WO2020039228A1 - The method for the production of nano-emulsion of water with heavy fluid fuels - Google Patents

The method for the production of nano-emulsion of water with heavy fluid fuels Download PDF

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Publication number
WO2020039228A1
WO2020039228A1 PCT/IB2018/056262 IB2018056262W WO2020039228A1 WO 2020039228 A1 WO2020039228 A1 WO 2020039228A1 IB 2018056262 W IB2018056262 W IB 2018056262W WO 2020039228 A1 WO2020039228 A1 WO 2020039228A1
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WO
WIPO (PCT)
Prior art keywords
emulsion
water
fuel
mixer
reactor
Prior art date
Application number
PCT/IB2018/056262
Other languages
French (fr)
Inventor
Hadi KHODAVERDYAN
Original Assignee
Khodaverdyan Hadi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Khodaverdyan Hadi filed Critical Khodaverdyan Hadi
Priority to EP18930612.9A priority Critical patent/EP3837039A4/en
Priority to PCT/IB2018/056262 priority patent/WO2020039228A1/en
Publication of WO2020039228A1 publication Critical patent/WO2020039228A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/40Mixing liquids with liquids; Emulsifying
    • B01F23/49Mixing systems, i.e. flow charts or diagrams
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/40Mixing liquids with liquids; Emulsifying
    • B01F23/41Emulsifying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/40Mixing liquids with liquids; Emulsifying
    • B01F23/41Emulsifying
    • B01F23/413Homogenising a raw emulsion or making monodisperse or fine emulsions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/40Mixing liquids with liquids; Emulsifying
    • B01F23/41Emulsifying
    • B01F23/414Emulsifying characterised by the internal structure of the emulsion
    • B01F23/4145Emulsions of oils, e.g. fuel, and water
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40Static mixers
    • B01F25/42Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/43Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
    • B01F25/431Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor
    • B01F25/4314Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor with helical baffles
    • B01F25/43141Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor with helical baffles composed of consecutive sections of helical formed elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/27Mixers with stator-rotor systems, e.g. with intermeshing teeth or cylinders or having orifices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00Other mixers; Mixing plants; Combinations of mixers
    • B01F33/80Mixing plants; Combinations of mixers
    • B01F33/82Combinations of dissimilar mixers
    • B01F33/821Combinations of dissimilar mixers with consecutive receptacles
    • B01F33/8212Combinations of dissimilar mixers with consecutive receptacles with moving and non-moving stirring devices

Definitions

  • This invention is about fossil fuels including fuels with relatively larger molecules, mixing procedure of water with fuel and required equipment for it and the aforementioned fuels' functions.
  • emulsion is the procedure through which materials such as water, oil or gasoline, which cannot be combined by one another, by nature, are mixed in order to make a temporary suspension by reducing particles' size.
  • suspension recovers into its early form as time passes by, in which materials used to be in two separate phases. The time during which suspension switches back into its earlier version is dependent on the viscosity type, particles' size and mixed materials' combination ratio as well as the temperature .In particular, if the particulate matters' size reduces to sub-micron, the mixture tends to keep the fluid state of emulsion for longer time.
  • Water emulsion in fuel can improve combustion efficiency while burning.
  • the mechanism is such that water particles get evaporated and dispersed in an explosive manner as a result of heating.
  • One gram of evaporated water gets 1244 times as voluminous and in its course disperses the surrounding fuel particles, which accordingly reduces the fuel particles' size. Smaller fuel particles have larger surface contact with oxygen and finally will finally improve the combustion efficiency.
  • the present invention produces the fuel-water emulsion with a particular method and a reactor. Due to the longevity of produced emulsion's homogenized state and very small size of suspended particulate matters in emulsion, it is applicable in most of industrial cases.
  • This invention is a set of equipment and method for the production of Nano- Emulsion of fuel and water, in which, according to fig.1 , fuel enters the emulsion production line through entrance pipe (fig.1 , partl) and later enters circulation pump by passing through control valve which is connected to production line management structure (fig.1 , part3) Afterwards, it is dispatched to maintenance repository.(fig.l part l l)In the meantime, fuel enters the repository through electronic control valve. The fuel is drained to main fuel tank after passing the dosing system by the help of a pump( fig.l part 8) Exit path through which the fuel mixed with additives is led to main pump's dosing by a pumping aid is designed under the tank.
  • the fluid tends to switch back to its earlier state, which in turn triggers the microscopic hits against existing particles and accordingly causes strife as a result of this shock.
  • the created cavitation causes the particles to get pulverized and mixed together.
  • the more the particles stay inside the reactor the smaller the particles become and more homogenized the mixture gets.
  • created particles in this invention are much smaller than micro scale and settle among one another in a homogenized manner, the existing force between two different fluids' molecules is stronger than molecular attraction, which henceforth hinders the union of similar particles and prevents the emulsion to get two-phase status.
  • Figure number one shows the production line's layout according to the cavitation reactor
  • Figure Number two shows cavitation reactor's secondary wall.
  • Figure Number three shows cavitation reactor's rotor Figure Number four displays stator and secondary wall of the reactor Figure Number five provides a perspective of the mixer Figure Number six is explosive map of cavitation reactor Figure Number seven shows full-fledged view of the cavitation reactor.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Feeding And Controlling Fuel (AREA)

Abstract

The present invention produces the fuel-water emulsion with a particular method and a reactor. Due to the longevity of produced emulsion`s homogenized state and very small size of suspended particulate matters in 5 emulsion, it is applicable in most of industrial cases.

Description

The method for the Production of Nano-Emulsion of water with heavy fluid fuels
TECHNICAL FIELD:
This invention is about fossil fuels including fuels with relatively larger molecules, mixing procedure of water with fuel and required equipment for it and the aforementioned fuels' functions.
BACKGROUND OF THE INVENTION:
One of these methods is the production of water-fuel emulsion. According to this method, emulsion is the procedure through which materials such as water, oil or gasoline, which cannot be combined by one another, by nature, are mixed in order to make a temporary suspension by reducing particles' size. However, suspension recovers into its early form as time passes by, in which materials used to be in two separate phases. The time during which suspension switches back into its earlier version is dependent on the viscosity type, particles' size and mixed materials' combination ratio as well as the temperature .In particular, if the particulate matters' size reduces to sub-micron, the mixture tends to keep the fluid state of emulsion for longer time. More amount of added water to the fuel leads to the production of fuel emulsion in the water whereas the reverse combination ratio would lead to water emulsion in fuel. Water emulsion in fuel can improve combustion efficiency while burning. The mechanism is such that water particles get evaporated and dispersed in an explosive manner as a result of heating. One gram of evaporated water gets 1244 times as voluminous and in its course disperses the surrounding fuel particles, which accordingly reduces the fuel particles' size. Smaller fuel particles have larger surface contact with oxygen and finally will finally improve the combustion efficiency.
Among the water emulsion in fuel samples is Mr. Viktor Maschenko's invention with registration number of EP20100741445 in which using a reactor cavitation, mixture of Mazut fuel with water of 120 degrees and stirring a turbulence in the flow, between the rotor wall and stator that is located on stator of parallel cavities, brings about the mixture of fuel and water and accordingly the creation of water emulsion in fuel.
In registration file of another invention with registration number of WO2013169669 Al by Victor Gurin, Mindaugas MACIJAUSKAS, Pavel Pikul and Serguei Permikov applied to register an invention about the system of producing water emulsion in fuel, in which they make use of the advantages of water emulsion in fuel by mixing gas, water, and fuel and injecting the produced mixture to the engine. In the past, many cases of fossil fuels which have been turned to emulsion by water have been examined. Hence, as regards the problems occurred by previous inventions are the quick switch of the fuel into two distinct phases and the large size of the fuel particles in the emulsion.
THE DESCRIPTION OF THE INVENTION: For resolving the problems mentioned above, the present invention produces the fuel-water emulsion with a particular method and a reactor. Due to the longevity of produced emulsion's homogenized state and very small size of suspended particulate matters in emulsion, it is applicable in most of industrial cases.
This invention is a set of equipment and method for the production of Nano- Emulsion of fuel and water, in which, according to fig.1 , fuel enters the emulsion production line through entrance pipe (fig.1 , partl) and later enters circulation pump by passing through control valve which is connected to production line management structure (fig.1 , part3) Afterwards, it is dispatched to maintenance repository.(fig.l part l l)In the meantime, fuel enters the repository through electronic control valve. The fuel is drained to main fuel tank after passing the dosing system by the help of a pump( fig.l part 8) Exit path through which the fuel mixed with additives is led to main pump's dosing by a pumping aid is designed under the tank. Passing through the dosing system enables the supervision of fuel inflow rate to the mixer (fig.l, part l2)On the other hand, pure water finds its path to the control valve through the pipeline in fig.l part 20 and by entering control valve (fig.l part 19)and enters water repository rank (fig.l, part 17) Later, water can be ushered to water pump dosing(fig.l, part 14) by passing through the control valve(fig.l, part 13) Afterwards, water enters the mixer with specific volume flow rate.(fig.l, part 12)
Inside the mixer (fig.5), there occurs a great deal of turbulence due to the numerous layers with corresponding angles and flowing movement. Occurring turbulence causes the water and fuel particles to mix and accordingly a heterogeneous emulsion with bigger particles. The pass of primary fluid emulsion through control valves(fig.l, parts 21& 25) helps to control the staying duration of primary emulsion inside cavitation(fig.l, part 22). According to the flow rate of water (discharge) from reactor by pump and outflow discharge rate which is adjusted by control valve (fig.l, part26), the product can be utilized directly or dispatched to the reservoir tank.
Taking the electric current flow rate in production line and the chance to increase it in comparison to the exit as well as for controlling the staying duration of materials in each section, another exit (fit.l, part 23) from secondary wall of the reactor in the form of bypass is sent inside the line before the mixer.
The mixture of fuel and water is thrown out of the rotor holes when they enter cavitation reactor because of high velocity of rotor. They also tend to move towards the inner crust of stator. In the meantime, due to having a bigger diameter of rotor's surface in comparison to bed diameter of rotor's holes, linear speed of fluid in created column in rotor's holes is higher than its speed in the hole’s bed. Henceforth, acceleration difference of the fluid in the created column and rotor holes’ bed, fluid undergoes a microscopic extension which in turn leads to the formation of vacuum bubbles. After the fluid containing vacuum microscopic bubbles to the environment between rotor and stator, the fluid tends to switch back to its earlier state, which in turn triggers the microscopic hits against existing particles and accordingly causes strife as a result of this shock. In other words, the created cavitation causes the particles to get pulverized and mixed together. The more the particles stay inside the reactor, the smaller the particles become and more homogenized the mixture gets. Bearing in mind that created particles in this invention are much smaller than micro scale and settle among one another in a homogenized manner, the existing force between two different fluids' molecules is stronger than molecular attraction, which henceforth hinders the union of similar particles and prevents the emulsion to get two-phase status.
BRIEF DESCRIPTION OF FIGURES: Figure number one shows the production line's layout according to the cavitation reactor
Figure Number two shows cavitation reactor's secondary wall.
Figure Number three shows cavitation reactor's rotor Figure Number four displays stator and secondary wall of the reactor Figure Number five provides a perspective of the mixer Figure Number six is explosive map of cavitation reactor Figure Number seven shows full-fledged view of the cavitation reactor.
Figure Number eight is a side-view of the mixer
Figure Number nine is a complete view of the mixer

Claims

CLAIMS:
1- The invention of a method for the production of Nano-Emulsion compound of water with heavy fluid fuels including at least a fuel tank, a water tank, two dosing pumps, a multi-layered mixer and a cavitation reactor.
2- The invention of number one claim in which the inflow rate of input material in system's entry can be stipulated by control valves.
3- The invention of the number one claim that the fluid input rate can be measured by any system and equipment
4- The invention of the first claim that necessary additives to the fuel can be added in primary fuel tank by a secondary mixer and tank
5- The invention of number one claim that production procedure can be managed relying on a computer system.
6- The invention of number one claim that any kind of mixer or a multi- layered mixer can be used in mixer section.
7- The invention of the first claim that any reactors can be used in cavitation reactor section
8- The invention of number one claim that creation and destruction of vacuum bubbles in cavitation reactor causes the fluid particles to crumble and hence produce a homogenous emulsion.
9- The invention of number one claim that a cavitation reactor is equipped with by-pass system
10- The invention of number one claim that the suspended particles' size of emulsion is in a direct relation to the staying duration of materials in the reactor.
PCT/IB2018/056262 2018-08-19 2018-08-19 The method for the production of nano-emulsion of water with heavy fluid fuels WO2020039228A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP18930612.9A EP3837039A4 (en) 2018-08-19 2018-08-19 The method for the production of nano-emulsion of water with heavy fluid fuels
PCT/IB2018/056262 WO2020039228A1 (en) 2018-08-19 2018-08-19 The method for the production of nano-emulsion of water with heavy fluid fuels

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IB2018/056262 WO2020039228A1 (en) 2018-08-19 2018-08-19 The method for the production of nano-emulsion of water with heavy fluid fuels

Publications (1)

Publication Number Publication Date
WO2020039228A1 true WO2020039228A1 (en) 2020-02-27

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020096456A1 (en) * 2000-11-11 2002-07-25 Wan-Mo Kim Wastewater treatment system using cavitating waterjet
WO2006120687A2 (en) * 2005-05-11 2006-11-16 Nano-Em Ltd. High-power sono-chemical reactor
WO2015053649A1 (en) * 2013-10-11 2015-04-16 Владимир Ильич КОРМИЛИЦЫН Cavitation reactor (variants)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4127332A (en) * 1976-11-19 1978-11-28 Daedalean Associates, Inc. Homogenizing method and apparatus
JP2009208002A (en) * 2008-03-04 2009-09-17 Toshiba Plant Systems & Services Corp Method and apparatus for preparing emulsion

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020096456A1 (en) * 2000-11-11 2002-07-25 Wan-Mo Kim Wastewater treatment system using cavitating waterjet
WO2006120687A2 (en) * 2005-05-11 2006-11-16 Nano-Em Ltd. High-power sono-chemical reactor
WO2015053649A1 (en) * 2013-10-11 2015-04-16 Владимир Ильич КОРМИЛИЦЫН Cavitation reactor (variants)

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Publication number Publication date
EP3837039A1 (en) 2021-06-23
EP3837039A4 (en) 2022-04-20

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