WO2017050821A1 - Composition contenant des tensioactifs pour le traitement de textiles avec un colorant - Google Patents

Composition contenant des tensioactifs pour le traitement de textiles avec un colorant Download PDF

Info

Publication number
WO2017050821A1
WO2017050821A1 PCT/EP2016/072415 EP2016072415W WO2017050821A1 WO 2017050821 A1 WO2017050821 A1 WO 2017050821A1 EP 2016072415 W EP2016072415 W EP 2016072415W WO 2017050821 A1 WO2017050821 A1 WO 2017050821A1
Authority
WO
WIPO (PCT)
Prior art keywords
dye
textiles
surfactant
composition
acid
Prior art date
Application number
PCT/EP2016/072415
Other languages
German (de)
English (en)
Inventor
Walter Heberlein
Ingrid Kraus
Dilek MADENCI
Regina Stehr
Original Assignee
Henkel Ag & Co. Kgaa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Ag & Co. Kgaa filed Critical Henkel Ag & Co. Kgaa
Publication of WO2017050821A1 publication Critical patent/WO2017050821A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents

Definitions

  • the present invention relates to a surfactant-containing composition, a process for its preparation and the use of the composition for the treatment of textiles.
  • Textiles and especially garments are exposed to UV radiation in everyday life.
  • colored textiles may lose their luminosity, since the UV radiation affects the dyes in the textile.
  • wearing on the body and the associated absorption of body perspiration, such as sweat also causes the textiles to be impaired in their color.
  • washing and cleaning agents or fabric softeners often comprise a bleaching agent. Although this allows a thorough cleaning but also leads to the color effect of textiles is affected. In particular, in textiles that have a rather dark hue, such as black, red or blue textiles, fading of the color caused by the bleaching agent can be clearly seen, after only a few washes. White textiles, on the other hand, often turn yellow over time.
  • EP 1 794 276 B1 discloses an ethanolic solution of a dye which is used to treat the polyester. However, a washing or cleaning agent containing the dye is not explicitly described here
  • Detergents and fabric softeners are usually in solid or liquid form. If a dye is then incorporated into it, the corresponding composition assumes the color of the dye. However, this can be undesirable if a certain association is to be awakened by the color of the washing and cleaning agent or laundry dishwasher, which is also found, for example, in the odor component.
  • the object of the present invention is now to provide textile treatment agents for colored textiles, which have a rather dark hue (such as black, dark red or dark blue textiles) which refreshes the hue and at best does not or to a lesser extent have the aforementioned disadvantages.
  • a rather dark hue such as black, dark red or dark blue textiles
  • a composition for treating textiles comprising at least one surfactant and a dye in which the dye is preferably not in direct contact with the at least one surfactant, accomplishes this task.
  • the dye is an organic compound which is used as a bluing agent for textiles to enhance the whiteness.
  • An organic compound has at least one covalent bond between hydrogen and carbon.
  • Direct contact for the purposes of the present invention means that dye and surfactant can not interact with each other within the composition, so there is no chemical or physical reaction between the two, which could interfere with each other in their effectiveness.
  • Textiles in the sense of the present application are all textile fabrics. These can consist of natural and / or synthetic materials. These materials may be in the form of processed fibers or in the form of nonwoven applications. Processing fibers here means weaving, braiding, spinning or other well-known processing methods of fibers for the production of textile fabrics.
  • An example of natural materials from which textiles according to the invention may consist are, for example, cotton, linen, silk, hemp fibers or wool.
  • Synthetic textiles may include, for example, polyester or polyamide.
  • the influence of oxygen or UV light on the dye can be reduced thereby, so that a further improvement in terms of storage stability can be achieved here as well.
  • the optical appearance remains stable, especially in liquid compositions. Streaks or agglomerations can thus be avoided.
  • composition according to the invention also makes it possible that the dye does not have any undesired influence on the active substances contained in the composition, such as, for example, surfactants.
  • the composition according to the invention thus makes it possible to provide a storage-stable product which exhibits the same optimum action over a longer period of time.
  • the dye allows a refreshing of the color impression of textiles.
  • the white impression can be improved in light and especially white textiles.
  • the remission value (Y value) is lowered by treatment with the composition according to the invention.
  • the remission value indicates in percentage terms how much lighter a colorful or achromatic hue is compared to a pure white surface.
  • a pure white area has a remission value of 100% and an ideal black area has a remission value of 0%.
  • the dye is not in direct contact with the surfactant, it can be incorporated according to the invention in a first preferred embodiment in soap needles. These soap needles are then included as an ingredient in the composition.
  • the composition is preferably a solid composition, in particular a solid detergent and cleaner.
  • Soaps in the sense of the present application are sodium or potassium salts of fatty acids. They are available as a solid preparation. Their shape has an elongated extension, which resembles that of needles of coniferous trees. This means that the soap needles preferably have a cross-sectional ratio in the range from 1: 5 to 1:20. The needles preferably have a diameter of 0.5 to 2 mm and a length of 2 to 10 mm.
  • the dye is contained in the core of a core-shell capsule, wherein the shell comprises gelatin and in particular consists thereof.
  • the prior art discloses core-shell capsules and, more particularly, microcapsules incorporating ingredients.
  • WO 2007/017070 A1 discloses a capsule comprising an active ingredient for an aqueous, liquid detergent and cleaner.
  • the capsule comprises an aluminum silicate and a silica in a matrix, wherein the aluminum silicate and the silica are present in a ratio of 1:10 to 10: 1.
  • US 6,855,681 discloses a detergent composition comprising a matrix-encapsulated active ingredient.
  • the matrix of the capsule contains a hydrated anionic gum and the encapsulated active ingredient is preferably a perfume.
  • the dye is preferably a monoazo dye.
  • the maximum extinction coefficient in a wavelength range of 400 to 750 nm is preferably greater than 1 .000 L / mol / cm, in an aqueous solution having a pH range of 7 to 1 1, the dye is preferably not charged or has a anionic charge, most preferably the dye is nonionic. It is inventively preferred if the dye in solution or dispersion (ethanol, at 20 ° C) has an absorption maximum in a wavelength range of 510 and 640 nm, more preferably from 530 to 620 nm.
  • the dye is one of the following general formula 1: in which F stands for the monoazo dye.
  • the aforementioned extinction coefficient relates to this dye F in the compound FH in an ethanolic solution.
  • L is an organic group which combines the monoazo dye F with the carboxyl group CO2M.
  • This linking group L preferably has one Molecular weight in the range of 14 to 1000 g / mol, in particular from 14 to 600 g / mol, particularly preferably from 28 to 300 g / mol.
  • the group L comprises substantially exclusively carbon and hydrogen and optionally further oxygen and / or nitrogen.
  • L is preferably an O-20-alkyl group which optionally has ethers and / or esters and / or amide groups as branching points.
  • the alkyl chain may be substituted according to the invention. Possible substituents are -OH, -CN, -NO 2, -SO 2 CH 3, - CL, -BR.
  • M is any counterion, usually hydrogen, sodium or potassium.
  • the dye comprises the following general formula 2:
  • R is an O-20, or C 2-12 alkyl radical which optionally has ether and / or ester and / or amide groups as branching points and the alkyl chain furthermore optionally with, for example, -OH, -CN, NO 2, -SO 2 CH 3, -CL, - BR is substituted;
  • R and R 2 are each independently selected and represent, for example, hydrogen; preferably each independently selected from electron-withdrawing groups such as -CN, -NO 2, -SO 2 CH 3, -CL, -BR;
  • Z is selected from an electron-withdrawing group and is preferably selected from cyano, sulfamoyl, N: N-diethylsulfamoyl, N-ethylsulfamoyl, trifluoromethyl, ethylsulfonyl, nitrosylfonyl, N -methylsulfamoyl, chloro and bromo; in particular Z is a nitro group;
  • Y hydrogen, a short one Alkyl, halo, -NHCOR, preferably hydrogen, -CH3 or -Cl;
  • X is hydrogen, a short (C 1-4) alkoxy chain or halogen, in particular hydrogen, methoxy, ethoxy or chloride.
  • Examples of short-chain alkyl and / or alkoxy radicals are methyl, ethyl, n-propyl, n-butyl, ethoxy and methoxy.
  • Examples of the optionally substituted, short-chain alkyl radicals which are represented by R in the general formula 2 are ⁇ -hydroxyethyl, ⁇ -cyanoethyl, ⁇ - (methoxy or ethoxy) -ethyl, ⁇ -methoxypropyl, benzyl- or ⁇ -phenylethyl, ⁇ -methoxycarbonyl-ethyl or ⁇ -acetoxyethyl.
  • the dye of the invention may, for example, have the following general formula 3:
  • Particularly preferred dyes are Basic Violet 10, Liquitint® Violet 200, Liquitint Violet CT or compounds of the following formula:
  • each R and R 2 is independently selected from R,
  • each R is independently selected from H, linear or branched C 1 -C 4 alkyl groups, benzyl and mixtures thereof, each R 'is independently selected from H, CH20 (CH2CH20) zH and
  • each R is independently selected from H, Chta,
  • the core comprises in particular a water-in-oil emulsion.
  • the core preferably consists of this water-in-oil emulsion.
  • the dye is contained in the water component of the emulsion.
  • the oil component of the emulsion may comprise, for example, a silicone oil. Such can then also be an effective component of the composition of the invention and serve, for example, the care of the textiles. Furthermore, it is possible according to the invention to use a perfume oil in the emulsion together with the dye. Other possible oil components which can be used in a composition for the treatment of textiles are well known to the person skilled in the art.
  • the composition is preferably a washing and cleaning agent, a fabric softener, a stain salt, a cloth impregnated with detergent or cleaning agent.
  • a washing and cleaning agent can according to the invention be present both in solid and in liquid form.
  • the fabric softener is preferably in liquid form.
  • the washing and cleaning agent is preferably a clear washing or cleaning agent with yield strength.
  • Such soap needles and in particular core-sheath Capsules are homogeneously distributed. These do not decrease over a longer period but remain evenly dispersed within the composition. This allows for a consistent concentration of dispersed particles within the full useful life of the user without, for example, shaking or stirring the product prior to use to obtain an even distribution of the active ingredients.
  • a yield point is understood to be the smallest stress (force per surface) above which a plastic substance behaves rheologically like a liquid. Such yield value is usually determined by measurement with a rheometer. In particular, absolutely measuring rheometers are suitable here, which determine absolute measured values independently of the measuring geometry used, such as, for example, the rheometer AR 1000-N from Texas Instruments.
  • a clear washing and cleaning agent in the sense of the present invention is one which is transparent or at least translucent. In contrast, there is cloudy, so an intransparent or non-translucent means. Transparency means matter that is transparent to the eye. Translucent are those materials that are translucent.
  • compositions according to the invention comprise at least one surfactant.
  • the at least one surfactant is preferably selected from the group of anionic, nonionic or cationic and / or amphoteric surfactants. In this case, mixtures of different surfactant types can be used. However, it is also possible according to the invention to use a plurality of surfactants of one type, for example a plurality of nonionic surfactants.
  • the composition according to the invention preferably comprises mixtures of anionic and nonionic surfactants.
  • composition comprises an anionic surfactant
  • anionic surfactant this is preferably selected from the group consisting of C9-i3-alkylbenzenesulfonates, olefinsulfonates, C12 -is-alkanesulfonates, ester sulfonates, alk (en) ylsulfates, fatty alcohol ether sulfates and mixtures thereof. It has been found that these sulfonate and sulfate surfactants are particularly suitable for the preparation of stable liquid compositions with yield point. Liquid compositions comprising anionic surfactant C9-i3-alkylbenzenesulfonates and fatty alcohol ether sulfates have particularly good dispersing properties.
  • Preferred surfactants of the sulfonate type are C9-i3-alkylbenzenesulfonates, olefinsulfonates, that is to say mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as are obtained, for example, from C12-monoolefins having a terminal or internal double bond by sulfonating with gaseous sulfur trioxide and subsequent alkaline or acidic hydrolysis of the sulfonation obtained.
  • Alk (en) ylsulfates are the alkali metal salts and, in particular, the sodium salts of the sulfuric monoesters of C 12-18 fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or the C 10 -C 20 oxo alcohols and those half esters secondary Alcohols of these chain lengths are preferred.
  • Ci2-Ci6-alkyl sulfates and Ci2-Ci5-alkyl sulfates and Cw-cis-alkyl sulfates are preferred.
  • 2,3-alkyl sulfates are also suitable anionic surfactants.
  • fatty alcohol ether sulfates such as the sulfuric acid monoesters of straight-chain or branched C7-2i alcohols ethoxylated with from 1 to 6 mol of ethylene oxide, such as 2-methyl-branched C9-11 alcohols having on average 3.5 moles of ethylene oxide (EO) or C12 -18 Fatty alcohols with 1 to 4 EO are suitable.
  • composition of the invention contains a mixture of sulfonate and sulfate surfactants.
  • the composition contains C9-i3-alkylbenzenesulfonates and fatty alcohol ether sulfates as anionic surfactant.
  • the composition may also contain soaps.
  • soaps Suitable are saturated and unsaturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, (hydrogenated) erucic acid and behenic acid and, in particular, soap mixtures derived from natural fatty acids, for example coconut, palm kernel, olive oil or tallow fatty acids.
  • the anionic surfactants and the soaps may be in the form of their sodium, potassium or magnesium or ammonium salts.
  • the anionic surfactants are in the form of their sodium salts.
  • Further preferred counterions for the anionic surfactants are also the protonated forms of choline, triethylamine, monoethanolamine or methylethylamine.
  • the composition may also comprise at least one nonionic surfactant in addition to the anionic surfactant.
  • the nonionic surfactant includes alkoxylated fatty alcohols, alkoxylated fatty acid alkyl esters, fatty acid amides, alkoxylated fatty acid amides, polyhydroxy fatty acid amides, alkylphenol polyglycol ethers, amine oxides, alkyl polyglucosides, and mixtures thereof.
  • the nonionic surfactant used is preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 4 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or may contain linear and methyl-branched radicals in the mixture, as they are usually present in Oxoalkoholresten.
  • EO ethylene oxide
  • alcohol ethoxylates having linear residues of alcohols of native origin 12 to 18 C atoms, for example from coconut, palm, tallow or oleyl alcohol, and on average 5 to 8 EO per mole of alcohol are preferred.
  • the preferred ethoxylated alcohols include, for example, C 12-14 alcohols with 4 EO or 7 EO, C 9 -n-alcohol with 7 EO, C ms alcohols with 5 EO, 7 EO or 8 EO, C 12-15 alcohols with 5 EO or 7 EO and mixtures of these.
  • the degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number.
  • Preferred alcohol ethoxylates have a narrow homolog distribution (narrow rank ethoxylates, NRE).
  • fatty alcohols with more than 12 EO can also be used.
  • Nonionic surfactants which contain EO and PO (propylene oxide) groups together in the molecule can also be used according to the invention. Also suitable are also a mixture of a (more) branched ethoxylated fatty alcohol and an unbranched ethoxylated fatty alcohol, such as a mixture of a Ci6-is fatty alcohol with 7 EO and 2-propylheptanol with 7 EO. Particularly preferably, the washing, cleaning, aftertreatment or washing aid contains a Ci2-i8 fatty alcohol with 7 EO or a C-ms oxo alcohol with 7 EO as a nonionic surfactant.
  • composition of the invention may further comprise one or more solvents. These may be water and / or non-aqueous solvents. Preferably, the composition contains water as the main solvent.
  • the composition may further comprise non-aqueous solvents. Suitable non-aqueous solvents include monohydric or polyhydric alcohols, alkanolamines or glycol ethers.
  • the solvents are preferably selected from ethanol, n-propanol, i-propanol, butanols, glycol, propanediol, butanediol, methylpropanediol, glycerol, diglycol, propyldiglycol, butyldiglycol, hexylene glycol, ethylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol propyl ether, ethylene glycol mono-n-butyl ether, diethylene glycol methyl ether, Diethylene glycol ethyl ether, propylene glycol methyl ether, propylene glycol ethyl ether, propylene glycol propyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, methoxytriglycol, ethoxytriglycol, butoxytriglycol, 1-butoxyethoxy-2-propanol,
  • composition according to the invention may further comprise builders and / or alkaline substances.
  • builders for example, polymeric polycarboxylates are suitable. These are, for example, the alkali metal salts of polyacrylic acid or polymethacrylic acid, for example, those having a molecular weight of 600 to 750,000 g / mol.
  • Suitable polymers are in particular polyacrylates, which preferably have a molecular weight of from 1,000 to 15,000 g / mol. Because of their superior solubility, this can be Group in turn, the short-chain polyacrylates, the molecular weights of from 1,000 to 10,000 g / mol, and particularly preferably from 1,000 to 5,000 g / mol, have to be preferred.
  • copolymeric polycarboxylates in particular those of acrylic acid with methacrylic acid and of acrylic acid or methacrylic acid with maleic acid.
  • the polymers may also contain allylsulfonic acids, such as allyloxybenzenesulfonic acid and methallylsulfonic acid, as a monomer.
  • Suitable builders which may be present in the composition according to the invention are, in particular, silicates, aluminum silicates (in particular zeolites), carbonates, salts of organic di- and polycarboxylic acids and mixtures of these substances.
  • Organic builders which may furthermore be present in the composition according to the invention are, for example, the polycarboxylic acids which can be used in the form of their sodium salts, polycarboxylic acids meaning those carboxylic acids which carry more than one acid function.
  • polycarboxylic acids meaning those carboxylic acids which carry more than one acid function.
  • these are, for example, citric acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, sugar acids, aminocarboxylic acids, nitrilotriacetic acid (NTA), methylglycinediacetic acid (MGDA) and derivatives thereof and mixtures thereof.
  • Preferred salts are the salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures thereof.
  • soluble builders such as, for example, citric acid, or acrylic polymers having a molar mass of from 1,000 to 5,000 g / mol.
  • alkaline substances or wash alkalis are chemicals for raising and stabilizing the pH of the composition.
  • composition may contain other components described in the prior art, such as optical brighteners, complexing agents, bleaches, bleach activators, dyes and fragrances, antioxidants, builders, enzymes, enzyme stabilizers, antimicrobial agents, graying inhibitors, anti-redeposition agents, pH adjusters, electrolytes, Detergency booster, vitamins, proteins, foam inhibitors and / or UV absorbers.
  • optical brighteners complexing agents, bleaches, bleach activators, dyes and fragrances
  • antioxidants builders, enzymes, enzyme stabilizers, antimicrobial agents, graying inhibitors, anti-redeposition agents, pH adjusters, electrolytes, Detergency booster, vitamins, proteins, foam inhibitors and / or UV absorbers.
  • composition according to the invention is a fabric softener, it usually comprises a fabric softening compound.
  • the fabric softening compound is selected from the group of quaternary ammonium compounds, polysiloxanes, fabric softening clays and mixtures thereof. These compounds are effective and commercially available fabric softening compounds.
  • the fabric softener contains a quaternary ammonium compound as fabric softening compound.
  • the quaternary ammonium compound is a compound of the following general formula (A):
  • R 4 is an aliphatic alk (en) yl radical having 1 1 to 21 carbon atoms with 0, 1, 2 or 3
  • R 5 is H, OH or O (CO) R 7 ,
  • R 6 is independently of R 5 is H, OH or 0 (CO) R 8 , wherein R 7 and R 8 are independent
  • n, n and p can each independently have the value 1, 2 or 3 and
  • X " may be either a halide, methosulfate, methophosphate or phosphate ion, as well as mixtures of these anions.
  • composition for laundry softeners conventional components such as fragrance compositions and other additives, such as alcohols, amphoteric or nonionic surfactants, pH buffers, enzymes, fungicides or antioxidants.
  • additives such as alcohols, amphoteric or nonionic surfactants, pH buffers, enzymes, fungicides or antioxidants.
  • the object underlying the present invention is achieved by a process for preparing a composition comprising at least one surfactant and a dye for refreshing the color impression of textiles, wherein the dye is not in direct contact with the at least one surfactant.
  • the preparation of the composition according to the invention ie the solid or liquid washing and cleaning agent or fabric softener is carried out by customary and known methods and processes in which, for example, the ingredients are mixed in stirred tanks, solvent and surfactant (s) are usually presented and the other ingredients in portions to be added.
  • the dye of the invention is preferably added to the composition as one of the last ingredients.
  • the proportion of the dye in the composition is preferably in the range of 0.00001 to 1 wt%, more preferably 0.00001 to 0.005 wt%, and more preferably in the range of 0.0001 to 0.0005 wt%.
  • composition according to the invention is used according to the invention for the treatment of textiles.
  • it finds use for cleaning and / or care of textiles.
  • a composition comprising at least one surfactant and at least one dye is used according to the invention for refreshing the color impression of dyed textiles, in particular black textiles.
  • Liquitint Violet 200 and Liquitint Violet CT are dyes sold under this trade name by the
  • V1 comparative experiment (not according to the invention)
  • a non-woven viscose cloth was printed with the following composition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

Compositions qui contiennent au moins un tensioactif, ainsi qu'un colorant tel qu'un azurant, et qui sont appropriées pour le rafraîchissement de la couleur de textiles teints. Il s'est révélé avantageux que le colorant présent dans la composition ne se trouve pas en contact direct avec le tensioactif.
PCT/EP2016/072415 2015-09-22 2016-09-21 Composition contenant des tensioactifs pour le traitement de textiles avec un colorant WO2017050821A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102015218190.1 2015-09-22
DE102015218190.1A DE102015218190A1 (de) 2015-09-22 2015-09-22 Tensid-enthaltende Zusammensetzung zur Behandlung von Textilien mit einem Farbstoff

Publications (1)

Publication Number Publication Date
WO2017050821A1 true WO2017050821A1 (fr) 2017-03-30

Family

ID=56997486

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2016/072415 WO2017050821A1 (fr) 2015-09-22 2016-09-21 Composition contenant des tensioactifs pour le traitement de textiles avec un colorant

Country Status (2)

Country Link
DE (1) DE102015218190A1 (fr)
WO (1) WO2017050821A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110651081A (zh) * 2017-05-12 2020-01-03 布劳恩斯-海特曼两合公司 用于将纺织材料染色或更新其中的颜色的含有靛类染料的颜色释放产品

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102015119949B4 (de) 2015-11-18 2024-08-14 Brauns-Heitmann Gmbh & Co. Kg Verwendung eines farbabgebendes Produktes zum Färben von oder Auffrischen von Färbungen in textilen Materialien

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2059449A (en) * 1935-05-20 1936-11-03 Albert A Fowler Washing compound
US4990280A (en) * 1988-03-14 1991-02-05 Danochemo A/S Photoactivator dye composition for detergent use
WO2000052120A2 (fr) * 1999-02-27 2000-09-08 Henkel Kommanditgesellschaft Auf Aktien Preparations contenant du peroxyde et des colorants microencapsules
DE10153295A1 (de) * 2001-10-31 2003-05-15 Henkel Kgaa Verfahren zum Färben von Textilien
DE10360842A1 (de) * 2003-12-20 2004-12-16 Henkel Kgaa Waschmittelsystem mit verzögerter Färbemittelwirkung
US6855681B1 (en) 1999-02-02 2005-02-15 Quest International B.V. Detergent composition
WO2007017070A1 (fr) 2005-08-10 2007-02-15 Henkel Kommanditgesellschaft Auf Aktien Produits de lavage et de nettoyage comprenant des capsules facilement solubles
EP1794276B1 (fr) 2004-09-23 2009-04-29 Unilever PLC Compositions de traitement de linge

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2059449A (en) * 1935-05-20 1936-11-03 Albert A Fowler Washing compound
US4990280A (en) * 1988-03-14 1991-02-05 Danochemo A/S Photoactivator dye composition for detergent use
US6855681B1 (en) 1999-02-02 2005-02-15 Quest International B.V. Detergent composition
WO2000052120A2 (fr) * 1999-02-27 2000-09-08 Henkel Kommanditgesellschaft Auf Aktien Preparations contenant du peroxyde et des colorants microencapsules
DE10153295A1 (de) * 2001-10-31 2003-05-15 Henkel Kgaa Verfahren zum Färben von Textilien
DE10360842A1 (de) * 2003-12-20 2004-12-16 Henkel Kgaa Waschmittelsystem mit verzögerter Färbemittelwirkung
EP1794276B1 (fr) 2004-09-23 2009-04-29 Unilever PLC Compositions de traitement de linge
WO2007017070A1 (fr) 2005-08-10 2007-02-15 Henkel Kommanditgesellschaft Auf Aktien Produits de lavage et de nettoyage comprenant des capsules facilement solubles

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110651081A (zh) * 2017-05-12 2020-01-03 布劳恩斯-海特曼两合公司 用于将纺织材料染色或更新其中的颜色的含有靛类染料的颜色释放产品
CN110651081B (zh) * 2017-05-12 2022-03-01 布劳恩斯-海特曼两合公司 用于将纺织材料染色或更新其中的颜色的含有靛类染料的颜色释放产品

Also Published As

Publication number Publication date
DE102015218190A1 (de) 2017-03-23

Similar Documents

Publication Publication Date Title
EP2773736B1 (fr) Produit de lavage ou de nettoyage structuré à limite d'écoulement
DE3518100A1 (de) Gewebeweichmachendes builderhaltiges waschmittel
EP2553077B1 (fr) Agent détergent pour textiles délicats
WO2013186170A1 (fr) Agents de lavage, de nettoyage ou de pré-traitement à pouvoir nettoyant renforcé
WO2008155160A1 (fr) Lessives ou détergents liquides hautement moussants, présentant une viscosité stable
WO2017050821A1 (fr) Composition contenant des tensioactifs pour le traitement de textiles avec un colorant
EP3116984B1 (fr) Mélange de tensioactifs amélioré ayant un degré d'éthoxylation optimisé
EP2414496B1 (fr) Composition d'agent de blanchiment liquide
EP2245131A1 (fr) Agent lavant ou nettoyant parfumé liquide faiblement concentré
DE102011085638A1 (de) Strukturiertes Wasch- oder Reinigungsmittel mit Fließgrenze II
DE102017120042A1 (de) Waschmittel, Verwendung des Waschmittels und Waschverfahren
EP3450532B1 (fr) Utilisation d'un copolymère amodiméthicone / organosilicium, détergent, utilisation du détergent et procédé de lavage
EP2716747A1 (fr) Mélange des agents tensioactifs tres performant et composition detergente le contenant
WO2014053365A1 (fr) Détergents plus puissants dotés d'agents complexants i
WO2013117361A1 (fr) Produit de lavage ou de nettoyage contenant de la cellulose ou un dérivé de cellulose
EP3525924A1 (fr) Composition de détergents à limite d'écoulement
WO1999066019A1 (fr) Agent et procede pour traiter des textiles d'une couleur non blanche sensiblement uniforme
EP3127996A1 (fr) Lessive comprenant une composition facilitant le repassage
EP2929003A1 (fr) Élimination de salissures grasses
WO2014195215A1 (fr) Agents de lavage, de nettoyage ou de pré-traitement à pouvoir nettoyant iii renforcé
EP2904084A1 (fr) Détergents dotés d'agents complexants ii, de performance améliorée
WO2008061845A1 (fr) Lessive ou détergent à viscosité stable
EP3127995A1 (fr) Nouvelle lessive renforçant la blancheur
DE102015215160A1 (de) Neue den Weißgrad verstärkende Waschmittel
CH669209A5 (de) Zum waschen von textilien in waschwasser bei einer temperatur von bis zu 60 c befaehigte waschmittelzusammensetzung.

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 16770744

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 16770744

Country of ref document: EP

Kind code of ref document: A1