ^, -piperidin] -l (2H) -yl} (2-chloropyridin-4-yl) methanone (known from W02003 / 106457) (CAS 637360-23-7), 2-chloro-N- [2- {1 - [ (2E) -3- (4-chlorophenyl) prop-2-en-1-yl] piperidin-4-yl} -4-

(trifluoromethyl) phenyl] isonicotinamide (known from WO2006 / 003494) (CAS 872999-66-1), 3- (4-chloro-2,6-dimethylphenyl) -4-hydroxy-8-methoxy-l, 8-diazaspiro [ 4.5] dec-3-en-2-one (known from WO 2010052161) (CAS 1225292-17-0), 3- (4-chloro-2, 6-dimethylphenyl) -8-methoxy-2-oxo-l, 8-diazaspiro [4.5] dec-3-en-4-yl-ethyl carbonate (known from EP 2647626) (CAS 1440516 42 6), 4- (but-2- in-l-yloxy) -6- (3.5 -dimethylpiperidin-l-yl) -5-fluoropyrimidine (known from W02004 / 099160) (CAS 792914-58-0), PF1364 (known from JP2010 / 018586) (CAS-Reg.No. 1204776-60-2), ( 3E) -3- [l - [(6-chloro-3-pyridyl) methyl] -2-pyridylidene] -l, l, l-trifluoropropan-2-one (known from WO2013 / 144213) (CAS 1461743-15- 6), N- [3- (benzylcarbamoyl) -4-chlorophenyl] -l-methyl-3- (pentafluoroethyl) -4-

(trifluoromethyl) -IH-pyrazole-5-carboxamide (known from WO2010 / 051926) (CAS 1226889-14-0), 5-bromo-4-chloro-N- [4-chloro-2-methyl-6- (methylcarbamoyl ) phenyl] -2- (3-chloro-2-pyridyl) pyrazole-3-carboxamide (known from CN103232431) (CAS 1449220-44-3), 4- [5- (3,5-dichlorophenyl) -4.5 -dihydro- 5- (trifluoromethyl) -3-isoxazolyl] -2-methyl-N- (cis-l-oxido-3-thietanyl) benzamide, 4- [5- (3,5-

Dichlorophenyl) -4,5-dihydro-5- (trifluoromethyl) -3-isoxazolyl] -2-methyl-N- (trans-l-oxido-3-thietanyl) benzamide and 4 - [(5S) -5- (3rd , 5-dichlorophenyl) -4,5-dihydro-5- (trifluoromethyl) -3-isoxazolyl] -2-methyl-N- (cis-l-oxido-3-thietanyl) benzamide (known from WO 2013/050317 Al) (CAS 1332628-83-7), N- [3-chloro-l- (3-pyridinyl) -IH-pyrazol-4-yl] -N-ethyl-3 - [(3,3,3-trifluoropropyl) sulfinyl ] propanamide, (+) - N- [3-chloro-l- (3-pyridinyl) -lH-pyrazol-4-yl] -N-ethyl-3 - [(3,3,3-trifluoropropyl) sulfinyl] propanamide and (-) - N- [3-chloro-1- (3-pyridinyl) -IH-pyrazol-4-yl] -N-ethyl-3 - [(3,3,3-trifluoropropyl) sulfinyl] propanamide (known from WO 2013/162715 A2, WO 2013/162716 A2, US 2014/0213448 A1) (CAS 1477923-37-7), 5- [[(2E) -3-chloro-2-propen-1-yl] amino] - 1 - [2,6-dichloro-4- (trifluoromethyl) phenyl] -4- [(trifluoromethyl) sulfinyl] -lH-pyrazole-3-carbonitrile (known from CN 101337937 A) (CAS 1105672-77-2), 3-bromo-N- [4-chloro-2-methyl-6 - [(methylamino) thioxomethyl] phenyl] -1- (3-chloro-2-pyridinyl) -lH-pyrazole-5-carboxamide, (Liudaiben jiaxuanan, known from CN 103109816 A) (CAS 1232543-85-9); N- [4-chloro-2- [[(1,1-dimethylethyl) amino] carbonyl] -6-methylphenyl] -1 - (3-chloro-2-pyridinyl) -3- (fluoromethoxy) -lH-pyrazole- 5-carboxamide (known from WO 2012/034403 Al) (CAS 1268277-22-0), N- [2- (5-amino-1, 3,4-thiadiazol-2-yl) -4-chloro-6- methylphenyl] -3-bromo-1 - (3-chloro-2-pyridinyl) - 1 H -pyrazole-5-carboxamide (known from WO 2011/085575 Al) (CAS 1233882-22-8), 4- [3- [2,6-dichloro-4- [(3,3-dichloro-2-propen-1-yl) oxy] phenoxy] propoxy] -2-methoxy-6- (trifluoromethyl) pyrimidine (known from CN 101337940 A) ( CAS 1108184-52-6); (2E) - and 2 (Z) -2- [2- (4-cyanophenyl) -l- [3-

(trifluoromethyl) phenyl] ethylidene] -N- [4- (difluoromethoxy) phenyl] hydrazine carboxamide (known from CN 101715774 A) (CAS 1232543-85-9); Cyclopropanecarboxylic acid 3- (2,2-dichloroethenyl) -2,2-dimethyl-4- (1H-benzimidazol-2-yl) phenyl ester (known from CN 103524422 A) (CAS 1542271-46-4); (4aS) -7-chloro-2,5-dihydro-2 - [[(methoxycarbonyl) [4 - [(trifluoromethyl) thio] phenyl] amino] carbonyl] indeno [1,2-e] [1,3,4 ] oxadiazin-4a (3H) -carboxylic acid methyl ester (known from CN 102391261 A) (CAS 1370358-69- 2); 6-deoxy-3-0-ethyl-2,4-di-0-methyl-1 - [N- [4- [1 - [4- (1, 1, 2,2,2-pentafluoroethoxy) phenyl] - 1H-1, 2,4-triazol-3-yl] phenyl] carbamate] -aL-mannopyranose (known from US 2014/0275503 Al) (CAS 1181213-14-8); 8- (2-Cyclopropylmethoxy-4-trifluoromethylphenoxy) -3- (6-trifluoromethylpyridazin-3-yl) -3- azabicyclo [3.2.1] octane (CAS 1253850-56-4), (8-anti) -8- (2-Cyclopropylmethoxy-4-trifluoromethylphenoxy) -3- (6-trifluoromethylpyridazin-3-yl) -3-azabicyclo [3.2.1] octane (CAS 933798-27-7), (8-syn) -8- (2nd -Cyclopropylmethoxy-4-trifluoromethylphenoxy) -3- (6-trifluoromethylpyridazin-3-yl) -3- azabicyclo [3.2.1] octane (known from WO 2007040280 Al, WO 2007040282 Al) (CAS 934001-66-8), N - [3-Chloro-l- (3-pyridinyl) -lH-pyrazol-4-yl] -N-ethyl-3 - [(3,3,3-trifluoropropyl) thio] propanamide (known from WO 2015/058021 Al, WO 2015/058028 Al) (CAS 1477919-27-9) and N- [4- (aminothioxomethyl) -2-methyl-6 - [(methylamino) carbonyl] phenyl] -3-bromo-l- (3- chloro-2-pyridinyl) - lH-pyrazole-5-carboxamide (known from CN 103265527 A) (CAS 1452877-50-7), 5- (l, 3-dioxan-2-yl) -4- [[4- (trifh rmethyl) phenyl] methoxy] pyrimidine (known from WO 2013/115391 Al) (CAS 1449021-97- 9), 3- (4-chloro-2,6-dimethylphenyl) -8-methoxy-l-methyl- 1,8-diazaspiro [4.5] decane-2,4-d ion (known from WO 2014/187846 Al) (CAS 1638765-58-8), 3- (4-chloro-2,6-dimethylphenyl) -8-methoxy-l-methyl-2-oxo-l, 8-diazaspiro [4.5] ethyl dec-3-en-4-yl-carboxylate (known from WO 2010/066780 Al, WO 2011151146 Al) (CAS 1229023-00-0), 4 - [(5S) -5- (3,5- Dichloro-4-fhmrophenyl) -4,5-dihydro-5- (trifluoromethyl) -3-isoxazolyl] -N - [(4R) -2-ethyl-3-oxo-4-isoxazolidinyl] -2-methyl-benzamide ( known from WO 2011/067272, W02013 / 050302) (CAS 1309959-62-3) and compound of the formula

known from WO 06/089633 A2.

Preferred active compound combinations are those in which the compound of the formula (I) is combined with the mixing partners indicated in Table A. The mixing ratios given in Table A are weight ratios. The ratio is to be understood in each case as a compound of formula (I) to mixed partner.

Each of the active ingredient combinations (mixtures) Nos. 1 to 22 is a preferred embodiment of the present invention. Table A:

Compound (II) is the compound of the formula

Surprisingly, the insecticidal and / or acaricidal and / or the nematicidal effect of the Active ingredient combinations according to the invention substantially higher than the sum of the effects of the individual active ingredients. There is an unforeseeable real synergistic effect and not just an addition.

The active compound combinations according to the invention can also be mixed with a further active compound, for example an insecticide / acaricide / nematicide.

The active compound combinations according to the invention are suitable with good plant tolerance, favorable warm-blood toxicity and good environmental compatibility for protecting plants and plant organs, for increasing crop yields, improving the quality of the crop and for combating animal pests, in particular insects, arachnids, helminths, nematodes and molluscs that occur in agriculture, horticulture, animal husbandry, in forests, in gardens and leisure facilities, in the protection of stored goods and materials as well as in the hygiene sector. They can preferably be used as pesticides. They are preferably used to control animal pests in agriculture. They are effective against normally sensitive and resistant species as well as against all or individual stages of development. The pests mentioned above include:

Pests from the Arthropoda strain, in particular from the Arachnida class, for example Acarus spp., Aceria kuko, Aceria sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Amphitetranychus viennensis, Argas spp., Boophilus spp., Brevipalpus spp. , Bryobia graminum, Bryobia praetiosa, Centruroides spp., Chorioptes spp., Dermanyssus gallinae, Dermatophagoides pteronyssinus, Dermatophagoides farinae, Dermacentor spp., Eotetranychus spp., Epitrimerus pyri, Eutetranyusususonophusph spp., Hyalomma spp., Ixodes spp., Latrodectus spp., Loxosceles spp., Metatetranychus spp., Neutrombicula autumnalis, Nuphersa spp., Oligonychus spp., Ornithodorus spp., Ornithonyssus spp., Phonychuschpp., Panonychuschpp multidigituli, Polyphagotarsonemus latus, Psoroptes spp., Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Steneotarsonemus spp., Steneotarsonemus spinki, Tarsonemus spp., Tet ranychus spp., Trombicula alfreddugesi, Vaejovis spp., Vasates lycopersici .; from the class of the Chilopoda, for example Geophilus spp., Scutigera spp .; from the order or class of the Collembola, for example Onychiurus armatus, Sminthurus viridis; from the class of the Diplopoda, for example, Blaniulus guttulatus; from the class of the Insecta, for example from the order of the leaf odea, for example Blattella asahinai, Blattella germanica, Blatta orientalis, Leucophaea maderae (Rhypaobia maderae), Panchlora spp., Parcoblatta spp., Periplaneta spp., Supella longipalpa, Loboptera decipiens, Neombifolia , Pycnoscelus sunnamensis; from the order of the Coleoptera, for example Acalymma vittatum, Acanthoscelides obtectus, Adoretus spp., Aethina tumida, Agelastica alni, Agriotes spp., Alphitobius diaperinus, Amphimallon solstitialis, Anobium punctatum, Anoplophora spp., Anthonomus spp., Anthrenus spp. , Apogonia spp., Atomaria spp., Attagenus spp., Baris caerulescens, Bruchidius obtectus, Bruchus spp., Cassida spp., Cerotoma trifurcata, Ceutorrhynchus spp., Chaetocnema spp., Cleonus mendicus, Conoderus spp., Cosmopolites zealandica, Ctenicera spp., Curculio spp., Cryptolestes ferrugineus, Cryptorhynchus lapathi, Cylindrocopturus spp., Dermestes spp., Diabrotica spp., Dichocrocis spp., Dicladispa armigera, Diloboderus spp., Epicaerachna spp., Epicaerachna spp. , Faustinus spp., Gibbium psylloides, Gnathocerus cornutus, Hellula undalis, Heteronychus arator, Heteronyx spp., Hylamorpha elegans, Hylotrupes bajulus, Hypera postica, Hypomeces squamosus, Hypothenemus spp., Lachnosterna consanguinea, Lasioderma serricorne, Latheticus oryzae, Lathridius spp., Lema spp., Leptinotarsa decemlineata, Leucoptera spp., Lissorhoptrus oryzophilus, Listronotus (= Hyperodes) spp., Lixus spp., Luperodes sppus, Super., Luperomorph. , Melanotus spp., Meligethes aeneus, Melolontha spp., Migdolus spp., Monochamus spp., Naupactus xanthographus, Necrobia spp., Neogalerucella spp., Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus surinamynchisppy. , Oulema melanopus, Oulema oryzae, Oxycetonia jucunda, Phaedon cochleariae, Phyllophaga spp., Phyllophaga helleri, Phyllotreta spp., Popillia japonica, Premnotrypes spp., Prostephanus truncatus, Psylliodes spp., Ptyllizobppis, v. Pt., Pt ., Rhynchophorus ferrugineus, Rhynchophorus palmarum, Sinoxylon perforans, Sitophilus spp., Sitophilus oryzae, Sphenophorus spp., Stegobium paniceum, Sternechus spp., Symphyletes spp., Tanymecus sp p., Tenebrio molitor, Tenebrioides mauretanicus, Tribolium spp., Trogoderma spp., Tychius spp., Xylotrechus spp., Zabrus spp .; from the order of the Diptera, for example Aedes spp., Agromyza spp., Anastrepha spp., Anopheles spp., Asphondylia spp., Bactrocera spp., Bibio hortulanus, Calliphora erythrocephala, Calliphora vicina, Ceratitis spp., Ceratironomus spp. Chrysomyia spp., Chrysops spp., Chrysozona pluvialis, Cochliomyia spp., Contarinia spp., Cordylobia anthropophaga, Cricotopus sylvestris, Culex spp., Culicoides spp., Culiseta spp., Cuterebra spp., Dacus olurae, Dasyneppa, Dasy ., Dermatobia hominis, Drosophila spp., Drosophila suzukii, Echinocnemus spp., Euleia heraclei, Fannia spp., Gasterophilus spp., Glossina spp., Haematopota spp., Hydrellia spp., Hydrellia griseola, Hylobya spp., Hippylia spp. Hypoderma spp., Liriomyza spp., Lucilia spp., Lutzomyia spp., Mansonia spp., Musca spp., Oestrus spp., Oscinella frit, Paratanytarsus spp., Paralauterborniella subcincta, Pegomyia spp., Phlebotomus spp., Phorbia spp. Phormia spp., Piophila casei, Platyparea poeciloptera, Prodiplosis spp., P sila rosae Rhagoletis spp., Sarcophaga spp., Simulium spp., Stomoxys spp., Tabanus spp., Tetanops spp., Tipula spp., Hippoboscoidea (= Pupipara), Toxotrypana curvicauda; from the subordination of Heteroptera e.g. Aelia spp., Anasa tristis, Antestiopsis spp., Boisea spp., Blissus spp., Calocoris spp., Campylomma livida, Cavelerius spp., Cimex spp., Collaria spp., Creontiades dilutus, Dasynus piperis, Dichelops furcatus, Diconocoris hewetti, Dysdercus spp., Euschistus spp., Eurydema spp., Eurygaster spp., Halyomorpha halys, Heliopeltis spp., Horcias nobilellus, Leptocorisa spp., Leptocorisa varicornis, Leptogyllususlossid spp., Macropes excavatus, Megacopta cribraria, Miridae, Monalonion atratum, Nezara spp., Nysius spp., Oebalus spp., Pentomidae, Piesma quadrata, Piezodorus spp., Psallus spp., Pseudacysta persea, Rhodnius sppis., Sahlbergella sing castanea, Scotinophora spp., Stephanitis nashi, Tibraca spp., Triatoma spp .; acaciaebaileyanae from the order of Hemiptera, for example Acizzia, Acizzia dodonaeae, Acizzia uncatoides, Acrida turrita, Acyrthosipon spp., Acrogonia spp., Aeneolamia spp., Agonoscena spp., Aleurocanthus spp., Aleyrodes proletella, Aleurolobus barodensis, Aleurothrixus floccosus, Allocaridara malayensis, Amrasca spp., Anuraphis cardui, Aonidiella spp., Aphanostigma piri, Aphis spp., Arboridia apicalis, spp Arytainilla., Aspidiella spp., spp Aspidiotus., spp Atanus., solani Aulacorthum, Bemisia tabaci, Blastopsylla occidentalis, Boreioglycaspis Melaleucae, Brachycaudus helichrysi, Brachycolus spp., Brevicoryne brassicae, Cacopsylla spp., Calligypona marginata, Capulinia spp., Carneocephala fulgida, Ceratovacuna lanigera, Cercopidae, Ceroplastes spp., Chaetosiphon fragaefoliisisisisomidisis, Chrion Chondaspumisis, Chionaspondisis, Chionaspidisis, Chionaspidisis, Chionaspidisis onion Chrysomphalus ficus, Cicadulina mbila, Coccomytilus half, Coccus spp., Cryptomyzus ribis, Cryptoneossa spp., Cten arytaina spp., Dalbulus spp., Dialeurodes chittendeni, Dialeurodes citri, Diaphorina citri, Diaspis spp., Diuraphis spp., Drosicha spp., Dysaphis spp., Dysmicoccus spp., Empoasca spp., Eriosoma sppura., Eryta spp., Euphyllura spp., Euscelis bilobatus, Ferrisia spp., Fiorinia spp., Furcaspis oceanica, Geococcus coffeae, Glycaspis spp., Heteropsylla cubana, Heteropsylla spinulosa, Homalodisca coagulata, Hyalopterus arundinis, Idaloptera, Hyaloptera spp. , Idioscopus spp., Laodelphax striatellus, Lecanium spp., Lepidosaphes spp., Lipaphis erysimi, Lopholeucaspis japonica, Lycorma delicatula, Macrosiphum spp., Macrosteies facifrons, Mahanarva spp., Melanaphis saccharippium, dirosaphia, Monosaphi costalis, Monelliopsis pecanis, Myzus spp., Nasonovia ribisnigri, Neomaskellia spp., Nephotettix spp., Nettigoniclla spectra, Nilaparvata lugens, Oncometopia spp., Orthezia praelonga, Oxya chinensis, Pachypsylla s pp., Parabemisia myricae, Paratrioza spp., Parlatoria spp., Pemphigus spp., Peregrinus maidis, Perkinsiella spp., Phenacoccus spp., Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp., Pinnaspoc flas sppppopop, spp pyriformis, Pseudaulacaspis pentagona, Pseudococcus spp., Psyllopsis spp., Psylla spp., Pteromalus spp., Pulvinaria spp., Pyrilla spp., Quadraspidiotus spp., Quesada gigas, Rastrococcus spp., Rhopalosiphum spp., titissapia, Saissetia , Schizaphis graminum, Selenaspidus articulatus, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonocephela spp., Tinocallis caryaefoliae, Tomaspis spp., Toxoptera spp., Trialeurodes vaporariorum, Trioza spp., Typhlocyba spp., Unaspis spp., Viteus vitifolii, Zygina spp .; from the order of Hymenoptera, for example Acromyrmex spp., Athalia spp., Atta spp., Camponotus spp., Dolichovespula spp., Diprion spp., Hoplocampa spp., Lasius spp., Linepithema (Iridiomyrmex) humile, Monomorium pharaonis, Paratrechina spp. , Paravespula spp., Plagiolepis spp., Sirex spp., Solenopsis invicta, Tapinoma spp., Technomyrmex albipes, Urocerus spp., Vespa spp., Wasmannia auropunctata, Xeris spp .; from the order of the Isopoda, for example Armadillidium vulgare, Oniscus asellus, Porcellio scaber; from the order of the Isoptera, for example Coptotermes spp., Cornitermes cumulans, Cryptotermes spp., Incisitermes spp., Kalotermes spp., Microtermes obesi, Nasutitermes spp., Odontotermes spp., Porotermes spp., Reticulitermes spp .; from the order of the Lepidoptera, for example Achroia grisella, Acronicta major, Adoxophyes spp., Aedia leucomelas, Agrotis spp., Alabama spp., Amyelois transitella, Anarsia spp., Anticarsia spp., Argyroploce spp., Autographa spp., Barathraacnaicae atra, Borbo cinnara, Bucculatrix thurberiella, Bupalus piniarius, Busseola spp., Cacoecia spp., Caloptilia theivora, Capua reticulana, Carpocapsa pomonella, Carposina niponensis, Cheimatobia brumata, Chilo spp., Choreutisysiaiasia , Cnaphalocerus spp., Cnaphalocrocis medinalis, Cnephasia spp., Conopomorpha spp., Conotrachelus spp., Copitarsia spp., Cydia spp., Dalaca noctuides, Diaphania spp., Diatraea saccharalis, Diparopsis spp., Ecasmasolop lignosellus, Eldana saccharina, Ephestia spp., Epinotia spp., Epiphyas postvittana, Erannis spp., Schwieroviella musculana, Etiella spp., Eudocima spp., Eu a spp., Eupoecilia ambiguella, Euproctis spp., Euxoa spp., Feltia spp., Galleria mellonella, Gracillaria spp., Grapholitha spp., Hedylepta spp., Helicoverpa spp., Heliothis spp., Hofmannophila pseudospretella, Homoeosoma spp., Homona spp., Hyponomeuta padella, Kakivataoria flof ., Laphygma spp., Laspeyresia molesta, Leucinodes orbonalis, Leucoptera spp., Lithocolletis spp., Lithophane antennata, Lobesia spp., Loxagrotis albicosta, Lymantria spp., Lyonetia spp., Malacosoma neustrica, Marucatrapp , Melanitis leda, Mocis spp., Monopis obviella, Mythimna separata, Nemapogon cloacellus, Nymphula spp., Oiketicus spp., Omphisa spp., Operophtera spp., Oria spp., Orthaga spp., Ostrinia spp., Panolis flammea, Parnara spp ., Pectinophora spp., Perileucoptera spp., Phthorimaea spp., Phyllocnistis citrella, Phyllonorycter spp., Pieris spp., Platynota stultana, Plodia interpunctella, Plusia spp., Plutella xylostella, Prays spp., Protodenia spp., Protodenia spp. Pseudaletia spp., Pseudaletia et al nipuncta, Pseudoplusia includens, Pyrausta nubilalis, Rachiplusia nu, Schoenobius spp., Scirpophaga spp., Scirpophaga innotata, Scotia segetum, Sesamia spp., Sesamia inferens, Sparganothis spp., Spodoptera spp., Spodoptera pra., Spodoptera pra. , Stomopteryx subsecivella, Synanthedon spp., Tecia solanivora, Thaumetopoea spp., Thermesia gemmatalis, Tinea cloacella, Tinea pellionella, Tineola bisselliella, Tortrix spp., Trichophaga tapetzella, Trichoplusia spp., Tryporyza incertulas, Tuta absoluta, Tuta absoluta, Vira from the order of the Orthoptera or Saltatoria, for example Acheta domesticus, Dichroplus spp., Gryllotalpa spp., Hieroglyphus spp., Locusta spp., Melanoplus spp., Paratlanticus ussuriensis, Schistocerca gregaria; from the order of the Phthiraptera, for example Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Phylloxera vastatrix, Phtirus pubis, Trichodectes spp .; from the order of Psocoptera, for example Lepinotus spp., Liposcelis spp .; from the order of the Siphonaptera, for example Ceratophyllus spp., Ctenocephalides spp., Pulex irritans, Tunga penetrans, Xenopsylla cheopsis; , Chaetanaphothrips leeuweni from the order of Thysanoptera Anaphothrips obscurus, for example, Baliothrips biformis, Drepanothrips reuteri, Enneothrips flavens, Frankliniella spp., Haplothrips spp., Heliothrips spp., Hercinothrips femoralis, spp Rhipiphorothrips cruentatus, Scirtothrips., Taeniothrips spp cardamomi, Thrips .; from the order of the Zygentoma (= Thysanura), e.g. B. Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus, Thermobia domestica; from the class of the Symphyla, for example Scutigerella spp .;

Pests from the Mollusca tribe, especially from the Bivalvia class, e.g. Dreissena spp., As well as from the gastropoda class e.g. Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Pomacea spp., Succinea spp .;

Animal parasites from the strains of Plathelminthes and Nematoda, e.g. Aelurostrongylus spp., Amidostomum spp., Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Ancylostoma spp., Angiostrongylus spp., Anisakispp., Anisakispp., Anisakispp., Anisakispp. , Baylisascaris spp., Brugia malayi, Brugia timori, Bunostomum spp., Capillaria spp., Chabertia spp., Clonorchis spp., Cooperia spp., Crenosoma spp., Cyathostoma spp., Dicrocoelium spp., Dictyocaulusotylidiumiumiphidium, diphyidium spp., Dirofilaria spp., Dracunculus medinensis, Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Eucoleus spp., Fasciola spp., Fascioloides spp., Fasciolopsis spp., Filaroides spp., Gongylonppact. spp., Gyr. , Haemonchus spp., Heligmosomoides spp., Heterakis spp., Hymenolepis nana, Hyostrongulus spp., Litomosoides spp., Loa Loa, Metastrongylus spp., Metorchis spp., Mesocestoides spp., Moniezia spp., Muellerius spp. , Necator spp., Nematodirus spp., Nippostrongylus spp., Oesophagostomum spp., Ollulanus spp., Onchocerca volvulus, Opisthorchis spp., Oslerus spp.,, Ostertagia spp., Oxyuris spp., Paracapillaria spp., Parafilaria spp., Paragonphalus spp., Parppimphalus spp ., Parascaris spp., Passalurus spp., Protostrongylus spp., Schistosom spp., Setaria spp., Spirocerca spp., Stephanofilaria spp., Stephanurus spp., Strongyloides fuelleborni, Strongyloides stercoralis, Strongylus spp., Syngamus sppata., Taenia , Taenia solium, Teladorsagia spp., Thelazia spp., Toxascaris spp., Toxocara spp., Trichinella spiralis, Trichinella nativa, Trichinella britovi, Trichinella nelsoni, Trichinella pseudopsiralis, Trichobilharzia spp., Trichostruria, spp., Trichostruria, spp. Wuchereria bancrofti;

Plant pests from the Nematoda tribe, i.e. plant-parasitic nematodes, in particular Aglenchus spp., Anguina spp., Aphelenchoides spp., Belonolaimus spp., Bursaphelenchus spp., Cacopaurus spp., Criconemella spp., Criconemoides spp., Ditylenchus spp., Dolichoderic spp., Dolichoderic spp ., Hemicriconemoides spp., Hemicycliophora spp., Heterodera spp., Hoplolaimus spp., Longidorus spp., Meloidogyne spp., Meloinema spp., Nacobbus spp., Neotylenchus spp., Paralongidorus spp., Paraphelenchichus spp. Pratylenchus spp., Pseudohalenchus spp., Psilenchus spp., Punctodera spp., Quinisulcius spp., Radopholus spp., Rotylenchulus spp., Rotylenchus spp., Scutellonema spp., Subanguina spp., Trichodorus spp., Tylenchulus ., Xiphinema spp .;

Furthermore, the order of the Coccidia e.g. Eimeria spp. fight.

Pests from the Aphididae family (tube lice) can be controlled particularly preferably with the active compound combinations according to the invention. Furthermore, pests from the Pemphigidae family (bladder lice) can be controlled with particular preference using the active compound combinations according to the invention. Furthermore, pests from the Phylloxeridae family (root lice) can be controlled particularly preferably with the active compound combinations according to the invention. Furthermore, pests from the Psyllidae family (leaf fleas) can be controlled particularly preferably with the active compound combinations according to the invention. Furthermore, pests from the Coccidae family (cup lice) can be controlled particularly preferably with the active compound combinations according to the invention. Furthermore, pests from the family of the Diaspididae (crested scale lice) can be controlled particularly preferably with the active compound combinations according to the invention. Furthermore, pests from the Ortheziidae family (tube scale lice) can be controlled particularly preferably with the active compound combinations according to the invention. Furthermore, pests from the family of the Pseudococcidae (mealybugs and mealybugs) can be controlled particularly preferably with the active compound combinations according to the invention. Furthermore, pests from the family of the Aleyrodidae (moth scale lice) can be controlled particularly preferably with the active compound combinations according to the invention. It is also particularly preferred to use the inventive Combination of active substances to fight pests from the family Thripidae (thrips). Furthermore, pests from the Cicadellidae family (dwarf cicadas) can be controlled particularly preferably with the active compound combinations according to the invention. Furthermore, pests from the Delphacidae family (leafhopper) can be controlled particularly preferably with the active compound combinations according to the invention. Furthermore, pests from the family of the Pentatomidae (tree bugs) can be controlled particularly preferably with the active compound combinations according to the invention. Furthermore, pests from the family Chrysomelidae (leaf beetles) can be controlled particularly preferably with the active compound combinations according to the invention.

The present invention further relates to formulations and use forms prepared therefrom as crop protection agents and / or pesticides, such as. B. drench, drip and spray broths, comprising at least one of the active compounds according to the invention. If appropriate, the forms of use contain further crop protection agents and / or pesticides and / or adjuvants which improve the action, such as penetration promoters, for. B. vegetative oils such as rapeseed oil, sunflower oil, mineral oils such as paraffin oils, alkyl esters of vegetative fatty acids such as rapeseed oil or soybean methyl or alkanol alkoxylates and / or spreading agents such as alkylsiloxanes and / or salts z. B. organic or inorganic ammonium or phosphomium salts such as ammonium sulfate or diammonium hydrogen phosphate and / or the retention-promoting agents such. B. dioctyl sulfosuccinate or hydroxypropyl guar polymers and / or humectants such as. B. glycerol and / or fertilizers such as ammonium, potassium or phosphorus-containing fertilizers.

Typical formulations are, for example, water-soluble liquids (SL), emulsion concentrates (EC), emulsions in water (EW), suspension concentrates (SC, SE, FS, OD), water-dispersible granules (WG), granules (GR) and capsule concentrates (CS) ; these and other possible types of formulations are described, for example, by Crop Life International and in Pesticide Specifications, Manual on development and use of FAO and WHO specifications for pesticides, FAO Plant Production and Protection Papers - 173, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications, 2004, ISBN: 9251048576. The formulations may contain, in addition to one or more active substances according to the invention, further agrochemical active substances.

These are preferably formulations or use forms which contain auxiliaries, such as, for example, extenders, solvents, promoters of spontaneity, carriers, emulsifiers, dispersants, antifreezes, biocides, thickeners and / or other auxiliaries, such as, for example, adjuvants. An adjuvant in this context is a component that improves the biological effect of the formulation without the component itself having a biological effect. Examples of adjuvants are agents that promote retention, spreading behavior, adherence to the leaf surface or penetration. These formulations are prepared in a known manner, for example by mixing the active ingredients with auxiliaries such as extenders, solvents and / or solid carriers and / or other auxiliaries such as surface-active substances. The formulations are either produced in suitable plants or before or during use.

Auxiliaries which can be used are substances which are suitable for imparting special properties, such as certain physical, technical and / or biological properties, to the formulation of the active ingredient or to the use forms prepared from these formulations (such as usable crop protection agents such as spray liquors or seed dressings).

Suitable extenders are e.g. Water, polar and non-polar organic chemical liquids e.g. from the classes of aromatic and non-aromatic hydrocarbons (such as paraffins, alkylbenzenes, alkylnaphthalines, chlorobenzenes), alcohols and polyols (which may also be substituted, etherified and / or esterified), ketones (such as acetone, cyclohexanone) , Esters (also fats and oils) and (poly) ethers, the simple and substituted amines, amides, lactams (such as N-alkylpyrrolidones) and lactones, the sulfones and sulfoxides (such as dimethyl sulfoxide).

If water is used as an extender, e.g. organic solvents can also be used as auxiliary solvents. The following are essentially suitable as liquid solvents: aromatics, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chlorethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g. Petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol as well as their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethyl formamide and dimethyl sulfoxide, and water.

In principle, all suitable solvents can be used. Suitable solvents are, for example, aromatic hydrocarbons, e.g. Xylene, toluene or alkylnaphthalenes, chlorinated aromatic or aliphatic hydrocarbons, e.g. Chlorobenzene, chloroethylene, or methylene chloride, aliphatic hydrocarbons such as e.g. Cyclohexane, paraffins, petroleum fractions, mineral and vegetable oils, alcohols, e.g. Methanol, ethanol, iso-propanol, butanol or glycol as well as their ethers and esters, ketones such as e.g. Acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethyl sulfoxide and water.

In principle, all suitable carriers can be used. Carrier materials in particular come into question: for example ammonium salts and natural rock powders, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock powders, such as highly disperse silica, aluminum oxide and natural or synthetic silicates, resins, waxes and / or solid fertilizers. Mixtures of such carriers can also be used. When Carriers for granules are possible: e.g. broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite as well as synthetic granules from inorganic and organic flours as well as granules from organic material such as sawdust, paper, coconut shells, corn cobs and tobacco stems.

Liquefied gaseous extenders or solvents can also be used. Particularly suitable extenders or carriers are those which are gaseous at normal temperature and pressure, e.g. Aerosol propellants, such as halogenated hydrocarbons, as well as butane, propane, nitrogen and carbon dioxide.

Examples of emulsifiers and / or foam-generating agents, dispersants or wetting agents with ionic or nonionic properties or mixtures of these surface-active substances are salts of polyacrylic acid, salts of lignosulphonic acid, salts of phenolsulphonic acid or naphthalenesulphonic acid, polycondensates of ethylene oxide with fatty alcohols or with fatty acids or with fatty amines, with substituted phenols (preferably alkylphenols or arylphenols), salts of sulphosuccinic acid esters, taurine derivatives (preferably alkyl taurates), phosphoric acid esters of polyethoxylated alcohols or phenols, fatty acid esters of polyols, and derivatives of the compounds containing sulphates, sulphonates and phosphates, for example Alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates, protein hydrolyzates, lignin sulfite waste liquors and methyl cellulose. The presence of a surface-active substance is advantageous if one of the active ingredients and / or one of the inert carriers is not soluble in water and if the application is carried out in water.

In the formulations and the use forms derived therefrom, dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and nutrient and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc are present.

Stabilizers such as cold stabilizers, preservatives, antioxidants, light stabilizers or other agents which improve chemical and / or physical stability can also be present. Foam-producing agents or defoamers can also be contained.

Furthermore, the formulations and use forms derived therefrom can also contain, as additional auxiliaries, adhesives such as carboxymethyl cellulose, natural and synthetic polymers in the form of powders, granules or latices, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and also natural phospholipids, such as cephalins and lecithins, and synthetic phospholipids. Other auxiliary substances can be mineral and vegetable oils.

If appropriate, further auxiliaries can be contained in the formulations and the use forms derived therefrom. Such additives are, for example, fragrances, protective Colloids, binders, adhesives, thickeners, thixotropic substances, penetration promoters, retention promoters, stabilizers, sequestering agents, complexing agents, humectans, spreading agents. In general, the active ingredients can be combined with any solid or liquid additive which is usually used for formulation purposes.

All substances which reduce the dynamic surface tension, such as dioctyl sulfosuccinate or which increase the visco-elasticity, such as hydroxypropyl guar polymers, are suitable as retention promoters.

In the present context, penetration promoters include all those substances that are usually used to improve the penetration of agrochemical active substances into plants. Penetration promoters are defined in this context by the fact that they penetrate the cuticle of the plant from the (usually aqueous) application broth and / or from the spray coating and can thereby increase the mobility of the active substances in the cuticle. The method described in the literature (Baur et al., 1997, Pesticide Science 51, 131-152) can be used to determine this property. Examples include alcohol alkoxylates such as coconut fat ethoxylate (10) or isotridecyl ethoxylate (12), fatty acid esters such as rapeseed oil or soybean oil methyl esters, fatty amine alkoxylates such as tallowamine ethoxylate (15) or ammonium and / or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate.

According to the invention, all plants and parts of plants can be treated. Plants are understood here to mean all plants and plant populations, such as desired and unwanted wild plants or crop plants (including naturally occurring crop plants). Cultivated plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant cultivars which can or cannot be protected by plant breeders' rights. The plants which can be treated with the active compound combinations according to the invention include, for. B. the following types of plants: turf, vines, cereals, for example wheat, barley, rye, oats, rice, corn and millet, triticale; Beets, for example sugar beets and fodder beets; Fruits, for example pome fruit, stone fruit and soft fruit, for example apples, pears, plums, peaches, almonds, cherries and berries, e.g. B. strawberries, raspberries, blackberries; Legumes, for example beans, lentils, peas and soybeans; Oil crops, for example rapeseed, mustard, poppy seeds, olives, sunflowers, coconut, castor oil plants, cocoa beans and peanuts; Cucumber plants, for example pumpkin, cucumber and melons; Fiber plants, for example cotton, flax, hemp and jute; Citrus fruits, for example oranges, lemons, grapefruits and mandarins; Vegetables, for example spinach, (head) salad, asparagus, cabbage, carrots, onions, tomatoes, potatoes and peppers; Laurel plants, for example avocado, cinnamomum, camphor, or plants such as tobacco, nuts, coffee, eggplant, sugar cane, tea, pepper, grapevines, hops, bananas, natural rubber plants and ornamental plants, for example flowers, shrubs, deciduous trees and conifers such as conifers. This list is not a limitation.

Plant parts are to be understood to mean all above-ground and underground parts and organs of the plants, such as shoots, leaves, flowers and roots, examples being leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds and roots, tubers and rhizomes . The plant parts also include crops and vegetative and generative propagation material, for example cuttings, tubers, rhiozomes, offshoots and seeds.

The treatment of the plants and parts of plants according to the invention with the active compound combinations is carried out directly or by acting on their surroundings, living space or storage space according to the customary treatment methods, e.g. by dipping, (spraying) spraying, (spraying) spraying, sprinkling, evaporating, atomizing, pouring on, atomizing, (scattering) scattering, foaming, brushing on spreading, injecting, watering (drenching), drip irrigation and on propagation material, in particular in the case of seeds, also by means of dry pickling, wet pickling, slurry pickling, incrustation, single or multi-layer coating.

A preferred direct treatment for the plants is leaf application, i.e. the active compound combinations according to the invention are applied to the foliage, the treatment frequency and the application rate being adapted to the infestation pressure of the respective pest.

In the case of systemically active compounds, the active compound combinations according to the invention reach the plants via the root system. The plants are then treated by the action of the active compound combinations according to the invention on the plant's habitat. This can be, for example, by drenching, mixing into the soil or the nutrient solution, i.e. the location of the plant (e.g. soil or hydroponic systems) is impregnated with a liquid form of the active compound combinations according to the invention, or by the soil application, i.e. the active compound combinations according to the invention are introduced in solid form (e.g. in the form of granules) into the location of the plants. In the case of water rice crops, this can also be done by metering the invention into a solid application form (e.g. as granules) in a flooded rice field.

The present invention therefore also relates in particular to a method for protecting seed and germinating plants from attack by pests by treating the seed with the active compound combinations according to the invention. The method according to the invention for protecting seeds and germinating plants from attack by pests comprises a method in which the seeds are treated simultaneously with the active ingredient of the formula (I) and mixing partners in one operation. It also includes a process in which the seed is mixed with the at different times Active ingredient of formula (I) and mixed partners is treated.

The invention also relates to the use of the active compound combinations according to the invention for the treatment of seed to protect the seed and the plant resulting therefrom from animal pests.

Furthermore, the invention relates to seeds which have been treated with the active compound combinations according to the invention for protection against animal pests. The invention also relates to seeds which were treated at the same time with the active ingredient of the formula (I) and mixing partner. The invention further relates to seeds which have been treated at different times with the active ingredient of the formula (I) and mixing partner. In the case of seeds which have been treated at different times with the active ingredient of the formula (I) and mixing partner, the individual active ingredients of the agent according to the invention can be present in different layers on the seed. The layers which contain the active ingredient of the formula (I) and mixing partners can, if appropriate, be separated by an intermediate layer. The invention also relates to seeds in which the active ingredient of the formula (I) and mixing partner are applied as part of a coating or as a further layer or further layers in addition to a coating.

The invention also relates to seeds which, after treatment with the active compound combinations according to the invention, are subjected to a film coating process in order to avoid dust abrasion on the seeds.

One of the advantages of the present invention is that, because of the special systemic properties of the agents according to the invention, the treatment of the seeds with these agents not only protects the seeds themselves, but also the plants resulting therefrom after emergence from animal pests. In this way, the immediate treatment of the crop at the time of sowing or shortly thereafter can be omitted.

Another advantage can be seen in the fact that the treatment of the seed with the active ingredient combinations according to the invention can promote germination and emergence of the treated seed.

It is also to be regarded as advantageous that active ingredient combinations according to the invention can also be used in particular with transgenic seeds.

As already mentioned above, all plants and their parts can be treated according to the invention. In a preferred embodiment, plant species and plant cultivars and their parts occurring wildly or obtained by conventional organic breeding methods, such as crossing or protoplast fusion, are treated. The traditional propagation and breeding methods can by one or more biotechnological methods, such as the use of double haploids, random and directed mutagenesis, molecular or genetic markers, or supported or supplemented by bioengineering methods and genetic engineering methods. In a further preferred embodiment, transgenic plants and plant cultivars which have been obtained by genetic engineering methods, if appropriate in combination with conventional methods (genetic modified organisms) and their parts are treated. Genetically modified plants (or transgenic plants) are plants in which a heterologous gene has been stably integrated into the genome. The term "heterologous gene" essentially means a gene that is provided or assembled outside of the plant or plant cell and that, when introduced into the nuclear genome, the chloroplast genome or the mitochondrial genome, gives the transformed plant new or improved agronomic or other characteristics imparts by expressing a protein or polypeptide of interest or by down-regulating or switching off another gene that is present in the plant or other genes that are present in the plant (e.g. by means of antisense technology, cosuppression technology , RNA interference technology (RNAi technology) or microRNA technology (miRNA technology)). A heterologous gene that has been integrated into the genome is also called a transgene. A transgene that has been integrated into the plant genome is called a transformation event or transgenic event. The terms "parts" or "parts of plants" or "plant parts" were explained above.

Plants of the plant varieties which are in each case commercially available or in use are particularly preferably treated according to the invention.

Depending on the plant species or plant cultivars, their location and growth conditions (soils, climate, growing season, nutrition), the treatment according to the invention can also cause superadditive ("synergistic") effects. For example, reduced application rates and / or widening of the spectrum of action and / or an increase in the action of the substances and agents which can be used according to the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to water or soil salt content, increased flowering performance , easier harvesting, acceleration of ripening, higher crop yields, larger fruits, higher plant height, more intense green color, of the leaf, earlier flowering, higher quality and / or higher nutritional value of the harvested products, higher sugar concentration in the fruit, higher storability and / or workability of the Harvest products possible that go beyond the expected effects.

The preferred transgenic (genetically engineered) plants or plant cultivars to be treated according to the invention include all plants which have received genetic material through the genetic engineering modification, which gives these plants particularly advantageous, valuable properties (“traits”). Examples of such properties are better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or against water or soil salt content, increased flowering performance, easier harvesting, acceleration of ripening, higher harvest yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or workability of the harvested products. Further and particularly highlighted examples of such properties are an increased defense of the plants against animal and microbial pests, such as against insects, mites, phytopathogenic fungi, bacteria and / or viruses, and an increased tolerance of the plants to certain herbicidal active ingredients. Examples of transgenic plants are the important crop plants, such as cereals (wheat, rice), corn, soybeans, potatoes, cotton, rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soybeans, potatoes and cotton and rapeseed are highlighted. The traits are particularly emphasized as the increased defense of the plants against insects by toxins which arise in the plants, in particular those which are caused by the genetic material from Bacillus thuringiensis (for example by the genes CrylA (a), CrylA (b), CrylA (c), CryllA, CrylllA, CryIIIB2, Cry9c, Cry2Ab, Cry3Bb and CrylF as well as their combinations) are produced in the plants (hereinafter "Bt plants"). The properties (“traits”) which are particularly emphasized are the increased tolerance of the plants to certain herbicidal active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (for example “PAT” gene). The genes imparting the desired properties (“traits”) can also occur in combinations with one another in the transgenic plants. Examples of "Bt plants" are corn varieties, cotton varieties, soy varieties and potato varieties that are sold under the trade names YIELD GARD ^® (e.g. corn, cotton, soy), KnockOut ^® (e.g. corn), StarLink ^® (e.g. corn), Bollgard ^® ( Cotton), Nucotn ^® (cotton) and NewLeaf ^® (potato). Examples of herbicide-tolerant plants are maize varieties, cotton varieties and soy varieties which are marketed under the trade names Roundup Ready ^® (tolerance to glyphosate e.g. corn, cotton, soybeans), Liberty Link ^® (tolerance to phosphinotricin, e.g. rapeseed), IMI ^® (tolerance to Imidazolinone) and STS ^® (tolerance to sulfonylureas such as maize). Herbicide-resistant plants (bred conventionally for herbicide tolerance) plants also sold under the name Clearfield ^® varieties (eg maize) are mentioned. Of course, these statements also apply to plant varieties developed in the future or coming onto the market in the future with these or future-developed genetic properties ("traits").

The plants listed can be treated particularly advantageously according to the invention with the active compound mixtures according to the invention. The preferred ranges given above for the active ingredient combinations also apply to the treatment of these plants. Plant treatment with the active ingredient combinations specifically listed in the present text should be particularly emphasized.

The good effects of the active compound combinations according to the invention can be seen from the examples below. While the individual active ingredients have weaknesses in their effects, the combinations show an effect that goes beyond a simple summation of effects. A synergistic effect is always present when the effect of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients.

Examples of use

Formula for the degree of killing of a combination of two active substances The expected effect for a given combination of two active substances can, according to S.R. Colby ("Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 15, 20-22, 1967) can be calculated as follows:

If

X the degree of killing, expressed in% of the untreated control, when using the

Active ingredient A in an application rate of m g / ha or in a concentration of m ppm means

Y the degree of killing, expressed in% of the untreated control, when using the

Active ingredient B in an application rate of ng / ha or in a concentration of n ppm and E means the degree of destruction, expressed in% of the untreated control, when using the active ingredients A and B in application rates of m and ng / ha or in a concentration of m and n means ppm, then is

If the actual kill rate is greater than the calculated kill rate (E), the combination is superadditive in its kill, i.e. there is a synergistic effect.

Schneider - Orelli: Formula for calculating the corrected activity% in pesticide

To attempt

% Mortality treated -% mortality untreated

Corrected% = (_) x 100

100 - Mortality in% control Example A

Phaedon cochleariae - spray test

Solvent: 78.0 parts by weight of acetone

1.5 parts by weight of dimethylformamide emulsifier: alkylaryl polyglycol ether

To produce a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and the mixture is filled with water which contains an emulsifier concentration of 1000 ppm until the desired concentration is reached. Further test concentrations are obtained by dilution with water containing emulsifier. Chinese cabbage leaf slices (Brassica pekinensis) are sprayed with an active ingredient preparation of the desired concentration and, after drying, are populated with larvae of the horseradish leaf beetle (Phaedon cochleariae).

After the desired time, the effect is determined in%. 100% means that all beetle larvae have been killed; 0% means that no beetle larvae have been killed. The determined killing values are calculated using the Colby formula.

In this test, the following combinations of active substances according to the present application showed a synergistically enhanced effectiveness compared to the individually used active substances:

Table A-1: Phaedon cochleariae - spray test

Table A-2: Phaedon cochleariae spray test

* found = effect found; ** calc. = Effect calculated according to the Colby formula

Example B

Spodoptera frugiperda - spray test

Solvent: 78.0 parts by weight of acetone, 1.5 parts by weight of dimethylformamide

Emulsifier: alkylaryl polyglycol ether

To produce a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and the mixture is filled with water which contains an emulsifier concentration of 1000 ppm until the desired concentration is reached. Further test concentrations are obtained by dilution with water containing emulsifier.

Corn leaf disks (Zea mays) are sprayed with an active ingredient preparation of the desired concentration and, after drying, are covered with caterpillars of the army worm (Spodoptera frugiperda).

After the desired time, the effect is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillar has been killed. The determined killing values are calculated using the Colby formula.

In this test, the following combination of active ingredients according to the present application showed a synergistically enhanced effectiveness compared to the individually used active ingredients: Table B1: Spodoptera frugiperda - spray test

Table B-2: Spodoptera frugiperda spray test

‘’ Values using Schneider-Orelli are determined in Example C.

Mvzus persicae - spray test

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: alkylary polyglycol ether

Savoy plants (Brassica oleracea), which are heavily infested with the green peach aphid (Myzus persicae), are treated by spraying with the active ingredient preparation in the desired concentration. After the desired time, the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed. The determined kill rates are calculated using the Colby formula.

Experiment I

Table C-l. L: Myzus persicae - spray test

Table C-1.2: Myzus persicae - spray test

Table C-1.3: Myzus persicae - spray test

Table C-1.4: Myzus persicae - spray test

* found = effect found; ** calc. = Effect calculated according to the Colby formula Exneriment TT

Table C-2.1: Myzus persicae - spray test

Table C-2.2: Myzus persicae - spray test

Table C-2.3: Myzus persicae - spray test

Table C-2.4: Myzus persicae - spray test

* found = effect found; ** ago. = Effect calculated according to the Colby formula

Example D

Aphis gossypii - spray test

Solvent: 7 parts by weight of dimethylformamide. Emulsifier: alkylaryl polyglycol ether

To produce a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and the mixture is filled with water which contains an emulsifier concentration of 1000 ppm until the desired concentration is reached. Further test concentrations are obtained by dilution with water containing emulsifier. Cotton plants (Gossypium hirsutum) that are heavily infested with the cotton aphid (Aphis gossypii) are sprayed with an active ingredient preparation of the desired concentration.

After the desired time, the kill is determined in%. 100% means that all aphids have been killed and 0% means that no aphids have been killed. The determined killing values are calculated using the Colby formula. In this test, the following combinations of active substances according to the present application showed a synergistically enhanced effectiveness compared to the individually used active substances:

Table D-1: Aphis gossypii - spray test

Table D-2: Aphis gossypii spray test

Table D-3: Aphis gossypii - spray test

Table D-4: Aphis gossypii spray test

Example E

Nilaparvata lugens spray application

Emulsifier: alkylaryl polyglycol ether

To produce a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and the mixture is filled with water which contains an emulsifier concentration of 1000 ppm until the desired concentration is reached. To prepare further test concentrations, dilute with water containing emulsifier.

Rice plants (Oryza sativa) are sprayed with the active ingredient preparation of the desired concentration and then infected with the brown-backed leafhopper (Nilaparvata lugens).

After the desired time, the effect is determined in%. 100% means that all aphids have been killed and 0% means that no aphids have been killed. The determined killing values are calculated using the Colby formula.

Table E: Nilaparvata lugens - spray test

Claims

1. Active substance mixtures containing the compound of the formula (I)

and at least one further active ingredient or product which is an insecticide or an acaricide or a nematicide.

2. Active ingredient mixture according to claim 1, selected from the following list

wherein compound (II) is the compound of formula

3. Plant protection agents containing an active ingredient combination according to claim 1 or 2, extenders and / or surface-active substances.

4. A process for the preparation of a crop protection agent according to claim 3, characterized in that an active ingredient combination according to claim 1 or 2 is mixed with extenders and / or surface-active substances.

5. Use of an active ingredient combination according to claim 1 or 2 or a crop protection agent according to claim 3 for combating animal pests.

6. Use of an active ingredient combination according to claim 1 or 2 or one

Plant protection product according to claim 3 for the treatment of seeds.

7. Use of an active ingredient combination according to claim 1 or 2 or one

Plant protection product according to claim 3 on transgenic plants.