WO2017085594A3 - Process and catalyst for conversion of co2 to syngas for a simultaneous production of olefins and methanol - Google Patents

Process and catalyst for conversion of co2 to syngas for a simultaneous production of olefins and methanol Download PDF

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Publication number
WO2017085594A3
WO2017085594A3 PCT/IB2016/056757 IB2016056757W WO2017085594A3 WO 2017085594 A3 WO2017085594 A3 WO 2017085594A3 IB 2016056757 W IB2016056757 W IB 2016056757W WO 2017085594 A3 WO2017085594 A3 WO 2017085594A3
Authority
WO
WIPO (PCT)
Prior art keywords
methanol
syngas
olefins
catalyst
conversion
Prior art date
Application number
PCT/IB2016/056757
Other languages
French (fr)
Other versions
WO2017085594A2 (en
Inventor
Aghaddin Mamedov
Clark Rea
Original Assignee
Sabic Global Technologies B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sabic Global Technologies B.V. filed Critical Sabic Global Technologies B.V.
Publication of WO2017085594A2 publication Critical patent/WO2017085594A2/en
Publication of WO2017085594A3 publication Critical patent/WO2017085594A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/12—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon dioxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/026—Increasing the carbon monoxide content, e.g. reverse water-gas shift [RWGS]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Methods of preparing olefins and methanol from syngas are provided. Methods include hydrogenation of carbon dioxide (CO2) via a reverse water gas shift (RWGS) reaction, separation of unreacted CO2, followed by simultaneous Fischer-Tropsch synthesis (FT) and methanol synthesis. Catalysts include Zn-Cu-Zr-O.
PCT/IB2016/056757 2015-11-16 2016-11-09 Process and catalyst for conversion of co2 to syngas for a simultaneous production of olefins and methanol WO2017085594A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201562255968P 2015-11-16 2015-11-16
US62/255,968 2015-11-16

Publications (2)

Publication Number Publication Date
WO2017085594A2 WO2017085594A2 (en) 2017-05-26
WO2017085594A3 true WO2017085594A3 (en) 2017-06-29

Family

ID=58718469

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2016/056757 WO2017085594A2 (en) 2015-11-16 2016-11-09 Process and catalyst for conversion of co2 to syngas for a simultaneous production of olefins and methanol

Country Status (1)

Country Link
WO (1) WO2017085594A2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109420486A (en) * 2017-08-29 2019-03-05 中国科学院大连化学物理研究所 The ZnZrO of synthesizing methanol by hydrogenating carbon dioxidexSolid solution catalyst and preparation and application
US11787759B2 (en) 2021-08-12 2023-10-17 Saudi Arabian Oil Company Dimethyl ether production via dry reforming and dimethyl ether synthesis in a vessel
US11578016B1 (en) 2021-08-12 2023-02-14 Saudi Arabian Oil Company Olefin production via dry reforming and olefin synthesis in a vessel
US11718575B2 (en) 2021-08-12 2023-08-08 Saudi Arabian Oil Company Methanol production via dry reforming and methanol synthesis in a vessel
US11827521B2 (en) 2021-12-14 2023-11-28 Industrial Technology Research Institute Method for selectively chemically reducing CO2 to form CO
US11617981B1 (en) 2022-01-03 2023-04-04 Saudi Arabian Oil Company Method for capturing CO2 with assisted vapor compression

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4393144A (en) * 1978-09-20 1983-07-12 Sagami Chemical Research Center Method for producing methanol
US4663305A (en) * 1984-06-29 1987-05-05 Exxon Research And Engineering Company Cobalt catalysts for the conversion of methanol and for Fischer-Tropsch synthesis to produce hydrocarbons
US6486219B1 (en) * 2000-09-27 2002-11-26 Exxonmobil Chemical Patents, Inc. Methanol, olefin, and hydrocarbon synthesis process
US20070244348A1 (en) * 2006-04-13 2007-10-18 Michel Molinier Process for producing olefin product from syngas
US7364650B2 (en) * 2001-11-06 2008-04-29 Bp Exploration Operating Company Limited Fischer tropsch composition and process
US8591861B2 (en) * 2007-04-18 2013-11-26 Schlumberger Technology Corporation Hydrogenating pre-reformer in synthesis gas production processes
US8961829B2 (en) * 2007-04-27 2015-02-24 Saudi Basic Industries Corporation Catalytic hyrogenation of carbon dioxide into syngas mixture

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4393144A (en) * 1978-09-20 1983-07-12 Sagami Chemical Research Center Method for producing methanol
US4663305A (en) * 1984-06-29 1987-05-05 Exxon Research And Engineering Company Cobalt catalysts for the conversion of methanol and for Fischer-Tropsch synthesis to produce hydrocarbons
US6486219B1 (en) * 2000-09-27 2002-11-26 Exxonmobil Chemical Patents, Inc. Methanol, olefin, and hydrocarbon synthesis process
US7364650B2 (en) * 2001-11-06 2008-04-29 Bp Exploration Operating Company Limited Fischer tropsch composition and process
US20070244348A1 (en) * 2006-04-13 2007-10-18 Michel Molinier Process for producing olefin product from syngas
US8591861B2 (en) * 2007-04-18 2013-11-26 Schlumberger Technology Corporation Hydrogenating pre-reformer in synthesis gas production processes
US8961829B2 (en) * 2007-04-27 2015-02-24 Saudi Basic Industries Corporation Catalytic hyrogenation of carbon dioxide into syngas mixture

Also Published As

Publication number Publication date
WO2017085594A2 (en) 2017-05-26

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